Abstract: Blocked polyisocyanates and one-component stoving systems containing these blocked polyisocyanates, and the preparation thereof and their use for the preparation of lacquers, paints, adhesives and elastomers. The blocked polyisocyanates are derived from polyisocyanates reacted with secondary amines and cationic, anionic and/or nonionic hydrophilizing agents such that they are incorporated into the polyisocyanate at a ratio of from 20:1 to 1:1, wherein the blocking agents correspond to the formula R1–R4 can be identical or different and independently of one another denote hydrogen, C1–C6-alkyl or C3–C6-cycloalkyl, R5 denotes C1–C10-alkyl, C3–C10-cycloalkyl, and B represents ?wherein R6–R8 can be identical or different and independently of one another denote C1–C6-alkyl and/or C1–C6-cycloalkyl, R9 denotes hydrogen or C3–C6-alkyl or C3–C6-cycloalkyl.

Abstract: The invention relates to an improvement in a process for imparting barrier properties to porous substrates, such as, concrete, masonry products, and wood products. The process comprises the steps of: applying an aqueous based sealing composition comprising a polymeric resin to said porous substrate, evaporating the water and forming a water repellent coating of said polymeric resin on said porous substrate. The improvement comprises: deriving the polymeric resin from an aqueous based polymer emulsion comprising a polymer comprised of emulsion polymerized units of vinyl acetate and ethylene, preferably with a carboxylic acid monomer, the polymer containing amorphous and crystalline ethylene segments and having: (a) a crystalline melting point (Tm) ranging from 35 to 110° C., preferably 50 to 100° C.; measured at a heat rate of 20° C./minute; and, (b) a tensile storage modulus of at least 1×105 dynes/cm2 at 115° C. measured at 6.28 rad/sec.

Abstract: The invention relates to water-repellant liquid silicone compositions intended for impregnating porous building materials, such as mineral or (ligno)cellulosic materials And comprising epoxy functionalized polyorganosiloxanes as main active material in these water-repellant liquid silicone compositions. The invention also relates to a process for making said porous building materials, water-repellant with the aid of the above said liquid silicone composition, and a process for preparing this composition is also targeted by the invention.

Abstract: The present invention relates to a polyurethane surface and more specifically to a polyurethane surface derived from the catalyzed reaction of equivalent volumes of a polyisocyanate component and an active hydrogen component. The two-component system achieves optimal gel time and cure response for application as an athletic surface having an isocyanate index between about 105 and 115. Moreover, the present invention achieves these results with a 1:1 by volume two-component system, which minimizes mixing errors during application of the surface.

Abstract: The present invention relates to a method for heat processing a substrate. After a coating film is formed on the substrate, the substrate is baked at a predetermined high temperature. The baking step is performed by first increasing the substrate temperature from a predetermined low temperature to a predetermined intermediate temperature that is lower than a predetermined reaction temperature at which the coating film reacts. Next, a second baking step maintains the substrate at the predetermined intermediate temperature for a predetermined period of time, and is followed by a third step of increasing the temperature of the substrate to the predetermined high temperature that is higher than the predetermined reaction temperature. This results in uniform temperature within the surface of the substrate when the temperature of the substrate reaches the reaction temperature. Consequently, a chemical reaction due to heat processing of the coating film within the surface of the substrate is performed uniformly.

Abstract: An aqueous coating composition having improved adhesion to friable surfaces including an emulsion polymer of certain compositions and certain acid numbers having a glass transition temperature of ?20 C to 100 C and an average particle diameter less than 120 nanometers; and 0.25-10%, by weight based on emulsion polymer weight, water-soluble alkoxylated amine is provided. In addition a method for for improving adhesion to friable surfaces by using the aqueous coating compositions of the invention is provided.

Abstract: A method for forming a craft coating on a glass or ceramic substrate is provided. The method generally includes applying a coating composition comprising an acetoacetoxy functional monomer to a glass or ceramic substrate to form a craft coating thereon. The glass or ceramic substrate can form a portion of an article of windows, kitchenwares, decorative housewares, and ceramic tiles.

Abstract: A method of decorating an article, the method comprising mixing a thermochromic ink with a transparent lacquer, applying the mixture on to part or all of the surface of an article, once the mixture is set, applying a second layer of dishwasher proof transparent lacquer.

Abstract: Novel undercoats for use on porous bases such as, for example, concrete are disclosed. Said undercoats contain or comprise at least one epoxy resin, at least one latent hardener and at least one solvent. The above are characterize in being easy to produce, contain no isocyanate groups and form a good ageing-resistant adhesion, in particular, with single component isocyanate-free sealants, cross-linked by means of silane groups.

Abstract: A method of inhibiting the loss of solar reflectivity over time of an exterior elastomeric coating composition comprising an organic binder and at least one inorganic additive comprises: replacing at least a part of the at least one inorganic additive with a solid, particulate, organic polymer having a Tg greater than 70° C. An improved exterior elastomeric coating composition is also disclosed.

Abstract: A method is provided for the fabrication of a protective coating for a crucible with channels being formed in the coating. A material is adhered to the outer wall of the crucible to form a pattern thereon. The outer wall of the crucible along with the pattern of material adhered thereto is next coated with another material. The material used to form the pattern should extend through the outer material coating to define at least one port therein. Next, the crucible with its pattern of material and outer coating material is heated to a temperature of transformation at which the pattern of material is transformed to a fluidic state while the crucible and outer coating material maintain their solid integrity. Such transformation could also be accomplished by using a solvent that causes the pattern of material to dissolve.

Abstract: The present invention provides a method for stabilizing irregular structures such as rock structures in mines and in construction sites as well as other rock and concrete structures. The method comprises concurrently heating and mixing a mixture of polyoxypropylene diamine with an aromatic diamine liquid, mechanically purging the mixture under pressure and applying the purged mixture to a desired irregular structure. The invention also provides a weather resistant and anti-corrosive polyurea coating material as a fibrous mesh, liquid film, geotextile mat and foam for stabilizing rock, concrete and molding tool structures.

Abstract: This invention concerns the application of substantially amorphous fluoropolymer compositions to stone so as to protect the stone from the deleterious effects of water and pollution.

Abstract: This invention concerns the application of substantially amorphous fluoropolymer compositions to stone so as to protect the stone from the deleterious effects of water and pollution.

Abstract: A method of decorating an article, the method comprising mixing a thermochromic ink with a transparent lacquer, applying the mixture on to part or all of the surface of an article, once the mixture is set, applying a second layer of dishwasher proof transparent lacquer.

Abstract: The invention relates to a method of preparing a conductive composite material, consisting of performing at least one cycle of deposition comprising the following steps: (a) putting an insulating porous substrate (1) in contact with a solution of a conductive polymer such as polyaniline in a volatile organic solvent such as trifluoroacetic acid, and (b) eliminating the organic solvent by evaporation, for forming a deposit of conductive polymer (5) in the pores (3) of the porous substrate.

Abstract: Paper and/or mat-faced gypsum board is prepared by applying a relatively thin coating of aqueous gypsum slurry containing a polyvinyl alcohol binder to one or two facer sheets. The polyvinyl alcohol binder provides adequate adhesion between the set gypsum core and the adjacent facer sheet(s) without the need for starch or other conventional binders. In one embodiment, polyvinyl alcohol is concentrated in one or more regions of the core adjacent to the facer sheet(s). In another embodiment, polyvinyl alcohol is applied to an aqueous gypsum slurry used to form the bulk core, such that the polyvinyl alcohol is present throughout the core.

Abstract: There is provided a building board which is colored by mixture of a pigment(s) into the raw materials and exhibiting an excellent color development effect. A pigment and a resin(s) are incorporated into the raw materials of the front layer to form a resin film simultaneously with cement curing, thereby blocking the inflow or outflow of water through the surface of the substrate to provide a cement board with good waterproofness. The cement board obstructs the efflorescence generation and exhibits an excellent pigment color development effect.

Abstract: A method including forming a first layer comprising a chemical conversion coating on a metal surface; and forming a second layer on the first layer through a sol gel process. An apparatus including a metal component having at least one surface; a first layer comprising a chemical conversion coating on the at least one surface; and a second layer derived from a sol gel composition on the first layer.

Abstract: According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry.

Abstract: The invention relates to a method for producing coated mineral shaped bodies by applying an aqueous coating agent containing a polymer dispersion serving as a bonding agent and at least one aqueous styrene maleic anhydride copolymer solution. The shaped body is subsequently hardened and the coating agent is dried. The invention is characterized in that the at least one aqueous styrene maleic anhydride copolymer solution is added to the polymer dispersion after completion of the polymerization. The shaped bodies coated in such a manner exhibit an improved efflorescence behavior. The method is particularly suited for coating roofing tiles and fibrated concrete slabs.

Abstract: An aqueous coating composition having improved adhesion to friable surfaces is provided. The aqueous coating composition includes a plurality of polymeric particles having a particle size of less than 120 nanometers, and containing at least two polymers, one of which contains, as polymerized units, acid functional monomers, water soluble monomers, or both. Optionally, the aqueous coating composition includes a nonionic surfactant. In addition, a method for improving adhesion to friable surfaces by using the aqueous coating compositions of the invention is provided.

Abstract: The cementitious material comprises a cement having a cement mass, and an aggregate having an aggregate mass. The cement mass and the aggregate mass has a combined mass of about 80 to 95 percent of the total mass. The cementitious material also includes a pozzolan composition comprising at least one of a silica fume and a metakaolin. The pozzolan composition is present in an amount of about 4.0 to 6.0 percent of the total mass. The cementitious material further includes an acrylic polymer composition.

Abstract: Aqueous formulations comprising as film-forming constituent at least one copolymer P, synthesized from ethylenically unsaturated monomers M, are used for coating shaped mineral articles, the copolymer P having a glass transition temperature in the range from −25 to +80° C. and the monomers M comprising more than 0.2% by weight and up to 5% by weight, based on their overall weight, of itaconic acid as monomer M1.

Abstract: A method is disclosed of improving the drying time of a thick, exterior, waterborne coating containing a quick-setting binder by applying the coating as at least two separate layers and as “wet-on-wet” layers.

Abstract: A method for sealing porous building materials, using a polyurethane and/or epoxy resin based sealing composition. The composition can include a substance/substance mixture with a viscosity of less than 100 mPa·s at 12° C. which can be added to a porous building material. This substance/substance mixture can be based on an epoxy resin. This resin can chemically react once inside of a porous region of the building material to substantially fill the pore system.

Abstract: A method of manufacturing a magnetic recording medium comprises steps of: (a) preparing a sol solution containing gel particles; (b) treating the sol solution to remove gel particles having a size greater than a predetermined maximum size; (c) providing a non-magnetic substrate for a magnetic recording medium, the substrate including a surface; and (d) applying a layer of the treated sol solution to the surface of the substrate; (e) converting the layer of treated sol solution to a layer of sol-gel having a hardness less than that of the surface of the substrate, an exposed surface of the layer of sol-gel having very low surface micro-waviness and substantially no defects in the form of protrusions or bumps; (f) forming a pattern in the exposed surface of the layer of sol-gel; (g) converting the layer of sol-gel to a glass or glass-like layer having a density and hardness substantially comparable to that of the surface of the substrate, while preserving the pattern formed in an exposed surface of the g

Abstract: The vinyl aromatic-1,3-diene copolymers stabilized with protection colloids are used in the form of aqueous polymer dispersions or water-redispersible polymer powders for modifying materials that contain plaster or calcium carbonate. The polymer dispersions or polymer powders are obtained by the emulsion-polymerization of a mixture containing at least one vinyl aromatic and at least one 1,3-diene in the presence of at least one protection colloid and without any emulsifier, and by optionally drying the aqueous polymer dispersions thus obtained.

Abstract: Processes for the preparation of adherent polyvinylidene fluoride, hexafluoropropylene coatings on objects and for the direct production of open celled foams from a polymer latex without a need for any blowing agent.

Abstract: The invention concerns a synthesis method for an oligosilazane-containing condensation product comprising the following step: conversion of oligosilazane composition with an average molecular weight of no more than 1000 g/mol, with a dialk(en)ylamino compound of the following formula (I) A[N(R4)2]m  (I) in which A is at least one element chosen from B, Al, Ti, Zr, and Hf, R4 is an alkyl group or alkenyl group and m is the valence of element A, in which the reaction is run so that an average of 1.6-2.

Abstract: The invention describes a method of coating a concrete molding which comprises a) the application of at least one plastic, cement-bound mineral composition to an uncoated mineral molding wherein said plastic composition comprises at least one aqueous polymer dispersion and b) bringing about the setting of the plastic composition, wherein the aqueous polymer dispersion comprises: at least one polymer P in the form of dispersed polymer particles with a glass transition temperature of from −20 to +80° C., the polymer containing not more than 2% by weight of copolymerized monoethylenically unsaturated monomers having an acid group.

Abstract: A decorative composite stone material, the finished face of which is more durable and requires less maintenance than previous composite stone products. The decorative component of the aggregate material is specifically limited to a hard aggregate of enhanced aesthetic appeal, specifically, to granules of quartz or other transparent or semi-transparent material having a Mohs index of at least 7, naturally occurring or synthetic. The granules of quartz are adjustably coated with a metallic, ceramic, plastic or other film, mixed with a binder, cast, and cured. In the surface finishing step, granules close to the surface are ground to create an exposed facet through which light passes in and out, the coating providing reflective properties that add color, sparkle, glitter, metallic or other visual effect to the hard composite stone surface without compromising the hardness and durability of the product.

Abstract: Disclosed are aqueous, storage-stable, crosslinkable polymer compositions comprising: (a) an aqueous dispersion of a an acrylic polymer component containing certain carbonyl-containing functional-groups; (b) a nitrogen-containing compound having at least two carbonyl-reactive nitrogen groups; and (c) optionally, co-solvents, pigments, fillers, dispersants, wetting agents, anti-foam agents, UV absorbers, antioxidants, biocides, and stabilizers. Such compositions are useful as coatings or binders in coating compositions, or as adhesives.

Abstract: An aqueous coating composition having improved adhesion to friable surfaces is provided. The aqueous coating composition includes a plurality of polymeric particles having a particle size of less than 120 nanometers, and containing at least two polymers, one of which contains, as polymerized units, acid functional monomers, water soluble monomers, or both. Optionally, the aqueous coating composition includes a nonionic surfactant. In addition, a method for improving adhesion to friable surfaces by using the aqueous coating compositions of the invention is provided.

Abstract: The present invention provides for the use of film-forming aqueous formulations comprising in dispersed form at least one crosslinked copolymer P for coating shaped mineral articles and for a method of coating shaped mineral articles, said copolymer P comprising in copolymerized form a) from 80 to 99.89% by weight of at least one monomer selected from esters of acrylic acid with C1-C12-alkanols, esters of methacrylic acid with C1-C8-alkanols, and monovinylaromatics, b) from 0.1 to 19.99% by weight of at least one monomer different from a), and c) from 0.01 to 1.9% by weight of at least one crosslinking monomer selected from esters of acrylic or methacrylic acid with linear or branched C3-C6-alkenols, cyclic C5-C7-alkenols and polycyclic C2-C12-alkenols.

Abstract: The present invention provides composition for treating a substrate comprising a homogeneous mixture of:

Abstract: A method for preparing a release coating and applying it to crucibles used to contain molten material while it solidifies, by mixing a release coating power with a dry organic binder into a powder and binder dry mixture, mixing a defoamer with a liquid into a liquid and defoamer mixture, mixing the dry mixture with the liquid and defoamer mixture into a wet release coating, sieving to remove lumps and particles, checking the viscosity, wet-spraying onto a crucible, evaporating the liquid from the wet release coating so as to leave a dry release coating on the crucible, and separating the binder from the dry release coating by thermal decomposition.

Abstract: A method of coating a mineral molding includes applying at least one aqueous preparation to at least one surface of the molding, the aqueous preparation including: (i) as film-forming constituent at least one polymer P which is composed of ethylenically unsaturated monomers M and which is present in dispersed form in the aqueous phase of the aqueous preparation and which has a glass transition temperature TG in the range from −25 to +80° C.

Abstract: The invention includes fibrous nonwoven multiple layer mats having at least two layers with a body portion layer and a surface portion layer having fine fibers and/or particles therein, both layers being bonded together and to each other with a same resin binder. Preferably most or essentially all of the particles and/or fibers in the surface layer are larger than openings between the fibers in the body portion of the mat. The mats produced according to this invention are useful as a facer for all types of boards such as wood boards, wood product boards, insulating boards and hard boards of all types, and also as reinforcement and dimensional stabilizers for making a large number of novel laminate products and for a myriad of other uses. These mats are made an a wet laid nonwoven mat machine with a modification to the binder preparation system, an inventive step in the preparation of the binder and in the selection of ingredients for a binder slurry.

Abstract: A method for applying a protective coating to a surface. The method is achieved by applying a radiation curable reactive coating material to the surface and exposing the applied coating to a source of light for a predetermined time and at a predetermined intensity to effect polymerization of the coating.

Abstract: A high gloss coating on a mineral substrate, such as a roof tile or floor tile, can be achieved by a method comprising: i) applying a first coating consisting of an aqueous composition comprising a film forming polymeric binder to a surface of the uncured substrate; ii) exposing said first coating to hot air or infrared, ultraviolet or microwave radiation, for sufficient time for at least the surface of said coating remote from the substrate body to form a film of polymeric binder, and iii) applying a second coating consisting of an aqueous composition comprising a film forming polymeric binder on top of the first coating. After application of the second coating, the substrate and coatings are dried and cured, for example in an oven or autoclave.

Abstract: Composite particles made of a resin and filler material are provided for use in subterranean formations. The filler is finely divided mineral and optional fiber. The particles are proppants useful to prop open subterranean formation fractures. The particles are also useful for water filtration. Methods of making the composite particles are also disclosed.

Abstract: A coating or sealing composition comprising: (a) at least one agent adapted to form a coat or seal when applied onto a substrate; (b) at least one sensor adapted to reveal the presence of the coat or seal under determined conditions; and (c) a volatile excipient in which the above and all other ingredients of the composition are dispersed or dissolved, p1 characterized in that said composition further comprises: (d) at least one UV stabilizer and/or antioxidant.

Abstract: Calcitic and/or siliceous particulate materials are provided with increased resistance to penetration by water, oil or grease damage from water, oil or grease by a process which comprises treating said materials with an aqueous composition containing: (A) from about 0.1 to 4% by weight on a 100% solids basis of an aqueous solution or self-dispersed emulsion or dispersion of a copolymer which is a reaction product of monomers containing fluorinated groups, cationic groups and nonionic groups, optionally (B) an effective amount of a penetration assistant, and (C) water to make up 100%.

Abstract: The present invention provides for the use of aqueous film-forming formulations comprising at least one copolymer P as film-forming constituent which is present in disperse form in the formulation and is composed of ethylenically unsaturated monomers M, the monomers M comprising i. from 70 to 99.9% by weight of at least one ester of methacrylic acid with a C1-C10-alkanol and ii. from 0.1 to 30% by weight of at least one different monoethylenically unsaturated monomer and at least 50% by weight of the monomers M being other than methyl methacrylate and not more than 1% by weight of the monomers M having two or more ethylenically unsaturated double bonds, for coating mineral moldings. The present invention additionally provides a method of coating the mineral moldings, and also the mineral moldings themselves.

Abstract: A method of providing a fire barrier that includes coating an opening in a structure with a composition that includes an elastomer. The composition is substantially free of volatile organic compounds and, when dry, exhibits a tensile strength of from about 300 psi to about 1500 psi, at least about 600% elongation, a modulus of from about 200 psi to about 600 psi, and a tensile toughness of greater than 10 in-lb.

Abstract: A panel for use in siding is disclosed. The panel has a cement core in a shape defining the panel of the siding, and a plastic film layer attached to the cement core. The plastic film layer is either a polymer or a copolymer of vinyl chloride. The panel may also have an adhesive layer which adheres the plastic film layer to the cement core. The cement core may contain fiber reinforcement.

Abstract: The method of the present invention provides a coated cementitious substrate with a glossy appearance, dirt pick-up resistance, and efflorescence resistance. The method includes the steps of applying a coating formulation onto a green cementitious substrate and of curing the coated green cementitious substrate. The coating formulation contains an emulsion polymer with a molecular weight in the range of 30,000 to 300,000 and a glass transition temperature in the range of −10° C. to 60° C. Also provided are an emulsion polymer including a photoinitiator monomer as polymerized unit, a coating formulation including photoinitiator molecule, and a coating formulation including an ethylenically unsaturated polymer.

Abstract: Vibrantly colored stones for use as decorative landscape elements are disclosed. The invention includes a process, including coating formulations, apparatus, and a method for preparing and applying specific acrylic-based color coatings to river rocks, stones, and the like thereby resulting in brightly colored decorative stones suitable for use in landscaping. End use stabilizers prevent color degradation, while the addition of faceted grains of mineral material enhance visual appearance. Colored stones produced according to the process herein are durable, colorfast, non-toxic, mildew resistant, algae resistant and otherwise environmentally safe. The stones may be used as decorative elements in a wide variety of landscape settings.

Abstract: The present invention relates to polymers whitened with optical brighteners obtained by (a) emulsion polymerization of acrylonitrile with or without a comonomer in the presence or absence of a graftable substrate, and (b) addition of an optical brightener before, during, or after the emulsion polymerization.