Synthetic Resin Coating Patents (Class 427/407.1)
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Patent number: 9925699Abstract: Printable magnetic receptive composite sheets are made by calendering a thin layer of a magnetic composition and bonding it to a top printable layer on one or both sides of the magnetic layer wherein the calendered layer has a thickness up to 10 mils.Type: GrantFiled: May 6, 2016Date of Patent: March 27, 2018Assignee: Schleicher Enterprises, LLCInventor: John E. Schleicher, Jr.
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Patent number: 9927168Abstract: A refrigeration appliance has a cabinet defining a refrigeration compartment with a thermoformed inner liner disposed within the refrigeration compartment. A light source is located within the refrigeration compartment and configured to emit light such that the refrigeration compartment is illuminated when the light source is powered. The thermoformed liner has a reflective surface. The reflective surface includes a plurality of microcrystalline structures and is positioned to reflect emitted light from the light source and ambient light.Type: GrantFiled: March 23, 2015Date of Patent: March 27, 2018Assignee: Whirlpool CorporationInventors: Muhammad Khizar, Vincent D. Csapos, Charles R. Cravens, David Edwards
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Patent number: 9920211Abstract: An inkjet ink includes a) an aqueous medium; and b) capsules composed of a polymeric shell surrounding a core; wherein the capsules are dispersed in the aqueous medium using a dispersing group covalently bonded to the polymeric shell; the dispersing group is selected from the group consisting of a carboxylic acid or salt thereof, a sulfonic acid or salt thereof, a phosphoric acid ester or salt thereof, a phosphonic acid or salt thereof, an ammonium group, a sulfonium group, and a phosphonium group; the core contains one or more chemical reactants capable of forming a reaction product upon application of heat and/or light; and the capsules have an average particle size of no more than 4 ?m as determined by dynamic laser diffraction.Type: GrantFiled: April 13, 2015Date of Patent: March 20, 2018Assignee: AGFA NVInventors: Johan Loccufier, Luc Decoster
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Patent number: 9878348Abstract: A double-layer coating composition having improved sparkling effect, and a method of coating the same are provided. The composition includes a first coating, which reinforces the sparkling effect and contains a greater amount of Al particle; and a second coating, which reinforces chromaticity and contains a less amount of Al particle. The method includes applying a first coating on an article and applying a second coating thereon.Type: GrantFiled: October 31, 2014Date of Patent: January 30, 2018Assignee: Hyundai Motor CompanyInventor: Sang G. Kim
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Patent number: 9868134Abstract: The present invention relates to a method for producing a multicoat paint system on a metallic substrate, in which a basecoat or a plurality of directly successive basecoats are produced directly on a metallic substrate coated with a cured electrocoat, a clearcoat is produced directly on the one basecoat or the uppermost of the plurality of basecoats, and then the one or more basecoats and the clearcoat are jointly cured, and wherein at least one basecoat material used for production of the basecoats comprises at least one aqueous dispersion comprising at least one copolymer (CP), said copolymer (CP) being preparable by initially charging an aqueous dispersion of at least one polyurethane, and then polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which a water-soluble initiator is used, the olefinically unsaturated monomers are metered in such that a concentration of 6.Type: GrantFiled: November 18, 2014Date of Patent: January 16, 2018Assignee: BASF Coatings GmbHInventors: Bernhard Steinmetz, Holger Krumm, Stephanie Pei Yii Goh, Peter Hoffmann, Hardy Reuter, Peggy Jankowski, Nadia Luhmann
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Patent number: 9834318Abstract: Systems and methods for lightning strike materials are disclosed. The material may include a carbon fiber tow. Carbon nanotubes may be grown on carbon fibers within the carbon fiber tow. The carbon nanotubes may cause the carbon fibers to separate, decreasing a carbon tow fiber volume fraction of the tow. The growth of the carbon nanotubes may be controlled to select a tow fiber volume fraction of the tow. The lightning strike material may transmit electricity to decrease damage to the composite structure in case of a lightning strike.Type: GrantFiled: April 25, 2014Date of Patent: December 5, 2017Assignee: ROHR, INC.Inventors: Teresa M. Kruckenberg, Vijay V. Pujar
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Patent number: 9802223Abstract: [Problem] In a coating method of a two-coat one-bake system where a clear coat paint is coated after a base coat paint is coated, then these two coated layers are simultaneously hardened, adhesive strength between the two coated layers is to increase in comparison with the conventional method. [Solution] Provided is a coating method; A specific hardener is used in the clear coat paint. The hardener is one containing a polyisocyanate derived from 1,6-hexamethylene diisocyanate, satisfying all the following conditions: 1) Hardener does not virtually include diisocyanate monomer, 2) Viscosity of hardener is not more than 1000 mPa·s/23° C., 3) Content of HDI trimer in hardener is not less than 60 weight %, and 4) Content of HDI dimer in hardener is less than 10 weight %.Type: GrantFiled: July 3, 2013Date of Patent: October 31, 2017Assignee: Covestro Deutschland AGInventors: Tomokazu Shigemori, Hiroshi Morita
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Patent number: 9708486Abstract: There is provided a highly branched lipophilic polymer that is excellent in blending and dispersing properties in a matrix resin, and is possible to provide surface modification properties such as excellent lipophilicity (anti-fingerprint property) and the like to a coating that is obtained from the resin composition while the intrinsic transparency of the resin is not impaired; and a photopolymeizable composition comprising the highly branched lipophilic polymer. A highly branched lipophilic polymer obtained by polymerizing a monomer A containing two or more radically polymerizable double bonds per molecule and a monomer B containing a C6-30 alkyl group or a C3-30 alicyclic group and at least one radically polymerizable double bond per molecule in the presence of 5 to 200 mol % of a polymerization initiator C relative to the number of moles of the monomer A. A photopolymeizable composition comprising the highly branched lipophilic polymer.Type: GrantFiled: December 1, 2015Date of Patent: July 18, 2017Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.Inventors: Motonobu Matsuyama, Masayuki Haraguchi, Masaaki Ozawa
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Patent number: 9701799Abstract: The invention provides a transparent gas barrier composite film and its preparation method. The transparent gas barrier composite film is formed by having polyvinyl alcohol, graphene oxide and a crosslinking agent undergo blending, crosslinking, film casting and isothermal crystallization processes where a weight ratio of graphene oxide to polyvinyl alcohol is 0.1 wt %, graphene oxide induces crystallization of polyvinyl alcohol to form a hybrid structure compose of polyvinyl alcohol crystals, graphene oxide and the crosslinking agent, crystallinity of polyvinyl alcohol is more than 30%, transmittance of the composite film is more than 85%, and the oxygen transmission rate of the composite film is less than 0.005 cc/m2/day.Type: GrantFiled: October 7, 2014Date of Patent: July 11, 2017Assignee: CHUNG YUAN CHRISTIAN UNIVERSITYInventors: Jung-Tsai Chen, Chien-Chieh Hu, Kueir-Rarn Lee, Juin-Yih Lai, Ywu-Jang Fu, Quan-Fu An, Shen-Chuan Lo, Yue-Zhe Zhong
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Patent number: 9636703Abstract: An object of the present invention is to provide a method for forming a multilayer coating film, the method making it possible to obtain, with excellent curability at low temperatures and in a short period of time, a multilayer coating film exhibiting an excellent finished appearance. The present invention provides a method for forming a multilayer coating film, wherein a substrate is sequentially coated with at least one layer of one or more base coating compositions, and with one or more clear coating compositions, the method being characterized by utilizing a clear coating composition containing a hydroxy-containing acrylic resin (A) having a hydroxy value in a specific range; a polyisocyanate compound (B) having a viscosity in a specific range; and an organometallic catalyst (C) containing a metallic compound (C1) in which the metal is a member selected from the group consisting of zinc, tin, zirconium, bismuth, lead, cobalt, manganese, titanium, aluminum, and molybdenum, and an amidine compound (C2).Type: GrantFiled: September 12, 2012Date of Patent: May 2, 2017Assignee: KANSAI PAINT CO., LTD.Inventors: Naoyuki Iwata, Fumio Yamashita
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Patent number: 9597858Abstract: An object of the present invention is to provide a method for manufacturing a touch panel. A laminated film is used. The laminated film comprises a resin layer, a protection film-constituent material layer provided on a surface of the resin layer, and a releasing layer provided on a surface of the protection film-constituent material layer. The protection film-constituent material layer is a layer containing fluorine-based substances. The releasing layer is a layer made by using a fluorine-based resin. The method comprises a molding process, a hardening treatment process for providing hardening treatment to the protection film-constituent material layer after the molding process, and a removal process for removing the releasing layer after the molding process. The protection film-constituent material layer is an uncured layer in the course of a molding process.Type: GrantFiled: February 25, 2014Date of Patent: March 21, 2017Assignees: PANAC CO., LTD., NIDEK CO., LTD., WONDER FUTURE CORPORATIONInventors: Takashi Watanabe, Hayato Agata, Tokuyoshi Kawai, Naohide Isogai, Shigehiro Koide, Akira Sato
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Patent number: 9534137Abstract: A single-liquid type paint composition comprises: a hydroxyl group-containing polyester resin (A) of which the weight average molecular weight is from 1,500 to 8,000, the acid value is from 0 to 50 mgKOH/g, the hydroxyl group value is from 100 to 180 mgKOH/g and the glass transition temperature is from ?30 to 0° C. and a crosslinking agent (B) which reacts with hydroxyl groups, wherein the (A) component has been obtained by reacting a polybasic acid (a), a polyhydric alcohol (b) and at least one type of component (c) having at least six carbon atoms selected from among the saturated mono-carboxylic acids, saturated mono-alcohols, saturated glycidyl ethers and saturated glycidyl esters where the proportion by mass of the (c) component is from 20 to 60 mass % with respect to the sum of the solid fraction masses of the (a) to (c) components.Type: GrantFiled: January 23, 2013Date of Patent: January 3, 2017Assignee: BASF Coatings GmbHInventors: Tetsu Konishi, Atsunori Tajima
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Patent number: 9512524Abstract: The invention relates to use of an aqueous composition for pretreating can body stock, whereby an inorganic-organic conversion layer is formed, which effects outstanding sliding behavior of the shaped can body stock and in addition offers an outstanding holding primer for subsequent coating. The invention comprises a process in which can body stock which is deep-drawn to form a half-open can cylinder, before further shaping processes, is contacted with an acidic aqueous composition which contains water-soluble inorganic compounds of Zr, Ti, Si, Hf or Ce, water-soluble polymers having carboxyl groups or hydroxyl groups and also a dispersed wax. Both outer and inner surfaces of metallic can cylinders can be pretreated in the process. The invention also relates to an acidic aqueous composition for use in the pretreatment process, which contains water-soluble polymers selected from condensation products of glycoluril and aldehydes.Type: GrantFiled: May 1, 2015Date of Patent: December 6, 2016Assignee: Henkel AG & Co. KGaAInventor: Joerg Riesop
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Patent number: 9482789Abstract: The present invention relates to an anti-reflective coating film. This anti-reflective coating film shows more improved interface adhesion and scratch resistance, which can be manufactured by a simple process.Type: GrantFiled: March 15, 2013Date of Patent: November 1, 2016Assignee: LG CHEM, LTD.Inventors: Heon Kim, Yeong-Rae Chang, Joon-Koo Kang, Jae-Pil Koo
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Patent number: 9458354Abstract: The presently disclosed and claimed inventive concept(s) relates generally to polyethylene terephthalate (“PET”) polymers, digested oligomeric derivatives of PET (“dPET”), functionalized oligomeric derivatives of dPET (“dfPET”), and polyurethane dispersions (“PUD”) made from or incorporating dfPET therein.Type: GrantFiled: February 21, 2012Date of Patent: October 4, 2016Assignee: Resinate Technologies, Inc.Inventors: Kristopher M. Felice, Adam W. Emerson, George F. Willard, Eric W. Uffman, Albert C. Lee
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Patent number: 9371589Abstract: A photoelectrochemical method on metal preservation is disclosed that includes applying a coating on metal surface and curing the coating. The coating includes: A) the film-forming component; and B) the surface modified nanometer titanium dioxide, which consists of nanometer titanium dioxide particle as substrate and the nonionic surfactant covered on the substrate surface. The diameter of the nanometer titanium dioxide substrate is 1-100 nm. The hydrophile-lipophile balance value of the nonionic surfactant is 1-10 and is contained of 1-20 wt % based on the weight of nanometer titanium dioxide substrate. The content of the surface modified nanometer titanium dioxide is 0.1-10 wt % based on the total weight of the coating. The photoelectrochemical method on metal preservation through this disclosure is low cost and high efficient and obviously reduce the corrosion speed.Type: GrantFiled: September 21, 2011Date of Patent: June 21, 2016Assignee: JIANGSU KFCC NEW MATERIALS CO., LTD.Inventors: Ruifen Xu, Lei Geng, Yilong Yu, Zhuoer Ma, Shuangying Xie
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Patent number: 9364858Abstract: Disclosed is a method for producing a multicoat color and/or effect paint system, comprising (1) applying a pigmented aqueous basecoat to a substrate, (2) forming a polymer film from the basecoat applied in stage (1), (3) applying a clearcoat to the polymer film, and then (4) curing the polymer film together with the applied clearcoat to form a clearcoat film. The pigmented aqueous basecoat comprises at least one ester characterized by the following structure: where R1 is selected from the group of ethyl and isopropyl and R2 is a C2 to C8 radical. The at least one ester is used here in an amount of 0.1% to 5% by weight, based on the total weight of the aqueous basecoat applied in stage (1). The invention further provides the corresponding coating materials and the use of the esters in pigmented aqueous coating materials.Type: GrantFiled: July 6, 2012Date of Patent: June 14, 2016Assignee: BASF Coatings GmbHInventors: Michael Matura, Bernhard Steinmetz, Matthias Schad
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Patent number: 9362503Abstract: A method of manufacturing an organic light-emitting display apparatus including preparing a mother substrate that includes a plurality of display areas; forming a plurality of pixel electrodes on each of the display areas of the mother substrate; preparing a donor mask that includes a base substrate having a plurality of display transferring areas corresponding to the plurality of display areas, the base substrate including a groove between the display transferring areas, a light-to-heat conversion layer on the base substrate, and a reflective layer between the base substrate and the light-to-heat conversion layer and being patterned to include through holes in each of the display transferring areas; depositing a transferring layer on the light-to-heat conversion layer of the donor mask; aligning the mother substrate and the donor mask; and transferring portions of the transferring layer that overlie the through holes onto the pixel electrodes on the mother substrate.Type: GrantFiled: November 7, 2014Date of Patent: June 7, 2016Assignee: SAMSUNG DISPLAY CO., LTD.Inventor: Tae-Wook Kang
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Patent number: 9227382Abstract: A release sheet comprising a base material and a release agent layer formed on at least one surface of the base material, wherein: the release agent layer is formed by using a release agent composition; the release agent composition contains a first polydimethylsiloxane having at least two alkenyl groups in one molecule and a second polydimethylsiloxane having at least two hydrosilyl groups in one molecule; the release agent composition contains 10.00 to 16.00 mmol of the alkenyl groups and 40.00 to 145.00 mmol of the hydrosilyl groups in a total of 30 g of the first polydimethylsiloxane and the second polydimethylsiloxane; and a molar ratio (b/a) of the hydrosilyl groups (b) to the alkenyl groups (a) is 2.0 to 15.0. According to the release sheet, it is possible to suppress the peeling force from increasing even when the release agent layer of the release sheet is exposed to the air for a long time.Type: GrantFiled: December 20, 2012Date of Patent: January 5, 2016Assignee: LINTEC CORPORATIONInventors: Keiichi Sato, Tomomi Fukaya
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Patent number: 9227368Abstract: This disclosure relates to golf balls having a cover layer made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The cover layer may have certain properties, such as a desirable flexural modulus value and a desirable Shore D hardness value, that further contribute to the golf ball having a high degree of scuff resistance.Type: GrantFiled: December 18, 2013Date of Patent: January 5, 2016Assignee: NIKE, Inc.Inventors: Hideyuki Ishii, Yasushi Ichikawa, Chien-Hsin Chou, Hsin Cheng, Chung-Yu Huang, Chen-Tai Liu
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Patent number: 9174239Abstract: A process for the production of a dark-color multi-layer coating, comprising the successive steps: (1) applying an NIR-opaque coating layer A? from a solventborne coating composition A to a substrate, (2) applying a coating layer B? from a solventborne coating composition B onto the substrate provided with coating layer A?, (3) subjecting the coated substrate obtained in step (2) to a drying step, (4) applying a clear coat layer, and (5) curing the coating layers simultaneously; wherein both coating compositions A and B comprise binders and crosslinkers comprising melamine-formaldehyde resin crosslinker, wherein both coating compositions A and B comprise certain proportions of cellulose ester binder and NAD binder and/or sheet silicate and/or fumed silica and/or urea SCA and/or polyolefine wax, wherein the pigment content of coating composition A comprises <90 wt.Type: GrantFiled: October 27, 2010Date of Patent: November 3, 2015Assignee: AXALTA COATING SYSTEMS IP CO., LLCInventors: Karl Friedrich Doessel, Gunter Richter
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Patent number: 9127230Abstract: A functional amine release agent displaying reduced coefficient of friction as compared to standard silicone oils, the release agent comprising a polydimethylsiloxane oil and a functional amine selected from the group consisting of pendant propylamines and pendant N-(2-aminoethyl)-3-aminopropyl; wherein the concentration of functional amine to polydimethylsiloxane oil is approximately less than 0.0006 meq/g. According to certain embodiments, the functional amine release agent is operable to impart a coefficient of friction of about 0.3 or more to the print media, resulting in improved finishing and converting equipment interaction.Type: GrantFiled: January 18, 2013Date of Patent: September 8, 2015Assignee: Xerox CorporationInventors: Jason M. LeFevre, Paul J. McConville, Santokh S. Badesha, James M. Chappell, David A. VanKouwenberg, Anthony S. Condello, Daniel J. McVeigh
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Patent number: 9095878Abstract: One aspect of the present invention is a coating system for use in a wet on wet coating application process. The coating system includes a first coating composition, a second coating composition, and a boundary layer. The first coating composition includes a first bulk polymer resin and a first reactive component selected from the group consisting of a part A and a part B reactive component. The second coating composition includes a second bulk polymer resin and a second reactive component comprised of the other reactive component of the part A and the part B reactive component group. The boundary is formed upon applying a first layer of the first coating composition to a second layer of the second coating composition. The boundary layer includes the reaction product of the part A and the part B reactive component and is situated between the first layer and the second layer.Type: GrantFiled: July 26, 2007Date of Patent: August 4, 2015Assignee: Ford Motor CompanyInventors: Dennis Lee Havlin, Jr., Mark Edward Nichols
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Patent number: 9051473Abstract: Disclosed herein is a clear coating composition comprising a dispersion of silica nano-particles prepared from silica nano-particles having reactive silane groups of 1-500 nm particle size, and at least 0.001 parts by weight of oligomer having at least two groups reactive with the silica nano-particles, or oligomer in combination with a film forming polymer, a low molecular weight coupling agent, or a combination of a film forming polymer and a low molecular weight coupling agent.Type: GrantFiled: June 14, 2007Date of Patent: June 9, 2015Assignee: AXALTA COATING SYSTEMS IP CO., LLCInventor: Jun Lin
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Publication number: 20150147477Abstract: A two-component grease package for lubricating a mechanism, wherein the grease package includes a first component comprising a thickener, and a second component comprising a fluid lubricant, whereby the two-component grease is obtained by mixing together the first and the second component.Type: ApplicationFiled: December 17, 2012Publication date: May 28, 2015Inventors: Ingemar Strandell, Frank Fiddelaers
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Publication number: 20150140316Abstract: The present disclosure describes a protective coating for a low index material, and a process for preparing a protected low index material. The protective coating partially penetrates the pores of a low index material, providing a seal protecting the pores, and can strengthen the construction by forming a gradient in properties of the protected low index material. The present disclosure further provides a diffusing low index optical element having a protected low index material and a diffusing layer disposed on the low index material.Type: ApplicationFiled: March 19, 2013Publication date: May 21, 2015Inventors: Michael L. Steiner, William D. Coggio, Thomas J. Ludemann, Emilie L. Rexeisen, William R. Dudley, Steven J. McMan, Michael L. Ruegsegger
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Patent number: 9034414Abstract: The object of the present invention is to provide a joint prosthesis, bearing material and a production method thereof, which suppresses wear in a sliding section and suppresses the production of abrasive powder even during repeated daily operation. To achieve the object, there is provided a biomaterial comprising: a substrate made of metal, alloy or ceramic; and a biocompatible material layer laminated on the substrate, wherein hydroxyl groups are formed on the substrate by surface-treating, while the biocompatible material layer comprises a polymer containing phosphorylcholine groups, the substrate and the biocompatible material layer are bound via a binder layer which is combined with the hydroxyl groups of the substrate and with the biocompatible material layer.Type: GrantFiled: February 21, 2014Date of Patent: May 19, 2015Assignees: KYOCERA MEDICAL CORPORATION, THE UNIVERSITY OF TOKYO, NATIONAL UNIVERSITY CORPORATION TOKYO MEDICAL AND DENTAL UNIVERSITYInventors: Masayuki Kyomoto, Kazuhiko Ishihara, Yasuhiko Iwasaki, Toru Moro, Kozo Nakamura, Yoshio Takatori, Hiroshi Kawaguchi, Tomohiro Konno, Noboru Yamawaki
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Patent number: 9034433Abstract: A method for creating a wood like appearance on a synthetic shutter using a sales client device, a network, computer instructions for creating a work order, a tray with scannable tray identifier to hold a shutter, a production client device connected to the network with computer instructions for applying a base coat, a glaze, and a top coat with spray treatment devices to the shutter as it automatically moves on a conveyer system. Scanning a scannable tray identifier with a plurality of sensors to link the tray identifier to the work order and to authenticate and validate the location of the tray on the conveyor system, or to initiate an alerting device. The method uses temperature control environments to control humidity and heating of the shutter while spraying, drying and UV curing.Type: GrantFiled: April 23, 2014Date of Patent: May 19, 2015Assignee: GLASSCRAFT DOOR COMPANYInventors: John B. Plummer, Matthew James O'Shea, Joseph Gene Denley
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Publication number: 20150123012Abstract: A sample plate in use with a MALDI-TOF (matrix-assisted laser desorption ionization time-of-flight) mass spectrometer. The sample plate is usable for the mass spectrometry of a polymeric material on the order of several hundreds of Da and a method of manufacturing the same sample plate. The sample plate including a target plate, an organic matrix formed on one surface of the target plate, and a Parylene thin film formed on the target plate on which the organic matrix is formed, the Parylene thin film entirely covering the organic matrix.Type: ApplicationFiled: November 6, 2014Publication date: May 7, 2015Inventors: Jaechul Pyun, Jo ll Kim
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Patent number: 9023430Abstract: The present invention is directed to a method for forming a composite coating on a substrate. The method comprises: (A) applying a first, waterborne coating composition to a surface of the substrate, the composition comprising: (a) a polymeric component containing acid functional groups and an additional, different functional group; (b) a curing agent having functional groups reactive with the additional functional groups on the polymeric component; and (c) microgel particles different from the curing agent, prepared from a diamine and an acid functional polyisocyanate, wherein the polyisocyanate contains an average of 0.75 acid functional groups per molecule and the wherein the polyisocyanate has at least three isocyanate functional groups, to form a substantially uncured first coating thereon; and (B) applying a second coating composition to the uncured first coating, to form a substantially uncured secondary coating thereon. Also provided are coated substrates prepared using the above method.Type: GrantFiled: October 14, 2011Date of Patent: May 5, 2015Assignee: PPG Industries Ohio, Inc.Inventors: Paul H. Lamers, Christopher A. Verardi, Michele L. Meli
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Publication number: 20150118404Abstract: The present invention relates to a membrane comprising a bulkhead layer, wherein more than 50% by weight of the bulkhead layer is composed of PVC, and a barrier layer. The barrier layer can, on the one hand, be a barrier layer S1, wherein the barrier layer S1 has a polyvinyl alcohol layer comprising more than 50% by weight of copolymer PA, which is connected to the bulkhead layer by a polyurethane layer, wherein more than 10% by weight of the polyurethane layer is composed of polyurethane PUR. The barrier layer can, on the other hand, be a barrier layer S2, wherein the barrier layer S2 has a composition comprising 5-50% by weight of polyurethane PUR and 50-95% by weight of copolymer PA. The membranes according to the invention have significantly lower plasticizer migration compared to the membranes of the prior art and are distinguished by improved resistance to aging, particularly as regards the adherence of the barrier layer on the bulkhead layer, and imperviousness to damp.Type: ApplicationFiled: April 2, 2013Publication date: April 30, 2015Inventors: Elyes Jendoubi, Carine Kerber
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Publication number: 20150118405Abstract: Provided is a method of forming an antifouling coating film including the steps of [1] preparing a colored antifouling paint containing a prescribed Si-containing hydrolyzable resin and a color pigment such that a coating film having a target dry film thickness T completely hides a surface of an object to be coated, the colored antifouling paint has a color difference ?E1 between the coating film having the thickness T and a coating film having a dry film thickness of 0.8 T, at least 2.0, and preferably the colored antifouling paint has a color difference ?E2 between the coating film having the thickness T and a coating film having a dry film thickness of 1.2 T, less than 1, and [2] coating a surface of the object with the colored antifouling paint until the surface of the object is completely hidden by the coating film formed from the colored antifouling paint.Type: ApplicationFiled: December 30, 2014Publication date: April 30, 2015Inventors: Ryo EHARA, Haruyasu Minami, Soichiro Tomiyama
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Patent number: 9017802Abstract: The present disclosure is drawn to a method for improving the durability of an ink printed on a substrate. In an aspect, the method comprises: (a) providing a substrate having an ink printed thereon; (b) applying an organosilane to the ink to form a coating over the ink, wherein the organosilane is of the formula X—SiR1R2R3, wherein R1, R2 and R3 are all hydrolysable groups, and X comprises an a nucleophilic nitrogen-containing group which is covalently bonded to Si in X—SiR1R2R3 via a non-hydrolysable linker group; and (c) curing the organosilane. The present disclosure further describes a substrate having an ink printed thereon, wherein the ink has a coating thereon formed by applying an organosilane to the ink and curing the organosilane.Type: GrantFiled: March 11, 2011Date of Patent: April 28, 2015Assignee: Hewlett-Packard Indigo B.V.Inventors: Hannoch Ron, Inna Tzomik, Shani Maor
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Patent number: 9017818Abstract: The present invention relates to coating compositions comprising (A) at least one hydroxyl-containing polyacrylate and/or at least one hydroxyl-containing polymethacrylate and (B) at least one compound containing isocyanate groups and having at least one structural unit (I) of the formula (I) —NR—(X—SiR?x(OR?)3-x)??(I), and having at least one structural unit (II) of the formula (II) —N(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(II), where (i) (A) has a glass transition temperature of less than 10° C., (ii) (B) contains more than 10 to more than 90 mol %, of at least one structural unit of the formula (I) and 10 to less than 90 mol % of at least one structural (II), based on the entirety of the structural units (I) and (II), and (iii) 10 to 60 mol % of the isocyanate groups of the diisocyanate and/or polyisocyanate parent structure of (I) and (II). The invention provides multistage coating processes using these coating compositions.Type: GrantFiled: March 8, 2010Date of Patent: April 28, 2015Assignee: BASF Coatings GmbHInventor: Matthijs Groenewolt
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Patent number: 9017766Abstract: Methods, compositions and articles of manufacture involving soluble conjugated polymers are provided. The conjugated polymers have a sufficient density of polar substituents to render them soluble in a polar medium, for example water and/or methanol. The conjugated polymer may desirably comprise monomers which alter its conductivity properties. In some embodiments, the inventors have provided cationic conjugated polymers (CCPs) comprising both solubilizing groups and conductive groups, resulting in conductive conjugated polymers soluble in polar media. The different solubility properties of these polymers allow their deposition in solution in multilayer formats with other conjugated polymers. Also provided are articles of manufacture comprising multiple layers of conjugated polymers having differing solubility characteristics. Embodiments of the invention are described further herein.Type: GrantFiled: September 17, 2004Date of Patent: April 28, 2015Assignee: The Regents of the University of CaliforniaInventors: Guillermo C. Bazan, Bin Liu, Xiong Gong, Alan J. Heeger, Wanli Ma, Parameswar K. Iyer
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Patent number: 9017768Abstract: The invention offers methods for forming multilayer coating film excelling in smoothness, distinctness of image, water resistance and chipping resistance, the methods comprising successively applying onto a coating object a water-based first coloring paint and a water-based second coloring paint, and simultaneously heating and curing the resultant first colored coating film and second colored coating film, in which the water-based first coloring paint comprises hydroxy-containing polyester resin, curing agent, and water-dispersible acrylic resin which is obtained by polymerization of a monomer component comprising 30-100 mass % of C5-22 alkyl-containing polymerizable unsaturated monomer and 0-70 mass % of polymerizable unsaturated monomer other than the C5-22 alkyl-containing polymerizable unsaturated monomer.Type: GrantFiled: June 24, 2009Date of Patent: April 28, 2015Assignee: Kansai Paint Co., Ltd.Inventors: Yasuhiro Tomizaki, Takuya Kawachi, Takahisa Ooya
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Publication number: 20150112017Abstract: The present invention relates to a composition comprising: (a) about 5 wt. % to about 30 wt. % of an amorphous polymer, said amorphous polymer having a glass transition temperature of lower than about ?20° C., (b) about 15 wt. % to about 60 wt. % of a filler, and (c) about 10 wt. % to about 80 wt. % of a solvent, wherein the amounts of (a), (b) and (c) are calculated on the total weight of the composition. The present invention also relates to a process for the application of a protective layer to a substrate, the process comprising application of a layer of the composition to the surface of the substrate or a part thereof. The present invention further relates to a container comprising the composition and a propellant.Type: ApplicationFiled: December 21, 2012Publication date: April 23, 2015Inventors: Franciscus Petrus Marie Nooren, Jan Frederik Doddema, Hindrik Harm Broesder
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Patent number: 9011980Abstract: A dampening device and method of making are provided, in which the method includes providing a first layer of a sponge rubber. An isocyanate-base prepolymer and a polyol base curing agent are combined to form a curable liquid urethane polymer. The curable liquid urethane polymer is shredded and during shredding air in the form of micro-bubbles is entrained in the curable liquid urethane polymer. The curable liquid urethane polymer is applied to form a second layer overlying the first layer and is then cured to form a tacky polyurethane cast elastomer. Micro-bubbles remain present in the tacky polyurethane cast elastomer and curing bonds the first and second layer forming a dampening device. The dampening device includes a first layer of neoprene and a second layer of a micro-bubble infused tacky polyurethane cast elastomer bonded to the first layer.Type: GrantFiled: March 6, 2013Date of Patent: April 21, 2015Assignee: Studio Lab, LLCInventor: Cristian Gene Beaulieu
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Publication number: 20150104658Abstract: The present invention relates to the use of aqueous multistage polymer dispersions obtainable by free-radically initiated aqueous emulsion polymerization, having a soft phase and a hard phase and having a hard-to-soft stage ratio of 25% to 95% by weight to 75% to 5% by weight, the glass transition temperature (Tg) of the soft phase, as first stage, being ?30 to 0° C. and that of the hard phase, as second stage, being 20 to 60° C., comprising at least one monomer of the general formula I in which the variables have the following definitions: n=0 to 2, R1, R2, R3=independently of one another hydrogen or methyl group, X?O or NH, Y?H, alkali metal or NH4, to coat metal sheets.Type: ApplicationFiled: June 4, 2013Publication date: April 16, 2015Applicant: BASF SEInventors: Ekkehard Jahns, Hans-Juergen Denu, Sebastian Roller, Alexander Kurek
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Publication number: 20150104583Abstract: A method for making a coating composition by mixing one or more latex polymers and an aliphatic epoxy resin system having an epoxy equivalent weight less than 1000 and being distinct from the one or more latex polymers to provide an aqueous first component, and providing a second component having reactive groups that can react with the one or more epoxy resins. A mixture of the first and second components provides a film-forming curable coating composition that may be used on substrates including cement, cement fiberboard, wood, metal, plastic, ceramic, glass and composites.Type: ApplicationFiled: December 16, 2014Publication date: April 16, 2015Inventors: Archie W. Garner, T. Howard Killilea, Carl Lewis Cavallin, Todd A. Peterson, Kevin W. Evanson, Dan Hartinger, Larry B. Brandenburger
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Patent number: 9005714Abstract: A process for the production of a dark-color multi-layer coating, comprising the successive steps: (1) applying an NIR-opaque coating layer A? from a solventborne coating composition A to a substrate, (2) applying a coating layer B? from a solventborne coating composition B onto the substrate provided with coating layer A?, (3) subjecting the coated substrate obtained in step (2) to a drying step, (4) applying a clear coat layer, and (5) curing the coating layers simultaneously; wherein both coating compositions A and B comprise binders and crosslinkers comprising melamine-formaldehyde resin crosslinker, wherein both coating compositions A and B comprise certain proportions of cellulose ester binder and NAD binder and/or sheet silicate and/or fumed silica and/or urea SCA and/or polyolefine wax, wherein the pigment content of coating composition A consists 90 to 100 wt. % of aluminum flake pigment and 0 to 10 wt. % of further pigment, wherein the pigment content of coating composition B consists 50 to 100 wt.Type: GrantFiled: October 27, 2010Date of Patent: April 14, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Karl-Friedrich Doessel, Gunter Richter
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Patent number: 9008984Abstract: The present invention is directed to a device for process for predicting gloss of a coating resulting from a wet layer of a low gloss coating composition, such as automotive OEM or refinish paint. The device includes measuring reflectance of the layer of the coating composition applied over a test substrate and then allowing the layer to dry and/or cure into a coating. Thereafter, its gloss is measured with a gloss meter. The device is repeated with varying amounts of one or flatting agents added to the composition and the reflectance vs. gloss is plotted on a graph and by using a curve fitting equation a gloss prediction curve is obtained. By measuring the reflectance of a wet layer of a target low gloss coating composition the gloss of a coating that would result from such a layer is then predicted by using the gloss prediction curve. The device is most useful during the manufacture of coating compositions, such as automotive OEM and refinishes paints.Type: GrantFiled: July 27, 2011Date of Patent: April 14, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Ayumu Yokoyama, Anthony Moy
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Patent number: 9005712Abstract: The present disclosure is directed to a method of applying at least one layer of a waterborne primer composition, at least one layer of a waterborne basecoat composition and at least one layer of a clearcoat composition to a substrate followed by a heating step which simultaneously cures the applied layers of coating composition.Type: GrantFiled: August 19, 2011Date of Patent: April 14, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Peter William Uhlianuk, Delson J Trindade, Alan E Smith, Brian J Ladd
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Patent number: 8999454Abstract: A nozzle for making a reinforced hollow fibre membrane discharges one or more reinforcing yarns at or near a plane where the dope exits the nozzle, or in the same plane as a discharge opening of dope passage, or both. Multiple discrete yarn discharge openings may be spaced around a longitudinal axis of the nozzle. A reinforcing yarn passage remains generally free of dope during use. The dope may be discharged in an annular ring inside of the one or more reinforcing yarns, in an annular ring outside of the reinforcing yarns, or both. Minimal tension is required to pull the yarns through the nozzle, which helps to reduce distortion of the membrane cross section in a coagulation bath.Type: GrantFiled: March 22, 2012Date of Patent: April 7, 2015Assignee: General Electric CompanyInventors: Steven Kristian Pedersen, John David Ireland
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Patent number: 8999453Abstract: Carbon nanotube-infused fiber materials containing substantially parallel-aligned, infused carbon nanotubes are described herein. The carbon nanotube-infused fiber materials contain a fiber material and a layer of carbon nanotubes infused to the fiber material, where the infused carbon nanotubes are aligned substantially parallel to the longitudinal axis of the fiber material and at least a portion of the substantially parallel-aligned, infused carbon nanotubes are crosslinked to each other, to the fiber material, or both. Crosslinking can occur through covalent bonding or pi-stacking interactions, for example. The carbon nanotube-infused fiber materials can further contain additional carbon nanotubes that are grown on the layer of substantially parallel-aligned, infused carbon nanotubes. Composite materials containing the carbon nanotube-infused fiber materials and methods for production of the carbon nanotube-infused fiber materials are also described herein.Type: GrantFiled: February 1, 2011Date of Patent: April 7, 2015Assignee: Applied NanoStructured Solutions, LLCInventors: Tushar K. Shah, Harry C. Malecki, Brandon K. Malet, Robert D. Hoskins, Jigar M. Patel
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Patent number: 8999429Abstract: Methods and systems for coating measurements are provided. A system for obtaining characteristics of a target coating layer include a clearcoat layer having a first surface and a second surface. A removable front support layer has an upper surface and a lower surface, where the lower surface is affixed over at least a portion of the second surface of the clearcoat layer. A back support layer has an inner surface and an outer surface, and at least a portion of the inner surface includes an adhesive layer. A separation layer is affixed over at least a portion of the adhesive layer, and the separation layer is removable from the adhesive layer.Type: GrantFiled: January 14, 2014Date of Patent: April 7, 2015Assignee: Axalta Coating Systems IP Co., LLCInventors: Larry Eugene Steenhoek, Allan Blase Joseph Rodrigues, Gerard T. Brosmer, David Lee Griffus
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Patent number: 8993673Abstract: An object of the present invention is to provide an aqueous coating composition with excellent finished appearance and removability in bell cleaning, and a method for forming a multilayer coating film having excellent smoothness by a 3-coat-1-bake method including successively applying an aqueous first colored coating composition, an aqueous second colored coating composition, and a clear coating composition to a substrate, and heat-curing the resulting three layers of the multilayer coating film all at once.Type: GrantFiled: February 9, 2010Date of Patent: March 31, 2015Assignee: Kansai Paint Co., Ltd.Inventors: Hiroshi Kitagawa, Munehiro Nakata, Daisuke Takayama, Tatsuya Azuma
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Patent number: 8993068Abstract: In one aspect, the present invention is directed to methods for modification of functionalized substrates. In another aspect, the invention relates to systems and methods for fabricating multilayer polymer compositions. In certain embodiments, the multilayer polymer compositions described herein can comprise heterobifunctional polymers and heterotrifunctional molecules.Type: GrantFiled: November 4, 2009Date of Patent: March 31, 2015Assignee: The Trustees of Columbia University in the City of New YorkInventors: Jeffrey T. Koberstein, Hernan R. Rengifo, Cristian Grigoras, Jeffrey Lancaster
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Patent number: 8986842Abstract: The present invention concerns a color conversion film comprising at least one active layer, said layer comprising an organic fluorescent dye containing a fluorescent core, wherein said dye is substituted with at least one polymer segment. It also concerns its method of preparation.Type: GrantFiled: May 24, 2011Date of Patent: March 24, 2015Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)Inventors: Holger Frauenrath, Rolando Ferrini, Libero Zuppiroli, Stéphane Suarez, Roman Niklaus Marty, Justin Gerard McMullen, Michael Schär
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Patent number: 8980437Abstract: The use of polyelectrolyte complexes is described, for providing an oxygen barrier to packaging materials made of polymer foils. Polymeric components of the polyelectrolyte complex are applied in polymerized form to the polymer foil. The polymer foil is either coated with an aqueous dispersion comprising a dispersed polyelectrolyte complex previously produced by water-in-water emulsion polymerization, or is coated with a composition comprising a polyelectrolyte complex produced from anionic polymer and from cationic surfactant, or the polymer foil is coated with at least three alternating layers, where respectively one of two adjacent layers comprises an anionic polyelectrolyte component and the other of two adjacent layers comprises a cationic polyelectrolyte component, and polyelectrolyte complexes form at the opposite, adjacent interfaces of the alternating layers.Type: GrantFiled: August 17, 2010Date of Patent: March 17, 2015Assignee: BASF SEInventors: Carmen-Elena Cimpeanu, Thomas Breiner, Dieter Urban, Karl-Heinz Schumacher, Volker Schaedler, Heiko Diehl, Hermann Seyffer