Abstract: A process for producing a heat-sensitive recording material superior in the stability of both base surface and recorded image, characterized by adjusting pH of a heat-sensitive coating suspension of 5 to 12.

Abstract: Disclosed in a fine-particle aggregate emulsion comprising aggregate particles formed from a copolymer (a) composed of an unsaturated carboxylic acid and a vinyl monomer copolymerizable therewith, and a foreign polymer (b) formed by polymerization of a vinyl monomer differing in composition from that used in copolymer (a), foreign polymer (b) being present in the form of particles having a diameter of 0.05 to 0.5 .mu., the aggregate particles having a diameter of 0.2 to 3.0 .mu..This fine-particle aggregate emulsion is useful in paints, paper coating and information recording paper.

Abstract: A thermal transfer printing receiver sheet for use in association with a compatible donor sheet comprises a supporting substrate having a dye-receptive receiving layer, said dye receiving layer comprises a dye-receptive polymer and from 0.5 to 30% by weight of the layer of at least one antiplasticizer therefor.

Abstract: A TTP receiver sheet having a backing layer comprising a polymeric resin binder and a non-film forming inert particulate material of mean particle size from 5 to 250 nm.

Abstract: A heat-sensitive recording material having a superior resistance against water, plasticizers, and oily substances, is provided with a heat-sensitive color-forming layer formed on a surface of a substrate sheet and comprising a dye precursor, a color-developing agent, and a binder; and a protecting layer formed on the heat-sensitive color-forming layer and comprising (A) a polyvinylalcohol resin, (B) a water-soluble cross-linking agent, (C) at least one organic boron-containing polymer of the formula (I): ##STR1## and optionally (D) an acetoacetylated polyvinylalcohol resin.

Abstract: A thermosensitive recording member comprises (1) a substrate, (2) a foamed dispersion layer, provided on the substrate, in which an aqueous, self-emulsifiable resin having an I/O value of 0.6 to 1.1 has been dispersed, and (3) a thermosensitive coloring layer, provided on the foamed dispersion layer, containing an electron-donating dye and an electron-accepting compound to present a color by reacting with the dye, improved in sensitivity.

Abstract: A heat-sensitive recording material comprising a substrate, an intermediate layer formed on the substrate, and a heat-sensitive recording layer formed on the intermediate layer, said intermediate layer comprising an inorganic powder having an oil absorption of 50 ml/100 g or more as measured in accordance with JIS K5101, an aqueous adhesive and a carboxymethyl cellulose in an amount of 3 to 20% by weight based on the weight of the aqueous adhesive, and said heat-sensitive recording layer comprising an electron-donating, colorless dye precursor, an electron-accepting developer and a sensitizer. Said heat-sensitive recording material has a high sensitivity and hardly causes scum adhesion to a thermal head.

Abstract: A compound having a carboxy group and a long-chain alkylthio group and/or a salt thereof is used as an emulsifier and, on the other hand, emulsion polymerization is carried out using a polymerizable monomer or monomers having, within their molecule, a group reactive with a carboxyl group as raw materials for emulsion polymerization, whereby the resin produced by emulsion polymerization and the emulsifier react with each other efficiently on the occasion of film formation and form a crosslinked structure. When a compound having a polymerizable unsaturated group in addition to the carboxyl group and long-chain alkylthio group and/or a salt thereof is used as the emulsifier, not only the above-mentioned crosslinked structure is formed but also the polymerizable unsaturated group in the emulsifier will react with the unsaturated group in the polymerizable monomer or monomers in the manner of grafting. As a result, the compatibility between the emulsifier and the emulsion-polymerized resin is improved.

Abstract: A developer sheet is composed, in one embodiment, of a reflecting layer formed by securely bonding an aluminum or other metal foil on a substrate and a developer layer formed on the reflecting layer. The developer sheet is capable of forming a color picture image on the reflecting layer, producing ornamental or decorative effects with high commercial value.

Abstract: Disclosed is a heat-sensitive recording material comprising:(a) a base sheet;(b) a heat-sensitive recording layer formed on the base sheet land comprising a colorless or pale-colored basic dye and a color developing material which develops a color on contact with the dye; and(c) a protective layer formed on the recording layer and comprising a binder and at least one metal salt selected from the group consisting of magnesium acetate, calcium acetate, aluminum acetate, magnesium formate, calcium formate and aluminum formate.

Abstract: Disclosed is a heat-sensitive recording material useful in the manufacture of thermal paper and thermal labels. The material comprises a cellulosic or other suitable substrate, a thermally imprintable color-producing layer, and a protective layer over the color-producing layer. It may also include a second protective layer and/or a pressure-sensitive adhesive layer, on the surface of the substrate opposite from the color-producing layer, and a releasable liner covering the adhesive layer. The color-producing layer includes a basic, acid-neutralizing agent for both reducing background discoloration during manufacturing and increasing image definition. The protective layer comprises a polymeric binder which is both ionically and covalently cross-linked to provide improved resistance to hydrophobic and hydrophillic solvents.

Abstract: A process for producing a recording medium comprising a substrate and a plurality of image forming elements disposed thereon, which comprises the steps of: applying a binder onto the substrate to form thereon a binder layer; disposing the image forming elements on the binder layer; and simultaneously applying a vibration and a pressure to the image forming elements disposed on the binder layer sufficient to bond the image forming elements to the substrate as a substantially monoparticle layer.

Abstract: A thermosensitive recording material bearing a specific intermediate layer comprising a specific alkyl ammonium salt provides a high color density even with a low printing energy and minimized background strain. The intermediate layer is provided between a support and a thermosensitive recording layer.

Abstract: A thermo-sensitive recording label paper comprising a laminate which comprises(1) a thermo-sensitive color-developing layer containing at least a colorless or lightly colored leuco-dye provided on one surface of a paper support, (2) a protective layer provided on the color-developing layer, and (3) at least one of a back layer and a protective underlayer, said back layer being provided on the other surface of the paper support, and said protective underlayer being provided between said paper support and said color-developing layer;the laminate having an internal bond strength of 2.5 kg-cm or more according to Tappi UM-403, and the surface of the protective layer of the laminate having a Bekk smoothness of 500 seconds or more according to JIS P8119.

Abstract: A thermal recording sheet having on a support a thermal recording layer adapted for developing color when heated has an outermost surface layer formed by bringing it into contact with the surface of a smooth body when it is in a wet state, drying it and separating it from the surface of the smooth body. The sheet has a surface which is so smooth that when a first straight line extending in parallel to the centerline of a roughness curve as obtained in accordance with the method of JIS B0601 crosses the roughness curve with a contact ratio of 10%, a second straight line extending in parallel to the centerline and between it and the first straight line and having a distance of 1.5 .mu.m from the first straight line crosses the roughness curve with a contact ratio of at least 80%. The sheet is, therefore, easy to bring into intimate contact with a thermal head and is of high image quality and sensitivity.

Abstract: An improved heat-sensitive recording material of the type having a substrate and a heat-sensitive recording layer formed on said substrate, said heat-sensitive recording layer containing a color former and a color developer to color said color former upon contact by heating, characterized in that said substrate comprises an adiabatic foamed polyester resin film containing minutes cavities with an apparent specific gravity in the range of 0.9 to 1.2.

Abstract: A recording medium which enables formation of an image on any desired substrate is disclosed, which comprises a support having provided thereon at least a color developer capable of color-forming reaction with a dye precursor, and an adhesive such as heat-sensitive adhesives, tackifying composition, etc.

Abstract: A substrate for heat-sensitive recording material is disclosed, comprising a film-like substrate made mainly of a synthetic resin and a sheet-like substrate made mainly of a fibrous materials laminated each other with an electron beam-curable adhesive. A heat-sensitive recording material using the above substrate provides an image having excellent quality.

Abstract: The heat-sensitive record materials have, between the base sheet and the recording layer, a middle layer which mainly comprises a binder and at least one pigment having an oil absorption of at leasat 80 cc/100 g measured by JIS K 5101. The middle layer comprises an acrylic thickener in an amount of 0.05 to 5 parts by weight per 100 parts by weight of the pigment on dry basis.The middle layer is formed by blade-coating on a base sheet a coating composition comprising at least one pigment having an oil absorption of at least 80 cc/100 g measured by JIS K 5101 and a binder, in which an acrylic thickener is comprised in such amount as described above.

Abstract: Disclosed is a developer sheet useful in forming reproductions having a glossy finish, or in forming transparencies comprising:a support having a layer of a finely divided, thermoplastic, developer material on the surface thereof, said developer material being capable of reacting with a color precursor to produce a visible image and being capable of coalescing into a thin film which imparts gloss to said image upon application of heat and/or pressure, and having a surfactant admixed within said layer of developer material to aid in the coalescing of said developer material into a thin film.

Abstract: A heat sensitive material which is comprised of a support having thereon a transparent heat sensitive layer and at least one layer selected from among a protective layer, a subbing layer and backing layer, wherein at least one of constituent layer contains fine grains of at least one crystalline metal oxide which has a volume resistivity ranging from 10.degree. to 10.sup.5 ohm.multidot.cm. An amount of said crystalline metal oxide is 0.0001 g-1 g per m.sup.2 and the best metal oxide is SnO.sub.2.

Abstract: A thermal transfer meltable color layer receives a protective polymer coating on the side thereof, to be contacted with the thermal printing head to hold the meltable color material away from the printing head, thereby forming a thermal printing ribbon without the need for a support foil.

Abstract: Disclosed is a heat-sensitive recording material comprising a support; a heat-sensitive recording layer formed over the support and containing a color forming material, a color developing material which forms a color on contact with the color forming material and a pigment which is about 80 to about 400 ml/100 g in oil absorption according to JIS K 5101 and about 3 to about 15 .mu.m in average particle size; and an overcoat layer formed over the heat-sensitive recording layer and comprising a binder and a pigment, wherein the pigment is used in an amount of about 0.5 to about 3.0 parts by weight per part by weight of the binder and the coating amount of the overcoat layer is about 0.3 to about 2.0 g/m.sup.2 on dry basis.

Abstract: Methods of preparation of dry transfer graphics article. The article is self-weeding to transfer fine graphic images without the use of detackifying radiation, solvents, etc. One of the elements of the article is a carrier having a surface which is compatible with an adhesive having a low work to fracture. The article further comprises a graphic pattern formed on the adhesive.

Abstract: In a photo and pressure sensitive recording medium, a layer of microcapsules is carried on a side of a substrate sheet. The side of the substrate sheet is subject to adhesion-facilitating processing.

Abstract: A protective coating composition for protection of thermal images on thermal paper is provided. A mixture of oligomers, monomers, and a photocatalyst are blended together, coated onto thermal paper and then cured by ultraviolet radiation. The coating provides protection to images subsequently printed on the paper by providing resistance to solvents, abrasion and fading due to exposure to light.

Abstract: By providing an intermediate layer composed of colloidal silica and/or alumina between a support and a thermosensitive color forming layer, a thermosensitive recording material having high color sensitivity which is free from undesirable foreign matters adhered to a thermal head can be provided. The colloidal silica and/or colloidal alumina is used in a coverage of 1 to 15 g/m.sup.2.

Abstract: A heat-sensitive recording material which comprises a heat-sensitive recording layer and a substrate, the substrate having as a constituent element a synthetic resin film layer containing minute cavities and a content of cavities in the synthetic resin film layer being 40 to 100 cc/100 g. The heat-sensitive recording material has excellent resolution and gives a clear recorded image having a high density even with low printing energy.

Abstract: There is disclosed a thermal recording paper comprising a support having a roughness index, measured by the method of liquid absorption test on paper and board (Bristow's method) in Japan TAPPI paper pulp test method No. 51-87, of not more than 8 ml/m.sup.2, a thermal recording layer, and an intermediate layer formed therebetween.

Abstract: A process for preparing a developer sheet and a developer sheet are disclosed wherein an aqueous dispersion of a phenolic resin containing about 30 to 60% by weight of a phenolic resin is applied to the front surface of a substrate; the composition provides good image intensity and when applied at a controlled rate in full or spot coverage can be used on press with limited drying.

Abstract: There is disclosed a thermosensitive recording material comprising a support, an undercoat layer provided thereon and comprising a first layer formed on the support and containing a pigment; a second layer formed on the first layer and containing an ureaformaldehyde resin, and a thermosensitive recording layer provided on the undercoat layer and containing a dye precursor and a developer capable of developing the color of the dye precursor when heated.

Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive recording layer, wherein (a) a microporous layer comprising at least one of a synthetic resin and a cellulose compound or (b) a layer comprising porous grains comprising secondary particles bound to the surface of primary particle as core is provided between the heat-sensitive recording layer and the support of the recording material.

Abstract: A thermosensitive recording material is disclosed, which comprises a substrate, a thermosensitive coloring layer comprising a leuco dye and a color developer capable of inducing color formation in the leuco dye, formed on the substrate, and a protective layer comprising at least one inorganic pigment selected from the group consisting of silica and calcium carbonate, each having an average particle diameter of 0.1 .mu.m or less, and a water-soluble binder, formed on the thermosensitive coloring layer.

Abstract: A thermosensitive recording material is disclosed, which comprises (a) a heat insulating support having a foamed portion with minute voids therein, (b) an undercoat layer formed on the heat insulating support, comprising as the main component a film-forming polymeric material in an amount ranging from more than 50 wt. % to 100 wt. % of the entire weight of the undercoat layer, and (c) a thermosensitive coloring layer formed on the undercoat layer, comprising a leuco dye and a color developer for inducing color formation in the leuco dye upon application of heat thereto.

Abstract: In a heat sensitive recording material comprising a substrate and a heat sensitive recording layer thereon containing a colorless or light-colored basic dye and a color acceptor which is reactive with the dye to form a color when contacted therewith, the recording material characterized in that an emulsion containing complex particles of colloidal silica and at least one of acrylic polymer and styrene-acrylic polymer is added to a coating composition for the recording layer and/or a coating composition for a protective layer formed on the recording layer.

Abstract: A thermosensitive recording material which comprises a support, an intermediate layer including a foamed portion with minute voids, having a smoothness of 2,000 seconds or more in terms of Bekk's smoothness, and a thermosensitive coloring layer, successively formed on the support, and which layers show the compression strain of 20% or more when a pressure of 0.55 kg/cm.sup.2 is applied in accordance with the Japanese Industrial Standards (JIS) P-8118. This thermosensitive recording material shows the compression strain of 5% or more as a whole when a pressure of 0.55 kg/cm.sup.2 is applied in accordance with the JIS P-8118.

Abstract: There is disclosed a thermosensitive recording material, comprising a support, a thermosensitive recording layer coated on said support and comprising a dye precursor and a color developer capable of developing a color of said dye precursor upon heating, and an porous undercoat layer comprising any one selected from water soluble polymers and latex resins and coated between said support and said thermosensitive recording layer.

Abstract: An imaging sheet used for achieving color balance in a full-color imaging system is disclosed. The sheet is characterized by utilizing three sets of microcapsules, each containing a different colorless image-agent and a photohardenable or photosoftenable composition, and a corrective dye associated with the substrate. Association of the corrective dye with the substrate achieves color balance by equalizing the speed of the different colorless color-forming microcapsules.

Abstract: This invention provides an overcoat composition for a heat-sensitive record material comprising as an effective component thereof an emulsion of graft copolymer prepared by graft-copolymerizing methyl (meth)acrylate (A), a lower hydroxalkyl (meth)acrylate (B) and (meth)acrylic acid (C) with a polyvinyl alcohol in the presence of water and a neutralization salt of diisobutylene-maleic anhydride copolymer; a heat-sensitive record material having a heat-sensitive layer coated over its surface with an overcoat composition defined above; and a process for preparing a heat-sensitive record material comprising coating the surface of the heat-sensitive layer of a heat-sensitive record material with an overcoat composition defined above.

Abstract: Record material comprising a paper sheet having on its front a printable pigment coating and on its back isolated droplets of colour former solution each confined within a pressure rupturable barrier, wherein the pigment coating comprises a binder for the pigment together with a synthetic reactive sizing agent or a coating structure agent or both the sizing agent and the coating structure agent.

Abstract: A recording sheet which comprises a substrate having a layer of a metal on the surface thereof and a layer of microcapsules, said microcapsules being bonded to one another by means of a crosslinking agent which has reactively interacted with reactive moieties on the surface of said microcapsules, to improve the adhesion of said microcapsule layer to said metal layer.

Abstract: Pressure sensitive carbonless transfer sheets are made capable of producing clear images by light impact marking means in multi-part carbonless forms packs containing at least six of the sheets, such as 8-12 sheets, by coating a chromogenic material onto a paper sheet characterized by a basis weight of 9-12 lbs of a ream of 500 sheets of paper each having dimensions of 17 by 22 inches, a thickness of 40-50 microns, a Gurley porosity of 400-4000 seconds, and a Bendtsen smoothness of 90-260 ml/min on the wire side and 60-280 ml/min on the felt side. Bar codes are also transferrable with good scannability through forms packs containing three or more sheets.

Abstract: A chemically self-copying paper intended for use in the combinations of a top sheet (CB), bottom sheet (CF) and one or more interleaving sheets (CFB) or a chemically copying, self-containing paper. The paper is formed of two fiber layers manufactured in separate wire sections and couched together while wet. The wire side of the upper fiber layer and the top surface of the lower fiber layer are couched together. The components inducing the color reaction are contained in the upper fiber layer which has been in contact with a smooth-surfaced press roll during the production of the paper.

Abstract: A heat-sensitive recording material comprising a support, a heat-sensitive recording layer containing a color former and a color developer forming color by the contact with the color former formed on the support, an interlayer containing a water-soluble resin or a water-dispersible resin as the main component formed on the heat-sensitive recording layer, and an overcoat layer formed by forming a layer containing (1) a macromonomer having a polymerizable functional group at one terminal of the molecular chain, the main component of the segment being organopolysiloxane and (2) a resin capable of being cured by electron beams on the interlayer and curing the layer by the irradiation of electron beams.

Abstract: The lower side of a transmitter sheet (1) of a copy form set of chemically reacting color reaction paper provided with a CB coating (2) is zonewise provided with an additional ink layer (4) e.g. on wax basis. On writing or printing upon the copy form set within the intensification zone (3) defined by the additional ink layer (4) the color pigments of the additional ink layer (4) are partially or completely dissolved by means of the CB substances of the CB coating and transmitted to the CF coating (5) of the receiver sheet (6). This results in that the copy is itensified within the area of the intensification zone (3), thus becoming particularly machine-readable.

Abstract: A thermosensitive recording material is disclosed, which comprises a support, and a thermosensitive recording layer formed on one side of the support, the thermosensitive recording layer comprising (i) a thermosensitive coloring layer comprising a thermosensitive coloring system capable of producing a color upon application of heat thereto, and (ii) a colored layer comprising a colored fluorescent dye composition.

Abstract: Substantially flat surfaced emulsion particles polymerized vinyl monomer, having a concavity in at least one of the flat surfaces, a diameter D of from 0.1 to 5.0 .mu.m, and a particle diameter thickness d ratio (d/D) of 1.2 to 5.0, prepared by the step of (1) aqueous emulsion polymerizing a first vinyl monomer or mixture of monomers (a) to form vinyl polymer seed particles; and (2) aqueous emulsion polymerizing a second vinyl monomer or mixture of monomers (b) in the presence of the vinyl polymer seed particles and a non-aqueous organic solvent having a surface tention to water at 20.degree. C. of 48 dyne/cm or more, in a weight ratio of monomer (a) to monomer (b) of 0.5/99.5 to 50/50; and are useful in high performance recording material, paint compositions and paper coating compositions.

Abstract: A heat-sensitive record material has a protective layer on the recording layer which is formed on a base sheet and which comprises a color forming material and a color developing material in the state of that they are contacted by heating to produce color images. The protective layer comprises a water-soluble high polymer and a polyethylene wax having an average particle size of 3 to 10 .mu.m. The protective layer comprising the granular polyethylene wax in an amount of 0.1 to 30 parts by weight per 100 parts by weight of the solid amount of the protective layer improves the property of the heat-sensitive record material, particularly the sliding property and the retainability of recorded images without accompanying either lowering the initial color density of recorded images or sticking.

Abstract: In a heat-sensitive record material having a heat-sensitive recording layer on a base sheet, a middle layer is formed between the heat-sensitive recording layer and the base sheet by blade-coating on the base sheet a coating composition which mainly comprises at least one pigment having an oil absorption of at least 80 cc/100 g measured by JIS K 5101 and a binder and in which the binder ratio is 5% to 16% by weight of the total solid and the solid amount is 35 to 55% by weight of the coating composition.

Abstract: A carbonless copy system which enables the formation of a plurality of different colored images on a substrate. A phenolic resin or reactive clay image-forming component is applied as a CF coating on a recording substrate. One or more coatings of encapsulated dye precursors (complementary image-forming components) are applied to selected portions of the CF coating on the recording substrate and one or more coatings of encapsulated dye precursors are applied to selected portions of a transfer substrate. The dye precursor coatings are capable of forming different colored reaction products when coming into contact and reacting with the phenolic resin or reactive clay. Upon applying pressure to the transfer substrate, the dye precursor capsules are ruptured, releasing the dye precursor which contacts and reacts with the phenolic resin or reactive clay to form the colored reaction products.