Abstract: A high temperature thermal sprayable material, such as a metal or metal oxide, is adhered to the surface of a thermal sprayable plastic particle to form a cladding layer thereon. The high temperature material cladding layer provides a thermal barrier that allows use of the plastic in a high temperature thermal spray process to create a duplex coating containing plastic.

Abstract: A method of forming a polymer backing on a glass substrate through the use of a pre-polymer powder applied onto the surface of the substrate. The backing is applied on-line in an existing substrate manufacturing or fabricating process while the substrate is at a high enough temperature to polymerize the powder. The resulting backed substrate is durable and abrasion resistant and exhibits excellent opacification and adhesion properties.

Abstract: The present invention relates to an aqueous powder coating dispersion based on epoxy resins and phenolic curing agents or carboxyl-containing polyesters for the coating of packaging containers, which dispersion consists of a solid, pulverulent component I and an aqueous component II, component I being a powder coating which containsA) at least one epoxy resin having an epoxide equivalent weight of from 300 to 5500 andB) at least one curing agent having more than one phenolic hydroxyl group per molecule and a hydroxyl equivalent weight, based on phenolic OH groups, of from 100 to 500, preferably from 200 to 300, orC) at least one polyester having an acid number of from 25 to 120 mg of KOH/g and an OH number >10 mg of KOH/g, andD) at least one epoxy resin having an epoxide equivalent weight of from 400 to 3000, and component II being the aqueous component of the dispersion which contains at least one nonionic or anionic thickener.

Abstract: Wood is electrostatically coated with a thermosetting powder coating system in which a mixture of a self-curing epoxy resin and a catalyst therefore is extruded and a low temperature curing agent are both pulverized and the powders are blended with conventional additives to make a coating powder which is deposited on a wooden substrate and heated to cure. The mixture of resin and catalyst does not cure within the extruder but it is made to cure at low temperatures by the separate addition of the curing agent. A small amount of the low temperature curing agent, insufficient to cause substantial curing during extrusion may be used in place of the catalyst.

Abstract: The invention relates to mononoble metal dithiolates, more particularly water-soluble monogold(I) dithiolates, to their production and to their use for the production of noblemetal-containing decorations on firing-resistant substrates.The mononoble metal dithiolates represent a new class of water-soluble thiolates for use in organic-aqueous and essentially purely aqueous noble metal preparations for decoration purposes.The mononoble metal dithiolates correspond to the following formula: ##STR1## in which Em=Au(I), Ag(I), an equivalent of Pd(II), Pt(II) or Rh(III),Q=a tetravalent organic radical containing 2 to 10 carbon atoms,Y=a hydrophilic group from the series comprising --COOH, --COO.sup.- cat.sup.+ or --COO--(CHR.sup.1 --CHR.sup.2 --O).sub.m R.sup.3Z=Y or H or a group from the series comprising --OR', --SR', --SO.sub.3 R', --NR'.sub.2, --NR.sub.3.sup.+ X.sup.-.

Abstract: Powder coatings made from a blend of one or more polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon (polyketone), and a compatible material are presented. The compatible materials can comprise another polyketone or novolac resins.

Abstract: Carbon fiber mat are embedded in a coating by first rolling on a coating of e.g. epoxy on the floor or wall, then applying sheets of fine carbon fibers, (optionally) removing the carbon fiber which is not adherent after the coating has dried, then applying one or more additional top coats of coating to additionally embed the carbon fibers. The result is an electrically conductive floor and/or wall coating system useful in antistatic rooms such as clean rooms, operating rooms, etc. Coatings can be sol vent based or waterborne urethanes, epoxies, alkyds, polyethylenes, acrylics, vinyls, vinyl acetates, esters, polyesters, sulfones, polysulfones, silicones, polysilicones and others. The preferred mats are carbon fiber "veils" or "paper" generally having a density of about 0.75 oz./square yard.

Abstract: A mass of ferromagnetic particles encapsulated in a polymeric shell having a plurality of denuded organic lubricant particles adhering to the surface of the shell so as to stand in relief from said surface unimpaired by the polymer or any other binder.

Abstract: A lining for a metal, a lining powder and a lining resin composition which comprise a mixture of a maleic acid-modified polypropylene and a polypropylene, or a mixture of the above-mentioned mixture and an ethylene propylene rubber and/or an antioxidant; and a lining method.

Abstract: A lining for a metal, a lining powder and a lining resin composition which comprise a mixture of a maleic acid-modified polypropylene and a polypropylene, or a mixture of the above-mentioned mixture and an ethylene propylene rubber and/or an antioxidant; and a lining method.

Abstract: A weather resistant sign and a method of printing a sign including the steps of providing a sign component and an image definition, applying dry toner powder to surface portions corresponding to the image definition, and fusing the applied toner. Preferably, the fused toner is protected from weather by a transparent protective layer. A toner composition and a computer program for printing are also disclosed.

Abstract: Process for the preparation of a flexible, thermoplastic, composite filament, containing continuous fibers basically consisting of a flexible sheath made of polyolefinic resin which covers a bundle of fibers impregnated with a polyolefmic resin, wherein the inorganic fibers are treated with a solution containing additives which improve the compatibility between reinforcement and polymeric matrix after transformation into end products.

Abstract: A process for coating a substrate with a metal giving a polished effect, the substrate being of a material that is dimensionally stable at temperatures up to at least 120.degree. C. The process includes the steps of cleaning the substrate or forming a top coating on the substrate by burning on a powdered lacquer, coating the cleaned or coated substrate with a metal giving a polished effect by plasma deposition within a vacuum chamber, and applying a top coating by burning on a powdered lacquer.

Abstract: A powder coating apparatus and method are provided for feeding fine powdered coating material such as thermoplastic type material to a succession of discrete articles passing by the apparatus. The invention also provides a powder feed system that deposits an excess of powdered coating material than that required to form the coating and provides for recirculation of the powder not ultimately used to form the coating back to the powder feeding apparatus.

Abstract: A powder coating composition contains acrylic resin (A) containing at least 40 percent by weight of a glycidyl-group-containing monomer and having a solubility parameter which is in the range of 11.0 to 11.6 and a glass transition temperature of at least 20.degree. C., a surface modifier (B) consisting of a polymer having a solubility parameter which is in the range of 10.4 to 11.0, and polyvalent carboxylic acid (B). The surface modifier (B) is in a content of 0.1 to 4 parts by weight with respect to a total content of 100 parts by weight of the acrylic resin (A) and the polyvalent carboxylic acid (C), while the components are so mixed with each other that the amount of carboxylic groups contained in the polyvalent carboxylic acid (C) is at an equivalence ratio of at least 0.5 to the amount of glycidyl groups contained in the acrylic resin (A).

Abstract: Sulfonimide cure catalysts are used with aminoplast crosslinking agents and resins capable of reacting with aminoplast crosslinking agents to prepare heat curable compositions capable of crosslinking to form coatings and articles. Liquid or solid curable compositions may be prepared. Solid sulfonimide catalysts used in combination with solid glycoluril type crosslinking agents are well suited for powder coating systems containing hydroxy- and carboxy-functional resins.

Abstract: The present invention relates to a method of forming a polyfluorocarbon coating on a razor blade cutting edge comprising the steps of: dispersing a fluorocarbon polymer in a supercritical fluid; coating said razor blade cutting edge with the dispersion; and heating the coating sufficiently to adhere the fluorocarbon polymer to the blade edge.

Abstract: Sulfonimide cure catalysts are used with aminoplast crosslinking agents and resins capable of reacting with aminoplast crosslinking agents to prepare heat curable compositions capable of crosslinking to form coatings and articles. Liquid or solid curable compositions may be prepared. Solid sulfonimide catalysts used in combination with solid glycoluril type crosslinking agents are well suited for powder coating systems containing hydroxy- and carboxy-functional resins.

Abstract: An apparatus and method for applying a resin coating to a plurality of discrete portions of a fastener, such as both internal and external threads. A conveyor supports a fastener. The fastener is first transported past a heater and then past a first powdered resin spray assembly. Powdered resin, supplied to the first spray assembly by a resin reservoir, is used to generate a first air-borne powdered resin stream which coats one set of threads with resin when the fastener traverses the resin stream. The conveyor also transports a second resin spray assembly through the first air-borne powdered resin stream. The second spray assembly uses a resin receiver to aspirate the air-borne resin. The resin is then used to generate a second powdered resin stream which coats the other set of fastener threads.

Abstract: This method and apparatus provide for uniformly coating a hot elongate member with a powder coating. The elongate member and power carry an electrostatic charge which aids in providing the uniform powder coating. This method and apparatus electrostatically charge and heat the elongated member prior to entering a powder coating booth. In the booth, we sequentially discharge the powder coating, electrostatically charge the powder coating and then coat the elongated member with the charged powder coating. In one development, this method and apparatus uniformly powder coats window lineals directly on a pultrusion line.

Abstract: A process for preparing uni-tape prepreg from polymer powder coated filamentary towpregs is provided. A plurality of polymer powder coated filamentary towpregs are provided. The towpregs are collimated so that each towpreg is parallel. A material is applied to each side of the towpreg to form a sandwich. The sandwich is heated to a temperature wherein the polymer flows and intimately contacts the filaments and pressure is repeatedly applied perpendicularly to the sandwich with a longitudinal oscillating action wherein the filaments move apart and the polymer wets the filaments forming a uni-tape prepreg. The uni-tape prepreg is subsequently cooled.

Abstract: A process for preparing a composite, continuous-fiber-containing filament which entails:a) unwinding a continuous fiber bundle from a bobbin,b) loosening the fiber bundle, in order to separate the bundle substantially into individual fibers,c) impregnating the individual fibers with a thermoplastic polymer powder, andd) recompacting the fiber bundle and providing a flexible sheltering sheath around the bundle, whereby the fiber bundle is caused to have a substantially elliptical cross-section.

Abstract: A self locking internally threaded fastener and an apparatus and process for making such fasteners, in which the self locking characteristic is derived from a patch of thermoplastic material having a circumferential extent of less than 360.degree. adhered selectively to at least a portion of the thread defining surface of the fastener.

Abstract: The problems caused by chemical and thermal shrinkage of hard roll covers, are reduced by the inclusion of one or more intermediate compressive layers between the metal roll and the outer cover, or "topstock". A compressive layer has the properties of being rigid enough to allow the cover to be applied to the roll, and compressible enough to buffer and absorb the stresses which occur as the cover is shrinking during processing.In one embodiment, the intermediate compressive layer comprises a three dimensional fabric that is filled preferably with a thermoset resin system which cures at lower temperature than cover. In a second embodiment, the precise amount of shrinkage in the roll can be predetermined to a high enough degree of accuracy so that a depth for the fabric layer can be used to compensate for the amount of shrinkage, thereby eliminating the need for filling. In a third embodiment, the compressive layer is comprised of a wax material.

Abstract: An acid cured coating composition containing a hydroxyfunctional acrylic or polyester resin and a 1,3,5-triazine-2,4,6-tris-carbamate. Also provided is an acid cured coating composition containing a hydroxyfunctional acrylic or polyester resin, a crosslinking agent such as a melamine-formaldehyde or a related aminoresin, and a co-crosslinking agent derived from a triazine tris-carbamate such as 2,4,6-tris-(butoxycarbonylamino)-1,3,5-triazine. Also provided is an improved method of coating using the above coating compositions. The coating compositions described in this invention have lower cure temperatures, lower formaldehyde emissions during cure, and produce films and objects which have superior environmental etch resistance than the conventional melamine-formaldehyde coatings which do not have a triazine tris-carbamate co-crosslinker.

Abstract: The present invention relates to a two coat one bake coating method in which the aqueous base coating composition and the powder clear coating composition are applied onto substrates in automobile painting processes. In accordance with the present invention, the aqueous base coat contains: (a) a vinyl polymer prepared by copolymerizing 8 to 30% by weight of an amido group containing ethylenic monomer, an acidic group containing ethylenic monomer, a hydroxyl group containing ethylenic monomer and at least one other ethylenic monomer; (b) an aqueous dispersion of hydrophilic group containing oligomers; and (c) pigment. The clear powder coating composition comprises an epoxy group containing acrylic resin, and may carry polymer microparticles on each powder particle.

Abstract: The present invention relates to commercial and institutional inlaid floorcoverings having a uniform, unpatterned decorative appearance. Colored spheroidal particles having an aspect ratio no greater than about 2:1 are provided in a dense, uniform matrix layer to create the decorative appearance. Flame retardant and smoke suppressant compositions can be incorporated in the floorcoverings without detrimentally affecting their appearance.

Abstract: Plastic substrates, such as but not limited to phenolic cellulosic composites such as those used in conventional toilet seats, are heated at a temperature and for a time sufficient to degas the substrate, and are then coated with a powder, and heated to cure the powder coating. In a preferred embodiment, a water-based electrically conductive coating is first applied to a phenolic cellulosic composite, and cured while the substrate is heated to degas the substrate sufficiently, such that a subsequently applied powder coating will not suffer from popping during curing. In a preferred embodiment, the part is coated at a temperature below the cure temperature of the coating composition.

Abstract: The subject matter of this invention relates to a method of making glass fiber mat reinforcement material with a thermoplastic adhesive powder. Fiberglass strands are chopped and randomly air dropped onto a Teflon.RTM. coated conveyor belt to form a loose mat. A water mist is then applied to the loose mat and transport belt, before a powdered adhesive is dispensed. Heat is applied to plasticize the adhesive and finally the adhesive is solidified by cooling. The adhesive will then release from the transport belt and is adhered to the material forming the fiberglass reinforcement mat.

Abstract: A process for the preparation of a matte coating on an article is described, which comprises applying to said article a powdered thermosetting composition comprising as binder a mixture of a linear carboxyl group-containing polyester and a glycidyl group-containing acrylic copolymer and curing the thus coated article at a temperature of from 160.degree. C. to 210.degree. C. for a period of up to about 30 minutes. The polyester has an acid number of 20 to 50 mg KOH/g, and is the esterification product of a hydroxyl group-containing polyester with an organic dicarboxylic acid. The acrylic copolymer is obtained from 5% to 30% by weight of glycidyl acrylate or glycidyl methacrylate and 70% to 95% by weight of methyl methacrylate, whereby up to 25% of the total weight of methyl methacrylate can be replaced by another vinyl monomer, said acrylic copolymer having a number-average molecular weight (Mn) of from about 4,000 to about 10,000.

Abstract: The present invention relates to a method for coating substrate materials with polymers containing lustre pigments, in which a substrate has applied to it a curable coating, followed by a coat of lustre pigments or lustre pigment mixtures and then a clear coat.

Abstract: An apparatus for improving the electrostatic charge developed on a resin powder composition for electrostatic coating of solid objects and the method of application thereof. The apparatus comprises a device for charging the powder by electrical induction/conduction such that the powder particles have a resistivity of from about 10.sup.9 to about 10.sup.13 ohm.meters at 20 percent relative humidity and spraying the charged powder onto an grounded solid object to which it adheres prior to the thermal fusing to produce a permanent finish.

Abstract: An absorbent material is provided which enjoys suppleness, possesses highly satisfactory absorption qualities (speed of absorption and capacity for absorption), allows section into pieces of desired size and shape, and excels in safety.An absorbent material comprising 100 parts by weight of absorbent resin particles and 15 to 150 parts by weight of water, which absorbent material is in the form of a sheet having a thickness in the approximate range of 0.3 to 5 mm, the form of a sheet resulting from mutual adhesion of the absorbent resin particles.

Abstract: Sheet molded compound articles which optionally can be in-mold coated have the edges and exterior margin surfaces thereof sealed with a water-free and solventless fine particle size powder coating. The coating thickness has a gradual and smooth transition from the sealed edge to the non powder coated exterior surface thereby eliminating the need for sanding. The desired method of application is by electrostatic spraying and the cured powder coating is free of pops.

Abstract: A method for forming a coating on at least one part to be coated has the steps of agitating a mixture including (i) the at least one part to be coated, (ii) a material that forms an adhesive layer on the at least one part to be coated, (iii) impact media, and (iv) multiple compositions of powder material; and fusing at least one of the multiple compositions of powder material.

Abstract: A stream of hot air passes from a combustion chamber through an application gun to a preheated substrate. A powdered thermoplastic is fed into the application gun. The hot air stream heats the powdered thermoplastic to its fusion temperature and transports it to the substrate.

Abstract: A conduit liner which is made by cladding the inner surface thereof with impact sprayed thereon while the conduit is heated. Preferably, the spray is polymeric material which may include a low friction additive.

Abstract: A method of coating the surface of semi-rigid porous materials such as open cell foam or fibrous compositions with a thermoplastic adhesive in powder form which will reactivate. The powdered adhesive in a size range of 0-600 microns will remain on the surface of such materials even when cell diameter of the foam or space between fibers is larger than adhesive particle size. High porosity is maintained in the coated product. First a thermoplastic adhesive in powder form is dispensed uniformly onto the surface of a carrier belt which is coated with a release agent and is moving continuously. The adhesive advances to a preheating station where the adhesive is plasticized and will adhere to the carrier belt to prevent movement, after which the foam or fibrous material is placed on the adhesive which is adhered to the belt. The adhesive and material advance to a second heating station where the adhesive is fully melted to allow the adhesive to bridge cells in the foam or space between fibers.

Abstract: A process for repairing surface defects in plastic articles, especially plastic articles formed from fiber reinforced thermosetting resins, includes the steps of applying a powder coating composition to a defective area on the surface of a plastic article, curing the applied powder coating composition through the application of heat, and removing excess cured powder coating composition from the area of the defect to conform the area of the defect to the proper contours of the plastic article. The process can be utilized for repairing surface defects such as porosity, scratches, gouges and sand-through areas of cured thermoset substrates such as automotive body panels formed from sheet or bulk molding compounds.

Abstract: The coils on dynamo-electric machine parts (such as electric motor armatures or stators) are stabilized and coated by electrostatically coating them with resin powder, and then fusing the powder into a continuous resin coating on the coils. For example, the powder may be fused by heat generated by briefly passing a relatively large electrical current through the coils. If desired, the coils may be formed with wire which has an outer layer of bonding material. Activation of the bonding material, which may occur simultaneously with fusing of the resin powder, bonds adjacent coil wires together.

Abstract: A novel process for bonding a fluoropolymer to a metal surface, the process including flowing the fluoropolymer on the metal surface at a temperature at or above the transition temperature of the fluoropolymer and then holding the fluoropolymer at a temperature incrementally above the melting temperature of the fluoropolymer. The holding period allows the chlorine or fluorine in the chloro-fluoro-polymer subunits of the fluoropolymer to react with the metal and thereby securely bond the fluoropolymer to the metal surface.

Abstract: Compositions suitable for application in powder coating processes are produced by melt atomisation of thermosettable mixtures. The product is characterised by improved particle size distribution and by a generally rounded particle shape.

Abstract: This invention is a blended powder mixture including a thermosetting resin and a solid, non-hydrolyzed, functional low molecular weight organosilane coupling agent. The powder mixture may be used to form a composite coating to protect a steel substrate from corrosion. The composite coating is formed by coating the substrate with an inorganic layer such as a silicate, depositing the powder mixture over the inorganic layer, heating the substrate to a temperature at least equal to the curing temperature of the resin and maintaining the substrate at the curing temperature for sufficient time to crosslink the resin and to diffuse the organosilane to the substrate whereby the crosslinked layer is coupled to the inorganic layer by the organosilane. The powder mixture includes 0.01-10 wt. % organosilane having a melting point no greater than the curing temperature of the resin. Preferred thermosetting resins include epoxy, polyester, epoxy-polyester, acrylic, acrylic-urethane or fluorovinyl.

Abstract: Filiform corrosion of aluminum and of chrome-plated steel is prevented by covering the surface of the bare metal with a powder coating containing a major amount of a thermosetting resin selected from the group consisting of polyurethanes, polyesters, and acrylics; a minor, adhesion promoting amount of an epoxy resin; and either an ultra-violet light absorber or a hindered amine light stabilizer or a mixture of both, and baking the coated article to give a clear coating on the metal.

Abstract: A curing agent for a composition for the production of matt epoxide and hybrid powder coatings which is a mixture comprising:a) salts of phthalic, isophthalic and terephthalic acid and the following guanidines. ##STR1## wherein R, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 may be identical or different radicals selected from the group consisting of H, (cyclo)alkyl and aromatic hydrocarbon radicals having 1-9 carbon atoms and where R.sup.1 with R.sup.2 and R.sup.3 with R.sup.4 each form a ring which contains an oxygen atom as heteroatom, and 0.5-2 mol of the guanidine A) react per mole of acid, andb) pyromellitic acid and/or trimellitic acid, 0.25-2 mol of b) employed per mole of a).

Abstract: A method of corrosion protecting steel structural components, such as motor vehicle structural frames and engine cradles, the method comprising: a steel shot blast mechanical cleaning of the steel structural component to remove scale, rust, and other oxidation residues, then an aluminum oxide shot blast mechanical cleaning of the steel structural component to remove any residual ferrous material, to flatten any undesirable metal peaks, and to leave a thin layer of aluminum oxide on the component, then the application of a powder paint, and then baking the steel structural component.

Abstract: A powder coating line for coating either coiled strip or pre-sheared and punched blanks is provided. In order to coat strip a catenary portion of the strip is suspended through a powder coating subsystem which includes a powder coating booth and a curing oven. The coated strip is the recoiled onto a rewind reel. In the alternative, the strip may be stopped and sheared at an input region and presheared blanks introduced to the powder coating subsystem. The blanks are placed on a belt conveyor, which transports them into the powder coating booth. The blanks are then passed in a conveyor through the powder coating booth and over for subsequent restacking. After passing out of the oven, and before coiled or stacking occurs, the strip or blanks pass through a quench and an air dryer. The powder coating subsystem can be incorporated into a larger pre-treating, cleaning, embossing or post-processing line.

Abstract: Spherical resin particles in micron order with a narrow particle diameter distribution, methods for the production thereof and uses thereof are disclosed. Overcoming various problems comprised in the hitherto-known polymerization granulation methods, resin particles using a condensation polymer in micron order of the present invention having spherical form and narrow particle diameter distribution serve well for various applications.

Abstract: A fluororubber-containing powder coating composition comprising a fluororubber, an adhesion-preventing material and optionally a cross-linking agent, which composition has an particle size of 10 to 2,000 .mu.m and an apparent density of at least 0.2 g/cc, which provides a homogeneous smooth coated film having no or only a small amount of bubbles.

Abstract: A polymer composite includes a thermoplastic plastic polymer having a fine grain metal or metal oxide dispersed therein. Preferably, the fine grains has a size of about 1,000 nm or less. A method of making the polymer composite by adhering a metal layer to a thermoplastic polymer layer in a thermodynamically nonequilibrated condition followed by relaxation of the polymer layer to obtain thermodynamic equilibrium which causes the metal layer to be absorbed by the polymer layer as fine grains is also disclosed.