Abstract: Disclosed herein are a recording paper which is partially pressure-sensitized, comprising microcapsules containing a solution of a colorless color former, sheet material and binder, the microcapsules being fixed to a specified part of a surface of the sheet material via the binder painted on the specified part and majority of the fixed microcapsules having at least a part of the microcapsule exposed to outside of the binder, and a process for producing the recording paper which is partially specified.

Abstract: A thermosensitive recording paper consisting of a dye precursor and a color developer capable of coloring said dye precursor on heating, wherein one type of overcoat layer selected from the group consisting of alginates, alumina sol, colloidal silica and a mixture of alumina sol with colloidal silica is provided as the topmost layer thereof to give improved chemical resistance and good printing quality with a reduced deterioration in sensitivity and no residues and sticking.

Abstract: A heat-sensitive recording paper is described, comprising a support having formed thereon a heat-sensitive recording layer containing a colorless or pale-colored electron donating dye precursor and an electron accepting substance that reacts with said electron donating dye precursor to develop color, and an overlying protective layer containing a water-soluble polymeric binder and a pigment, wherein the back side of the support is provided with a backcoat layer containing an alkali salt of a styrene-maleic acid copolymer.

Abstract: Disclosed is a heat-sensitive recording material useful, for example, in the manufacture of labels used in connection with the sale of meat, produce, and the like. The material comprises a cellulosic or other suitable substrate, a thermally imprintable color producing layer and a water-insoluble protective layer over the color-producing layer. It may also include a second protective layer and/or a pressure-sensitive adhesive layer on the opposite side of the substrate from the color-producing layer, and a releasable liner covering the adhesive layer. The color-producing layer has a colorless or pale leuco dye, an acidic developer for producing upon imagewise heating of the recording material, a water-soluble, polymeric binder material, and a basic, acid-neutralizing agent for reducing background discoloration.

Abstract: A thermosensitive recording label includes a thermosensitive color-forming layer disposed on one side of a substrate and a heat reflecting layer disposed on another side of the substrate and a delayed action adhesive disposed on the heat reflecting layer. The thermosensitive recording label may be manufactured and used without a backing sheet, thus considerably reducing the weight and volume of the label. In use, the thermosensitive recording label is drawn from a roll or stack and the delayed action adhesive activated by a heat lamp, or the like, to place it in a tacky condition for placement on goods. The heat reflecting layer disposed between the delayed action adhesive and the thermosensitive color-forming layer prevents activation of the color-forming layer during heating of the delayed action adhesive.

Abstract: Heat-sensitive recording sheet comprising a heat-sensitive color developing layer having particular chemicals on the support sheet and an overcoat layer laminated thereon and a backcoat layer on the back of the support sheet, wherein the sheet provides excellent coloring characteristics and high stability in storage.

Abstract: A heat-sensitive recording paper is disclosed, comprising a base having thereon (a) a heat-sensitive color forming layer containing a substantially colorless electron donating dye and an acid substance capable of forming a coloration by coming into contact with said dye upon heating, wherein a coating layer containing a binder comprising modified polyvinyl alcohol containing silicon atoms in the molecule and at least one of colloidal silica and amorphous silica is provided on said color forming layer.

Abstract: A thermosensitive recording label includes a substrate, a thermosensitive color-forming layer disposed on one side of said substrate, a protective layer disposed on the thermosensitive color-forming layer, and electron beam setting printing ink disposed in a preselected pattern on the protective layer, a pressure-sensitive adhesive layer disposed on another side of the substrate and a releasing bold backing sheet disposed on the pressure-sensitive adhesive layer. A visible pattern is thereafter created by exposing the thermosensitive recording label to an electron beam to set, or cure the electron beam setting ink. The electron beam setting ink may be printed additionally on the substrate and the backing sheet to enable product coding information to be printed on the substrate as well as the printing of a manufacturer's logo on the backing sheet.

Abstract: A thermosensitive recording material which comprises a support material and a thermosensitive color-forming layer formed on the support material, comprising a colorless or light-colored leuco dye and a color developer capable of inducing color formation in the leuco dye upon application of heat thereto, is disclosed, in which the color developer is 4-hydroxydimethylphthalate or a first bisphenol derivative of the formula (I) ##STR1## wherein n is an integer of 1 or 2, and there is interposed between the support material and the thermosensitive color-forming layer an undercoated layer comprising a second bisphenol derivative of the formula (II), ##STR2## wherein X represents halogen, Y represents --SO.sub.2 --or-- ##STR3## m is an integer of 1 or 2, and the substitution positions of Xm in the benzene rings are symmetrical with respect to Y.

Abstract: A heat-sensitive recording material composed of a heat-sensitive, color-forming layer on a sheet substrate. The heat-sensitive, color-forming layer is mainly composed of a color-forming component consisting of a colorless or light-colored leucodye and an acidic compound for allowing said leucodye to develop color by heating, and further includes on the upper surface thereof a protective layer composed mainly of a polyvinyl alcohol and containing an epoxy compound having in its molecule at least two epoxy groups or an ethylenimine compound having in its molecule at least two ethylenimine groups.

Abstract: A colorless, heat-sensitive and heat transfer recording sheet with pressure sensitivity comprising a base sheet, a heat-sensitive recording layer provided on one side of the base sheet and a heat transfer recording layer provided on the other side of the base sheet, the heat transfer recording layer being formed by coating on the base sheet a coating color comprising 3 to 20 parts by weight of microcapsules containing a colorless, electron-donating color former, 3 to 30 parts by weight of microcapsules containing a colorless, electron-accepting color developer, 3 to 30 parts by weight of a solid of a colorless, electron-donating, color former, 10 to 50 parts by weight of a solid of a colorless, electron-accepting, color developer and 25 to 200 parts by weight of a wax.

Abstract: A heat-sensitive recording paper is described, comprising a paper support and a heat-sensitive color-forming layer on the paper support, wherein the paper support contains a cationic softening agent, such as a maleic anhydride copolymer/polyalkylenepolyamine reaction product. This recording paper is excellent both in highspeed recording and curling properties.

Abstract: A color-developing ink containing at least one color developer selected from the group consisting of phenolic resins, aromatic carboxylic acids and metal salts thereof as well as a higher chain ether having total carbon atoms of 10 to 40, has various advantages such as the density of the developed image is high, fading of the developed image with time is at a low level, blurring of the developed letters is also at a low level, there is no abnormal tinting by the developed image, there is no swell of rubber rolls of a printer, and printability on a printer is excellent.

Abstract: A low-profile transfer article having an adhesive layer, a coating of particles on one surface of the adhesive layer, and a graphic image formed of one or more layers of ink adherably bonded to the ink-receptive surface of the particles, the transfer article being free of a permanent self-supporting film support layer.

Abstract: A method for producing a reversible thermochromic display composed of multiple, overlapping color images. In accordance with the invention, a plurality of overlapping colored image layers are formed on a support, at least one of which layers provides a reversible thermochromic image. Each of the images on the various layers has a different visual density, and at least one reversible thermochromic image changes color at a temperature below or above a predetermined temperature and provides a color which is more intense and more easily discernible than the colors of the other ones of the images.

Abstract: A carbonless CFB paper includes an aqueous wax emulsion added to the CB coating to act as a barrier between the reactants in the CB coating and in the CF coating, thereby preventing precolor caused by reactants seeping into or penetrating the base paper and reacting with any ruptured capsules in the CB coating.

Abstract: This invention provides a multicolor record material comprising a plurality of color forming systems each containing a color forming material and a color developing material and adapted to produce different colors individually, the multicolor record material being characterized in that each of the systems contains a substance which absorbs an infrared beam of specified wavelength for causing the system to produce its color but which substantially does not absorb an infrared beam of different wavelength for causing another system to produce the color thereof.

Abstract: A heat-sensitive color transfer recording media comprising a continuous foundation and a multiplicity of coated areas of heat-sensitive transfer inks applied onto the foundation; the multiplicity of the coated areas being disposed on the continuous foundation side by side so as to traverse the continuous foundation; the multiplicity of the coated areas being arranged sequentially in the longitudinal direction of the continuous foundation in a repeating unit which comprises a plurality of different color coated areas; each of the different color coated areas included in the repeating unit having a length in the longitudinal direction of the continuous foundation substantially equal to the length or width of a copy sheet; each of the heat sensitive transfer ink layers of the coated areas being a transparent ink layer comprising a transparent coloring agent and a transparent hot-melt vehicle; and said plurality of the different color heat-sensitive transfer ink layers of the coated areas of the recording media b

Abstract: A transfer type heat-sensitive recording medium having a porous base impregnated with a colorless color former. A layer of thermally melting ink is formed on one side of the porous base. The first layer is brought into contact with a recording sheet. A layer of thermally melting wax containing a color developer is formed on the opposite side of said porous base and selectively heated according to a video signal. The wax melts and permeates into the porous base to allow the color developer to color on reaction with the colorless color former. The wax layer is further heated by thermal irradiating so that the ink of the ink layer is molten in correspondence to the coloring.

Abstract: Mono and bis substituted (arylsulfonyl)alkanes useful as color formers, particularly in carbonless duplicating and thermal marking systems, are prepared by the interaction of the appropriate aldehyde or dialdehyde with the appropriate aryl or heterocyclic moiety and the appropriate phenylsulfinic acid in the presence of a catalyst.

Abstract: This invention provides a heat-sensitive record material comprising a base sheet and a heat-sensitive record layer formed over the base sheet and containing a color forming material and a color developing material which undergoes a color forming reaction on contact with the color forming material, the heat-sensitive record material being characterized in that a resin coating layer cured with electron beam is formed over the heat-sensitive record layer; and also a heat-sensitive record material comprising a base sheet and a heat-sensitive record layer formed over the base sheet and containing a color forming material and a color developing material which undergoes a color forming reaction on contact with the color forming material, the heat-sensitive record material being characterized by a resin coating layer cured with electron beam, formed over the heat-sensitive record layer and containing about 5 to about 300 parts by weight of a pigment per 100 parts by weight of the resin.

Abstract: A barrier pigment is added to a fluorescent ribbon to prevent light from being absorbed into the media upon which the pigment is applied during printing. The barrier pigment is added to the fluorescent layer or is applied over the fluorescent layer as an additional layer.

Abstract: This invention relates to a plastic identification card with an improved signature panel. There is a problem with existig credit cards in that the existing signature can be obscured by printing over with a patch of clay composition similar to that used to provide the original signature panel. A new signature can then be applied. This problem is overcome by providing a signature panel which is sandwiched between the core stock and a protective transparent film. The signature panel comprises a layer of chemicals reactive under the pressure of a signature to release a colored dye conforming with the signature.

Abstract: A first coating liquid 3 is applied to one surface of a continuously running web 1 and fluidity of the first coating layer is eliminated by an air blower 6, after which the web is float supported over a cylindrical blower 7 by static gas pressure. A second coating liquid 11 is applied to the opposite surface of the web in the vicinity of the float region by a freely falling curtain film 12 or by a pressure extruded jet film 15. spThis is a continuation of application Ser. No. 887,400, filed Mar. 16, 1978, now abandoned.

Abstract: A method for the preparation of conductive graphite particles useful as an electrically anisotropic support layer for an electroconductive transfer film comprising initially grinding a slurry of graphite particles in the presence of water or a solvent having freezing and vapor pressure properties similar to water, for a period of time sufficient to substantially completely disperse the graphite particles in the water or solvent. A binding or film forming polymer is then added to the graphite slurry, said polymer being soluble in the water or solvent. The resulting slurry is then subjected to a freeze drying step so that the water or solvent present is caused to sublime resulting in the formation of polymeric coated graphite particles of at least 0.2 microns in diameter. These particles can be incorporated into the support layer of a electroconductive transfer film.

Abstract: A desensitizing ink for pressure sensitive copying sheets using at least a desensitizing agent, pigment and binder, wherein said desensitizing agent comprises at least propylene oxide addition compound selected from compounds of the following formulas: ##STR1## wherein a, b and c represent identical or different integers greater than 1; R is an alkyl group, an alkenyl group, an aryl group, substituted alkyl group, substituted alkenyl group or substituted aryl group; and n is an integer greater than 1. The desensitizing inks of the present invention exhibit sufficient desensitizing effect, excellent yellowing resistance and excellent printability, particularly in wet offset printing.

Abstract: A multi-ply business form comprising a plurality of sheets in superposed relationship wherein the top sheet comprises a support bearing a localized coating comprising both microscopic pressure rupturable capsules containing a chromogenic material, and an electron acceptor material. At least one underlying sheet can comprise a support bearing a second localized autogenous coating comprising chromogen-containing microscopic pressure rupturable capsules and an electron acceptor material on its upper surface wherein the localized autogenous coatings are non-coextensive.

Abstract: In a color-forming sheet for no-carbon copying paper applied with a coating color basically composed of color former-containing microcapsules, a capsule protective agent and an adhesive, the edge padding aptitude of no-carbon copying papers could be improved by containing in said coating color a surface active agent in an amount of 0.1 to 4% by weight based on the microcapsules.

Abstract: The present invention relates to a sheet-form or web-form copying material having an improved shelf life. More particularly, the invention relates to that part of copying materials of the type in question which contains the dye precursor by providing a new type of binder which may be used in conjunction with a variety of known dye precursors. Applied to the support material, it forms a unit of the pressure-sensitive copying material which, in combination with a plurality of known units containing dye acceptor material, forms pressure-sensitive copying material according to the invention.

Abstract: A heat-sensitive recording material comprising a heat-sensitive color forming layer on a base is disclosed. The color forming layer contains an electron donating colorless dye and an organic acid to which a heat-fusible substance having a melting point in the range of from 60.degree. to 150.degree. C. is fusion-bonded. A process for producing such recording material by applying to a base a coating solution containing a developer for heat-sensitive recording is also disclosed. The developer is prepared by the steps of dispersing in a dispersion medium a heat-fusible substance having a melting point in the range of from 60.degree. C. to 150.degree. C. and an organic acid, heating the resulting dispersion under conditions that form a turbulent flow, and cooling the heated dispersion to ordinary temperatures.

Abstract: A thermosensitive recording paper consisting of a dye precursor and a color developer capable of coloring said dye precursor on heating, wherein one type of overcoat layer selected from the group consisting of alginates, alumina sol, colloidal silica and a mixture of alumina sol with colloidal silica is provided as the topmost layer thereof to give improved chemical resistance and good printing quality with a reduced deterioration in sensitivity and no residues and sticking.

Abstract: A color developer for pressure-sensitive recording paper which is derived from a clay mineral having a layer-structure composed of regular tetrahedrons of silica and which shows(A) the diffraction pattern attributable to the crystals of layer-structure composed of regular tetrahedrons of silica when subjected to an electron diffraction analysis, but(B) substantially no diffraction pattern attributable to the crystals of said layer-structure when subjected to an X-ray diffraction analysis, and which(C) contains as the constituting elements besides oxygen, at least silicon, magnesium and/or aluminum.This color developer is produced by acid-treating a clay mineral having a layer-structure composed of regular tetrahedrons of silica until its SiO.sub.2 content reaches 82-96.5% by weight on dry basis (drying at 105.degree. C.

Abstract: The invention relates to a pressure-sensitive, carbonless copying system and to a process for the production of pressure-sensitive, carbonless copying system wherein a non-aqueous, substantially solvent free printing ink containing micro-capsules which contain dye-precursors, is applied by wet and dry offset and book printing techniques to all or part of at least one surface of a paper substrate; and to printing inks comprising(1) binders, (2) microcapsules containing dye precursors, (3) spacers having a grain size of from 1.5 to 10 times the diameter of the microcapsules, and optionally auxiliaries and additives.

Abstract: A novel thermosensitive recording material suitable for credit cards, season tickets or passes, and the like to be used for a relatively long period comprises a substrate, a first thermosensitive layer having an acidic developer dispersed in a solid vehicle and laminated on the substrate, and a second thermosensitive layer having a leuco-dye dispersed in a solid vehicle and laminated on the first thermosensitive layer. The recording material can further have a primer layer, an overcoat layer and/or a magnetic recording layer.

Abstract: Disclosed is a pressure sensitive recording unit which comprises a single base web sheet and a methine-type dyestuff and an organic oxidizing compound both supported on the single base web sheet, or a combination of first and second base web sheets and the methine-type dyestuff and organic oxidizing compound supported individually on the first and second base web sheets. Such a recording unit includes for example a pressure sensitive recording unit formed in combination of (a) a back-coated topsheet (CB-sheet) making use of microscopic capsules containing a solution obtained by dissolving a methine-type dyestuff in a solvent having a high boiling point and (b) a front-coated undersheet (CF-sheet) carrying an organic oxidizing compound coated thereon. Also disclosed is a pressure sensitive recording unit which includes a base web sheet carrying thereon such a methine-type dyestuff together with a metal ion sequestering agent and/or alkanol amine.

Abstract: The disclosed adhesive products include a carrier sheet bearing a polymeric film and an adhesive layer, overlying the film as in dry transfers or underlying the film in products such as wire markers and other labels, or there may be adhesive layers both over and underneath the polymeric film. A constituent initially contained in the polymeric film layer migrates into an ordinarily non-tacky precursor of the adhesive layer, thereby rendering the precursor tacky. The precursor layer becomes adhesive only where it is opposite the polymeric film, being non-tacky outside the area of the film. In important applications, the common area of film and adhesive layers does not cover the whole carrier sheet. Both the adhesive precursor layer and the polymeric film may include portions extending outside the common area.

Abstract: There is disclosed no-carbon copying paper composed fundamentally of a color former sheet produced by coating a support with microcapsules containing a colorless electron-donative organic compound as a color former and a color developer sheet produced by coating a support with a coating color containing activated clay as a color developer which adsorbs the aforesaid electron-donative organic compound to develop color. When said coating color is prepared by adding a polyvinyl alcohol, a styrene-butadiene latex and a wax emulsion to the activated clay, it becomes possible to apply it at a high concentration and there are accomplished the maintenance of surface strength of the color developer sheet, the decrease in stains on the blanket and the improvement in sunlight resistance of the colored characters and in the aptitude for pasting.

Abstract: A releasable heat-sensitive recording paper is disclosed wherein a heat-sensitive color forming layer and a protective layer are laminated in succession on the surface of a substrate, said color forming layer consisting essentially of a leuco dye and an acidic substance, said protective layer consisting essentially of a water soluble resin, and further a required pattern is printed on this protective layer with an ultraviolet setting type printing ink, while a pressure-sensitive adhesive layer is formed on the back of the substrate and the thus formed layer is covered with a releasable paper.

Abstract: Desensitization of carbonless copy systems is provided by contacting an electron-accepting, color-reactant material capable of reacting with a substantially colorless chromogenic compound to form a visible image with a desensitizing agent comprising, in combination, a non-volatile, polyoxygenated compound and a strong chelating agent. In this manner, acid-reactive clay coatings typically used in carbonless copy paper systems are effectively desensitized and prevented from reacting with conventional chromogens, such as crystal violet lactone and benzoyl leuco methylene blue.

Abstract: A pressure sensitive copying element in the form of a web having on one side a color forming coating containing a mixture of alkanes of m.w. 500-3500 and dispersed therein 0.1 to 10% by weight of an incompatible material which is a cellulose derivative, hydrocarbon resin, melamine resin, phenolic resin, or styrene resin, and a solution of a color former in a solvent compatible with the material but incompatible with the alkanes. On the other side there may be a color developing coating containing aluminium oxide together with a binder.

Abstract: A pressure-sensitive chromogenic copy system utilizing a color developer capable of reacting with a chromogen to form a color image, said color developer comprising an oligomeric aromatic carboxylic acid and the method of making such oligomer by reaction of the acid with an aldehyde under alkaline conditions.

Abstract: A transfer paper for use in drawing patterns or marking designs on a sheet material, comprising a base material and on one or both surfaces thereof, a water-soluble or water-dispersible transfer coating comprising cobalt thiocyanate, wax, a non-ionic surfactant and another surfactant.

Abstract: A method of intensifying or amplifying an image substrate obtained by imagewise release or transfer of a microcapsular substance which is liquid at room temperature, unaltered in state, by a pigment developer, and fixing the image.

Abstract: Stable, concentrated, free-flowing aqueous dispersion compositions containing one or more colorless dyestuff precursors and one or more surface active agents, are useful in the manufacture of paper for pressure sensitive carbonless duplicating manifold systems and thermal marking systems.

Abstract: This invention provides an image-forming and image-transferring sheet comprising a base layer having a first surface and a second surface. The base layer is impregnated with a first image-forming reactant whereas each of the surfaces of the base layer has coated thereon a microporous membrane layer having a gradient in elasticity across the thickness thereof. The more elastic surface of the membrane is in contact with the base layer. The other surface of the membrane is coated with a second image-forming reactant. Upon impact by an image instrument such as a typewriter key, the membrane becomes extended to allow diffusion of the first reactant through the membrane to react with the second image-forming reactant on the surface of an adjacent sheet to form an image on the surface of the adjacent sheet. A method of preparing an image-forming and image-transferring sheet is also provided.

Abstract: An electric recording material comprising(A) a semiconductive resin layer comprising a resin matrix and a conductivity-imparting agent dispersed therein and having a surface resistance of more than 1 ohm to less than 10.sup.5 ohms,(B) a metal-containing resin layer comprising a resin matrix and 5 to 60% by volume of a metal powder dispersed therein and having a surface resistance of 10.sup.5 to 10.sup.16 ohms, said metal-containing layer being laminated to one surface of said semiconductive resin layer (A),(C) an electrically conductive covering layer having a surface resistance not exceeding 10.sup.

Abstract: A transfer-onto-plain paper type pressure-sensitive copying paper which is excellent in transferability and coloring property could be obtained by coating in monolayer to one surface of a substrate a colorless electron-donating color former, a colorless electron-accepting color developer which reacts with said color former to give a colored product, and a wax mixture comprising an amide wax selected from the group consisting of saturated fatty acid amides having 14 or less carbon atoms and unsaturated fatty acid amides having one or more unsaturated bonds, and other wax.

Abstract: Fluoran compounds of the formula ##STR1## wherein one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents n-alkyl having 6 to 12 carbon atoms and the other R's, independently of each other, represent hydrogen, alkyl having 1 to 12 carbon atoms, alkoxyalkyl having 2 to 8 carbon atoms or benzyl optionally substituted in the ring by nitro, halogen or alkyl having 1 to 6 carbon atoms.The fluoran compounds are particularly useful as color formers which give intense dark green color when they are brought into contact with an electron-accepting co-reactant.

Abstract: An improved chemical carbonless copy paper system including an improved hot melt type of coating for CB type pressure sensitive carbonless copy paper having discrete liquid droplets of metallic salt solution electron accepting chromogenic reagent material contained therein.

Abstract: An improved chemical carbonless copy paper system including an improved hot melt type of coating for one surface of pressure sensitive carbonless copy paper having discrete liquid droplets of metallic salt solution electron accepting chromogenic reagent material contained therein in operative association with an image receptor coating for the other surface of said paper employing tri (p-phenylamino) phenyl methanol as a dye precursor type chromogenic reagent material therein.