Abstract: The present disclosure relates to methods by which lead from spent lead-acid batteries may be extracted, purified, and used in the construction of new lead-acid batteries. A method includes: (A) forming a mixture including a carboxylate source and a lead-bearing material; (B) generating a first lead salt precipitate in the mixture as the carboxylate source reacts with the lead-bearing material; (C) increasing the pH of the mixture to dissolve the first lead salt precipitate; (D) isolating a liquid component of the mixture from one or more insoluble components of the mixture; (E) decreasing the pH of the liquid component of the mixture to generate a second lead salt precipitate; and (F) isolating the second lead salt precipitate from the liquid component of the mixture. Thereafter, the isolated lead salt precipitate may be converted to leady oxide for use in the manufacture of new lead-acid batteries.

Abstract: The invention relates to a method for separating chlorine from a gaseous anode outlet stream mass flow of an electrochemical cell reactor. In a first aspect, the method makes use of an absorption step, wherein an anode outlet stream mass flow of the electrochemical cell reactor is exposed to an organic solvent being essentially immiscible with water for achieving an exergy-efficient separation of chlorine and hydrogen chloride. In a further aspect, the method makes use of absorption step, wherein the anode outlet stream mass flow is exposed to an ionic liquid, wherein the hydrogen chloride is dissolved in said ionic liquid, thereby forming a gas flow containing essentially chlorine and a solution mass flow comprising the ionic liquid and the hydrogen chloride. The hydrogen chloride is desorbed from the solution mass flow in a desorption step.

Abstract: A substrate processing apparatus includes: a process container configured to receive a substrate therein; a pressure detection part configured to measure an internal pressure of the process container; an exhaust-side valve installed in an exhaust pipe configured to exhaust an interior of the process container; a gas storage tank connected to the process container through a first gas supply pipe; a gas amount measuring part configured to measure an amount of gas stored in the gas storage tank; and a control valve installed in the first gas supply pipe and configured to control the internal pressure of the process container by changing an opening degree of the control valve based on the internal pressure of the process container which is detected by the pressure detection part and by controlling a flow path cross section through which the gas is supplied from the gas storage tank to the process container.

Abstract: A method of modeling phase characteristics of thermodynamic systems utilizing pseudo-properties strategy and a reduced number of variables is disclosed herein. The method describes a means of determining the probability of phase splitting of mixtures of materials at a given temperature, pressure, and composition by characterizing the functions that describe the system via pseudo-properties, and also by describing the system in n?1 or fewer variables, where n represents the number of components in the system of interest. In an embodiment, a multi-component system is characterized in one variable, thereby providing simplified thermodynamic models in a time-efficient manner. In addition, the information generated by this reduced-variable calculation can further be used as a starting point for calculations of equations of state.

Abstract: The present invention discloses a method for thermochemical production of hydrogen and oxygen from water by a low temperature, multi-step, closed, cyclic copper-chlorine (Cu—Cl) process involving the reactions of copper and chlorine compounds. A method for production of hydrogen via Cu—Cl thermochemical cycle consists of four thermal reactions and one electrochemical reaction and one unit operation. The cycle involves six steps: (1) hydrogen production step; (2) copper production step; (3) drying step; (4) hydrogen chloride production step; (5) decomposition step; (6) oxygen production step. The net reaction of the sequential process is the decomposition of water into hydrogen and oxygen. The methods for production of copper oxide which comprises contacting copper chloride particles with superheated steam and production of oxygen comprises reaction of copper oxide with dry chlorine as a part of hydrogen production by thermochemical Copper-Chlorine (Cu—Cl) cycle.

Abstract: Method and apparatus for producing molten purified crystalline silicon from low-grade siliceous fluorspar ore, sulfur trioxide gas, and a metallic iodide salt. Method involves: (1) initially reacting silicon dioxide-bearing fluorspar ore and sulfur trioxide gas in sulfuric acid to create silicon tetrafluoride gas and fluorogypsum; (2) reacting the product gas with a heated iodide salt to form a fluoride salt and silicon tetraiodide; (3) isolating silicon tetraiodide from impurities and purifying it by washing steps and distillation in a series of distillation columns; (4) heating the silicon tetraiodide to its decomposition temperature in a silicon crystal casting machine, producing pure molten silicon metal ready for crystallization; and pure iodine gas, extracted as liquid in a cold-wall chamber. The system is batch process-based, with continuous elements. The system operates largely at atmospheric pressure, requiring limited inert gas purges during batch changes.

Abstract: Elemental fluorine is used as etching agent for the manufacture of electronic devices, especially semiconductor devices, micro-electromechanical devices, thin film transistors, flat panel displays and solar panels, and as chamber cleaning agent mainly for plasma-enhanced vapor deposition (PECVD) apparatus. For this purpose, fluorine often is produced on-site. The invention provides a process wherein the contamination of the elemental fluorine with gaseous impurities, such as air or moisture, is prevented by producing it on site and delivering it to the point of use under a pressure higher than ambient pressure.

Abstract: Elemental fluorine is often manufactured electrochemically from a solution of KF in hydrogen fluoride and contains varying amounts of entrained electrolyte salt in solid form as impurity. The invention concerns a process for the purification of such impure elemental fluorine by contact with liquid hydrogen fluoride, e.g., in a jet gas scrubber or by bubbling the raw fluorine through liquid hydrogen fluoride. After this purification step, any entrained hydrogen fluoride is removed by adsorption, condensing it out or both. After passing through a filter with very small pores, the purified fluorine is especially suited for the semiconductor industry as etching gas or as chamber cleaning gas in the manufacture of semiconductors, TFTs and solar cells, or for the manufacture of micro-electromechanical systems (“MEMS”).

Abstract: Methods and products are provided for treating a wound or infection in a mammal or disinfecting a surface with a hypochlorous acid solution that has been activated by a catalyst. Additionally provided is a process for preparing an antimicrobial product that produces an activated hypochlorous acid solution for use as an antimicrobial.

Abstract: Processes and systems that include use of a packed wet oxidation reactor for oxidizing aqueous metal bromide salts in a bromine-based process for converting lower molecular weight alkanes to higher molecular weight hydrocarbons. A stream comprising a dissolved metal bromide salt may be oxidized in a wet oxidation reactor comprising a packed section to produce at least a partially oxidized liquid stream comprising oxidized products of the metal bromide salt and a gaseous bromine stream comprising elemental bromine.

Abstract: There is provided a process for recovering high purity litharge PbO from spent lead acid battery paste at low temperatures and the further preparation of highly pure lead oxides and Pb(OH)2.

Abstract: Systems and methods for controlling the temperature of items such as a sample in a vessel or a specimen, in a thermal bath using thermally efficient pellets as the thermal media. The pellets are typically oblong metallic or oblong metallic-coated pellets with rounded edges, a hardened surface, a smooth polished finish, and characteristics that enable efficient thermal communication between the bath's thermal source, the pellets, and the items that are inserted into the mass of pellets. Further, the pellets are dry and moisture and gas impermeable, and they resist microbial growth and are readily decontaminated by several methods including applying an antimicrobial compound to the pellets. The thermal source is controlled to achieve the desired temperature of the items inserted into the pellets.

Abstract: For the plasma assisted manufacture of semiconductors, photovoltaic cells, thin film transistor liquid crystal displays and micro-electromechanical systems, and for chamber cleaning, F2 or COF2 is applied as etchant. It was found that a plasma emitter providing microwaves with a frequency of equal to or greater than 15 MHz provides plasma very effectively.

Abstract: A polyvinylidene fluoride (PVDF) pyrolyzate adsorbent is described, having utility for storing gases in an adsorbed state, and from which adsorbed gas may be desorbed to supply same for use. The PVDF pyrolyzate adsorbent can be of monolithic unitary form, or in a bead, powder, film, particulate or other finely divided form. The adsorbent is particularly suited for storage and supply of fluorine-containing gases, such as fluorine gas, nitrogen trifluoride, carbo-fluoride gases, and the like. The adsorbent may be utilized in a gas storage and dispensing system, in which the adsorbent is contained in a supply vessel, from which sorbate gas can be selectively dispensed.

Abstract: A process for converting gaseous alkanes to olefins, higher molecular weight hydrocarbons or mixtures thereof wherein a gaseous feed containing alkanes may be thermally or catalytically reacted with a dry bromine vapor to form alkyl bromides and hydrogen bromide. Poly-brominated alkanes present in the alkyl bromides may be further reacted with methane over a suitable catalyst to form mono-brominated species. The mixture of alkyl bromides and hydrogen bromide may then be reacted over a suitable catalyst at a temperature sufficient to form olefins, higher molecular weight hydrocarbons or mixtures thereof and hydrogen bromide. Various methods and reactions are disclosed to remove the hydrogen bromide from the higher molecular weight hydrocarbons, to generate bromine from the hydrogen bromide for use in the process, to store and subsequently release bromine for use in the process, and to selectively form mono-brominated alkanes in the bromination step.

Abstract: A start-up method of a process for producing chlorine from hydrogen chloride has a mixed gas producing step of producing a mixed gas containing chlorine from hydrogen chloride, a compressed mixed gas producing step of introducing the mixed gas into an inlet of a compressor and compressing the mixed gas in compressor, a purifying step of introducing the compressed mixed gas into a purifying column and separating the compressed mixed gas into purified chlorine and impurities by distillation, and a recompressing step of introducing the purified chlorine into an inlet of the compressor and compressing the mixed gas and the purified chlorine.

Abstract: A process is described for the production of chlorine by a catalysed gas-phase oxidation of hydrogen chloride with an oxygen-containing gas stream.

Abstract: A process for preparing gaseous elemental bromine and transferring it to a site of its intended use, comprising feeding a bromide (Br—) source, an oxidant and an acid into a reaction vessel to form an acidic aqueous reaction mixture, oxidizing the bromide at a temperature in the range between 59 C and the boiling point of said reaction mixture, thereby forming elemental bromine in a gaseous state, passing a stream of air through the reaction vessel and transferring metered amounts of the resultant mixture of air and bromine vapors to said site of use. The invention also provides an apparatus for carrying out the process.

Abstract: Processes are provided for conjointly producing Br2, a concentrated aqueous solution containing CaCI2, and Cl2 from an aqueous HBr-rich stream and a feed brine dilute in CaCI2 that comprises NaCI. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 from a Cl2 source, at least a portion of which is produced according to this invention, to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution, producing Cl2 and caustics from residual chlorides such as NaCI, and using at least a portion of the thus produced Cl2 in the Cl2 source.

Abstract: Processes are provided for conjointly producing Br2 and a concentrated aqueous solution containing at least about 5 wt % CaCI2, based on the weight of the concentrated aqueous solution, from an aqueous HBr rich stream and, optionally, a feed brine dilute in CaCI2. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, and, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution.

Abstract: Processes are provided for conjointly producing Br2 and a concentrated aqueous solution containing at least about 5 wt % CaCI2, based on the weight of the concentrated aqueous solution, from an HBr-rich recycle stream and a feed brine dilute in CaCI2. wherein the aqueous HBr-rich stream is produced from an HBr-rich recycle stream and a portion of the feed brine.

Abstract: There is provided a fluorine storage material comprising a novel fluorinated carbon nanohorn, which stores a large amount of fluorine per its unit mass, withstand repeated use for fluorine storage, and enables a high purity fluorine gas to be taken out by a safe and efficient method, and also there is provided a method of taking out a fluorine gas by applying heat to the fluorine storage material or placing the fluorine storage material in a pressure-reduced atmosphere.

Abstract: A process for extracting fluorine from a fluoro-refractory coating includes the steps of providing an article having a fluoro-refractory coating; treating hydrothermally the fluoro-refractory coating at a temperature and for a period time sufficient to liberate a quantity of fluoride from the fluoro-refractory coating; and drying a hydrothermally treated article.

Abstract: To provide a good and simple method for decomposing and detoxifying a hardly decomposable fluorinated organic compound. Specifically, a fluorinated organic compound is decomposed by bringing an aqueous solution of the fluorinated organic compound into contact with a catalyst containing a metal oxide. The metal oxide may preferably be an oxide of at least one metal selected from the group consisting of Ni, Pd, Cu, Mn, Fe and Co, and more preferably be nickel oxide. The contact temperature is preferably within the range of from 0 to 100° C. Preferably, the fluorinated organic compound to be decomposed is an organic fluorocarboxylic acid, an organic fluorosulfonic acid or a salt thereof, which is used as a surfactant or an surface treatment agent.

Abstract: The present disclosure provides a process and a system for producing dichlorine (Cl2).

Abstract: A desalination and minerals extraction process includes a desalination facility fluidly coupled to a minerals extraction facility. The desalination facility includes a nanofiltration membrane section producing a first tailings stream and a reverse osmosis membrane section producing a second tailings stream and a desalinated water outlet stream from an inlet feed stream. The extraction facility produces at least one mineral compound, an extraction tailings stream, and a second desalinated water outlet stream. At least one of the first tailings stream and the second tailings stream is fed into the extraction facility. In certain exemplary embodiments, a natural gas combined cycle power unit supplies power to at least one of the desalination facility and the extraction facility. In certain exemplary embodiments, the extraction tailings stream is recycled into the desalination facility and there are no extraction tailings streams or desalination tailings streams discharged into the environment.

Abstract: Ceramic materials that are highly resistant to strong acids such as concentrated sulfuric acid and halides such as hydrogen iodide are employed to make block elements through which a large number of circular ingress channels extend in perpendicular directions and which are joined and piled in the heat exchanging medium section to provide a compact heat exchanger that excels not only in corrosion resistance but also in high-temperature strength.

Abstract: Manganese tetrafluoride is prepared by a reaction between manganese difluoride or manganese trifluoride particles and elemental fluorine. During the reaction, surfaces of the particles are rendered fresh, e.g. by mechanical impact on the particles. Thereby, also agglomeration, sintering or vitrification of the particles is prevented. The impact is not so intensive that the particles would be crushed.

Abstract: An in-line mixing apparatus is especially useful for iodine extraction from brine. Three fluids (brine, an oxidant such as sodium hypochlorite, and an acid such as HCl) are mixed in the apparatus. The apparatus includes an inner tube and an outer tube. Openings are present in the sidewall of the inner tube to connect the interior volume of the inner tube with the annular volume between the inner tube and the outer tube. Fluid is passed into the inner tube and flows through the openings into the annular volume, causing immediate and vigorous mixing and chemical reaction to obtain elemental iodine.

Abstract: The present invention provides processes and equipments for safely and easily preparing an F2-containing gas, as well as processes and equipments for surface modification using the F2-containing gas prepared. According to the present invention, a gas containing a fluoro compound that is easier to handle than F2 is supplied and the fluoro compound is excited and decomposed to convert it into F2 gas before surface modification and then used for surface modification. According to the present invention, there is no necessity of providing, storing and transporting a large amount of F2 gas in advance because a necessary amount of F2 gas is obtained immediately before surface modification.

Abstract: Fluorine extraction systems and associated processes are described herein. In one embodiment, a fluorine extraction process can include loading a mixture containing a uranium fluoride (UxFy, where x and y are integers) and an oxidizing agent into a reaction vessel. The reaction vessel has a closed bottom section and an opening spaced apart from the bottom section. The fluorine extraction process can also include heating the mixture containing uranium fluoride and the oxidizing agent in the reaction vessel, forming at least one uranium dioxide and a non-radioactive gas product from the heated mixture, and controlling a depth of the mixture in the reaction vessel to achieve a desired reaction yield of the non-radioactive gas product.

Abstract: The invention relates to a method for recovering gold in connection with the hydrometallurgical production of copper from a waste or intermediate product containing sulphur and iron that is generated in the leaching of the copper raw material. The recovery of both copper and gold occurs in a chloride environment. The gold contained in the waste or intermediate is leached by means of divalent copper, oxygen and alkali bromide in a solution of copper (II) chloride and alkali chloride, in conditions where the oxygen-reduction potential is a maximum of 650 mV and the pH a minimum of 0.5. The bromide accelerates the dissolution of the gold.

Abstract: A method of fractionating biomass, by permeability conditioning biomass suspended in a pH adjusted solution of at least one water-based polar solvent to form a conditioned biomass, intimately contacting the pH adjusted solution with at least one non-polar solvent, partitioning to obtain an non-polar solvent solution and a polar biomass solution, and recovering cell and cell derived products from the non-polar solvent solution and polar biomass solution. Products recovered from the above method. A method of operating a renewable and sustainable plant for growing and processing algae.

Abstract: A hydrogen iodide manufacturing method which includes a step of producing aqueous solution of hydrogen iodide and sulfuric acid by causing iodine-containing aqueous solution and sulfur dioxide to react with each other in a pressurized condition. The pressurized condition may be of not lower than 0.1 MPa in gauge pressure. The method may further include: a separation step of adding iodine to the aqueous solution of hydrogen iodide and separating an upper phase containing sulfuric acid relatively to a large extent and a lower phase containing hydrogen iodide relatively to a large extent; and a step of producing hydrogen iodide by adding sulfur dioxide to the upper phase in a pressurized condition and extracting the produced hydrogen iodide to the lower phase.

Abstract: The present invention relates to a method for separation and recycling of pure sulfur dioxide from a gaseous mixture in the IS cycle. More specifically, the present invention relates to a method for separation and recycling of pure sulfur dioxide from a gaseous mixture in the IS cycle using an ionic liquid under a specific condition. When compared with the conventional amine-based absorbent, the use of the ionic liquid enables continuous absorption and stripping of SO2 even at high temperature, and enables a reversible absorption of SO2 without loss, decomposition or degradation of a solvent due to good chemical stability, thereby enabling separation and recycling of pure SO2 from a gaseous mixture in the IS cycle.

Abstract: Methods are provided for producing bromine wherein an aqueous solution is formed from at least a bromide source, an oxidant, and a catalyst comprising a Group 1 cation and an oxide of a transition metal.

Abstract: Systems and methods for the recovery of iodine are described. In particular, recovery systems and methods produce an iodine complex from an aqueous brine containing iodide. A head tank for maintains a supply of the brine, a pH controller acidifies brine received from the head tank and an oxidizer converts iodide in the acidified brine to elemental iodine. At least one activated carbon contactor module is removably inserted into a stream of the oxidized brine provided by the oxidizer and binds the molecular iodine to form the iodine complex. A container may enclose the head tank, the pH controller and the oxidizer in order to facilitate transportation of the system and performance of the methods and processes in proximity to a brine source. The brine may be employed or associated with oilfield operations.

Abstract: Solid water treatment compositions are provided comprising (a) a halogen-containing source; (b) a boron-containing source; and (c) a polyphosphate-containing source. Methods for their use are also provided.

Abstract: This invention describes a system of reactions for a partial sequestration of carbon (CO2 and CO) from coal burning plants and zero emission production of hydrogen and hydrides. The only raw material to be used is salt (sodium chloride, NaCl), coal and water or a metal for the hydride. Sodium hydroxide (NaOH) generated from the chloride is used for locking carbon dioxide in sodium carbonate and bicarbonate.

Abstract: Nitrogen is fed into a sealed container (18) to expel oxygen (step 1) and, in such a state, the inside temperature of the container (18) is incrementally raised step by a heater built into the container (18). In sequential steps 2 through 5, Water content, chlorine, and high-molecular gases are extracted. Reusable carbon and metal remain in the container (18) in step 6, or when left standing for a prescribed time or more. Gases extracted in steps 2 to 5 can be liquefied for recycling. No carbon dioxide or dioxins are produced because heating is performed in an oxygen-free atmosphere. A furnace is not required because the heater is installed in the container (18), and treatment efficiency is high. A space-saving, energy-efficient, and low-cost treatment system, by which carbon (e.g., inert carbon), metals, and the like can be recovered in a reusable state without producing carbon dioxide or dioxins, is obtained.

Abstract: Methods for treating feline hyperthyroidism comprising (1) administering to a feline an antithyroid agent in conjunction with feeding the feline a composition comprising from about 0.1 to less than about 1 mg/kg iodine or (2) feeding the feline a composition comprising from about 0.1 to less than about 1 mg/kg selenium on a dry matter basis.

Abstract: A process for producing a fluorine gas of the invention comprises a step (1) of generating a fluorine gas by sectioning the interior of a fluorine gas generation container equipped with a heating means, by the use of a structure having gas permeability, then filling each section with a high-valence metal fluoride and heating the high-valence metal fluoride. The process may comprise a step (2) of allowing the high-valence metal fluoride, from which a fluorine gas has been generated in the step (1), to occlude a fluorine gas. According to the process of the invention, a high-purity fluorine gas that is employable as an etching gas or a cleaning gas in the process for manufacturing semiconductors or liquid crystals can be produced inexpensively on a mass scale.

Abstract: Disclosed is a process for producing manganese fluoride, comprising a step (1) of allowing a manganese compound such as MnF2 having been dried at a temperature of not lower than 100° C. to react with a fluorinating agent such as F2 at a temperature of 50 to 250° C. and a step (2) of further allowing a product obtained in the step (1) to react with a fluorinating agent at a temperature of 250 to 450° C. According to this process, manganese fluoride capable of generating a fluorine gas can be easily and inexpensively produced on a mass scale under the conditions of low temperature and low pressure without going through steps of sublimation and solidification.

Abstract: There is provided a fluorine storage material comprising a novel fluorinated carbon nanohorn, which stores a large amount of fluorine per its unit mass, withstand repeated use for fluorine storage, and enables a high purity fluorine gas to be taken out by a safe and efficient method, and also there is provided a method of taking out a fluorine gas by applying heat to the fluorine storage material or placing the fluorine storage material in a pressure-reduced atmosphere.

Abstract: A process for extracting fluorine from a fluoro-refractory coating includes the steps of providing an article having a fluoro-refractory coating; treating hydrothermally the fluoro-refractory coating at a temperature and for a period time sufficient to liberate a quantity of fluoride from the fluoro-refractory coating; and drying a hydrothermally treated article.

Abstract: The present invention provides processes and equipments for safely and easily preparing an F2-containing gas, as well as processes and equipments for surface modification using the F2-containing gas prepared. According to the present invention, a gas containing a fluoro compound that is easier to handle than F2 is supplied and the fluoro compound is excited and decomposed to convert it into F2 gas before surface modification and then used for surface modification. According to the present invention, there is no necessity of providing, storing and transporting a large amount of F2 gas in advance because a necessary amount of F2 gas is obtained immediately before surface modification.

Abstract: It is intended to provide methods of producing a chlorine gas having a small bromine content, an aqueous sodium hypochlorite solution having a small bromic acid content, and liquid chlorine having a small bromine content. More specifically, a chlorine gas is produced by a method comprising the steps of: (A) washing a chlorine gas that contains bromine, in a gas washing unit composed of a packed column or a tray tower, wherein the chlorine gas introduced via a lower part of the gas washing unit is brought into counterflow gas/liquid contact with a liquid chlorine introduced via an upper part of the gas washing unit; and (B) taking out a purified chlorine gas thus washed, via the upper part of the gas washing unit, wherein a weight ratio of the chlorine gas and the liquid chlorine introduced in the step (A) is 1/1.0 to 1/0.3.

Abstract: A method for circuit inspection comprises steps of providing a substrate having a conductive line; and forming a metal layer on at least the conductive layer to increase a contrast between the conductive layer and adjacent area for the circuit inspection. The method further comprising removing the metal layer. The metal layer is removed by a mixture of nitric acid, hydrogen peroxide and fluoride boric acid. The metal includes Silver, Nickel or Tin. The deposit metal can be removed by inter diffusion and form intermetallic compounds (for example Cu6Sn5) into the under laying conducting line.

Abstract: A process for producing a fluorine gas of the invention comprises a step (1) of generating a fluorine gas by sectioning the interior of a fluorine gas generation container equipped with a heating means, by the use of a structure having gas permeability, then filling each section with a high-valence metal fluoride and heating the high-valence metal fluoride. The process may comprise a step (2) of allowing the high-valence metal fluoride, from which a fluorine gas has been generated in the step (1), to occlude a fluorine gas. According to the process of the invention, a high-purity fluorine gas that is employable as an etching gas or a cleaning gas in the process for manufacturing semiconductors or liquid crystals can be produced inexpensively on a mass scale.

Abstract: A metal container to be filled with a halogen containing gas, with the inner surface processed with a polishing agent. The gas has a reduced purity decline by the increase of the water content or impurities from the inner surface of the container which is absorbed by the gas over the passage of time. The inner surface processing method is improved such that the value of dividing the area of the Si2s peak by the area of the Fe2p3/2 peak in the X-ray photoelectron spectrum of the gas container inner surface with the inner surface process with a polishing agent applied is 0.3 or less.