Metal Coating Patents (Class 427/319)
  • Patent number: 5837317
    Abstract: The present invention provides a method of producing a hydrogen storage alloy low in cobalt content which can restrains a decrease in cycle life characteristic and preservation characteristic of an alkaline storage battery when the alloy is used as a negative electrode. The method includes the following steps. An Mm-Ni system hydrogen storage alloy which has a crystal structure of CaCu.sub.5 and contains 15 atom % or less of cobalt is powdered to have an average particle diameter of 10-100 .mu.m. Then, the powdered alloy is immersed in a treatment solution at 80.degree.-130.degree. C., the treatment solution comprising an alkaline aqueous solution containing 10 g/l or more of lithium hydroxide and having a specific gravity of 1.1 or higher, and cobalt ions which is contained in the alkaline aqueous solution, thereby forming a layer containing nickel and cobalt in higher concentration than in the bulk of the powdered alloy onto the alloy surface.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: November 17, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yoshio Moriwaki, Yoichi Izumi, Yasuharu Yamamura, Hideo Kaiya
  • Patent number: 5730853
    Abstract: A method for plating a graphite aluminum metal matrix composite material with nickel and gold utilizes the steps of: cleaning a surface of the metal matrix composite material so as to substantially remove grease and particulates therefrom; forming a layer of copper upon the surface of the metal matrix composite material; heating the copper layer to drive out entrapped fluids; applying acid to the copper layer to remove oxidation therefrom; forming a layer of nickel upon at least a portion of the layer of copper; heating the nickel layer to relieve stress therein; and electrolytically forming a layer of gold upon at least a portion of the layer of nickel.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: March 24, 1998
    Assignee: Northrop Grumman Corporation
    Inventors: Carl R. Smith, Marvin J. Back, Breton Johnson, John R. De Valle, Lawrence J. Maher
  • Patent number: 5725907
    Abstract: A metal material characterized in that the material comprises a substrate metal, a film comprising a nickel fluoride layer and formed on the substrate metal, and a film comprising a carbon layer and formed on the film.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: March 10, 1998
    Assignees: Hashimoto Chemical Co., Ltd., Mitsubishi Aluminum Co., Ltd.
    Inventors: Tadahiro Ohmi, Kazuo Chiba, Hideo Kume, Yutaka Mikasa, Matagoro Maeno, Yoshinori Nakagawa, Hiroto Izumi, Kazuhito Yamane
  • Patent number: 5677005
    Abstract: In connection with the manufacture of zinc hot dip galvanized or galvannealed steel strip using a high strength, high tensile steel strip containing Si, Mn or Cr as a starting steel strip, the invention provides a method for hot dip galvanizing a high tensile steel strip with minimal bare spots which can manufacture a bare spot-free steel strip of quality in an inexpensive manner while minimizing process complications and lowered productivity. The invention is achieved by subjecting a cold rolled steel strip containing at least one component of 0.1 to 2.0% of Si, 0.5 to 2.0% of Mn, and 0.1 to 2.0% of Cr and optionally further containing up to 0.2% of P, in % by weight, to recrystallization annealing in a continuous annealing line, cooling the steel strip, removing a steel component concentrated layer at the surface of the steel strip by polishing and/or pickling, subjecting the steel strip again to heat reduction at a temperature from 650.degree. C.
    Type: Grant
    Filed: February 13, 1995
    Date of Patent: October 14, 1997
    Assignee: Kawasaki Steel Corporation
    Inventors: Makoto Isobe, Nobue Fujibayashi, Kazuaki Kyono, Nobuo Totsuka, Nobuyuki Morito
  • Patent number: 5569543
    Abstract: A method and composition for coating an automotive brake rotor to render it corrosion resistant without impeding the braking function of the rotor, includes cleaning the rotor and thereafter applying a coating composition thereto which composition includes an inorganic alkali metal-silicate binder and a finely divided metal admixed therewith.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: October 29, 1996
    Assignees: Inorganic Coatings, Inc., Ford Motor Company
    Inventors: Parke Schaffer, Jr., Thomas Laughin, David M. Mann
  • Patent number: 5547709
    Abstract: A process for surface treatment and wear resistant coating of opening rollers for open end spinning of the type having a basic metallic body and a raw wire clothing, includes the steps of introducing the opening roller into a sealing bath in such a way that this sealing bath fills even the smallest voids between the raw wire and the basic body of the roller, rinsing off the opening roller clean on the outside, heat treating the opening roller, and subjecting the opening roller thus pretreated to deburring and antiwear coating in a conventional manner.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: August 20, 1996
    Assignee: Elektroschmelzwerk Kempten GmbH
    Inventors: Jorg Lukschandel, Rudolf Patzon, Jurgen Hassler
  • Patent number: 5518769
    Abstract: It is an object to provide a process for manufacturing galvannealed steel sheets exhibiting excellent anti-powdering property when press formed, and uniform frictional properties in a coil. A steel strip is galvanized in a bath having a low aluminum content after entering it at a high temperature as defined in relation to the aluminum content of the both, so that the formation of a .zeta. phase may be promoted. Then, the strip is heated for alloying in a high-frequency induction heating furnace so as to have a temperature not exceeding 495.degree. C. when leaving the furnace to yield a plated steel strip having a coating containing a uniformly distributed .zeta. phase. After such heat treatment and cooling, the strip can be plated with an iron or iron-alloy top coating having an iron content of at least 50% and a coating weight of at least 1 g/m.sup.2 to achieve an improved press formability.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: May 21, 1996
    Assignee: NKK Corporation
    Inventors: Masaru Sagiyama, Masaki Abe, Junichi Inagaki, Akira Hiraya, Masaya Morita
  • Patent number: 5506017
    Abstract: This patent teaches a new method of roughening the surface of a magnetic recording medium in order to reduce the stiction and friction between a recording head and the medium to thereby improve mechanical reliability. During this method, the medium substrate is heated to form second phase precipitates which result in roughening of the medium surface. The medium roughness can be controlled by proper selection of the heating temperature and time and the substrate alloy. This results in improved contact-start-stop (CSS) performance of the medium. The method of the present invention allows for lower costs and potentially higher throughput than conventional texturing processes.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 9, 1996
    Assignee: Komag Incorporated
    Inventors: Rajiv Y. Ranjan, Kuo H. Huang, Caroline A. Ross
  • Patent number: 5472739
    Abstract: A process of producing a hot dipped wire. During the wire drawing, the base wire is passed over a passage surface made of a non-iron material. After steam heating, cleaning and drying steps, the wire is heated in an atmosphere of a reducing gas for effectively removing an oxide layer on the surface of the wire and for preheating the wire to accelerate a reaction between the wire and a molten hot dipping metal used in the subsequent hot dipping step.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: December 5, 1995
    Assignee: Totoku Electric Co., Ltd.
    Inventors: Misao Kubota, Yoshitada Hanai, Kouichi Otani
  • Patent number: 5472740
    Abstract: A process of producing a hot dipped wire. During the wire drawing by the use of a water soluble lubricant, the base wire is passed over a passage surface made of a non-iron material. The drawn wire is heated in an atmosphere of a reducing gas for effectively removing an organic residue such as the lubricant and/or an oxide such as an iron oxide, inevitably adhered to the surface of the wire, and for annealing and for preheating the wire to accelerate a reaction between the wire and a molten hot dipping metal used in a subsequent hot dipping step.
    Type: Grant
    Filed: October 3, 1991
    Date of Patent: December 5, 1995
    Assignee: Totoku Electric Co., Ltd.
    Inventors: Misao Kubota, Yoshitada Hanai, Kouichi Otani
  • Patent number: 5339329
    Abstract: A shallow vessel (50,52) for being horizontally disposed when containing a molten metal or metal alloy (66) for meniscus coating one side of a clean metal strip (34A) when the strip is moved vertically past one side of the vessel. The vessel includes a shell (68) such as austenitic stainless steel, a refractory lining (70), a molten metal departure lip (72) mounted on the upper surface of the side of the vessel, a spirally shaped induction coil (64) for maintaining the molten metal above its melting point and a flux concentrator (74). The induction coil is positioned below the refractory lining and the flux concentrator is positioned below the induction coil. The induction coil and the flux concentrator underlie the area occupied by the molten metal.
    Type: Grant
    Filed: January 25, 1993
    Date of Patent: August 16, 1994
    Assignee: Armco Steel Company, L.P.
    Inventors: Charles Flinchum, Gerald L. Barney, Gregory S. Burgess, Davis L. Kleinmeyer, Larry E. Parrella
  • Patent number: 5312650
    Abstract: The method of making a composite article of different metal portions by spraying molten metal on the surface of a solid metal member that has been cleaned and preheated in a controlled atmosphere at low pressure. The molten metal is sprayed on the surface of the solid metal member, preferably by plasma jet spraying. It is rapidly solidified to be adherent to the surface of the solid metal member to form a composite preform. The composite preform is cooled at a rate sufficiently low to reduce residual stresses and then hot pressed to eliminate voids in the sprayed metal portion and metallurgically bonded to the surface of the solid member.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: May 17, 1994
    Assignee: Howmet Corporation
    Inventors: Ranes P. Dalal, John M. McFadden, Mark J. Straszheim, Louis E. Dardi
  • Patent number: 5290588
    Abstract: An improved process is provided for forming a multilayer structure (18) suitable for tape automated bonding thereto or for forming contacts. In the process, a first layer (12) of aluminum is formed on a substrate (10), a second layer (14) of a TiW alloy is formed on the first layer of aluminum, and a third layer (16) of gold is formed on the second layer of the TiW alloy, to which third layer of gold bonding is done. The improvement comprises annealing the second layer of the TiW alloy in an inert atmosphere at a temperature less than about 500.degree. C. for a period of time sufficient to form a film of an Al--TiW phase (20), believed to comprise TiAl.sub.3, at the interface between the first layer of aluminum and the second layer of the TiW alloy. The annealing is done prior to forming the third layer of gold on the second layer of the TiW alloy.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: March 1, 1994
    Assignee: Advanced Micro Devices, Incorporated
    Inventors: Jeremias D. Romero, Homi Fatemi, Eugene A. Delenia, Muhib M. Khan
  • Patent number: 5271967
    Abstract: A method for the application of a thermal spray coating to the cylinder wall portions of an aluminum engine block casting is disclosed in which the casting is inverted and water is caused to flow through the cooling passages of the engine block in a series flow from one end of a bank of cylinders to the other while the block is supported on a fixture that seals the cooling passage outlets in the head of the block. The fixture further permits the spray of a metallized coating onto the cylinder walls without adherence of the spray to the fixture or to other portions of the block.
    Type: Grant
    Filed: August 21, 1992
    Date of Patent: December 21, 1993
    Assignee: General Motors Corporation
    Inventors: Martin S. Kramer, Larry E. Byrnes, Gary L. Holmes
  • Patent number: 5252360
    Abstract: A process for the production of engraved rolls and plates for printing operations wherein there are applied to a base member of metal, after it has been engraved, at least two layers of a metal and, respectively, a metal compound for increasing the hardness and the corrosion protection in order to achieve surface hardness values of at least 2000 HV.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: October 12, 1993
    Inventors: Wolfgang Huttl, Alois Vester
  • Patent number: 5223052
    Abstract: A method treating a surface of rotors in a screw-type rotary fluid machine, with the method comprising the steps of: conducting a non-electrolytic Ni plating on the surface of each rotor so as to form a first layer of non-electrolytic Ni plating layer; heating the rotor having the first layer at a temperature not lower than 500.degree. C.; and forming, at least, a second layer of an organic resin so as to cover the first layer.
    Type: Grant
    Filed: April 3, 1991
    Date of Patent: June 29, 1993
    Assignee: Hitachi, Ltd.
    Inventors: Akihiko Yamamoto, Toshihiro Yamada, Tatsuo Natori, Kotaro Naya, Motohiro Satoo, Mitsuru Fujiwara, Katsumi Matsubara, Kazuaki Shiinoki, Hirotaka Kameya
  • Patent number: 5198268
    Abstract: Preparation of feed screw having a wear resistant alloy coating thereon for the injection molding or extrusion of plastic. Nickel-based alloys that have shown themselves to be compatible with inlaid barrel liners by virtue of similar wear ratios, modulus of elasticity, ultimate yield strength, and linear thermal coefficients of expansion, are sprayed at high velocity onto a heated feed screw to mechanically bond the alloy to the feed screw. The alloy is then fused to the feed screw in a controlled manner. Following the fusing process, the feed screw and alloy thereon is heated and allowed to cool in a highly controlled environment to produce a crack-free dense coating of the alloy on the screw substrate.
    Type: Grant
    Filed: November 14, 1991
    Date of Patent: March 30, 1993
    Assignee: Xaloy, Incorporated
    Inventor: David Grossman
  • Patent number: 5077094
    Abstract: A process for applying a metal coating 11 to a metal strip substrate 2 by preheating the casting surface in a non-oxidizing atmosphere and maintaining a casting surface temperature T.sub.s below the solidus temperature of the metal coating material, passing the casting surface through a melt pool 9 of the metal coating material at a pool temperature at least 25.degree. C. in excess of its melting temperature to deposit a melt layer 21 at a casting temperature T.sub.c, and simultaneously rapidly cooling the metal strip substrate from the back surface to solidify the melt layer to an adherent solid coating, wherein the surface temperature T.sub.s is less than about 20 percent (in .degree.K.) below the casting temperature T.sub.c.The process is particularly useful when coating metal strip with an alloy of limited solubility metals.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: December 31, 1991
    Assignee: Battelle Development Corp.
    Inventors: James L. McCall, Robert E. Maringer
  • Patent number: 5071672
    Abstract: A process for heating and coating a weld joint in a pipe comprising placing an open heating and coating ring on the pipe over the center of the weld joint; the heating and coating ring being an articulated yoke adapted to encircle the pipe when the ring is in the closed position and comprising an upper yoke section and two side yoke sections which pivot with respect to the upper yoke section, a pair of releasable locking devices mounted on the upper yoke section for engaging the side yoke sections when the latter are pivoted outwardly away from each other to an open position of the ring thereby locking the side yoke sections in the open position; the upper yoke section having a powder dispensing system mounted thereon for later dispensing a powdered coating material therefrom onto the surface of the pipe; each side yoke section having an induction heating assembly mounted thereon, each induction heater assembly including an induction coil comprising a length of hollow copper tubing wound in an elliptical patt
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: December 10, 1991
    Assignee: Commercial Resins Company
    Inventors: Ronald E. Carlson, Jr., David Paulley
  • Patent number: 5071678
    Abstract: A process for forming a diffusion coating to the surface of a metal article. The process is particularly adapted for forming diffusion aluminide coatings on metal blades and vanes used in gas turbine engines. According to the invention, halide vapor is caused to react with a source of aluminum to form an aluminum rich halide gas. This gas then reacts with the part surface to form the aluminide coating. A key aspect of the invention relates to the timing of the reaction between the halide vapor and the source of aluminum.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: December 10, 1991
    Assignee: United Technologies Corporation
    Inventors: Edward J. Grybowski, Walter E. Olson
  • Patent number: 5055319
    Abstract: A process for depositing metal oxides by activated reactive evaporation (ARE) wherein deposition rate and film quality is controlled by reference to the relative amounts of metal and metal oxide present on the surface of the target material. The ratio of metal surface area to metal oxide surface area required to obtain high deposition rates is achieved by maintaining a relatively high concentration of oxygen in the reaction zone. This relative ratio of metal surface area to metal oxide surface area on target material provides a continuous indirect measure of film deposition rate and quality during the ARE process.
    Type: Grant
    Filed: April 2, 1990
    Date of Patent: October 8, 1991
    Assignee: The Regents of the University of California
    Inventors: Rointan F. Bunshah, Chandra V. Deshpandey, Hans J. Doerr, Jong S. Yoon
  • Patent number: 5041309
    Abstract: An improved method of diffusion coating a workpiece, such as ferritic tubing employing a ceramic carrier provided with a diffusion composition. The diffusion composition includes a diffusion element such as chromium, silicon, aluminum, and boron. The carrier is subjected to an elevated diffusion temperature in a controlled environment to diffusion coat either the external or internal surface of the workpiece.
    Type: Grant
    Filed: February 28, 1990
    Date of Patent: August 20, 1991
    Assignee: The Babcock & Wilcox Company
    Inventors: Thomas L. Davis, Dale F. LaCount, Steven E. LeBeau, Kenneth D. Seibert
  • Patent number: 5032421
    Abstract: This invention includes a method featuring steps having a transport (64, 68) to carry metal articles (10, 14) through a vacuum chamber (62, 66, 90) containing a plasma cleaning station (32) followed by exposure to an evaporant of metal (42) generated by an E-Beam (50) caused to condense on the articles in high vacuum. A channel structure (51) is provided to cause selective condensation upon the surface of said articles. The apparatus includes several stations (101, 102, 103) to provide multiple coatings on one or both sides of an article to be coated.
    Type: Grant
    Filed: August 21, 1990
    Date of Patent: July 16, 1991
    Assignee: AMP Incorporated
    Inventors: Srinivasan V. Sarma, Walajabad S. Sampath, Nagarajan Subramanian, Paul J. Wilbur
  • Patent number: 4981716
    Abstract: A method for providing a metal substrate with an impact resistant surface is disclosed. The surface of the substrate is exposed to high intensity laser radiation to melt a spot of the surface. Particles of a material such as WC are injected into the melt.In order to enhance the percentage of particles in the surface, thus increasing the wear resistance, there is a forced reflection of stray particles back toward the melted spot.Further a fixture for holding the substrate, comprising the essential reflection surfaces for achieving the desired back reflection is described as well as a device for carrying out the method.
    Type: Grant
    Filed: May 3, 1989
    Date of Patent: January 1, 1991
    Assignee: International Business Machines Corporation
    Inventor: Per Sundstrom
  • Patent number: 4908226
    Abstract: A method for depositing metallic lines on an IC chip or mask is described using a focused ion beam (FIB) with a much lower ion dosage than previously required, on the order of 10.sup.14 -10.sup.15 ions/cm.sup.2. A substrate is scanned with the FIB to produce a series of nucleation sites on the substrate surface. These nucleation sites can be in an adlayer or can be produced by lattice damage or sputtering directly in the substrate material. The substrate is then exposed to a source gas containing the material to be deposited, while heated to a temperature slightly less than the spontaneous thermal decomposition temperature of the source gas. This results in a well-defined line of materials being deposited from the source gas along the line defined by the nucleation sites. The ratio of the spontaneous activation energy to the autocatalytic activation energy for the gases is preferably at least about an order of magnitude, and the FIB is preferably moved in multiple scans across the desired line.
    Type: Grant
    Filed: May 23, 1988
    Date of Patent: March 13, 1990
    Assignee: Hughes Aircraft Company
    Inventors: Randall L. Kubena, Thomas M. Mayer
  • Patent number: 4888215
    Abstract: A granular carbonaceous heat insulator comprising a carbon black pellet the surface of which is coated with a carbon layer having a dense structure is disclosed. This heat insulator is prepared by adhering a binder solution to a carbon black pellet, heating the resulting coating to remove a solvent from the binder solution and, at the same time, to cure the binder, and baking the carbon black pellet coated with the cured binder in a non-oxidizing atmosphere to carbonize the cured binder. Alternatively, the heat insulator is prepared by subjecting a carbon black pellet having specific characteristics to wet granulation in the presence of a binder solution to crush the carbon black pellet and, at the same time, to granulate the crushed pellet, thereby preparing a granulated carbon black pellet, followed by removal of the solvent from the prepared pellet, curing of the binder and baking of the cured binder in the same manner as that described above.
    Type: Grant
    Filed: December 17, 1987
    Date of Patent: December 19, 1989
    Assignee: Tokai Carbon Co., Ltd.
    Inventors: Toshio Nakada, Fumio Takemura, Masao Ishiwata
  • Patent number: 4856174
    Abstract: A stainless steel vacuum bottle comprises inner and outer bottles made of stainless steel, the inner and outer bottles being joined together at tip portions of their bottle necks to form a double-walled construction with a space between the two bottles, the space being evacuated. The vacuum bottle is characterized in that surfaces surrounding the space of the inner and outer bottles are provided, on at least the outer surface of the inner bottle, with an oxide layer and a silver mirror layer formed thereon.
    Type: Grant
    Filed: May 17, 1985
    Date of Patent: August 15, 1989
    Assignee: Zojirushi Vacuum Bottle Co., Ltd.
    Inventors: Hidetsurumaro Ishizaki, Riyozo Taguchi
  • Patent number: 4755265
    Abstract: Methods for depositing metals on or removing metals from substrates are provided which involve the use of electrolytic cells comprising an anode and cathode, sulfuric acid, and a chalcogen-containing compound soluble in said bath and having the empirical formula ##STR1## wherein X is a chalcogen, each of R.sub.1 and R.sub.2 is selected from hydrogen, NR.sub.3 R.sub.4 and NR.sub.5, at least one of R.sub.1 and R.sub.2 is other than hydrogen, each of R.sub.3 and R.sub.4 is hydrogen or a monovalent organic radical, and R.sub.5 is a divalent organic radical, in which the molar ratio of the chalcogen compound to sulfuric acid is about 1 or more, and the molar ratio of water to the combination of acid and chalcogen compound is about 20 or less.
    Type: Grant
    Filed: March 3, 1987
    Date of Patent: July 5, 1988
    Assignee: Union Oil Company of California
    Inventor: Donald C. Young
  • Patent number: 4729905
    Abstract: A method for the production of cutting tools from an iron-based alloy and having a wear-resistant coating based on interstitial phases is provided and comprises depositing the wear-resistant coating by condensing a cathode material evaporable by an arc discharge, use being made of titanium or a titanium-based alloy as the cathode material. Upon depositing a coating of a predetermined thickness, an oxygen-containing redox gas or gaseous mixture is fed into the vacuum chamber and the cutting tool is heated up to the temperature of the eutectoid decomposition in the pseudobinary `iron-titanium` system. Thereupon the cutting tool is subjected to annealing in an atmosphere of the oxygen-containing redox gas or gaseous mixture for 10 to 40 minutes at the temperature of the martensitic transformation in the pseudobinary `iron-titanium` system.
    Type: Grant
    Filed: January 9, 1987
    Date of Patent: March 8, 1988
    Assignee: Vsesojuzny Nauchno-Issledovatelsky Institut Instrumenta
    Inventors: Viktor P. Zhed, Alexei G. Gavrilov, Elena I. Kurbatova, Andrei K. Sinelschikov, Albert M. Boyarunas, Vitaly M. Smirnov
  • Patent number: 4726967
    Abstract: In an isotope separation system in which hot, isotopically separated vapor is deposited on enriched product and depleted tails plates, deposit adherence is improved and plate cooling simplified. The tails plate is liquid-cooled to a lower temperature which permits the product plate to be radiatively cooled by it simplifying product plate cooling and lowering its temperature to reduce the tendency for the product plate deposit to separate during temperature cycling. In one embodiment plate surfaces are cleaned of impurities in a vacuum by allowing the temperature of the tails plates to reach the relatively low operating temperature prior to proceeding with the deposition. In another embodiment plate surfaces are provided with rough surfaces to promote air penetration during deposit stripping, which permits the formation of a brittle, more easily severed bond between plate and deposit.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: February 23, 1988
    Assignee: Jersey Nuclear-Avco Isotopes, Inc.
    Inventors: Paul N. Arendt, Michael A. Bayne, Lester M. Finch
  • Patent number: 4719962
    Abstract: The metal substrate (4) is covered with a coating (6) consisting of another metal or alloy having a thickness of 4 to 50 .mu.m, by deposition of molten metal or alloy (5) through a nozzle (2), this melting point [sic] being lower than that of the substrate metal. This coating comprises, at the interface with the substrate, a layer of intermetallic compound with a thickness of between 0.5 and 4 .mu.m not exceeding 40% of the total thickness, the remainder consisting of the initial metal or alloy used for the coating, in a proportion of between 97% and 99.5% by weight.
    Type: Grant
    Filed: November 3, 1986
    Date of Patent: January 19, 1988
    Assignee: Battelle Memorial Institute
    Inventors: Georges Haour, Dag F. Richter, Peter Boswell, Willy Wagnieres
  • Patent number: 4713262
    Abstract: A method for manufacturing a magnetic recording medium, comprising evaporating a magnetic metal material from an evaporation source to form a vapor stream of the magnetic metal material, vapor-depositing the magnetic metal material on a tape-shaped substrate moving along a cooling can such that the incident angle (.theta.) of the vapor stream which is incident upon the substrate changes continuously from a high incident angle (.theta.max) to a low incident angle (.theta.min), and at the same time introducing one or more gases selected from the group consisting of a rare gas, CO.sub.2 gas, N.sub.2 gas, and nitrogen oxide gas, or a mixed gas composed of oxygen gas and one or more gases selected from the group consisting of a rare gas, CO.sub.2 gas, N.sub.2 gas and nitrogen oxide gas from a gas inlet part disposed at a position in the vicinity of the substrate and near the vapor stream at a low incident angle (.theta.min) upon the substrate, thereby providing a ferromagnetic metal film on the substrate.
    Type: Grant
    Filed: October 2, 1986
    Date of Patent: December 15, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Yasunaga, Ryuji Shirahata
  • Patent number: 4702935
    Abstract: A production method for producing a high permeability alloy film which includes evaporating an alloy material composed of 1-6 wt % Al, 20-35 wt % Si, and the remainder of iron by irradiating the alloy with an electron beam, and then depositing the vapor from the alloy material onto a substrate for a predetermined time to produce an alloy film composition having a high permeability. The vapor deposition onto the substrate is preferably intercepted with the shutter until the concentration of aluminum of the vapor to be deposited has been decreased to a value between 20 and about 4 wt %.
    Type: Grant
    Filed: October 22, 1984
    Date of Patent: October 27, 1987
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Masaru Kadono, Kumio Nago, Tatsushi Yamamoto, Tersuro Muramatsu, Shuuhei Tsuchimoto, Mitsuhiko Yoshikawa, Masatoshi Tomita
  • Patent number: 4686017
    Abstract: An electrolytic bath, suitable for depositing a metal on or removing a metal from a substrate is provided which comprises an anode and cathode, an acid having a pK.sub.a of about 6 or less, and a chalcogen-containing compound soluble in said bath and having the empirical formula ##STR1## wherein X is a chalcogen, each of R.sub.1 and R.sub.2 is selected from hydrogen, NR.sub.3 R.sub.4 and NR.sub.5, at least one of R.sub.1 and R.sub.2 is other than hydrogen, each of R.sub.3 and R.sub.4 is hydrogen or a monovalent organic radical, and R.sub.5 is a divalent organic radical, in which the molar ratio of the chalcogen compound to the acid is about 1 or more, and the molar ratio of water to the combination of acid and chalcogen compound is about 10 or less.
    Type: Grant
    Filed: June 28, 1985
    Date of Patent: August 11, 1987
    Assignee: Union Oil Co. of California
    Inventor: Donald C. Young
  • Patent number: 4657787
    Abstract: Aluminum is flow-coated onto ferrous strip by reducing the hot strip in hydrogen, cooling it to 650.degree.-680.degree. C. in nitrogen and spraying molten aluminum on it such that the aluminum splats flow into each other but solidify in 0.2-0.5 seconds. The aluminum is bonded to the strip through an intermetallic layer less than quarter of the total coating thickness, the aluminum having a cast structure.
    Type: Grant
    Filed: July 31, 1985
    Date of Patent: April 14, 1987
    Assignee: National Research Development Corporation
    Inventors: Alfred R. E. Singer, Walter N. Jenkins, Asgar M. H. Alibhai
  • Patent number: 4650700
    Abstract: Surface treatment of metal blanks is achieved by applying an oxirane ring-containing compound in the gas phase to the surface of a metal blank maintained at a high temperature. According to this method, a covering layer which is much thinner than a conventional so-called adhesive primer coating layer and has a thickness of the angstrom order is formed on the surface of a metal blank. If a thermoplastic resin layer is coated on the metal surface treated with this oxirane ring-containing compound, the initial adhesion and the adhesion after lapse of time are highly improved over these adhesions attainable by the conventional methods. Even if a lacquer containing a thermosetting resin instead of the thermoplastic resin is coated and dried on the metal surface treated with this bonding compound, a similar effect can be attained.
    Type: Grant
    Filed: October 11, 1985
    Date of Patent: March 17, 1987
    Assignee: Toyo Seikan Kaisha, Ltd.
    Inventors: Yoichi Kitamura, Hisashi Hotta
  • Patent number: 4627896
    Abstract: Method for applying a corrosion-protection layer to the base body (1) of a gas turbine blade by embedding particles (3) of SiC in a metallic matrix by means of powder, paste or electrolytic/electrophoretic methods and compacting, welding or fusing and bonding the matrix-forming material to the base body (1) by means of hot-pressing, hot isostatic pressing or laser beam, electron beam or electric arc. Protective layers are formed which do not flake off and with high silicon content which is at least partially contained in the embedded, partly modified SiC particles (6) as a reservoir for the operation.
    Type: Grant
    Filed: June 27, 1985
    Date of Patent: December 9, 1986
    Assignee: BBC Brown, Boveri & Company Limited
    Inventors: Mohamed Nazmy, Robert Singer
  • Patent number: 4627990
    Abstract: A method of and an apparatus for supplying a powdery material to a workpiece to be processed thereby. According to the method, the powdery material is discharged from a hopper and metered, and then fed into a tube extending in the vicinity of the workpiece. Ultrasonic vibrations are imparted to the tube to supply the powdery material to a portion to be processed of the workpiece while the amount of the supplied powdery material is being detected. The apparatus includes a hopper for storing the powdery material, the hopper having an outlet, a tube extending from the outlet to a position adjacent to the workpiece for conveying the powdery material therethrough, and an ultrasonic vibrating device mounted on the tube for imparting ultrasonic vibrations to the tube, and a device mounted on the tube for detecting the amount of the powdery material supplied through the tube.
    Type: Grant
    Filed: March 6, 1985
    Date of Patent: December 9, 1986
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Toshihiko Saga, Tsuyoshi Makita, Hisao Hirono, Akitaka Inao
  • Patent number: 4595600
    Abstract: A method and apparatus for uniformly cladding a metal wire with a coating of a second metal is provided. The metal wire to be coated is preheated in a non-oxidizing atmosphere to a temperature slightly less than the melting point of the metal coating. The metal coating is present as a molten metal in an atomization chamber. A source of preheated, pressurized, non-oxidizing gas is utilized to inject such gas into spray nozzles. Each spray nozzle also receives molten metal that is drawn into and atomized in the nozzle. The molten metal is thusly sprayed onto the metal wire moving through the atomization chamber.
    Type: Grant
    Filed: November 13, 1984
    Date of Patent: June 17, 1986
    Assignee: FL Industries, Inc.
    Inventors: James C. Keeven, Donald R. Felin, Henry J. Fisher
  • Patent number: 4529628
    Abstract: The coating device comprises a furnace (1) comprising a crucible (4) and a lateral distribution conduit (3) whose outlet communicates with an externally open release aperture (2) serving to distribute the molten metal over the entire width of the metal strip (6) to be coated. This strip (6) is entrained from a supply spool (7) to a storage spool (8) and passes over a positioning roll (10) mounted opposite to the release aperture (2), the spacing between this roll and the edge of the release aperture being adjustable by means of a screw (15). A bank of burners (16) is located opposite to the reverse of the strip (6) and upstream of the release aperture (2) in order to heat the strip before it passes in front of the release aperture (2). A molten metal bath is thus constantly maintained between this release aperture (2) and the face to be coated of the strip (6) which is covered with a layer of metal during its displacement.
    Type: Grant
    Filed: July 12, 1982
    Date of Patent: July 16, 1985
    Assignee: Battelle Memorial Institute
    Inventors: Georges Haour, Michel Kornmann, Wagnieres Willy
  • Patent number: 4521663
    Abstract: Wear resistant coatings of highly alloyed filler metal are deposited on base materials of carbon and manganese bearing ferrous alloys and this, depending on the carbon and manganese content of the base material with or without buffer layer, employing low current levels such that the quotient current level/diameter of filler metal wire lies between 70 and 80 and the corresponding quotient for the buffer layer between 120 and 160.Selected as filler metal are alloys containing 3.0-4.5% Si, 1.5-2.0% Mn, and C.gtoreq.5%, preferred is the composition 5.5% C, 12.5% Cr, 2.0% Mn, 4.0% Si, 8.0% Mo, 8.0% Nb, 2.0% W, 1.0% V, 57.0% Fe.
    Type: Grant
    Filed: May 16, 1983
    Date of Patent: June 4, 1985
    Assignee: Swiss Aluminum Ltd.
    Inventor: Marinus C. Kesting
  • Patent number: 4505946
    Abstract: A method for coating metal with a dissimilar metal which comprises heating a parent metal at a temperature at which substitution of a halide metal for said parent metal occurs or a higher temperature while directly contacting the powdered halide metal with the surface of said parent metal to effect the substitution reaction of said halide metal, then cooling the resulting product, and removing the residue from said product.
    Type: Grant
    Filed: November 30, 1981
    Date of Patent: March 19, 1985
    Assignee: Aichi Steel Works, Limited
    Inventors: Michihiko Suzuki, Katsukiyo Kawaguchi, Yoshihiko Kojima
  • Patent number: 4481264
    Abstract: The invention relates to a method for chromizing metallic pieces such as steel pieces and to chromized metallic pieces obtained thereby, said metallic pieces, particularly steel, comprising a chromized surface layer with a hardness at least equal to 1200 Vickers degrees and a thickness at least equal to 12 microns as well as an adjacent sub-layer with a hardness less than that of the core of said piece. The chromized surface layer has a depth preferably at least equal to 20 microns, more preferably 30 microns, and the hardness of the sublayer presents a maximum variation of 25 Vickers degrees with respect to that of the core of said piece.
    Type: Grant
    Filed: November 20, 1981
    Date of Patent: November 6, 1984
    Assignee: Societe Anonyme Dite: Aubert & Duval
    Inventor: Andre Faure
  • Patent number: 4478892
    Abstract: An improved method of and apparatus for hot dip metal coating of steel strip in which the strip is heated and cleaned in a furnace then passed through a protective hood containing a reducing gas and into the molten coating metal bath. Coating metal oxides evolved in the hood are removed by flowing a nonoxidizing gas across the surface of the coating metal in the hood and withdrawing the gas and entrained oxides from a location in the vicinity of the coating metal surface. The oxides are removed from the withdrawn gas, and the gas returned to be again flowed across the coating metal surface.
    Type: Grant
    Filed: March 16, 1983
    Date of Patent: October 23, 1984
    Assignee: National Steel Corporation
    Inventor: Paul E. Amberson
  • Patent number: 4477291
    Abstract: Aluminium is coated on steel strip. The steel strip is heated in hydrogen to reduce surface oxides to iron, and is then sprayed at 400.degree. C. with nitrogen-atomized molten aluminium to a depth of 150 microns. Still in nitrogen/hydrogen, at 350.degree. C., the coated strip is rolled. Under these conditions, the aluminium is subjected to very high compressive stress (compared with its yield stress) while the steel does not even reach its yield stress.
    Type: Grant
    Filed: March 1, 1984
    Date of Patent: October 16, 1984
    Assignee: National Research Development Corporation
    Inventor: Alfred R. E. Singer
  • Patent number: 4467016
    Abstract: Low alloy steel tubing is decarburized, chromized and then aluminized with or without masking at the sites at which the tubing is to be welded in place, to greatly increase resistance of the tubing to high temperature oxidation and sulfidation. Low surface aluminum content after aluminizing makes it easier to weld at that surface.
    Type: Grant
    Filed: July 16, 1982
    Date of Patent: August 21, 1984
    Assignee: Alloy Surfaces Company, Inc.
    Inventor: Alfonso L. Baldi
  • Patent number: 4448809
    Abstract: A method of silver plating stainless steel vacuum bottle surfaces includes the steps of thermally treating the surfaces to be coated at a temperature of at least 200.degree. C. and then using an electroless plating technique to silver plate the thermally treated surfaces. The thermal treatment can be as low as 200.degree. C. if it occurs in an atmosphere of at least 5% hydrogen gas. If the thermal treatment occurs in a vacuum, however, the temperature must be at least 700.degree. C.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: May 15, 1984
    Assignee: Taiyo Sanso Co., Ltd.
    Inventors: Kiyoshi Nagai, Hiroshi Shinohara, Nobuo Imamura
  • Patent number: 4431688
    Abstract: In a case where filament-like articles (e.g. wires) are dip-coated by upwardly passing the article into a bath of molten metal through the bottom and top vertical openings of a spout containing the molten metal, the article to be coated is wrapped, before it enters the bottom inlet opening in the spout, with a blanket of protective gas at a pressure sufficient to cause the gas to penetrate into the spout simultaneously with the article, to progressively and regularly circulate around the molten metal and to steadily emerge from the upper opening of the spout still effectively shielding the freshly coated article.
    Type: Grant
    Filed: October 22, 1981
    Date of Patent: February 14, 1984
    Assignee: Kokoku Steel-Wire Ltd.
    Inventor: Michel Kornmann
  • Patent number: 4421569
    Abstract: Polymeric coatings are provided on steel pipes to protect the same against corrosion. Monomers and prepolymers are permanently adhered to the surface of steel pipes by graft polymerization to form a barrier which keeps out moisture, oxygen and other corrosive gases from the steel substrate. The monomers and prepolymers are chosen to provide a low moisture vapor transmission rate and oxygen permeability.
    Type: Grant
    Filed: May 7, 1982
    Date of Patent: December 20, 1983
    Assignee: Sharon Tube Corp.
    Inventors: Michael Dichter, Carl Horowitz
  • Patent number: RE32399
    Abstract: An improved method for manufacturing a composite metal wire including a core metal wire having extruded therearound a coating metal layer which is different in material from the core metal wire, includes feeding the coating metal into a narrow passageway which is defined between a circumferential groove formed on the outer edge of a rotary wheel and a close fitting surface of a fixed shoe block, carrying the coating metal towards an outlet end of the passageway by frictional drag with the surface of the passageway in accordance with the rotation of the wheel, and passing a core metal wire harder in material than the coating metal through a covering chamber of a larger cross sectional area which is provided with a die and a nipple at the front and rear portions, respectively, whereby the core metal wire is covered with the coating metal in the covering chamber so that a predetermined construction of a composite metal wire is extruded through the die.
    Type: Grant
    Filed: December 9, 1985
    Date of Patent: April 14, 1987
    Assignee: Hitachi Cable, Ltd.
    Inventors: Masahiro Nagai, Yasuhiko Miyake