Superoxide Or Ozone Patents (Class 423/581)
  • Publication number: 20150086423
    Abstract: A sterilization treatment method includes producing a plasma-treated solution in which biocidal activity is held by diffusing, in a liquid, superoxide anion radicals (O2?.) or a precursor of the superoxide anion radicals (O2?.) by plasma generated in a vicinity of or in a manner to make contact with the liquid; freezing the plasma-treated solution to produce solid ice and store the solid ice in a frozen state; thawing the solid ice to the plasma-treated solution in which biocidal activity by the superoxide anion radicals (O2?.) or the precursor of the superoxide anion radicals (O2?.) is held; and applying a sterilization treatment by any one of the following: allowing the plasma-treated solution to have a pH value of 4.8 or lower to apply the resultant plasma-treated solution to an object, and applying the plasma-treated solution to an object of which a pH value is 4.8 or lower.
    Type: Application
    Filed: October 24, 2014
    Publication date: March 26, 2015
    Applicant: OSAKA UNIVERSITY
    Inventors: Katsuhisa KITANO, Satoshi Ikawa
  • Patent number: 8851010
    Abstract: Systems and methods to determine ozone concentration in a gas mixture of ozone and oxygen, based on measurements of the total gas mixture properties, can enable the measurements of ozone concentration at low pressure settings. The ozone concentration determination can be applied to vacuum processing chamber, using either novel ozone sensor or existing mass flow meter or controller.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: October 7, 2014
    Assignee: Intermolecular, Inc.
    Inventors: ShouQian Shao, Jay DeDontney, Jason Wright
  • Patent number: 8840705
    Abstract: A method for producing ozone for use in ozonolysis reactions. Oxygen is separated from the mixture of ozone and oxygen from an ozone generation unit and is fed back to the oxygen feed to the generation unit. Nitrogen is fed to the ozone separation unit and the mixture of nitrogen and ozone is fed to the ozonation reactor where the ozone will react with organic compounds to produce desired end products.
    Type: Grant
    Filed: July 2, 2012
    Date of Patent: September 23, 2014
    Assignee: Linde Aktiengesellschaft
    Inventors: Frank R. Fitch, Naresh J. Suchak
  • Publication number: 20140113811
    Abstract: Provided are methods for storing gases on porous adsorbents, methods for optimizing the storage of gases on porous adsorbents, methods of making porous adsorbents, and methods of gas storage of optimized compositions, as in systems containing porous adsorbents and gas adsorbed on the surface of the porous adsorbent. The disclosed methods and systems feature a constant or increasing isosteric enthalpy of adsorption as a function of uptake of the gas onto the exposed surface of a porous adsorbent. Adsorbents with a porous geometry and surface dimensions suited to a particular adsorbate are exposed to the gas at elevated pressures in the specific regime where n/V (density) is larger than predicted by the ideal gas law by more than several percent.
    Type: Application
    Filed: October 10, 2013
    Publication date: April 24, 2014
    Inventors: Nicholas P. STADIE, Brent T. FULTZ, Channing AHN, Maxwell MURIALDO
  • Publication number: 20140072653
    Abstract: Systems and methods for generating reactive oxygen species formulations useful in various oxidation applications. Exemplary formulations include singlet oxygen or superoxide and can also contain hydroxyl radicals or hydroperoxy radicals, among others. Formulations can contain other reactive species, including other radicals. Exemplary formulations containing peracids are activated to generate singlet oxygen. Exemplary formulations include those containing a mixture of superoxide and hydrogen peroxide. Exemplary formulations include those in which one or more components of the formulation are generated electrochemically. Formulations of the invention containing reactive oxygen species can be further activated to generate reactive oxygen species using activation chosen from a Fenton or Fenton-like catalyst, ultrasound, ultraviolet radiation or thermal activation.
    Type: Application
    Filed: September 7, 2013
    Publication date: March 13, 2014
    Applicant: CLEAN CHEMISTRY, LLC
    Inventor: Wayne BUSCHMANN
  • Patent number: 8574521
    Abstract: An apparatus and method for removing contaminants from a gas stream is provided which includes (a) introducing the gas stream into a reaction chamber of a scrubber; (b) oxidizing first contaminants in a liquid phase with a reactive species in a sump of the scrubber for providing an oxidizing solution; (c) oxidizing second contaminants in a gas phase of the gas stream above the sump with excess reactive species disengaging from the oxidizing solution in the sump; (d) oxidizing and scrubbing third contaminants in a gas-liquid contact assembly disposed above the gas stream.
    Type: Grant
    Filed: September 29, 2010
    Date of Patent: November 5, 2013
    Assignee: Linde Aktiengesellschaft
    Inventors: Naresh J. Suchak, Steven Finley
  • Patent number: 8497132
    Abstract: An ozone gas concentration measurement method that can easily measure the concentration of ozone gas. A process gas containing ozone gas is produced from a raw gas containing oxygen gas. The number of moles of gas molecules contained in the process gas is measured. The concentration of the ozone gas contained in the process gas is calculated based on the number of moles of gas molecules contained in the process gas.
    Type: Grant
    Filed: November 5, 2009
    Date of Patent: July 30, 2013
    Assignee: Tokyo Electron Limited
    Inventor: Takehiro Shindou
  • Publication number: 20130177497
    Abstract: A method for producing ozone for use in ozonolysis reactions. Oxygen is separated from the mixture of ozone and oxygen from an ozone generation unit and is fed back to the oxygen feed to the generation unit. Nitrogen is fed to the ozone separation unit and the mixture of nitrogen and ozone is fed to the ozonation reactor where the ozone will react with organic compounds to produce desired end products.
    Type: Application
    Filed: July 2, 2012
    Publication date: July 11, 2013
    Inventors: Frank R. FITCH, Naresh J. Suchak
  • Publication number: 20130108610
    Abstract: The present invention is directed to a method of inhibiting aconitase activity of fungal cells in an individual, the method comprising administering an inhibitor of aconitase activity to the fungal cell in an amount effective to inhibit activity of aconitase by said fungal cells.
    Type: Application
    Filed: October 28, 2011
    Publication date: May 2, 2013
    Inventors: James Robert SCHWARTZ, Charles Winston Saunders, Robert Scott Youngquist, Jun Xu
  • Patent number: 8273384
    Abstract: The present invention provides novel methods of making a non-corrosive base solution for use as an alkalinity increasing agent and/or antioxidant. The present invention further provides novel compositions and methods which can be used to provide relief from disorders related to or complicated by acidosis or excessive free radical or other reactive oxygen species production including, but not limited to, gout, Lesch-Nyhan syndrome, hemochromatosis, Alzheimer's, amyotropic lateral sclerosis, arthritis, atherosclerosis, cancer, cataracts, chronic obstructive pulmonary disease, diabetes, cellulitis, coronary artery disease, heart failure, hypertension, inflammatory bowel disease, macular degeneration, multiple sclerosis, Parkinson's, Reynaud's phenomenon, reperfusion injury, pancreatic impairment, skin infections, Hepatitis C, methicillin-resistant Staphylococcus aureus and infection.
    Type: Grant
    Filed: July 2, 2008
    Date of Patent: September 25, 2012
    Inventor: Stephen Ray Wurzberger
  • Publication number: 20120189520
    Abstract: Concentrated aqueous hydrogen peroxide or another reactive compound in a liquid carrier is activated by atomization and contact with a suitable catalyst that is concurrently atomized in a carrier liquid. Concentrated hydrogen peroxide and a hydrogen peroxide activation catalyst are atomized into a droplet spray for catalytic activation of the hydrogen peroxide in this invention, useful for treatment of a combustion flue gas containing contaminants such as NO? and/or Hg.
    Type: Application
    Filed: July 29, 2010
    Publication date: July 26, 2012
    Applicants: INDIGO TECHNOLOGIES GROUP PTY. LTD., FMC CORPORATION
    Inventors: Henry A. Pfeffer, Timothy A. Holtz, Rodney J. Truce, JoAnn Pacinelli, Luke F. Wilkinson
  • Patent number: 8182785
    Abstract: Methods for producing singlet oxygen from 1,1-dihydroperoxides are provided herein. In some embodiments, the methods involve base-mediated decomposition of monoactivated derivatives of 1,1-dihydroperoxides. In some embodiments, the methods involve additive-mediated decomposition of 1,1-dihydroperoxides.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: May 22, 2012
    Assignee: Nutech Ventures
    Inventors: Patrick H. Dussault, Prasanta Ghorai
  • Patent number: 8147792
    Abstract: The subject invention provides a potentially economically viable method for the preparation of reactive superoxide ion in deep eutectic solvents (DES). The superoxide ion can be used for many applications, e.g. the degradation of hazardous chemicals at ambient conditions or in the synthesis of some special chemicals, e.g. carboxylic acids, aldehydes, and ketones from the corresponding alcohols. The superoxide ion can be formed by either the electrochemical reduction of oxygen in DES or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: April 3, 2012
    Assignee: King Saud University
    Inventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
  • Patent number: 8147876
    Abstract: An object of the present invention is to provide a medical agent that has an excellent effect on the diseases resulting from one of inflammation and remodeling and that can prevent or treat them in response to various mechanisms of onset and development of the diseases. Thus, the present invention relates to a medical agent for preventing or treating diseases resulting from one of inflammation and remodeling in blood vessel, including nanobubbles.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: April 3, 2012
    Assignees: National University Corporation Tokyo Medical and Dental University, REO Laboratory, Co., Ltd.
    Inventors: Yukihiro Hojo, Kaneo Chiba, Yoshihiro Mano
  • Patent number: 8049056
    Abstract: A method and system for the reduction of contamination in soil and groundwater is provided. A clathrate of ozone and a cyclic oligosaccharide can provide for an extended zone of influence due to, for instance, the improved stability of the ozone. The clathrate can include cyclodextrin and ozone and can improve the oxidative destruction of organic and inorganic contaminants.
    Type: Grant
    Filed: May 12, 2009
    Date of Patent: November 1, 2011
    Assignee: EnChem Engineering, Inc.
    Inventor: Raymond G. Ball
  • Publication number: 20110250125
    Abstract: A device, system, and method, for the formation of advanced oxidation products by contacting a hydrated catalytic surface of a catalytic target structure with broad spectrum ultraviolet light in the 100 nm to 300 nm range that preferably includes 185 nm and 254 nm wavelengths. The catalytic surface reacts with the ultraviolet light energy and hydrate at the catalytic surface to form advanced oxidation products, The catalytic surface in one embodiment includes a hydrophilic agent, titanium dioxide, silver, copper, and rhodium. Preferably, the catalytic surface is coated with a coating that includes the hydrophilic; agent, titanium dioxide, silver, copper, and rhodium. A photohydroionization cell (100) that includes an ultraviolet light source (204) and a catalytic target structure (110) in an air environment to form advanced oxidation product is also provided. A U.V. light indicator and a monitor and/or control system for the photohydroionization cell (100) are also provided.
    Type: Application
    Filed: June 17, 2011
    Publication date: October 13, 2011
    Applicant: RGF Environmental Group, Inc.
    Inventors: Ronald G. FINK, Walter B. Ellis
  • Publication number: 20110123430
    Abstract: A method of concentrating ozone gas in which, although the apparatus configuration is simple, ozone gas of a predetermined concentration can be efficiently taken out, and an apparatus therefor are provided. In a method of concentrating ozone gas in which an ozone-oxygen mixture gas is acted in an adsorbing column that is filled with an adsorbent, to cause the adsorbent to selectively adsorb the ozone gas, and the selectively adsorbed ozone gas is desorbed, thereby concentrating and purifying the ozone gas, the ozone-oxygen mixture gas is acted on the adsorbent in a non-cooled state to cause the ozone gas to be selectively adsorbed to the adsorbent, the adsorbing column is vacuumed when performing an operation desorbing of the ozone gas, thereby desorbing the ozone gas from the adsorbent, and an initial amount of the leading out of the desorbed ozone gas is not recovered, thereby obtaining high-concentration ozone gas.
    Type: Application
    Filed: July 23, 2008
    Publication date: May 26, 2011
    Applicants: IWATANI CORPORATION, KOHTAKI PRECISION MACHINE CO., LTD.
    Inventors: Kunihiko Koike, Sadaki Nakamura, Naohisa Makihira, Koichi Izumi, Shigenori Takatori
  • Publication number: 20110108410
    Abstract: A dispensing apparatus including a product dispenser in which product is dispensed by manual movement of an activation mechanism as, for example, by moving a lever with a person's hand, arm or foot. The dispensing apparatus includes an electrical generator for generating electrical energy as a result of the manual movement of the activation mechanism, preferably by electromagnetic induction, electrochemistry or piezoelectricity. The electrical energy from the generator may be utilized in the dispensing apparatus to power a data communication unit for receiving information about the product dispenser and transmitting the information to a receiver, preferably but not necessarily wirelessly. The relative amounts of electrical energy generated may be used to estimate the amount of fluid dispensed and the extent to which a fluid reservoir is full.
    Type: Application
    Filed: January 14, 2011
    Publication date: May 12, 2011
    Inventor: Heiner Ophardt
  • Patent number: 7922875
    Abstract: A method of enriching a heavy oxygen isotope by distillation of the present invention includes: a first distillation step of feeding oxygen and ozone generated by an ozonizer 12 into a distillation column 13 filled with a diluent gas, and separating the oxygen, and the ozone and the diluent gas; a photodecomposition step of introducing a mixed gas of the ozone and the diluent gas from a bottom of the distillation column into a photoreaction cell 14, and irradiating the mixed gas with a laser light to selectively decompose the ozone containing the heavy oxygen isotope; and a second distillation step of returning non-decomposed ozone and oxygen containing the heavy oxygen isotope to the distillation column, and separating the oxygen, and the ozone and the diluent gas.
    Type: Grant
    Filed: September 20, 2007
    Date of Patent: April 12, 2011
    Assignee: Taiyo Nippon Sanso Corporation
    Inventors: Takashi Kambe, Hitoshi Kihara, Norihisa Nara, Hiroshi Kawakami
  • Publication number: 20110052483
    Abstract: An ozonized gas having a pressure exceeding atmospheric pressure and having a predetermined concentration is supplied to adsorption/desorption columns (4) at a low temperature state of 0° C. or less and a high pressure and packed with silica gel (6) serving as an adsorbent. The adsorption/desorption columns (4) have been constituted so that at least three of a plurality of adsorption/desorption columns (4), i.e., adsorption/desorption columns (4-1, 4-2, and 4-3), are disposed in a serial cycle arrangement to constitute a main adsorption/desorption column group (99), and that an adsorption/desorption column (4-4) is disposed in parallel with the main adsorption/desorption column group (99) to constitute an auxiliary adsorption/desorption column (999). In a period in which none of the three columns of the main adsorption/desorption column group (99) is performing desorption processing, the auxiliary adsorption/desorption column (999) performs desorption processing.
    Type: Application
    Filed: November 28, 2008
    Publication date: March 3, 2011
    Applicants: TOSHIBA MITSUBISHI-ELECTRIC INDUSTRIAL SYS. CORP., MITSUBISHI ELECTRIC CORPORATION
    Inventors: Yoichiro Tabata, Yujiro Okihara, Tetsuya Saitsu, Noriyuki Nakamura, Ryohei Ueda, Koji Ota, Yasuhiro Tanimura
  • Publication number: 20100329972
    Abstract: The invention relates to a cooking oven (1), having a cavity (2) which is closable by a door (3). To reduce bacteria growth the invention is characterized in that oxygenating gas or ozone generating means (4) are provided for supplying at least a part of the cavity (2) or a region (5) adjacent to the cavity (2) with oxygenating gas or ozone.
    Type: Application
    Filed: May 16, 2008
    Publication date: December 30, 2010
    Applicant: ELECTROLUX HOME PRODUCTS CORPORATION N.V.
    Inventors: Fabienne Reinhard-Herrscher, Thomas Fich Pedersen, Kersten Kaiser
  • Publication number: 20100322844
    Abstract: An ozone supplier 11 of the present invention includes a mixer 1 which dissolves an oxygen-ozone mixed gas in a fluorine-based solvent to produce a mixed solution, an undissolved gas removing device 2 which removes an undissolved gas from the mixed solution, and a deaerator 3 which extracts an ozone-containing gas, which is dissolved in the mixed solution subjected to removal of the undissolved gas, from the mixed solution.
    Type: Application
    Filed: June 22, 2010
    Publication date: December 23, 2010
    Inventors: Hiroshi SANUI, Yoshiki Nishiwaki
  • Publication number: 20100239707
    Abstract: The present methods and compounds relate to increasing meat tenderness by inducing post-mortem breakdown in muscle tissue. This is achieved by the use of beta-blockers in the pre-mortem period, which results in higher calpastatin levels, and reduced hyperplasia. This is also achieved by the use of agents immediately before slaughter that induce apoptosis in muscle tissue. This is further achieved by administering agents that induce muscle fiber fission.
    Type: Application
    Filed: October 9, 2008
    Publication date: September 23, 2010
    Inventors: David Goldberg, Keith E. Belk, Phillip D. Bass, Hyungchul Han, Joseph D. Tatum, Gary L. Mason
  • Publication number: 20100189635
    Abstract: A pressure swing adsorption cycle designed to reduce the variations in ozone concentration, and produce a higher average ozone concentration, in a product gas stream throughout the cycle. The cycle includes a relatively long air sweep stage and provides for the overlapping of the air sweep stage in two adsorber vessels. Effluent from an adsorber vessel in a feed rinse stage is routed to another adsorber vessel that is in an air sweep stage.
    Type: Application
    Filed: January 23, 2009
    Publication date: July 29, 2010
    Applicant: AIR PRODUCTS AND CHEMICALS, INC.
    Inventor: Edward Landis Weist, JR.
  • Publication number: 20100119439
    Abstract: An ozone gas concentration measurement method that can easily measure the concentration of ozone gas. A process gas containing ozone gas is produced from a raw gas containing oxygen gas. The number of moles of gas molecules contained in the process gas is measured. The concentration of the ozone gas contained in the process gas is calculated based on the number of moles of gas molecules contained in the process gas.
    Type: Application
    Filed: November 5, 2009
    Publication date: May 13, 2010
    Applicant: TOKYO ELECTRON LIMITED
    Inventor: Takehiro SHINDOU
  • Publication number: 20100040530
    Abstract: Methods for producing singlet oxygen from 1,1-dihydroperoxides are provided herein. In some embodiments, the methods involve base-mediated decomposition of monoactivated derivatives of 1,1-dihydroperoxides. In some embodiments, the methods involve additive-mediated decomposition of 1,1-dihydroperoxides.
    Type: Application
    Filed: June 10, 2009
    Publication date: February 18, 2010
    Inventors: Patrick H. Dussault, Prasanta Ghorai
  • Publication number: 20090258125
    Abstract: The present invention provides an ozone emitter, which can continue to emit ozone gas for a long time, which can continue to exert effective detergent and bactericidal action due to ozone gas for a long time, and which is easily portable, a method and equipment for producing the ozone emitter, and a method for utilizing the same. The ozone emitter is provided in such a manner that ozone gas is filled into a container which is obtained by forming an ozone gas impermeable film material in a container shape, wherein the film material is provided with a number of fine permeable pores through which molecules of ozone gas can permeate.
    Type: Application
    Filed: September 28, 2006
    Publication date: October 15, 2009
    Applicant: ICEMAN CO., LTD.
    Inventor: Tomoaki Akiyama
  • Patent number: 7588750
    Abstract: Devices for generating and storing ozone. The device includes a tank for containing gas therein; an ozone generator for generating ozone and communicating the ozone with the tank; and at least one valve for admitting gas into the device, holding gas in the device, and discharging gas from the device.
    Type: Grant
    Filed: July 3, 2007
    Date of Patent: September 15, 2009
    Assignee: Amarante Technologies, Inc.
    Inventor: Jeff Ifland
  • Patent number: 7588749
    Abstract: Apparatus, method and system for delivering a sterile unit dose of ozone that may include concentrating oxygen from air, which can include pressurizing at least one zeolite chamber having at least one zeolite material where the at least one zeolite material selectively adsorbs a substantial amount of nitrogen and not a substantial amount of oxygen. An oxygen-ozone cell may be filled with substantially concentrated oxygen from the at least one zeolite chamber. The oxygen-ozone cell may then be sequestered. The oxygen-ozone cell may be removed and may be engaged with an ozone conversion unit. The ozone conversion unit may charge the substantially concentrated oxygen generating a predetermined concentration of ozone. The oxygen-ozone cell may be disengaged from the ozone conversion unit.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: September 15, 2009
    Assignee: Minimus Spine, Inc.
    Inventors: David M. Hooper, Thomas Foster, Noel Henson
  • Publication number: 20090010835
    Abstract: Devices for generating and storing ozone. The device includes a tank for containing gas therein; an ozone generator for generating ozone and communicating the ozone with the tank; and at least one valve for admitting gas into the device, holding gas in the device, and discharging gas from the device.
    Type: Application
    Filed: July 3, 2007
    Publication date: January 8, 2009
    Applicant: Amarante Technologies, Inc.
    Inventor: Jeff Ifland
  • Publication number: 20080292498
    Abstract: A system and method for producing an ozone-containing disinfecting cloud includes an enclosure. A pair of atomizing nozzles are affixed to the enclosure in substantially directly opposed relation. Each nozzle produces a spray of ozonated water from compressed gas, ozone, and water and are positioned to direct the sprays toward each other to form a cloud comprising droplets having a size distribution. A portion of the cloud that comprises droplets having a size less than a predetermined limit is expelled from the enclosure. Droplets having a size greater than the predetermined limit remain in the enclosure. The expelled cloud has been found to have a pH lower than a pH of the remaining droplets. The cloud so produced can be used to disinfect an area by directing the cloud to the area desired to be disinfected, which can comprise a surface and/or a space.
    Type: Application
    Filed: May 22, 2008
    Publication date: November 27, 2008
    Applicant: VAPEX TECHNOLOGIES, INC.
    Inventors: Darrel R. Resch, Griscom Bettle, III
  • Publication number: 20080241052
    Abstract: Apparatus, method and system for delivering a sterile unit dose of ozone that may include concentrating oxygen from air, which can include pressurizing at least one zeolite chamber having at least one zeolite material where the at least one zeolite material selectively adsorbs a substantial amount of nitrogen and not a substantial amount of oxygen. An oxygen-ozone cell may be filled with substantially concentrated oxygen from the at least one zeolite chamber. The oxygen-ozone cell may then be sequestered. The oxygen-ozone cell may be removed and may be engaged with an ozone conversion unit. The ozone conversion unit may charge the substantially concentrated oxygen generating a predetermined concentration of ozone. The oxygen-ozone cell may be disengaged from the ozone conversion unit.
    Type: Application
    Filed: March 29, 2007
    Publication date: October 2, 2008
    Inventors: David M. Hooper, Thomas Foster, Noel Henson
  • Publication number: 20080220089
    Abstract: An object of the present invention is to provide a medical agent that has an excellent effect on the diseases resulting from one of inflammation and remodeling and that can prevent or treat them in response to various mechanisms of onset and development of the diseases. Thus, the present invention relates to a medical agent for preventing or treating diseases resulting from one of inflammation and remodeling in blood vessel, including nanobubbles.
    Type: Application
    Filed: February 26, 2008
    Publication date: September 11, 2008
    Applicants: NATIONAL UNIVERSITY CORPORATION TOKYO MEDICAL AND DENTAL UNIVERSITY, REO LABORATORY CO., LTD
    Inventors: Yukihiro Hojo, Kaneo Chiba, Yoshihiro Mano
  • Patent number: 7347944
    Abstract: A method for making super-oxygenated and structured water that includes receiving water from a source, preconditioning the water for electrolysis, performing electrolysis on the preconditioned water to produce alkaline water, combining the alkaline water with oxygen, spinning the alkaline water/oxygen combination, outputting super-oxygenated, tuned and structured water, receiving the super-oxygenated and structured water into a coil system and passing the water therethrough, combining water output by the coil system with structured ozone, inputting the combined water and structured ozone to a multicoil system and passing the water therethrough and outputting super-oxygenated, tuned and structured water.
    Type: Grant
    Filed: June 3, 2005
    Date of Patent: March 25, 2008
    Inventor: David Bagley
  • Publication number: 20070217987
    Abstract: This invention describes a stand-alone ozone generator and method to generate high quantities of ozone which can be injected in a multitude of applications where great quantities are needed at a low production cost. This generator can be useful for flue gas oxidation, water purification, HVAC air purification, and any other commercial or industrial process where ozone is needed to oxidize organic or inorganic species. The process relies on the reaction of air or oxygen with a solution of white or yellow phosphorus contained in a reactor. In this method, the ozone generated is purified in-Situ and can be directly used in any process. The elemental phosphorus and the phosphorus derivatives are enclosed in the ozone generator and are not allowed to escape. The process can pay for itself by the sales of the phosphorus derivatives generated through the reaction.
    Type: Application
    Filed: March 15, 2007
    Publication date: September 20, 2007
    Applicant: THERMAL ENERGY INTERNATIONAL INC.
    Inventors: Raymond Belanger, Robert Triebe, Tim Angus, Oliver Toffoli
  • Patent number: 7264747
    Abstract: A microporous diffuser includes a first elongated member including at least one sidewall having a plurality of microscopic openings. The sidewall defines an interior hollow portion of the member. The diffuser has a second elongated member having a second sidewall having a plurality of microscopic openings, the second member being disposed through the hollow region of the first member. The diffuser includes an end cap to seal a first end of the microporous diffuser and an inlet cap disposed at a second end of microporous diffuser for receiving inlet fittings.
    Type: Grant
    Filed: January 9, 2006
    Date of Patent: September 4, 2007
    Inventor: William B. Kerfoot
  • Patent number: 7261959
    Abstract: Novel methods of air-oxidizing a molten alkali hydroxide at least partially to superoxide state and then reversing the reaction to obtain nitrogen-free oxygen, and then regenerating the molten hydroxide for repeated use, providing for the generating of concentrated oxygen from air.
    Type: Grant
    Filed: December 28, 2004
    Date of Patent: August 28, 2007
    Inventor: Walter Juda
  • Patent number: 7067102
    Abstract: A method of producing ozone comprises the steps of generating intermittent bursts of corona discharge in an electrode region 20.2, and passing oxygen-containing fluid through the region, thereby to cause ionization of the oxygen. The electrode is energized by a train of voltage pulses. Each pulse has a rise time of better than 2 kV/100 ns.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: June 27, 2006
    Assignee: Potchefstroom University for Christian Higher Education
    Inventor: Barend Visser
  • Patent number: 6818193
    Abstract: A plasma reactor including a first dielectric having at least one capillary defined therethrough, and a segmented electrode including a plurality of electrode segments, each electrode segment is disposed proximate an associated capillary. Each electrode segment may be formed in different shapes, for example, a pin, stud, washer, ring, or disk. The electrode segment may be hollow, solid, or made from a porous material. The reactor may include a second electrode and dielectric with the first and second dielectrics separated by a predetermined distance to form a channel therebetween into which the plasma exiting from the capillaries in the first dielectric is discharged. The fluid to be treated is passed through the channel and exposed to the plasma discharge. If the electrode segment is hollow or made of a porous material, then the fluid to be treated may be fed into the capillaries in the first dielectric and exposed therein to the maximum plasma density.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: November 16, 2004
    Assignees: Plasmasol Corporation, Stevens Institute of Technology, LLC
    Inventors: Christos Christodoulatos, George Korfiatis, Richard Crowe, Erich E Kunhardt
  • Publication number: 20030035764
    Abstract: An apparatus for generating an effective concentration of ozone for killing bacteria, viruses and other harmful microorganisms includes a housing having an ozone chamber defining an enclosed space for containing elevated concentrations of ozone. The ozone chamber includes ports providing access to the interior of the ozone chamber. A second chamber of the apparatus houses an ozone reactor. A programmable control circuit operates both the ozone reactor and a pump for directing ambient air to the ozone reactor. The control circuit includes a motion detector mounted in the ozone chamber for activating the ozone generator of the invention and initiating the generation of ozone directed into the ozone chamber of the apparatus of the invention.
    Type: Application
    Filed: August 17, 2001
    Publication date: February 20, 2003
    Inventors: Robert Malcolm Thomas, Karl Frederick Thomas
  • Patent number: 6333017
    Abstract: A method of producing ozone comprises heating a gas containing molecular oxygen under pressure in a first vessel to a temperature of greater than about (eg.) 2300° K to at least partially dissociate molecular oxygen into monoatomic oxygen. The monoatomic oxygen is supersonically transported from the first vessel to a second vessel at a temperature less than about (eg.) 1000° K via a convergent-divergent nozzle, where it forms ozone. Supersonically transporting the monoatomic oxygen via the convergent-divergent nozzle produces frozen flow conditions, thereby preserving the oxygen in its monoatomic state. Optionally, the monoatomic oxygen is mixed with the molecular oxygen to form ozone.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: December 25, 2001
    Assignee: Omachron Technologies, Inc.
    Inventors: Wayne Ernest Conrad, Ted Szylowiec
  • Publication number: 20010042691
    Abstract: A method and apparatus for manufacturing high concentration ozone gas, characterized by employing a pressure swing adsorbing apparatus having a plurality of adsorbing layers filled with ozone adsorbent, in which the ozone adsorbent is one or two or more kinds of adsorbent selected from the group consisting of high silica pentasyl zeolite, dealuminized fogersite, and mesoporous silicate.
    Type: Application
    Filed: April 20, 2001
    Publication date: November 22, 2001
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Jun Izumi, Akinori Yasutake, Nariyuki Tomonaga, Hiroyuki Tsutaya
  • Publication number: 20010031234
    Abstract: A plasma reactor including a first dielectric having at least one capillary defined therethrough, and a segmented electrode including a plurality of electrode segments, each electrode segment is disposed proximate an associated capillary. Each electrode segment may be formed in different shapes, for example, a pin, stud, washer, ring, or disk. The electrode segment may be hollow, solid, or made from a porous material. The reactor may include a second electrode and dielectric with the first and second dielectrics separated by a predetermined distance to form a channel therebetween into which the plasma exiting from the capillaries in the first dielectric is discharged. The fluid to be treated is passed through the channel and exposed to the plasma discharge. If the electrode segment is hollow or made of a porous material, then the fluid to be treated may be fed into the capillaries in the first dielectric and exposed therein to the maximum plasma density.
    Type: Application
    Filed: December 15, 2000
    Publication date: October 18, 2001
    Inventors: Christos Christodoulatos, George Korfiatis, Richard Crowe, Erich E. Kunhardt
  • Publication number: 20010007649
    Abstract: Ascorbic acid and/or ascorbic acid salt is made to act together with oxygen on an organic compound. Alternatively, light radiation is applied during chemical action with oxygen so as to improve a composition efficiency of an organic compound and obtain a preferable decomposition amount. This reduces the load caused by an organic compound decomposition on the environment.
    Type: Application
    Filed: January 11, 2001
    Publication date: July 12, 2001
    Applicant: Sony Corporation
    Inventor: Yasuhito Inagaki
  • Patent number: 6096277
    Abstract: A catalyst system useful at room temperature for the destruction of ozone (O.sub.3), which is comprised of a washcoat of high surface area support containing Mn/Cu catalyst deposited on a macroporous carrier, such as a honeycomb monolith, optionally with the addition of noble metal (such as Pt) washcoat to remove carbon monoxide.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: August 1, 2000
    Assignee: Goal Line Environmental Technologies LLC
    Inventors: Larry E. Campbell, Michele W. Sanders
  • Patent number: 6030598
    Abstract: An ozone containing gas stream is produced from oxygen by subjecting oxygen to an electric discharge and the ozone is then adsorbed on to a solid adsorbent, such as zeolite, the oxygen containing stream leaving the adsorbent is recycled to the ozonising process. Periodically, oxygen adsorbed on the adsorbent is desorbed by co-currently passing a purge gas over the adsorbent and the desorbed oxygen is also recycled to the ozoniser. Lastly ozone is desorbed from the adsorbent by a counter-current flow of purge gas and used in an ozone demanding process.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: February 29, 2000
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Anthony K. J. Topham, Rodney J. Allam
  • Patent number: 5891344
    Abstract: A flow control apparatus for enriching gas containing oxygen with ozone includes a generator for producing the enriched mixture. A flow meter is connected to the generator outlet to measure the flow of the generated enriched gas. A mass flow control device is connected downstream of the flow meter. A flow control comparator compares a flow value as obtained from the measuring means and a preset constant value. A signal output of the flow control comparator is connected to a signal input of the mass flow control device for varying the mass flow in accordance with the comparison. An outlet of the mass flow control device is connected to an inlet of a compressor for compressing gas, the inlet gas pressure varying to keep compressed gas at a constant pressure. Feedback is provided between an outlet and an inlet of the compressor. A second mass control device is intermediately connected along the feedback connection for adjusting the mass flow of gas passing through the feedback means.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: April 6, 1999
    Assignee: Ozonia International
    Inventors: Pierre A. Liechti, Helmut Lang
  • Patent number: 5705468
    Abstract: A vehicle and method for storing ozone is disclosed. A vehicle made of a water miscible, organic compound of a glycol-containing chemical compound, a tertiary alcohol or a mixture thereof that is capable of receiving and containing ozone is disclosed. The method involves producing ozone gas, introducing the ozone-containing gas into a mixing vessel that contains the aforementioned organic compound, agitating the organic compound in the presence of the ozone-containing gas, wherein the ozone-containing gas is at atmospheric pressure or at a pressure of up to about 150 psig., and releasing the pressure if pressures in excess of atmospheric are used.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: January 6, 1998
    Assignee: Quantum Technologies, Inc.
    Inventors: Robert E. Yant, Marilyn M. Hurst, David B. Galluch
  • Patent number: 5478533
    Abstract: A water treatment apparatus is provided in which the ozone generation and the water treatment may take place simultaneously. The ozone is generated from a continuous supply of air and/or oxygen at the surface of a running water by means of a high voltage electrode placed in the air or in oxygen at some distance above the water surface. The strong electric field between the high voltage electrode and the surface of the electrically grounded water stream generates a multitude of small Taylor cones at the surface of the water. Each Taylor cone goes into corona and in the process it generates the ozone. As the ozone is generated at the water surface, a substantial amount of ozone is immediately dissolved in water and the ozone that diffuses in the air continues to be in contact with the water surface. The undissolved ozone may be percolated through the same water for an additional primary or secondary ozonation.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: December 26, 1995
    Assignee: Cleft Engineering Corporation
    Inventor: Ion I. Inculet
  • Patent number: 5407637
    Abstract: An apparatus and method for producing an antibiotic liquid. The apparatus includes an ion generator that produces negatively-charged molecules of the formula [MO.sub.x ].sup.-, where M is a positive ion, O is oxygen and x is a number at least equal to 3, and means for mixing a gas containing said molecules with a liquid such as water. Molecules [MO.sub.x ].sup.- are produced in a generator that comprises a specially shaped anode and cathode spaced apart from each other in a non-conducting housing. When a substantially constant voltage is applied across the anode and cathode, a plasma forms between and around them that in turn forms a magnetic field around the plasma and the anode. Diatomic oxygen molecules enter the housing and are polarized by the magnetic field and the resulting oxygen ions accelerated toward the plasma.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: April 18, 1995
    Assignee: Scientific Products Corporation
    Inventor: James W. Gibboney, Jr.