Aerosol Hair Preparation Patents (Class 424/DIG1)
  • Patent number: 4638822
    Abstract: The invention relates to a hair-setting process which consists of applying to the hair, in a first stage, at least one cationic polymer and at least one anionic polymer in a solvent medium, then drying the hair thus treated, and wetting or rinsing the dried hair immediately after drying with an aqueous composition and setting and drying the hair.
    Type: Grant
    Filed: July 21, 1983
    Date of Patent: January 27, 1987
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Claire Fiquet, Chantal Fourcadier, Claude Dubief, Daniele Cauwet
  • Patent number: 4606913
    Abstract: An improved high-internal-phase emulsion having increased stability under conditions of long term storage at elevated temperatures and freeze-thaw conditions, methods for preparing and stabilizing said emulsions and cosmetic preparations based thereon are disclosed. The improvement comprises incorporating into said emulsion an amount sufficient to increase the stability of said emulsion of an electrolyte contained in the aqueous phase of the emulsion.
    Type: Grant
    Filed: December 14, 1979
    Date of Patent: August 19, 1986
    Assignee: Lever Brothers Company
    Inventors: Michael P. Aronson, Michael F. Petko
  • Patent number: 4600530
    Abstract: Corrosion inhibitor compositions comprising a mixture of a nitroalkane containing 1-3 carbon atoms and a tertiary C.sub.12-14 alkylammonium carboxylate selected from the group consisting of a C.sub.12-14 alkylammonium benzoate and a tertiary C.sub.12-14 alkylammonium-N-oleoyl sarcosinate. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.
    Type: Grant
    Filed: March 27, 1985
    Date of Patent: July 15, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Philip L. Bartlett
  • Patent number: 4597895
    Abstract: Corrosion inhibitor compositions comprising a mixture of a nitroalkane containing 1-3 carbon atoms and a cocoamide of diethanolamine. Such compositions are useful in inhibiting corrosion on the interior surfaces of tin-plated aerosol cans containing water-based aerosol formulations.
    Type: Grant
    Filed: December 6, 1984
    Date of Patent: July 1, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Philip L. Bartlett
  • Patent number: 4595585
    Abstract: A cosmetic composition contains a polycondensate having units of the formula ##STR1## wherein t is 0 or 1. When t=1, R.sub.1 and R'.sub.1 each independently represent linear or branched alkylene having 1-38 carbon atoms optionally interrupted by --CONH-- or --CO--; alkenyl or alkynyl having 2-18 carbon atoms; cycloalkylene having 5-6 carbon atoms; arylene or bis-arylene optionally substituted by alkyl or alkoxy; or a divalent radical of the formula, --CHR'--O--C.sub.2 H.sub.3 (R')--O].sub.n HCR'-- wherein n is 0-20 and R' represents hydrogen or methyl, and R.sub.2, R'.sub.2, R.sub.3 and R'.sub.3 each independently represent --COOR.sub.4, --CN, --CONH.sub.2 or --COCH.sub.3, wherein R.sub.4 represents hydrogen, linear or branched alkyl having 1-18 carbon atoms or cycloalkyl having 5-6 carbon atoms.
    Type: Grant
    Filed: April 17, 1984
    Date of Patent: June 17, 1986
    Assignee: L'Oreal
    Inventors: Christos Papantoniou, Jean Mondet, Claudine Lapoiriere ex. spouse Vandenbossche
  • Patent number: 4585577
    Abstract: Propellant gas compositions for aerosol products are disclosed consisting essentially of monochlorodifluoromethane, dimethyl ether and methylene chloride, said compositions having a vapor pressure of about 50 to 60 psig at 70.degree. F.
    Type: Grant
    Filed: December 12, 1983
    Date of Patent: April 29, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Philip L. Bartlett, John J. Daly, Jr., John D. Sterling, Jr.
  • Patent number: 4567040
    Abstract: A hair spray composition comprising an alcoholic solution of partially neutralized vinyl/maleic copolymer and an alkali metal borohydride or oxidizer stabilized against discoloration.
    Type: Grant
    Filed: January 30, 1985
    Date of Patent: January 28, 1986
    Assignee: Clairol Incorporated
    Inventors: Joseph J. Varco, Carl E. Williams
  • Patent number: 4567035
    Abstract: A low molecular weight hair spray resin containing a vinyl monomer having a ##STR1## electron withdrawing group and consisting essentially of alternating units of vinyl ester and an alkyl half ester maleate derived from an alternating vinyl ester/maleic anhydride copolymer. The resins of this invention are defined by the structure: ##STR2## wherein R and R.sub.1 are each independently alkyl having from 1 to 6 carbon atoms and n has a value between about 40 and 250, preferably 60 to 220.
    Type: Grant
    Filed: August 22, 1983
    Date of Patent: January 28, 1986
    Assignee: GAF Corporation
    Inventors: Burton H. Waxman, I. Sioun Lin
  • Patent number: 4559057
    Abstract: A process and composition for coloring human hair on the head with pigments that employ a dispersion of pigment or pigments in an aqueous alcoholic liquid medium that contains a cationic polymer that is compatible with the aqueous alcoholic medium.
    Type: Grant
    Filed: July 1, 1983
    Date of Patent: December 17, 1985
    Assignee: Clairol Incorporated
    Inventors: Herman Bogaty, Keith Brown, Norman P. Loveless, Leszek J. Wolfram
  • Patent number: 4556554
    Abstract: A cosmetic composition is provided for the removal ofsebum exudate from the skin. The composition comprises immobilzed enzymes in cosmetically acceptable vehicles for topical application. The immobilized enzymes are lipolytic lipases, proteolytic proteases and enzymes for the breakdown of sugar oligomers from glucoproteins in the skin exudates. The enzymes may be present individually or in any desired combination. The enzymes are immobilized in known manners by chemical and or physical means and are released from immobilization upon application to the skin.
    Type: Grant
    Filed: June 1, 1981
    Date of Patent: December 3, 1985
    Assignee: Germaine Monteil Cosmetiques Corp.
    Inventor: Luis C. Calvo
  • Patent number: 4552754
    Abstract: A hair cosmetic composition having a strong gelation-preventive property comprising about 0.1 to about 10% by weight of a certain quaternary ammonium salt, about 0.05 to about 3.0% by weight of a certain 1-hydroxy-2-pyridone salt, about 0.05 to about 20% by weight of a certain polyol derivative, and a cosmetically acceptable carrier.
    Type: Grant
    Filed: April 6, 1983
    Date of Patent: November 12, 1985
    Assignee: Lion Corporation
    Inventors: Kazuhiro Muramatsu, Yuuzi Watari, Masaru Tajima, Isamu Nakaju
  • Patent number: 4543202
    Abstract: Propellant gas compositions for aerosol products consisting essentially of monochlorodifluoromethane, dimethyl ether and 1-chloro-1,1-difluoroethane, said compositions having a vapor pressure of about 50 to 60 psig at 70.degree. F.
    Type: Grant
    Filed: March 23, 1984
    Date of Patent: September 24, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Philip L. Bartlett, John J. Daly, Jr., John D. Sterling, Jr.
  • Patent number: 4543249
    Abstract: Hair spray compositions, particularly non-aerosol compositions containing partially to fully neutralized copolymers of 70 to 90 percent methylmethacrylate and 10 to 30 percent methacrylic acid dissolved in aqueous alcohol containing up to 35 percent water.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: September 24, 1985
    Assignee: American Cyanamid Co.
    Inventor: Elliot Nelson
  • Patent number: 4536390
    Abstract: An aerosol hair treating composition which forms a relatively stable yet collapsible foam comprising 3 to 90% by weight propellent and 97 to 10% by weight of an aqueous intermediate of 0.25 to 5% by weight polymer, 0.25 to 2% quaternary ammonium compound and water.
    Type: Grant
    Filed: February 18, 1983
    Date of Patent: August 20, 1985
    Assignee: S. C. Johnson & Son, Inc.
    Inventor: Timothy J. Padden
  • Patent number: 4530829
    Abstract: Disclosed herein is a hair treatment which comprises the following two ingredients (A) and (B): (A) polyphenol compound . . . 0.001-5.0 wt % (B) chelating agent . . . 0.01-5.0 wt %. Also disclosed a hair treatment which comprises, in addition to the ingredients (A) and (B), the third ingredient (C): (C) At least one decomposition derivative of keratin material selected from the group consisting of (1) hydrolysates of keratin material, (2) alkali salts of decomposition products obtained by oxidation of keratin material, and (3) alkali salts of derivatives at the thiol groups of decomposition products obtained by reduction of keratin material . . . 0.05-10.0 wt %. The hair treatment according to this invention can prevent proteins from eluting from hair and restore appropriate degrees of resiliency and flexibility of the hair which have once been lost by treatments for beauty care.
    Type: Grant
    Filed: September 10, 1982
    Date of Patent: July 23, 1985
    Assignee: Kao Corporation
    Inventor: Yoshiaki Abe
  • Patent number: 4526781
    Abstract: Disclosed are cosmetic compositions for the hair, containing hydrogenated tallow N,N-dimethyl glycinate, in the form of aqueous, alcoholic or aqueous-alcoholic solutions.
    Type: Grant
    Filed: April 25, 1984
    Date of Patent: July 2, 1985
    Assignee: Revlon, Inc.
    Inventors: Marvin Goldberg, Arthur Brandon
  • Patent number: 4522808
    Abstract: Anti-sunburn compositions are provided which comprise, as active ingredient, at least one compound of the general formula: ##STR1## in which: R.sub.1 is selected from hydrogen, alkyl radicals containing 1 to about 12 carbon atoms and optionally branched carboxyalkyl radicals containing 1 to 4 carbon atoms;R.sub.2 is selected from hydrogen, alkoxy radicals containing 1 to 4 carbon atoms, at least one alkyl and carboxyalkyl radical containing 1 to 4 carbon atoms, and halogen atoms.R.sub.3 is selected from hydrogen, carboxyalkyl radicals containing 1 to 4 carbon atoms and --S--R.sub.8 radicals, each of R.sub.4, R.sub.5, R.sub.6 and R.sub.7 is independently selected from hydrogen, and alkyl, carboxyalkyl and alkoxy radicals containing 1 to 4 carbon atoms, provided that if R.sub.3 denotes hydrogen, at least one of the radicals R.sub.1 R.sub.2, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 is not hydrogen, in an amount of at least about 0.05% by weight based on the total weight of the composition.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: June 11, 1985
    Assignee: Societe Anonyme dite: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang, Alain Malaval
  • Patent number: 4520008
    Abstract: There is disclosed a hair setting lotion which comprises a predetermined amount of a polymeric compound for setting the hair and a propylene oxide and ethylene oxide adduct of a higher alcohol. The adduct is contained in an amount of 0.05-1.0 time the polymeric compound on the weight basis. In order to further improve the hair setting effect, squalane can be added in an amount of 0.05-2.0 times the polymeric compound on the weight basis.
    Type: Grant
    Filed: March 31, 1982
    Date of Patent: May 28, 1985
    Assignee: Kao Soap Co., Ltd.
    Inventors: Hiroshi Ando, Takeo Okumura
  • Patent number: 4504644
    Abstract: The invention describes a protein derivative which has a molecular weight of 500 to 50,000 and has been chemically modified by grafting onto the protein chain radicals which absorb ultraviolet radiation. Also described are a process for the preparation of this protein derivative and compositions, containing this derivative as the active substance, for treating and protecting the skin and hair against photochemical degradation.
    Type: Grant
    Filed: August 16, 1983
    Date of Patent: March 12, 1985
    Assignee: L'Oreal
    Inventors: Gerard Lang, Alain Malaval
  • Patent number: 4493823
    Abstract: This invention relates to topical cosmetic preparations. More particularly, this invention relates to a topical cosmetic preparation for the treatment of oily hair and seborrheic skin which comprises an effective amount of at least one compound of the formula ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3, any of which may be the same or different, each represent hydrogen, hydroxyl, or --OR.sub.4, where R.sub.4 is an alkyl of from 1 to 6 carbon atoms or a substituted or unsubstituted benzyl, or two of the groups R.sub.1, R.sub.2, and R.sub.3 represent methylenedioxy; X is a substituted or unsubstituted alkylene of from 1 to 3 carbon atoms; and Y is --COOH, --CN, --CONR.sub.5 R.sub.6, or --COOR.sub.7, where R.sub.5 and R.sub.6 each represent hydrogen, alkyl of from 1 to 6 carbon atoms, or substituted or unsubstituted aryl, or aralkyl, or together with the nitrogen atom R.sub.5 and R.sub.6 represent a heterocycle, and R.sub.7 is an alkyl of from 1 to 6 carbon atoms or a substituted or unsubstituted aralkyl.
    Type: Grant
    Filed: November 10, 1981
    Date of Patent: January 15, 1985
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hinrich Moller, Siegfried Wallat, Friedhelm Bartnik, Wolfgang Pittermann
  • Patent number: 4487760
    Abstract: Hair cosmetics comprising as its effective component .alpha.-mono(methyl-branched alkyl) glyceryl ether of the formulaR--OCH.sub.2 CH(OH)CH.sub.2 OHwherein R represents a methyl-branched saturated hydrocarbon group having 12-24 carbon atoms. The glyceryl ether is usually present in an amount of 0.5-30 wt % of the cosmetic composition.
    Type: Grant
    Filed: January 19, 1982
    Date of Patent: December 11, 1984
    Assignee: Kao Soap Co., Ltd.
    Inventors: Hiromi Yamamoto, Takeo Okumura
  • Patent number: 4456586
    Abstract: Non-ionic surface-active agents of the formula are disclosed: ##STR1## in which a=0 or 1, R denotes a C.sub.8 -C.sub.30 aliphatic or alicyclic radical, x+y totals a number from 1 to 10 and, in each unit, one of Z.sub.1 and Z.sub.2 denotes hydrogen and the other denotes the radical ##STR2## in which R.sub.1 denotes methyl or ethyl. These products can be prepared simply and are suitable for use in cosmetic or pharmaceutical compositions and in particular in cosmetic compositions for treating the hair or skin.
    Type: Grant
    Filed: October 23, 1981
    Date of Patent: June 26, 1984
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag, Rene Pierre
  • Patent number: 4445521
    Abstract: New compositions for the treatment of keratin material, in particular human hair, skin and nails are provided comprising a combination of a cationic polymer with an anionic polymer. Surprisingly the anionic polymer can be retained well on the hair, even after rinsing, when applied with the cationic polymer.
    Type: Grant
    Filed: August 22, 1980
    Date of Patent: May 1, 1984
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Claire Fiquet, Chantal Fourcadier, Claude Dubief, Daniele Cauwet
  • Patent number: 4444749
    Abstract: Cosmetic composition for human hair containing water-soluble polyamine derivatives of maleic anhydride/ethylenic polymers.
    Type: Grant
    Filed: December 29, 1978
    Date of Patent: April 24, 1984
    Inventor: Jean M. Rouet
  • Patent number: 4439417
    Abstract: A shampoo composition is provided which is of the type which comprises a shampoo base containing at least one anionic surface active agent and a decomposition derivative of keratin material. The decomposition derivative is one or more of (1) decomposition products obtained by oxidation of keratin materials and derivatives at a thiol group of decomposition products obtained by reduction of keratin material.
    Type: Grant
    Filed: October 29, 1981
    Date of Patent: March 27, 1984
    Assignee: Kao Soap Co., Ltd.
    Inventors: Kinjiro Matsunaga, Takeo Okumura, Sachio Naito, Rikio Tsushima
  • Patent number: 4436722
    Abstract: A hair rinse composition which comprises at least one cationic surface active agent and a decomposition derivative of a keratin material which have been dissolved or dispersed in a suitable solvent. The decomposition derivative is a member selected from hydrolysates of keratin material, alkali salts of decomposition products obtained by oxidation of keratin material, alkali salts of derivatives at a thiol group of decomposition products obtained by reduction of keratin material and a mixture thereof.
    Type: Grant
    Filed: October 29, 1981
    Date of Patent: March 13, 1984
    Assignee: Kao Soap Co., Ltd.
    Inventors: Kinjiro Matsunaga, Takeo Okumura, Sachio Naito, Rikio Tsushima
  • Patent number: 4422853
    Abstract: A quaternized polymer for use as a cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or -CH.sub.2 -CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is a divalent group selected from(1) o-, m- or p-xylylidene of the formula ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,(3) --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --,(4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --,(5) --(CH.sub.2).sub.n --S--S--(CH.sub.2 (.sub.n --,(6) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --,(7) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.
    Type: Grant
    Filed: June 26, 1980
    Date of Patent: December 27, 1983
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 4397836
    Abstract: A sprayable aerosol hair lacquer composition packaged under pressure in an aerosol container comprises a synthetic polymer for fixing the hair, an aliphatic alcohol and as an aerosol propellant a mixture of trifluoromonochloroethane and carbon dioxide and/or nitrous oxide.
    Type: Grant
    Filed: June 26, 1981
    Date of Patent: August 9, 1983
    Assignee: Societe Anonyme Dite: L'OREAL
    Inventors: Annie Madrange, Jean-Louis Refregier
  • Patent number: 4390522
    Abstract: A cosmetic composition for application to the hair, skin or nails comprises in a cosmetic vehicle selected from water, a lower alkanol or a dilute lower alkanol solution, 0.01 to 15 percent by weight of a cationic polymer having units of the formula ##STR1## said polymer having a molecular weight between 1,000 and 50,000. R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represent alkyl or hydroxyalkyl wherein the alkyl of each has 1-20 carbon atoms. A is alkylene, hydroxyalkylene, --(CH.sub.2).sub.n --Z--(CH.sub.2).sub.n -- wherein Z is oxygen and n is a whole number ranging from 2-10, or --EO).sub.m.sbsb.1 (DO.sub.m D.sub.1 wherein E is alkylene or hydroxyalkylene containing 1-5 carbon atoms, m.sub.1 is 0 or 1, m is 1-600 with the proviso that m is greater than 1 when m.sub.1 =0. D.sub.1 represents E when m.sub.1 =1 and D.sub.1 represents D when m.sub.1 =0. B represents --EO).sub.m.sbsb.1 (DO).sub.m D.sub.1 wherein E, D, D.sub.1, m and m.sub.1 are defined above X.sup..crclbar.
    Type: Grant
    Filed: December 17, 1980
    Date of Patent: June 28, 1983
    Assignee: Societe Anonyme dite: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang, Alain Malaval, Serge Forestier, Do Le Trung
  • Patent number: 4376114
    Abstract: The copolymer of N-vinyl pyrrolidone and a vinylic, allylic or methallylic ester of a cyclic .alpha.- or .beta.- carboxylic acid is employed as a cosmetic film forming resin in cosmetic compositions for the hair, including hair setting lotions and lacquers, hair rinses and shampoos.
    Type: Grant
    Filed: October 21, 1981
    Date of Patent: March 8, 1983
    Assignee: Societe Anonyme dite: L'Oreal
    Inventors: Bernard Jacquet, Christos Papantoniou, Guy Vanlerberghe, Jean Mondet
  • Patent number: 4344763
    Abstract: Reactive silicone hair setting compositions composed of isopropanol solutions containing at least one aminoalkylalkoxysilane and a titanate ester. Optional ingredients include hair conditioners and tetraalkoxysilanes. The compositions provide high set holding levels at high humidities.
    Type: Grant
    Filed: November 15, 1977
    Date of Patent: August 17, 1982
    Assignee: The Gillette Company
    Inventors: Eva Tolgyesi, Ann F. Bresak
  • Patent number: 4331656
    Abstract: A composition for treating oily hair or skin to reduce the oily appearance thereof comprises in an appropriate vehicle an active compound having the formula, ##STR1## wherein n is a whole number from 1-10 inclusive, p is 0, 1 or 2, and R.sub.1 is ##STR2## wherein R.sub.2 is ##STR3## or --CO.sub.2 H wherein R.sub.3 and R.sub.4 represent hydrogen, 2-hydroxy ethyl, 2-hydroxy propyl or 2,3-dihydroxy propyl; (iii) --(CH.sub.2 --CHR.sub.5) OH wherein R.sub.5 is hydrogen, methyl or hydroxy methyl; ##STR4## wherein R.sub.3 and R.sub.4 have the meanings given above; or (v) ##STR5## wherein q is 1 or 2 and A represents hydrogen, acyl, succinoyl, nictinoyl or thenoyl; with the proviso that p is other than 0 and n is other than 2-4 when R.sub.1 is (iv) or (v).
    Type: Grant
    Filed: January 21, 1980
    Date of Patent: May 25, 1982
    Assignee: L'Oreal
    Inventors: Claude Bouillon, Jean Maignan
  • Patent number: 4331167
    Abstract: A composition adapted for application to hair before the hair is wound upon curlers and treated for permanent waving thereof comprising:(a) at least one methylpolysiloxane having a boiling point in the range of 100.degree. to 190.degree. C. and/or at least one paraffin or isoparaffin having a boiling point in the range of 100.degree. to 190.degree. C.,(b) at least one cation active, non-capillary active compound, and(c) at least one ampholytic, capillary active imidazoline compound.
    Type: Grant
    Filed: February 7, 1980
    Date of Patent: May 25, 1982
    Assignee: Wella Aktiengesellschaft
    Inventor: Theodor Wajaroff
  • Patent number: 4283384
    Abstract: A cosmetic composition for application to the hair or skin comprises in an appropriate cosmetic vehicle at least one polymer produced by polymerizing an unsaturated monomer and a compound having at least one OH function, the said polymerization being carried out in an aqueous medium and in the presence of cerium ions.
    Type: Grant
    Filed: January 23, 1979
    Date of Patent: August 11, 1981
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Jean Mondet, Christos Papantoniou
  • Patent number: 4282203
    Abstract: A cosmetic composition comprises a cosmetically acceptable vehicle and at least one copolymer having units of a vinyl, allyl or methally ester of an .alpha.- or .beta.-cyclic carboxylic acid. A process for producing the said copolymer comprises reacting the monomeric constituents of the copolymer at a temperature between 45.degree.-100.degree. C. for a period ranging from 6 to 24 hours.
    Type: Grant
    Filed: October 16, 1979
    Date of Patent: August 4, 1981
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Christos Papantoniou, Guy Vanlerberghe, Claude Mahieu, Vahan Zorayan
  • Patent number: 4272511
    Abstract: This invention relates to cosmetic tetrapolymer or higher polymer compositions useful as lacquers and setting lotions.
    Type: Grant
    Filed: June 20, 1979
    Date of Patent: June 9, 1981
    Assignee: L'Oreal
    Inventors: Christos Papantoniou, Jean Mondet
  • Patent number: 4247410
    Abstract: An activated silicon-containing aluminum complex containing minor amounts of halogen, silicon, oxygen and hydrogen, the silicon being present in amounts of at least trace and having a hexagonal structure; the ratio of oxygen to hydrogen in the complex usually being 16:18. A process for making such complex comprises the steps of treating substantially pure aluminum with acid, then with mercury, then with a halogen acid again to form a slurry therein; said slurry is then applied under heat and low humidity to an aluminum material containing trace to about 2% by weight silicon to form a growth of powder thereon; this powder is then treated with a flow of hydrogen to form the complex which is capable of releasing oxygen and hydrogen from an oxygen and hydrogen-containing fluid.
    Type: Grant
    Filed: June 19, 1978
    Date of Patent: January 27, 1981
    Assignee: Humatec Resources, Inc.
    Inventor: Fred B. Bernat
  • Patent number: 4246181
    Abstract: A two-stage process for producing indoanilines includes oxidizing in a first stage a paraphenylene diamine to a quinone diimine and in a second stage condensing the said quinone diimine with a phenolic compound. The resulting indoanilines can be incorporated into a dye composition for keratinous fibers, especially, human hair.
    Type: Grant
    Filed: May 30, 1978
    Date of Patent: January 20, 1981
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 4243657
    Abstract: A hair cosmetic composition comprising a cosmetic base containing 0.5 to 40% by weight of a diol derivative having the formula (I): ##STR1## wherein X.sub.1 is R--or ##STR2## in which R is branched alkyl having 6 to 12 carbon atoms, X.sub.2 is --H or ##STR3## in which R is branched alkyl having 6 to 12 carbon atoms, R.sub.1 is H, CH.sub.3, C.sub.2 H.sub.5 or C.sub.3 H.sub.7, R.sub.2 is H, CH.sub.3, C.sub.2 H.sub.5 or OH, and n and m each is an integer of from 1 to 3,or a branched aliphatic alcohol having the formula (II): ##STR4## wherein R.sub.3 is linear or branched alkyl having 8 to 10 carbon atoms and R.sub.4 is linear or branched alkyl having 6 to 8 carbon atoms,said hair cosmetic composition also having incorporated therein from 0.5 to 10% of a methylpolysiloxane having the formula (III): ##STR5## wherein l is an integer of from 3 to 14.
    Type: Grant
    Filed: September 1, 1978
    Date of Patent: January 6, 1981
    Assignee: Kao Soap Co., Ltd.
    Inventors: Takeo Okumura, Atsuo Ishida, Shizuo Hayashi
  • Patent number: 4243548
    Abstract: The subject of the invention is a pressurised aerosol formulation, which is in the form of a mixture, to be sprayed as a cosmetic, room or medicinal spray, of a propellant gas and organic solvents, as the propellant, and also active compounds and solvents for the active compounds, wherein the improvement comprises that the mixture is in the form of a homogeneous solution and this contains at least 50 percent by weight, preferably at least 55 percent by weight, of non-combustible constituents--relative to the total weight of the mixture--and contains, as the propellant gases, carbon dioxide and dimethyl ether, and, as non-combustible constituents, at least water, carbon dioxide, methylene chloride and/or 1,1,1-trichloroethane. This pressurized aerosol formulation is during transport, on storage and in use a product of low accident risk for the indicated purpose.
    Type: Grant
    Filed: November 27, 1978
    Date of Patent: January 6, 1981
    Assignee: Hans Schwarzkopf GmbH
    Inventors: Dieter Heeb, Uwe Bergemann, Claus-Dieter Frenzel
  • Patent number: 4240450
    Abstract: New compositions for the treatment of keratin material, in particular human hair, skin and nails are provided comprising a combination of a cationic polymer with an anionic polymer. Surprisingly the anionic polymer can be retained well on the hair, even after rinsing, when applied with the cationic polymer.
    Type: Grant
    Filed: March 14, 1978
    Date of Patent: December 23, 1980
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Claire Fiquet, Chantal Fourcadier, Claude Dubief, Daniele Cauwet
  • Patent number: 4223009
    Abstract: Hair preparations containing a copolymer of about 99.5 to 45.1 mole percent vinyl pyrrolidone and about 0.5 to 4.9 mole percent diloweralkylaminoalkyl acrylate or methacrylate, and method of setting and conditioning hair therewith.
    Type: Grant
    Filed: June 10, 1977
    Date of Patent: September 16, 1980
    Assignee: GAF Corporation
    Inventor: Paritosh M. Chakrabarti
  • Patent number: 4221729
    Abstract: Indoaniline of the formula ##STR1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye compositions for keratinic fibers, especially living human hair.
    Type: Grant
    Filed: May 28, 1976
    Date of Patent: September 9, 1980
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 4217914
    Abstract: A quaternized polymer for use as a hair or skin cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing up to 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is(1) o-, m- or p-xylylidene of the formula ##STR2## ##STR3## wherein x, y and t are whole numbers ranging from 0 to 11 so the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,(3) --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --,(4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --,(5) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --,(6) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --,(7) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.
    Type: Grant
    Filed: November 8, 1977
    Date of Patent: August 19, 1980
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 4213960
    Abstract: The invention relates to cosmetic compositions for conditioning the hair, which contain polyaminoamides and quaternary ammonium homopolymers or compolymers.
    Type: Grant
    Filed: March 1, 1978
    Date of Patent: July 22, 1980
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Claire Fiquet, Chantal Fourcadier, Claude Dubief, Daniele Cauwet
  • Patent number: 4210755
    Abstract: Aminated .gamma.-dialdehyde and the quaternary ammonium salts thereof are prepared by acid hydrolysis of their respective corresponding 2,5-dialkoxy 3-amino 4-hydroxy tetrahydrofurans or by acid hydrolysis of their respective corresponding tetraalkyl acetals. The aminated .gamma.-dialdehydes and the quaternary ammonium salts thereof are usefully employed in cosmetic compositions to tan the skin or to strengthen or restructure the hair.
    Type: Grant
    Filed: July 10, 1978
    Date of Patent: July 1, 1980
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Georges Rosenbaum
  • Patent number: 4208402
    Abstract: A process for improving the appearance of oily hair or skin, including the scalp, comprises applying thereto an effective amount of an aqueous or hydroalcoholic solution of gelatin present in an amount of about 0.5 to 1.5 percent by weight thereof.
    Type: Grant
    Filed: January 10, 1977
    Date of Patent: June 17, 1980
    Assignee: L'Oreal
    Inventors: Pierre Bore, Lucienne Tourenq
  • Patent number: 4201235
    Abstract: Compositions comprising mixtures of certain amino acids and vitamins particularly useful in the formulation of topically-applicable cosmetic compositions. The topical application of the compositions acts to improve the general complexion of the skin and to invigorate and revitalize the hair and scalp. Separate formulations are provided for each use.
    Type: Grant
    Filed: January 3, 1978
    Date of Patent: May 6, 1980
    Assignee: Mare Corporation
    Inventor: Vitale G. Ciavatta
  • Patent number: 4199562
    Abstract: Sequenced oligomer surfactant has the formula: P--O----C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' [C.sub.2 H.sub.3 (CH.sub.2 A)O].sub.m --C.sub.2 H.sub.3 C.sub.2 B)O].sub.n Q wherein one of P and Q represents hydrogen and the other represents alkyl having 1-20 carbon atoms; A represents R--CH.sub.2 -- or R'--O-- wherein R is alkyl having 4-16 carbon atoms and R' is alkyl having 4-20 carbon atoms; B is selected from OH, R.sub.1 R.sub.2 N, R.sub.1 R.sub.2 N.fwdarw.O, R.sub.1 R.sub.2 N--O.sup..sym. HV.sup..crclbar., R.sub.1 R.sub.2 N.sup..sym. HV.sup..crclbar., R.sub.1 R.sub.2 R.sub.3 N.sup..sym. Z.sup..crclbar. and R.sub.4 S.fwdarw.(O)a, wherein R.sub.1 and R.sub.2 represent alkyl or hydroxyalkyl, R.sub.3 is methyl or ethyl, R.sub.4 is alkyl, hydroxyalkyl or dihydroxyalkyl, Z.sup..crclbar. is an anion selected from HSO.sub.3.sup..crclbar., CH.sub.3 SO.sub.3.sup..crclbar., CH.sub.3 SO.sub.4.sup. .crclbar. and CH.sub.3 --C.sub.6 H.sub.4 --SO.sub.3.sup..crclbar., R.sub.1 R.sub.2 N.sup..sym. HV.sup..crclbar. and R.sub.
    Type: Grant
    Filed: July 14, 1977
    Date of Patent: April 22, 1980
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag
  • Patent number: 4197865
    Abstract: A quaternized polymer having recurring units of the formula ##STR1## wherein X.sup..crclbar. represents an anion derived from an organic or mineral acid;R'.sub.2 is an aliphatic radical having a maximum of 20 carbon atoms;R'.sub.1 is an aliphatic, alicyclic or arylaliphatic radical containing a minimum of 2 carbon atoms and a maximum of 20 carbon atoms, or R'.sub.1 and R'.sub.
    Type: Grant
    Filed: April 24, 1978
    Date of Patent: April 15, 1980
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang