Aluminum Containing Patents (Class 420/460)
  • Patent number: 6720088
    Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: April 13, 2004
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson, Richard John Grylls, Ramgopal Darolia
  • Patent number: 6652991
    Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: November 25, 2003
    Assignee: The Governors of the University of Alberta
    Inventors: You Wang, Weixing Chen
  • Patent number: 6635362
    Abstract: Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.
    Type: Grant
    Filed: June 4, 2001
    Date of Patent: October 21, 2003
    Inventor: Xiaoci Maggie Zheng
  • Publication number: 20030170139
    Abstract: A fin and a tube for a high-temperature heat exchanger are made of a nickel-based alloy which contains 2.0 to 5.0% of Al and further contains, as required, at least one selected from the group consisting of 0.1 to 2.5% of Si, 0.8 to 4.0% of Cr, and 0.1 to 1.5% of Mn, the balance being Ni and unavoidable impurities.
    Type: Application
    Filed: March 7, 2003
    Publication date: September 11, 2003
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventor: Akira Mitsuhashi
  • Patent number: 6475642
    Abstract: An oxidation-resistant coating is described, formed of an alloy containing: about 40 to about 50 atom % aluminum and about 0.5 atom % to about 3 atom % tantalum; with a balance of nickel; cobalt, iron, or combinations thereof. The coating may also include chromium and a precious metal, as well as other components, such as zirconium or molybdenum. A method for applying the oxidation-resistant coating to a substrate is also described. The substrate can be formed of superalloy material, e.g., a turbine engine component. Related articles are also disclosed.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: November 5, 2002
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson, Ramgopal Darolia
  • Patent number: 6471791
    Abstract: The invention relates to a coating which contains large volumetric fractions, preferably from 20 to 90% by volume, of NiAl-&bgr; phase in a &ggr; matrix. It contains the following microalloying elements which increase the ductility of the coating (data in % by weight): 0.1-8 Fe and/or 0.1-8 Mo and/or 0.1-8 Ga, where the total Fe, Mo and Ga content is at most 10%. In addition, small amounts of Zr, C and/or B may be added to the alloy, strengthening the &bgr;/&ggr; phase boundaries.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: October 29, 2002
    Assignee: Alstom (Switzerland) Ltd
    Inventors: Mohamed Nazmy, Hans Joachim Schmutzler
  • Patent number: 6410153
    Abstract: A nickel based single crystal superalloy comprising 6-11 wt % cobalt, 4.7-5.7 wt % chromium, 2.4-3.0 wt % molybdenum, 3.0-3.8 wt % tungsten, 3.0-3.8 wt % rhenium, 5.5-7.0 wt % aluminium, 5.0-6.0 wt % tantalum, 0.5-1.0 wt % niobium, 0-0.2 wt % hafnium, 0-150 ppm carbon, 0-100 ppm yttrium, 0-100 ppm lanthanum, 0-5 ppm sulphur and the balance nickel plus incidental impurities. The nickel based single crystal superalloy is suitable for use as a gas turbine engine turbine blade or turbine vane. It is of particular use on cooled turbine blades and turbine vanes which have ceramic thermal barrier coatings, because the superalloy is compatible with the ceramic thermal barrier coating to minimize spalling. The superalloy has lower density than other second generation single crystal superalloys but similar creep strength and oxidation resistance.
    Type: Grant
    Filed: February 14, 2000
    Date of Patent: June 25, 2002
    Assignee: Rolls-Royce plc
    Inventors: Robert W Broomfield, Colin N Jones
  • Patent number: 6355212
    Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.
    Type: Grant
    Filed: January 5, 2000
    Date of Patent: March 12, 2002
    Assignee: Turbocoating SpA
    Inventor: Nelso Antolotti
  • Patent number: 6280857
    Abstract: A coating composition for superalloy structural parts, especially, for gas turbine vanes and blades, which has high resistance to oxidation and corrosion and has excellent mechanical behavior. The coating preferably comprises: 18 to 28 wt % of Co; 11 to 15 wt % of Cr; 11.5 to 14 wt % of Al; 1 to 8 wt % of Re; 1 to 2.3 wt % of Si; 0.2 to 1.5 wt % of Ta; 0.2 to 1.5 wt % of Nb; 0.3 to 1.3 wt % of Y; 0 to 1.5 wt % of Mg; 0 to 0.5 wt % of a total of La and La-series; 0 to 0.1 wt % of B; less than 0.1 wt % of Hf; and less than 0.1 wt % of C. The balance of the coating is Ni. A total of Y, La, and La-series is from 0.3 to 2.0 wt %, and a total of Si and Ta is equal to or less than 2.5 wt %.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: August 28, 2001
    Assignee: Alstom
    Inventors: Marianne Sommer, Hans-Peter Bossmann, Maxim Konter, Peter Holmes, Christoph Toennes, Hans Joachim Schmutzler
  • Patent number: 6242113
    Abstract: A nickel, chromium, iron alloy for use in producing weld deposits. The alloy comprises, in weight percent, about 27 to 31.5 chromium; about 7 to 11 iron; about 0.005 to 0.05 carbon; less than about 1.0 manganese, preferably 0.30 to 0.95 manganese; about 0.60 to 0.95 niobium; less than 0.50 silicon, preferably 0.10 to 0.30 silicon; 0.01 to 0.35 titanium; 0.01 to 0.25 aluminum; less than 0.20 copper; less than 1.0 tungsten; less than 1.0 molybdenum; less than 0.12 cobalt; less than 0.10 tantalum; less than about 0.10 zirconium, preferably 0.002 to 0.10 zirconium; less than about 0.01 sulfur; less than about 0.01 boron, preferably 0.001 to 0.01 boron; less than about 0.02 phosphorous; and balance nickel and incidental impurities.
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: June 5, 2001
    Assignee: Inco Alloys International, Inc.
    Inventor: Samuel D. Kiser
  • Patent number: 6238620
    Abstract: A novel Ni3Al-based alloy exhibits strengths and hardness in excess of the standard base alloy IC-221M at temperatures of up to about 1000° C. The alloy is useful in tool and die applications requiring such temperatures, and for structural elements in engineering systems exposed to such temperatures.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: May 29, 2001
    Assignee: U.T.Battelle, LLC
    Inventors: Chain T. Liu, Everett E. Bloom
  • Patent number: 6096141
    Abstract: Carbide-forming elements are added to nickel-based superalloys so as to minimize grain defects, such as freckle and stray grain defects. More specifically, carbide-forming elements that form from the liquid in the mushy zone of the solidification front of single crystal (SC) and directionally solidified (DS) nickel-based superalloys are added so as to reduce the formation of freckle and stray grain defects in such alloys. A preferred nickel-based superalloy includes, by weight, between about 6.00%-9.25% tantalum, 4.75%-6.50% tungsten, at least about 2.75% rhenium, between about 5.00% to about 7.00% aluminum, at least about 0.10% hafnium and carbon in an amount sufficient (typically between about 0.10-0.15% by weight) to form carbides with other constituents to reduce significantly freckle formation in the mushy zone of the superalloy during casting.
    Type: Grant
    Filed: August 3, 1998
    Date of Patent: August 1, 2000
    Assignee: General Electric Co.
    Inventors: Warren Tan King, Tresa M. Pollock, Christine Louise Zemsky, Wendy Howard Murphy
  • Patent number: 6093262
    Abstract: A ferromagnetic, high strength, corrosion resistant material for use in electromagnetic equipment. The material comprises Cobalt or Nickel or a combination of these elements in an amount equal to or greater than 60% by weight, with the balance comprising one of a group consisting of Beryllium, Lithium, Aluminum, or Titanium. In different embodiments of the invention, 3% or less of the material comprises Beryllium, with the balance comprising Nickel or Cobalt. The material provides adequate yield strength for use downhole in wellbores, is highly resistant to corrosion induced by downhole well fluids and sea water, and has high ferromagnetic characteristics suitable for use in solenoid valves and other downhole well equipment.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: July 25, 2000
    Assignee: PES, Inc.
    Inventor: Brett Bouldin
  • Patent number: 6083327
    Abstract: A Ni based hydrogen occluding alloy having the composition, comprising: by weight:(i) 32-38% of at least one of La or Ce,(ii) 0.1-17% Co,(iii) 0.1-3.5% Al,(iv) 0.5-10% Mn,(v) 0.005-0.1% of hydrogen, withthe balance being Ni and unavoidable impurities, wherein said alloy has a microstructure of a phase having a Ce.sub.2 Ni.sub.7 -type crystal structure and rare earth element hydride dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure and, wherein the amount of said phase having a Ce.sub.2 Ni.sub.7 -type crystal structure is 1-40% by area and the amount of said rare earth element hydride is 0.5-20% by area.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: July 4, 2000
    Assignee: Mitsubishi Materials Corporation
    Inventors: Kouichi Kita, Katsuo Sugahara, Masahiro Wada, Takuya Murai, Takeshi Isobe
  • Patent number: 6066291
    Abstract: Castings based on the nickel aluminide intermetallic alloy IC-221M were melted and poured with an addition of enough molybdenum to bring its concentration to 5 weight %. This resulted in a minimization or elimination of the nickel-zirconium eutectic phase in the dies machined and prepared from these castings. The benefit of eliminating or minimizing the nickel zirconium eutectic phase with the addition of measurable amounts of molybdenum (Mo) to the nickel aluminide (Ni.sub.3 Al) alloy is the increase in the useful service life of the tooling made from it; thus providing the advantages of increased productivity, enhanced quality and reduced costs in a manufacturing setting. Heat treatment of the dies machined and prepared from these castings was also undertaken. The heat treatment regimen includes solution treatment at 2100.degree. F. for 24 hours and aging from between 1150.degree. F. and 1300.degree. F. for between 12 to 24 hours.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: May 23, 2000
    Assignee: United Defense, L.P.
    Inventors: Chien-Hua Chen, Guy Monroe Maddox, Jr., John Edward Orth, Elliott Lee Turbeville
  • Patent number: 5964966
    Abstract: Specific alloys, in particular Ni-based alloys, that can be biaxially textured, with a well-developed, single component texture are disclosed. These alloys have a significantly reduced Curie point, which is very desirable from the point of view of superconductivity applications. The biaxially textured alloy substrates also possess greatly enhanced mechanical properties (yield strength, ultimate tensile strength) which are essential for most applications, in particular, superconductors. A method is disclosed for producing complex multicomponent alloys which have the ideal physical properties for specific applications, such as lattice parameter, degree of magnetism and mechanical strength, and which cannot be fabricated in textured form. In addition, a method for making ultra thin biaxially textured substrates with complex compositions is disclosed.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: October 12, 1999
    Assignee: Lockheed Martin Energy Research Corporation
    Inventors: Amit Goyal, Eliot D. Specht, Donald M. Kroeger, Mariappan Paranthaman
  • Patent number: 5908487
    Abstract: A hydrogen absorbing alloy-packed container packed with a mixture of powders classified respectively into at least two particle-size distribution groups, each of which is different in mean particle size, the powders comprising a hydrogen absorbing alloy singly or the combination of a hydrogen absorbing alloy and a substance not absorbing hydrogen, the mixture having a ratio r.sub.N+1 /r.sub.N, wherein r.sub.N is the mean particle size of the powder having a particle-size distribution of the Nth largest mean particle size, N being an integer of not smaller than 1, and r.sub.N+1 is the mean particle size of the powder having a particle-size distribution of the (N+1)th largest mean particle size, of at least 0.03 to not greater than 0.50. The alloy powders can be selected from the group consisting of lanthanum-nickel, mischmetal-nickel, iron titanium and titanium manganese.
    Type: Grant
    Filed: March 21, 1997
    Date of Patent: June 1, 1999
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Koichi Nishimura, Takahiro Yonesaki, Shin Fujitani, Hiroshi Nakamura, Yumiko Nakamura, Ikuo Yonezu, Hiroshi Watanabe
  • Patent number: 5902700
    Abstract: A hydrogen storage alloy electrode for use in electrochemical hydrogen storage cells, the electrode being in the form of a negative electrode fabricated by sintering a mixture of a hydrogen storage alloy containing manganese and an alloy containing a measured amount of manganese.
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: May 11, 1999
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Takamichi Hirosawa, Takaaki Ikemachi
  • Patent number: 5900334
    Abstract: The present invention provides a hydrogen occluding alloy exhibiting high hydrogen absorption and desorption rates, and excellent initial activation in practical use, and a method of making it. There is provided a hydrogen occluding alloy having a composition comprising, by wt %, 32 to 38% of rare earth elements essentially consisting of La and/or Ce, 0.5 to 3.5% of Al, 0.5 to 10% of Mn, 0.005 to 0.5% of hydrogen, optionally 0.1 to 17% of Co, and the balance being Ni and unavoidable impurities; wherein the alloy has a microstructure characterized in that fine rare earth element hydride is dispersively distributed in a matrix having a CaCu.sub.5 -type crystal structure in a ratio of 0.5 to 20% by area. There are also provided electrodes and batteries containing such alloys, and methods of making and using such electrodes and batteries.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: May 4, 1999
    Assignee: Mitsubishi Materials Corporation
    Inventors: Masahiro Wada, Yoshio Takizawa
  • Patent number: 5830415
    Abstract: The present invention provides a car exhaust purifying filter member which is high in the capacity to collect solid and liquid contents in exhausts and which has such high heat resistance as to be capable of withstanding heat when burned for cleaning and a method of manufacturing the same. A three-dimensional mesh-like metallic porous member made from Ni--Cr--Al and having a three-dimensional framework is heated at 800-1000 .degree. C. in the atmosphere to form on its surface a densely grown fibrous alumina crystal. This member is used as a filter member. Such a filter member shows excellent collecting capacity and corrosion resistance and can withstand high temperatures. Also, it is possible to firmly carry a catalyst on the fibrous alumina crystal formed on the surface. Because of its increased surface area, it has an increased catalyst carrying capacity.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: November 3, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takao Maeda, Masayuki Ishii, Hiroshi Yoshino, Shunsuke Ban
  • Patent number: 5824166
    Abstract: Described is a material handling apparatus for processing heated formed ferrous metal products and/or glass products comprising a face centered cubic crystal intermetallic alloy of a metal aluminide having the property of withstanding repeated thermal cycling from ambient temperature to about 1600.degree. F. wherein the metal is selected from the group consisting of a group VIII metal of the Periodic Table. Also described is an aluminide roll that also is characterized as retaining its ultimate tensile strength at 1600.degree. F. of at least 75% of the tensile strength the roll had at ambient room temperature.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: October 20, 1998
    Assignee: Metallamics
    Inventor: Robert R. McDonald
  • Patent number: 5725691
    Abstract: Alloys for use in structural applications based upon NiAl to which are added selected elements to enhance room temperature ductility and high temperature strength. Specifically, small additions of molybdenum produce a beneficial alloy, while further additions of boron, carbon, iron, niobium, tantalum, zirconium and hafnium further improve performance of alloys at both room temperature and high temperatures. A preferred alloy system composition is Ni--(49.1.+-.0.8%)Al--(1.0.+-.0.8%)Mo--(0.7.+-.0.5%)Nb/Ta/Zr/Hf--(nearly zero to 0.03%)B/C, where the % is at. % in each of the concentrations. All alloys demonstrated good oxidation resistance at the elevated temperatures. The alloys can be fabricated into components using conventional techniques.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: March 10, 1998
    Assignee: Lockheed Martin Energy Systems, Inc.
    Inventor: Chain T. Liu
  • Patent number: 5725687
    Abstract: The present invention relates to a wear-resistant high permeability alloy nsisting of Ni, Nb, C and Fe, a wear-resistant high permeability alloy consisting of Ni, Nb, C and Fe as main components and at least one element selected from the group consisting of Cr, Mo, Ge, Au, Co, V, W, Cu, Ta, Mn, Al, Si, Ti, Zr, Hf, Sn, Sb, Ga, In, Tl, Zn, Cd, rare earth element, platinum element, Be, Ag, Sr, B, P, N, O, S as a secondary component and a method of manufacturing the same and a magnetic recording and reproducing head, and an object of the invention is to obtain an excellent wear-resistant magnetic alloy having easy forging processability, a large effective permeability, a saturated flux density of more than 4000G, and a recrystallization texture of {110}<112>+{311}<112>+{111}<112>, and a wear-resistant high permeability alloy consisting by weight of Ni 60-90%, Nb 0.5-14%, C 0.0003-0.
    Type: Grant
    Filed: October 30, 1995
    Date of Patent: March 10, 1998
    Assignee: The Foundation: The Research Institute of Electric and Magnetic Alloys
    Inventors: Yuetsu Murakami, Katashi Masumoto
  • Patent number: 5669989
    Abstract: A Ni--Fe magnetic alloy consists essentially of: 77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.?Ni!-11.13.times.?Mo!-1.25.times.?Cu!-5.03.times.?M n!)/(2.13.times.?Fe!).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/(Mo average content).vertline..times.100%. A method for producing a magnetic Ni--Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: September 23, 1997
    Assignee: NKK Corporation
    Inventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
  • Patent number: 5628814
    Abstract: A nickel-base superalloy article has a coating having a composition, in weight percent, of from about 10 to about 20 percent cobalt, from about 14 to about 25 percent chromium, from about 2 to about 12 percent aluminum, from 0 to about 0.2 percent yttrium, from about 0.001 to about 3 percent boron, from about 1 to about 10 percent silicon, balance nickel and incidental impurities. The coating is preferably applied by mixing together two powders, one with a higher solidus temperature and one with a lower solidus temperature, whose net composition is that of the coating. The powder mixture is compacted with a binder, applied to a surface of the article, and heated to a temperature above the lower solidus temperature.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: May 13, 1997
    Assignee: General Electric Company
    Inventors: Jim D. Reeves, David E. Budinger, Robert A. Anderson
  • Patent number: 5500057
    Abstract: A Ni-Fe magnetic alloy consists essentially of:77 to 80 wt. % Ni, 3.5 to 5 wt. % Mo, 1.5 to 3 wt. % Cu, 0.1 to 1.1 wt. % Mn, 0.1 wt. % or less Cr, 0.003 wt. % or less S, 0.01 wt. % or less P, 0.005 wt. % or less 0, 0.003 wt. % or less N, 0.02 wt. % or less C, 0.001 to 0.05 wt. % Al, 1 wt. % or less Si, 2.6-6 of the weight ratio of Ca to S, (Ca/S), and the balance being Fe and inevitable impurities, satisfies an equation of 3.2.ltoreq.(2.02.times.[Ni]-11.13.times.[Mo]-1.25.times.[Cu]-5.03.times.[M n])/ (2.13.times.[Fe]).ltoreq.3.8; and has a Mo segregation ratio defined by a seregration equation satisfying 5% or less, the seregration equation being .vertline.(Mo content in a segregation region-Mo average content)/ (Mo average content).vertline..times.100%.A method for producing a magnetic Ni-Fe alloy comprises the steps of: a first heating step of heating an alloy ingot to 1200.degree. to 1300.degree. C. for 10 to 30 hrs; slabbing the heated ingot at a finishing temperature of 950.degree. C.
    Type: Grant
    Filed: October 1, 1993
    Date of Patent: March 19, 1996
    Assignee: NKK Corporation
    Inventors: Tadashi Inoue, Kiyoshi Tsuru, Shinichi Okimoto, Naokazu Yamamura, Tetsuo Yamamoto, Hirohisa Haiji
  • Patent number: 5472663
    Abstract: To improve high-temperature strength, as well as increased resistance to wear due to sparking, a Ni-based alloy sparking plug electrode material for use in an internal combustion engine is provided. Such a Ni-based alloy sparking plug electrode material contain, by weight, from 3.1 to 4.3 of Al, from 0.5 to 1.5% of Si, from 0.45 to 0.65% of Mn, from 0.002 to 0.01% of C, from 0.005 to 0.05% of at least one of Mg and Ca, and, as necessitated, from to 2% of Cr, with the balance substantially Ni and inevitable impurities.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: December 5, 1995
    Assignee: Mitsubishi Materials Corporation
    Inventors: Hideo Kitamura, Kensho Sahira, Akira Mimura
  • Patent number: 5374319
    Abstract: A process is provided for welding a gamma-prime precipitation-strengthened nickel base superalloy by heating the weld area and adjacent region to a ductile temperature, welding while maintaining the entire weld area and adjacent region at the ductile temperature and holding the weldment, weld area and adjacent region at the ductile temperature until the entire weld has solidified. The ductile temperature is above the aging temperature but below the incipient melting temperature of the superalloy.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: December 20, 1994
    Assignee: Chromalloy Gas Turbine Corporation
    Inventors: Richard J. Stueber, Thomas Milidantri, Moshen Tadayon
  • Patent number: 5167732
    Abstract: Nickel aluminide single crystal alloys having improved strength and ductility at elevated temperatures, produced by major elemental additions to strengthen the Ni.sub.3 Al phase by solid solutioning and/or secondary phase formation. The major elemental additions comprise (by weight) 7-20% Al, 0.5-9% molybedenum, 0.5-10% tungsten and 2-15% titanium. Optional minor elemental additions of boron, manganese, silcon and/or hafnium are preferred.
    Type: Grant
    Filed: October 3, 1991
    Date of Patent: December 1, 1992
    Assignee: Textron, Inc.
    Inventor: Subhash K. Naik
  • Patent number: 5116438
    Abstract: A beta phase nickel aluminide microalloyed with gallium having improved ductility. Nickel aluminide intermetallics alloyed with up to about 0.25 atomic percent gallium have significantly improved room temperature ductility over conventional unalloyed beta phase nickel aluminides or beta phase nickel aluminides alloyed with higher percentages of gallium.
    Type: Grant
    Filed: March 4, 1991
    Date of Patent: May 26, 1992
    Assignee: General Electric Company
    Inventors: Ramgopal Darolia, David F. Lahrman
  • Patent number: 5116691
    Abstract: A NiAl nickel aluminide alloyed with yttrium, optionally gallium, and an element selected from the group consisting of chromium, molybdenum and combinations thereof, having improved room temperature ductility and plastic strain. NiAl nickel aluminide intermetallics alloyed with no more than about 5 atomic percent of additional elements have significantly improved room temperature ductility over conventional unalloyed beta phase nickel aluminides or beta phase nickel aluminides alloyed with higher percentages of additional elements. The NiAl nickel aluminide comprises, in atomic percent, at least 50% nickel, about 0.01% to about 0.25% yttrium, about 0 to about 0.15% gallium, about 0.05% to about 4% of an element selected from the group consisting of chromium, molybdenum and combinations thereof, and balance from about 40% to about 49.85% aluminum and trace impurities.
    Type: Grant
    Filed: March 4, 1991
    Date of Patent: May 26, 1992
    Assignee: General Electric Company
    Inventors: Ramgopal Darolia, David F. Lahrman
  • Patent number: 5069179
    Abstract: An internal combustion engine is described which comprises a main combustion chamber and a secondary combustion chamber which is arranged in the cylinder head of the internal combustion engine and is connected via a shot channel to the main combustion chamber. To increase the high-temperature stability, the parts of the secondary combustion chamber which are acted upon by the hot gas jet are made of a material of intermetallic phase.
    Type: Grant
    Filed: October 25, 1999
    Date of Patent: December 3, 1991
    Assignee: Mercedes-Benz AG
    Inventors: Johann Kramer, Rainer Renz
  • Patent number: 5059259
    Abstract: An oxidation- and corrosion-resistant high-temperature alloy of high toughness at room temperature for directional solidification, based on an intermetallic compound of the nickel aluminide type and having the following composition:Al=10-20 atom %Si=0.5-8 atom %Nb=2-10 atom %B=0.1-2 atom %Ni=remainder,the total of Al, Si, Nb and B amounting at most to a value of 25 atom %. The alloy contains at least 90% by volume of the intermetallic phases Ni.sub.3 Al, Ni.sub.3 Si and Ni.sub.3 Nb.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: October 22, 1991
    Assignee: Asea Brown Boveri Ltd.
    Inventors: Mohamed Nazmy, Markus Staubli
  • Patent number: 4990199
    Abstract: An oxidation-resistant and corrosion-resistant high-temperature alloy for directional solidification on the basis of an intermetallic compound of the nickel aluminide type having the following composition:Al=10-16 atomic %Si=0.5-8 atomic %Ta=0.5-9 atomic %Hf=0.1-2 atomic %B=0.1-2 atomic %Ni=the remainderThe alloy has at least 90% by volume of the intermetallic phases Ni.sub.3 Al, Ni.sub.3 Si and Ni.sub.3 Ta.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: February 5, 1991
    Assignee: Asea Brown Boveri Ltd.
    Inventors: Maohamed Nazmy, Markus Staubli
  • Patent number: 4988488
    Abstract: The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: January 29, 1991
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Doohee Kang
  • Patent number: 4983474
    Abstract: A hydrogen absorbing Ni-based alloy comprising 5 to 25% by weight of titanium (Ti), 10 to 37% by weight of zirconium (Zr), 4 to 20% by weight of manganese (Mn), 0.1 to 12% by weight of vanadium (V), 0.01 to 5% by weight of iron (Fe), 0.01 to 4.5% by weight of aluminum (Al), and balance nickel (Ni) and unavoidable impurities, and a sealed Ni-hydrogen rechargeable battery comprising a negative electrode provided with such a hydrogen absorbing alloy as an active material, an Ni positive electrode, a separator and an alkaline electrolyte solution.
    Type: Grant
    Filed: May 17, 1989
    Date of Patent: January 8, 1991
    Assignee: Mitsubishi Metal Corporation
    Inventors: Hidekazu Doi, Ritsue Yabuki
  • Patent number: 4961905
    Abstract: A modified class of nickel aluminide (NiAl) type material is disclosed having useful amounts of toughness and ductility at low temperatures, e.g. room temperature. The basic NiAl material is modified with an additional of the material such as cobalt which produces a structure which is susceptible to undergoing a martensitic transformation. The martensitic structure when produced results in a significant increase in toughness and ductility at low temperatures.
    Type: Grant
    Filed: December 13, 1988
    Date of Patent: October 9, 1990
    Assignee: United Technologies Corporation
    Inventors: Chi C. Law, Scott M. Russell
  • Patent number: 4898794
    Abstract: A hydrogen absorbing Ni,Zr-based alloy comprising 5 to 20% by weight of titanium (Ti), 10 to 37% by weight of zirconium (Zr), 5 to 30% by weight of manganese (Mn), 0.01 to 15% by weight of tungsten (W), 6 to 30% by weight of iron (Fe), and optionally at least one of 0.1 to 7% by weight of Cu, 0.05 to 6% by weight of Cr and 0.01 to 5% by weight of Al, and balance nickel (Ni) and unavoidable impurities; and a sealed Ni-hydrogen rechargeable battery comprising a negative electrode provided with a hydrogen absorbing alloy as an active material, an Ni positive electrode, a separator and an alkaline electrolytic solution, wherein the hydrogen absorbing alloy is composed of such hydrogen absorbing Ni,Zr-based alloy.
    Type: Grant
    Filed: July 17, 1989
    Date of Patent: February 6, 1990
    Assignee: Mitsubishi Metal Corporation
    Inventors: Hidekazu Doi, Ritsue Yabuki
  • Patent number: 4861550
    Abstract: The invention relates to a Ni-base alloy which contains Mo, Al and Fe, and further, as required, one or more of the following: a group consisting of one or more of V, W, Cr and Cu; one or both of B and Ca; and Co. The alloy of the invention has excellent resistance to stress corrosion cracking even after being subjected to thermal processing such as welding without need for solution treatment thereafter.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: August 29, 1989
    Assignee: Mitsubishi Metal Corporation of Tokyo
    Inventors: Takeshi Yoshida, Yoshio Takizawa, Ichiro Sekine
  • Patent number: 4828613
    Abstract: A powdery raw material for manufacturing an anode of a fuel cell comprises a powder of a nickel-base alloy consisting essentially of 0.5-10 percent by weight aluminum, and the balance of nickel and inevitable impurities, and having a mean grain size of 3-20 microns. The nickel-base alloy powder may contain 0.01-1.0 percent by weight oxygen, and/or may have an apparent density of 0.5-3.5 g/cm.sup.3, and a specific surface area of at least 0.12 m.sup.2 /g. Advantageously, the nickel-base alloy powder is formed by means of water-atomization under a condition that the water injection pressure is 400 Kg/cm.sup.2, and the specific water quantity is 0.02-0.2 m.sup.3 /Kg, the thus manufactured anodes exhibit initial anode characteristics as excellent as those of conventional anodes, and possess such excellent high-temperature creep strength and sintering resistance, thereby exhibiting excellent anode characteristics over a long period of time.
    Type: Grant
    Filed: August 17, 1987
    Date of Patent: May 9, 1989
    Assignees: Mitsubishi Kinzoku Kabushiki Kaisha, Mitsubishi Electric Corporation
    Inventors: Koji Hoshino, Fumio Nouda, Seiro Yahata
  • Patent number: 4816216
    Abstract: The present invention relates to an iron-nickel alloy containing from about 30% to about 60% nickel, from about 0.001% to about 0.15% nitrogen, at least one element selected from the group consisting of from about 1% to about 10% molybdenum and from about 0.001% to about 2% aluminum and the balance essentially iron. The alloys demonstrate improved resistance to intermetallic compound formation, improved glass to metal sealing properties, and improved wirebonding performance. The alloys of the present invention have particular utility as a lead frame material for semiconductor packages.
    Type: Grant
    Filed: November 29, 1985
    Date of Patent: March 28, 1989
    Assignee: Olin Corporation
    Inventors: Chung-Yao Chao, John F. Breedis
  • Patent number: 4762558
    Abstract: Reactive sintering process for producing a shaped body containing the nickel aluminide compound Ni.sub.3 Al, which comprises sintering a compacted shaped mass containing an intimate mixture of substances, e.g. including elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni.sub.3 Al, by heating the mass, e.g. in a vacuum, to an elevated sintering temperature, e.g. 500-750.degree. C., sufficiently to initiate an exothermic reaction, and at a heating rate sufficiently for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering sufficiently to form a densified shaped body containing the nickel aluminide compound Ni.sub.
    Type: Grant
    Filed: May 15, 1987
    Date of Patent: August 9, 1988
    Assignee: Rensselaer Polytechnic Institute
    Inventors: Randall M. German, Animesh Bose, David Sims
  • Patent number: 4740354
    Abstract: A nickel-base cast alloy for use in high-temperature forging dies operable in the atmosphere, consisting essentially of 4-10 weight % of Al, 13-23 weight % of Mo and the balance of Ni and impurities. The nickel-base cast alloy may further contain up to 0.1 weight % of at least one of rare earth metals and Y. It may also contain up to 15 weight % of W and/or Ta substituting for a part of Mo. Ni may be replaced by up to 20 weight % of Co. The cast alloy of the present invention has high resistance to compression deformation and oxidation.
    Type: Grant
    Filed: September 19, 1986
    Date of Patent: April 26, 1988
    Assignee: Hitachi, Metals Ltd.
    Inventors: Rikizo Watanabe, Takehiro Ohno, Toshiaki Nonomura
  • Patent number: 4731221
    Abstract: Nickel aluminides and nickel-iron aluminides treated with hafnium or zirconium, boron and cerium to which have been added chromium to significantly improve high temperature ductility, creep resistance and oxidation properties in oxidizing environments.
    Type: Grant
    Filed: October 11, 1985
    Date of Patent: March 15, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Chain T. Liu
  • Patent number: 4725322
    Abstract: A tri-nickel aluminide base alloy composition is provided with a desirable combination of tensile strength and ductility. The composition is prepared to include boron dopant in combination with relatively low percentages of carbon for the high increase in strength achieved. The composition has an Ll.sub.2 of crystalline structure. It is prepared by rapid solidification at a cooling rate of at least 10.sup.3 .degree. C. per second.
    Type: Grant
    Filed: October 3, 1985
    Date of Patent: February 16, 1988
    Assignee: General Electric Company
    Inventors: Shyh-Chin Huang, Keh-Minn Chang, Alan I. Taub
  • Patent number: 4710247
    Abstract: A method for achieving both improved strength and improved ductility in intermediate phases is provided. The method, briefly stated, comprises the steps of providing a melt whose composition substantially corresponds to that of a preselected intermetallic phase having a crystal structure of the Ll.sub.2 type, such as nickel alumininde, modified with from about 0.01 to 2.5 atomic percent boron, and modified further with cobalt substituent metal and rapidly solidifying the melt at a cooling rate of at least about 10.sup.3 .degree. C./second to form a solid body, the principal phase of which is of the Ll.sub.2 type crystal structure in either its ordered or disordered state.
    Type: Grant
    Filed: March 14, 1986
    Date of Patent: December 1, 1987
    Assignee: General Electric Company
    Inventors: Shyh-Chin Huang, Keh-Minn Chang, Alan I. Taub
  • Patent number: 4710243
    Abstract: A wear-resistant alloy of high permeability having an effective permeabil of at least about 3,000 at 1 KHz, a saturation magnetic flux density of at least about 4,000 G, and a recrystallization texture of {110}<112>+{311}<112> is provided. The alloy is produced by cold working a forged or hot worked ingot of an alloy of a desired composition at a cold working ratio of at least about 50%, heating the cold worked alloy at a temperature which is below the m.p. of the alloy and not less than about 900.degree. C., and cooling the heated alloy from a temperature which is not less than an order-disorder transformation point (about 600.degree. C.) of the alloy. Alternatively, the alloy is produced by reheating the cooled alloy to a temperature which is not over than the order-disorder transformation point, and cooling the reheated alloy.
    Type: Grant
    Filed: July 29, 1985
    Date of Patent: December 1, 1987
    Assignee: The Foundation: The Research Institute of Electric and Magnetic Alloys
    Inventors: Hakaru Masumoto, Yuetsu Murakami
  • Patent number: 4676829
    Abstract: Improvements in the positive temperature dependence of yield strength and in the work hardening rate of tri-nickel aluminide base alloys are achieved. The novel alloy composition has seven alloying ingredients as follows:______________________________________ Concentration Ingredient in Atomic % ______________________________________ Ni balance Co 8-12 Al 16-20 Si 4-6 Nb 0.26-0.30 Zr 0.02-0.04 B 0.2-0.7 ______________________________________The novel composition may be prepared by forming a melt of the composition and atomizing the melt with an inert gas to form fine particles with Ll.sub.2 type crystal structure. The powder is densified by heat and pressure to a novel alloy composition having the improvements in positive temperature dependence of yield strength and work hardening rate as noted above.
    Type: Grant
    Filed: October 3, 1985
    Date of Patent: June 30, 1987
    Assignee: General Electric Company
    Inventors: Keh-Minn Chang, Alan I. Taub, Shyh-Chin Huang
  • Patent number: 4668311
    Abstract: A substantial increase in strength of a boron doped nickel aluminide is achieved by employing a substituent metal in the Ni.sub.3 Al composition to replace a part of the aluminum. Vanadium and silicon are successfully substituted for a portion of the aluminum to provide a composition:(Ni.sub.0.75 Al.sub.0.20 X.sub.0.05).sub.99 B.sub.1where X is selected from the group consisting of vanadium or silicon.
    Type: Grant
    Filed: June 5, 1986
    Date of Patent: May 26, 1987
    Assignee: General Electric Company
    Inventors: Shyh-Chin Huang, Keh-Minn Chang, Alan I. Taub
  • Patent number: 4661156
    Abstract: A metal body having high tensile strength and ductility at temperatures over 1000.degree. F. is provided. The body is prepared by hot isostatic pressing of powder formed by atomization of a melt of an alloy. The alloy composition base is according to the formula:(Ni.sub.1-x Al.sub.x).sub.100-y B.sub.ywhere x is between 0.23 and 0.25, and where y is 0.1 to 2.0.The consolidated body is suitable for machining and may be annealed for a couple of hours at temperatures between 800.degree. C. and 1200.degree. C. following such machining.
    Type: Grant
    Filed: October 3, 1985
    Date of Patent: April 28, 1987
    Assignee: General Electric Company
    Inventors: Keh-Minn Chang, Alan I. Taub, Shyh-Chin Huang