Abstract: A process for producing methanol, where a hydrocarbon feedstock (1) is reformed and a make-up syngas is reacted in a synthesis loop, obtaining crude methanol which is further treated to obtain high-grade methanol, and where the carbon dioxide dissolved in the crude methanol is recycled to the reforming section in order to adjust the stoichiometric number of the make-up syngas. In a preferred embodiment, a flash gas (9) separated from the crude methanol (8) and light ends (10) coming from distillation are recycled to a compressor (106) and fed to a primary reformer (100); further carbon dioxide can be recycled from the flue gas (11).
Abstract: A method comprises providing a bio-based feedstock; contacting the bio-based feedstock with a solvent in a hydrolysis reaction to form an intermediate stream comprising carbohydrates; contacting the intermediate stream with an aqueous phase reforming catalyst to form a plurality of oxygenated intermediates, wherein a first portion of the oxygenated intermediates are recycled to form the solvent; and contacting at least a second portion of the oxygenated intermediates with a condensation catalyst comprising a base functionality to form a fuel blend.
Type:
Application
Filed:
May 12, 2011
Publication date:
November 17, 2011
Applicant:
SHELL OIL COMPANY
Inventors:
Juben Nemchand Chheda, Lorna Beatriz Ortiz-Soto, Joseph Broun Powell
Abstract: In an oligomerization apparatus comprising at least two oligomerization reactors, at least portions of product streams from two reactors are separated in the same separator vessel; a liquid product stream from the first oligomerization reactor is fed to a fractionation column and a side cut from the fractionation column feeds the second oligomerization reactor.
Type:
Grant
Filed:
August 20, 2010
Date of Patent:
November 8, 2011
Assignee:
UOP LLC
Inventors:
Bipin V. Vora, Charles P. Luebke, Jill M. Meister, Michael A. Schultz, Dale J. Shields
Abstract: An apparatus and method for storing and releasing hydrogen is disclosed. In one embodiment, the apparatus includes a reactor, a heater having a first portion that is located in the reactor; a dehydrogenation catalyst that is affixed to the first portion of the heater; a hydrogen release conduit in communication with the reactor; a chamber containing a hydrogenated carrier; and an energy source coupled to the heater.
Type:
Application
Filed:
May 3, 2010
Publication date:
November 3, 2011
Applicant:
AIR PRODUCTS AND CHEMICALS, INC.
Inventors:
Alan Charles Cooper, Robert Gregory Wolf
Abstract: An apparatus is described for the preferential conversion to 2-butene of a stream containing C4 compounds including 1-butene and 2-butene involving mixing the C4 stream with a first hydrogen stream to form a feed stream, hydroisomerizing the feed stream in the presence of a first hydroisomerization catalyst in order to convert at least a portion of the 1-butene to 2-butene, thereby producing a hydroisomerization effluent, passing the hydroisomerization effluent through a fractionation column to form a top stream comprising isobutane and isobutylene and a bottoms stream comprising 2-butene, withdrawing a recycle stream from said fractionation column at a location above the feed point at which the weight ratio of 1-butene to 2-butene is high, and combining the recycle stream with at least one of the C4 stream and the feed stream upstream from the hydroisomerization catalyst.
Type:
Grant
Filed:
July 16, 2009
Date of Patent:
September 27, 2011
Assignee:
Lummus Technology Inc.
Inventors:
Robert J. Gartside, Thomas P. Skourlis, Hassan Kaleem
Abstract: The invention relates to a plant for carrying out chemical reactions, having a reactor (1), the reaction space of which contains hydrogen peroxide (H2O2) and titanium silicalite (TS-1). The object of the invention is to improve such a plant such that continuous separation and recycling of the active catalyst to the reaction space is possible with a long filter service life. This is achieved in that the reaction space contains a solid silicon source, in that the plant comprises a water takeoff line (3) which is set up for drawing off water in addition to components which are dissolved and/or dispersed therein from the reaction space, in that the water takeoff line (3) leads to a filter (4) which separates off the components which are dissolved and/or dispersed in the water, and in that the plant has a return line (5) which is set up for recirculating to the reaction space components which are separated off by means of the filter (4).
Type:
Grant
Filed:
September 9, 2008
Date of Patent:
September 20, 2011
Assignee:
Evonik Degussa GmbH
Inventors:
Goetz Baumgarten, Martin Roos, Stephan Schaeflein, Rolf Augenstein
Abstract: A system and method for producing natural gas is provided. a gas dynamic laser is powered by a gas, such as carbon dioxide, while the same gas is converted by a catalytic converter heated by the beam of the laser. Other gases can be formed simultaneously in other catalytic converters heated by the laser beam. The resulting converted gases can be used to produce a fuel gas. Excess heat and/or by-products of the process can be used to produce electricity.
Abstract: This invention relates to a process for cracking hydrocarbon feedstock containing resid comprising: (a) heating a hydrocarbon feedstock containing resid; (b) adding molecular hydrogen to said heated feedstock to form a mixture stream; (c) adding a catalyst containing metal-sulfide particles to said heated feedstock and/or said mixture stream; (d) reacting said mixture in a catalytic hydrovisbreaking reactor under conditions of temperature, pressure and residence time sufficient to catalytically hydrovisbreak at least a portion of said resid into hydrovisbroken hydrocarbon components; (e) passing said reacted mixture stream into a high pressure separator and separating hydrogen from said reacted mixture; (f) passing said reacted mixture through a knockout drum to remove catalyst and unreacted or uncracked resid as a bottoms stream; and (g) passing said catalytically hydrovisbroken hydrocarbon components into a steam cracking furnace and thermally cracking said hydrocarbon components to form light olefins, a
Type:
Application
Filed:
January 22, 2010
Publication date:
July 28, 2011
Inventors:
Stephen Mark Davis, Paul F. Keusenkothen, Jonathan Martin Mcconnachie, Larry L. Iaccino, Richard C. Stell
Abstract: A system for converting fuel is provided and includes a first reactor comprising a plurality of ceramic composite particles, the ceramic composite particles comprising at least one metal oxide disposed on a support, wherein the first reactor is configured to reduce the at least one metal oxide with a fuel to produce a reduced metal or a reduced metal oxide; a second reactor configured to oxidize at least a portion of the reduced metal or reduced metal oxide from the said first reactor to produce a metal oxide intermediate; a source of air; and a third reactor communicating with said source of air and configured to regenerate the at least one metal oxide from the remaining portion of the solids discharged from the said first reactor and the solids discharged from the said second reactor by oxidizing the metal oxide intermediate.
Abstract: A method comprises providing a bio-based feedstock; contacting the bio-based feedstock with a solvent in a hydrolysis reaction to form an intermediate stream comprising carbohydrates; contacting the intermediate stream with an apr catalyst to form a plurality of oxygenated intermediates, wherein a first portion of the oxygenated intermediates are recycled to form the solvent; and processing at least a second portion of the oxygenated intermediates to form a fuel blend.
Type:
Application
Filed:
December 17, 2010
Publication date:
June 30, 2011
Inventors:
Juben Nemchand CHHEDA, Joseph Broun Powell
Abstract: A method and system for treating coal with hydrogen fluoride to remove fly ash and thereafter regenerating substantially all of the hydrogen fluoride used during the process (thereby significantly reducing the amount of HF on site). An exemplary method includes the steps of charging at least one reaction vessel with coal containing fly ash; feeding hydrogen fluoride into the reaction vessel to form a first reaction mixture of soluble reaction products, insoluble fluoride compounds and initially clean coal; separating out the first soluble and insoluble reaction products; feeding nitric acid into the same reaction vessel to react with any remaining fly ash components and separating out those second reaction products; and regenerating substantially all of the hydrogen fluoride used in the first fluoride reaction.
Type:
Application
Filed:
October 1, 2009
Publication date:
April 7, 2011
Inventors:
Chandrashekhar Ganpatrao Sonwane, Sam David Draper, Eric Stephen Kaufman, Michael David Newkirk
Abstract: Processing schemes and arrangements are provided for obtaining ethylene and ethane via the catalytic cracking of a heavy hydrocarbon feedstock and converting the ethylene into ethyl benzene without separating the ethane from the feed stream. The disclosed processing schemes and arrangements advantageously eliminate any separation of ethylene from ethane produced by a FCC process prior to using the combined ethylene/ethane stream as a feed for an ethyl benzene process. Further, heat from the alkylation reactor is used for one of the strippers of the FCC process and at least one bottoms stream from alkylation process is used as an absorption solvent in the FCC process.
Abstract: A system comprising a riser reactor comprising a gas oil feedstock and a first catalyst under catalytic cracking conditions to yield a riser reactor product comprising a cracked gas oil product and a first used catalyst; an intermediate reactor comprising at least a portion of the cracked gas oil product, a raffinate stream, and a second catalyst under high severity conditions to yield a cracked intermediate product and a second used catalyst; and a recycle conduit to send at least a portion of the cracked gas oil product to the riser reactor.