Tin, Lead, Or Germanium Containing (e.g., Stannate, Plumbate, Etc.) Patents (Class 423/594.9)
  • Patent number: 7901657
    Abstract: The invention relates to amphiphilic, nanoscalar particles comprising lipophilic hydrolyzable groups on their surface. The invention also relates to methods for producing amphiphilic, nanoscalar particles and to compositions containing said particles.
    Type: Grant
    Filed: February 25, 2005
    Date of Patent: March 8, 2011
    Assignee: Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige GmbH
    Inventors: Ertugrul Arpac, Helmut Schmidt, Murat Akarsu
  • Publication number: 20110042712
    Abstract: The present disclosure provides a new type of gapless semiconductor material having electronic properties that can be characterized by an electronic band structure which comprises valence and conduction band portions VB1 and CB1, respectively, for a first electron spin polarisation, and valence and conducting band portions VB2 and CB2, respectively, for a second electron spin polarisation. The valence band portion VB1 has a first energy level and one of CB1 and CB2 have a second energy level that are positioned so that gapless electronic transitions are possible between VB1 and the one of CB1 and CB2, and wherein the gapless semiconductor material is arranged so that an energy bandgap is defined between VB2 and the other one of CB1 and CB2.
    Type: Application
    Filed: March 12, 2009
    Publication date: February 24, 2011
    Inventor: Xiaolin Wang
  • Publication number: 20110036269
    Abstract: Surface-modified agglomerate of indium tin oxohydrate with a proportion of indium of 80 to 98.9% by weight, of tin of 2 to 20% by weight and of carbon of 0.01 to 1% by weight. Process for preparing a surface-modified agglomerate of indium tin oxide, in which the surface-modified agglomerate of indium tin oxohydrate is dried under air at temperatures of more than 150° C. and less than 310° C., and is then calcined under reducing conditions. Surface-modified agglomerate of indium tin oxide obtainable by this process. Process for preparing a surface-modified powder of indium tin oxide and a dispersion thereof, in which the surface-modified agglomerate and one or more solvents are combined to give a mixture, the mixture is converted to a dispersion by means of a dispersing unit and liquid constituents are optionally removed from the dispersion in order to obtain a powder.
    Type: Application
    Filed: April 16, 2009
    Publication date: February 17, 2011
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Sven Hill, Willibald Wombacher, Katharina Dauth
  • Publication number: 20110015325
    Abstract: A polymer additive for improving the reheat characteristics of a polymer or polymeric composition comprises an inorganic material which is such that a 2.5 mm thick polyethylene terephthalate plaque incorporating the inorganic material has, when tested, an absorption ratio of less than 0.9, wherein the absorption ratio is either the ratio of A1/A2 or the ratio A1/A3, wherein: A1 is the maximum absorption between 400 nm and 550 nm; A2 is the maximum absorption between 700 to 1100 nm; A3 is the maximum absorption between 700 to 1600 nm. Preferred inorganic materials are titanium nitride, indium tin oxide and lanthanum hexaboride.
    Type: Application
    Filed: September 22, 2010
    Publication date: January 20, 2011
    Inventors: Anthony Jarvis, Mark Frost, Mark Rule
  • Patent number: 7867472
    Abstract: An insulating target material for obtaining a conductive complex oxide film represented by a general formula ABO3. The insulating target material includes: an oxide of an element A; an oxide of an element B; an oxide of an element X; and at least one of an Si compound and a Ge compound, the element A being at least one element selected from La, Ca, Sr, Mn, Ba, and Re, the element B being at least one element selected from Ti, V, Sr, Cr, Fe, Co, Ni, Cu, Ru, Ir, Pb, and Nd, and the element X being at least one element selected from Nb, Ta, and V.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: January 11, 2011
    Assignee: Seiko Epson Corporation
    Inventors: Koji Ohashi, Takeshi Kijima, Setsuya Iwashita
  • Patent number: 7867471
    Abstract: A process of producing a ceramic powder including providing a plurality of precursor materials in solution, wherein each of the plurality of precursor materials in solution further comprises at least one constituent ionic species of a ceramic powder, combining the plurality of precursor materials in solution with an onium dicarboxylate precipitant solution to cause co-precipitation of the ceramic powder precursor in a combined solution; and separating the ceramic powder precursor from the combined solution. The process may further include calcining the ceramic powder precursor.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: January 11, 2011
    Assignee: SACHEM, Inc.
    Inventor: Wilfred Wayne Wilson
  • Publication number: 20110002831
    Abstract: A sol-gel process for preparing a mixture of metal-oxide-metal compounds wherein at least one metal oxide precursor is subjected to a hydrolysis treatment to obtain one or more corresponding metal oxide hydroxides, the metal oxide hydroxides so obtained are subjected to a condensation treatment to form the metal-oxide-metal compounds, which process is carried out in the presence of an encapsulated catalyst, whereby the catalytically active species is released from the encapsulating unit by exposure to an external stimulus, and wherein the catalytically active species released after exposure to such external stimulus is capable of catalyzing the condensation of the metal-hydroxide groups that are present in the metal oxide hydroxides so obtained.
    Type: Application
    Filed: December 15, 2008
    Publication date: January 6, 2011
    Inventors: Nanning Joerg Arfsten, Pascal Jozef Paul Buskens, Jens Christoph Thies
  • Patent number: 7837781
    Abstract: A pigment of empirical composition (TiO2)a(ZnO)b(SnO)c(SnO2)d(RExOy)e(AEO)f(MuOv)g wherein RE is a metal from transition group 3 or a rare earth metal, AE is an alkaline earth metal, and M is any other metal, where a=0.8-3; b=0.5-1.3; c=0.5-1.3; d=0-0.5; e=0-0.3; f=0-0.3; and g=0-0.1, and e+f?0.01. Preferably RE is selected from the elements Y, La, Ce, and Pr. The pigments are used as colorants for coloring paints, inks, plastics, and rubber.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: November 23, 2010
    Assignee: BASF SE
    Inventors: Norbert Mronga, Kirill Bramnik
  • Patent number: 7820138
    Abstract: At least one basic precipitant selected from the group consisting of NaOH, KOH, NH4OH, NH3, NH4HCO3 and (NH4)2CO3 is added to an indium salt solution, which contains 0.1 to 3 M of indium, in an adding time of not longer than 24 hours, while the solution is maintained at a temperature of 5 to 95° C. until the equivalent of the basic precipitant reaches an equivalent of 0.5 to 3. Then, a precipitate obtained from the solution by a solid-liquid separation is dried and calcined at a temperature of 570 to 780° C. in an non-oxidizing atmosphere which contains ammonia gas and water vapor.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: October 26, 2010
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Makoto Watanabe, Tatsumi Inamura, Yoshio Moteki
  • Publication number: 20100266787
    Abstract: An oxide material including indium (In), tin (Sn), and metal element M, and including an ilmenite structure compound; a sputtering target composed thereof; a transparent conductive film formed by using such a sputtering target; and a transparent electrode composed of such a transparent conductive film.
    Type: Application
    Filed: September 15, 2006
    Publication date: October 21, 2010
    Inventors: Koki Yano, Kazuyoshi Inoue, Nobuo Tanaka, Tokie Tanaka
  • Publication number: 20100266485
    Abstract: A process comprises (a) combining (1) at least one base and (2) at least one metal carboxylate salt comprising (i) a metal cation selected from metal cations that form amphoteric metal oxides or oxyhydroxides and (ii) a lactate or thiolactate anion, or metal carboxylate salt precursors comprising (i) at least one metal salt comprising the metal cation and a non-interfering anion and (ii) lactic or thiolactic acid, a lactate or thiolactate salt of a non-interfering, non-metal cation, or a mixture thereof; and (b) allowing the base and the metal carboxylate salt or metal carboxylate salt precursors to react.
    Type: Application
    Filed: December 16, 2008
    Publication date: October 21, 2010
    Inventor: Timothy D. Dunbar
  • Patent number: 7799312
    Abstract: A method for manufacturing an indium tin oxide (ITO) target and methods for preparing indium oxide powder (In2O3) and tin oxide powder (SnO2). The method for manufacturing an ITO (indium tin oxide) target includes preparing an In2O3 powder having a surface area of about 10-18 m2/g and an average particle diameter of between about 40 to 80 nm; preparing a SnO2 powder having a surface area of about 8-15 m2/g and an average particle diameter of about 60-100 nm; molding a mixture of the In2O3 powder and the SnO2 powder; and sintering the mixture at atmospheric pressure under oxidation atmosphere. The ITO target is applicable for a high-quality, transparent electrode for a display, such as a liquid crystal display, electroluminescent display, or field emission display.
    Type: Grant
    Filed: May 29, 2007
    Date of Patent: September 21, 2010
    Assignee: Samsung Corning Precision Glass Co., Ltd.
    Inventors: Kyong-hwa Song, Sang-cheol Park, Jung-gyu Nam
  • Patent number: 7781491
    Abstract: A process of doping zero-valance double metals into a cationic exchange resin to increase reactive activity of zero-valance metals includes providing a cationic exchange resin to contact a first metal in the form of ions to reduce the first metal which then attaches to the cationic exchange resin; providing a second metal in the form of ions to contact and attach to the first metal; and reducing the second metal to zero valance and forming a carrier containing double metals. The cationic exchange resin is selected from a strong acidic ion exchange resin of which the ion exchange functional group is SO3Na and SO3H. The first metal is selected from the noble metal group: palladium, platinum and copper. The second metal is selected from the normal metals group, such as tin. The first metal and the second metal respectively have particle diameters ranging from 20 to 100 nm.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: August 24, 2010
    Inventors: Ya-Hsuan Liou, Shang-Lien Lo, Chin-Jung Lin
  • Publication number: 20100189636
    Abstract: Provided is an amorphous film comprised substantially of indium, tin, magnesium and oxygen, and containing tin at a ratio of 5 to 15% based on an atomicity ratio of Sn/(In+Sn+Mg) and magnesium at a ratio of 0.1 to 2.0% based on an atomicity ratio of Mg/(In+Sn+Mg) with remnant being indium and oxygen, and having a film resistivity of 0.4 m?cm or less as a result of crystallizing the film by annealing the film at a temperature of 260° C. or lower. An amorphous ITO thin film for use as a display electrode and the like in flat panel displays is obtained by way of sputter deposition without heating the substrate and without the need of adding water during the deposition. This amorphous ITO film has the property of being crystallized by annealing at 260° C. or lower, which is not such a high temperature, and having low resistivity after crystallization. Also provided are a method of producing the film and a sintered compact for producing the film.
    Type: Application
    Filed: June 13, 2008
    Publication date: July 29, 2010
    Applicant: NIPPON MINING & METALS CO., LTD.
    Inventors: Masakatsu Ikisawa, Masataka Yahagi
  • Patent number: 7759006
    Abstract: Disclosed is a compound represented by the following formula 1. A lithium secondary battery using the same compound as electrode active material, preferably as cathode active material, is also disclosed. LiMP1-xAxO4??[Formula 1] wherein M is a transition metal, A is an element having an oxidation number of +4 or less and 0<x<1. The electrode active material comprising a compound represented by the formula of LiMP1-xAxO4 shows excellent conductivity and charge/discharge capacity compared to LiMPO4.
    Type: Grant
    Filed: July 14, 2005
    Date of Patent: July 20, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Sung Kyun Chang, Jeong Ju Cho
  • Publication number: 20100135937
    Abstract: Nanocrystalline forms of metal oxides, including binary metal oxide, perovskite type metal oxides, and complex metal oxides, including doped metal oxides, are provided. Methods of preparation of the nanocrystals are also provided. The nanocrystals, including uncapped and uncoated metal oxide nanocrystals, can be dispersed in a liquid to provide dispersions that are stable and do not precipitate over a period of time ranging from hours to months. Methods of preparation of the dispersions, and methods of use of the dispersions in forming films, are likewise provided. The films can include an organic, inorganic, or mixed organic/inorganic matrix. The films can be substantially free of all organic materials. The films can be used as coatings, or can be used as dielectric layers in a variety of electronics applications, for example as a dielectric material for an ultracapacitor, which can include a mesoporous material. Or the films can be used as a high-K dielectric in organic field-effect transistors.
    Type: Application
    Filed: September 24, 2009
    Publication date: June 3, 2010
    Applicant: The Trustees of Columbia University in the City of New York
    Inventors: Stephen O'Brien, Limin Huang, Zhuoying Chen, Ioannis Kymissis, Zhang Jia
  • Publication number: 20100111803
    Abstract: Disclosed herein is a spinel article. The article comprises a spinel material, wherein the spinel material has a monomodal grain size distribution with average grain sizes of less than or equal to about 15 micrometers, and a biaxial flexural strength of greater than or equal to about 300 megapascals when measured by a ring-on-ring flexural test as per ASTM Standard C1499-08. Disclosed herein too is a spinel article manufactured by a method comprising calcining a spinel powder; milling the powder in a milling medium; granulating the powder; screening the powder to a mesh size of about 40 to about 200 mesh; pressing the powder to form an article; burning out organics from the article; sintering the article; and hot isostatically pressing the article.
    Type: Application
    Filed: November 6, 2008
    Publication date: May 6, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Milivoj Konstantin Brun, Anteneh Kebbede, Sean Michael Sweeney, Timothy James Yosenick
  • Patent number: 7700067
    Abstract: A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.
    Type: Grant
    Filed: February 22, 2008
    Date of Patent: April 20, 2010
    Assignee: NGK Insulators, Ltd.
    Inventors: Shohei Yokoyama, Nobuyuki Kobayashi, Tsutomu Nanataki
  • Patent number: 7691352
    Abstract: A new set of additives to be sued in the preparation of inorganic materials; especially of perovskite nature is proposed. The chemical compositions of the perovskites prepared in the presence of the mentioned additives are found to be more homogenous, leading to better catalytic behavior, including higher selectivity and yields as compared to catalysts of identical formulations prepared through the conventional method of using EDTA/citrate (or other organic additive) method.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: April 6, 2010
    Assignee: Research Institute of Petroleum Industry (RIPI)
    Inventors: Khodadad Nazari, Zahra Taheri, Naser Seyed Matin, Reza Ahmadi, Saeed Zarrinpashneh, Morteza Rezapour
  • Patent number: 7670585
    Abstract: Provided is a method for preparing an electroconductive mayenite type compound with good properties readily and stably at low cost without need for expensive facilities, a reaction at high temperature and for a long period of time, or complicated control of reaction. A method for preparing an electroconductive mayenite type compound comprises a step of subjecting a precursor to heat treatment, wherein the precursor contains Ca and/or Sr, and Al, a molar ratio of (a total of CaO and SrO:Al2O3) is from (12.6:6.4) to (11.7:7.3) as calculated as oxides, a total content of CaO, SrO and Al2O3 in the precursor is at least 50 mol %, and the precursor is a vitreous or crystalline material; and the method comprises a step of mixing the precursor with a reducing agent and performing the heat treatment of holding the mixture at 600-1,415° C. in an inert gas or vacuum atmosphere with an oxygen partial pressure of at most 10 Pa.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: March 2, 2010
    Assignees: Asahi Glass Company, Limited, Tokyo Institute of Technology
    Inventors: Hideo Hosono, Katsuro Hayashi, Sung Wng Kim, Masahiro Hirano, Satoru Narushima, Setsuro Ito
  • Patent number: 7632477
    Abstract: This invention relates to a process for preparing zirconium oxide, in its various forms, including zirconium-based mixed oxides. There is described a process for preparing a zirconium oxide in the absence of a cerium salt which comprises precipitating a zirconium hydroxide from an aqueous solution of a zirconium salt by reaction with an alkali in the presence of a controlled amount of sulphate anions at a temperature not greater than 50° C. and then calcining the hydroxide to form an oxide, wherein the oxide thus formed is essentially sulphate free. Catalysts and ceramics can be produced from the product oxides having improved thermal stability and improved sinterability, respectively. A particular use of the product oxide is as a promoter or catalyst support in automobile exhaust systems.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: December 15, 2009
    Assignee: Magnesium Elektron, Ltd.
    Inventors: Yasuhide Takao, Colin Norman, Gavin Edwards, Ian Chisem, Clare Jones
  • Publication number: 20090272437
    Abstract: A photovoltaic cell can include a transparent conductive layer including cadmium stannate.
    Type: Application
    Filed: May 1, 2009
    Publication date: November 5, 2009
    Applicant: First Solar, Inc.
    Inventors: Dale Roberts, John German, Keith J. Burrows, Benyamin Buller, Boil Pashmakov
  • Patent number: 7601661
    Abstract: The invention provides an indium oxide-tin oxide powder which can be produced at low cost and which can provide a high-density sputtering target having a prolonged target life, and a sputtering target employing the powder. The indium oxide-tin oxide powder containing an In—Sn oxide as a predominant component is characterized in that the oxide powder contains no compound oxide (In4Sn3O12) detectable through X-ray diffraction and has a SnO2 solid solution amount in In2O3 of 2.3 mass % or more, the SnO2 solid solution amount being calculated from the precipitated SnO2 content (mass %) obtained from the ratio between integral diffraction intensity attributed to In2O3 (222) and integral diffraction intensity attributed to SnO2 (110).
    Type: Grant
    Filed: December 24, 2004
    Date of Patent: October 13, 2009
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Seiichiro Takahashi, Hiroshi Watanabe
  • Patent number: 7582276
    Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: September 1, 2009
    Assignee: ITN Nanovation AG
    Inventor: Ralph Nonninger
  • Patent number: 7582222
    Abstract: An oxide semiconductor doped with a transition metal and exhibiting room-temperature ferromagnetism is disclosed. The transition metal-doped oxide semiconductor is preferably manufactured in powder form, and the transition metal is preferably evenly distributed throughout the oxide semiconductor. The preferred embodiments are iron-doped tin dioxide and cobalt-doped tin dioxide. Gases may be detected by passing them across a material and measuring the change in magnetic properties of the material; the preferred material is iron-doped tin dioxide.
    Type: Grant
    Filed: August 1, 2005
    Date of Patent: September 1, 2009
    Assignee: Boise State University
    Inventor: Alex Punnoose
  • Patent number: 7578455
    Abstract: A particulate material is ground more efficiently using a mixture of at least two different sizes of yttrium-stabilized zirconia balls. The method facilitates preparation of photocatalysts with high activity.
    Type: Grant
    Filed: August 9, 2004
    Date of Patent: August 25, 2009
    Assignee: General Motors Corporation
    Inventors: Jin D. Kim, Wei Li, Se H. Oh
  • Publication number: 20090208404
    Abstract: An alloy generating hydrogen easily and safely for a long time is obtained. The alloy is obtained by melting in a blast furnace a first metal composed of one or more metals of Al, Zn and Mg and a second metal composed of one or more metals of Ga, Cd, In, Sn, Sb, Hg, Pb and Bi; and then placing the alloy in a molten state in water to cool the alloy.
    Type: Application
    Filed: June 15, 2007
    Publication date: August 20, 2009
    Applicants: CENTRAL GLASS COMPANY, LIMITED
    Inventor: Isao Itoh
  • Publication number: 20090185971
    Abstract: A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.
    Type: Application
    Filed: February 22, 2008
    Publication date: July 23, 2009
    Applicant: NGK Insulators, Ltd.
    Inventors: Shohei Yokoyama, Nobuyuki Kobayashi, Tsutomu Nanataki
  • Publication number: 20090185412
    Abstract: A phase-change material and a memory unit using the phase-change material are provided. The phase-change material is in a single crystalline state and includes a compound of a metal oxide or nitroxide, wherein the metal is at least one selected from a group consisting of indium, gallium and germanium. The memory unit includes a substrate; at least a first contact electrode formed on the substrate; a dielectric layer disposed on the substrate and formed with an opening for a layer of the phase-change material to be formed therein; and at least a second contact electrode disposed on the dielectric layer. As the phase-change material is in a single crystalline state and of a great discrepancy between high and low resistance states, the memory unit using the phase-changed material can achieve a phase-change characteristic rapidly by pulse voltage and avert any incomplete reset while with a low critical power.
    Type: Application
    Filed: July 30, 2008
    Publication date: July 23, 2009
    Applicant: NATIONAL TAIWAN UNIVERSITY
    Inventors: Lung-Han Peng, Sung-Li Wang, Meng-Kuei Hsieh, Chien-Yu Chen
  • Publication number: 20090136757
    Abstract: A method of fractionating a dispersion of oxidic nanoparticles wherein at least one step of the method is a membrane crossflow filtration step, the flow of the dispersion over the membrane being brought about by means of driven rotating parts; and dispersions of oxidic nanoparticles that are obtainable by the method.
    Type: Application
    Filed: November 14, 2008
    Publication date: May 28, 2009
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Roland WURSCHE, Goetz Baumgarten, Wolfgang Lortz, Michael Kroell
  • Patent number: 7534528
    Abstract: An electrode material for an anode of a rechargeable lithium battery, containing a particulate comprising an amorphous Sn.A.X alloy with a substantially non-stoichiometric ratio composition. For said formula Sn.A.X , A indicates at least one kind of an element selected from a group consisting of transition metal elements, X indicates at least one kind of an element selected from a group consisting of O, F, N, Mg, Ba, Sr, Ca, La, Ce, Si, Ge, C, P, B, Pb, Bi, Sb, Al, Ga, In, Tl, Zn, Be, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, As, Se, Te, Li and S, where the element X is not always necessary to be contained. The content of the constituent element Sn of the amorphous Sn.A.X alloy is Sn/(Sn+A+X)=20 to 80 atomic %.
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: May 19, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Soichiro Kawakami, Masaya Asao
  • Patent number: 7510693
    Abstract: Process for the production of a metal oxide powder having a BET surface area of at least 20 m2/g by reacting an aerosol with oxygen in a reaction space at a reaction temperature of more than 700° C. and then separating the resulting powder from gaseous substances in the reaction space, wherein the aerosol is obtained by atomisation using a multi-component nozzle of at least one starting material, as such in liquid form or in solution, and at least one atomising gas, the volume-related mean drop diameter D30 of the aerosol is from 30 to 100 ?m and the number of aerosol drops larger than 100 ?m is up to 10%, based on the total number of drops, and metal oxide powder obtainable by this process.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: March 31, 2009
    Assignee: Degussa AG
    Inventors: Stipan Katusic, Michael Kraemer, Michael Kroell, Peter Kress, Edwin Staab
  • Patent number: 7504351
    Abstract: Provided are an ITO sputtering target wherein the number of particles having a grain diameter of 100 nm or greater exposed in the ITO sputtering target as a result of royal water etching or sputter etching is 1 particle/?m2, and an ITO sputtering target having a density of 7.12 g/cm3 or greater capable of improving the sputtering performance, in particular inhibiting the generation of arcing, suppressing the generation of defects in the ITO film caused by such arcing, and thereby effectively inhibiting the deterioration of the ITO film.
    Type: Grant
    Filed: August 4, 2004
    Date of Patent: March 17, 2009
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventor: Toshiya Kurihara
  • Publication number: 20080299035
    Abstract: A method for recycling a used sputtering target is provided, including the steps of: (1) cleaning, (2) pulverization, (3) dissolution, (4) filtering, (5) peptization, (6) neutralization and precipitation, (7) rinsing and filtering, (8) drying, and (9) calcination; through the steps above, which can then be recycling used sputtering target to recover the constituent components of the ITO targets.
    Type: Application
    Filed: May 30, 2007
    Publication date: December 4, 2008
    Inventors: Hsin-Chun Lu, Chih-Ming Hsieh, Yi-Chieh Chen, Cherng-Yuan Shiao, Kuo-Shu Hsu, Nai-Sheng Syu
  • Patent number: 7449235
    Abstract: An aqueous alkaline solution containing a tin salt dissolved therein is mixed with a zinc compound, and an aqueous solution of an indium salt is added to the mixture. The resultant hydroxide or hydrate containing tin, indium and zinc is treated by heating at a temperature of 110 to 300° C. in the present of water. Then, the resultant product is filtered, dried and treated by heating at a temperature of 300 to 1,000° C. in an air and further reduced at a temperature of 150 to 400° C. under a reducing atmosphere to obtain composite indium oxide particles of zinc oxide and tin-containing indium oxide, which have an average particle size of 5 to 100 nm. The resultant composite particles of zinc oxide and tin-containing indium oxide are suitably used to form a transparent conductive coating film having a UV-shielding effect.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: November 11, 2008
    Assignee: Hitachi Maxell, Ltd.
    Inventors: Yuko Sawaki, Mikio Kishimoto
  • Publication number: 20080272682
    Abstract: The invention relates to a discharge lamp having a thin film indium oxide coating on the interior lamp envelope surface that effectively reflects UV, near IR and microwave radiation while transmitting light in the visible spectrum, the lamp being a high temperature operating lamp.
    Type: Application
    Filed: May 1, 2007
    Publication date: November 6, 2008
    Inventors: Deeder Aurongzeb, Philip Ellis
  • Patent number: 7442668
    Abstract: An object is to provide a sulfated tin oxide catalyst with strong catalytic activity, and a method for preparation thereof. It was discovered that in the preparation of a solid acid catalyst containing tin, stronger solid acid properties than before could be achieved by preparing a support comprising a crystalline tin oxide, preferably metastannic acid, bringing this support into contact with organic acid ions, then bringing it into contact with a sulfate group-containing compound, and then calcining it. The solid acid catalyst of the present invention has a tin content of 30% or more by weight as metal in the catalyst, a sulfate group supported thereon and an argon adsorption heat of more than 30 kJ/mol, and is used in acid-catalytic reactions.
    Type: Grant
    Filed: April 21, 2004
    Date of Patent: October 28, 2008
    Assignee: Japan Energy Corporation
    Inventor: Satoshi Furuta
  • Publication number: 20080260622
    Abstract: A method of preparing indium tin oxide (ITO) and such an oxide per se are described. The method utilises a cryogenic process wherein an aqueous formulation of indium sulphate, ammonium sulphate and a tin compound, optionally in the presence of an organic polymer, are frozen to produce a solid; the solid is conditioned by heating it to cause crystallisation of water in the solid; the water is removed for example by freeze drying; and the solid is then calcined. The ITO produced may have a surface tin concentration of less than 2 and other desirable properties.
    Type: Application
    Filed: May 24, 2005
    Publication date: October 23, 2008
    Applicant: Imperial Chemical Industries Pic
    Inventor: Derek A. Graham
  • Publication number: 20080233033
    Abstract: This invention relates to a Polyoxometalate (POM) represented by the formula: (An)m+[HqM16X8W48O184(OH)32]m? or solvates thereof, wherein: A represents a cation, n is the number of the cations A, m is the charge of the polyoxoanion, q is the number of protons and varies from 0 to 12, M represents a transition metal, and X represents a heteroatom selected from P, As and mixtures thereof. This invention also relates to a process to produce such POMs and to a process for the homogeneous or heterogeneous oxidation of organic substrates comprising contacting the organic substrate with such POMs.
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventors: Ulrich Kortz, Sib Sankar Mal
  • Publication number: 20080226528
    Abstract: The product of a molten alkali metal metalate phase separation can be processed into a purified metal from a metal source. Metal sources include native ores, recycled metal, metal alloys, impure metal stock, recycle materials, etc. The method uses a molten alkali metal metalate as a process medium or solvent in purifying or extracting high value metal or metal oxides from metal sources. Vitrification methods using the silicate glass separation phase can be prepared as is or can be prepared with a particulate phase distributed throughout the silica glass phase and encapsulated and fixed within the continuous glass phase. Tungsten metal can be obtained from an alkali metal tungstate. A typically finely divided tungsten metal powder can be obtained from a variety of tungsten sources including recycled tungsten scrap, tungsten carbide scrap, low grade tungsten ore typically comprising tungsten oxide or other form of tungsten in a variety of oxidation states.
    Type: Application
    Filed: December 7, 2007
    Publication date: September 18, 2008
    Inventor: RODNEY KIETH WILLIAMS
  • Publication number: 20080210902
    Abstract: Lattice doped stoichiometric-nanostructured materials having a plurality of discrete nanocrystalline particles, which are at least 95% crystalline, and a dopant either substituted in at least one nanocrystalline particle crystal lattice or interstitially located between crystal lattices or crystal planes of the nanocrystalline particles.
    Type: Application
    Filed: July 12, 2007
    Publication date: September 4, 2008
    Applicant: NANOPHASE TECHNOLOGIES CORPORATION
    Inventors: Dan Coy, Harry Sarkas, Robert Haines
  • Publication number: 20080163994
    Abstract: The present invention relates to a security feature for security papers, value documents and the like having an acid-labile feature substance as the core and a shell consisting substantially of metal oxide, the security feature exhibiting greater stability against the action of acids compared with the acid-labile feature substance.
    Type: Application
    Filed: December 15, 2005
    Publication date: July 10, 2008
    Inventors: Rainer Hoppe, Thomas Giering
  • Publication number: 20080166289
    Abstract: Surface-modified indium-tin oxides are produced by mixing the oxides with the surface-modifying agent in liquid or vapour form and heat treating the mixture. They can be used to produce coating systems.
    Type: Application
    Filed: October 29, 2005
    Publication date: July 10, 2008
    Applicant: DEGUSSA AG
    Inventors: Jürgen Meyer, Günther Michael
  • Publication number: 20080124265
    Abstract: An anode in a Direct Carbon Fuel Cell (DCFC) operating in a temperature range between 500 and 1200 degrees Celsius is provided. The anode material has high catalytic activity and selectivity for carbon oxidation, sufficient oxygen non-stoichiometry, rapid oxygen chemical diffusion, wide thermodynamic stability window to withstand reducing environment, sufficient electronic conductivity and tolerance to sulfur and CO2 environments. The anode has doped ruthenate compositions A1?xA?xRuO3, AB1?yRuyO3, or A1?xA?xB1?yRuyO3. A and A? may be divalent, trivalent, or tetravalent cation, and B is a multivalent cation. A is among lanthanide series elements La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er or Yb, and dopant A? is from Group IIA, IIIB, or IVB elements. The doped ruthenates can also be a (AB1?yRuyO3) structure or an ordered Ruddlesden-Popper series ((A1?xAx?)n+1(B1?yRuy)nO3n+1) structure where n=1 or 2. The dopant B is among Group IVB, VB, VIB, VIII, IB, and IIB elements.
    Type: Application
    Filed: October 16, 2007
    Publication date: May 29, 2008
    Inventor: Turgut M. Gur
  • Patent number: 7357910
    Abstract: Method for producing metal oxide nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone into metal vapor. The metal vapor is directed away from the hot zone and into the cooler plasma afterglow where it oxidizes, cools and condenses to form solid metal oxide nanoparticles.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: April 15, 2008
    Assignee: Los Alamos National Security, LLC
    Inventors: Jonathan Phillips, Daniel Mendoza, Chun-Ku Chen
  • Patent number: 7354565
    Abstract: The present invention discloses a relaxor material lead iron tungstate which has been synthesized in doped and undoped conditions by single and two step heat treatment. The relaxor material is seen to exhibit almost negligible hysteresis and a transducer made thereby shows pressure measurement capability over a wide range from 0.5 MPa to 415 MPa with accuracy of ±0.05%.
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: April 8, 2008
    Assignees: Council of Scientific & Industrial Research, Indian Institute of Technology - Delhi
    Inventors: Kamlesh Kumar Jain, Vinay Kumar, Subhash Chand Kashyap
  • Patent number: 7338647
    Abstract: The present invention relates to a method for preparing an electroactive metal polyanion or a mixed metal polyanion comprising forming a slurry comprising a polymeric material, a solvent, a polyanion source or alkali metal polyanion source and at least one metal ion source; heating said slurry at a temperature and for a time sufficient to remove the solvent and form an essentially dried mixture; and heating said mixture at a temperature and for a time sufficient to produce an electroactive metal polyanion or electroactive mixed metal polyanion.
    Type: Grant
    Filed: May 20, 2004
    Date of Patent: March 4, 2008
    Assignee: Valence Technology, Inc.
    Inventors: Biying Huang, Jeffrey Swoyer, M. Yazid Saidi, Haitao Huang
  • Publication number: 20080020236
    Abstract: Provided are an alkaline earth metal silicate-based phosphor which is a compound represented by Formula 1 below, and a white light-emitting device (LED) including the same. (M11-x-yAxBy)aMgbM2cOdZeFormula 1 wherein, M1 is one selected from the group consisting of Ba, Ca, and Sr; M2 is at least one selected from Si or Ge; A and B are each independently one selected from the group consisting of Eu, Ce, Mn, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Bi, Sn, and Sb; Z is at least one selected from the group consisting of a monovalent or divalent element, H, and N; and 0<x<1, 0?y?1, 6.3<a<7.7, 0.9<b<1.1, 3.6<c<4.4, 14.4<d<17.6, 14.4<d+e<17.6, and 0?e?0.18. The alkaline earth metal silicate-based phosphor has a broad excitation wavelength range, and thus, both a UV-LED and a blue LED can be used as excitation sources for white LEDs.
    Type: Application
    Filed: March 19, 2007
    Publication date: January 24, 2008
    Applicant: SAMSUNG ELECTRONICS CO., LTD.
    Inventors: Kubota Shunichi, Young-sic KIM, Seoung-jae IM
  • Publication number: 20080003161
    Abstract: A method of manufacturing a complex metal oxide powder, the method including: preparing a raw material composition for forming a complex metal oxide; mixing an oxidizing solution including an oxidizing substance into the raw material composition to produce complex metal oxide particles to obtain a liquid dispersion of the particles; and separating the particles from the liquid dispersion to obtain a complex metal oxide powder. The complex metal oxide is shown by a general formula AB1-xCxO3, an element A including at least Pb, an element B including at least one of Zr, Ti, V, W, and Hf, and an element C including at least one of Nb and Ta.
    Type: Application
    Filed: June 26, 2007
    Publication date: January 3, 2008
    Inventors: Takeshi Kijima, Hidemichi Furihata, Setsuya Iwashita, Satoshi Kimura, Toshihiko Kaneda
  • Patent number: 7297322
    Abstract: A process for producing powders of metal compound containing oxygen including the steps of: feeding at least one material selected from a liquid material and a solution material obtained by dissolving solid ingredient in organic solvent via a liquid flow controller into a vaporizer; vaporizing the materials in the vaporizer; adding oxygen; heating; cooling; and crystallizing. Also disclosed is the product formed by this process, and apparatus used in performing the process. The process and the apparatus enable easily mass-producing fine powders of metal compound containing oxygen used as materials for optical crystals, nonlinear crystals or magneto-optical crystals with reasonable production cost.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: November 20, 2007
    Assignee: Japan Pionics Co., Ltd.
    Inventors: Yukichi Takamatsu, Koji Kiriyama, Akira Asano, Takafumi Ishii