Chromium Containing Patents (Class 420/79)
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Patent number: 11242576Abstract: An optimized Gamma-prime (??) strengthened austenitic transformation induced plasticity (TRIP) steel comprises a composition designed and processed such that the optimized ?? strengthened austenitic TRIP steel meets property objectives comprising a yield strength of 896 MPa (130 ksi), and an austenite stability designed to have Ms?(sh)=?40° C., wherein Ms?(sh) is a temperature for shear, and wherein the property objectives are design specifications of the optimized ?? strengthened austenitic TRIP steel. The optimized ?? strengthened austenitic TRIP steel is Blastalloy TRIP 130.Type: GrantFiled: April 10, 2017Date of Patent: February 8, 2022Assignee: NORTHWESTERN UNIVERSITYInventors: Nicholas J. Wengrenovich, Gregory B. Olson
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Patent number: 10336037Abstract: A galvanized steel sheet according to the present invention includes a steel sheet and a galvanizing layer which is formed on a surface of the steel sheet. The steel sheet includes as a chemical component, by mass %, C: more than 0.100% to 0.500%, Si: 0.0001% to less than 0.20%, Mn: more than 0.20% to 3.00%, Al: 3.0% to 10.0%, N: 0.0030% to 0.0100%, Ti: more than 0.100% to 1.000%, P: 0.00001% to 0.0200%, S: 0.00001% to 0.0100% and a remainder including Fe and impurities. The galvanizing layer includes as a chemical composition, by mass %, Fe: 0.01% to 15% and a remainder including Zn and impurities. The galvanized steel sheet has a specific gravity of 5.5 to less than 7.5.Type: GrantFiled: April 28, 2014Date of Patent: July 2, 2019Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Masaharu Oka, Nobuhiro Fujita, Manabu Takahashi, Riki Okamoto, Kenichiroh Matsumura
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Patent number: 10273556Abstract: The present invention relates to a lightweight steel sheet and a method of manufacturing the same, wherein high strength and ductility can be achieved in the lightweight steel sheet even when a small amount of carbon and manganese is added, by preventing loss of austenite due to decarburizing through inhibiting decarburization, which occurs during a heat treatment step of a steel sheet containing austenite.Type: GrantFiled: December 26, 2013Date of Patent: April 30, 2019Assignee: POSCOInventors: Jai-Hyun Kwak, Min-Seo Koo, Dong-Seoug Sin
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Publication number: 20150013845Abstract: A hot strip for producing an electric steel sheet has the following alloy composition in weight %: C: 0.001 to 0.08 Al: 4.8 to 20 Si: 0.05 to 10 B: up to 0.1 Zr: up to 0.1 Cr: 0.1 to 4, remainder iron and melting related impurities.Type: ApplicationFiled: January 30, 2013Publication date: January 15, 2015Inventors: Zacharias Georgeou, Alexander Redenius
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Publication number: 20140363694Abstract: A low density high strength steel sheet including 0.15% to 0.25% C, 2.5% to 4% Mn, 0.02% or less P, 0.015% or less S, 6% to 9% Al and 0.01% or less N, the balance being iron and inevitable impurities, wherein 1.7·(Mn—Al)+52.7·C is at least 3 and at most 4.5. A method of producing the low density and high strength steel sheet.Type: ApplicationFiled: February 21, 2012Publication date: December 11, 2014Applicant: TATA STEEL NEDERLAND TECHNOLOGY BVInventors: Cheng Liu, Radhakanta Rana
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Patent number: 8899222Abstract: A combustion chamber, having an upper part and a lower part, may include an annular constriction, in combination with the combustion chamber, to aid in directing partially combusted gases such as carbon monoxide away from the periphery of the combustion chamber back toward its center, and into the flame front. The annular constriction may also impede the flow of partially combusted gases located at the periphery, thus increasing the time these gases spend within the combustion chamber and increasing the likelihood that any products of incomplete combustion will undergo combustion. The combustion chamber may further comprise a dual burner cooktop for directing combustion gases and exhaust to multiple cooking vessels. In further embodiments, the combustion chamber may be made of, lined, or clad with a metal alloy comprising iron, chromium, and aluminum.Type: GrantFiled: April 8, 2010Date of Patent: December 2, 2014Assignees: Colorado State University Research Foundation, UT-Battelle, LLCInventors: Morgan W. DeFoort, Bryan D. Willson, Nathan Lorenz, Michael P. Brady, Anthony Marchese, Daniel D. Miller-Lionberg
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Patent number: 8778097Abstract: A low specific gravity and high strength steel sheet includes C of 0.2% to 0.8%, Mn of 2% to 10%, P of 0.02% or less, S of 0.015% or less, Al of 3% to 15%, and N of 0.01% or less. A ratio of Mn/Al is 0.4 to 1.0. Retained austenite in a structure is included in the range of 1% or more. The steel sheet further includes one or two or more elements selected from the group consisting of Si of 0.1% to 2.0%, Cr of 0.1% to 0.3%, Mo of 0.05% to 0.5%, Ni of 0.1% to 2.0%, Cu of 0.1% to 1.0%, B of 0.0005% to 0.003%, Ti of 0.01% to 0.2%, Zr of 0.005% to 0.2%, Nb of 0.005% to 0.2%, W of 0.1% to 1.0%, Sb of 0.005% to 0.2%, and Ca of 0.001% to 0.2%.Type: GrantFiled: October 29, 2008Date of Patent: July 15, 2014Assignee: PoscoInventors: Kwang Geun Chin, Jai Hyun Kwak
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Publication number: 20140065316Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <20 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the steps of determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: ApplicationFiled: August 22, 2013Publication date: March 6, 2014Applicant: Scoperta, Inc.Inventors: Justin Lee Cheney, John Hamilton Madok
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Patent number: 8580190Abstract: An iron-chromium-aluminum alloy having a long service life and exhibiting little change in heat resistance, comprising (as percentages by weight) 4.5 to 6.5% Al, 16 to 24% Cr, 1.0 to 4.0% W, 0.05 to 0.7% Si, 0.001 to 0.5% Mn, 0.02 to 0.1% Y, 0.02 to 0.1% Zr, 0.02 to 0.1% Hf, 0.003 to 0.030% C, 0.002 to 0.03% N, a maximum of 0.01% S, and a maximum of 0.5% Cu, the remainder being iron and the usual steel production-related impurities.Type: GrantFiled: April 2, 2009Date of Patent: November 12, 2013Assignee: Outokumpu VDM GmbHInventor: Heike Hattendorf
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Patent number: 8431072Abstract: An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.Type: GrantFiled: May 24, 2011Date of Patent: April 30, 2013Assignee: UT-Battelle, LLCInventors: Govindarajan Muralidharan, Yukinori Yamamoto, Michael P. Brady
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Patent number: 8257646Abstract: UHC lightweight structural steel with improved scaling resistance, comprising the composition in % by weight C: 1 to 1.6, Al: 5 to 10, Cr: 0.5 to 3, Si: 0.1 to 2.8, the remainder iron and customary impurities accompanying steel, and a method for producing components hot-formed from this in air, wherein hot-forming temperatures of from 800 to 1050° C. are used, depending on the Si content.Type: GrantFiled: August 21, 2007Date of Patent: September 4, 2012Assignee: Daimler AGInventors: Tilmann Haug, Wolfgang Kleinekathoefer, Frédéric Pol
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Patent number: 8202629Abstract: A cladding tube configured for use with nuclear fuels or nuclear feel elements and configured for contact with molten lead or molten lead alloys at up to 800° C. The cladding tube includes a tube including at least one of ferritic/martenisitic steel and austenitic steel. An alloy layer of up to 50 ?m thickness is disposed on a surface of the tube and operable for corrosion resistance. The alloy layer includes 0-25% chromium, 3-15% aluminum and 60-97% iron. A method of making the cladding tube includes the use of a pulsed electron beam to melt the alloy layer on the tube.Type: GrantFiled: June 20, 2006Date of Patent: June 19, 2012Assignee: Forschungszentrum Karlsruhe GmbHInventors: Annette Heinzel, Georg Mueller, Alfons Weisenburger, Frank Zimmermann, Gustav Schumacher, Vladimir Engelko
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Patent number: 8153054Abstract: An iron-based high-temperature alloy is disclosed which contains the following chemical composition: 20% by weight Cr; 5 to 6% by weight Al; 4% by weight Ta; 4% by weight Mo; 3 to 4% by weight Re; 0.2% by weight Zr; 0.05% by weight B; 0.1% by weight Y; 0.1% by weight Hf; 0 to 0.05% by weight C; and remainder Fe and unavoidable impurities. The alloy can be produced at low cost and can possess outstanding oxidation resistance and good mechanical properties at temperatures up to 1200° C.Type: GrantFiled: July 24, 2009Date of Patent: April 10, 2012Assignee: Alstom Technology LtdInventors: Mohamed Nazmy, Andreas Künzler, Giuseppe Bandiera, Hanspeter Zinn
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Publication number: 20110318218Abstract: Steel for forging having high strength and superior machinability due to controlled cooling immediately after shaping by hot forging followed by tempering and having a lower specific gravity than ordinary steel for forging use, the steel containing C: 0.05 to 0.50%, Si: 0.01 to 1.50%, Mn: 3.0 to 7.0%, P: 0.001 to 0.050%, S: 0.020 to 0.200%, Al: 3.0 to 6.0%, Cr: 0.01 to 1.00%, and N: 0.0040 to 0.0200% and having a balance of Fe and unavoidable impurities.Type: ApplicationFiled: April 8, 2010Publication date: December 29, 2011Inventors: Hiromasa Takada, Suguru Yoshida
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Patent number: 8012271Abstract: The presently described technology relates to a material for components of a gas turbine, in particular for components of a gas turbine aircraft engine, having a matrix of an iron-based alloy material, wherein the matrix of the iron-based alloy material being hardened by means of an intermetallic material of the Laves phase.Type: GrantFiled: December 15, 2006Date of Patent: September 6, 2011Assignee: MTU Aero Engines GmbHInventors: Wilfried Smarsly, Gerhard Sauthoff
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Publication number: 20110192507Abstract: An iron alloy according to the present invention comprises: Al in an amount of from 3 to 5.5%; Mn in an amount from 0.2 to 6%; and the balance being iron (Fe), and inevitable impurities and/or a modifying element; when the entirety is taken as 100%. Since a high damping factor is obtainable at a low-strain amplitude, this iron alloy demonstrates a stable damping property even in a high-temperature region. Moreover, since the alloying elements are Al and Mn alone, and since their contents are less, the iron alloy according to the present invention is low in cost.Type: ApplicationFiled: September 8, 2009Publication date: August 11, 2011Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Keita Yamana, Motoharu Tanizawa, Masanori Harata, Kyoichi Kinoshita
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Publication number: 20110121056Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m Nb and W carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are methods of designing an alloy capable of forming a crack free hardbanding weld overlay, the methods comprising the steps of determining an amorphous forming epicenter composition, determining a variant composition having a predetermined change in constituent elements from the amorphous forming epicenter composition, and forming and analyzing an alloy having the variant composition.Type: ApplicationFiled: November 3, 2010Publication date: May 26, 2011Inventors: Justin Lee Cheney, John Hamilton Madok
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Publication number: 20100074791Abstract: A ferrous abrasion resistant sliding material capable of improving seizing resistance, abrasion resistance and heat crack resistance is provided. The ferrous abrasion resistant sliding material has a martensite parent phase which forms a solid solution with carbon of 0.15 to 0.5 wt %, and the martensite parent phase contains one or more types of each special carbide of Cr, Mo, W and V dispersed therein in a total content of 10 to 50% by volume.Type: ApplicationFiled: November 30, 2009Publication date: March 25, 2010Inventor: Takemori Takayama
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Publication number: 20100021339Abstract: UHC lightweight structural steel with improved scaling resistance, comprising the composition in % by weight C: 1 to 1.6, Al: 5 to 10, Cr: 0.5 to 3, Si: 0.1 to 2.8, the remainder iron and customary impurities accompanying steel, and a method for producing components hot-formed from this in air, wherein hot-forming temperatures of from 800 to 1050° C. are used, depending on the Si content.Type: ApplicationFiled: August 21, 2007Publication date: January 28, 2010Applicant: Daimler AGInventors: Tilmann Haug, Wolfgang Kleinekathoefer, Frédéric Pol
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Publication number: 20090297387Abstract: A low specific gravity and high strength steel sheet includes C of 0.2% to 0.8%, Mn of 2% to 10%, P of 0.02% or less, S of 0.015% or less, Al of 3% to 15%, and N of 0.01% or less. A ratio of Mn/Al is 0.4 to 1.0. Retained austenite in a structure is included in the range of 1% or more. The steel sheet further includes one or two or more elements selected from the group consisting of Si of 0.1% to 2.0%, Cr of 0.1% to 0.3%, Mo of 0.05% to 0.5%, Ni of 0.1% to 2.0%, Cu of 0.1% to 1.0%, B of 0.0005% to 0.003%, Ti of 0.01% to 0.2%, Zr of 0.005% to 0.2%, Nb of 0.005% to 0.2%, W of 0.1% to 1.0%, Sb of 0.005% to 0.2%, and Ca of 0.001% to 0.2%.Type: ApplicationFiled: October 29, 2008Publication date: December 3, 2009Applicant: POSCOInventors: Kwang Geun Chin, Jai Hyun Kwak
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Patent number: 7601672Abstract: The present invention provides an Fe—Cr—Al based stainless steel sheet and double layered sheet having a high Al content of greater than 6.5%, honeycomb bodies employing the stainless steel sheet or double layered sheet, and a process for fabrication of the steel sheet or double layered sheet. The sheet is a high Al-containing Fe—Cr—Al based stainless steel sheet or high Al-containing double layered sheet characterized by comprising, by weight, Cr: 10-30% and Al: >6.5%-15%. Preferably, the steel sheet further comprises either or both Ti: 0.02-0.1% and Nb: 0.02-0.3%, and also comprises La: 0.01-0.1%, Ce: 0.01-0.1% and P: 0.01-0.05%. It also preferably comprises Cu: 0.01-1.0% by weight, and preferably further comprises Mg: 0.001-0.1% by weight. There is also provided a honeycomb body fabricated using the Fe—Cr—Al based stainless steel sheet.Type: GrantFiled: November 20, 2003Date of Patent: October 13, 2009Assignee: Nippon Steel CorporationInventors: Tooru Inaguma, Shogo Konya, Hiroaki Sakamoto, Motonori Tamura
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Publication number: 20090202381Abstract: The presently described technology relates to a material for components of a gas turbine, in particular for components of a gas turbine aircraft engine, having a matrix of an iron-based alloy material, wherein the matrix of the iron-based alloy material being hardened by means of an intermetallic material of the Laves phase.Type: ApplicationFiled: December 15, 2006Publication date: August 13, 2009Inventors: Wilfried Smarsly, Gerhard Sauthoff
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Publication number: 20080124240Abstract: Provided is free cutting alloy excellent in machinability, preserving various characteristics as alloy. The free cutting alloy contains: one or more of Ti and Zr as a metal element component; and C being an indispensable element as a bonding component with the metal element component, wherein a (Ti,Zr) based compound including one or more of S, Se and Te is formed in a matrix metal phase. The free cutting alloy is more excellent in machinability, preserving various characteristics as alloy at similar levels to a conventional case. The effect is especially conspicuous, for example, when a compound expressed in a chemical form of (Ti,Zr)4C2(S,Se,Te)2 as the (Ti,Zr) based compound is formed at least in a dispersed state in the alloy structure.Type: ApplicationFiled: October 19, 2007Publication date: May 29, 2008Applicants: Kiyohito ISHIDA, Katsunari OIKAWA, Daido Steel Co., Ltd., Tohoku Steel Co., Ltd., Japan Industrial Technology Association, Tohoku Techno Arch Co., Ltd.Inventors: Kiyohito Ishida, Katsunari Oikawa, Takashi Ebata, Takayuki Inoguchi, Tetsuya Shimizu, Michio Okabe
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Patent number: 6905651Abstract: A ferritic stainless steel alloy useful as a substrate for catalytic converter material consists of, by weight: 15-21% Cr, 8-12% Al, 0.01-0.09% Ce, 0.02-0.1% total of REM, and possible minor amounts of further elements, other than the ones mentioned, the balance being Fe with normally occurring impurities. These alloys have managed to combine a high content of Al with a good hot and cold workability.Type: GrantFiled: November 8, 2002Date of Patent: June 14, 2005Assignee: Sandvik ABInventors: Simon Johansson, Bo Rogberg
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Patent number: 6830676Abstract: A cracking tube includes a lining of a fouling resistant and corrosion resistant iron aluminide alloy. The iron aluminide alloy can include 14-32 wt. % Al, at least 2 vol. % transition metal oxides, 0.003 to 0.020 wt. % B, 0.2 to 2.0 wt. % Mo, 0.05 to 1.0 wt. % Zr, 0.2 to 2.0 wt. % Ti, 0.10 to 1.0 wt. % La, 0.05 to 0.2 wt. % C., balance Fe, and optionally ≦1 wt. % Cr, and the coefficient of thermal expansion of the iron aluminide alloy is substantially the same as the coefficient of thermal expansion over the temperature range of ambient to about 1200° C. of an outer metal layer. A cracking tube utilizing the iron aluminide alloy can be formed from powders of the iron aluminide alloy by consolidation methods including cold isostatic pressing (CIP), hot isostatic pressing (HIP), reaction synthesis, spraying techniques, or co-extrusion with a second material of the cracking tube.Type: GrantFiled: June 11, 2001Date of Patent: December 14, 2004Assignee: Chrysalis Technologies IncorporatedInventor: Seetharama C. Deevi
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Patent number: 6652991Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.Type: GrantFiled: October 9, 2002Date of Patent: November 25, 2003Assignee: The Governors of the University of AlbertaInventors: You Wang, Weixing Chen
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Patent number: 6627007Abstract: A method has been developed for surface modifications of high temperature resistant alloys, such as FeCrAl alloys, in order to increase their resistance to corrosion at high temperatures. Coating it with a Ca-containing compound before heat-treating builds a continuos uniform and adherent layer on the surface of the alloy, that the aluminum depletion of the FeCrAl alloy is reduced under cyclic thermal stress. By this surface modification the resistance to high temperature corrosion of the FeCrAl alloy and its lifetime are significantly increased.Type: GrantFiled: July 3, 2001Date of Patent: September 30, 2003Assignee: Sandvik ABInventors: Jan Andersson, Magnus Cedergren
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Patent number: 6582835Abstract: Dip-coated ferrite stainless steel sheet usable in the automobile exhaust sector, characterized in that it comprises a steel core with the following composition by weight: 10.5%≦chromium≦20% 0%≦aluminum≦0.6% 0.003%≦carbon≦0.06% 0.003%≦nitrogen≦0.04% 0%≦silicon≦0.6% 0%≦manganese≦0.6% 0%≦sulfur≦0.002% iron and impurities inherent in processing, and a metal coating deposited by dipping the strip in a molten metal bath containing in particular aluminum and at least one rare earth element: cerium, lanthanum, praseodymium, neodymium, mixed metal and/or yttrium.Type: GrantFiled: March 29, 2001Date of Patent: June 24, 2003Assignee: UsinorInventors: Laurent Antoni, Raphael Craen
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Publication number: 20030086809Abstract: A hot workable ferric stainless steel alloy resistant to thermal cyclic stress and oxidation at elevated temperatures having improved mechanical properties rendering it especially suitable as a substrate for exhaust gas purifying applications, such as catalytic converters or heating applications, has a composition including (in weight-%): 1 C ≦0.05%; Cr 16.0-24.0%; Ni more than 1.0-15.0%; Al 4.5-12.0%; Mo + W ≦4.0%; Mn ≦1.0%; Si ≦2.0%; Zr + Hf ≦0.1%; REM ≦0.1%; N ≦0.Type: ApplicationFiled: October 2, 2002Publication date: May 8, 2003Inventors: Magnus Cedergren, Kenneth Goransson
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Patent number: 6524405Abstract: The present invention is directed to an iron, aluminum, chromium, carbon alloy and a method of producing the same, wherein the alloy has good room temperature ductility, excellent high temperature oxidation resistance and ductility. The alloy includes about 10 to 70 at. % iron, about 10 to 45 at. % aluminum, about 1 to 70 at. % chromium and about 0.9 to 15 at. % carbon. The invention is also directed to a material comprising a body-centered-cubic solid solution of this alloy, and a method for strengthening this material by the precipitation of body-centered-cubic particles within the solid solution, wherein the particles have substantially the same lattice parameters as the underlying solid solution. The ease of processing and excellent mechanical properties exhibited by the alloy, especially at high temperatures, allows it to be used in high temperature structural applications, such as a turbocharger component.Type: GrantFiled: March 31, 2000Date of Patent: February 25, 2003Inventor: Hui Lin
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Patent number: 6436163Abstract: A porous metal filter possessing enhanced anticorrosive properties is provided including sintered metal particles composed of an alloy composition of iron aluminide having a range in concentration corresponding to Fe3Al to FeAl phases and having a Bubble Point ratio of about 1.6 or less.Type: GrantFiled: December 24, 1998Date of Patent: August 20, 2002Assignee: Pall CorporationInventors: Stephen A. Geibel, Paul C. Koehler, John L. Hurley
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Patent number: 6383662Abstract: A high-strength lightweight steel and its use for car parts and facade linings is a purely ferritic steel having, in mass %, more than 5 to 9% Al, less than 0.2% Si, and 0.03 to 0.2% Mn.Type: GrantFiled: May 12, 2000Date of Patent: May 7, 2002Inventor: Georg Frommeyer
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Patent number: 6355212Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.Type: GrantFiled: January 5, 2000Date of Patent: March 12, 2002Assignee: Turbocoating SpAInventor: Nelso Antolotti
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Patent number: 6296953Abstract: A compound tube comprises a layer of a Fe—Cr—Al-alloy and a layer of a load-carrying component and optionally one or several additional layers. The Fe—Cr—Al-alloy has the following analysis in weight-%: carbon<0.3, chromium 5-30, nickel<10, manganese<5, molybdenum<5, aluminium 3-20 , silicon<5, nitrogen<0.3, cerium+bafnium+yttrium<1.0, titanium 0.005-1.0, zirconium 0.005-1.0, niobium 0.005-1.0, the remainder iron, and naturally occurring impurities. These tubes are very resistant towards carbonization and “metal dusting” and are being used to advantage for bayonet tubing, superheat tubing and reformer tubing in steam formation.Type: GrantFiled: April 6, 2000Date of Patent: October 2, 2001Assignee: Sandvik ABInventors: Johan Lindén, Urban Forsberg
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Patent number: 6267921Abstract: The invention concerns a high specification non-magnetic stainless steel which is corrosion resistant in physiological media and which can be produced at atmospheric pressure, characterized in that its composition in % by weight is as follows: Mn 15% to 24% Ti ≦0.020% Cr 15% to 20% Al ≦0.020% Mo 2.5% to 4% S ≦0.0020% N 0.6% to 0.85% B ≦0.020% V 0.1% to 0.5% Nb + Ta ≦0.5% C ≦0.06% Co ≦0.5% Ni ≦0.25% Cu ≦0.5% silica ≦0.25% and from 0 to 0.5% of each of elements Cu, Co and of the sum Nb+Ta, the remainder being constituted by iron and impurities, and in that its composition satisfies the following conditions: (%Cr)+2.5(%Mo)≦27 (I) (%Cr)+3.3(%Mo)≧26 (II); and Log(%N)+0.0605(%N)=−1.3+[125(%V)+80(%Nb)+52(%Cr)+19(%Mn)]×10−3−[4.Type: GrantFiled: December 3, 1999Date of Patent: July 31, 2001Assignee: Societe Industrielle de MetallurgieInventors: Jacques Montagnon, Jean-Yves Moraux
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Publication number: 20010002296Abstract: An iron aluminide coating consists essentially of: 1 5-35% by weight aluminum 15-25% by weight chromium 0.5-10% by weight molybdenum, tungsten, tantalum and niobium 0-0.Type: ApplicationFiled: December 14, 2000Publication date: May 31, 2001Inventors: Mohamed Nazmy, Markus Staubli
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Patent number: 5944917Abstract: A stainless steel having excellent corrosion resistance to ozone added water, such as ozone added ultrapure water used in semiconductor manufacturing processes and the like, as well as a manufacturing method. The stainless steel comprises a base metal and an oxide film formed on the surface of the base metal, the base metal being a stainless steel which contains 12 to 30% of Cr, 0 to 35% of Ni, and 1 to 6% of Al and Si while the contents of the other alloying elements are limited to as low a level as possible, the oxide film mainly comprising Al oxide or a Si oxide or both. The oxide film may be formed on the base metal surface through the dry oxidation process or the wet oxidation process. In the stainless steel, metallic ions are rarely dissolved from the base metal into the ozone added water.Type: GrantFiled: May 29, 1997Date of Patent: August 31, 1999Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kiyoko Takeda, Shigeki Azuma, Yoshio Tarutani, Yoshitaka Nishiyama, Yasushi Matsuda
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Patent number: 5670216Abstract: The present invention comprises a method for preparing a surface for application of a non-stick coating, the method wherein the surface to be prepared for non-stick coating is prepared by thermally spraying a stainless steel alloy containing at most 6.0% aluminum, and is substantially free of Nickel. The present invention further includes a cooking utensil having a substrate to which an intermediate layer, for receiving the non-stick coating, is prepared by thermally spraying the stainless steel alloy containing at most 6.0% aluminum, and is substantially free of Nickel.Type: GrantFiled: July 25, 1994Date of Patent: September 23, 1997Assignee: Regal Ware, Inc.Inventors: Albert Charley Oak, Leonard C. Brumbaugh, Daryl E. Crawmer
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Patent number: 5653032Abstract: Fabricating an article of manufacture having a Fe.sub.3 Al-based alloy cutting edge. The fabrication comprises the steps of casting an Fe.sub.3 Al-based alloy, extruding into rectangular cross section, rolling into a sheet at 800.degree. C. for a period of time followed by rolling at 650.degree. C., cutting the rolled sheet into an article having an edge, and grinding the edge of the article to form a cutting edge.Type: GrantFiled: December 4, 1995Date of Patent: August 5, 1997Assignee: Lockheed Martin Energy Systems, Inc.Inventor: Vinod K. Sikka
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Patent number: 5618491Abstract: Disclosed is a stud for a boiler or other high temperature application, such as a furnace. The stud is made of an iron aluminum alloy which comprises about 81 to 91 wt. % iron, about 8 to 13 wt. % aluminum, about 0.01 to 0.3 wt. % carbon, and zero to about 3 wt. % of a refractory metal and/or zero to about 1.5 wt. % zirconium. The studs are welded to a surface of a component of the boiler or furnace by arc or resistance welding. The aluminum of the iron aluminum alloy imparts good oxidation and sulfidation resistance to the studs. The alloy also has a good electrical resistance which makes the alloy especially useful for arc or resistance welding. The aluminum content acts as a getter to eliminate gas porosity in the resulting welds. The present invention is particularly useful for making boiler heat exchange surfaces or refractory covered surfaces wherein the studs function as refractory anchors.Type: GrantFiled: February 22, 1996Date of Patent: April 8, 1997Assignee: TRW, Inc.Inventors: Mohan Kurup, Clark Champney
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Patent number: 5422070Abstract: The alloy is based on doped iron aluminide Fe.sub.3 Al. It contains the following alloying constituents in atomic percent:______________________________________ 24 28 aluminum, 0.1 2 niobium, tantalum and/or tungsten, 0.1 10 chromium, 0.1 2 silicon, 0.1 5 boron, 0.01 2 titanium, ______________________________________the remainder being iron. The alloy is notable for a high oxidation resistance and corrosion resistance even at temperatures above 700.degree. C. and is preferably used in components which are exposed to oxidizing and corrosive actions at high temperatures and low mechanical stress.Type: GrantFiled: January 14, 1994Date of Patent: June 6, 1995Inventors: Mohamed Y. Nazmy, Corrado Noseda, Markus Staubli
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Patent number: 5411702Abstract: The iron-aluminum alloy comprises the following constituents in atom percent:______________________________________ 12-18 aluminum 0.1-10 chromium 0.1-2 niobium 0.1-2 silicon 0.1-5 boron 0.01-2 titanium 100-500 ppm carbon 50-200 ppm zirconium remainder iron. ______________________________________This alloy is distinguished by high thermal-shock resistance and, at temperatures of 800.degree. C., still has comparatively good mechanical properties. The alloy can be used advantageously in components such as, for example, casings of gas turbines, which, with comparatively low mechanical loading, are subject to frequent thermal cycling.Type: GrantFiled: December 28, 1993Date of Patent: May 2, 1995Assignee: ABB Management AGInventors: Mohamed Nazmy, Corrado Noseda, Markus Staubli
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Patent number: 5286442Abstract: A ferric stainless steel consists by weight of less than 0.03% carbon, less than 1% silicon, less than 1% manganese, less than 0.04% phosphorus, less than 0.03% sulphur, from 15% to 25% chromium, less than 0.03% nitrogen, from 3% to 6% aluminum, from 0.1% to 4% molybdenum. A small amount of rare-earth elements and yttrium of from 0.01% to 0.15% are added in the steel.Type: GrantFiled: March 17, 1992Date of Patent: February 15, 1994Assignee: Nisshin Steel Co., Ltd.Inventors: Yoshihiro Uematsu, Katsuhisa Miyakusu, Naoto Hiramatsu
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Patent number: 5278881Abstract: An Fe-Cr-Mn alloy is disclosed which has the following composition by wt% and corrosion resistance of which is improved and deterioration in its strength is prevented at grain boundaries due to irradiation of high-energy particles such as neutrons: 5 to 40% of Mn, 5 to 18% of Cr, 2.0 to 12% of Al and the balance of Fe except for unavoidable impurities. In the alloy according to the present invention, Al is added to an Fe-Cr-Mn alloy by a restricted quantity as a main component element. As a result of the addition of Al, an alloy can be obtained in which lowering of concentration of Cr at grain boundaries due to irradiation of high-energy particles such as neutrons can be prevented or concentration of the solutes can be raised.Type: GrantFiled: October 30, 1992Date of Patent: January 11, 1994Assignee: Hitachi, Ltd.Inventors: Takahiko Kato, Heishichiro Takahashi, Shinzoo Ikeda, Jiro Kuniya
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Patent number: 5238645Abstract: Iron-aluminum alloys having selectable room-temperature ductilities of greater than 20%, high resistance to oxidation and sulfidation, resistant pitting and corrosion in aqueous solutions, and possessing relatively high yield and ultimate tensile strengths are described. These alloys comprise 8 to 9.5% aluminum, up to 7% chromium, up to 4% molybdenum, up to 0.05% carbon, up to 0.5% of a carbide former such as zirconium, up to 0.1 yttrium, and the balance iron. These alloys in wrought form are annealed at a selected temperature in the range of 700.degree. C. to about 1100.degree. C. for providing the alloys with selected room-temperature ductilities in the range of 20 to about 29%.Type: GrantFiled: June 26, 1992Date of Patent: August 24, 1993Assignee: Martin Marietta Energy Systems, Inc.Inventors: Vinod K. Sikka, Claudette G. McKamey
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Patent number: 5165899Abstract: An element is disclosed for filtering and/or purifying hot gases, comprising a fibrous structure with a predetermined degree of porosity and formed of metal alloy fibrils of the MCrAlX type, in which M is a matrix chosen from iron and/or nickel and/or cobalt, and X is an element reinforcing the adhesion of the oxide layer which is formed on the fibrils in contact with the hot gases, chosen from zirconium, yttrium, cerium, lanthanum and misch metal.Type: GrantFiled: August 30, 1990Date of Patent: November 24, 1992Assignee: Office National d'Etudes et de Recherches AerospatialesInventors: Christophe Delaunay, Didier Loco, Andre Walder
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Patent number: 5129959Abstract: A method for producing aluminum-containing ferritic stainless steel from a magnesium-contaminated melt such that the steel is suitable for growing oxide whiskers to cover the surface thereof is disclosed. The method comprises adding sulfur to the contaminated melt in an amount sufficient to increase the sulfur content not less than 1.3 time the magnesium content, whereupon the sulfur reacts with the magnesium to render the magnesium inert to whisker growth. The method also preferably comprises an addition of titanium, zirconium of hafnium in amounts sufficient to react with residual sulfur in excess of the amount required for magnesium reaction, thereby mitigating the adverse affect of sulfur on oxide adhesion.Type: GrantFiled: April 2, 1990Date of Patent: July 14, 1992Assignee: General Motors CorporationInventor: David R Sigler
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Patent number: 5130085Abstract: High Al austenitic steels are particularly susceptible to deterioration of the hot workability and suffer from severe cracking during hot working, with working becoming impossible in some cases. The present invention remarkably improves the hot workability by strictly limiting the impurities in the steel, in particular the S, O, Mg, Pb, Bi, etc. That is, the present invention reduces the S and O by adding one or more of Ca, Y, and REM to satisfy the range of -50<(S)+(O)-0.8.times.(Ca)-0.2.times.(Y)-0.1 .times.(REM)<30 (unit: ppm) and further limits the Mg to no more than 100 ppm, the Pb to no more than 10 ppm, and the Bi to no more than 5 ppm. According to the present invention, it is possible to obtain a high Al austenitic heat-resistant steel superior in hot workability which is free from occurrence of edge cracks, surface flaws, and other surface defects during hot rolling, hot casting, etc.Type: GrantFiled: August 22, 1990Date of Patent: July 14, 1992Assignee: Nippon Steel CorporationInventors: Masayuki Tendo, Mikio Yamanaka, Masamitsu Tsuchinaga, Harumi Tsuboi
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Patent number: 5085829Abstract: An oxidation-resistant Fe-Cr-Al steel, having superior workability, oxidation resistance at high temperature and corrosion resistance, has a composition which contains: up to but not more than about 0.05 wt % of C; about 0.1 to about 1.0 wt % of Si; up to but not more than about 1.0 wt % of Mn; from about 3.0 to 7.5 wt % of Cr; from about 4.5 to 6.5 wt % of Al; up to but not more than about 0.05 wt % of N; one or more elements selected from about the group consisting of 1), from about 0.01 wt % to 0.3 wt % of Zr, 2), from 0.01 wt % to 0.3 wt % of Ti, and 3), from about 0.001 wt % to 0.2 wt %, expressed as a total, of Y, La, Ce, Pr, Nd and Hf; and the balance sustantially Fe and incidental inclusions.Type: GrantFiled: December 21, 1990Date of Patent: February 4, 1992Assignee: Kawasaki Steel CorporationInventors: Kazuhide Ishii, Tatsuo Kawasaki
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Patent number: 4961903Abstract: An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.Type: GrantFiled: March 7, 1989Date of Patent: October 9, 1990Assignee: Martin Marietta Energy Systems, Inc.Inventors: Claudette G. McKamey, Chain T. Liu