Abstract: A semiconductor nanocrystal particle including a transition metal chalcogenide represented by Chemical Formula 1, the semiconductor nanocrystal particle having a size of less than or equal to about 100 nanometers, and a method of producing the same: M1M2Cha3??Chemical Formula 1 wherein M1 is Ca, Sr, Ba, or a combination thereof, M2 is Ti, Zr, Hf, or a combination thereof, and Cha is S, Se, Te, or a combination thereof.

Abstract: Provided in one embodiment is a continuous process for converting waste plastic comprising polyethylene and/or polypropylene into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene, polypropylene, or a mixture thereof, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil comprising a naphtha, diesel and heavy fractions, and char. The pyrolysis oil, or at least a fraction, is passed to a filtration/metal oxide treatment, with the treated product passed to a refinery FCC unit. A liquid petroleum gas C3 olefin/paraffin mixture fraction is recovered from the FCC unit, as well as a C4 olefin/paraffin mixture fraction.

Abstract: A process for devulcanizing EPDM rubber comprising the step of introducing sulfur-cured EPDM to an extruder, introducing from about 0.5 to about 20 wt % scavenging agent, based upon the total weight of the EPDM and scavenging agent, and mixing and masticating the EPDM at a temperature sufficient to at least partially devulcanize the sulfur-cured EPDM.

Abstract: A solution for forming at least a portion of an active layer of an electronic or electro-optic device includes a solvent, an additive mixed with the solvent to provide a solvent-additive blend, and a solute that includes at least one of a transition metal, an alkali metal, an alkaline earth metal, Al, Ga, In, Ge, Sn, or Sb dissolved in elemental form in the solvent-additive blend. The additive is selected from the group of additives consisting of NR1R2NHCOOH, NH2N—HCONHNH2, NH2COOH.NH3, NH2NHC(?NH)NH2.H2CO3, NH2NHCSNHNH2, NH2NHCSSH and all combinations thereof. R1 and R2 are each independently selected from hydrogen, aryl, methyl, ethyl and a linear, branched or cyclic alkyl of 3-6 carbon atoms. Methods of producing the solution, a method of producing a Kesterite film on a substructure and devices made with the solutions and methods are also provided.

Abstract: An approach is provided for generating red mercury (II) sulfide from elemental mercury. Elemental mercury is combined with sulfur and heated until vaporized. At least a portion of the elemental mercury reacts with the vaporized sulfur to form the mercury (II) sulfide. Un-reacted elemental mercury is drawn off and condensed by a condenser.

Abstract: The present invention disclosed use of lactam as a solvent in the preparation of nanomaterials by precipitation method, sol-gel method or high temperature pyrolysis. These methods are able to recycle lactam solvent, which meet requirements of environmental protection.

Abstract: Described herein are multi-segmented nanowires, nanosheets and nanobelts, and devices and methods using them for the generation of multicolor and white light.

Abstract: Provided are methods for making quantum nanostructures based on use of a combination of nucleation and growth precursors. The methods can be used to provide quantum nanostructures of a selected size. Also provided are quantum nanostructures, compositions comprising the quantum nanostructures, and uses of the quantum nanostructures. The quantum nanostructures can be used, for example, in imaging applications.

Abstract: An approach is provided for generating red mercury (II) sulfide from elemental mercury. Elemental mercury is combined with sulfur and heated until vaporized. At least a portion of the elemental mercury reacts with the vaporized sulfur to form the mercury (II) sulfide. Un-reacted elemental mercury is drawn off and condensed by a condenser.

Abstract: A novel quantum dot capable of near infrared emissions at wavelengths of 750-1100 is made by forming solid solutions of metal sulfide, metal selenide or metal sulfide selenide by incorporating a suitable amount of an additional metallic element or elements to provide an emission wavelength in the range of 750 nm to 1100 nm. The quantum dots may be enabled for bioconjugation and may be used in a method for tissue imaging and analyte detection.

Abstract: Apparatuses and methods for synthesizing nanoparticles are provided.

Abstract: This disclosure is directed to systems and methods for sorting a native aggregate, such as a fluorescent nanoparticle aggregate, which includes multiple objects, some of which have different characteristics, into lower level ensembles, such as monochromatic nanoparticle ensembles. In one aspect, the system includes two detectors, one of which accepts all emitted wavelengths and another one which is preceded by a filter to permit transmission of a specific wavelength or range of wavelengths. In another aspect, the system includes multiple detectors, each detector configured to detect a given wavelength or range of wavelengths, such that no two detectors have overlapping wavelengths or ranges. In yet another aspect, the system includes an optical regulator in front of a detector. This disclosure is also directed to systems and methods for multiplexing and analyzing a target analyte using the monochromatic nanoparticle ensembles.

Abstract: Disclosed are a new composite material and a process for synthesizing highly charged, highly monodisperse, core-shell particles with high refractive index cores, as well as stable, long lasting crystalline colloidal arrays (CCAs) formed thereof. A preferred embodiment of the core particle can be highly monodisperse zinc sulfide (ZnS) particles and a preferred embodiment of the shell can be highly charged polyelectrolytes. The CCAs formed thereof are charge stabilized photonic crystals that shows distinctive first and second order Bragg diffraction peaks whose locations vary over a wide spectral region from UV through visible to IR, with unusually strong intensity and broad band width due to the high index of refraction. These high refractive index particles are useful in applications such as optical filters, optical coatings, cosmetics and photonic crystals sensors and devices.

Abstract: Disclosed herein are methods of preparing inorganic nanoparticles. In one aspect, the methods can comprise heating a reaction mixture comprising a C8 to C20 alkyl- or arylphosphonic acid and a source of cadmium or zinc to a temperature of greater than about 300° C.; adding to the reaction mixture an injection mixture comprising a C2 to C16 trialkyl- or triarylphosphine and a source of selenium, sulfur, or tellurium; and decreasing the temperature of the reaction mixture to less than about 300° C. Also disclosed herein are nanoparticles made from the disclosed methods. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: The present invention provides a method of producing a crystalline metal sulfide nanostructure. The metal is a transitional metal or a Group IV metal. In the method, a porous membrane is placed between a metal precursor solution and a sulfur precursor solution. The metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure.

Abstract: The invention relates to a polycrystalline IR transparent material produced by sintering chalcogenide powder, e.g., ZnS powder, using hot uniaxial pressing followed by hot isostatic pressing. The microstructure of the material described in this disclosure is much finer than that found in material produced using the state of the art process. By using a powder with a particle size fine enough to improve sintering behavior but coarse enough to prevent a lowering of the wurtzite-sphalerite transition temperature, a highly transparent material with improved strength is created without degrading the optical properties. A high degree of transparency is achieved during hot pressing by applying pressure after the part has reached a desired temperature. This allows some degree of plastic deformation and prevents rapid grain growth which can entrap porosity. The crystallographic twins created during this process further inhibit grain growth during hot isostatic pressing.

Abstract: A method of producing a Group II-VI compound semiconductor. The method involves generating a pulsed electrical discharge plasma between metallic electrodes in sulfur to produce a Group II-VI compound semiconductor. A method of producing a Group II-VI compound semiconductor phosphor using a pulsed electrical discharge plasma. A hexagonal crystal of Group II-VI compound semiconductor composed of a plurality of twin crystals.

Abstract: Disclosed are the metallic sulfide photocatalyst and its preparation method. The photocatalyst includes at least one soluble metallic salt and a sulfide with the oxidation state of S atom ?+4. The photocatalyst is afforded by reacting the sulfide with the at least one soluble metallic salt dissolved in the complexing agent. Additionally, the photocatalyst further is customized with co-catalyst such as RuCl to form Ru-carried metallic sulfide photocatalyst. The metallic sulfide photocatalyst and Ru-carried metallic sulfide photocatalyst are capable of effectively reducing CO2 to CH3OH under the visible light illumination.

Abstract: In one aspect, the invention relates to an inorganic nanoparticle or nanocrystal, also referred to as a quantum dot, capable of emitting white light. In a further aspect, the invention relates to an inorganic nanoparticle capable of absorbing energy from a first electromagnetic region and capable of emitting light in a second electromagnetic region, wherein the second electromagnetic region comprises an at least about 50 nm wide band of wavelengths and to methods for the preparation thereof. In further aspects, the invention relates to a frequency converter, a light emitting diode device, a modified fluorescent light source, an electroluminescent device, and an energy cascade system comprising the nanoparticle of the invention. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: The invention relates to a method for the preparation of nanoparticles in ionic liquids. Specifically, the invention relates to a simple, quick and effective method for the preparation of dispersions of nanoparticles (nanofluids) in an ionic liquid.

Abstract: Disclosed herein are photocatalyst powder and a production method thereof, and by having photocatalyst particles corn binded without reduction of a specific surface area, the reduction of the specific surface area is nearly none while the pores are developed, as well as the absorption rate with respect to light is superior, the method of producing photocatalyst powder includes forming initial photocatalyst powder by molding nanoparticles of photocatalyst substance into a certain shape through extrusion, and splitting the initial photocatalyst powder into a plurality of photocatalyst powder by injecting the initial photocatalyst powder into a predetermined splitting solution, the initial photocatalyst powder being split into the plurality of photocatalyst powder by the predetermined spliting solution.

Abstract: This invention provides a method of biosynthesizing nanoparticles and quantum dots. The method may comprise culturing photosynthetic cells and/or fungal cells of a multicellular fungus in a culture medium comprising one or more species of metal in ionic or non-ionic form; and one or more counter elements to the one or more species of metal, or one or more compound comprising one or more counter elements to the one or more species of metal; wherein the cells biosynthesize nanoparticles and quantum dots incorporating the metal. The invention also provides biosynthesized nanoparticles and quantum dots.

Abstract: The subject matter of the present invention is marked inorganic additives, a method for their production and also their use.

Abstract: The present invention provides a method for producing a zinc sulfide based phosphor by firing a zinc sulfide based precursor, comprising at least: a first firing step and a second firing step. Use of the method of the present invention makes it possible to provide a zinc sulfide based phosphor material suitable in the production of an EL device that shows high brightness.

Abstract: Low scatter water clear zinc sulfide with reduced metal contamination is prepared by cleaning an inert foil with an acid cleaning method and also cleaning zinc sulfide to reduce metal contamination. The zinc sulfide is wrapped in the inert foil and then treated by a HIP process to provide a water-clear zinc sulfide. The low scatter water-clear zinc sulfide may be used in articles such as windows and domes.

Abstract: This invention provides a method of biosynthesizing nanoparticles and quantum dots. The method may comprise culturing photosynthetic cells and/or fungal cells of a multicellular fungus in a culture medium comprising one or more species of metal in ionic or non-ionic form; and one or more counter elements to the one or more species of metal, or one or more compound comprising one or more counter elements to the one or more species of metal; wherein the cells biosynthesize nanoparticles and quantum dots incorporating the metal. The invention also provides biosynthesized nanoparticles and quantum dots.

Abstract: The present invention provides a method of forming a nanocrystal of the composition CdA, with A being S or Se. The method includes forming in a suitable solvent a solution of cadmium, or a compound thereof, in a form suitable for the generation of a nanocrystal. The solvent includes a compound selected from an ether and an amine. The method further includes bringing the solution to a temperature selected in the range from about 20° C. to about 200° C. The method also includes adding at the temperature selected in the range from about 20° C. to about 200° C. the element A in a form suitable for the generation of a nanocrystal. Thereby the forming of a nanocrystal of the composition CdA is allowed.

Abstract: A process for producing a Group II metal sulfide phosphor precursor, comprising adding to an organic solvent an aqueous solution containing at least one of a Group II element compound, a sulfurizing agent, and a compound containing any of copper, silver, manganese, gold, and rare-earth elements to obtain a reaction mixture, heating the reaction mixture to produce an azeotrope of the water and the organic solvent, and removing water from the reaction mixture to produce a desired Group II metal sulfide in the reaction mixture, wherein the removal of water from the reaction mixture occurs by recovering only the water condensed from a vapor produced by the azeotropic distillation.

Abstract: An economic, direct synthetic method for producing water soluble QDs that are ready for bioconjugation is provided. The method can produce aqueous QDs with emission wavelengths varying from 400 nm to 700 nm. Highly luminescent metal sulfide (MS) QDs are produced via an aqueous synthesis route. MS QDs are capped with thiol-containing charged molecules in a single step. The resultant MS QDs exhibit the distinctive excitonic photoluminescence desired of QDs and can be fabricated to avoid undesirable broadband emissions at higher wavelengths. This provides a significant improvement over the present complex and expensive commercial processes for the production of QDs. The aqueous QDs are stable in biological fluids over a long period of time. In addition, nontoxic ZnS QDs have been produced with good photoluminescence properties by refluxing the ZnS QD suspensions over a period of time.

Abstract: Cd-112 isotope is recycled from a Cd-112 chemical separated solution or a remainder of an electroplating solution having a Cd-112 target. The present invention recycles Cd-112 isotope with a low cost, a high purity and a high recycle rate. The recycled Cd-112 isotope can be easily stored. And, the Cd-112 isotope can be used as an imaging agent in nuclear medicine.

Abstract: Disclosed are inorganic nanoparticles comprising a body comprising cadmium and/or zinc crystallized with selenium, sulfur, and/or tellurium; a multiplicity of phosphonic acid ligands comprising at least about 20% of the total surface ligand coverage; wherein the nanocrystal is capable of absorbing energy from a first electromagnetic region and capable of emitting light in a second electromagnetic region, wherein the maximum absorbance wavelength of the first electromagnetic region is different from the maximum emission wavelength of the second electromagnetic region, thereby providing a Stokes shift of at least about 20 nm, wherein the second electromagnetic region comprises an at least about 100 nm wide band of wavelengths, and wherein the nanoparticle exhibits has a quantum yield of at least about 10%. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Abstract: Single source precursors are subjected to carbon dioxide to form particles of material. The carbon dioxide may be in a supercritical state. Single source precursors also may be subjected to supercritical fluids other than supercritical carbon dioxide to form particles of material. The methods may be used to form nanoparticles. In some embodiments, the methods are used to form chalcopyrite materials. Devices such as, for example, semiconductor devices may be fabricated that include such particles. Methods of forming semiconductor devices include subjecting single source precursors to carbon dioxide to form particles of semiconductor material, and establishing electrical contact between the particles and an electrode.

Abstract: The present invention provides a method of producing a crystalline metal sulfide nanostructure. The method comprising: providing a metal precursor solution and providing a sulfur precursor solution; placing a porous membrane between the metal precursor solution and the sulfur precursor solution, wherein metal cations of the metal precursor solution and sulfur ions of the sulfur precursor solution react, thereby producing a crystalline metal sulfide nanostructure, wherein the metal is a transitional metal or a Group IV metal.

Abstract: A method for reclaiming a semiconductor material from a glass substrate is disclosed, the method comprises the steps of providing at least one glass substrate having the semiconductor material disposed thereon, reducing the glass substrate having a semiconductor material disposed thereon to a plurality of glass particles having the semiconductor material disposed thereon by introducing a source of energy thereto, separating the semiconductor material from the plurality of glass particles to obtain semiconductor particles, and pyrometall?rgicaHy refining the semiconductor particles and the fine glass particles.

Abstract: There is provided a sintered body that does not readily deform during use and that allows a high flexibility for the design of surface layers, a method for manufacturing the sintered body, and an optical component including the sintered body. The method for manufacturing a sintered body includes a sintered body having a predetermined shape, the sintered body having a ceramic base material, the method for manufacturing a sintered body comprising a step for preparing a ceramic preform, a step for using a predetermined mold having an upper die and a lower die to hot-press the ceramic preform to form a pressure-sintered body, and a step for cooling the pressure-sintered body while applying a pressure load of approximately 5% or more and 100% or less (and preferably approximately 20% or more and 40% or less) of the pressure load applied during the step for forming the pressure-sintered body.

Abstract: A method and apparatus for pyrolytic destruction of polymer products including whole vehicle vulcanised rubber tyres is disclosed. The apparatus 111 has a reaction chamber 153 into which a tyre can be placed, and immersed for pyrolytic decomposition in a molten alloy of zinc with a minor proportion of aluminium. The apparatus 111 has a heated reservoir 155 in which the alloy is maintained in a molten state, and from where it can be transferred to the reaction chamber 153 to immerse the tyre. Fluid hydrocarbon byproducts are drawn off for condensation and recovery, and solid zinc sulphides are also recovered. Where steel belted tyres are processed, carbon and steel residues are also recovered.

Abstract: An economic, direct synthetic method for producing water soluble QDs that are ready for bioconjugation is provided. The method can produce aqueous QDs with emission wavelengths varying from 400 nm to 700 nm. Highly luminescent metal sulfide (MS) QDs are produced via an aqueous synthesis route. MS QDs are capped with thiol-containing charged molecules in a single step. The resultant MS QDs exhibit the distinctive excitonic photoluminescence desired of QDs and can be fabricated to avoid undesirable broadband emissions at higher wavelengths. This provides a significant improvement over the present complex and expensive commercial processes for the production of QDs. The aqueous QDs are stable in biological fluids over a long period of time. In addition, nontoxic ZnS QDs have been produced with good photoluminescence properties by refluxing the ZnS QD suspensions over a period of time.

Abstract: The separation method for zinc sulfide, in the hydrometallurgical process by a High Pressure Acid Leach for nickel oxide ore comprising leaching and solid/liquid separation step, neutralization step, zinc removal step, and nickel recovery step, which can inhibit clogging of a filter cloth and reduce a frequency of washing operation and replacement operation of a filter cloth by improving filtration performance of zinc sulfide, and inhibit decrease of nickel recovery ratio, in the zinc removal step in which zinc sulfide is formed by adding a sulfurizing agent to the neutralization final liquid containing zinc as well as nickel and cobalt and zinc sulfide is separated to obtain a mother liquid for nickel recovery containing nickel and cobalt. The separation method for zinc sulfide of the present invention is characterized in that in the above-described neutralization step, the leach residue is added to the leach liquor, and pH of the neutralization final liquid is adjusted so as to fall to the range from 3.

Abstract: A nanophosphor including ZnS, having an average particle diameter of about 10 to about 500 nanometers, and having a ZnS cubic (111) peak in an X-ray diffraction spectrum, wherein the ZnS cubic (111) peak has a full width at half maximum (“FWHM”) of about 0.280 degrees or less.

Abstract: A process for immobilizing mercury by producing crystalline mercury sulfide for subsequent disposal of the mercury sulfide, the mercury sulfide being formed by the reaction of elemental mercury and an additive material of elemental sulfur or a sulfur compound. The reaction of the mercury and of the additive material takes place at least during one time interval at a temperature above the melting point of the additive material.

Abstract: A cadmium sulfide nanocrystal, wherein the cadmium sulfide nanocrystal shows maximum luminescence peaks at two or more wavelengths and most of the atoms constituting the nanocrystal are present at the surface of the nanocrystal to form defects.

Abstract: An object of the invention is to provide a method for the stable production of a high-purity Group II-VI compound semiconductor on an industrial scale, and also a hexagonal crystal of Group II-VI compound semiconductor in which a metal can be doped easily. Another object of the invention is to provide a method of producing a Group II-VI compound semiconductor phosphor. The objects are achieved by a method of producing a Group II-VI compound semiconductor comprising generating a pulsed electrical discharge plasma between metallic electrodes in sulfur to produce a Group II-VI compound semiconductor; a method of producing a Group II-VI compound semiconductor phosphor using a pulsed electrical discharge plasma; and a hexagonal crystal of Group II-VI compound semiconductor composed of a plurality of twin crystals.

Abstract: A semiconductor nanocrystal, wherein the semiconductor nanocrystal shows maximum luminescence peaks at two or more wavelengths and most of the atoms constituting the nanocrystal are present at the surface of the nanocrystal to form defects.

Abstract: A method for synthesizing a chalcogenide nanoparticle is provided. The method comprises reacting a metal component with an elemental chalcogen precursor in the presence of an organic solvent. The chalcogenide nanoparticles include ternary, binary and/or multinary chalcogenide nanoparticles and the metal component comprises metal halides or elemental metal precursors. The alkylamine solvent has a normal boiling temperature of above about 220° C. and an average particle size of from about 5 nm to about 1000 nm.

Abstract: An economic, direct synthetic method for producing water soluble QDs that are ready for bioconjugation is provided. The method can produce aqueous QDs with emission wavelengths varying from 400 nm to 700 nm. Highly luminescent metal sulfide (MS) QDs are produced via an aqueous synthesis route. MS QDs are capped with thiol-containing charged molecules in a single step. The resultant MS QDs exhibit the distinctive excitonic photoluminescence desired of QDs and can be fabricated to avoid undesirable broadband emissions at higher wavelengths. This provides a significant improvement over the present complex and expensive commercial processes for the production of QDs. The aqueous QDs are stable in biological fluids over a long period of time. In addition, nontoxic ZnS QDs have been produced with good photoluminescence properties by refluxing the ZnS QD suspensions over a period of time.

Abstract: The present disclosure provides a solid dopant for doping a conductive polymer, which has a high dispersibility in a solvent by a plasma treatment, a method and an apparatus for preparing the solid dopants, a solid doping method of a conductive polymer using the solid dopants, and a solid doping method of a conductive polymer using plasma.

Abstract: The process of the invention is provided to achieve uniform doping of an activator metal into phosphor particles and to improve efficiency of utlization of a metal element to be used in the production of a Group II metal sulfide phosphor and a precursor thereof. Specifically, the object of the invention is achieved by a process for producing a Group II metal sulfide phosphor precursor, comprising adding to an organic solvent an aqueous solution containing at least one of a Group II element compound, a sulfurizing agent, and a compound containing any of copper, silver, manganese, gold, and rare-earth elements to obtain a reaction mixture, heating the reaction mixture to produce an azeotrope of the water and the organic solvent, and removing the water from the reaction mixture to produce a desired Group II metal sulfide in the reaction mixture, wherein the removal of the water from the reaction mixture is carried out by recovering only the water condensed from a vapor produced by the azeotropic distillation.

Abstract: A method and apparatus for producing surface stabilized nanometer-sized particles includes the steps of mixing reactants, a surface-stabilizing surfactant, and a high boiling point liquid to form a mixture, continuously passing the mixture through an ultrasonic spray nozzle to form a mist of droplets of the mixture, injecting the mist directly into a furnace to cause a reaction between species of the mixture, and collecting the nanometer-sized products. The ultrasonic nozzle is positioned directly at one end of the heating furnace, preferably the top end, for travel of the droplets through the furnace. The continuous liquid-flow process, along with certain operating parameters, eliminates the need for dilution of the high boiling point liquid with a low boiling point solvent as in the prior art, significantly increases the yield, improves the quality of the product, and makes the process scalable.

Abstract: The invention provides a simple and cost-effective method for preparing particles such as anisotropic semiconductor nanoparticles (e.g. CdS) and devices thereof. The method comprises (i) dispersing at least part of particle-forming reactants in a self-organized medium such as surfactant-aqueous solution system, and (ii) conducting a particle-forming reaction using the particle-forming reactants dispersed in the self-organized medium under shear condition to form the particles. The anisotropic property of the particles is controlled at least partially by the shear condition. The invention may be used to prepare quantum dots in a liquid crystal, and various devices such as nonlinear optics, optoelectronic devices, and solar cells, among others.

Abstract: Methods of processing nanocrystals to remove excess free and bound organic material and particularly surfactants used during the synthesis process, and resulting nanocrystal compositions, devices and systems that are physically, electrically and chemically integratable into an end application.