Free Metal In Coating Patents (Class 428/381)
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Patent number: 6017628Abstract: An article (130) comprising a non-conductive substrate (136), preferably of an environmentally degradeable character, having a thickness of an oxidizable metal coating (138) thereon, and optionally an oxidation enhancingly effective amount of a salt (140), e.g., from about 0.005 to about 25% by weight of salt, based on the weight of oxidizable metal, present on the oxidizable metal coating. Also disclosed is a related method of forming such article, comprising chemical vapor depositing the oxidizable metal coating on the substrate. When utilized in a form comprising fine-diameter substrate elements such as filaments, the resulting product may be usefully employed as an "evanescent" chaff. In the presence of atmospheric moisture, such evanescent chaff undergoes oxidization of the oxidizable metal coating so that the conductivity and radar absorbance/reflectance characteristics of the chaff transiently decays.Type: GrantFiled: January 8, 1997Date of Patent: January 25, 2000Assignee: Alliant Defense Electronics Systems, Inc.Inventors: Ward C Stevens, Edward A. Sturm
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Patent number: 6010788Abstract: A high speed data transmission cable comprises a pair of primary cables positioned adjacent to each other along their lengths with each primary cable including a pair of generally parallel conductors coupled together and surrounded by insulation. A shield layer surrounds each primary cable along its length to isolate the primary cables from each other. The primary cables and corresponding shield layers are twisted together around a center axis and form a double helical structure, thereby providing improved transmission characteristics in the high speed data transmission cable.Type: GrantFiled: December 16, 1997Date of Patent: January 4, 2000Assignee: Tensolite CompanyInventors: Matthew T. Kebabjian, Jerry J. Kulaga
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Patent number: 5968854Abstract: An electromagnetic shielding fabric is formed entirely from a plurality of synthetic fiber yarns which have been previously coated with silver. The preferred yarn structure comprises silver-coated nylon yarns, although other synthetic yarns can also be used as a base for the silver-coated yarns. The silver content of the silver-coated synthetic yarn is preferably not less than 20% by weight, and the conductivity of the silver-coated yarn is preferably not less than 1.2 ohms/cm. The silver-coated synthetic yarns are preferably formed into a planar textile material by means of a warp-knitting method which interlocks all of the yarns in a continuous chain stitch. The resulting fabric is thus formed entirely of the conductive silver-coated yarns thereby providing superior conductivity and electromagnetic shielding capability.Type: GrantFiled: October 3, 1997Date of Patent: October 19, 1999Assignee: Electromagnetic Protection, Inc.Inventors: Vladimir Akopian, Alexander Chirkov
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Patent number: 5935706Abstract: All surfaces of yarn formed of polymeric monofilament fibers are coated with a layer of electroless nickel which can also include an electrolytic metal such as copper on the nickel. The yarn is passed through an electroless Ni aqueous bath under little or no tension so that the electroless Ni can coat all of the monofilament surface substantially uniformly. The nickel coated yarn then can be coated with electrolytic metal such as copper in an electrolytic metal plating step.Type: GrantFiled: May 30, 1996Date of Patent: August 10, 1999Assignee: E. I. DuPont De Nemours & CompInventors: Merwin F. Hoover, Thomas F. Burke, Thomas H. Stearns
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Patent number: 5908812Abstract: A superconducting oxide composite structure including a superconducting oxide member, a metal layer surrounding the superconducting oxide member, and an insulating layer of a complex oxide formed in situ adjacent to the superconducting oxide member and the metal layer is provided together with a method of forming such a superconducting oxide composite structure including encapsulating a superconducting oxide member or precursor within a metal matrix layer from the group of: (i) a reactive metal sheath adjacent to the superconducting oxide member or precursor, the reactive metal sheath surrounded by a second metal layer or (ii) an alloy containing a reactive metal; to form an intermediate product, and, heating the intermediate product at temperatures and for time sufficient to form an insulating layer of a complex oxide in situ, the insulating layer to the superconducting oxide member or precursor and the metal matrix layer.Type: GrantFiled: February 5, 1996Date of Patent: June 1, 1999Assignee: The Regents of the University of CaliforniaInventors: James D. Cotton, Gilbert Neal Riley, Jr.
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Patent number: 5869430Abstract: According to an aspect, a tape-type high temperature superconducting wire is provided by applying compression work to a wire manufactured by drawing so that an oxide high temperature superconductor is divided into a plurality of superconductors by a stabilizing material of substantially equal thickness. According to another aspect, a high temperature superconducting wire is provided by packing a material which becomes a superconductor portion into a metal sheath which becomes the stabilizing material and applying drawing work thereto, followed by bundling an assembly of these wire in a metal sheath and applying drawing work thereto. The thickness of the superconductor portion is approximately 10% or less than the thickness of the wire. The critical current density is hardly decreased in the high temperature superconducting wire even if subjected to bending work.Type: GrantFiled: June 7, 1995Date of Patent: February 9, 1999Assignee: Sumitomo Electric Industries, Ltd.Inventors: Hidehito Mukai, Kenichi Sato, Nobuhiro Shibuta
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Patent number: 5802607Abstract: A garment for use in electronically-scored, contact-sports competitions is described. The garment is in the form of a fencing jacket or vest, is substantially wireless, and is woven from electrically conductive threads which cooperate with an electric sports implement to register a score when the implement contacts the electrically conductive garment. The fabric can be woven with the electrically-conductive threads extending in only one of the warp and weft directions, and preferably only in the weft direction.Type: GrantFiled: October 20, 1995Date of Patent: September 8, 1998Inventor: Walter W. Triplette
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Patent number: 5712034Abstract: A rubber article has a body consisting of rubber and a reinforcement structure with cables embedded in the rubber body. The cables have at least one inner layer with at least one first filament wherein at least one first filament consists of a metallic alloy. The outermost layer has second filaments embedded adhesively in the rubber body. All of the first and second filaments that consist of a metallic alloy are coated with a corrosion-protective coating. The corrosion-protective coating for at least one of the first filaments consists of an intrinsically conductive polymer.Type: GrantFiled: June 26, 1996Date of Patent: January 27, 1998Assignee: Continental AktiengesellschaftInventors: Hendrik Stevens, Bernd Kaiser, Klaus Kleinhoff
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Patent number: 5695847Abstract: A thermally conductive film that includes a film of polymeric matrix material having a thickness t defined between a top surface and a bottom surface. A plurality of fibers, having a greater thermal conductivity than the polymeric matrix material, is disposed in the film and extends between the top surface and the bottom surface. Each of the fibers are oriented in the film to form a fiber-to-film surface angle .theta. relative to the top and bottom surfaces that is greater than about 45.degree. but is less than arctan t/d, where t is the thickness of the film and d is the diameter of the fibers in the direction of the angle .theta.. A shear/extruder apparatus is used to form the thermally conductive film from a sheet of composite prepreg material. An upper die block and a lower die block separated by a predetermined distance form an extrusion slot therebetween.Type: GrantFiled: July 10, 1996Date of Patent: December 9, 1997Inventor: James M. Browne
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Patent number: 5686178Abstract: An article comprising a non-conductive substrate, preferably of an environmentally degradeable character, having a thickness of an oxidizable metal coating thereon, and optionally an oxidation enhancingly effective amount of a salt, e.g., from about 0.005 to about 25% by weight of salt, based on the weight of oxidizable metal, present on the oxidizable metal coating. Also disclosed is a related method of forming such article, comprising chemical vapor depositing the oxidizable metal coating on the substrate. When utilized in a form comprising fine-diameter substrate elements such as filaments, the resulting product may be usefully employed as an "evanescent" chaff. In the presence of atmospheric moisture, such evanescent chaff undergoes oxidization of the oxidizable metal coating so that the conductivity and radar absorbance/reflectance characteristics of the chaff transiently decays.Type: GrantFiled: July 11, 1994Date of Patent: November 11, 1997Assignee: Advanced Technology Materials, Inc.Inventors: Ward C. Stevens, Edward A. Sturm
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Patent number: 5674612Abstract: Articles made from poly(p-phenylene terephthalamide) polymer having an inherent viscosity of 1.5 to 4 dL/g, 5 to 20 mols of sulfur, as sulfonate, per 100 mols of polymer repeat units, and at least 0.5 weight percent of tungsten oxides or molybdenum oxides; and the process for making such articles.Type: GrantFiled: November 22, 1996Date of Patent: October 7, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Hamid Moayed Ghorashi, Robert Valentine Kasowski
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Patent number: 5571621Abstract: An infrared radiation-interactive article comprising a supported or unsupported oxidizable metal film of an infrared radiation-interactive size and shape, with an oxidation-promoting salt in contact with the metal film, arranged so that in exposure to ambient moisture, the metal film is oxidizable to an infrared radiation non-interactive form. The article of the invention may be employed to carry out a method of generating a transient infrared radiation response, e.g., an infrared radiation reflectance signature, or infrared radiation absorption, at a selected locus receiving infrared radiation incident thereon, by disposing at the locus an infrared radiation interactively-effective amount of such infrared radiation-interactive article.Type: GrantFiled: June 7, 1995Date of Patent: November 5, 1996Assignee: Advanced Technology Materials, Inc.Inventors: Ward C. Stevens, Edward A. Sturm
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Patent number: 5545474Abstract: An electromagnetic-attenuating coating having fibers uniformly dispersed in a lightly loaded dielectric matrix material. The fibers are metal-coated dielectric or semi-conductive fibers such as graphite fibers and the fibers are provided in an amount of less than 1 weight % of the coating. The dielectric matrix material is a resin material such as silicone. The fiber lengths and diameters, the material of the fibers and metal coating, the thickness and tolerance range of the metal coating and the loading of the metal coated fibers in the matrix material can be adjusted depending on the frequency range to be attenuated.Type: GrantFiled: March 1, 1994Date of Patent: August 13, 1996Assignee: Martin Marietta CorporationInventors: Stanley Podlaseck, Gene P. Shumaker, Paul D. Rimer
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Patent number: 5536574Abstract: The oxidation protection for a surface of a carbon/carbon composite substrate having a primary protective coating previously formed thereon is improved by applying to said surface a layer of a coating material comprising titanium diboride, colloidal silica, and an intermetallic compound, e.g., silicon carbide. The primary coating can be a boronated silicon carbide coating.Type: GrantFiled: March 28, 1995Date of Patent: July 16, 1996Assignee: Loral Vought Systems CorporationInventor: John A. Carter
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Patent number: 5527612Abstract: A fluorocarbon copolymer-insulated wire comprising, around a conductor, an insulating layer made of a composition comprising an ethylene-tetrafluoroethylene copolymer and an unsintered tetrafluoroethylene-propylene copolymer, which is resistant to heat, abrasion and oil, and improved in flexibility. The wire can be efficiently installed in a narrow space in various equipments and enables easy wiring work.Type: GrantFiled: June 30, 1994Date of Patent: June 18, 1996Assignee: Mitsubishi Cable Industries, Ltd.Inventors: Yutaka Ohta, Tamotsu Kaide, Kiyogo Nakagawa, Yosikazu Ebiike
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Patent number: 5506027Abstract: A method for preparing a metal matrix composite (MMC) monotape from a monofilament, is provided. The monofilament is first coated with a primary coating having metal particles uniformly distributed therein to form a primary monofilament. The primary monofilament is then clad with a secondary coating of a resin binder that does not resolvate the primary coating and thus interrupt the distribution of the metal particles therein, to form a doubly coated monofilament. The doubly coated monofilament is then wound in adjacent coils on a mandrel while the secondary coating is still wet so that the coils are bound together by the secondary coating. The end of the monofilament is then cut on the mandrel and secured to a coil adjacent thereto and the so-wound monofilament is then dried on the mandrel. Then the so-wound secondary monofilament is cut across its coils on the mandrel and removed to obtain the resulting MMC monotape.Type: GrantFiled: June 17, 1994Date of Patent: April 9, 1996Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Stuart A. Sanders, Penny D. Wooton, Robert J. Surace
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Patent number: 5494748Abstract: The invention relates to reinforcing and/or process fibers based on plant fibers, obtainable thereby that plant fibers from which the wood components have been removed by ultrasonic treatment are treated with an aqueous solution of at least one metal compound selected among metal oxides, hydroxides, carbonates, sulfates, thiosulfates, sulfites, silicates or phosphates, subsequently washed and treated with an inorganic or organic binding agent or the fibers which have not been washed are neutralized with a mineral acid or that plant fibers from which the wood components have been removed are treated with an oxidation agent or that non-pretreated plant fibers are treated at 250.degree. to 350.degree. C. with the controlled addition of air so that carbonization of the fibers takes place.Type: GrantFiled: June 8, 1993Date of Patent: February 27, 1996Assignee: Ecco Gleittechnik GmbHInventor: Jean L. Spehner
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Patent number: 5426000Abstract: Fiber-reinforced titanium alloy and intermetallic matrix composites having improved stability and tensile strength properties at elevated temperatures. The base reinforced fibers are pre-coated with a tailorable tri-layer coating, such as Ti--TiN--Ti. Preferably the TiN layer is graded so as to have metal-rich outer surfaces, such as titanium-rich TiN, providing excellent bonding affinity for the base titanium layer, bonded to the surface of the fibers, such as silicon carbide, and for the outer titanium layer, bonded to the titanium aluminum matrix, and a compound core, such as stoichiometric TiN, providing a stable interfacial barrier against chemical reactions, whereby the tensile strength and resistance to cracking of the composite is preserved even at elevated temperatures of 900.degree. C. or higher.Type: GrantFiled: August 5, 1992Date of Patent: June 20, 1995Assignee: AlliedSignal Inc.Inventors: Mohamed E. Labib, Bawa Singh
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Patent number: 5418040Abstract: A thermosetting damper material which is in a liquid phase at normal temperature is coated on a surface of an automobile fuel tank. Thereafter, the coated thermosetting damper material is heated to thermoset the thermosetting damper material into a damper layer on the surface of the automobile fuel tank. A paint layer may be coated on the surface of the automobile fuel tank over or under the damper layer.Type: GrantFiled: August 5, 1992Date of Patent: May 23, 1995Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Mitsuo Kaneko, Kouzou Hannuki, Hiroyoshi Nozaki, Shigeo Kaibuki
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Patent number: 5411804Abstract: The present invention relates to a heat resistant composition which exhibits excellent heat and wear resistances after being cured. Further, it has excellent releaseability and durability, and the cured film thereof has a more excellent stability than a prior art adhesive of this type, by preparing it from two components: a powder mixture consisting of 20% by weight or more of zirconium oxide, 1 to 10% by weight of sodium titanate, 2 to 15% by weight of yttria based on the zirconium oxide and the balance of silica; and a sodium silicate containing a small amount of water added thereto.Type: GrantFiled: August 4, 1993Date of Patent: May 2, 1995Assignee: Sugianikinzokukogyo Co. Ltd.Inventor: Nobuhiro Sugitani
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Patent number: 5407740Abstract: A preferred composite which is useful at temperatures in excess of about 0.degree. C. comprising a ceramic matrix and 40-60% on volume basis of coated and uncoated fibers embedded in the matrix generally parallel to each other and in a controlled arrangement; the matrix is selected from the group consisting essentially of silicon nitride, silicon carbide and zirconium titanate; the fibers are silicon carbides fibers 5-20 microns thick; the coating on the coated fibers is boron nitride 0.1-0.3 microns thick; cross-section of the composite contains about one half, on volume basis, of uncoated fibers in one band extending from one side edge of the cross-section to the opposite side edge; the composite having unexpectedly improved strength and/or toughness compared to a composite composed of only coated or only uncoated fibers.Type: GrantFiled: January 7, 1994Date of Patent: April 18, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventor: Todd L. Jessen
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Patent number: 5399425Abstract: A method is disclosed for metallizing polymers comprising generating anionic sites on the structures, contacting same with the cation of the metal and then reducing the metal cation to metal at the anionic sites or treating the metal cations to form a semiconductor. The metallized polymers are useful as electrical conductors or semiconductors.Type: GrantFiled: August 14, 1992Date of Patent: March 21, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert R. Burch
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Patent number: 5397608Abstract: The present invention relates to articles, particularly plate or sheet-like articles made of plastic in which very low contents of fine electrically conductive fibers are uniformly dispersed so as to make the articles conductive. It also relates to specific intermediate plastic products, referred to as grains, threads and granules, and the processes for manufacturing each of these products as well as the final conductive articles. The articles can be used as a suitable shielding against radio-frequency and high-frequency electromagnetic radiation or as antistatic plastic articles.Type: GrantFiled: July 23, 1986Date of Patent: March 14, 1995Inventor: Lode J. Soens
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Patent number: 5372886Abstract: An insulated wire is suitable for use as a distribution wire, a wire for winding a coil or the like, which is used in a high-vacuum environment or in a high-temperature environment such as a high vacuum apparatus or a high temperature service apparatus. The insulated wire has a base material (1) forming a substrate, a chromium oxide CrO.sub.3-x containing intermediate layer (2) on the substrate, and an oxide insulating layer (3) on the intermediate layer. The base material (1) is an electrical conductor. The chromium oxide containing layer (2) is so formed that the ratio of oxygen to chromium O/Cr is not less than 0.5 but less than 1.5 to avoid the formation of chromic oxide Cr.sub.2 O.sub.3 which reduces the adhesive bonding strength. The oxide insulating layer (3) is formed by applying a precursor solution of a metallic oxide onto the chromium oxide containing layer (2) by a sol-gel method or an organic acid salt pyrolytic method.Type: GrantFiled: February 26, 1993Date of Patent: December 13, 1994Assignee: Sumitomo Electric Industries, Ltd.Inventors: Shinji Inazawa, Kouichi Yamada, Kazuo Sawada
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Patent number: 5356711Abstract: At least one metal wire embedded in a vulcanized elastomeric matrix obtained from a mixture comprising at least one vulcanizable elastomer and at least one vulcanization agent such as sulfur. The metal wire is galvanized steel and the vulcanizable mixture contains at least 0.2% by weight of trimercapto triazine, with respect to the weight of said elastomer, and 0.1-0.5% by weight of cobalt, with respect to the weight of said elastomer.Type: GrantFiled: December 27, 1991Date of Patent: October 18, 1994Assignee: Pirelli Coordinamento Pneumatici S.p.A.Inventors: Luciano Garro, Enzo Falzolgher
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Patent number: 5352519Abstract: An article comprising a non-conductive substrate having a sub-micron thickness of a sulfur-doped oxidizable metal coating thereon. Optionally, the sulfur-doped oxidizable metal-coated substrate may be further coated with (i) a promoter metal which is galvanically effective to promote the corrosion of the oxidizable metal, discontinuously coated on the oxidizable metal coating, and/or (ii) a salt, to accelerate the galvanic corrosion reaction by which the oxidizable metal coating is oxidized. When utilized in a form comprising fine diameter substrate elements such as glass or ceramic filaments, the resulting product may usefully be employed as an evanescent chaff. In the presence of atmospheric moisture, such evanescent chaff undergoes oxidation of the oxidizable metal coating so that the radar signature of the chaff transiently decays.Type: GrantFiled: November 27, 1992Date of Patent: October 4, 1994Assignee: Advanced Technology Materials, Inc.Inventors: Ward C. Stevens, Edward A. Sturm, Bruce C. Roman
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Patent number: 5298298Abstract: This invention offers a unique method to fabricate unique, straight, curved, or coiled tubes as small as 1 micron (0.000004 inches) in diameter with wall thicknesses starting at less than 0.01 microns. These tubes can be made from many of the materials that can be applied to a surface of carbon, glass, or other tube forming fibers and then made to withstand the environment used to remove the fiber. A monolithic piece can be formed where the tubes are channels or holes.Type: GrantFiled: January 30, 1991Date of Patent: March 29, 1994Assignee: The United States of America as represented by the Secretary of the Air ForceInventor: Wesley P. Hoffman
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Patent number: 5283121Abstract: A coating comprising a non-porous textured corrosion resistant and abrasion resistant base layer of metal is applied by a thermal flame spray process using a high-velocity oxy-fuel, and a top coating of a continuous film of fluoropolymer is used to enhance and protect the surface bare metal on industrial rollers in a multitude of industrial environments that are corrosive, abrasive or otherwise have elements present which tend to stick to the roller surface. The corresponding method comprises the steps of providing a body member having a relatively soft and corrodible metal first layer, applying a middle metal layer to the first layer by a high-velocity oxy-fuel type metal thermal spray process, applying an outer layer comprising a fluoropolymer coating over said middle layer to provide a non-sticking characteristic to the coating; and heating said outer layer to a level above the curing temperature of the fluoropolymer so as to bond the fluoropolymer to said middle layer.Type: GrantFiled: November 8, 1991Date of Patent: February 1, 1994Inventor: Barry A. Bordner
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Patent number: 5244748Abstract: A fiber coating which allows ceramic or metal fibers to be wetted by molten metals is disclosed. The coating inhibits degradation of the physical properties caused by chemical reaction between the fiber and the coating itself or between the fiber and the metal matrix. The fiber coating preferably includes at least a wetting layer, and in some applications, a wetting layer and a barrier layer between the fiber and the wetting layer. The wetting layer promotes fiber wetting by the metal matrix. The barrier layer inhibits fiber degradation. The fiber coating permits the fibers to be infiltrated with the metal matrix resulting in composites having unique properties not obtainable in pure materials.Type: GrantFiled: January 27, 1989Date of Patent: September 14, 1993Assignee: Technical Research Associates, Inc.Inventors: Joseph K. Weeks, Jr., Chantal Gensse
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Patent number: 5238741Abstract: Silicon carbide filaments are coated to protect them from attack by a titanium matrix material when incorporating them into a metal matrix composite. The coating method comprises coating the filaments firstly with a carbon layer and then with a titanium carbide or boride layer whose carbon or boron content decreases progressively from its interface with the carbon layer to its exterior surface. A layer of titanium or a titanium based alloy may be provided on the titanium carbide or boride layer to facilitate incorporation into a metal matrix. Preferably, the layers are applied by sputter ion plating.Type: GrantFiled: July 17, 1992Date of Patent: August 24, 1993Assignee: United Kingdom Atomic Energy AuthorityInventors: Clive F. Knights, John Cook, David S. Rickerby
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Patent number: 5232779Abstract: The invention relates to reinforcing and/or process fibers based on plant fibers, obtainable thereby that plant fibers from which the wood components have been removed are treated with an aqueous solution of at least one metal compound selected among metal oxides, hydroxides, carbonates, sulfates, thiosulfates, sulfites, silicates or phosphates, subsequently washed and treated with an inorganic or organic binding agent or the fibers which have not been washed are neutralized with a mineral acid or that plant fibers from which the wood components have been removed are treated with an oxidation agent or that non-pretreated plant fibers are treated at 250.degree. to 350.degree. C. with the controlled addition of air so that carbonization of the fibers takes place.Type: GrantFiled: December 14, 1990Date of Patent: August 3, 1993Assignee: Ecco Gleittechnik GmbHInventor: Jean L. Spehner
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Patent number: 5217808Abstract: An optical cable portion (10), resident within a cable closure (14), is caused to receive a water blocking arrangement which is effective to prevent water, which enters an internal cable portion (24) through an unintended cut (21) in an outer jacket (18) of a cable portion (20), from entering an interior of the cable closure. A plurality of water blocking materials (30 and 32) are coaxially disposed about the outer jacket and a core tube (26) of the cable portion, respectively, and cooperate with a heat shrinkable plastic tube (34) which substantially covers the water blocking materials to prevent the movement of water from the internal cable portion past the water blocking materials.Type: GrantFiled: November 29, 1989Date of Patent: June 8, 1993Assignee: AT&T Bell LaboratoriesInventor: Gary S. Cobb
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Patent number: 5212013Abstract: The need for high current, high field, low loss, stable superconductors has led to the development of multifilamentary Nb.sub.3 Sn as the most promising candidate for use in superconducting machines. However, the brittle nature of Nb.sub.3 Sn and the high reaction temperature (.about.700.degree. C.) required to form it preclude the use of standard organic insulation systems. A recently developed class of high temperature dielectric materials which are characterized by unusually large specific heats and thermal conductivities at cryogenic temperatures offers the opportunity of providing increased enthalpy stabilization in a superconducting winding, as well as the required dielectric strength. The inorganic insulation system consists of a composite glass and ceramic powder vitrified at a temperature which coincides with the superconducting formation temperature of 600.degree.-800.degree. C.Type: GrantFiled: June 9, 1988Date of Patent: May 18, 1993Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Tapan K. Gupta, George J. Bich, William N. Lawless
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Patent number: 5176767Abstract: The present invention is directed to bead wires which has a Cu/Sn deposit having an Sn content of 9 to 13% by weight and a Cu content of 91 to 87% by weight, in an amount of 0.65 to 0.85 g per kilogram of the wire. The present invention is also directed to rubber-coated bead wires for tires comprising the plated bead wire as mentioned above, a rubber layer formed on the bead wire from a composition comprising 100 parts of a rubber polymer, 80 to 140 parts of a carbon, 4 to 10 parts of sulfur, 0.4 to 0.9 part of a vulcanization accelerator, 10 to 7 parts of zinc oxide, and 1 to 4 parts of stearic acid, and to tires prepared by using the above-mentioned bead wires. The bead wires of the present invention have excellent adhesion between the plated bead wire and the rubber layer, so that the tires obtained using such bead wires avoid wild wires.Type: GrantFiled: March 15, 1991Date of Patent: January 5, 1993Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hiroshi Hoshino, Shinichi Miyazaki
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Patent number: 5156912Abstract: The subject invention relates to a coated reinforcement material comprising a SiC reinforcement having a coating of at least three layers, wherein the layers are alternately A-material layers of the general formula:Al.sub.x O.sub.y N.sub.zwherein x is up to about 60 atomic % of the coating;y is from about 20 atomic % to about 55 atomic % of the coating; andz is from about 5 atomic % to about 45 atomic % of the coating, with the proviso that x+y+z=100, and B-material layers comprising a metal alloy, such that the first and last layers of the coating are A-material layers. The invention further relates to a high strength, high temperature performance composite containing the above-specified coated reinforcement.Type: GrantFiled: December 20, 1989Date of Patent: October 20, 1992Assignee: The Standard Oil CompanyInventors: D. Lukco, M. A. Tenhover
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Patent number: 5139874Abstract: Steel cables are utilized for reinforcing a wide variety of rubber articles. For instance, pneumatic tires are normally reinforced with steel tire cords. It is important for such reinforcing cables to exhibit good fatigue and corrosion resistance. It has been unexpectedly found that the fatigue and corrosion resistance of such cables can be improved by incorporating syndiotactic-1,2-polybutadiene into the interstices between the steel filaments in such cables. This invention more specifically relates to a cable for reinforcing rubber articles having improved fatigue and corrosion resistance which is comprised of a plurality of steel filaments and syndiotactic-1,2-polybutadiene, wherein the syndiotactic-1,2-polybutadiene is dispersed within interstices between said steel filaments.Type: GrantFiled: May 9, 1991Date of Patent: August 18, 1992Assignee: The Goodyear Tire & Rubber CompanyInventors: Thomas W. Starinshak, Robert M. Shemenski, John W. Price, Jr., Robert J. Gartland
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Patent number: 5118568Abstract: A steel cord for reinforcing rubber. It is made of three steel filaments all having different diameters from one another. The small-diameter and medium-diameter ones of the three filaments have internal stresses adapted to be released when the cord is cut at both ends thereof. Owing to these stresses, the diameter of the cord is adapted to increase after it is cut at both ends. At the same time, the medium-diameter and small-diameter filaments retract inwardly from the ends of the large-diameter and medium-diameter ones, respectively.Type: GrantFiled: April 4, 1990Date of Patent: June 2, 1992Assignees: Sumitomo Electric Industries, Ltd., Sumitomo Rubber Industries, Ltd.Inventors: Kenichi Okamoto, Hidekazu Nakata, Kazuhiko Kawamura
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Patent number: 5093184Abstract: This invention is concerned with security paper for bank notes, cheques and like documents in a security strip of enhanced security which is more difficult to counterfeit than the present bank notes containing window threads.Type: GrantFiled: May 29, 1990Date of Patent: March 3, 1992Assignee: Portals LimitedInventor: David J. Edwards
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Patent number: 5087515Abstract: An article comprising a non-conductive substrate which is coated with a sub-micron thickness of an oxidizable metal and overcoated with a microporous layer of an inorganic electrically insulative material. Optionally, the oxidizable metal-coated substrate may be sulfurized and/or further coated with (i) a promoter metal which is galvanically effective to promote the corrosion of the oxidizable metal, discontinuously coated on the oxidizable metal coating, and/or (ii) a salt, to accelerate the galvanic corrosion reaction by which the oxidizable metal coating is oxidized, prior to overcoating with the microporous insulative layer. Also disclosed is a related method of forming such articles, comprising chemical vapor depositing the oxidizable metal coating on the substrate and contacting the metallized substrate with a sol gel dispersion of the inorganic electrically insulative material which then is dried under suitable conditions to form the microporous layer on the substrate.Type: GrantFiled: December 11, 1989Date of Patent: February 11, 1992Assignee: Advanced Technology Materials, Inc.Inventors: Ward C. Stevens, Edward A. Sturm, Bruce C. Roman
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Patent number: 5075160Abstract: A filter for removing particulate matter from high temperature flowing fluids, and in particular gases, that is reinforced with ceramic fibers. The filter has a ceramic base fiber material in the form of a fabric, felt, paper of the like, with the refractory fibers thereof coated with a thin layer of a protective and bonding refractory applied by chemical vapor deposition techniques. This coating causes each fiber to be physically joined to adjoining fibers so as to prevent movement of the fibers during use and to increase the strength and toughness of the composite filter. Further, the coating can be selected to minimize any reactions between the constituents of the fluids and the fibers. A description is given of the formation of a composite filter using a felt preform of commercial silicon carbide fibers together with the coating of these fibers with pure silicon carbide. Filter efficiency approaching 100% has been demonstrated with these filters.Type: GrantFiled: June 13, 1988Date of Patent: December 24, 1991Assignee: Martin Marietta Energy Systems, Inc.Inventors: David P. Stinton, Jerry C. McLaughlin, Richard A. Lowden
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Patent number: 5034274Abstract: An article comprising a non-conductive substrate having a sub-micron thickness of an oxidizable metal coating thereon, and an oxidation enhancingly effective amount of a salt, e.g., from about 0.005 to about 25% by weight of salt, based on the weight of oxidizable metal, present on the oxidizable metal coating. Also disclosed is a related method of forming such article, comprising chemical vapor depositing the oxidizable metal coating on the substrate, applying the salt by contacting of the oxidizable metal-coated substrate with a salt solution, and drying of the salt solution on the oxidizable metal film to yield the product salt-doped, oxidizable metal-coated substrate article. When utilized in a form comprising fine-diameter substrate elements such as glass or ceramic filaments, the resulting product may be usefully employed as an "evanescent" chaff.Type: GrantFiled: December 11, 1989Date of Patent: July 23, 1991Assignee: Advanced Technology Materials, Inc.Inventors: Ward C. Stevens, Edward A. Sturm, Bruce C. Roman
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Patent number: 4960640Abstract: A fibrous substrate having a first coefficient of thermal expansion and having porous characteristics is formed from discrete elements, such as carbon fibers, having anisotropic properties. A matrix formed from a refractory material encases the discrete elements and has a second coefficient of thermal expansion different from the first coefficient. The matrix has minimal chemical or mechanical bonding to the discrete elements to provide for a displacement of the matrix relative to the substrate with mechanical shock or changes in temperature. The matrix includes a first element having refractory properties and selected from the group consisting of hafnium, zirconium, tantalum, tungsten and molybdenum and also includes a second element bound to the first element. The matrix is preferably formed by providing a mixture of a first gas containing the refractory element and a second gas containing the second element and by introducing the gases into a chamber containing the substrate.Type: GrantFiled: February 19, 1988Date of Patent: October 2, 1990Assignee: Refractory Composites, Inc.Inventors: Edward L. Paquette, Marc G. Simpson
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Patent number: 4952554Abstract: A method of producing normal-metal-clad superconductive oxide wire, tape and the like is disclosed. The method comprises forming an intermediate body by surrounding a quantity of the oxide powder (e.g., Ba.sub.2 YCu.sub.3 O.sub.6.9) with an appropriate normal metal jacket, reducing the cross section of the intermediate body by any appropriate technique (e.g., drawing or rolling), and heat treating the elongated body such that substantial sintering of the powder results, and such that, after completion of the heat treatment, the sintered oxide has a composition that is associated with superconductivity in unclad bulk samples of the oxide. The latter condition requires that at least the portion of the cladding that is in contact with the oxide powder is substantially inert with respect to oxygen and the oxide under the conditions of the heat treatment. Silver is the currently preferred inert normal metal. Exemplarily, Ag can be used to provide a diffusion barrier with other normal metal (e.g.Type: GrantFiled: April 6, 1987Date of Patent: August 28, 1990Assignee: AT&T Bell LaboratoriesInventors: Sungho Jin, Richard C. Sherwood, Robert B. van Dover
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Patent number: 4935296Abstract: A metal-coated substrate, e.g., of glass, ceramic, or a hydroxy-functionalized material, wherein the improvement comprises a polysilicate, titania, or alumina interlayer between the substrate and the metal coating. The interlayer may have a porous microstructure, e.g., a polysilicate interlayer with an average pore size on the order of 50-150 Angstroms.Such articles, e.g., in the form of metal-coated fibers, may suitably be employed as reinforcing media in material composites having utility in structural applications, such as EMI shielding elements.Also disclosed is a corresponding method for forming a metal coating on a substrate by the provision of an interlayer of the above type. The interlayer may suitably be formed by applying to the substrate a sol gel dispersion of the polysilicate, titania, or alumina material, followed by drying of the applied dispersion.Type: GrantFiled: October 31, 1988Date of Patent: June 19, 1990Assignee: Advanced Technology Materials, Inc.Inventor: Ward C. Stevens
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Patent number: 4900618Abstract: Oxidation-resistant, electrolessly deposited metal coatings, e.g. of copper, can be provided on a variety of substrates such as fibers and films. Precursor substrates have nascent or actual clusters of catalytic metal with dimensions less than 100 nanometers, e.g. about 10 nanometers. Disclosed methods can produce electrically conductive, copper-coated PET or acrylic multifilament with a resistance of less than 20 ohms/meter.Type: GrantFiled: June 19, 1987Date of Patent: February 13, 1990Assignee: Monsanto CompanyInventors: Michael T. O'Connor, James D. Capistran, James P. Brozek, Albert W. Morgan
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Patent number: 4882227Abstract: There is provided an electric conductive resin composition formed into a pellet, which includes an electric conductive filler comprising electric conductive fibers and a low-melting point metal, and being coated on the surface thereof with a thermoplastic resin. Flux and/or a phosphorus-based antioxidant may be added to the filler. There is also provided an electromagnetic wave shielding molded product prepared by using the electric conductive resin composition mentioned above, wherein the electric conductive fibers dispersed within the molded product are fixed each other through the low-melting point metal.Type: GrantFiled: March 9, 1988Date of Patent: November 21, 1989Assignee: Toshiba Chemical CorporationInventors: Hidehiro Iwase, Keiichi Habata
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Patent number: 4863798Abstract: A porous substrate is formed from discrete elements preferably anisotropic and permeable to oxygen and preferably having a first coefficient of thermal expansion. A pyrolytic material permeable to oxygen may be deposited in a thin layer on the discrete elements. A barrier material (e.g. boron carbide or silicon carbide) may be deposited in a thin layer on the pyrolytic material to inhibit diffusion of elements into the pyrolytic material. A material impermeable to oxygen (e.g. boron nitride or silicon nitride) may be deposited in a thin layer on the barrier material. A refractory matrix permeable to oxygen may be deposited on the impermeable material. The matrix may include a metallic element (e.g. silicon, hafnium, tantalum or zirconium) and another element (e.g. oxygen, nitrogen, carbon or boron) chemically bonded to the metallic element. The matrix may have a second coefficient of thermal expansion different from the first coefficient and may have a minimal bond to the substrate.Type: GrantFiled: July 21, 1988Date of Patent: September 5, 1989Assignee: Refractory Composites, Inc.Inventors: David L. Arenz, Edward L. Paquette, Marc G. Simpson
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Patent number: 4849288Abstract: A superconducting fiber of a superconducting fiber bundle includes a carrier fiber having an outer surface, and superconducting layers and separating layers alternatingly surrounding the outer surface of the carrier fiber and a method for producing the same.Type: GrantFiled: July 7, 1986Date of Patent: July 18, 1989Assignees: Brown, Boveri & Cie. AG, Kernforschungszentrum Karlsruhe GmbHInventors: Franz Schmaderer, Georg F. Wahl, Cord-Heinrich Dustmann, Erich Fitzer, Karl Brennfleck, Manfred Dietrich
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Patent number: 4816618Abstract: A coaxial cable is provided having a ribbon inner conductor surrounded by a dielectric and a circumferential conductor. The coaxial cable may be microminiature comprising a very thin ribbon strip conductor from between 5 to 15 .mu.m thick and from 150 to 200 .mu.m wide, having a surrounding foamed dielectric or parylene applied thereon by a vapor plasma process and an outer conductor of an adhering high conductivity metal vacuum deposited on the dielectric. Alternately, the foam dielectric embodiment may have a contiguous parylene coating applied adjacent the inner conductor or the outer conductor or both. Also, the cable may be fabricated by forming a thin ribbon of strip conductive material into an inner conductor, applying thereabout a dielectric by spraying on a solution of polystyrene and polyethylene and then vacuum depositing and adhering high conductivity metal about the dielectric.Type: GrantFiled: October 15, 1986Date of Patent: March 28, 1989Assignee: University of CaliforniaInventor: Wayne L. Bongianni
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Patent number: 4792645Abstract: Disclosed herein is a process for producing electroconductive fibrous shaped-articles comprising the steps of:soaking water-absorptive fibrous shaped-articles in a palladium hydrosol containing a cationic surfactant, an anionic surfactant, a non-ionic surfactant or a mixture thereof, and after (i) drying the thus treated shaped-articles, (ii) washing the thus treated shaped-articles with water or (iii) washing the thus treated shaped-articles and then drying, subjecting the thus obtained, shaped-articles on which colloidal palladium is adsorbed to chemical plating, thereby obtaining the electroconductive fibrous shaped-articles of which fibers thereof are subjected to metallizing plating.Type: GrantFiled: August 28, 1985Date of Patent: December 20, 1988Assignees: The Agency of Industrial Science & Technology, Toda Kogy Corp.Inventors: Yukimichi Nakao, Kyoji Kaeriyama, Yoshio Suda, Tomoyuki Imai, Osamu Oze, Nanao Horiishi