Alkali Metal Or Ammonium Containing Patents (Class 423/312)
  • Patent number: 9023523
    Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bMb1Fe1-cMc2Pd-eMe3Ox, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Kirill Bramnik, Hartmut Hibst, Jordan Keith Lampert
  • Publication number: 20150118395
    Abstract: Metal silicates or phosphates are deposited on a heated substrate by the reaction of vapors of alkoxysilanols or alkylphosphates along with reactive metal amides, alkyls or alkoxides. For example, vapors of tris(tert-butoxy)silanol react with vapors of tetrakis(ethylmethylamido)hafnium to deposit hafnium silicate on surfaces heated to 300° C. The product film has a very uniform stoichiometry throughout the reactor. Similarly, vapors of diisopropylphosphate react with vapors of lithium bis(ethyldimethylsilyl)amide to deposit lithium phosphate films on substrates heated to 250° C. Supplying the vapors in alternating pulses produces these same compositions with a very uniform distribution of thickness and excellent step coverage.
    Type: Application
    Filed: December 31, 2014
    Publication date: April 30, 2015
    Inventors: Roy Gerald GORDON, Jill S. BECKER, Dennis HAUSMANN, Seigi SUH
  • Publication number: 20150064119
    Abstract: The invention relates to a cosmetic formulation comprising an additive agent. The additive agent having a water soluble linear alkali polyphosphate with a chain length of at least 4 to 50. The alkali polyphosphate exhibits complexing, dispersing, and antimicrobial effects. The alkali polyphosphate has a pH in the range of 6.5 to 8.5 (in aqueous solutions).
    Type: Application
    Filed: March 27, 2014
    Publication date: March 5, 2015
    Applicant: BK Giulini Chemie Gmbh
    Inventors: Thauern Henrike, Gabriele Brix, Thomas Staffel
  • Patent number: 8951667
    Abstract: Electrode active material of the invention is mainly an amorphous transition metal complex represented by AxMPyOz (where x and y are values which independently satisfy 0?x?2 and 0?y?2, respectively, and z=(x+5y+valence of M)/2 to satisfy stoichiometry; also, A is an alkali metal and M is a metal element selected from transition metals), and has a peak near 220 cm?1 in Raman spectroscopy. Applying the electrode active material of the invention to a nonaqueous electrolyte secondary battery increases the capacity of the nonaqueous electrolyte secondary battery.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: February 10, 2015
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Motoshi Isono
  • Patent number: 8795894
    Abstract: Disclosed are a positive electrode active material and a method for producing an olivine-type phosphate. The positive electrode active material comprises an olivine-type phosphate represented by the following formula (I), wherein the maximum peak in an X-ray diffraction pattern obtained using a CuK? ray is the peak of the (031) plane of the olivine-type phosphate and the half-value width of the peak is 1.5° or less: AaMbPO4 (I), wherein A represents one or more elements selected from among alkali metals; M represents one or more elements selected from among transition metals; a is from 0.5 to 1.5; and b is from 0.5 to 1.5. The method for producing an olivine-type phosphate comprises preparing a raw material comprising element A, element M, and phosphorus (P) so that a A:M:P molar ratio may be a:b:1, preliminary calcining the raw material, and mainly calcining the preliminary calcined raw material.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: August 5, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Maiko Sakai, Taketsugu Yamamoto, Masami Makidera, Satoru Kuze, Takeshi Hattori
  • Patent number: 8778289
    Abstract: The present invention relates to a method of extracting lithium from a lithium bearing solution. More specifically, the present invention provides a method of economical extraction of lithium from a lithium bearing solution by adding a phosphorous supplying material to the solution to precipitate lithium phosphate from the dissolved lithium.
    Type: Grant
    Filed: January 8, 2013
    Date of Patent: July 15, 2014
    Assignee: Research Institute of Industrial Science & Technology
    Inventors: Uong Chon, Oh Joon Kwon, Ki Hong Kim, Chang Ho Song, Gi Chun Han, Ki Young Kim
  • Patent number: 8673497
    Abstract: The present invention relates to a Process for the preparation of compounds of general formula (I), Lia-bM1bFe1-cM2cPd-eM3eOx, wherein M1, M2, M3, a, b, c, d and e: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.
    Type: Grant
    Filed: April 16, 2009
    Date of Patent: March 18, 2014
    Assignee: BASF SE
    Inventors: Hartmut Hibst, Brian Roberts, Jordan Keith Lampert, Kirill Bramnik
  • Publication number: 20140037521
    Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.
    Type: Application
    Filed: October 3, 2013
    Publication date: February 6, 2014
    Applicant: Simbol Inc.
    Inventors: Stephen Harrison, Robert Blanchet
  • Publication number: 20130338350
    Abstract: The current disclosure provides methods and kits for isolating nucleic acid from an environmental sample. The current methods and compositions further provide methods for isolating nucleic acids by reducing adsorption of nucleic acids by charged ions and particles within an environmental sample. The methods of the current disclosure provide methods for isolating nucleic acids by releasing adsorbed nucleic acids from charged particles during the nucleic acid isolation process. The current disclosure facilitates the isolation of nucleic acids of sufficient quality and quantity to enable one of ordinary skill in the art to utilize or analyze the isolated nucleic acids for a wide variety of applications including, sequencing or species population analysis.
    Type: Application
    Filed: June 14, 2013
    Publication date: December 19, 2013
    Inventors: Richard Ashley Hurt, JR., Dwayne A. Elias
  • Patent number: 8586241
    Abstract: The present invention relates to a process for the preparation of compounds of general Formula (I) La-bM1bFe1-cM2cPd-eM3eOx (I), wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, 15 d: 0.8-1.9, e: 0-0.5, x: 1.
    Type: Grant
    Filed: August 25, 2009
    Date of Patent: November 19, 2013
    Assignee: BASF SE
    Inventors: Kirill Bramnik, Hartmut Hibst, Jordan Keith Lampert
  • Patent number: 8518359
    Abstract: Phosphorous ions are extracted (210) from solutions by adsorbing phosphorous ions in a scavenger and by releasing the phosphorous ions into an eluate during regeneration (230) of the scavenger. The regeneration (230) is performed by ammonia. Phosphate anions are precipitated (262) in form of tri-ammonium phosphate upon introduction (260) of excess amounts of ammonia. The ammonia remaining in solution after the precipitation of tri-ammonium phosphate is reused (266) for regenerating the scavenger.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: August 27, 2013
    Assignee: EasyMining Sweden AB
    Inventor: Yariv Cohen
  • Patent number: 8496902
    Abstract: Process for the preparation of an insertion compound of an alkali metal in which the following successive stages are carried out: a) an organic complex of a transition metal or of a mixture of transition metals M in an oxidation state of greater than 2 is brought into contact with an alkali metal A in the ionic form and with an entity of formula Hb(XO4), where X is chosen from Si, S, Al, P, Ge, As or Mo and b has a value from 0 to 5, in a liquid medium in a closed chamber; the chamber is brought to a temperature T which makes possible the decomposition of the organic complex in the said liquid medium; the temperature and the pressure in the chamber are brought back to ambient temperature and atmospheric pressure and the insertion compound for an alkali metal of formula AMXO4, in which M is in the +2 oxidation state, is recovered.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: July 30, 2013
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Sylvain Franger, Sébastien Martinet, Frédéric Le Cras, Carole Bourbon
  • Patent number: 8486354
    Abstract: A method for extracting rare earth elements from monazite is disclosed. The method includes milling a mixture of monazite including phosphates and rare earth elements and sodium hydroxides inside a mill containing a plurality of balls to form powder by colliding the mixture into balls with each other, converting the mixture into rare earth hydroxides and sodium phosphates through the reaction occurring in the process of repeated collision, and extracting rare earth elements from the powder.
    Type: Grant
    Filed: November 26, 2009
    Date of Patent: July 16, 2013
    Assignee: Korea Institute of Geoscience and Mineral Resources (KIGAM)
    Inventors: Hee-Young Shin, Whan-Tae Kim, In-Kook Bae, Soo-Chun Chae
  • Patent number: 8461239
    Abstract: A flame retardant agent for a thermoplastic resin, which enables the thermoplastic resin containing the flame retardant agent to keep its viscous property, to be made into a fiber readily, and to exhibit flame retardant effect even when ammonium dihydrogen phosphate is contained in the flame retardant agent as a non-halogen flame retardant component. Also disclosed is a flame retardant resin composition containing the flame retardant agent. Specifically, the flame retardant agent for a thermoplastic resin comprises ammonium dihydrogen phosphate, potassium hydroxide, glycerin and urea, wherein the potassium hydroxide is contained in an amount of 10 to 70 parts by weight, glycerin is contained in an amount of 0.1 to 4.0 parts by weight, and urea is contained in an amount of 1 to 9 parts by weight relative to 100 parts by weight of ammonium dihydrogen phosphate.
    Type: Grant
    Filed: January 12, 2012
    Date of Patent: June 11, 2013
    Assignee: Morikawa Shoten Co., Ltd.
    Inventors: Keisuke Morikawa, Shoji Ichii
  • Publication number: 20130121906
    Abstract: The present invention relates to a process for preparing inorganic hydrogels with alkali halides such as common salt (NaCl) and methods of making such hydrogels. The present invention provides hydrogels that may be formed by the self-assembly or may be brought about by a change in one or more characteristics of the solution. A characteristic of the solution that may change includes pH, temperature, and concentration of one or more specific ion. This invention further discloses the use of only inorganic components towards the formation of inorganic hydrogels.
    Type: Application
    Filed: March 10, 2011
    Publication date: May 16, 2013
    Inventors: Ajeet Singh, Bishwajit Ganguly
  • Patent number: 8318118
    Abstract: A process for the treatment of gas phase alkaline chlorides in a combustion plant that is arranged for combustion of solid fuel and which includes a combustion chamber from which a flue-gas flow is directed to pass a heat transfer device. A phosphorous substance is added to the flue-gas flow, separate from the fuel, the substance chosen from a group of substances that form phosphorous oxide at combustion temperatures of approx. 500° C. or above, wherein the phosphorous substance is distributed in the flue-gas at a location upstream of the heat transfer device. The phosphorous substance is added to an amount which results in phosphatising of gas phase alkaline chlorides included in the flue-gas flow before the chlorides reach the heat transfer device. A corresponding combustion plant is disclosed, as well as the use of a phosphorous substance for phosphatising alkaline chloride in gaseous phase in a flue-gas flow.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: November 27, 2012
    Assignee: Vattenfall AB
    Inventors: Matts Ahlmark, Magnus Berg
  • Publication number: 20120207660
    Abstract: A preparation method for a water-insoluble crystal form ammonium polyphosphate includes conveying crystal H-type phosphorus pentoxide and diammonium phosphate at a molar ratio of 1:1-1.5 into a malaxator with twin screws, and injecting ammonia gas for 3-40 minutes into the malaxator at 20-25 m3/h while preheating the material at a temperature between 100° C. and 300° C. Therafter one injects ammonia gas again at 8-15 m3/h for 4-8 hours. The resulting material is transferred to another sealed container and stirred while coupling agent is added. Stirring continues until the material drops below 60° C., the material then being transferred into organic solvent for washing for 30-50 minutes. Thereafter the material is first filter pressed, then subjected to low temperature drying, and then sieved to obtain the final product.
    Type: Application
    Filed: February 15, 2012
    Publication date: August 16, 2012
    Applicant: Presafer (Qingyuan) Phosphor Chemical Company Limited
    Inventors: Sizheng Xie, Ken Zhou
  • Patent number: 8197781
    Abstract: A method of forming a lithium orthophosphate sputter target or tile and resulting target material is presented. The target is fabricated from a pure lithium orthophosphate powder refined to a fine powder grain size. After steps of consolidation into a ceramic body, packaging and degassing, the ceramic body is densified to high density, and transformed into a stable single phase of pure lithium orthophosphate under sealed atmosphere. The lithium orthophosphate target is comprised of a single phase, and can preferably have a phase purity greater than 95% and a density of greater than 95%.
    Type: Grant
    Filed: November 5, 2007
    Date of Patent: June 12, 2012
    Assignee: Infinite Power Solutions, Inc.
    Inventors: Bernd J. Neudecker, Vassiliki Milonopoulou
  • Publication number: 20120108716
    Abstract: A flame retardant agent for a thermoplastic resin, which enables the thermoplastic resin containing the flame retardant agent to keep its viscous property, to be made into a fiber readily, and to exhibit flame retardant effect even when ammonium dihydrogen phosphate is contained in the flame retardant agent as a non-halogen flame retardant component. Also disclosed is a flame retardant resin composition containing the flame retardant agent. Specifically, the flame retardant agent for a thermoplastic resin comprises ammonium dihydrogen phosphate, potassium hydroxide, glycerin and urea, wherein the potassium hydroxide is contained in an amount of 10 to 70 parts by weight, glycerin is contained in an amount of 0.1 to 4.0 parts by weight, and urea is contained in an amount of 1 to 9 parts by weight relative to 100 parts by weight of ammonium dihydrogen phosphate.
    Type: Application
    Filed: January 12, 2012
    Publication date: May 3, 2012
    Inventors: Keisuke Morikawa, Shoji Ichii
  • Patent number: 8152891
    Abstract: The invention provides a method for the combined production of (I) a sulfur oxide containing product and (II) a fertilizer selected from a group consisting of ammonium nitrate, ammonium phosphates and a combination thereof, through an indirect neutralization of ammonia with an acid selected from the group consisting of nitric acid, phosphoric acid and a combination thereof, the method comprising: a. contacting a precipitate containing calcium sulfite with a solution of nitric acid and a solution of ammonia in two separate steps, to form the fertilizer, the sulfur oxide containing product and a precipitate containing calcium hydroxide; and b. separating at least portion of the fertilizer, the sulfur oxide and the calcium hydroxide into three separated streams.
    Type: Grant
    Filed: November 28, 2006
    Date of Patent: April 10, 2012
    Assignee: Clue AS
    Inventor: Riki Canari
  • Patent number: 8053075
    Abstract: The invention relates to a crystalline ion-conducting material made of LiMPO4 nanoparticles, wherein M is selected from Cr, Mn, Co, Fe and Ni, in addition to mixtures thereof and the nanoparticles have an essentially flat prismatic shape. The invention also relates to a method for producing said type of crystalline ion-conducting material which consists of the following steps: a precursor component is produced in a solution front a lithium compound of a component containing metal ions M and a phosphate compound, the precursor compound is subsequently precipitated from the solution and, optionally, a suspension of the precursor compound is formed, the precursor compound and/or the suspension is dispersed and/or ground, and the precursor compound and/or the suspension is converted under hydrothermal conditions and subsequently, the crystalline material is extracted.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: November 8, 2011
    Assignee: Sued-Chemie AG
    Inventors: Norbert Schall, Gerhard Nuspl, Christian Vogler, Lucia Wimmer, Max Eisgruber
  • Patent number: 8012631
    Abstract: A solid electrolyte including a lithium (Li) element, a phosphorus (P) element and a sulfur (S) element, the 31P MAS NMR spectrum thereof having a peak ascribed to a crystal at 90.9±0.4 ppm and 86.5±0.4 ppm; and the ratio (xc) of the crystal in the solid electrolyte being from 60 mol % to 100 mol %.
    Type: Grant
    Filed: November 28, 2006
    Date of Patent: September 6, 2011
    Assignee: Idemitsu Kosan Co., Ltd
    Inventors: Yoshikatsu Seino, Masaru Nakagawa, Minoru Senga, Masatoshi Shibata
  • Publication number: 20100196500
    Abstract: The present invention provides anhydrous dicalcium phosphate particles which satisfies the conflicting requirements of the improvement of handling properties such as high flowability and a small bulk and the improvement of tableting properties at the same time during preparation and a method of producing the same. The method of producing anhydrous dicalcium phosphate by heating water suspensions of a phosphoric acid compound and a calcium compound at 50 to 100° C., comprises the step of: heating the phosphoric acid compound and the calcium compound at 75° C. or higher in advance to carry out a neutralization reaction in the presence of an alkali to obtain agglomerated anhydrous dicalcium phosphate particles.
    Type: Application
    Filed: September 18, 2008
    Publication date: August 5, 2010
    Inventor: Kazuo Kitakado
  • Patent number: 7759006
    Abstract: Disclosed is a compound represented by the following formula 1. A lithium secondary battery using the same compound as electrode active material, preferably as cathode active material, is also disclosed. LiMP1-xAxO4??[Formula 1] wherein M is a transition metal, A is an element having an oxidation number of +4 or less and 0<x<1. The electrode active material comprising a compound represented by the formula of LiMP1-xAxO4 shows excellent conductivity and charge/discharge capacity compared to LiMPO4.
    Type: Grant
    Filed: July 14, 2005
    Date of Patent: July 20, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Sung Kyun Chang, Jeong Ju Cho
  • Patent number: 7722848
    Abstract: Lithium iron phosphate cathode materials for lithium secondary batteries and methods of preparation thereof are disclosed. Better cathode materials may be produced by multiple annealing and/or heating steps. The annealing step can be carried out before and/or after the heating steps to provide cathode materials, which exhibit superior electrical properties. In some instances, divalent iron compounds are incorporated as starting materials.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: May 25, 2010
    Assignee: BYD Company Limited
    Inventors: Quan Dai, Julin Shen
  • Publication number: 20100056362
    Abstract: A substrate, such as a glass, glass ceramic, ceramic or metal substrate, is provided with a thermocatalytically active coating on at least a part of the substrate surface. The thermocatalytic coating contains an inorganic lithium salt or organic lithium-containing compound in an amount that is equivalent to not less than 2 wt. % of lithium ions, based on total coating weight. The thermocatalytic coating has a glass, glass solder or sol-gel matrix in which the lithium salt or organic lithium-containing compound is introduced. Optional barrier and IR-reflecting layers are arranged between the substrate surface and the thermocatalytically active coating.
    Type: Application
    Filed: August 21, 2009
    Publication date: March 4, 2010
    Inventors: Inka Henze, Hrabanus Hack, Gerhard Weber, Hans-Joachim Schmitt, Wolfgang Schmidbauer, Torsten Gabelmann
  • Patent number: 7588744
    Abstract: A method for removing and recovering phosphorus from a spent adsorbent medium to result in a regenerated medium and a phosphorus-containing solution useful as a fertilizer.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: September 15, 2009
    Assignee: Layne Christensen Company
    Inventor: Paul Sylvester
  • Publication number: 20080274030
    Abstract: The present invention provides compositions and a novel high-yielding process for preparing high purity Group III nitrides. The process involves heating a Group III metal and a catalytic amount of a metal wetting agent in the presence of a nitrogen source. Group III metals can be stoichiometrically converted into high purity Group III nitride powders in a short period of time. The process can provide multi-gram quantities of high purity Group III nitrides in relatively short reaction times. Detailed characterizations of GaN powder were performed and are reported herein, including morphology and structure by SEM and XRD, optical properties by cathodoluminescence (CL), and Raman spectra to determine the quality of the GaN particles. The purity of GaN powder was found to be greater than 99.9% pure, as analyzed by Glow Discharge Mass Spectrometry (GDMS). Green, yellow, and red light emission can be obtained from doped GaN powders.
    Type: Application
    Filed: April 1, 2008
    Publication date: November 6, 2008
    Inventors: Michael G. Spencer, Francis J. DiSalvo, Huaqiang Wu
  • Patent number: 7442365
    Abstract: A process for preparing beads of various compositions has been developed. The process involves preparing a reaction mixture of sources of framework elements of a molecular sieve. The reaction mixture can optionally contain molecular sieve seeds. Additional sources of the framework elements are added to give a concentration above the critical supersaturation limit thereby forming beads. Depending on the composition of the reaction mixture and the reaction conditions one can obtain beads which are substantially amorphous, to beads that are substantially crystalline molecular sieve. These beads in turn can be further processed to deposit a molecular sieve layer onto the beads.
    Type: Grant
    Filed: June 14, 2004
    Date of Patent: October 28, 2008
    Assignee: UOP LLC
    Inventors: Lance L. Jacobsen, Brian S. Konrad, David A. Lesch, Beckay J. Mezza, James G. Vassilakis, Cynthia R. Berinti-Vondrasek
  • Patent number: 7416803
    Abstract: Improved solid acid electrolyte materials, methods of synthesizing such materials, and electrochemical devices incorporating such materials are provided. The stable electrolyte material comprises a solid acid capable undergoing rotational disorder of oxyanion groups and capable of extended operation at elevated temperatures, that is, solid acids having hydrogen bonded anion groups; a superprotonic, trigonal, tetragonal, or cubic, disordered phase; and capable of being operating at temperatures of ˜100° C. and higher.
    Type: Grant
    Filed: August 1, 2002
    Date of Patent: August 26, 2008
    Assignee: California Institute of Technology
    Inventors: Sossina M. Haile, Calum Chisholm, Ryan B. Merle, Dane A. Boysen, Sekharipuram R. Narayanan
  • Publication number: 20080176175
    Abstract: The present invention relates to a flame reaction material, particularly a gas combustion flame reaction material for gas combustion appliances and a flame reaction member thereof. The gas combustion flame reaction material is formed by a single alkali metal or alkaline earth metal compound, and said alkali metal or alkaline earth metal compound has a melting point lower than combustion temperature of combustible gases and produces a crystal after high-temperature combustion. The flame reaction member comprises a substrate and a flame reaction material adhered to the surface of the substrate in the form of crystal. The substrate is a metal conductor. Because the gas combustion flame reaction material is formed by a single alkali metal or alkaline earth metal compound, the proportion of it to other materials is not required to consider when fabricated and thus it is convenient to produce.
    Type: Application
    Filed: November 27, 2007
    Publication date: July 24, 2008
    Applicant: Ningbo Xinhai Electric Co., Ltd.
    Inventor: Da Zheng
  • Patent number: 7374740
    Abstract: Phosphate rock is reacted with phosphoric acid to produce monobasic calcium phosphate. Monobasic calcium phosphate is reacted with ammonium carbonate to produce ammonium phosphate. Dibasic calcium phosphate is also produced as a by-product when monobasic calcium phosphate reacting with ammonium carbonate. The dibasic calcium phosphate is reacted with sulfuric acid to produce phosphoric acid. The phosphoric acid is used to react with phosphate rock. Ammonium sulfate or ammonium hydroxide may be used instead of ammonium carbonate. Phosphate other than ammonium phosphate can be produced if calcium phosphate is reacted with x-y to produce x-phosphate, where x is lithium, sodium, ammonium or potassium and y is carbonate, bicarbonate hydroxide or sulfate.
    Type: Grant
    Filed: March 31, 2005
    Date of Patent: May 20, 2008
    Assignee: Cargill, Incorporated
    Inventors: Xiangsheng Meng, Paris Tsobanakis, Alan Peacock, Don Clark, Colin Weyrauch
  • Patent number: 7169728
    Abstract: A condensed phosphate containing an alkaline earth metal is caused to be present on the surface of titanium dioxide fine particles, and as a result, the condensed phosphate is firmly coupled with the fine particles and is barely liberated from the surface of the fine particles into a medium such as a binder or a resin. As a result, photo-functional particles exhibiting durability and dispersion stability are obtained. By use of the photo-functional particles, a powder and a slurry exhibiting excellent photo-functional property, durability, dispersion stability, and hydrophilicity are produced. In addition, by use of the powder and slurry, a polymer composition, a coating agent, a photo-functional formed article, and a photo-functional structure are produced.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: January 30, 2007
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masayuki Sanbayashi, Hiroyuki Hagihara, Jun Tanaka, Yoshinori Ueyoshi
  • Patent number: 7078068
    Abstract: Methods for coagulating collagen and producing a food product by contacting the collagen with a solution comprising at least about 40% by weight of a phosphate salt mixture wherein the phosphate salt mixture is comprised of at least two phosphate salts selected from the group consisting of monosodium phosphate, disodium phosphate, trisodium phosphate, monopotassium phosphate, dipotassium phosphate, and tripotassium phosphate.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: July 18, 2006
    Assignee: Astaris L.L.C.
    Inventor: Sharon L. Book
  • Patent number: 7060643
    Abstract: A condensed phosphate containing an alkaline earth metal is caused to be present on the surface of titanium dioxide fine particles, and as a result, the condensed phosphate is firmly coupled with the fine particles and is barely liberated from the surface of the fine particles into a medium such as a binder or a resin. As a result, photo-functional particles exhibiting durability and dispersion stability are obtained. By use of the photo-functional particles, a powder and a slurry exhibiting excellent photo-functional property, durability, dispersion stability, and hydrophilicity are produced. In addition, by use of the powder and slurry, a polymer composition, a coating agent, a photo-functional formed article, and a photo-functional structure are produced.
    Type: Grant
    Filed: December 28, 2001
    Date of Patent: June 13, 2006
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masayuki Sanbayashi, Hiroyuki Hagihara, Jun Tanaka, Yoshinori Ueyoshi
  • Patent number: 7060206
    Abstract: Active materials of the invention contain at least one alkali metal and at least one other metal capable of being oxidized to a higher oxidation state. Preferred other metals are accordingly selected from the group consisting of transition metals (defined as Groups 4–11 of the periodic table), as well as certain other non-transition metals such as tin, bismuth, and lead. The active materials may be synthesized in single step reactions or in multi-step reactions. In at least one of the steps of the synthesis reaction, reducing carbon is used as a starting material. In one aspect, the reducing carbon is provided by elemental carbon, preferably in particulate form such as graphites, amorphous carbon, carbon blacks and the like. In another aspect, reducing carbon may also be provided by an organic precursor material, or by a mixture of elemental carbon and organic precursor material.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: June 13, 2006
    Assignee: Valence Technology, Inc.
    Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey Swoyer, Ming Dong
  • Patent number: 7008566
    Abstract: The invention provides an electrochemical cell which includes a first electrode and a second electrode which is a counter electrode to said first electrode, and an electrolyte material interposed there between. The first electrode includes an active material having an alkali metal-containing oligo phosphate-based electrode active material.
    Type: Grant
    Filed: April 8, 2003
    Date of Patent: March 7, 2006
    Assignee: Valence Technology, Inc.
    Inventors: Jeremy Barker, M. Yazid Saidi
  • Patent number: 6949236
    Abstract: Addition of an aminosulfonate product to an inorganic nitrogen-containing salt provides a composition of matter with improved properties. In particular, 2-acrylamido-2-methylpropanesulfonic acid and its derivatives can be added to ammonium nitrate to provide improved prills.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: September 27, 2005
    Assignee: The Lubrizol Corporation
    Inventors: Kastrui Lal, Alvin E. Haas, Ricardo M. Collins, Jeffrey M. Carey
  • Patent number: 6893494
    Abstract: The invention provides a stable metal zirconium phosphates having formula (I), in which X is a metal or a combination of metals selected from Co, Mn, Ni, Cu, Cd, Fe, Cr, Al, Sn, V, Zn, Sc, Na, Mg, Ca and Si; and n has a molar value in the range of 1.25 to 22. These metal zirconium phosphates are prepared by sol-gel process.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: May 17, 2005
    Assignee: Carborundum Universal Limited
    Inventor: Ravichandran Joghee
  • Patent number: 6890647
    Abstract: Highly transparent alumina hydrate particles having a large pore volume, having a pore diameter which falls in a specified range and, when formed into a high-concentration dispersion sol, exhibiting a low viscosity are provided. Alumina hydrate particles having a composition represented by the general formula xM2O.y(NH4)2O.Al2O3.zH2O (2×10?4?x?25×10?4, 0.1×10?4?y?20×10?4, 0.6?z?2.5, M represents an alkali metal; when the alkali metal is in the form of M2O, x is the number of moles thereof per mol of Al2O3; when ammonia is in the form of (NH4)2O, y is the number of moles thereof per mol of Al2O3; and z is the number of moles of hydration water (H2O) per mol of Al2O3), the alumina hydrate particles having an average particle diameter of 0.02 to 0.2 ?m, a total pore volume of 0.5 to 1.5 ml/g, and a volume of pores whose diameter is from 15 to 30 nm ranging from 0.3 to 1.0 ml/g.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: May 10, 2005
    Assignee: Catalysts & Chemicals Industries Co., Ltd.
    Inventors: Hiroyasu Nishida, Naoyuki Enomoto, Michio Komatsu
  • Patent number: 6855462
    Abstract: The invention provides new and novel lithium-metal-fluorophosphates which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-metal-fluorophosphates. The lithium-metal-fluorophosphates comprise lithium and at least one other metal besides lithium.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: February 15, 2005
    Assignee: Valence Technology, Inc.
    Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey Swoyer
  • Patent number: 6846493
    Abstract: The present invention is directed to a synthetic biomaterial compound based on stabilized calcium phosphates and more particularly to the molecular, structural and physical characterization of this compound. The compound comprises calcium, oxygen and phosphorous, wherein at least one of the elements is substituted with an element having an ionic radius of approximately 0.1 to 1.1 ?. The knowledge of the specific molecular and chemical properties of the compound allows for the development of several uses of the compound in various bone-related clinical conditions.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: January 25, 2005
    Assignee: Millenium Biologix Inc.
    Inventors: Sydney M. Pugh, Timothy J. N. Smith, Michael Sayer, Sarah Dorthea Langstaff
  • Patent number: 6818356
    Abstract: A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing a sulfide ion dopant wherein the atomic ratio of sulfide ion to phosphorus ion (S/P) in the electrolyte ranges greater than 0 up to about 0.2. The composition is represented by the formula: LiwPOxNySz, where 2x+3y+2z=5+w, x ranges from about 3.2 to about 3.8, y ranges from about 0.13 to about 0.46, z ranges from greater than zero up to about 0.2, and w ranges from about 2.9 to about 3.3. Thin-film batteries containing the sulfide doped lithium oxynitride electrolyte are capable of delivering more power and energy than thin-film batteries containing electrolytes without sulfide doping.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: November 16, 2004
    Assignee: Oak Ridge Micro-Energy, Inc.
    Inventor: John B Bates
  • Patent number: 6702961
    Abstract: The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.
    Type: Grant
    Filed: June 13, 2003
    Date of Patent: March 9, 2004
    Assignee: Valence Technology, Inc.
    Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey Swoyer
  • Patent number: 6585992
    Abstract: The present invention is directed to a synthetic biomaterial compound based on stabilized calcium phosphates and more particularly to the molecular, structural and physical characterization of this compound. The compound comprises calcium, oxygen and phosphorous, wherein at least one of the elements is substituted with an element having an ionic radius of approximately 0.1 to 1.1 Å. The knowledge of the specific molecular and chemical properties of the compound allows for the development of several uses of the compound in various bone-related clinical conditions.
    Type: Grant
    Filed: October 4, 2001
    Date of Patent: July 1, 2003
    Assignee: Millenium Biologix, Inc.
    Inventors: Sydney M. Pugh, Timothy J. N. Smith, Michael Sayer, Sarah Dorthea Langstaff
  • Patent number: 6372451
    Abstract: A novel aurophosphate stain for staining a slide-mounted brain tissue slice or section to label myelin therein, the method of staining, and the method of making the stain. The stain is potassium aurophosphate or sodium aurophosphate produced as the reaction product of an aurochloride and a dibasic potassium or sodium phosphate. Slide-mounted brain tissue slices are stained by immersing the slice in a warn solution of the aurophosphate. The stained slice may be intensified by immersing the slide-mounted stained tissue slice in a potassium tetrachloroaureate solution. The stained or intensified slice can be fixed by immersion in a sodium thiosulfate solution. Large bundles of stained myelin appear deep red-brown, while smaller bundles and individual fibers appear black.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: April 16, 2002
    Inventor: Laurence C. Schmued
  • Patent number: 6323146
    Abstract: The present invention is directed to a synthetic biomaterial compound based on stabilized calcium phosphates and more particularly to the molecular, structural and physical characterization of this compound. The compound comprises calcium, oxygen and phosphorous, wherein at least one of the elements is substituted with an element having an ionic radius of approximately 0.1 to 1.1 Å. The knowledge of the specific molecular and chemical properties of the compound allows for the development of several uses of the compound in various bone-related clinical conditions.
    Type: Grant
    Filed: March 19, 1998
    Date of Patent: November 27, 2001
    Assignee: Millenium Biologix, Inc.
    Inventors: Sydney M. Pugh, Timothy J. N. Smith, Michael Sayer, Sarah Dorthea Langstaff
  • Patent number: 6274105
    Abstract: The present invention relates to a new selective process for producing high-purity potassium nitrate or potassium phosphate. The process uses a liquid agricultural or fermentation by-product, such as molasses, vinasse or potato thick juice as its potassium source and comprises the following unit operations: clarification, ion exchange, neutralization, concentration and crystallization. Importantly, the present invention also concerns a process for producing an ingredient for animal feed, said ingredient having a reduced potassium content.
    Type: Grant
    Filed: December 4, 1998
    Date of Patent: August 14, 2001
    Assignees: Avebe B.A., Kemira Agro Oy
    Inventors: Marcus Vorage, Per Eichner
  • Patent number: 6183712
    Abstract: A method of producing dicalcium phosphate from calcium phosphate includes reacting the calcium phosphate with a mineral acid such as sulphuric acid to produce a calcium salt and phosphoric acid. The calcium salt may then be hydrolyzed to form a calcium alkali which may then be reacted with the phosphoric acid to produce dicalcium phosphate. Also, a method of producing monocalcium phosphate from calcium phosphate includes reacting the calcium phosphate with sulphuric acid to produce monocalcium phosphate. The monocalcium phosphate may be further processed to remove fluorine contamination and to produce fluorine-free dicalcium phosphate or dicalcium phosphate dihydrate.
    Type: Grant
    Filed: August 25, 1999
    Date of Patent: February 6, 2001
    Inventor: Jan C. De Waal
  • Patent number: RE41251
    Abstract: The present invention is directed to a synthetic biomaterial compound based on stabilized calcium phosphates and more particularly to the molecular, structural and physical characterization of this compound. The compound comprises calcium, oxygen and phosphorous, wherein at least one of the elements is substituted with an element having an ionic radius of approximately 0.1 to 1.1 ?. The knowledge of the specific molecular and chemical properties of the compound allows for the development of several uses of the compound in various bone-related clinical conditions.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: April 20, 2010
    Inventors: Sydney M. Pugh, Timothy J. N. Smith, Michael Sayer, Sarah D. Langstaff