Abstract: A co-mingled polyurethane-polyvinyl ester composition can be used as a coating, which has good scratch, mar and solvent resistance. The coating is derived from a waterborne polyurethane solution containing free radically polymerizable monomers such as acrylate, ultraviolet light initiators, and optionally urethane crosslinking agents. A process for forming the co-mingled polyurethane-polyvinyl ester composition comprises drying the waterborne polyurethane containing the polymerizable monomers therein and radiation polymerizing, as by ultraviolet light, the free radically polymerizable monomers on a substrate such as a plastic sheet to form a laminate. Subsequently, the laminate can be utilized to form a coating on a product as by thermoforming, where if urethane crosslinking agents are utilized, the polyurethane will be crosslinked.

Abstract: A polycarbonate composition featuring improved adhesion to polyurethane, preferably polyurethane foam is disclosed. The composition contains (A) an aromatic polycarbonate and/or polyester-carbonate, (B) a graft polymer and (C) a copolymer of styrene and a monomer containing carboxyl groups, the copolymer having a weight average molecular weight Mw of >10,500 g/mol. Composite materials containing layers of the inventive composition and polyurethane layer, preferably foam, are also disclosed.

Abstract: The invention relates to protective coverings with a coating build-up of at least two layers, the first coating comprising an adhesion promoter based on a two-component polyurethane binder containing alkoxysilyl groups and the second coating comprising an inorganic coating, a process for the production of these protective coverings and the covered substrates.

Abstract: A multi-layered article comprising a first layer of a thermoset polyurethane. A second layer of a polymeric composition is bonded to the first layer. The polyurethane has available isocyanate groups prior to the application of the second layer. The second layer is applied onto the first layer in a pre-polymeric or polymeric state wherein the material has carboxyl groups and a cross-linking agent.

Abstract: A metallized composite comprising a first thermoplastic layer, a discontinuous intermediate layer comprising discrete islands of metal in an adhesive, and a second thermoplastic layer. The metallized composites of the invention can be employed as reflective surfaces, such as are used as mirrors or substitutes for chrome trim on automobiles. A particularly preferred metal as a component of the discontinuous layer of the composite is indium.

Abstract: A laminate comprising a printed layer, a transparent thermoplastic polyurethane layer and a layer forming a substrate of a thermoplastic material is disclosed. The laminate that is characterized in that the printed layer is interposed between the layer forming a substrate and the polyurethane layer is suitable for the preparation of a variety of articles.

Abstract: A co-mingled polyurethane-polyvinyl ester composition can be used as a coating, which has good scratch, mar and solvent resistance. The coating is derived from a waterborne polyurethane solution containing free radically polymerizable monomers such as acrylate, ultraviolet light initiators, and optionally urethane crosslinking agents. A process for forming the co-mingled polyurethane-polyvinyl ester composition comprises drying the waterborne polyurethane containing the polymerizable monomers therein and radiation polymerizing, as by ultraviolet light, the free radically polymerizable monomers on a substrate such as a plastic sheet to form a laminate. Subsequently, the laminate can be utilized to form a coating on a product as by thermoforming, where if urethane crosslinking agents are utilized, the polyurethane will be crosslinked.

Abstract: An optically transparent glazing measures about 3 to 5 mm in total thickness, and has an interlayer film, the interlayer film comprises at least two polymeric film layers: a core film layer having a modulus of at least 25,000 psi (173 MPa) and a surface film layer having a maximum modulus of 15,000 (104 MPa) at 50 to 10,000 Hz and 20° C.; and the glazing is characterized by an acoustical barrier insulating capacity at least equivalent to that of a 3.85 mm thick monolithic pane of glass. The glazing also has an Articulation Index value of less than 64.2% at 50 to 10,000 Hz, a sharpness value of less than 150 at 50 to 10,000 Hz, a penetration resistance of at least 9 meters in test method ECE R43, A6 4.2, and a maximum haze of 4%. The interlayer film has a bending stiffness of at least 0.01 Pa*m3. The surface film layer has a maximum tan delta of 0.6 at 50 to 10,000 Hz and 20° C. The interlayer film preferably comprises one core film layer of between 1.0 and 1.

Abstract: A metallized article and method for making the article, including a substrate having a polyurethane basecoat disposed thereon, with a layer of electrically discrete metallic islands of a corrosion prone metal disposed on the basecoat. A cross-linked polyurethane topcoat, containing an aminosilane, is further disposed on an encapsulates the discrete metallic islands.

Abstract: An optical article comprising a first layer of a transparent resin having a self-healing property; an antireflection layer consisting essentially of a non-crystalline fluorine-containing polymer disposed underneath said first layer; and a circular polarizer disposed underneath said antireflection layer. The optical article has anti-reflective and anti-glare properties and also has self-healing properties and scuff resistance imparted by a thin, multi-layered film. The optical article thus is effective in reducing reflection and glare.

Abstract: A window for use in a vehicular convertible top comprises a thin, flexible, optically transparent plastic substrate sheet, and a thin, flexible, optically transparent abrasion-resistant protective outer film layer adherently bonded as a permanent coating to both sides of the plastic substrate sheet. The protective outer film layer comprises a weatherable polymer which is transparent in thin film form reacted with a cross-linking agent and blended with a dispersed lubricant to provide a level of abrasion-resistance and a self-lubricating exterior surface to the finished protective outer film. The window withstands repeated folding and unfolding without self-adhesion of the contacting surfaces owing to the release properties provided by the lubricant. In one embodiment, the weatherable polymer comprises a solvent based solution of a polyurethane material reacted with a polyisocyanate cross-linking agent and blended with a polyol-ester glycol-based external lubricant.

Abstract: A hydrophilic coating having a covalently cross-linked hydrophilic polymer suitable for coating medical devices or instruments for introduction into human cavities, the coating further having a water soluble compound, the water soluble compound being glucose, sorbitol, a halide, nitrate, acetate, citrate or benzoate of an alkali metal or alkaline earth metal or silver; acetic acid, glycine or urea. A medical device or instrument for introduction into human cavities having a hydrophilic coating and a method of producing such a medical device or instrument.

Abstract: Multilayer composite materials with at least one aerogel-containing layer and at least one other layer, a process for producing the same and their use are disclosed. The aerogel-containing layer(s) further contain at least one binder.

Abstract: The present invention relates to chloride-selective electrodes which comprise insoluble metal salt layer and a protecting membrane formed of hydrophilic polyurethane thereon, wherein the hydrophilic polyurethane coated chloride-selective electrodes show fast activation and response time and are usefully employed to accurately measure the chloride by reducing the interference from bromide and iodide or preventing the surface of the electrode from protein adsorption.

Abstract: An artificial leather strip, and methods of making such a strip. The synthetic leather strip is suitable for sporting applications such as lacing baseball gloves and shoes. The strip comprises at least one reinforcing cord embedded in a matrix. The matrix comprises PVC and additives such as nitrile rubber and/or urethane, and is sufficiently tough to resist the “cheesecutter” effect when the strip is flexed, for example by being tied in a knot.

Abstract: A composite article is provided which includes a fluoropolymer intimately bonded to a component including a substantially non-fluorinated thermoplastic having pendant phenolic groups in combination with a base. Increased adhesion is observed by a greater peel strength value between the fluoropolymer component and a non-fluorinated thermoplastic having pendant phenolic groups.

Abstract: A primer for the metallization of substrate surfaces by chemical reduction, comprising a) from about 3 to about 40% by weight of a film or matrix former, b) from about 0.1 to about 15% by weight of an additive having a molecular mass of 500 to 20,000, c) from about 0.1to about 15% by weight of an ionic and/or colloidal metal or its organometallic covalent compound or complex compound with organic ligands, d) from about 0.5 to about 30% by weight of an organic and/or inorganic filler, e) from about 0.05 to about 5% by weight of a hydrophilic swelling material comprising finely divided particles containing silanol groups and/or partly modified silanol groups having a diameter of from 7 to 40 nm and a specific surface area of 50 to 380 m2/g, and f) from about 50 to about 90% by weight of organic solvents, in which all amounts by weight being based on the overall primer formulation, offers advantages at low bath loadings.

Abstract: There is a need for polymers that offer a high level of heat and ultraviolet light resistance. It is particularly critical for polymers that are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. Polymer blends having such characteristics can be made by blending certain rubbery polymers with halogen containing polymers, such as polyvinyl chloride (PVC). There is currently a demand for halogen-free polymers having such characteristics. This invention discloses a rubbery polymer that can be blended with polyolefins, such as polyethylene or polypropylene, to make leathery compositions having good heat and ultraviolet light resistance. The rubbery polymer of this invention is comprised of repeat units which are comprised of (a) butyl acrylate, (b) an alkoxyalkylene acrylate, (c) styrene, (d) a half ester maleate soap, and (e) a crosslinking agent.

Abstract: A photovoltaic module that contains one or more layers of a multi layered composite film is disclosed. The multilayered film contains at least one layer of polycarbonate and at least one layer of fluorine-containing polymer. The photovoltaic module of the invention features improved printability and mechanical properties.

Abstract: An extended life fluorescent polyvinyl chloride sheeting and a method for forming the sheeting are disclosed. The sheeting includes a polyvinyl chloride film having a fluorescent colorant incorporated therein. A protective polymer layer is attached to the polyvinyl chloride film. A light filtering agent is incorporated into the protective layer, wherein the filter agent blocks the 425 nm and lower wavelengths of the visible spectrum.

Abstract: A process is disclosed for the manufacture of reinforced composites. This method provides a process that allows for the direct mixing of discontinuous reinforcement such as wet chopped strands of glass fiber or continuous reinforcement such as glass strands, with an aqueous suspension of a solution polymerized polymer, such as polyvinyl chloride. The process results in a cost-effective means for reinforcing polymers such as PVC while simultaneously substantially improving properties such as impact strength, stiffness, and moldability without the need for a binder.

Abstract: Described is a preferred UV curable coating composition comprising (exclusive of any solvent present): (a) about 5% to 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 500 to 2000 and comprising an aliphatic urethane based on a polymer of allyl carbomonocycle diisocyanate with alkanepolyol polyacrylates, (b) about 5% to 30% by weight of a multifunctional acrylate having a molecular weight of about 170 to 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes of coating a plastic and coated articles involving the preferred coating compositions.

Abstract: In one embodiment the present invention provides a coated substrate comprising a substrate, a radiation-cured coating or a thermally-cured on at least a portion of the substrate, wherein the coating comprises an inherent macroscopic texture. In another embodiment, the present invention provides a pre-cured coating mixture comprising a radiation-curable resin and an initiator, or a thermally-curable resin and thermal initiator, wherein the radiation- or thermally-curable resin and the respective initiator form a pre-cured coating mixture capable of forming a macroscopic texture upon application of the mixture on a substrate. In another embodiment the present invention provides a pre-cured coating mixture comprising a radiation- or thermally-curable resin, an initiator, and texture-producing particles having an effective size to provide a macroscopic texture upon application of the mixture on a substrate.

Abstract: Compositions comprising a fluorochemical agent, a copolymer extender, and a blocked isocyanate extender and substrates treated with such compositions that possess high initial water repellency and laundry durable water repellency.

Abstract: The invention relates to a pressure and vacuum deformable, grained bonding foil for linings of motor vehicle interiors with at least one support layer, a single or multi-layer bed of polyurethane, and also, if applicable, an adhesion facilitator layer, arranged in between, a primary layer and also additional conventional layers, whereby the layer of polyurethane has a Shore D Hardness of less than 50, specifically less than approximately 48. Subject of the invention is also a method for the manufacture of the bonding foil as well as its utilization for lining the interiors of motor vehicles. Said bonding foil demonstrates excellent manipulation properties and presents outstanding physical/mechanical properties, such as excellent breaking elongation, grain stability, scratch resistance, high resistance to wear and tear, high UV-resistance, excellent solvent resistance as well as very high thermal aging resistance.

Abstract: A thermoplastic laminate film containing a thermoplastic substrate film and a layer formed from a resin composition containing a polyester graft copolymer (A) and a resin (B), the layer being formed on at least one side of the thermoplastic substrate film, the polyester graft copolymer (A) being obtained by grafting at least one polymerizable unsaturated monomer, which contains an acid anhydride having a double bond, to a hydrophobic polyester resin, and the resin (B) containing at least one member selected from the group consisting of a polyurethane resin, an acrylic resin and a vinyl resin. The adhesion improving layer of the inventive thermoplastic laminate film shows superior adhesion strength in a broad range of applications.

Abstract: A compounded and plasticized vinyl chloride polymer layer, optionally supported with a fabric, contains an outer adherent, stain resistant layer having durability and flexibility. The adherent, stain resistant layer is derived from a water-based polyester-amino resin composition. The stain resistant layer comprises the reaction product of said polyester, an acid catalyst, and an amino resin. The vinyl chloride layer may be printed or embossed or both printed and embossed, optionally printed again, before the outer layer is applied. A laminate formed from the polyvinyl chloride polymer layer and the stain resistant layer can also be embossed.