Abstract: The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound, comprising a step of making contact between said hydrocarbon compound and a catalytic composition comprising a chromium-based catalyst, said process being performed in a reactor made of a material comprising a base layer made of a material M1 and an inner layer made of a material M2, said base layer and said inner layer being laid against each other by bonding.

Abstract: The FCC process relies upon cyclones to physically separate vapor gases from solid catalyst particles. This device relates to the use of acoustic detectors to allow on-line measurement of cyclone performance and assist in unit troubleshooting and monitoring. In a fluid catalytic cracking (FCC) vessel containing a cyclone for separating solids from a solids-gas mixture, the cyclone comprises an outlet and an acoustic sensor attached to the outlet of the cyclone.

Abstract: The present disclosure relates to reactor components and their use, e.g., in regenerative reactors. A process and apparatus for utilizing different wetted areas along the flow path of a fluid in a pyrolysis reactor, e.g., a thermally regenerating reactor, such as a regenerative, reverse-flow reactor, is described.

Abstract: A method of forming a heterogeneous protective layer on a surface of a component in a reactor is useful for repair and/or protection. The reactor may be used for production of polycrystalline silicon or a reactant thereof. The heterogeneous protective layer comprises silicon, and may comprise silicon carbide (SiC) and/or silicon nitride (Si3N4). The method comprises providing a polymeric composition for forming the heterogeneous protective layer. The polymeric composition may comprise a polycarbosilane and/or a polysilazane. The method further comprises providing the component. The surface of the component comprises carbon, such as graphite, carbon fiber reinforced carbon, or a combination thereof. The method further comprises applying the polymeric composition on the surface to form a pre-cured coating layer. The method further comprises heating the pre-cured coating layer to form the heterogeneous protective layer.

Abstract: The invention relates to a process and apparatus for the production of synthesis gas from a hydrocarbon feedstock in a heat exchanger reformer, wherein a cooling medium is added to the heat exchange reformer.

Abstract: Compounds, synthesis of, and methods for synthesizing metal alkoxide derivatives; and metal alkoxide derivatives for use as flame retardants are described. Group 13 metal alkoxides having flame retardant properties may be prepared by reacting the group 13 metal trihydroxide with an alcohol.

Abstract: A cracking furnace construction includes a firebox defining a chamber having a high emissivity thermal protective coating disposed on at least part of the refractory walls and/or on process tubes disposed within the chamber. The coating contains an inorganic adhesive for metal/alloy tubes or colloidal silica and/or colloidal alumina for refractory walls or ceramic tubes, a filler, and one or more emissivity agents. A method of coating the firebox chamber includes preparing the surface of the tubes/refractory walls, preparing the coating, and applying the coating to the surface.

Abstract: A substrate processing chamber component comprising a chamber component structure having an yttrium-aluminum coating. The yttrium-aluminum coating comprises a compositional gradient through a thickness of the coating.

Abstract: A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst.

Abstract: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10?22 bar and oxygen partial pressure of 10?10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.

Abstract: Reactor and method of forming reactor that includes at least one wall section having an inner surface bounding an interior space, a lining arranged on the inner surface of the at least one wall to face the interior space, and at least one fluid connection, to which a negative pressure is appliable, that is structured to run through the at least one wall section to open into a space between the inner surface and the lining.

Abstract: A process and apparatus are disclosed for treating a hydrocarbon stream, the process including flowing the hydrocarbon stream through a hydrocarbon treating vessel, heating a portion of the hydrocarbon treating vessel to a predetermined temperature and for a predetermined amount of time and controlling sensitization and chloride stress corrosion cracking of the portion of the interior surface of the hydrocarbon treating vessel.

Abstract: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having an oxygen partial pressure of 10?15 bar, a carbon partial pressure above the carbon partial pressure of the zirconium carbide and zirconium oxide phase transition at the same temperature, and at temperatures below the temperature of the zirconium triple point at the oxygen partial pressure of 10?15 bar; and ii) when exposed to a gas having an oxygen partial pressure of 10?15 bar and at temperatures above the zirconium triple point at the oxygen partial pressure of 10?15 bar. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus.

Abstract: A countercurrent tank type supercritical water reactor with a sacrificial lining, comprising a cylinder body and a catalyst tank arranged inside, the upper part of the cylinder body is connected with a top cover, and the lower part of the cylinder body is connected with a spherical head, the inner side of the cylinder body, the inner side of the spherical head and the inner side of the top cover constitute the inner wall of the reactor, wherein the inner wall of the reactor is provided with a high temperature resistance and thermal insulation coating layer, the inner wall of the high temperature resistance and thermal insulation coating layer is provided with a sealing coating layer, and the inner wall of the sealing coating layer is provided with the sacrificial lining. The reactor is of a countercurrent tank type, which can prevent the reactor blockage caused by salt deposition.

Abstract: A shell which encloses an interior and has at least one first orifice for feeding at least one gas stream into the interior and at least one second orifice for withdrawing a gas stream fed to the interior beforehand via the at least one first orifice from the interior, the surface of the shell, on its side in contact with the interior, being manufactured at least partly, in a layer thickness of at least 1 mm, from a steel which has a specific elemental composition, and in the interior, a process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated is carried out in a reactor which is manufactured from the steel on its side in contact with the reaction gas.

Abstract: A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a composite material which consists, on its side in contact with the reaction chamber, of a steel B with specific elemental composition which, on its side facing away from the reaction chamber, either directly or via an intermediate layer of copper, or of nickel, or of copper and nickel, is plated onto a steel A with specific elemental composition, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.

Abstract: The invention relates to an adsorber, including a reaction chamber, an adsorbent having adsorption properties enabling the at least partial removal of water from a gas stream including NOx and/or SOx, and a coating essentially consisting of a polymer material on at least a portion of the inner metal wall of the reaction chamber, said polymer being resistant to the acidic liquids at temperatures above 150° C.

Abstract: A reactor vessel liner system includes a liner having an inner wall, an outer wall, and a plurality of passages extending between the inner wall and the outer wall. An attachment member extends outwards from the outer wall for securing the liner.

Abstract: Sintered refractory product including, in percentages by weight on the basis of the oxides, —more than 10% of chromium oxide Cr2O3, —more than 2% of hafnium oxide HfO2, —more than 1% of zirconium oxide ZrO2, the total content of chromium, hafnium and zirconium oxides Cr2O3+HfO2+ZrO2 being greater than 70%.

Abstract: A Low Temperature Conversion apparatus composed of tri-tubes which simultaneously carries out the functions of vessel and heat exchanger is provided. The apparatus is capable of thermally decomposing any kind of organic material to obtain coal, oil, water and non-condensable gases, and also decontaminating soils and residues contaminated with organochlorides and dioxins and comprises: an outer box (2) with a hermetic lid (19); a thermal insulation layer (5) disposed throughout the inner surface of the outer box (2) and lid; and at least a structure with three concentric tubes disposed internally, positioned substantially vertically and with a wall width suitable for heating by means of gases from an inner side and outer side of said structure. An associated process for thermal decomposition using the apparatus is also provided.

Abstract: Tube-bundle equipment for heat exchange operations at high pressures and temperatures, under conditions of high aggressiveness of the process fluids, comprising a titanium lining (11) and a series of tubes (1) consisting of at least one layer of zirconium (2), positioned in contact with said fluids, wherein the tube plate on which said tubes are inserted comprises an outer layer (S) of zirconium or an alloy thereof and an underlying layer (5) of titanium welded to the lining of the equipment. Said equipment is particularly used as a heat exchanger, for example as a stripper, in the high-pressure cycle of urea syntheses processes.

Abstract: Disclosed are a process and an apparatus for synthesizing nitroalkanes by reaction of a hydrocarbon feedstock with aqueous nitric acid. By using an isothermal reactor with multiple input ports for aqueous nitric acid, a hydrocarbon feedstock may be sequentially exposed to a plurality of flows of aqueous nitric acid as it flows through the reactor.

Abstract: A method for the oxidative coupling of hydrocarbons includes providing an oxidative catalyst inside a reactor and carrying out the oxidative coupling reaction under a set of reaction conditions. The reactor surfaces that contact the reactants and products do not provide a significant detrimental catalyzing effect. In an embodiment the reactor contains an inert lining or a portion of the reactor inner surface is treated to reduce the detrimental catalytic effects. In an embodiment the reactor contains a lining that includes an oxidative catalyst.

Abstract: A heater liner assembly suitable for covering the interior of a plasma processing chamber is provided. In some embodiments, a liner assembly for a processing chamber can include a heating element embedded in a body. A flange extending outward from an outer diameter of the body includes an upper surface having a sealing surface and at least one pad that extends from the upper surface of the flange to an elevation beyond the sealing surface. The pad contributes to control of the temperature of the liner assembly by maintaining the liner assembly spaced apart from the processing chamber.

Abstract: An embodiment of the invention includes a riser reactor for reacting a feedstock and catalyst. The riser reactor wall defines an interior. A continuous refractory lining is attached to the reactor wall and defines a plurality of flow disruptors that extend inward from the wall into the reactor interior and disrupt flow patterns of the feedstock and catalyst.

Abstract: In an embodiment, a reactor includes a section, wherein at least a portion of the section includes a base layer, wherein the base layer has a first composition that contains a silicide-forming metal element; and a silicide coating layer, wherein the silicide coating layer is formed by a process of exposing, at a first temperature above 600 degrees Celsius and a sufficient low pressure, the base layer having a sufficient amount of the silicide-forming metal element to a sufficient amount of a silicon source gas having a sufficient amount of silicon element, wherein the silicon source gas is capable of decomposing to produce the sufficient amount of silicon element at a second temperature below 1000 degrees Celsius; reacting the sufficient amount of the silicide-forming metal element with the sufficient amount of silicon element, and forming the silicide coating layer.

Abstract: Provided is a gas isolation valve which separates reactive materials, principally gases, contained in a high temperature reactor from the surrounding atmosphere. The valve is of modular construction with each module having a gas providing section and a gas removal section. Any number of modules can be provided in series. A central chamber, open at each end gives unimpeded access to the high temperature reactor. It is through the central chamber that the product of the reactor is removed and harvested. In the case of Ilas invention the product is carbon nanotubes.

Abstract: There is described an apparatus, a tubular laminar flow, plug flow reactor, for making silylamines and particularly trisilylamine (TSA) in high yields from ammonia gas and a monohalosilane gas. The apparatus can be a tubular flow reactor comprising a first portion of the reactor defining a gas entry zone, a second portion of the reactor defining a reaction zone and a third portion of the reactor defining a separation zone, the reaction zone providing a reactant contacting region. Trisilylamine can be recovered in the separation zone in a cold trap collection vessel.

Abstract: An anchoring system is provided for supporting a double-layered refractory lining of a process vessel. The refractory lining includes a first layer positioned adjacent to an inner surface of the process vessel and a second layer positioned adjacent to the first layer. The anchoring system has a plurality of bifurcated anchors extending from the internal surface of the process vessel through the first layer and into the second layer of the double-layered lining adjacent the first layer wherein the plurality of bifurcated anchors have a bifurcation disposed within the second layer.

Abstract: In operating the carbon monoxide removal reactor or the fuel reforming system, there is provided a technique for removing carbon monoxide in a stable manner for an extended period of time. In a method of removing carbon monoxide including an introducing step of introducing a reactant gas including mixture gas and an oxidizer added thereto to a carbon monoxide removal reactor forming in its casing a catalyst layer comprising a carbon monoxide removal catalyst for removing carbon monoxide contained in the mixture gas and a removing step of removing the carbon monoxide by causing the oxidizer to react with the mixture gas on the carbon monoxide removal catalyst, in said introducing step, the reactant gas of 100° C. or lower is introduced to the carbon monoxide removal reactor.

Abstract: A containment system, for instance, for containment of heat and/or chemical gases, is described, for instance, carbon-based containment systems that can include an insulation segment, a shield segment, and/or a divider segment, wherein each can be a plurality of panels, such as wall panels, that form walls.

Abstract: The invention describes catalysts, methods of making catalysts, methods of making a microchannel reactor, and methods of conducting chemical reactions. It has been discovered that superior performance can be obtained from a catalyst formed by directly depositing a catalytic material onto a (low surface area) thermally-grown alumina layer. Improved methods of conducting oxidative dehydrogenations are also described.

Abstract: Reactor for carrying out chemical and physical materials transformations, which comprises a reaction space enclosed by a reactor housing, where the reactor housing has at least two lateral fluid inlets having adjustably mounted nozzles which include an angle of about 20-160 degrees and through which fluid jets which impinge on one another at a common collision point within the reaction space are passed and the reactor has a fluid outlet at the bottom of the reaction space, which is characterized in that—an exchangeable bottom plate•which has a hole as fluid outlet and•on which moveably supported spheres are located so as to block the original path of the individual fluid jets in the unaligned state rests on the bottom of the reaction space and—a half shell standing upright on the bottom of the reaction space is located between each moveably supported sphere and the wall of the reactor space and—bottom plate, half shell and moveably supported spheres comprise one or more hard materials.

Abstract: A refractory wall is provided. The refractory wall includes a plurality of wall bricks coupled together to define an inner surface of the refractory wall, and a sensor port coupled to the plurality of wall bricks. The sensor port includes an outer wall defining a radial cross-sectional shape of the sensor port and defining a top ridge of the sensor port, an inner wall defining an opening extending through the sensor port, and an end wall extending between the outer wall and the inner wall. The end wall is positioned radially inward a distance from the inner surface. A method for fabricating the refractory wall is also provided.

Abstract: Collecting line for removing hot process gases conducted in process gas tubes from tubular reformers, wherein the collecting line has on the inside at least one insulation layer made of fire-resistant concrete or fire-resistant brick, and on the outside a wall made of a metallic outer tube, comprises a plurality of stubs via which the process gas tubes of the tubular furnace can be connected to the collecting line, wherein in the region of the stubs, the process gas tubes are at least in part conducted in guide tubes, and each gas outlet connected to the respective process gas tube projects into the collecting line, by means of which the process gas is introduced into the collecting line in correct functioning, and at least one gas outlet is constructed as a pipe bend.

Abstract: The present invention is a process for converting methane to methanol, comprising: feeding methane and gaseous air or oxygen or gaseous air enriched with oxygen to a reactor under an elevated pressure; said reactor having an internal surface, made of silica or coated with silica, surrounding a zone in which said gases react; and reacting said gases in said reaction zone at an elevated temperature at conditions effective to produce methanol and for valuable oxygenates. Advantageously the internal surface is made of quartz or coated with quartz Advantageously the internal surface, made of silica (advantageously quartz) or coated with silica (advantageously quartz), is treated with HF before the conversion of methane to methanol. Advantageously the reaction is carried out in the absence in said reaction zone of any added material which measurably affects the rate of the reaction or the yield of the product. Advantageously the reactor is operated under a pressure from 1 to 7.5 MPa.

Abstract: The disclosed invention relates to a decontaminant dispenser which may be used as a projectile. The invention also relates to a decontamination process using the decontaminant dispenser. The decontaminant dispenser may be thrown by hand, launched as an artillery shell or the payload for a missile, or dropped by an airplane into the area to be decontaminated. The dispenser may be placed in the area to be decontaminated. The decontaminant dispenser may be ruggedized for use in hostile environments such as those that may be anticipated for military applications.

Abstract: A method and apparatus for conducting supercritical wet oxidation reactions wherein any precipitated solids do not contact the solid side walls of the containment vessel so as to prevent any of these precipitated solids from adhering to or corrode the vessel walls is provided. To do this, a controlled, continuous flow of clean fluid, preferably under supercritical conditions, is introduced to the process so as to form a film-like, clean fluid surface between the physical containment vessel walls and the supercritical wet oxidation reactants.

Abstract: A process and a reactor system for the preparation of an olefinic product by reacting an oxygenate feedstock in the presence of an oxygenate conversion catalyst within a reactor system under oxygenate-to-olefin conversion conditions, to obtain the olefinic product, wherein the reactor system has a contact surface coming in contact with oxygenates and wherein at least part of the contact surface is an material of the formula MX wherein: M is a metal and X is C, or M is a metal or Si and X is N.

Abstract: Methods and apparatus for the production of high purity silicon including a fluidized bed reactor with one or more protective layers deposited on an inside surface of the fluidized bed reactor. The protective layer may be resistant to corrosion by fluidizing gases and silicon-bearing gases.

Abstract: The invention concerns a water treatment device comprising a reactor (1) and means for injecting (2) at least one reagent into said reactor, characterized in that it comprises means for supporting said injection means mobile relative to said reactor (1) between an active position whereby the injecting means (2) are arranged inside said reactor and a retracted position whereby the injecting means (2) are brought outside said reactor.

Abstract: A reactor for moisture generation generates high-purity moisture at a catalytic reaction temperature that is lower than an ignition point of hydrogen gas and oxygen gas so hydrogen and oxygen gas are supplied into the reactor having a platinum catalyst layer to catalyze the reaction of the gases without combustion, wherein the reactor maintains high adhesion strength for a long time of the platinum catalyst layer to a barrier layer provided between the base material and the platinum catalyst layer. The reactor includes a reactor main body that has a gas inlet and a moisture outlet, and the Y2O3 barrier layer is formed on at least a part of an internal wall surface of the reactor main body, and the platinum catalyst layer is formed on at least a part of the Y2O3 barrier layer. A film thickness of the Y2O3 barrier layer is preferably 50 nm to 5 ?m.

Abstract: A coating applied to at least a portion of the surfaces of reactors, reactor internals, other reactor components, and/or heater tubes is provided in order to minimize the formation of metal catalyzed coke in hydrocarbon conversion processes operating at temperatures at about 350° C. (662° F.) or greater and in reducing environments. These coatings may comprise Nickel coatings or complexes thereof, such as Ni—Al, Ni—Cr/Cr carbide, as well as aluminum painted coatings that are applied in a reduction cure process (e.g., application temperatures of about 600° C. (1112° F.)). Additionally, where H2S is necessary for the process, such as to minimize thermal cracking, the coatings also reduce corrosion of base metal due to sulfidation attack and eliminate the requirement of continuous replacement of reactor internals and other components.

Abstract: A refractory lining system comprises an inner refractory layer; and an outer layer located outside of the inner refractory layer, the outer layer comprising: a plurality of layer segments; and at least one control joint located between the plurality of layer segments, the at least one control joint configured to allow expansion and contraction in the outer layer. A segment of an outer layer of a refractory lining comprises an edge shaped corresponding to a control joint configured to allow expansion and contraction in the outer layer.

Abstract: A component capable of being exposed to a plasma in a process chamber has a structure having an electroplated coating comprising yttrium-containing species. The electroplated coating can include zirconium oxide, or can have an oxide layer thereon. In another embodiment the electroplated coating comprises a first species and is coated with a second electroplated coating comprising a second species that is different from the first species. The electroplated coating is resistant to corrosion in the plasma. In another embodiment, the electroplated coating has an interface having a thickness with a first concentration gradient of an yttrium-containing species and a second concentration gradient of a second species. An electroplated coating having a layer comprising first and second concentration gradients of first and second metals can be formed by varying the concentration of the first and second metal electrolyte species in the electroplating bath to electroplate the coating.

Abstract: This specification describes the use of a composition comprising a nanoscale powder, a porous ceramic powder and a solvent for protecting a metallic surface against chemical attacks at high temperatures, in particular in a reducing and/or carburizing atmosphere, and also a corresponding process. Furthermore, this specification describes a plant part having a metallic surface which, in the operating state, is exposed to a reducing and/or carburizing atmosphere, wherein the surface is coated with a porous protective coating having a specific surface area of at least 20 m2/g.

Abstract: A method for cracking hydrocarbon, comprises: providing steam and hydrocarbon; and feeding steam and hydrocarbon into a reactor accessible to hydrocarbon and comprising a perovskite material of formula AaBbCcDdO3-?, wherein 0<a<1.2, 0?b?1.2, 0.9<a+b?1.2, 0<c<1.2, 0?d?1.2, 0.9<c+d?1.2, ?0.5<?<0.

Abstract: The invention relates to coated reactors resistant to acid corrosion, the production method thereof and the use of same in processes in superacid media. More specifically, the invention relates to a reactor comprising an inner metal wall having a fluoropolymer coating anchored thereto using a perforated sheet positioned between the inner metal wall and the fluoropolymer coating. The surface of the sheet that is in contact with the metal wall of the reactor has a sufficient roughness in order to form a free space (for gases) between same and the metal wall of the reactor. In addition, the reactor is provided with a device for maintaining the pressure in the free space below that in the reactor.

Abstract: The invention relates to a complete method for producing pure silicon that is suitable for use as solar-grade silicon, comprising the reduction of a silicon oxide, purified by acidic precipitation from an aqueous solution of a silicon oxide dissolved in an aqueous phase, using one or more pure carbon sources, the purified silicon oxide being obtained, in particular, by the precipitation of a silicon oxide dissolved in an aqueous phase in an acidifier. The invention also relates to a formulation containing an activator and to a device for producing silicon, a reactor and electrodes.

Abstract: High performance coated metal compositions resistant to metal dusting corrosion and methods of providing such compositions are provided by the present invention. The coated metal compositions are represented by the structure (PQR), wherein P is an oxide layer at the surface of (PQR), Q is a coating metal layer interposed between P and R, and R is a base metal. P includes alumina, chromia, silica, mullite or mixtures thereof. Q includes Ni and Al, and at least one element selected from the group consisting of Cr, Si, Mn, Fe, Co, B, C, N, P, Ga, Ge, As, In, Sn, Sb, Pb, Sc, La, Y, Ce, Ti, Zr, Hf, V, Nb, Ta, Mo, W, Ru, Rh, Ir, Pd, Pt, Cu, Ag, Au and mixtures thereof. R is selected from the group consisting of carbon steels, low chromium steels, ferritic stainless steels, austenetic stainless steels, duplex stainless steels, Inconel alloys, Incoloy alloys, Fe—Ni based alloys, Ni-based alloys and Co-based alloys.