Arsenic Base Or Selenium Or Tellurium Base Alloy Containing Metal Patents (Class 420/579)
  • Patent number: 11846015
    Abstract: An Sb—Te-based alloy sintered compact sputtering target having Sb and Te as main components and which contains 0.1 to 30 at % of carbon or boron and comprises a uniform mixed structure of Sb—Te-based alloy particles and fine carbon (C) or boron (B) particles is provided. An average grain size of the Sb—Te-based alloy particles is 3 ?m or less and a standard deviation thereof is less than 1.00. An average grain size of the C or B particles is 0.5 ?m or less and a standard deviation thereof is less than 0.20. When the average grain size of the Sb—Te-based alloy particles is X and the average grain size of the carbon or boron particles is Y, Y/X is within a range of 0.1 to 0.5. This provides an improved Sb—Te-based alloy sputtering target that inhibits generation of cracks in the sintered target and prevents generation of arcing during sputtering.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: December 19, 2023
    Assignee: JX Metals Corporation
    Inventors: Hideyuki Takahashi, Yoshimasa Koido
  • Patent number: 9889425
    Abstract: Provided are an adsorbent for trapping a radioactive iodine gas generated in a process of oxidizing a nuclear fuel at a high temperature after use and a method of preparing the same, and more particularly, a radioactive iodine gas adsorbent which is formed of bismuth as a main component, thereby exhibiting an excellent radioactive iodine gas trapping capability and an excellent thermal stability after trapping, and a method of preparing the same. An adsorbent for trapping a radioactive iodine gas prepared by a method of preparing an adsorbent for trapping a radioactive iodine gas according to the present disclosure may effectively trap a radioactive iodine off-gas generated in a nuclear fuel pre-treated oxidizing process after use. Particularly, the adsorbent may trap iodine in a larger amount, which is twice or more, than a silver-containing zeolite widely used to trap a radioactive iodine gas, and the trapped iodine forms a stable compound, which is more advantageous for long-term storage.
    Type: Grant
    Filed: December 23, 2014
    Date of Patent: February 13, 2018
    Assignee: KOREA ATOMIC ENERGY RESEARCH INSTITUTE
    Inventors: Jae Hwan Yang, Jin-Myeong Shin, Jang Jin Park, Geun-Il Park
  • Publication number: 20150144186
    Abstract: Embodiments disclosed herein include photovoltaic absorber materials (302) and photovoltaic devices (300) having absorber materials (302) with intentionally increased permittivity. Alternative embodiments include methods (200) of producing thin film photovoltaic absorbers (302) from materials having increased permittivity or methods of producing devices having absorbers (302) with increased permittivity. In selected embodiments, the permittivity of an absorber material (302) is increased by incorporating a permittivity increasing material therein.
    Type: Application
    Filed: May 16, 2013
    Publication date: May 28, 2015
    Inventor: Timothy A. Gessert
  • Publication number: 20150075065
    Abstract: The invention provides a processing method for upgrading an organic phase substance by removing heavy element species from the organic phase substance originating from a resource substance in mild environmental conditions, and further provides a method for collecting removed heavy element species and a method for collecting other substances.
    Type: Application
    Filed: October 24, 2014
    Publication date: March 19, 2015
    Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
    Inventors: Tooru Nakamura, Yutaka Hayashi, Akira Suzuki, Richard Brommeland, Andrew Myles
  • Publication number: 20140348203
    Abstract: Provided in one embodiment is a method of identifying a stable phase of an ordering binary alloy system comprising a solute element and a solvent element, the method comprising: determining at least three thermodynamic parameters associated with grain boundary segregation, phase separation, and intermetallic compound formation of the ordering binary alloy system; and identifying the stable phase of the ordering binary alloy system based on the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter by comparing the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter with a predetermined set of respective thermodynamic parameters to identify the stable phase; wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase.
    Type: Application
    Filed: May 20, 2014
    Publication date: November 27, 2014
    Applicant: Massachusetts Institute of Technology
    Inventors: Heather A. Murdoch, Christopher A. Schuh
  • Patent number: 8882975
    Abstract: Provided is an Sb—Te base alloy sinter sputtering target having Sb and Te as its primary component and comprising a structure in which Sb—Te base alloy particles are surrounded by fine carbon or boron particles; wherein, if the mean diameter of the Sb—Te base alloy particles is X and the particle size of carbon or boron is Y, Y/X is within the range of 1/10 to 1/10000. The present invention seeks to improve the Sb—Te base alloy sputtering target structure, inhibit the generation of cracks in the sintered target, and prevent the generation of arcing during the sputtering process.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: November 11, 2014
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Masataka Yahagi, Hideyuki Takahashi, Hirohisa Ajima
  • Patent number: 8784703
    Abstract: A method of making a colloidal solution of high confinement semiconductor nanocrystals includes: forming a first solution by combining a solvent, growth ligands, and at most one semiconductor precursor; heating the first solution to the nucleation temperature; and adding to the first solution, a second solution having a solvent, growth ligands, and at least one additional and different precursor than that in the first solution to form a crude solution of nanocrystals having a compact homogenous semiconductor region. The method further includes: waiting 0.5 to 20 seconds and adding to the crude solution a third solution having a solvent, growth ligands, and at least one additional and different precursor than those in the first and second solutions; and lowering the growth temperature to enable the formation of a gradient alloy region around the compact homogenous semiconductor region, resulting in the formation of a colloidal solution of high confinement semiconductor nanocrystals.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: July 22, 2014
    Assignee: Eastman Kodak Company
    Inventors: Keith Brian Kahen, Matthew Holland, Sudeep Pallikkara Kuttiatoor
  • Publication number: 20140099232
    Abstract: A method of forming a sheet of semiconductor material utilizes a system. The system comprises a first convex member extending along a first axis and capable of rotating about the first axis and a second convex member spaced from the first convex member and extending along a second axis and capable of rotating about the second axis. The first and second convex members define a nip gap therebetween. The method comprises applying a melt of the semiconductor material on an external surface of at least one of the first and second convex members to form a deposit on the external surface of at least one of the first and second convex members. The method further comprises rotating the first and second convex members in a direction opposite one another to allow for the deposit to pass through the nip gap, thereby forming the sheet of semiconductor material.
    Type: Application
    Filed: March 15, 2013
    Publication date: April 10, 2014
    Applicant: Corning Incorporated
    Inventors: Samir Biswas, Douglass Lane Blanding, Glen Bennett Cook, Prantik Mazumder, Kamal Kishore Soni, Balram Suman
  • Patent number: 8679377
    Abstract: A gamma radiation source comprises 75Selenium wherein the 75Selenium is provided in the form of compounds, alloys or mixtures with one or more nonmetals which upon irradiation do not produce products capable of sustained emission of radiation which would unacceptably interfere with the gamma radiation of 75Selenium. A further gamma radiation source comprises 75Selenium wherein the 75Selenium is provided in the form of compounds, alloys or mixtures with one or more metals or nonmetals, the neutron irradiation of which does produce products capable of sustained emission of radiation which would acceptably complement the gamma radiation of 75Selenium. Further, the gamma radiation source may have components that are separately irradiated before being combined and the components may be of natural isotopic composition or of isotopically modified composition so that the subsequent radiation peaks may also be adjusted in relative frequency.
    Type: Grant
    Filed: December 5, 2012
    Date of Patent: March 25, 2014
    Inventors: John J. Munro, III, Kevin J. Schehr
  • Publication number: 20130042801
    Abstract: Embodiments described herein provide processes for forming and removing epitaxial films and materials from growth wafers by epitaxial lift off (ELO) processes. In some embodiments, the growth wafer has edge surfaces with an off-axis orientation which is utilized during the ELO process. The off-axis orientation of the edge surface provides an additional variable for controlling the etch rate during the ELO process- and therefore the etch front may be modulated to prevent the formation of high stress points which reduces or prevents stressing and cracking the epitaxial film stack. In one embodiment, the growth wafer is rectangular and has an edge surface with an off-axis orientation rotated by an angle greater than 0° and up to 90° relative to an edge orientation of <110> at 0°.
    Type: Application
    Filed: August 15, 2011
    Publication date: February 21, 2013
    Inventors: Thomas Gmitter, Gang He, Melissa Archer, Siew Neo
  • Publication number: 20120288403
    Abstract: The present invention provides a GaAs single crystal wafer and a method of manufacturing the same, wherein the wafer is characterized in that, when the strain in the radial direction in the GaAs single crystal wafer is expressed as Sr and the strain in the tangential direction on the circumference of the same is expressed as St, the residual stress in a wafer plane of the semi-insulating GaAs wafer denoted by |Sr?St| is smaller than 1.0×10?5 in the center area of such wafer plane and in that the wafer has such a region in which the value |Sr?St| is not smaller than 1.0×10?5 in the outer area and has such a region in which the value |Sr?St| is smaller than 1.0×10?5 in the direction [011] in the outer area of such wafer plane.
    Type: Application
    Filed: May 1, 2012
    Publication date: November 15, 2012
    Applicant: HITACHI CABLE, LTD.
    Inventor: Takashi KIMURA
  • Publication number: 20120282133
    Abstract: Systems and methods are disclosed for crystal growth using VGF and VB growth processes to reduce body lineage. In one exemplary embodiment, there is provided a method of inserting an ampoule with raw material into a furnace having a heating source, growing a crystal using a vertical gradient freeze process wherein the crystallizing temperature gradient is moved relative to the crystal and/or furnace to melt the raw material and reform it as a monocrystalline compound, and growing the crystal using a vertical Bridgman process on the wherein the ampoule/heating source are moved relative each other to continue to melt the raw material and reform it as a monocrystalline compound.
    Type: Application
    Filed: May 30, 2012
    Publication date: November 8, 2012
    Inventors: Weiguo Liu, A. Grant Elliot
  • Publication number: 20120128915
    Abstract: There is provided a method for manufacturing a GaAs wafer comprising: growing a GaAs single crystal by an LEC method; and fabricating a GaAs wafer by slicing the GaAs single crystal obtained by growing the GaAs single crystal, wherein in growing the GaAs single crystal, a crystal-melt interface between the GaAs single crystal and a raw material melt is formed into a convex-shape toward the raw material melt side, and a ratio T1/T2 of a length T1 from an interface between the raw material melt and a liquid encapsulant to a tip of the GaAs single crystal, and an outer diameter T2 of the GaAs single crystal, is in a range of 0.25?T1/T2?0.45, and the GaAs wafer obtained by fabricating the GaAs wafer has a universal hardness of 4000 N/mm2 or more and 4850 N/mm2 or less uniformly in a wafer surface.
    Type: Application
    Filed: November 14, 2011
    Publication date: May 24, 2012
    Applicant: HITACHI CABLE, LTD.
    Inventor: Takeshi KIMURA
  • Publication number: 20120091404
    Abstract: The inventors demonstrate herein that various Zintl compounds can be useful as thermoelectric materials for a variety of applications. Specifically, the utility of Ca3AlSb3, Ca5Al2Sb6, Ca5In2Sb6, Ca5Ga2Sb6, is described herein. Carrier concentration control via doping has also been demonstrated, resulting in considerably improved thermoelectric performance in the various systems described herein.
    Type: Application
    Filed: October 19, 2011
    Publication date: April 19, 2012
    Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
    Inventors: G. Jeffrey Snyder, Eric Toberer, Alex Zevalkink
  • Publication number: 20110318221
    Abstract: An embodiment of the invention provides a single crystal cleaved from a larger crystal and having a cleavage surface that extends along a natural crystallographic plane of the single crystal, the cleavage surface produced by generating a stress field to propagate a crack in the larger crystal along the natural plane, so that during cracking by the stress field a magnitude of a derivative of an energy release rate, G(?), generated by the stress field at a front of the crack as a function of angular deviation, ?, from the natural plane, is less than or equal to twice an effective step energy, ?e, divided by a step height, h.
    Type: Application
    Filed: September 7, 2011
    Publication date: December 29, 2011
    Applicant: FREIBERGER COMPOUND MATERIALS GMBH
    Inventors: Ralf Hammer, Manfred Jurisch
  • Patent number: 7927516
    Abstract: A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.
    Type: Grant
    Filed: September 20, 2005
    Date of Patent: April 19, 2011
    Assignee: The Regents of the University of California
    Inventors: Geoffrey F. Strouse, Jeffrey A. Gerbec, Donny Magana
  • Publication number: 20100247489
    Abstract: The present invention relates to a composition comprising one or more minerals selected from the group consisting of selenium, molybdenum or tungsten, which is carried out galenically or chemically in a way that the mineral or minerals are released completely or in part, just before, during or shortly after arrival at the large intestine, and their use in the manufacture of a medicament for administering to a mammal for the prevention or reduction of gas formation in the colon thus conditioned abdominal complaints, particularly bloatings, meteorism or abdominal cramps. Furthermore, the invention relates to a procedure for the isolation of acetogenic and butyrogenic bacterial strains that are suitable for therapeutic purposes outlined above.
    Type: Application
    Filed: December 21, 2007
    Publication date: September 30, 2010
    Inventor: Roland SAUR-BROSCH
  • Publication number: 20090283761
    Abstract: A method of dividing single crystals, particularly of plates of parts thereof, is proposed, which can comprise: pre-adjusting the crystallographic cleavage plane (2?) relative to the cleavage device, setting a tensional intensity (K) by means of tensional fields (3?, 4?), determining an energy release rate G(?) in dependence from a possible deflection angle (?) from the cleavage plane (2?) upon crack propagation, controlling the tensional fields (3?, 4?) such that the crack further propagates in the single crystal, wherein G(0)?2?e(0) and simultaneously at least one of the following conditions is satisfied: ? ? G ? ? ? ? = 0 ? 2 ? ? e h ? ? if ? ? ? 2 ? G ? ? 2 ? 0 ? ? or ( 2.1 ) ? ? G ? ? ? ? 2 ? ? e h ? ? ? ? : ? ? 1 < ? < ? 2 , ( 2.
    Type: Application
    Filed: November 14, 2008
    Publication date: November 19, 2009
    Inventors: Ralf HAMMER, Manfred Jurisch
  • Publication number: 20090235969
    Abstract: A thermoelectric material and a method of fabricating a thermoelectric material are provided. The thermoelectric material includes a compound having an elemental formula of A1?xB1+yC2+z and having a coefficient of thermal expansion greater than 20 parts-per-million per degree Celsius in at least one direction at one or more operating temperatures. The A component of the compound includes at least one element selected from the group consisting of: at least one Group Ia element and at least one Group Ib element, the B component of the compound includes at least one element selected from the group consisting of: at least one Group V element and at least one Group VIII element, and the C component of the compound includes at least one Group VI element. In addition, x is between ?0.2 and 0.3, y is between ?0.2 and 0.4, and z is between ?0.2 and 0.8.
    Type: Application
    Filed: January 23, 2009
    Publication date: September 24, 2009
    Applicants: The Ohio State University Research Foundation, The Board of Trustee of Michigan State University
    Inventors: Joseph P. Heremans, Vladimir Jovovic, Donald T. Morelli
  • Publication number: 20080292877
    Abstract: The present invention provides a method of cleaning a GaAs substrate with less precipitate particles after cleaning. This cleaning method comprises an acid cleaning step (S11), a deionized water rinsing step (S12), and a rotary drying step (S13). First, a GaAs substrate with a mirror finished surface is immersed in an acid cleaning solution in the acid cleaning step (S11). In the acid cleaning step, the cleaning time is less than 30 seconds. Next, the deionized water rinsing step performs the cleaned GaAs substrate with deionized water (S12) to wash away the cleaning solution deposited thereon. Subsequently, the rotary drying step dries the GaAs substrate deposited on deionized water (S13). This provides the cleaned GaAs substrate with less precipitate particles.
    Type: Application
    Filed: April 25, 2005
    Publication date: November 27, 2008
    Inventors: Yusuke Horie, Takayuki Nishiura, Tomoki Uemura
  • Patent number: 7056471
    Abstract: The present invention relates to nanocrystals consisting of a homogeneous ternary or quaternary alloy having the composition M11-xM2xA and M11-xM2xAyB1-y, respectively, a process for its production, as well as to uses of such nanocrystals such as as short wavelength light-emitting devices, and in the detection of analytes, in particular biomolecules.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: June 6, 2006
    Assignee: Agency for Science Technology & Research
    Inventors: Mingyong Han, Xinhua Zhong, Wolfgang Knoll
  • Patent number: 6875377
    Abstract: A gamma radiation source comprising selenium-75 or a precursor therefore, wherein the selenium is provided in the form of one or more thermally stable compounds, alloys, or mixed metal phases.
    Type: Grant
    Filed: April 20, 2000
    Date of Patent: April 5, 2005
    Assignee: AEA Technology PLC
    Inventor: Mark Golder Shilton
  • Publication number: 20040106065
    Abstract: An phase-change optical disk comprises a substrate, a first protective layer, a first thermostable layer, a recording layer, a second thermostable layer, a second protective layer, an absorptance control layer, and a heat-diffusing layer which are provided in this order from a side on which a laser beam comes thereinto, wherein a recording layer material has composition ratios which are within a range surrounded by composition points of B3 (Bi3, Ge46, Te51), C3 (Bi4, Ge46, Te50), D3 (Bi5, Ge46, Te49), D5 (Bi10, Ge42, Te48), C5 (Bi10, Ge41, Te49), and B5 (Bi7, Ge41, Te52) on a triangular composition diagram. Recrystallization is not caused even when information is recorded on an inner circumferential portion, a reproduced signal is scarcely deteriorated even when rewriting is performed multiple times, and any erasing residue of amorphous matters scarcely appears at an outer circumferential portion.
    Type: Application
    Filed: September 8, 2003
    Publication date: June 3, 2004
    Applicant: HITACHI MAXELL, LTD.
    Inventors: Makoto Miyamoto, Reiji Tamura, Akira Kashiwakura, Hiroshi Shirai, Yoshihiro Ikari, Makoto Iimura, Yumiko Anzai, Kazuyo Umezawa
  • Patent number: 6273969
    Abstract: The present invention relates to an alloy comprising a first element A, a second element B, a third element C, and a fourth element D. In the alloy, first element A and second element B are present as a binary compound AB, and third element C and fourth element D are present as a binary compound CD. In addition, the alloy is substantially free from binary compounds AD, BC, AC, and BD. These alloys can be characterized as semiconducting, quasi-binary, single phase alloys having the formula (AB)x(CD)1−x, where x is between 0 and 1 and where A, B, C, and D are different. The present invention also relates to a method of producing an alloy. The method includes providing a first binary material AB and providing a second binary material CD. The first binary material AB and the second binary material CD are contacted under conditions effective to mix the first binary material AB and the second binary material CD without decomposing either the first binary material AB or the second binary material CD.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: August 14, 2001
    Assignee: Rensselaer Polytechnic Institute
    Inventors: Partha S. Dutta, Aleksandar G. Ostrogorsky
  • Patent number: 6180269
    Abstract: A GaAs single crystal substrate and an epitaxial wafer using the same suppress the generation of slips during growth of the epitaxial layer, and improve the breakdown withstanding characteristic of devices fabricated on such substrates. The GaAs single crystal substrate has a mean dislocation density in plane of at most 2×104 cm−2, a carbon concentration of 2.5 to 20.0×1015 cm−3, a boron concentration of 2.0 to 20.0×1016 cm−3, an impurity concentration other than carbon and boron of at most 1×1017 cm−3, an EL2 concentration of 5.0 to 10.0×1015 cm−3, resistivity of 1.0 to 5.0×108 &OHgr;·cm and a mean residual strain measured by photoelastic analysis of at most 1.0×10−5.
    Type: Grant
    Filed: June 16, 1999
    Date of Patent: January 30, 2001
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yoshiaki Hagi, Ryusuke Nakai
  • Patent number: 5705695
    Abstract: The quaternary Zintl material (Et.sub.4 N).sub.4 ?Au(Ag.sub.1-x Au.sub.x).sub.2 Sn.sub.2 Te.sub.9 ! that contains 1-D semiconducting chains composed of four metallic elements is prepared by treating ethylenediamine extracts of a pentanary K--Au--Ag--Sn--Te alloy with Et.sub.4 NI.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: January 6, 1998
    Assignee: NEC Research Institute, Inc.
    Inventors: Robert C. Haushalter, Sandeep S. Dhingra
  • Patent number: 5523022
    Abstract: Novel compound semiconductors are of the general formula, X.sub.5 YZ.sub.4, wherein X is a member selected from the group consisting of Cu, Ag and mixtures thereof, Y is a member selected from the group consisting of Al Ga, Tl and mixtures thereof, and Z is a member selected from the group consisting of Se, S, Te and mixtures thereof. Typical of the compound semiconductors are Cu.sub.5 AlSe.sub.4 and Ag.sub.5 AlSe.sub.4. These compound semiconductors are especially useful for making blue to UV light-emitting devices which include n-type and p-type compound semiconductor layers made of the above compound semiconductors.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: June 4, 1996
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Yoshio Morita
  • Patent number: 5503475
    Abstract: In measuring a cooling curve by means of thermal analysis of cast iron, a compressed powder moulding or sintered moulding of tellurium, bismuth, boron, zinc and/or aluminum is fixed to the inner surface of a cooling curve measuring cup, and a melt is poured into said cup when primaly crystalized and eutectic temperatures based on the metastable solidification of iron, cementite and silicon cleary appear. This method allows the carbon equivalent, carbon content and silicon content of the cast iron to be determined and the physical and mechanical properties of the iron to be estimated. Additionally, said compressed metallic powder moulding or sintered moulding is arranged at and fixed to said cooling curve measuring cup used in the method, while enclosing a thermocouple.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: April 2, 1996
    Assignee: Metec Corporation
    Inventor: Takeshi Yamaguchi
  • Patent number: 5474591
    Abstract: The present invention relates, in general, to a method of synthesizing nanocrystals and, in particular, to a method of synthesizing III-V semiconductor nanocrystals in solution at a low temperature and in a high yield. The method comprises the combination of mixing a Na/K alloy with an excess of Group VA element (E) in an aromatic solvent to form a (Na/K).sub.3 E pnictide, and subsequently mixing the pnictide with a Group IIIA trihalide (MX.sub.3) in a coordinating solution to form a suspension that includes the nanocrystalline semiconductor.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: December 12, 1995
    Assignee: Duke University
    Inventors: Richard L. Wells, Shreyas S. Kher
  • Patent number: 5458867
    Abstract: A process for producing bismuth telluride including dissolving tellurium to form a first solution; heating the first solution to approximately 70.degree. C.; stirring the first solution; slowly and quantatively adding an amount of bismuth trioxide (Bi.sub.2 O.sub.3) to produce a Bi/Te second solution wherein the ratio of Bi: Te=2:3; cooling the second solution to approximately 25.degree. C.; preparing a solution of concentrated aqueous ammonia and distilled water; adding the solution of aqueous ammonia and distilled water dropwise to the second solution at approximately 25.degree. C. to form a third solution; rapidly stirring the third solution to produce a precipitate therefrom; separating the precipitate from the third solution by centrifugation; washing the separated precipitate in distilled water; drying the washed precipitate in air to produce a Bi.sub.2 Te.sub.3 O.sub.9.xH.sub.2 O, where x=1, precursor powder; heating predetermined quantities of the dried precursor powder to 250.degree. C.-275.degree.
    Type: Grant
    Filed: September 9, 1994
    Date of Patent: October 17, 1995
    Assignee: The United States of America as represented by the Secretary of Commerce
    Inventor: Joseph J. Ritter
  • Patent number: 5427716
    Abstract: Novel compound semiconductors are of the general formula,X.sub.5 YZ.sub.4,wherein X is a member selected from the group consisting of Cu, Ag and mixtures thereof, Y is a member selected from the group consisting of Al, Ga, Tl and mixtures thereof, and Z is a member selected from the group consisting of Se, S, Te and mixtures thereof. Typical of the compound semiconductors are Cu.sub.5 AlSe.sub.4 and Ag.sub.5 AlSe.sub.4. These compound semiconductors are especially useful for making blue to UV light-emitting devices which include n-type and p-type compound semiconductor layers made of the above compound semiconductors.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: June 27, 1995
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Yoshio Morita
  • Patent number: 5330708
    Abstract: A new ternary sulfide alloy exhibits a metal-semiconductor phase transition with hysteresis as a function of temperature. One embodiment of the bistable material includes barium, cobalt, nickel and sulfur in amounts in accordance with the formula Ba(Co.sub.1-x Ni.sub.x)S.sub.2-y, and x is between 0 and 1 and y varies from 0 to 2.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: July 19, 1994
    Assignee: The University of Iowa Research Foundation
    Inventors: Lee S. Martinson, John W. Schweitzer, Norman C. Baenziger
  • Patent number: 5217750
    Abstract: Disclosed is a process which comprises providing an alloy of selenium, preparing powdered particles of the alloy with an average particle diameter of less than 300 microns, placing the powdered particles into a container and tumbling the container, and subsequently removing the powdered particles from the container and compressing the powdered particles into pellets.
    Type: Grant
    Filed: May 21, 1992
    Date of Patent: June 8, 1993
    Assignee: Xerox Corporation
    Inventors: Lawrence E. Kowalczyk, Barry A. Lees, Monroe J. Hordon, Paul F. Zukoski, Alan B. Mistrater
  • Patent number: 5128099
    Abstract: A state changeable memory alloy and device employing same. The memory alloy is capable of changing from a first state to a second state in response to the input of energy, such as projected optical beam energy, electrical energy or thermal energy. The alloy has a first detectable characteristic when in the first state and a second detectable characteristic when in the second state. It is further characterized in that the first state comprises a single phase, and the second state comprises either: (1) a single phase having the same composition as the first phase or (2) a plurality of phases which have substantially similar crystallization temperatures and kinetics.
    Type: Grant
    Filed: February 15, 1991
    Date of Patent: July 7, 1992
    Assignee: Energy Conversion Devices, Inc.
    Inventors: David A. Strand, Stanford R. Ovshinsky
  • Patent number: 5126168
    Abstract: Lewis base-borane complexes such as (CH.sub.3).sub.2 S.BHBr.sub.2 are utilized as molecular precursors for the formation of both bulk powders, films and coatings of boron nitride. The complexes are subjected to slow heating under an ammonia atmosphere to displace the base and pyrolyze the resulting complex to BN. Analogous processes may be used to prepare Group IIIA-VA compounds of the formula MM' where M is selected from the group consisting of B, Al, Ga, In, and Tl, and M' is selected from the group consisting of N, P, As, Sb and Bi.
    Type: Grant
    Filed: February 1, 1989
    Date of Patent: June 30, 1992
    Assignee: The Trustees of the University of Pennsylvania
    Inventors: Larry G. Sneddon, Jeffrey Beck
  • Patent number: 5084301
    Abstract: Disclosed is an alloying process which comprises, in the order stated (1) heating in a reaction vessel a mixture of selenium and tellurium from ambient temperature to form about 270.degree. C. to about 330.degree. C. while maintaining the mixture in a quiescent state; (2) maintaining the mixture at from about 270.degree. C. to about 330.degree. C. until the entire mixture has reached substantial equilibrium with respect to temperature while maintaining the mixture in a quiescent state; (3) subsequently heating the mixture from the range of from about 270.degree. C. to about 330.degree. C. to the range of from about 500.degree. C. to about 580.degree. C. while maintaining the mixture in a quiescent state; (4) maintaining the mixture at from about 500.degree. C. to about 580.degree. C. until the entire mixture has reached substantial equilibrium with respect to temperature while maintaining the mixture in a quiescent state; (5) thereafter maintaining the mixture at from about 500.degree. C. to about 580.degree.
    Type: Grant
    Filed: September 4, 1990
    Date of Patent: January 28, 1992
    Assignee: Xerox Corporation
    Inventors: Monroe J. Hordon, Lawrence E. Kowalczyk
  • Patent number: 5075191
    Abstract: Disclosed is a process for treating particles of selenium alloy to reduce fractionation when the particles are subsequently vacuum evaporated onto a substrate which comprises (1) heating particles of an alloy of selenium and an alloying component selected from the group are exposed to oxygen; (2) exposing the particles to water vapor; and (3) subjecting the particles previously exposed to oxygen and water vapor to a vacuum. Also disclosed is a process which comprises (1) providing particles of an alloy of selenium and an alloying component selected from the group consisting of tellurium, arsenic, and mixtures thereof; (2) forming selenium oxide on the surfaces of the particles; (3) converting the selenium oxide on the particle surfaces to selenious acid; and (4) removing the selenious acid from the particle surfaces.
    Type: Grant
    Filed: July 2, 1990
    Date of Patent: December 24, 1991
    Assignee: Xerox Corporation
    Inventors: Roger W. LaForce, Lawrence E. Kowalczyk, Santokh S. Badesha, Paul F. Zukoski, Monroe J. Hordon, Steven M. Sterling, Barry A. Lees, Fred A. Elder
  • Patent number: 5035857
    Abstract: A process for the preparation of chalcogenide alloys which comprises crystallizing a chalcogenide alloy, grinding and pelletizing the crystallized product, and evaporating the alloy on, for example, a supporting substrate to form a photoreceptor.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: July 30, 1991
    Assignee: Xerox Corporation
    Inventors: Lawrence E. Kowalczyk, Santokh S. Badesha, Paul F. Zukoski, Monroe J. Hordon, Steven M. Sterling, Barry A. Lees, Frederick A. Elder, Roger W. LaForce
  • Patent number: 5002734
    Abstract: A process for the preparation of chalcogenide alloys which comprises crystallizing a chalcogenide alloy, grinding and pelletizing the crystallized product, and evaporating the alloy on, for example, a supporting substrate to form a photoreceptor.
    Type: Grant
    Filed: January 31, 1989
    Date of Patent: March 26, 1991
    Assignee: Xerox Corporation
    Inventors: Lawrence E. Kowalczyk, Santokh S. Badesha, Paul F. Zukoski, Monroe J. Hordon, Steven M. Sterling, Barry A. Lees, Frederick A. Elder, Roger W. LaForce
  • Patent number: 4904559
    Abstract: A process for the preparation of chalcogenide alloy compositions which comprises providing a chalcogenide alloy; admixing therewith crystalline or amorphous selenium; and subsequently subjecting the resulting mixture to evaporation.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: February 27, 1990
    Assignee: Xerox Corporation
    Inventors: Santokh S. Badesha, Paul Cherin, Harvey J. Hewitt
  • Patent number: 4863508
    Abstract: Disclosed is a process for the preparation of chalcogenide alloys, particularly selenium tellurium alloys, of high purify wherein there is provided a solution mixture of the aforementioned compounds; and thereafter this mixture is subjected to a simultaneous oxidation reaction.
    Type: Grant
    Filed: October 1, 1987
    Date of Patent: September 5, 1989
    Assignee: Xerox Corporation
    Inventors: Santokh S. Badesha, Martin A. Abkowitz
  • Patent number: 4859411
    Abstract: A process for controlling fractionation in selenium alloys comprising providing pellets of an alloy comprising amorphous selenium and an alloying component selected from the group consisting of tellurium, arsenic, and mixtures thereof, the particles having an average particle size between about 300 micrometers and about 3,000 micrometers, exposing the pellets to an ambient temperature of between about 114.degree. C. and about 190.degree. C. until an exotherm occurs in the pellets resulting in substantially complete crystallization between about 104.degree. C. and about 180.degree. C., grinding the pellets into fresh powder having an average particle size of less than about 200 micrometers, and compressing the fresh powder into fresh pellets having an average weight between about 50 mg and about 1000 mg. The resulting fresh pellets may be heated in a vacuum chamber to vacuum deposit the alloy onto a substrate.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: August 22, 1989
    Assignee: Xerox Corporation
    Inventors: Gerald H. Sweatman, Roy Hodgson, Robert H. Haste
  • Patent number: 4855203
    Abstract: A layered photoresponsive imaging member comprised of a supporting substrate; an amorphous photoconductive layer and a hole transport layer dispersed in a resinous binder, which layer is formulated from a solution mixture; and wherein the photoconductive layer is prepared by a process which comprises dissolving an inorganic photoconductive component in a solvent, removing the suspended particles therefrom, depositing the resulting solution on the supporting substrate, and subsequently heating the aforementioned member.
    Type: Grant
    Filed: August 31, 1987
    Date of Patent: August 8, 1989
    Assignee: Xerox Corporation
    Inventors: Santokh S. Badesha, Geoffrey M. T. Foley, Damodar M. Pai, Richard H. Zallen, Michael L. Slade, Martin A. Abkowitz
  • Patent number: 4842973
    Abstract: A process for fabricating an electrophotographic imaging member is disclosed comprising providing in a vacuum chamber at least one crucible containing particles of an alloy comprising selenium and an alloying component selected from the group consisting of tellurium, arsenic, and mixtures thereof, providing a substrate in the vacuum chamber, applying a partial vacuum to the vacuum chamber, and rapidly heating the crucible to a temperature between about 250.degree. C. and 450.degree. C. to deposit a thin continuous selenium alloy layer on the substrate.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: June 27, 1989
    Assignee: Xerox Corporation
    Inventors: Santokh S. Badesha, Paul Cherin, Geoffrey M. T. Foley, Barry A. Lees, John Wozniak
  • Patent number: 4822712
    Abstract: An alloy treatment process is disclosed which comprises providing particles of an alloy comprising amorphous selenium and an alloying component selected from the group consisting of tellurium, arsenic, and mixtures thereof, the particles having an average particle size of at least about 300 micrometers and an average weight of less than about 1000 mg, forming crystalline nuclei on at least the surface of the particles while maintaining the substantial surface integrity of the particles, heating the particles to an initial temperature between about 50.degree. C. and about 80.degree. C. for at least about 30 minutes to form a thin, substantially continuous layer of crystalline material on the surface of the particles while maintaining the core of selenium alloy in the particles in an amorphous state, and rapidly heating the particles to at least a second temperature below the softening temperature of the particles that is at least 20.degree. C. higher than the initial temperature and between about 85.degree. C.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: April 18, 1989
    Assignee: Xerox Corporation
    Inventors: Geoffrey M. Foley, Santokh S. Badesha, Paul Cherin, Kenneth J. Pheilshifter, Philip G. Perry
  • Patent number: 4798701
    Abstract: A method of synthesizing amorphous Group IIIA-Group VA compounds. A first solution is prepared which consists of a tris(trialkylsilyl) derivative of either a Group IIIA or Group VA element dissolved in an organic solvent. A second solution is then prepared which consists of a halide of the other of the Group IIIA or Group VA element dissolved in an organic solvent. Then the first and second solutions are mixed such that a Group IIIA-Group VA compound is formed along with a trialkylhalosilane by-product. The final step of the method consists of removing the trialkylhalosilane by-product and organic solvent mixture to form the Group IIIA-Group VA condensed phase.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: January 17, 1989
    Assignee: International Business Machines Corporation
    Inventor: Lawrence D. David
  • Patent number: 4756747
    Abstract: Amorphous metallic precipitates having the formula (M.sub.1).sub.a (M.sub.2).sub.b wherein M.sub.1 is at least one transition metal, M.sub.2 is at least one main group metal and the integers "a" and "b" provide stoichiometric balance; the precipitates having a degree of local order characteristic of chemical compounds from the precipitation process and useful electrical and mechanical properties.
    Type: Grant
    Filed: July 24, 1986
    Date of Patent: July 12, 1988
    Assignee: The United States of America as represented by the Department of Energy
    Inventor: Robert C. Haushalter
  • Patent number: 4721539
    Abstract: New alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2 (where x ranges between 0 and 1 and preferably has a value of about 0.75) and CuIn.sub.y Ga.sub.(1-y) Se.sub.2 (where y ranges between 0 and 1 and preferably has a value of about 0.90) in the form of single crystals with enhanced structure perfection, which crystals are substantially free of fissures are disclosed. Processes are disclosed for preparing the new alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2. The process includes placing stoichiometric quantities of a Cu, Ag, In, and Se reaction mixture or stoichiometric quantities of a Cu, In, Ga, and Se reaction mixture in a refractory crucible in such a manner that the reaction mixture is surrounded by B.sub.2 O.sub.3, placing the thus loaded crucible in a chamber under a high pressure atmosphere of inert gas to confine the volatile Se to the crucible, and heating the reaction mixture to its melting point.
    Type: Grant
    Filed: July 15, 1986
    Date of Patent: January 26, 1988
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Theodore F. Ciszek
  • Patent number: 4707198
    Abstract: An amorphous alloy consists of iron and tellurium and has a tellurium content of from about 14 to 90 atomic%. The amorphous alloy can be utilized as an information material for optical recording and the like, and as a magnetic material and the like. The corrosion resistance and particularly heat resistance are excellent.
    Type: Grant
    Filed: June 19, 1986
    Date of Patent: November 17, 1987
    Assignee: Teijin Limited
    Inventors: Kiyoshi Chiba, Hiromitsu Ino, Kazuto Tokumitsu
  • Patent number: 4626296
    Abstract: Amorphous metallic precipitates having the formula (M.sub.1).sub.a (M.sub.2).sub.b wherein M.sub.1 is at least one transition metal, M.sub.2 is at least one main group metal and the integers "a" and "b" provide stoichiometric balance; the precipitates having a degree of local order characteristic of chemical compounds from the precipitation process and useful electrical and mechanical properties.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: December 2, 1986
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Robert C. Haushalter