Zirconium Containing (e.g., Zirconate, Etc.) Patents (Class 423/594.12)
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Patent number: 7820586Abstract: The invention concerns a composition based on zirconium and cerium oxides in an atomic ratio Zr/Ce>1, and further comprising lanthanum oxide or an oxide of a rare earth other than cerium and lanthanum. The invention is characterized in that after calcination for 6 hours at 1150 .C it has a specific surface area of not less than 10 m;/g. The composition is obtained by forming a mixture containing a sol of a zirconium compound and cerium, lanthanum, said rare earth compounds, contacting said mixture with a basic compound solution, while heating and calcining the resulting precipitate. The composition can be used as catalyst.Type: GrantFiled: June 26, 2003Date of Patent: October 26, 2010Assignee: Rhodia OperationsInventor: Catherine Hedouin
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Patent number: 7806694Abstract: Dental articles are produced using relatively low sintering temperatures to achieve high density dental articles exhibiting strengths equal to and greater than about 700 MPa. Ceramic powders comprised of nanoparticulate crystallites are used to manufacture dental articles. The ceramic powders may include sintering agents, binders and other similar additives to aid in the processing of the ceramic powder into a dental article. The ceramic powders may be processed into dental articles using various methods including, but not limited to, injection molding, gel-casting, slip casting, or electroforming, hand, cad/camming and other various rapid prototyping methods. The ceramic powder may be formed into a suspension, pellet, feedstock material or a pre-sintered blank prior to forming into the dental article.Type: GrantFiled: June 24, 2009Date of Patent: October 5, 2010Assignee: Pentron Ceramics, Inc.Inventors: Dmitri Brodkin, Moisey Y. Gamarnik
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Patent number: 7794687Abstract: This invention relates to an improved amorphous zirconium hydroxide and a method for its production. The hydroxide has a surface area of at least 300 m2/g, a total pore volume of at least 0.70 cm3/g and an average pore size of between 5 nm and 15 nm, and is prepared by a process which comprises the steps of: a) preparing an aqueous solution comprising sulphate anions and a zirconium salt such that the ZrO2:SO3 ratio is 1:0.40 to 1:0.52, (b) chilling the solution to below 25° C., (c) adding an alkali in order to precipitate the amorphous zirconium hydroxide, (d) filtering and washing the precipitated zirconium hydroxide with water or an alkali to remove residual sulphate and chloride, (e) hydrothermally treating the zirconium hydroxide at a pressure of less than 3 barg, and (f) drying the zirconium hydroxide. The zirconium hydroxide of the present invention, which can be doped, is particularly useful in catalytic applications.Type: GrantFiled: January 24, 2007Date of Patent: September 14, 2010Assignee: Magnesium Elektron LimitedInventors: Heather Bradshaw, Clive Butler, Hazel Stephenson
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Patent number: 7780943Abstract: A compound oxide powder producing method for producing compound oxide powder made of at least two kinds of metals. A solution, in which a first metal compound for producing, when hydrolyzed, a hydroxide or oxide is dissolved in an organic solvent, and an emulsion, which contains another metal in the form of ions in an aqueous phase inside of inverse micelles formed by a surfactant in an organic solvent, are individually mixed in flowing states. The mixed liquid is stirred while being continuously caused to flow to the downstream side of a mixing portion of the first solution and the emulsion. Primary particles are formed by the hydrolysis of the first metal compound inside or in the interface of the inverse micelles whereas secondary particles are formed by the agglomeration of the primary particles.Type: GrantFiled: October 4, 2006Date of Patent: August 24, 2010Assignee: Toyota Jidosha Kabushiki KaishaInventor: Shinichi Takeshima
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Patent number: 7781365Abstract: The present invention provides a zirconia-based mixed oxide which, together with improving the heat resistance of specific surface area at a high temperature (1000° C. for 3 hours), has a ceria reduction rate of 80% or more, or in other words, improves the heat resistance of specific surface area and the reduction rate of ceria. The zirconia-based mixed oxide has zirconia for the main component thereof and contains 5% or more of ceria and 1 to 30% of a rare earth metal oxide other than ceria, wherein the specific surface area after heat treating for 3 hours at 1000° C. is 50 m2/g or more, the reduction rate of the ceria contained in the mixed oxide is 80% or more, and preferably the specific surface area after heat treating for 3 hours at 1100° C. is 20 m2/g or more.Type: GrantFiled: June 14, 2007Date of Patent: August 24, 2010Assignee: Daiichi Kigenso Kagaku Kogyo Co., Ltd.Inventor: Hiroshi Okamoto
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Patent number: 7759006Abstract: Disclosed is a compound represented by the following formula 1. A lithium secondary battery using the same compound as electrode active material, preferably as cathode active material, is also disclosed. LiMP1-xAxO4??[Formula 1] wherein M is a transition metal, A is an element having an oxidation number of +4 or less and 0<x<1. The electrode active material comprising a compound represented by the formula of LiMP1-xAxO4 shows excellent conductivity and charge/discharge capacity compared to LiMPO4.Type: GrantFiled: July 14, 2005Date of Patent: July 20, 2010Assignee: LG Chem, Ltd.Inventors: Sung Kyun Chang, Jeong Ju Cho
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Patent number: 7744847Abstract: A process for upgrading an inferior grade of zircon to a superior grade thereof includes mixing the inferior grade of zircon, in comminuted form, with at least one mineralizer, to obtain a zircon/mineralizer mixture, which is a calcined product. The calcined product is washed, and thereafter, in a comminution step, the washed calcined product is comminuted to obtain a superior grade of zircon, which is suitable for use as a glaze opacifier.Type: GrantFiled: May 24, 2005Date of Patent: June 29, 2010Assignee: The South African Nuclear Energy Corporation LimitedInventor: Ettienne Snyders
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Patent number: 7744845Abstract: A process is disclosed for the preparation of lithium zirconate and doped lithium zirconates for use as regenerable carbon dioxide sorbants by wet mixing zirconium hydroxide with lithium carbonate and then calcining the mixture. Due to the improved physical properties resulting from the disclosed preparation process, the lithium zirconates produced by this process are capable of absorbing carbon dioxide at high rates and in large amounts.Type: GrantFiled: August 25, 2006Date of Patent: June 29, 2010Assignee: Magnesium Elektron LimitedInventor: Hazel Stephenson
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Patent number: 7731933Abstract: An insulating target material for obtaining an insulating complex oxide film represented by a general formula AB1-XCXO3, an element A including at least Pb, an element B including at least one of Zr, Ti, V, W, and Hf, and an element C including at least one of Nb and Ta.Type: GrantFiled: August 29, 2006Date of Patent: June 8, 2010Assignee: Seiko Epson CorporationInventors: Takeshi Kijima, Takamitsu Higuchi
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Publication number: 20100135937Abstract: Nanocrystalline forms of metal oxides, including binary metal oxide, perovskite type metal oxides, and complex metal oxides, including doped metal oxides, are provided. Methods of preparation of the nanocrystals are also provided. The nanocrystals, including uncapped and uncoated metal oxide nanocrystals, can be dispersed in a liquid to provide dispersions that are stable and do not precipitate over a period of time ranging from hours to months. Methods of preparation of the dispersions, and methods of use of the dispersions in forming films, are likewise provided. The films can include an organic, inorganic, or mixed organic/inorganic matrix. The films can be substantially free of all organic materials. The films can be used as coatings, or can be used as dielectric layers in a variety of electronics applications, for example as a dielectric material for an ultracapacitor, which can include a mesoporous material. Or the films can be used as a high-K dielectric in organic field-effect transistors.Type: ApplicationFiled: September 24, 2009Publication date: June 3, 2010Applicant: The Trustees of Columbia University in the City of New YorkInventors: Stephen O'Brien, Limin Huang, Zhuoying Chen, Ioannis Kymissis, Zhang Jia
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Patent number: 7727322Abstract: A method for manufacturing a precursor solution for forming a PZTN compound oxide with Pb, Zr, Ti and Nb as constituent elements by a sol-gel method includes: a step of dissolving at least lead carboxylate with an organic solvent having an alkoxy group, to thereby form a first solution; a step of heat treating the first solution to remove crystallization water of the lead carboxylate and to form lead alkoxide by a ligand replacement reaction between the lead carboxylate and the organic solvent having the alkoxy group, to thereby form a second solution including the lead alkoxide; a step of mixing an alkoxide of a metal selected from at least one of Zr, Ti and Nb excluding Pb with the second solution, to thereby form a third solution including metal alkoxides of Pb, Zr, Ti and Nb, respectively; and a step of adding water to the third solution to cause hydrolysis-condensation of the metal alkoxides, to thereby form a fourth solution including a precursor of PZTN compound oxide.Type: GrantFiled: September 12, 2005Date of Patent: June 1, 2010Assignee: Seiko Epson CorporationInventor: Motohisa Noguchi
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Publication number: 20100129286Abstract: The present invention includes a method of making a plurality of nanoparticles comprising single crystalline spherical BaZrO3 particles, cubic BaZrO3 particles or a mixture of both. The method comprises: providing a mixture of a barium precursor, a zirconium precursor and a hydroxide salt or hydroxide salts; heating the mixture to an isothermic annealing temperature, wherein the annealing temperature is in a range of from about 470° C. to about 800° C.; annealing the mixture at the isothermic annealing temperature for an annealing time of in a range of about 15 minutes to about 280 minutes; and cooling the mixture at a fixed cooling rate to form the plurality of nanoparticles, wherein the cooling rate is in a range of from about 2° C./minute to about 200° C./minute.Type: ApplicationFiled: October 6, 2009Publication date: May 27, 2010Inventors: Stanislaus S. Wong, Hongjun Zhou
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Patent number: 7713504Abstract: A process to produce mixed metal oxides and metal oxide compounds. The process includes evaporating a feed solution that contains at least two metal salts to form an intermediate. The evaporation is conducted at a temperature above the boiling point of the feed solution but below the temperature where there is significant crystal growth or below the calcination temperature of the intermediate. The intermediate is calcined, optionally in the presence of an oxidizing agent, to form the desired oxides. The calcined material can be milled and dispersed to yield individual particles of controllable size and narrow size distribution.Type: GrantFiled: November 28, 2005Date of Patent: May 11, 2010Assignee: Altair Nanomaterials, Inc.Inventors: Bruce J. Sabacky, Timothy M. Spitler, Jan Prochazka
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Patent number: 7704483Abstract: A zirconia-containing composition and processes for synthesizing same. The composition comprises least about 99.9 percent tetragonal phase zirconia, based on the total crystalline zirconia in the zirconia-containing composition as determined by x-ray diffraction (XRD). The composition also has a substantially spherical morphology and comprises less than 100 wppm chlorine, based on the total weight of the zirconia-containing composition. The zirconia-containing composition has an average surface area of at least 80 m2/g and an average particle size of less than about 10 microns.Type: GrantFiled: April 29, 2005Date of Patent: April 27, 2010Assignee: Cabot CorporationInventors: Jian-Ping Shen, Qi Fu, Jian Zheng, Paolina Atanassova, Mark J. Hampden-Smith
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Patent number: 7700067Abstract: A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.Type: GrantFiled: February 22, 2008Date of Patent: April 20, 2010Assignee: NGK Insulators, Ltd.Inventors: Shohei Yokoyama, Nobuyuki Kobayashi, Tsutomu Nanataki
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Patent number: 7666526Abstract: Non-volatile resistance-switching oxide films, and devices therewith, are disclosed. One embodiment of a suitable device is composed of a SRO-CZO thin film having a thickness of from about 6 to about 30 nm, and composed of from about 3 to about 10 molar % of a SrRuO3 conducting oxide dopant and from about 90 to about 97 molar % of a CaZrO3 insulating oxide material.Type: GrantFiled: April 26, 2007Date of Patent: February 23, 2010Assignee: The Trustees of the University of PennsylvaniaInventors: I-Wei Chen, Yudi Wang, Soo Gil Kim
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Patent number: 7632477Abstract: This invention relates to a process for preparing zirconium oxide, in its various forms, including zirconium-based mixed oxides. There is described a process for preparing a zirconium oxide in the absence of a cerium salt which comprises precipitating a zirconium hydroxide from an aqueous solution of a zirconium salt by reaction with an alkali in the presence of a controlled amount of sulphate anions at a temperature not greater than 50° C. and then calcining the hydroxide to form an oxide, wherein the oxide thus formed is essentially sulphate free. Catalysts and ceramics can be produced from the product oxides having improved thermal stability and improved sinterability, respectively. A particular use of the product oxide is as a promoter or catalyst support in automobile exhaust systems.Type: GrantFiled: April 29, 2004Date of Patent: December 15, 2009Assignee: Magnesium Elektron, Ltd.Inventors: Yasuhide Takao, Colin Norman, Gavin Edwards, Ian Chisem, Clare Jones
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Publication number: 20090297421Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.Type: ApplicationFiled: May 29, 2009Publication date: December 3, 2009Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Shinichi Takeshima, Kohei Yoshida, Akio Koyama
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Patent number: 7625836Abstract: To provide a heat-resistant oxide which is excellent in heat resistance and durability at high temperature and has high activity, a heat-resistant oxide which has an oxide crystal structure and in which a rate of a solid solution of a noble metal in the oxide crystal structure is 50% or more is obtained by heat-treating (secondarily baking) a precursor composition comprising zirconia, at least one coordinative element selected from the group consisting of rare earth elements, alkaline earth elements, aluminum and silicon, and at least one noble metal selected from the group consisting of platinum, rhodium and palladium at 650° C. or higher.Type: GrantFiled: December 13, 2005Date of Patent: December 1, 2009Assignees: Cataler Corporation, Daihatsu Motor Co., Ltd.Inventors: Satoshi Matsueda, Mareo Kimura, Naoto Miyoshi, Yoshinori Ishii, Hirohisa Tanaka, Isao Tan, Mari Uenishi, Masashi Taniguchi
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Patent number: 7622426Abstract: The present invention is a method for producing a crystalline end-product. The method comprising exposing a fluoride-containing precursor to a hydrogen fluoride absorber under conditions suitable for the conversion of the precursor into the crystalline end-product.Type: GrantFiled: October 6, 2005Date of Patent: November 24, 2009Assignee: Brookhaven Science Associates, LLCInventors: Vyacheslav Solovyov, Harold Wiesmann
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Patent number: 7622411Abstract: There is provided a novel thermal barrier coating material which does not have a problem of phase transition, whose melting point is higher than its working temperature range, whose thermal conductivity is smaller than that of zirconia, and whose thermal expansion coefficient is greater than that of zirconia. The thermal barrier coating material comprises as a main component, a composition having an orthorhombic or monoclinic structure derived from perovskite (for example, a tabular perovskite structure expressed by the composition formula A2B2O7), or a tetragonal layer structure having a c axis/a axis ratio equal to or greater than 3 (for example, a K2NiF4 structure, a Sr3Ti2O7 structure, or a Sr4Ti3O10 structure), a composition expressed by the composition formula LaTaO4, or a composition having an olivine type structure expressed by the composition formula M2SiO4 or (MM?)2SiO4 (where M, M? are divalent metal elements).Type: GrantFiled: March 24, 2004Date of Patent: November 24, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsunori Akiyama, Ichiro Nagano, Masato Shida, Satoshi Ota
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Patent number: 7615201Abstract: By using a halogen-free siloxane and an organometallic compound containing at least one metal other than silicon as feed stocks, and simultaneously atomizing and burning them in a flame, spherical particles of silica-containing compound oxide are prepared which are substantially halogen-free, consist of 0.5-99% by weight of metal oxides and the balance of silica, and have a particle size of 10 nm to 3 ?m. The particles are useful as a filler in epoxy resin base semiconductor sealants, a refractive index modifier or the like.Type: GrantFiled: July 23, 2002Date of Patent: November 10, 2009Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshiharu Konya, Koichiro Watanabe, Susumu Ueno
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Patent number: 7604789Abstract: The present invention provides a porous composite oxide comprising an aggregate of secondary particles in the form of aggregates of primary particles of a composite oxide containing two or more types of metal elements, and having mesopores having a pore diameter of 2-100 nm between the secondary particles; wherein, the percentage of the mesopores between the secondary particles having a diameter of 10 nm or more is 10% or more of the total mesopore volume after firing for 5 hours at 600° C. in an oxygen atmosphere.Type: GrantFiled: May 19, 2004Date of Patent: October 20, 2009Assignee: Toyota Jidosha Kabushiki KaishaInventors: Shinichi Takeshima, Kohei Yoshida, Akio Koyama
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Patent number: 7595036Abstract: Novel, monodispersed, spherical ZrO2 particles in the size range of approximately 10 to approximately 600 nm exhibiting metastable tetragonal crystal structure at room temperature and novel methods of preparation. The ZrO2 particles are approximately 100% in the tetragonal phase at room temperature and can be pure and free of foreign oxides. The novel method can include mixing zirconium-alkoxide and an alcohol, forming preparation one, followed by separately dissolving completely de-ionized water and a polymeric steric stabilizer in an alcohol forming preparation two. Next the preparations can be mixed with vigorous stirring while subjecting the materials to hydrolysis and condensation reactions with very slow stirring. Next, there is waiting for the formation of a sol from the mixture, followed by drying at approximately 80 degrees C. to form resultant material followed by crushing the resultant material.Type: GrantFiled: January 15, 2009Date of Patent: September 29, 2009Assignee: University of Central Florida Research Foundation, Inc.Inventors: Sudipta Seal, Satyajit Shukla
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Patent number: 7582276Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.Type: GrantFiled: August 30, 2002Date of Patent: September 1, 2009Assignee: ITN Nanovation AGInventor: Ralph Nonninger
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Patent number: 7572748Abstract: A method for manufacturing barium zirconate particles includes providing a mixture of materials that includes barium, zirconium and a sintering aid, wherein the sintering aid includes at least one of barium tungstate, potassium niobate, tungsten oxide, barium molybdate, molybdenum oxide, potassium tantalate, potassium oxide, sodium niobate, sodium tantalate, sodium oxide, lithium niobate, lithium tantalate, lithium oxide, copper oxide, manganese oxide, zinc oxide, calcium zirconate and strontium zirconate; and heating the mixture of materials to produce barium zirconate particles that include the sintering aid.Type: GrantFiled: May 10, 2007Date of Patent: August 11, 2009Assignee: Skyworks Solutions, Inc.Inventors: Michael D. Hill, David Cruickshank, David Cronin, Barry Treadway
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Patent number: 7531690Abstract: A catalyst for the production of an oxygen-containing compound, comprising palladium, tungsten and zirconium, a production process thereof, and a production process of an oxygen-containing compound using the catalyst. The catalyst can provide an oxygen-containing compound from a lower olefin and oxygen with high productivity and high selectivity.Type: GrantFiled: March 28, 2005Date of Patent: May 12, 2009Assignee: Showa Denko K.K.Inventor: Toshio Okuhara
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Patent number: 7510693Abstract: Process for the production of a metal oxide powder having a BET surface area of at least 20 m2/g by reacting an aerosol with oxygen in a reaction space at a reaction temperature of more than 700° C. and then separating the resulting powder from gaseous substances in the reaction space, wherein the aerosol is obtained by atomisation using a multi-component nozzle of at least one starting material, as such in liquid form or in solution, and at least one atomising gas, the volume-related mean drop diameter D30 of the aerosol is from 30 to 100 ?m and the number of aerosol drops larger than 100 ?m is up to 10%, based on the total number of drops, and metal oxide powder obtainable by this process.Type: GrantFiled: January 30, 2006Date of Patent: March 31, 2009Assignee: Degussa AGInventors: Stipan Katusic, Michael Kraemer, Michael Kroell, Peter Kress, Edwin Staab
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Publication number: 20090068531Abstract: The present invention provides a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity in an alkaline form, and stably keeps high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state. The invention is useful in an electrochemical system using the solid electrolyte, such as a fuel cell. The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, and also a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a solution including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.Type: ApplicationFiled: July 1, 2008Publication date: March 12, 2009Inventors: Haruo SAWA, Haruyuki Nakanishi, Shinichi Matsumoto
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Publication number: 20090069586Abstract: To provide: a production method using a catalyst which can substantially suppress leaching of active metal components and exhibit high activity for both reactions of transesterification of glycerides and esterification of free fatty acids each contained in a fat or oil; and the catalyst.Type: ApplicationFiled: February 20, 2006Publication date: March 12, 2009Applicants: Nippon Shokubai Co., Ltd., Research Institute of Innovative Technology For the EarthInventors: Tomoharu Oku, Toshimitsu Moriguchi, Takeo Akatsuka, Masanori Nonoguchi
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Patent number: 7482382Abstract: The present invention is directed to novel sol-gel methods in which metal oxide precursor and an alcohol-based solution are mixed to form a reaction mixture that is then allowed to react to produce nanosized metal oxide particles. The methods of the present invention are more suitable for preparing nanosized metal oxide than are previously-described sol-gel methods. The present invention can provide for nanosized metal oxide particles more efficiently than the previously-described sol-gel methods by permitting higher concentrations of metal oxide precursor to be employed in the reaction mixture. The foregoing is provided by careful control of the pH conditions during synthesis and by ensuring that the pH is maintained at a value of about 7 or higher.Type: GrantFiled: May 19, 2004Date of Patent: January 27, 2009Assignees: The Texas A&M University System, Kaneka CorporationInventors: Yuntao Li, Hung-Jue Sue, Riichi Nishimura, Nobuo Miyatake
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Publication number: 20080308456Abstract: Oxidic composition consisting essentially of oxidic forms of a first metal, a second metal, and optionally a third metal, the first metal being either Ca or Ba and being present in the composition in an amount of from about 5 to about 80 wt %, the second metal being Al and being present in the composition in an amount of from about 5 to about 80 wt %, the third metal being selected from the group consisting of La, Ti, and Zr, and being present in an amount of from 0 to about 17 wt %—all weight percentages calculated as oxides and based on the weight of the oxidic composition, the oxidic composition being obtainable by (a) preparing a physical mixture comprising solid compounds of the first, the second, and the optional third metal, (b) optionally aging the physical mixture, without anionic clay being formed, and (c) calcining the mixture. This composition is suitable for use in FCC processes for the passivation of metals with only minimal influence on the zeolite's hydrothermal stability.Type: ApplicationFiled: June 2, 2006Publication date: December 18, 2008Applicant: ALBEMARLE NETHERLANDS B.V.Inventors: Dennis Stamires, Paul O'Connor, William Jones
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Publication number: 20080260623Abstract: A process for producing an inorganic doped-zircon pigment includes calcining a base mixture comprising raw plasma-dissociated zircon, a chromophore, and at least one mineralizer, to produce a raw pigment. The raw pigment is refined to obtain an inorganic doped-zircon pigment.Type: ApplicationFiled: April 26, 2005Publication date: October 23, 2008Inventor: Ettienne Snyders
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Publication number: 20080260624Abstract: The invention provides a process for production of a composition comprising a perovskite structure compound, the process comprising: a first process to heat a hydrous oxide of at least one B group element selected from the group consisting of Ti, Zr, Hf, and Sn at a temperature within a range of 80 to 300° C. in the presence of an aqueous medium so as to dehydrate the hydrous oxide; and a second process to heat a reaction product obtained in the first process and a hydroxide of at least one A group element selected from the group consisting of Ba, Sr, Ca, Mg and Pb at a temperature within a range of 100 to 300° C. in the presence of an aqueous medium. The process provides a composition comprising an ABO3 compound in the form of uniform and fine spherical particles which have an average particle diameter of 1 ?m or less, preferably within a range of 0.01 to 0.5 ?m, high crystallinity, and a controlled A/B ratio as desired, as well as few internal pores in the crystalline particles.Type: ApplicationFiled: February 25, 2005Publication date: October 23, 2008Applicant: Sakai Chemical Industry, Co., Ltd.Inventors: Yoshiaki Ikeda, Masami Kuwai, Shinji Ogama, Yukihiro Kuniyoshi, Kazuhisa Hidaka
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Patent number: 7438837Abstract: A method of producing a solid electrolyte (3, 13) is disclosed wherein solid electrolyte material is prepared having a composition expressed by a formula: (1-x) ZrO2 {xSc2O3 (where x is a number equal to or greater than 0.05 and equal to or less than 0.15), and a spark plasma method is carried out to sinter solid electrolyte material, resulting in a solid electrolyte. Such spark plasma method is executed by applying first compression load, equal to or less that 40 MPa, to solid electrolyte material, to sinter the solid electrolyte material to obtain sintered material, which is then cooled by applying second compression load, less than first compression load, to the sintered material, resulting in a solid electrolyte.Type: GrantFiled: March 19, 2004Date of Patent: October 21, 2008Assignees: Nissan Motor Co., Ltd., National Institute of Advanced Industrial Science and TechnologyInventors: Masaharu Hatano, Mitsugu Yamanaka, Makoto Uchiyama, Kenji Furuya, Yoshio Akimune, Masaya Okamoto
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Publication number: 20080247931Abstract: The preparation of finely divided, alkali metal-containing metal oxide powders which contain at least one alkali metal and at least one further metal from the group consisting of the transition metals, the remaining main group metals, the lanthanides and actinides is described. Precursor compounds of these components are introduced in solid form or in the form of a solution or a suspension into a pulsation reactor having a gas flow resulting from a flameless combustion and partly or completely converted into the desired multicomponent metal oxide powder.Type: ApplicationFiled: September 10, 2005Publication date: October 9, 2008Applicant: UMICORE AG & CO. KGInventors: Rainer Domesle, Stefan Ambrousius, Thomas Kreuzer
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Patent number: 7431910Abstract: A process for preparing zirconium-cerium-based mixed oxides which comprises reacting an alkali with an aqueous solution of a zirconium salt containing 0.42-0.7 mole of sulphate anion (SO42?) per mole of zirconium cation at a temperature of not greater than 50° C., in the presence of a cerium salt to form a cerium-zirconium mixed hydroxide, and then calcining the cerium—zirconium mixed hydroxide to form a mixed oxide. The mixed oxides possess good thermal stability and are essentially single phase and are suitable as promoters and catalyst supports in, particularly, automobile exhaust systems.Type: GrantFiled: October 30, 2002Date of Patent: October 7, 2008Assignee: Magnesium Elektron Ltd.Inventors: Yasuhide Takao, Colin Norman, Gavin Edwards, Ian Chisem
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Publication number: 20080226526Abstract: A process for the preparation of a nanoparticulate carbon dioxide acceptor. The acceptor is a mixed metal oxide having at least two metal ions X and Y. The process includes contacting in solution a precursor of an oxide of metal ion X and a precursor of an oxide of metal ion Y; drying said solution to form an amorphous solid; and calcining the amorphous solid to form the acceptor.Type: ApplicationFiled: April 18, 2006Publication date: September 18, 2008Applicant: NTNU TECHNOLOGY TRANSFER ASInventors: Magnus Ronning, Esther Ochoa-Fernandez, Tor Grande, De Chen
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Publication number: 20080226542Abstract: A process is disclosed for the preparation of lithium zirconate and doped lithium zirconates for use as regenerable carbon dioxide sorbants by wet mixing zirconium hydroxide with lithium carbonate and then calcining the mixture. Due to the improved physical properties resulting from the disclosed preparation process, the lithium zirconates produced by this process are capable of absorbing carbon dioxide at high rates and in large amounts.Type: ApplicationFiled: August 25, 2006Publication date: September 18, 2008Applicant: MAGNESIUM ELEKTRON LIMITEDInventor: Hazel Stephenson
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Publication number: 20080226528Abstract: The product of a molten alkali metal metalate phase separation can be processed into a purified metal from a metal source. Metal sources include native ores, recycled metal, metal alloys, impure metal stock, recycle materials, etc. The method uses a molten alkali metal metalate as a process medium or solvent in purifying or extracting high value metal or metal oxides from metal sources. Vitrification methods using the silicate glass separation phase can be prepared as is or can be prepared with a particulate phase distributed throughout the silica glass phase and encapsulated and fixed within the continuous glass phase. Tungsten metal can be obtained from an alkali metal tungstate. A typically finely divided tungsten metal powder can be obtained from a variety of tungsten sources including recycled tungsten scrap, tungsten carbide scrap, low grade tungsten ore typically comprising tungsten oxide or other form of tungsten in a variety of oxidation states.Type: ApplicationFiled: December 7, 2007Publication date: September 18, 2008Inventor: RODNEY KIETH WILLIAMS
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Publication number: 20080210902Abstract: Lattice doped stoichiometric-nanostructured materials having a plurality of discrete nanocrystalline particles, which are at least 95% crystalline, and a dopant either substituted in at least one nanocrystalline particle crystal lattice or interstitially located between crystal lattices or crystal planes of the nanocrystalline particles.Type: ApplicationFiled: July 12, 2007Publication date: September 4, 2008Applicant: NANOPHASE TECHNOLOGIES CORPORATIONInventors: Dan Coy, Harry Sarkas, Robert Haines
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Publication number: 20080160433Abstract: A coatable inorganic material is provided, which is suitable for being coated on a substrate in the form of sol-gel solution and then being directly written with thermochemical mode by using a laser beam. The coatable inorganic material is an oxide, in which the chemical element constitution is more than one element selected from Te, Al, Zr, and Ti.Type: ApplicationFiled: February 16, 2007Publication date: July 3, 2008Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Chin-Tien Yang, Ming-Fang Hsu, Sheng-Li Chang, Tzuan-Ren Jeng
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Patent number: 7381394Abstract: Methods of producing a safe and hygienic method for industrially and efficiently producing a perovskite-type composite oxide are provided that can maintain the catalytic activity of a noble metal at a high level. Methods include preparing a precursor of the perovskite-type composite oxide by mixing organometal salts of elementary components of the perovskite-type composite oxide and heat treating the precursor. The precursor may be prepared by mixing all elementary components constituting the perovskite-type composite oxide, or by mixing one or more organometal salts of part of the elementary components with the other elementary components prepared as alkoxides, a coprecipitate of salts, or a citrate complex of the respective elements.Type: GrantFiled: July 3, 2003Date of Patent: June 3, 2008Assignees: Daihatsu Motor Co., Ltd., Hokko Chemical Industry Co. Ltd.Inventors: Hirohisa Tanaka, Kimiyoshi Kaneko
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Publication number: 20080124265Abstract: An anode in a Direct Carbon Fuel Cell (DCFC) operating in a temperature range between 500 and 1200 degrees Celsius is provided. The anode material has high catalytic activity and selectivity for carbon oxidation, sufficient oxygen non-stoichiometry, rapid oxygen chemical diffusion, wide thermodynamic stability window to withstand reducing environment, sufficient electronic conductivity and tolerance to sulfur and CO2 environments. The anode has doped ruthenate compositions A1?xA?xRuO3, AB1?yRuyO3, or A1?xA?xB1?yRuyO3. A and A? may be divalent, trivalent, or tetravalent cation, and B is a multivalent cation. A is among lanthanide series elements La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er or Yb, and dopant A? is from Group IIA, IIIB, or IVB elements. The doped ruthenates can also be a (AB1?yRuyO3) structure or an ordered Ruddlesden-Popper series ((A1?xAx?)n+1(B1?yRuy)nO3n+1) structure where n=1 or 2. The dopant B is among Group IVB, VB, VIB, VIII, IB, and IIB elements.Type: ApplicationFiled: October 16, 2007Publication date: May 29, 2008Inventor: Turgut M. Gur
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Patent number: 7368097Abstract: Process for preparing nanocrystalline lithium titanate spinels by reacting lithium hydroxide and a titanium alkoxide at elevated temperature in a reaction mixture which forms water of reaction.Type: GrantFiled: April 22, 2004Date of Patent: May 6, 2008Assignee: BASF AktiengesellschaftInventor: Hans-Josef Sterzel
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Patent number: 7357910Abstract: Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.Type: GrantFiled: July 15, 2002Date of Patent: April 15, 2008Assignee: Los Alamos National Security, LLCInventors: Jonathan Phillips, Daniel Mendoza, Chun-Ku Chen
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Patent number: 7326398Abstract: A method for preparation for mesoporous oxide comprising a non silica oxide having a hexagonal pore structure periodicity and an average maximum pore length of from 2 nm to 5 nm, characterized by comprising blending 0.003 mol to 0.01 mol of TaCl5, NbCl5 or a mixture thereof and Al isopropoxide comprising 10 g of an aliphatic linear alcohol and 1 g of a template compound to prepare a mixture for forming a sol solution, adding 5 mol to 35 mol (based on the metal compounds) of water or an aqueous inorganic acid solution to the mixture followed by hydrolysis and polycondensation to give a sol solution, transferring the sol into an oxygen containing atmosphere followed by again at 40° C. to 100° C. to form a gel, and then calcinating the gel in an oxygen containing atmosphere at 350° C. to 550° C.; and the mesoporous oxide obtained by the method.Type: GrantFiled: November 11, 2002Date of Patent: February 5, 2008Assignee: Japan Science and Technology AgencyInventors: Kazunari Domen, Junko Nomura, Tokumitsu Kato
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Publication number: 20080020925Abstract: The composition is based on zirconium oxide and at least one additive selected from zirconium oxide and at least one additive chosen from praseodymium, lanthanum or neodymium oxides, has a specific surface of at least 29 m 2/g after calcination at 1000° C. during a period of 10 hoursand is is obtained by a method wherein a mixture of zirconium compounds and additive is precipitated with a base; the medium thus obtained, containing a precipitate, is heated and a compound chosen from anionic surfactants, non-ionic surfactants, polyethylene glycols, carboxylic acids and the salts thereof and surfactants such as the ethoxylates of caroboxymethyl fatty alcohols is added to the compound and the precipitate is calcinated; the composition can be used as a catalyst.Type: ApplicationFiled: February 25, 2005Publication date: January 24, 2008Inventors: Olivier Larcher, Philippe Moissonnier, Emmanuel Rohart
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Patent number: 7314607Abstract: A meso porous transition metal oxide comprising one or more transition metal oxides, wherein the metal is selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Ru, Cd, In, Sn, Sb, Hf, Ta, W and Re, and the pore wall of the meso pore thereof has a crystalline structure; and a method for preparing the meso porous transition metal oxide, characterized as comprising a step of carrying out a secondary calcination at 600-800° C. for 10 minutes to 10 hours.Type: GrantFiled: November 24, 2000Date of Patent: January 1, 2008Assignee: Japan Science and Technology Corporation et al.Inventors: Kazunari Domen, Li Byonjin, Junko Nomura
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Patent number: 7271114Abstract: A ceramic powder having a perovskite structure is manufactured by synthesizing a ceramic powder by a dry synthesis process and then heat-treating the synthesized ceramic powder in a solution. The dry synthesis method includes a solid phase synthesis method, an oxalate method, a citric acid method and a gas phase synthesis method.Type: GrantFiled: March 24, 2004Date of Patent: September 18, 2007Assignee: Taiyo Yuden Co., Ltd.Inventors: Chie Kawamura, Atsushi Tanada, Hirokazu Chazono