Unitary (i.e., Nonparticulate) Contact Bed (e.g., Monolithic Catalyst Bed, Etc.) Patents (Class 422/180)
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Patent number: 8778297Abstract: A sulfur recovery unit comprising: a reaction furnace configured to carry out a high-temperature Claus reaction between hydrogen-sulfide-containing gas and oxygen-containing gas introduced to the reaction furnace; a sulfur condenser configured to cool reaction gas discharged from the reaction furnace and condense sulfur contained in the reaction gas; and a pipe that connects the reaction furnace to the sulfur condenser, wherein the reaction furnace is fixed to the ground; and the sulfur condenser and the pipe are arranged so as to be able to move relative to the reaction furnace.Type: GrantFiled: April 2, 2012Date of Patent: July 15, 2014Assignee: JGC CorporationInventors: Tatsuo Kamisuki, Hiroyuki Kosasayama, Yasushi Yamada, Shingo Arai, Mitsuru Kida
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Publication number: 20140186244Abstract: A catalysed substrate monolith 12 for use in treating exhaust gas emitted from a lean-burn internal combustion engine, which catalysed substrate monolith 12 comprising a first washcoat coating 16 and a second washcoat coating 18, wherein the first washcoat coating comprises a catalyst composition comprising at least one platinum group metal (PGM) and at least one support material for the at least one PGM, wherein at least one PGM in the first washcoat coating is liable to volatilise when the first washcoat coating is exposed to relatively extreme conditions including relatively high temperatures, wherein the second washcoat coating comprises at least one metal oxide for trapping volatilised PGM and wherein the second washcoat coating is oriented to contact exhaust gas that has contacted the first washcoat coating.Type: ApplicationFiled: March 6, 2014Publication date: July 3, 2014Applicant: Johnson Matthey Public Limited CompanyInventors: Philip Gerald BLAKEMAN, Gavin Michael BROWN, Sougato CHATTERJEE, Andrew Francis CHIFFEY, Jane GAST, Paul Richard PHILLIPS, Raj Rao RAJARAM, Glen SPREITZER, Andrew Peter WALKER
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Publication number: 20140186228Abstract: A filter for filtering particulate matter (PM) from exhaust gas emitted from a compression ignition engine, which filter comprising a porous substrate having inlet surfaces and outlet surfaces, wherein the inlet surfaces are separated from the outlet surfaces by a porous structure containing pores of a first mean pore size, wherein the porous substrate is coated with a wash coat comprising a plurality of solid particles comprising a molecular sieve promoted with at least one metal wherein the porous structure of the wash coated porous substrate contains pores of a second mean pore size, and wherein the second mean pore size is less than the first mean pore size.Type: ApplicationFiled: December 16, 2013Publication date: July 3, 2014Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Louise ARNOLD, Robert BRISLEY, Guy Richard CHANDLER, Andrew Francis CHIFFEY, Keith Anthony FLANAGAN, David GREENWELL, Christopher MORGAN
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Patent number: 8764872Abstract: A honeycomb filter includes a honeycomb base material, plugged portions, and a porous collecting layer disposed on the surface of the partition wall parent material in at least the remaining cells. The collecting layer has a constitution in which a plurality of particles combine or intertwine with one another, and the collecting layer includes fibrous fiber particles as the plurality of particles, and includes the particles having an average fiber diameter of 0.1 to 15 ?m and an average aspect ratio of 3 or larger. An open area ratio of the surface of the collecting layer is 20% or larger.Type: GrantFiled: March 9, 2012Date of Patent: July 1, 2014Assignee: NGK Insulators, Ltd.Inventors: Yoshinori Isoda, Yoshio Kikuchi
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Patent number: 8765084Abstract: Several embodiments of high-efficiency catalytic converters and associated systems and methods are disclosed. In one embodiment, a catalytic converter for treating a flow of exhaust gas comprising a reaction chamber, a heating enclosure enclosing at least a portion of the reaction chamber, and an optional coolant channel encasing the heating enclosure. The reaction chamber can have a first end section through which the exhaust gas flows into the reaction chamber and a second end section from which the exhaust gas exits the reaction chamber. The heating enclosure is configured to contain heated gas along the exterior of the reaction chamber, and the optional coolant channel is configured to contain a flow of coolant around the heating enclosure. The catalytic converter can further include a catalytic element in the reaction chamber.Type: GrantFiled: October 30, 2012Date of Patent: July 1, 2014Assignee: in the worksInventors: Todd K. Hansen, David A. Endrigo
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Publication number: 20140178263Abstract: An aftertreatment system and method treats exhaust gasses produced by an internal combustion process or similar process. The system includes an aftertreatment module having at least one sleeve extending between a first end and a second end. One or more aftertreatment bricks may be axially inserted through an opening disposed in the first end of the sleeve. The aftertreatment brick may include an substrate matrix surrounded by a tubular, protective mantle. To prevent the aftertreatment bricks from unintentionally exiting the sleeve, a retention ring is releasably engaged with the first end of the sleeve. The retention ring may include a dimension that is less than a dimension of the opening in the first end so that at least a portion of the retention ring contacts the mantle of the aftertreatment brick.Type: ApplicationFiled: December 21, 2012Publication date: June 26, 2014Applicant: CATERPILLAR INC.Inventors: Mirza P. Baig, Andrew M. Denis
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Publication number: 20140178262Abstract: Hollow porous metal oxide microspheres are provided. The microspheres may be used as a support for a catalyst, particularly an exhaust treatment catalyst for an internal combustion engine. Also provided are methods of making the microspheres, methods of using the microspheres as catalyst supports, and methods of exhaust treatment using catalyst articles comprising the microspheres.Type: ApplicationFiled: December 20, 2012Publication date: June 26, 2014Applicant: BASF CorporationInventors: Pascaline Harrison Tran, Michael P. Galligan, Ye Liu, Xiaolin David Yang, Qingyuan Hu, Doan Lieu
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Patent number: 8758695Abstract: The present invention relates to a treatment system for a gasoline engine exhaust gas stream comprising a particulate filter, said particulate filter comprising: a particulate filter substrate, an inlet layer disposed on the exhaust gas inlet surface of the filter substrate, and an outlet layer disposed on the exhaust gas outlet surface of the filter substrate, wherein the inlet layer comprises Rh and/or Pd, and the outlet layer comprises Rh and/or a zeolite.Type: GrantFiled: June 30, 2010Date of Patent: June 24, 2014Assignee: BASF SEInventors: Torsten Neubauer, Marcus Hilgendorff, Stephan Siemund, Alfred H. Punke, Gerd Grubert
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Patent number: 8758464Abstract: The disclosed exhaust treatment device for a diesel engine can prevent heat damage to a DPF when regenerating said DPF. If a selection device (7), which selects whether to allow or prohibit an automatic DPF regeneration process, is set to prohibit the automatic DPF regeneration process, a DPF regeneration control device (4) is made able to start a process to cancel execution of the automatic DPF regeneration process. If the selection device (7) is set to allow the automatic DPF regeneration process, the DPF regeneration control device (4) retracts the cancellation of the automatic DPF regeneration process, allowing execution of the previously-cancelled automatic DPF regeneration process to begin.Type: GrantFiled: March 16, 2011Date of Patent: June 24, 2014Assignee: KUBOTA CorporationInventors: Yasuo Fujii, Masanori Fujiwara, Katsushi Inoue, Yuuki Ishii, Kenta Mitamura, Noriyoshi Eguchi, Yongchol Lee, Tomohiro Ninomiya
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Publication number: 20140170032Abstract: The present invention relates to a metal filter for purifying the exhaust gas from a ship, and a preparation method thereof. The purpose of the present invention is to provide: a metal filter for purifying the exhaust gas from a ship, capable of reducing nitrogen oxide by 85% or more at 250-300° C.; and a preparation method thereof. The metal filter for removing nitrogen oxide contained in the exhaust gas from a ship of the present invention comprises an integrated catalyst, wherein a metal substrate comprising irregularities is coated with a low temperature active catalyst in which vanadium (V), tungsten (W) and alumina sol are supported in a Ti-pillared clay (Ti-PILC) powdered support.Type: ApplicationFiled: March 22, 2013Publication date: June 19, 2014Applicants: HYUNDAI HEAVY INDUSTRIES CO., LTD., E&d CO., LTD., HYUNDAI BANGSTEEL CO., LTD.Inventors: Hee-Sung Yang, Joon-Ho Ko, Chan-do Park, Seok-Lyong Song, Jae-Woo Lee, Sung-Young Lee, Jai-Hyun Park, Kyoung-Jae Kim, Seung-Han Han, Young-Jin Cho, Tae-Min Kim, Ju-Yong Jung
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Patent number: 8753597Abstract: Systems and method for adjusting a cone angle of injected reductant directed into an engine exhaust upstream of a catalytic device based on the temperature distribution within the catalytic device are disclosed. In one particular example, a dosing unit comprising an adjustable piston is described whose adjustment further controls the distribution and amount of reaction fluid delivered therefrom. In this way, the fluid flow shape may be controlled to achieve a more optimal exhaust gas conversion based on the prevailing conditions within the exhaust gas system.Type: GrantFiled: May 22, 2013Date of Patent: June 17, 2014Assignee: Ford Global Technologies, LLCInventor: Yasser Mohamed sayed Yacoub
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Patent number: 8753598Abstract: A method of using a catalyst comprises exposing a catalyst to at least one reactant in a chemical process. The catalyst comprises copper and a small pore molecular sieve having a maximum ring size of eight tetrahedral atoms. The chemical process undergoes at least one period of exposure to a reducing atmosphere. The catalyst has an initial activity and the catalyst has a final activity after the at least one period of exposure to the reducing atmosphere. The final activity is within 30% of the initial activity at a temperature between 200 and 500° C.Type: GrantFiled: August 5, 2013Date of Patent: June 17, 2014Assignee: Johnson Matthey Public Limited CompanyInventors: Paul Joseph Andersen, Hai-Ying Chen, Joseph Michael Fedeyko, Erich Weigert
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Publication number: 20140157763Abstract: An extruded honeycomb catalyst for nitrogen oxide reduction according to the selective catalytic reduction (SCR) method in exhaust gases from motor vehicles includes an extruded active carrier in honeycomb form having a first SCR catalytically active component and with a plurality of channels through which the exhaust gas flows during operation, and a washcoat coating having a second SCR catalytically active component being applied to the extruded body, wherein the first SCR catalytically active component and the second SCR catalytically active component are each independently one of: (i) vanadium catalyst with vanadium as catalytically active component; (ii) mixed-oxide catalyst with one or more oxides, in particular those of transition metals or lanthanides as catalytically active component; and (iii) an Fe- or a Cu-zeolite catalyst.Type: ApplicationFiled: July 31, 2012Publication date: June 12, 2014Applicant: Johnson Matthey Public Limited CompanyInventors: Guy Richard Chandler, Neil Robert Collins, Ralf Dotzel, Jörg Werner Münch, Paul Richard Philips, Gudmund Smedler, Andrew Peter Walker
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Publication number: 20140161693Abstract: A catalysed soot filter for a diesel engine comprises a wall flow substrate having a substrate axial length, wherein surfaces of both the internal walls of a plurality of inlet and a plurality of outlet channels comprise a catalytic washcoat of at least one on-wall coating composition for oxidising NO in exhaust gas to NO2, wherein the washcoat on the inlet channels extends for an axial inlet coating length from an open inlet end to a downstream inlet coating end, the washcoat on the outlet channels extends for an axial outlet coating length from an upstream outlet end to an open outlet end, the axial inlet coating length and the axial outlet coating length are both less than the substrate axial length and the outlet coating length is greater than the inlet coating length.Type: ApplicationFiled: October 31, 2013Publication date: June 12, 2014Applicant: Johnson Matthey Public Limited CompanyInventors: Gavin Michael BROWN, Andrew Francis CHIFFEY, David MARVELL
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Patent number: 8747766Abstract: A hydrogen separation membrane comprising a palladium alloy that includes at least palladium, an added metal A, and an added metal B, the added metal A and the added metal B being two different metals other than palladium, each of the added metal A and the added metal B forming a complete solid solution with palladium, and the added metal A and the added metal B having a triple point in an equilibrium diagram and not forming an intermetallic compound. The hydrogen separation membrane exhibits excellent hydrogen permeability and durability.Type: GrantFiled: November 20, 2009Date of Patent: June 10, 2014Assignee: NGK Insulators, Ltd.Inventor: Kenichi Noda
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Patent number: 8747508Abstract: There is provided a honeycomb filter including: a honeycomb base material; plugged portions; and a porous collecting layer disposed on the surface of the partition wall parent material in at least the remaining cells. The collecting layer has a constitution in which a plurality of particles combine or intertwine with one another, and the collecting layer includes flat plate-like particles as the plurality of particles. The plurality of particles are particles in which an average long diameter is 0.2 ?m or larger and smaller than 10 ?m, an average value of ratios (long diameters/short diameters) of the long diameters to the short diameters of the respective particles is smaller than 3, and an average value of ratios (the long diameters/thicknesses) of the long diameters to thicknesses of the respective particles is 3 or larger. An open area ratio of the surface of the collecting layer is 10% or larger.Type: GrantFiled: March 15, 2012Date of Patent: June 10, 2014Assignee: NGK Insulators, Ltd.Inventors: Yoshinori Isoda, Yoshio Kikuchi
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Patent number: 8747510Abstract: An exhaust treatment unit including a longitudinal core around an axis, a support mat, and powdered insulation impregnated between first and second layers of the support mat. In assembly, the mat is first wrapped around the core once, and powdered insulation is applied to the surface of the unwrapped portion of the mat prior to further winding whereby powdered insulation is disposed between mat layers after further winding.Type: GrantFiled: September 12, 2012Date of Patent: June 10, 2014Assignee: Tenneco Automotive Operating Company, Inc.Inventors: Ruth Latham, William Alcini
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Patent number: 8747509Abstract: There is provided a honeycomb filter including a honeycomb base material including a porous partition wall parent material; plugged portions arranged in open frontal areas of predetermined cells in an end surface on an inflow side of the fluid, and open frontal areas of the remaining cells in an end surface on an outflow side of the fluid; and a porous collecting layer disposed on the surface of the partition wall parent material in the remaining cells. In a cross section orthogonal to an extending direction of the cells, a shape of the cells is a rectangular shape, and a thickness of a portion of the collecting layer which is positioned in each of corner portions of each of the cells is from one to three times that of a portion of the collecting layer which is positioned in the center of each of sides of the cell.Type: GrantFiled: March 20, 2012Date of Patent: June 10, 2014Assignee: NGK Insulators, Ltd.Inventor: Yoshio Kikuchi
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Patent number: 8745856Abstract: A ceramic filter element of ceramic material has an exterior surface that is provided with structural elements. The structural elements are produced by a non-cutting method. The structural elements are molded in the ceramic material in the form of grids, periodic patterns, irregular patterns, lettering or labels.Type: GrantFiled: August 8, 2011Date of Patent: June 10, 2014Assignee: Mann + Hummel GmbHInventors: Jochen Linhart, Sabine Otterbach, Kathrin Lichtenwalter, Michael Micke, Karin Gerlach
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Patent number: 8747788Abstract: An aftertreatment module for use with an engine is disclosed. The aftertreatment module may include a housing having an inlet configured to direct exhaust in a first flow direction into the aftertreatment module, and an outlet configured to direct exhaust in the first flow direction out of the aftertreatment module. The aftertreatment module may also include a catalyst bank separating the inlet from the outlet. The catalyst bank may have a face disposed at an oblique angle with respect to the first flow direction. The oblique angle may create an inlet passage extending from the inlet to the catalyst bank and having a decreasing cross-sectional area, and an outlet passage extending from the catalyst bank to the outlet and having an increasing cross-sectional area.Type: GrantFiled: January 25, 2013Date of Patent: June 10, 2014Assignee: Caterpillar Inc.Inventors: Mirza Pervaiz Baig, Andrew Michael Denis, Raymond Bassilli Gerges, Raymond Upano Isada
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Patent number: 8747511Abstract: A honeycomb filter includes a tubular honeycomb structure having porous partition walls with which there are formed a plurality of cells extending from one end surface to the other end surface to become through channels of a fluid; and plugged portions arranged in one open end portion of each of predetermined cells and the other open end portion of each of the remaining cells, porosities of the partition walls are 46% or less, a pore volume ratio of pores having pore diameters of 40 ?m or more is 7.5% or less, and a pore volume ratio of pores having pore diameters of 10 ?m or less is 25% or less, a permeability of the honeycomb structure is 0.8 ?m2 or more, and a coefficient of thermal expansion of the honeycomb structure in a range of 40 to 800° C. is 1.0×10?6/° C. or less.Type: GrantFiled: February 11, 2013Date of Patent: June 10, 2014Assignee: NGK Insulators, Ltd.Inventors: Koji Motoki, Hiroyuki Suenobu, Eriko Kodama
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Publication number: 20140154160Abstract: An emission control catalyst composition comprising a supported bimetallic catalyst consisting of gold and a metal selected from the group consisting of platinum, rhodium, ruthenium, copper and nickel is disclosed. Also disclosed is a catalytic convertor comprising a substrate monolith coated with the emission control catalyst composition and a lean burn internal combustion engine exhaust gas emission treatment system comprising the catalytic convertor. A variety of processes for preparing the catalyst composition are claimed.Type: ApplicationFiled: November 6, 2013Publication date: June 5, 2014Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANYInventors: Janet Mary FISHER, David THOMPSETT
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Publication number: 20140154145Abstract: A honeycomb catalyst body includes a plugged honeycomb structure having porous partition walls, inflow side plugged portions, outflow side plugged portions, and porous projecting portions which project so as to extend from the partition walls into the cells and are formed integrally with the partition walls; and catalyst loaded onto the projecting portions of the plugged honeycomb structure. A porosity of the partition walls of the plugged honeycomb structure is 40 to 70%, a thickness of the projecting portions is from 30 to 140% of a thickness of the partition walls, and an amount of a catalyst loaded onto pore surfaces of the partition walls of the plugged honeycomb structure is smaller than an amount of the catalyst loaded onto the projecting portions. The catalyst loaded onto projecting portions is a three-way catalyst, and the catalyst loaded onto projecting portions is a selective reduction catalyst.Type: ApplicationFiled: November 21, 2013Publication date: June 5, 2014Applicant: NGK INSULATORS, LTD.Inventor: Takashi AOKI
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Publication number: 20140154144Abstract: A honeycomb catalyst body capable of containing in a limited space, having high mechanical strength, less pressure loss, and suitable purification performance is provided, and it includes a plugged honeycomb structure having porous partition walls defining cells, plugged portions, and porous projecting portions projecting so as to extend from the partition walls into the cells and being formed integrally with the partition walls; and catalysts loaded onto the projecting portions, wherein a porosity of the partition walls is 40 to 70%, thicknesses of the projecting portions is from 30 to 140% of thicknesses of the partition wall, an amount of the catalyst loaded onto the partition walls thereof is smaller than an amount of the catalyst loaded onto the projecting portions, one catalyst loaded onto projecting portions is a selective reduction catalyst, and another catalyst loaded onto projecting portions is an ammonia slip preventing catalyst.Type: ApplicationFiled: November 21, 2013Publication date: June 5, 2014Applicant: NGK INSULATORS, LTD.Inventor: Takashi AOKI
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Publication number: 20140154146Abstract: A honeycomb catalyst body having high mechanical strength, less pressure loss, and suitable purification performance is provided, and includes a plugged honeycomb structure having porous partition walls defining cells extending from one end face to another end face, inflow side plugged portions provided at one ends of the predetermined cells, outflow side plugged portions provided at another ends of the remaining cells, and porous projecting portions projecting so as to extend from the partition walls into the cells and being formed integrally with the partition walls; and a catalyst loaded onto the projecting portions of the plugged honeycomb structure, wherein porosities of the partition walls are 40% or more and smaller than 60%, thicknesses of the projecting portions are from 30 to 140% of thicknesses of the partition walls, and a catalyst amount loaded onto the partition walls thereof is smaller than a catalyst amount loaded onto the projecting portions.Type: ApplicationFiled: November 26, 2013Publication date: June 5, 2014Applicant: NGK INSULATORS, LTD.Inventor: Takashi AOKI
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Publication number: 20140154147Abstract: The present invention relates to a mat for mounting one or more pollution control elements in a pollution control device for the treatment of exhaust gases, said mat comprising heat-treated glass fibers containing Al2O3 in an amount of 10 to 30% by weight and SiO2 in an amount of 52 to 65% by weight based on the total weight of the glass fibers.Type: ApplicationFiled: December 19, 2013Publication date: June 5, 2014Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventors: Ulrich E. Kunze, Lahoussaine Lalouch, Claus Middendorf, Harald H. Krieg
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Patent number: 8741242Abstract: A NOx storage component comprises caesium silicate (Cs2SiO3) and at least one platinum group metal. The invention also includes a NOx absorber catalyst comprising a NOx storage component according to the invention disposed on a substrate monolith; a method of treating exhaust gas containing NOx from a lean burn internal combustion engine comprising the steps of contacting a NOx storage component comprising caesium silicate (Cs2SiO3) and at least one platinum group metal with lean exhaust gas containing NOx to adsorb NOx thereon; and periodically desorbing adsorbed NOx by contacting the NOx storage component with stoichiometric or rich exhaust gas; and a method of making a NOx storage component according to the invention comprising the steps of combining and reacting an aqueous salt of at least one platinum group metal, an aqueous caesium salt and a source of silica.Type: GrantFiled: October 20, 2011Date of Patent: June 3, 2014Assignee: Johnson Matthey PLCInventors: Jonathan Ashley Cooper, Michael Anthony Howard
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Patent number: 8741020Abstract: An object is to provide an exhaust gas purification filter that can achieve high trapping efficiency of particulate matter and low pressure loss, and the exhaust gas purification filter includes an inflow surface through which exhaust gas containing particulate matter flows in, a discharge surface from which purified gas is discharged, and a filter base body that is formed from a porous body, wherein the filter base body includes porous partition walls and gas flow paths surrounded by the partition walls, a porous film having a pore size smaller than that of pores of the partition walls is provided on each surface of the partition walls, and microgrooves having a depth shallower than the thickness of the porous film are formed on at least a part of a surface of the porous film.Type: GrantFiled: April 7, 2011Date of Patent: June 3, 2014Assignees: Sumitomo Osaka Cement Co., Ltd., Honda Motor Co., Ltd.Inventors: Atsushi Kishimoto, Masamichi Tanaka, Keita Ishizaki, Katsunori Hanamura
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Publication number: 20140147359Abstract: A catalysed soot filter comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from a compression ignition engine disposed on a filtering substrate, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component.Type: ApplicationFiled: November 21, 2013Publication date: May 29, 2014Applicant: Johnson Matthey Public Limited CompanyInventors: David BERGEAL, Andrew Francis CHIFFEY, John Benjamin GOODWIN, Daniel HATCHER, Francois MOREAU, Agnes RAJ, Raj Rao RAJARAM, Paul Richard PHILLIPS, Cathal PRENDERGAST, Gavin Michael BROWN
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Publication number: 20140147342Abstract: There is disclosed a honeycomb catalyst body including porous partition walls in which a plurality of cells that become through channels of a fluid are defined and formed, and a plurality of pores are formed, wherein a cell density is from 93 to 186 cells/cm2, and onto the partition walls, a catalyst containing the zeolite is loaded in an amount of 100 to 300 g/L, a porosity (A) of the partition walls before the catalyst is loaded thereonto is 50% or more, and a porosity (B) of the partition walls in a state where the catalyst is loaded thereonto is from 0.3 to 0.6 times as much as the porosity (A).Type: ApplicationFiled: November 19, 2013Publication date: May 29, 2014Applicant: NGK INSULATORS, LTD.Inventors: Shogo HIROSE, Kazuto MIURA, Hirotaka YAMAMOTO, Fumio KATSUBE
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Publication number: 20140147341Abstract: A layered composite oxide is provided which is excellent in oxygen ion conductivity and, is capable of effectively decreasing a PM oxidation temperature without using a noble metal such as platinum or the like. The layered composite oxide is used in an oxidation catalyst, DPF, a ternary catalyst, and a NOx purification catalyst. The layered composite oxide has a composition represented by the following formula (1), La1.5Sr1.5Mn2-yByO7 . . . (1) (wherein B represents Cu and/or Fe, and y satisfies 0<y?0.2).Type: ApplicationFiled: October 3, 2011Publication date: May 29, 2014Applicant: Nissan Motor Co., Ltd.Inventors: Kohji Masuda, Fumio Munakata
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Patent number: 8734743Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.Type: GrantFiled: June 9, 2011Date of Patent: May 27, 2014Assignee: BASF SEInventors: Torsten W. Müller-Stach, Susanne Stiebels, Edith Schneider, Torsten Neubauer
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Patent number: 8734558Abstract: An exhaust gas purification filter 100 includes: a honeycomb structure 10 having partition walls 12, plugging portions 13, and a surface trapping layer 14 having an average pore size of 0.1 ?m or more and 5 ?m or less, a porosity of 50% or more and 80% or less, and a thickness of 1 ?m or more and 50 ?m or less. The partition walls 12 have a thickness of 0.05 mm or more and 0.18 mm or less and an average pore size of 10 or more and 18 ?m or less, and the proportion of the volume of the pores having a size of twice the average pore size or more in the entire pore volume in a pore size distribution of the partition walls 12 is 5% or more and 40% or less.Type: GrantFiled: May 11, 2012Date of Patent: May 27, 2014Assignee: NGK Insulators, Ltd.Inventor: Yukio Miyairi
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Patent number: 8728401Abstract: The pleated filter bag, which can be used in a bag-house type dust collector, is elongated and has a longitudinal hollow center with an open end, and a pleated filter wall circumscribing the hollow center. The pleated filter wall has a felt such as PTFE fibers felted onto an apertured and pleatable scrim which can be made of metal, and having a permeability lower than a permeability of the scrim. A membrane of lower-permeability material, such as an E-PTFE membrane, covers the support felt on the outer side of the bag.Type: GrantFiled: October 26, 2009Date of Patent: May 20, 2014Assignee: Sefar BDH, Inc.Inventors: Luc Parent, Sylvain Vieuille
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Publication number: 20140134063Abstract: Method for the preparation of a wall flow particulate filter catalysed at its inlet side with a first catalyst having activity in the removal of residual hydrocarbons and carbon monoxide and catalysing at rich burn engine operation conditions the reaction of nitrogen oxides with hydrogen and/or carbon monoxide to ammonia and catalysed at its outlet side with a second catalyst having activity in the selective reduction of NOx by reaction with ammonia being formed in the inlet side. The method involves the provision of a first catalyst having a particle size larger than the filter wall mean pore size, and a second catalyst having a particle size smaller than the filter wall mean pore size, and mixing the first and second catalyst into one suspension, which is used for wash-coating from the inlet end. The second catalyst thereby diffuses into the partition wall.Type: ApplicationFiled: June 14, 2012Publication date: May 15, 2014Applicant: Haldor Topsøe A/SInventors: Pär L. Gabrielsson, Keld Johansen
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Publication number: 20140130760Abstract: The invention provides an exhaust gas cleaning oxidation catalyst and in particular to an oxidation catalyst for cleaning the exhaust gas discharged from internal combustion engines of compression ignition type (particularly diesel engines). The invention further relates to a catalysed substrate monolith comprising an oxidising catalyst on a substrate monolith for use in treating exhaust gas emitted from a lean-burn internal combustion engine. In particular, the invention relates to a catalysed substrate monolith comprising a first washcoat coating and a second washcoat coating, wherein the second washcoat coating is disposed in a layer above the first washcoat coating.Type: ApplicationFiled: January 20, 2014Publication date: May 15, 2014Applicants: JOHNSON MATTHEY PUBLIC LIMITED COMPANY, JOHNSON MATTHEY JAPAN G.K.Inventors: SATOSHI SUMIYA, LIFENG WANG, HANAKO OYAMADA, PHILIP GERALD BLAKEMAN, MICHAEL GAVIN BROWN, SOUGATO CHATTERJEE, ANDREW FRANCIS CHIFFEY, JANE GAST, PAUL RICHARD PHILLIPS, RAJ RAO RAJARAM, ANDREW PETER WALKER
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Publication number: 20140135204Abstract: Objects of the invention are to provide silicoaluminophosphate particles that have excellent NOx purification performance and can suppress water adsorption-caused contraction and water desorption-caused expansion and to provide a honeycomb structure that has excellent NOx purification performance and can suppress the breakage of the honeycomb unit due to the adsorption or desorption of water, a method for manufacturing the honeycomb structure, and an exhaust gas purifying apparatus including the honeycomb structure. The silicoaluminophosphate particles of the invention have a metallic oxide attached to silicoaluminophosphate particles with a ratio of an amount of Si to a sum of amounts of Al and P in a range of 0.16 to 0.33, in which a specific surface area is in a range of 250 m2/g to 450 m2/g, and an external surface area is in a range of 10 m2/g to 35 m2/g.Type: ApplicationFiled: August 18, 2011Publication date: May 15, 2014Applicant: IBIDEN CO., LTD.Inventors: Yoshitoyo Nishio, Takunari Murakami
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Patent number: 8721978Abstract: Disclosed is a catalyst carrier which is used for carrying a catalyst thereon. The catalyst carrier is characterized in that the apparent specific heat measured at 800° C. is 1.8 times or more greater than that measured at room temperature, wherein the apparent specific heat means a charge heat amount required for substantially increasing the temperature of a unit mass (kg) by 1 K, inclusive of the influence of endotherm or exotherm caused by change in crystalline form, partial melting, coagulation, phase transformation, vitrification, amorphous-formation, crystallization and the like.Type: GrantFiled: June 11, 2008Date of Patent: May 13, 2014Assignee: NGK Insulators, Ltd.Inventor: Yukio Miyairi
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Patent number: 8722572Abstract: A metal catalyst substrate 1 is equipped with a honeycomb body 2 in which a corrugated metal foil 4 and a flat metal foil 5 are multiply rolled, their leader portions being overlapped with each other. A restricting portion 8 is formed at a core portion 7 of the honeycomb body 2 by a portion of the core portion being deformed to restrict flow of exhaust gas in a core portion 7.Type: GrantFiled: January 12, 2010Date of Patent: May 13, 2014Assignee: Calsonic Kansei CorporationInventors: Hiroshi Kodama, Kimiyoshi Nishizawa, Hiroshi Tanabe, Akio Sano, Misao Oinuma
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Patent number: 8721979Abstract: A honeycomb structure includes a ceramic block including a plurality of honeycomb fired bodies. Each of the plurality of honeycomb fired bodies includes large volume cells and small volume cells. Either one of the end portions of each of the large volume cells and the small volume cells is plugged. An aperture in the cross section in a central part of the honeycomb structure is about 65% or more. A ratio of an aperture of the first end face to an aperture of the second end face of the honeycomb structure is about 1.4 or more. Each of the cell walls except the peripheral walls has a thickness of about 0.1 mm to about 0.2 mm. The honeycomb structure has a diameter of about 200 mm or more. A ratio of a length to the diameter of the honeycomb structure is about 1.0 or less.Type: GrantFiled: January 4, 2012Date of Patent: May 13, 2014Assignee: Ibiden Co., Ltd.Inventors: Shigeaki Goto, Toyoki Ogasawara
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Patent number: 8721977Abstract: An exhaust treatment device includes an insulation material positioned between an inner shell and an outer shell. An inlet tube has an end in communication with a cavity defined by the inner shell. A substrate for treating engine exhaust is positioned within the inner shell. A metal mounting ring is positioned between the inner and outer shells and includes a mounting provision for receipt of a fastener.Type: GrantFiled: October 7, 2011Date of Patent: May 13, 2014Assignee: Tenneco Automotive Operating Company Inc.Inventors: Megan Wikaryasz, Rick Thompson, Pavel Robles, Cary Wright
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Publication number: 20140127088Abstract: A honeycomb structure includes honeycomb units which contain silicoaluminophosphate particles and an inorganic binder and are provided with a plurality of cells that extend in the longitudinal direction from a first end surface to a second end surface of the honeycomb structure and are partitioned by cell walls, in which Si/(Al+P) of the silicoaluminophosphate particles is in a range of 0.16 to 0.33 by molar ratio, a thickness of the cell wall is in a range of 0.10 mm to 0.25 mm, a cell density of the cells is in a range of 93 cells/cm2 to 155 cells/cm2, and a ratio R/L of a diameter R of the honeycomb structure to a total length L of the honeycomb structure is 1.0 or more.Type: ApplicationFiled: August 18, 2011Publication date: May 8, 2014Applicant: IBIDEN CO., LTD.Inventors: Toshiyuki Miyashita, Shin Fujii
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Publication number: 20140127087Abstract: An object of the invention is to provide composite particles that have excellent NOx purification performance and can suppress water adsorption-caused contraction and water desorption-caused expansion and to provide a honeycomb structure that has excellent NOx purification performance and can suppress the breakage of the honeycomb unit due to the adsorption or desorption of water, a method for manufacturing the honeycomb structure, and an exhaust gas purifying apparatus including the honeycomb structure. The composite particles of the invention are composite particles having a metallic oxide attached to silicoaluminophosphate particles with a ratio of an amount of Si to a sum of amounts of Al and P in a range of 0.16 to 0.33, in which a specific surface area is in a range of 250 m2/g to 450 m2/g, and an external surface area is in a range of 30 m2/g to 90 m2/g.Type: ApplicationFiled: August 18, 2011Publication date: May 8, 2014Applicant: IBIDEN CO., LTD.Inventors: Yoshitoyo Nishio, Takunari Murakami
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Patent number: 8715807Abstract: A mixture of fused grains mainly comprising or composed of an oxide phase of pseudo-brookite type and comprising titanium, aluminum and magnesium, the fused grains having the following chemical composition, in weight percentages on the basis of the oxides: less than 55% of Al2O3; more than 30% and less than 70% of TiO2; more than 1% and less than 15% of MgO, the fused grains also corresponding to the following composition, in molar percentages and on the basis of the single oxides Al2O3, TiO2, MgO: 180?3t+a?220, a?50, m=100?a?t, in which: a is the molar percentage of Al2O3; t is the molar percentage of TiO2; m is the molar percentage of MgO. A ceramic product obtained from such fused grains.Type: GrantFiled: July 2, 2009Date of Patent: May 6, 2014Assignee: Saint-Gobain Centre de Recherches et d'Etudes EuropeenInventors: Yves Boussant-Roux, Isabelle Cabodi, Samuel Marlin
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Patent number: 8715579Abstract: A honeycomb structure has a substantially circular-pillar-shape. The honeycomb structure includes at least one electrically conductive honeycomb unit, a first electrode, and a second electrode. The at least one electrically conductive honeycomb unit includes walls extending along a longitudinal direction of the at least one electrically conductive honeycomb unit to define a plurality of through holes. The first electrode is provided on an outer circumferential surface of the honeycomb structure. The second electrode is provided in a vicinity of a central axis of the honeycomb structure extending along the longitudinal direction.Type: GrantFiled: March 10, 2011Date of Patent: May 6, 2014Assignee: Ibiden Co., Ltd.Inventors: Takahiko Ido, Yoshihiro Koga, Takumi Asanuma, Keisuke Tange
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Patent number: 8715580Abstract: An exhaust gas treatment device is disposed in an exhaust gas treatment system and comprises a rolled metal cylinder of corrugated metal sheet having longitudinally extending passages extending axially from an inlet end to an outlet end and a conduit disposed between layers of the rolled metal cylinder and configured for circulation of a heat transfer medium therethrough, the conduit extending axially and radially the rolled metal cylinder.Type: GrantFiled: March 9, 2010Date of Patent: May 6, 2014Assignee: GM Global Technology Operations LLCInventor: John R. Bucknell
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Publication number: 20140120003Abstract: An electro-catalytic honeycomb for controlling exhaust emissions, which adopts to purify a lean-burn exhaust, comprises a honeycomb structural body, a solid-oxide layer and a cathode layer. The honeycomb structural body includes an anode, a plurality of gas channels, and a shell. The anode is formed as a backbone, the gas channels are formed inside the backbone for passing the exhaust, and the shell covers an outer surface of the anode. The solid-oxide layer is adhered to an inner surface of the anode and connects the shell so as to encapsulate the anode. The cathode layer is adhered to a tube wall of the solid-oxide layer and has an oxidizing environment. The anode has a reducing environment. The reducing and the oxidizing environment facilitate an electromotive force to occur between the anode and the cathode layer to promote a decomposition of nitrogen oxides of the exhaust into nitrogen and oxygen.Type: ApplicationFiled: November 1, 2012Publication date: May 1, 2014Inventor: Ta-Jen Huang
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High porosity ceramic honeycomb article containing rare earth oxide and method of manufacturing same
Patent number: 8709577Abstract: The present invention describes a high porosity (% P?45%), refractory, ceramic article comprising a cordierite ceramic phase and at least about 0.1 wt. % of a rare earth oxide, such as yttrium oxide or lanthanum oxide. When compared to typical high-porosity cordierite articles, the articles of the present invention may exhibit relatively high strength, relatively low microcracking, relatively high strain tolerance (MOR/E), and/or relatively high thermal shock resistance (TSP).Type: GrantFiled: June 28, 2007Date of Patent: April 29, 2014Assignee: Corning IncorporatedInventors: Douglas Munroe Beall, Yves Andre Henri Brocheton, Gregory Albert Merkel -
Patent number: 8709365Abstract: The invention relates to a catalytically active particulate filter which, in addition to the properties typical of particulate filters, has hydrogen sulphide block function, and to a process for removing nitrogen oxides and particulates from the exhaust gas of internal combustion engines operated predominantly under lean conditions (so-called “lean-burn engines”) using the inventive catalytically active particulate filter. This particulate filter comprises a filter body, a copper compound and an oxidation-catalytic active coating which comprises at least one catalytically active platinum group metal. The copper compound is in a second coating applied to the filter body. The two functional coatings may be applied to the filter body consecutive in the direction of flow, i.e. zoned, or layered one on top of the other.Type: GrantFiled: July 8, 2010Date of Patent: April 29, 2014Assignee: Umicore AG & Co. KGInventors: Franz Dornhaus, Stephanie Frantz, Ina Grisstede
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Patent number: 8709349Abstract: There is provided a wall flow type exhaust gas purification filter is provided with a honeycomb structure having porous ceramic partition walls 12 and plugging portions disposed in one side opening end portions of predetermined cells and the other side opening end portions of the other cells. In the exhaust gas purification filter, when an average pore size is obtained for each region of ? mm×? mm in a range of 10 mm2 in an arbitrary cross section perpendicular to a surface of the partition walls 12, a large pore region having an average pore size of 15 ?m or more has an area of 0.1 mm2 or more, and a small pore region having an average pore size of 8 ?m or less has an area of 0.1 mm2 or more.Type: GrantFiled: August 29, 2012Date of Patent: April 29, 2014Assignee: NGK Insulators, Ltd.Inventor: Yukio Miyairi