Abstract: A process for the production of a multi-layer paint coating in which base paints are employed which contain 5 to 20% by weight of crosslinked polymer microparticles, 2 to 15% by weight of a cellulose ester and 5 to 20% by weight of an epoxidized fatty acid ester, the weight percentages relating to the total content of nonvolatile constituents, excluding pigments and inorganic fillers, and the cellulose ester being so selected that a solution of 15 parts by weight of the cellulose ester in 85 parts by weight of a 9:1 mixture of acetone and ethanol at 23.degree. C. has a viscosity of 200 to 600 mPa.s.

Abstract: An improved method of prevention of adhesion of hot-mix asphalt to dump trucks and other containers or equipment comprises preparing an aqueous dispersion of a vegetable oil and applying the dispersion to the surface of the container before loading the hot-mix asphalt therein. Vegetable oils which are useful as release agents in aqeous dispersion include cottonseed oil, soya oil, rate (canola) oil, peanut oil, corn oil, sunflower oil, palm oil, coconut oil, and palm kernel oil. The oil is emulsified in water, using a suitable emulsifier, preferably a sorbitol base emulsifier, in the amount of 1-5 oz. per gallon of water. The oil and emulsifier are preferably premixed and supplied as a self-emulsifier composition. The resulting emulsion is applied in an amount to provide a thin coating on the wall of the container or equipment. The emulsion is applied in the amount of 3-4 qts. to coat a dump truck or 4-6 qts. to coat a trailer. The hot-mix asphalt is easily removed from the container, i.e.

Abstract: A biologically degradable film is prepared consisting of a synthetic polymer and a biologically degradable polymer. The biologically degradable polymer is divided into small particles in an aqueous suspension by means of enzymes that split and release small molecules from the surface of the biopolymer particles. After achieving desired particle size, an emulsion is formed with vegetable oil and the particles coated with enzyme protein become coated with vegetable oil, which at the same time interrupts the degradation of the biopolymer particles by the enzyme. The coated particles with the oil are separated from the suspension to remove small molecules after which the particles are re-dried and then pulverized. The final film is prepared in a film extruder in which the biopolymer is mixed with the synthetic polymer and possibly other additives that are generally used informing polymer films.

Abstract: Disclosed are waterproofing agent primer compositions which can be applied to wet and dry structures and methods of waterproofing structures made of waterpenetrable construction materials which can be used on wet and dry structures. The primer compositions include a C.sub.8 -C.sub.18 fatty acid, a natural or synthetic rubber, a resin, and an organic solvent.

Abstract: The invention relates to the impregnation of clothing, specifically Battle ress Uniforms (BDUs) used by the U.S. Military, with amylopectin fabric wrinkle inhibitor and permethrin insect/arthropod repellent in combination. In one disclosed embodiment of the invention, BDUs are loaded into a field laundry, are rinsed with clear water at 120 degrees Fahrenheit, and amylopectin is applied at a particular concentration. The BDUs preferably are then steam pressed. Permethrin at a predetermined concentration is then applied preferably by the "Individual Dynamic Absorption Application" (IDAA) procedure. The retention of permethrin by clothing treated with amylopectin unexpectedly reveals a substantially higher retention level than clothing without treatment by amylopectin after multiple laundry cycles, providing thereby a dramatic improvement in the insect/arthropod repelling action of the clothing over time.

Abstract: Silica products obtained from trivalent metal e.g. Al compounds and silica can be used as corrosion inhibitors or adhesion promoters for organic coatings on surfaces by way of no-rinse or phosphating treatment or as pigments.

Abstract: A coating composition and method of applying the coating to metal surfaces to improve corrosion resistance and substantially reduce coated parts from sticking to one another during the curing step is disclosed wherein a temporary dispersion of a di-phase mixture containing a resin film forming component and a soap film forming component are applied in a single coating step to a metal part. Upon curing the coated part, two distinct layers are formed wherein the resin film is adhered to the surface of the part and the soap film forming component is deposited uniformly over the resin film. During the curing step, the carrier agent portion of the soap film forming component is essentially volatized leaving only an upper layer of a soap film. The soap film is dry to the touch and forms an additional corrosion resistant barrier in cooperation with the underlying resin film.

Abstract: A process for coating a metallic substrate, characterized by applying on a metallic substrate a electrocoating paint, applying thereon a barrier coat comprising a film-forming thermoplastic resin other than a modified polyolefin resin and capable of forming a barrier coat film having a static glass transition temperature of 0.degree. to -75.degree. C., optionally applying on said barrier coat an intermediate coating paint and then applying thereon a top coating paint.

Abstract: Electroplated steel sheet suitable for soldering is provided by coating the plated steel sheet with a post-treatment solution in the range of 0.01 to 2 um in dry thickness. The post-treatment solution contains from 2 to 200 g/liter of at least one water-soluble or water-dispersed materials other than phosphoric esters, and/or from 5 to 200 g/liter of phosphoric esters, and also contains from 2 to 100 g/liter of at least one water-soluble or water-dispersable organic fluoro compound. The post-treatment solution may further contain from 0.01 to 3 g/liter of Cr.sup.6+ ion, and/or from 10 to 100 g/liter of organic amine soap. A suitable pH value of the post-treatment solution is between 3 and 10.

Abstract: A method of painting a clay body and maintaining a durable, decorative surface finish by providing a barrier film layer between the paint coat layer and the clay body such that the oily substance contained in the clay body is blocked from permeating through the barrier film to adversely affect the paint coat layer.

Abstract: A process for coating a metallic substrate, characterized by applying on a metallic substrate an electrocoating paint, applying thereon a barrier coat comprising a film-forming thermoplastic resin other than a modified polyolefin resin and capable of forming a barrier coat film having a static glass transition temperature of 0.degree. to -75.degree. C., optionally applying on said barrier coat an intermediate coating paint and then applying thereon a top coating paint.

Abstract: A method for retarding or preventing the calcification of a prosthesis implanted in a mammal by covalently coupling to the prosthesis before implantation an effective amount of an anticalcification agent in the form of an aliphatic carboxylic acid, or a derivative thereof, which contains from about 8 to about 30 carbon atoms and which may be straight-chain or branched-chain and saturated or unsaturated. Such acid is substituted by at least one amino, mercapto, carboxyl or hydroxyl group by which the covalent coupling takes place. For a natural tissue prosthesis, such coupling may be to an aldehyde group of gluteraldehyde in which the tissue is pre-soaked.

Abstract: Silica products obtained from trivalent metal e.g. Al compounds and silica can be used as corrosion inhibitors or adhesion promoters for organic coatings on surfaces by way of no-rinse or phosphating treatment or as pigments.

Abstract: A composition which contains (a) 80 to 99% w of a bitumen component; (b) 1 to 20% w of an elastomer; (c) 1 to 60% w of a hydrocarbon resin which has been modified to contain carboxyl, carboxylic anhydride, hydroxyl and/or amino groups; and (d) 1 to 100% w of an inorganic filler, the weight percentages being based on the total weight of the bitumen component and elastomer, is suitable for coating structures and a process for applying the composition at elevated temperature onto a suitable structure.

Abstract: A method of treating phosphated metal surfaces to improve the corrosion-inhibiting properties of the metal surfaces and to improve the adhesion of siccative organic coatings thereto is described. The method comprises treating a phosphated metal surface with an aqueous solution of a water-soluble organic titanium chelate which forms a water-insoluble deposit on the phosphated metal surface. Preferably, the water-soluble organic titanium chelate compound is TYZOR CLA, TYZOR 131 OR TYZOR 101. Optionally, though not required, the titanium chelate treated phosphated metal surfaces can be rinsed with water prior to the application of a siccative organic coating. In lieu of, or in addition to, the siccative organic coating, the titanium chelate treated, phosphated metal surfaces can be given a seal coating of a rust-inhibiting oil. Metal surfaces and metal articles treated in accordance with the method of the present invention also are described.

Abstract: A method for the manufacture of an artificial organ having a film of a fat-soluble vitamin deposited on the surfaces of parts of said artificial organ susceptible to contact with body fluid in motion through a zone for flow of said body fluid within said artificial organ, which method is characterized by the steps of causing a solution of said fat-soluble vitamin in an organic solvent to flow into said zone for flow of body fluid within said artificial organ and allowing said parts to be amply wetted with said solution, then discharging an excess of said solution out of said artificial organ, and subsequently drying said solution deposited on said parts thereby expelling said organic solvent from the solution. The invention also provides a method for sterilizing said artificial organ after contact with a physiologically harmless liquid.

Abstract: Roofing roll products are manufactured by method and apparatus which projects a plurality of aluminum chips onto a tacky upper surface of a base material such that the chips have a flat contiguous relationship to provide a protective layer on the upper surface of the roofing material.

Abstract: Metal substrates with a protective coating are provided, the coating being formed of a varnish-bonded, carbon-containing layer adherently bonded to the metal substrate. Optionally, the coating may also contain a dispersion of finely divided material selected from the group consisting of certain metal oxides and carbonates.

Abstract: Provided is a method for coating glass articles with a pourable, stable aqueous based emulsion comprising an unsaturated fatty acid, e.g., oleic or linoleic acid, and an alkali metal salt thereof, wherein the weight ratio of acid to salt in the emulsion ranges from about 2:1 to about 1:1. Application of the emulsion as a coating can be readily effected at glassware temperatures below 200.degree. F. The resultant coating is clear and transparent and provides superior lubricious and abrasion resistant properties.

Abstract: A method is provided wherein an aqueous titanate chelate is applied "in-line" to non-lubricated or lubricated tinplate surfaces during metal forming operations. The method provides economical benefits in using a non-combustible solvent system and in requiring minimal energy output for application or activation of the chelate. Inks or coatings that are subsequently applied to the chelate treated surfaces show improved adhesion.

Abstract: A process for color coding of a sintered powder metal part is disclosed. The process comprises contacting said metal part with a color formulation comprising: from about 1 to 10 parts of a colorant, from about 1 to 5 parts of nitrocellulose, up to about 45 parts of an alkyl acetate, and the remainder an alcohol and continuing said contact until a color coating is deposited on said metal part.

Abstract: A release coating for asphalt roofing sheet material comprises a mixture of fatty acid monoalkanol amides such as a mixture of cocamide MEA and stearamide MEA. The amides may be applied as dilute aqueous solutions or dispersions, and may be used with both asphalt shingles and roll roofing.

Abstract: The invention is a process for the manufacture of substantially pore-free shaped articles from polycrystalline material, such as tungsten carbide, silicon nitride, titanium boride or silicon carbide, in which encased articles preformed from pulverulent materials and having open pores are isostatically hot-pressed in a vacuum-sealed casing of vitreous or ceramic-like material in a high-pressure autoclave using an inert gas as pressure-transfer medium. Before the application of the casing material, a first layer comprising material that can be decomposed or melted, such as an organic wax or a resin-like product, or of a compressible heat-resistant material such as inorganic fibers or felts, is applied to the preformed articles. Then, the encased articles are thermally treated until the glass or ceramic layer is fused or sintered gas-tight. The articles pretreated in this manner are then isostatically hot-pressed.

Abstract: A reinforced bitumen pipe has an inner, strength-providing, reinforced thermosetting resin layer which is coated on its inner and outer sides with a bitumen layer. The bitumen layer on the inner side, and preferably also the bitumen layer on the outer side, is separated from the strength-providing reinforced thermosetting resin layer with the aid of an insulating glass fiber layer into which the thermosetting resin and the bitumen partially penetrate without finding their way up to each other.

Abstract: Coating methods and compositions for products and transfer media, such as carbon papers, in which a preliminary coating of liquid-dispersed colorant, such as carbon black, is applied at a first stage followed by a transfer overcoating at a second stage. The multistage coating procedure affords the threefold benefits of (1) improved image transfer properties in the product; (2) a reduced tendency of the product to smudge; and (3) less than the conventional amount of transfer materials for a specified result being required.

Abstract: Copper or copper alloy sheet or foil displaying improved forming and working properties is prepared by the provision over its surface of a thin coating containing a copper salt of an organophosphonic acid, and subsequently, an outer film of lubricant strongly retained by the coating is applied. To form the coating, the sheet or foil is immersed for a short time in an aqueous solution containing a phosphonic acid, rinsed and dried, the treatment being combined with or preceded by oxidation of the sheet surface, and the lubricant film is applied prior to forming operations, preferably as the final step in the production of the cupreous sheet.

Abstract: A stopper for a blood collection tube adapted to receive whole blood for centrifugal separation into its relatively light and heavy phases. The stopper is provided with a coating which prevents red blood cells from adhering to it so as to avoid red cell contamination of the lighter phase after phase separation. The stopper is coated with a cationic binding agent, such as tridodecylmethylammonium chloride, and then with an anionic anticoagulant such as dextran sulfate. A lubricant, such as silicone oil, is applied to the coated stopper to facilitate insertion of the stopper into the tube.

Abstract: A method for coating arylene sulfide polymers onto substrates by applying to the surface of the substrate a sufficient amount of a compound that acts as an aid in obtaining a smooth surface of arylene sulfide polymer over the substrate, applying a sufficient amount of arylene sulfide polymer to form a surface coating, and raising the temperature of the coated surface sufficiently to cure the coating of arylene sulfide polymer. In one embodiment, the compound acting as an aid in obtaining a smooth surface is applied as a film over the substrate surface and this film is overcoated with poly(arylene sulfide). In another embodiment, the aid for obtaining a smooth surface is applied over the substrate as part of a powdered mixture containing both the compound and powdered poly(arylene sulfide).

Abstract: According to the present invention the microporous surface of a corrodible metal body is protected against corrosive agents of the atmosphere and even such severely corrosive agents as those found in marine environments, by an impregnation in the pores of an inner protective material, preferably oil, that is substantially impervious to corrosive agents, and a covering of outer protective material, preferably resin, that is intimately bonded to the outer surface of the metal and bridges over the impregnated pores. After the impregnation, any of the inner protective material such as oil that may remain on the outer surface of the metal is selectively removed, while the inner protective material in the pores is selectively retained, whereby a secure, intimate bond of the covering to the metal is assured to protect the metal from corrosion initiating from the outside, while the inner protective material remains operatively disposed in the pores to protect the covering from corrosive undermining.

Abstract: A method for "hot end" coating of vitreous articles, and particularly glassware such as bottles, with zinc oxide and magnesium oxide coatings from aqueous solutions of organic and inorganic zinc compounds, magnesium compounds, and mixtures thereof. Particularly useful are zinc acetate and magnesium acetate, which are applied to the vitreous surface at an elevated temperature, and preferably between about 425.degree. C. and 650.degree. C., to evaporate the water from the solution and pyrolytically decompose the metal compound or compounds to form refractory oxide coatings which are transparent and adherent, and articles coated by such a method.

Abstract: A method of treating metal parts to provide durable and rust-inhibiting coatings is described. The application method can be used to treat single parts or bulk barrel processing of parts. The method comprises the steps of(a) phosphating the metal parts with an aqueous metal phosphating solution,(b) electrophoretically depositing a siccative organic coating on the phosphated metal parts, and(c) applying a corrosion inhibiting film of oil as a seal coat.

Abstract: This invention relates to a method and apparatus, for applying a first and second coating to the exterior surface of a can. The apparatus comprises a mandrel rotatably mounted on a pivotable arm, so that pivoting of the arm carries a can on the mandrel to a first position, in which it is held by a solenoid acting upon a portion of the arm, while a first coating means applies a first coating. Thereafter the arm is released for pivoting to a second position where it is held by a second holding means while a second coating means applies a second coating.

Abstract: A pipe coating composition consisting essentially of a binder, mineral aggregates, a finely divided mineral filler and synthetic organic fibers exhibits improved cracking time as compared to a pipe coating composition containing glass fibers instead of the organic fibers.

Abstract: Drying oils are used to improve strength and durability characteristics of gypsum wallboard paper with many unexpected additional advantages. Applied before board manufacture, critical porosity characteristics are left uninterrupted. Applied after board manufacture, shear strengths are obtained beyond expectations.

Abstract: Lead paint can be extremely hazardous when ingested as a result of ionic lead, produced by the action of stomach acids, being subsequently absorbed into the blood stream. According to this invention, it has been found that certain metal salts of the dithiocarbamates of multifunctional amines are effective precipitants for lead ions. When ingested simultaneously with lead paint they precipitate the lead ion in a substantially insoluble and indigestible form and thereby prevent absorption of lead into the blood stream. The preferred compounds are: zinc pentaerythrityl tetrakis (dithiocarbamate), tetrasodium pentaerythrityl tetrakis (dithiocarbamate), disodium ethylene bis(dithiocarbamate), and zinc ethylene bis(dithiocarbamate). These materials can be included in a digestible coating which can be applied over lead based paints to effectively detoxify the lead paint.

Abstract: The surfaces of antifriction elements and other steel surfaces in mutual sliding contact are improved by first degreasing the surfaces in a mild alkaline aqueous degreasing bath at a pH of about 7 to 10, by then rinsing with cold water, by browning the surfaces in a saturated aqueous solution of a selected salt material at temperatures of from 128.degree. to 135.degree. C.

Abstract: An aluminum container has an inner surface treated to suppress foaming of carbonated liquids subsequently placed therein by first chemically cleaning the aluminum surface, forming a conversion coating on the surface using a solution containing ions of phosphate, hexavalent chromium and fluoride; and treating the coated aluminum surface with an aqueous solution containing glycerol.

Abstract: A fire resistant and weathering resistant shingle or surface covering material ecologically desirable in its utilization of disposable glass is disclosed. The shingle has an asphalt coating with specified characteristics, and the asphalt coating contains from 10 to 55% by weight granular glass and preferably a combination of granular glass and non-glass granular mineral filler a major portion of which is granular glass, with each having a specified particle size distribution.A process is disclosed for producing a fire-resistant shingle or surface covering. The process includes saturating a felt base with a bitumen, admixing asphalt with granular glass and preferably with a specified combination of granular glass and non-glass granular mineral filler of specified characteristics, and then coating at least one side of the saturated felt with the filled asphalt.

Abstract: Improved rinsing formulations are disclosed which comprise an emulsifiable mineral oil, an organic cationic surfactant and a polyol. The formulations may be mixed with water to obtain oil-in-water emulsions which are especially suitable for use in automobile washing facilities.

Abstract: A pipe coating composition consisting essentially of a binder, mineral aggregates, a finely divided mineral filler and synthetic organic fibers exhibits improved cracking time as compared to a pipe coating composition containing glass fibers instead of the organic fiber.

Abstract: A method for protecting the surface of a metal surface which comprises applying to said surface an organophosphorus compound of the formula ##STR1## wherein A IS 0 OR 1R is a branched or unbranched chained bivalent alkylene radical of 1 to 12 carbon atoms which is substituted or unsubstituted and can contain in the chain structure --O--, --S--, ##STR2## R' is a branched or unbranched alkyl radical of 1 to 12 carbon atoms which can be halogen substituted and can contain in the chain structure ##STR3## X is an epoxy ring, halogen, alkylene, carboxylic acid ester residue, amino, isocyanato, isothiocyanato, urea, thiourea, urethano, alkyl substituted thio radical or the radical or a heterocyclic ring containing O, S, or N in the ring structure; a new organophosphorus compounds having the formula set forth above and more particularly defined by specific chemical structures.

Abstract: A steel plate for preparing cans by ironing having on its surface a composite oil coating which comprises a base oil and one or more, each amounting to 3 to 50 parts, selective from the group comprising of polybutene, polypropylene, polyethylene and ethyl or methyl polymethacrylate, the average molecular weight for each being in the range 500 to 30,000.

Abstract: The invention provides a novel method of increasing the corrosion resistance and improving the organic coating characteristics of cold rolled flat steel. In practicing the method, cold rolled flat steel in the as rolled condition having iron oxide and thermally degradable rolling oil on the surface thereof is heat treated at a tempterature sufficiently elevated to thermally degrade the rolling oil. The surface of the cold rolled steel has a relatively low corrosion resistance and relatively poor organic coating characteristics initially, and the heat treatment is continued until the corrosion resistance and the organic coating characteristics of the resulting heat treated steel are improved. Thereafter the heat treated steel is cooled to a temperature sufficiently low to prevent further thermal degradation of the rolling oil and produce a residual film on the heat treated steel surface which imparts corrosion resistance and improved organic coating characteristics.

Abstract: This invention relates to articles comprising a coating bonded to a substrate by means of an intervening bond-promoting primer, the latter comprising certain selectively hydrogenated block copolymers and a resin compatible with the non-elastomeric blocks of the copolymer and, in some instances, also including a carboxylated resin.

Abstract: There is disclosed a process for preparing chemically modified polyolefins or copolymers thereof which comprises reacting an olefin polymer with a co-reactant having a structure containing both a hydrocarbon residue and at least one highly polar functional group, said reaction being conducted in the presence of a source capable of generating free radicals in the presence of heat, light, oxygen, ionizing radiation, etc.

Abstract: An oil-coated metal sheet coated with a surface coating oil in an amount of from 0.05 - 1.0 g/B.B., said surface coating oil comprising diisodecyl phthalate and 0.1 -5% of one or more of a fatty acid having 14-18 carbon atoms.

Abstract: An improved polyethylene terephthalate tire yarn is prepared by applying to the yarn a finish composition comprising a polyalkylene glycol compound having the formulaR--(O--R.sub.1 --O--R.sub.2).sub.n --OHin which R.sub.1 and R.sub.2 are the same or different lower alkylene units such as ethylene, propylene and so forth up to 5 carbon atoms, R is an alkyl group containing 1 to 8 carbon atoms, and n has a value to produce a molecular weight of at least about 300; and about 5 to 35 parts per 100 parts, by weight, of said polyalkylene glycol compound of a triol compound having the formula: ##EQU1## WHEREIN R and R' are independently at each occurrence hydrogen, methyl or ethyl and r, s, and t are integers from 1 to about 20. This method of finishing the tire yarn results in an improved adhesion of the fiber to rubber.

Abstract: A novel self-adhesive type multi-layer laminated bituminous roofing membrane suitable for the formation of the roofing or waterproofing layer on roofs, floors and the like is provided. It comprises a base sheet of a sheet-like material, one or more bitumen layers coated on all or part of one or both faces of the base sheet, at least one layer of compound bitumen including both bitumen and rubber and/or resin laminated on all or part of the surface of said bitumen-coated layer on the base sheet and at least one release sheet laid over the whole surface of said compound bitumen layer.This roofing membrane is produced by uniting the bitumen-coated base sheet and the compound bitumen-coated release sheet, and can be applied over a substrate in a simple manner, without the step of melting or liquefying bitumen as in the conventional application process.