Abstract: A polymer sheet having a bifunctional surface modifying agent deposited on the surface of the sheet and a method of manufacturing a polymer sheet having a bifunctional surface modifying agent on the surface of the sheet. The polymer sheet preferably comprises polyvinyl butyral, a plasticizer incorporated into the polyvinyl butyral, and a bifunctional surface modifying agent disposed as a coating on the plasticized polyvinyl butyral, the bifunctional surface modifying agent comprising an anti-blocking segment and a compatibility segment, the anti-blocking segment comprising a hydrocarbon group comprising a linear hydrocarbon chain, a cyclic group, or a combination of linear hydrocarbon chains and cyclic groups, the compatibility segment comprising a sulfonate, sulfate, carboxylate, or phosphate radical.

Abstract: A polymer sheet having enhanced blocking resistance properties comprising a bifunctional surface modifying agent disposed at a surface of the plasticized polyvinyl butyral sheet. The bifunctional surface modifying agent comprises an anti-blocking segment comprising a polyethylene block or a hydrocarbon chain block and a compatibility segment comprising a poly(alkylene glycol) block. A method of manufacturing a polymer sheet having enhanced blocking resistance properties comprises melt processing a polymer into a sheet and disposing a bifunctional surface modifying agent at a surface of the polymer sheet, the bifunctional surface modifying agent comprising a polyethylene block or a hydrocarbon chain block and a poly(alkylene glycol) block.

Abstract: A curable composition comprising (A) constituents containing carbamate groups I: —O—C(O)—NHR??(I) in which R=a hydrogen atom or an alkyl, cycloalkyl or aryl group, (B) constituents containing carbamate-reactive groups, the equivalents ratio of carbamate-reactive groups in (B) to carbamate groups in (A) being >0.

Abstract: A dry-strippable coating composition can be incorporated into a composite article and comprises a dried water-borne polyurethane dispersion including a release additive comprising a releasing co-solvent or other selected release material. When water is removed from the polyurethane dispersion of the composite article and when the article comprises a thermoformable substrate, the article can be thermoformed to provide a shaped article. Dry-stripping the coating composition from the substrate provides a thermoformed substrate and a thermoformed protective layer. The dry-strippable coatings provide temporary protection for the surface of various products and components during manufacture, assembly, shipping, installation, painting, and refinishing operations.

Abstract: Mesoporous silica is shown to be a sample holder for laser desorption/ionization of mass spectrometry. Supported mesoporous silica was prepared by coating an ethanolic silicate solution having a removable surfactant onto a substrate to produce a self-assembled, ordered, nanocomposite silica thin film. The surfactant was chosen to provide a desired pore size between about 1 nanometer diameter and 50 nanometers diameter. Removal of the surfactant resulted in a mesoporous silica thin film on the substrate. Samples having a molecular weight below 1000, such as C60 and tryptophan, were adsorbed onto and into the mesoporous silica thin film sample holder and analyzed using laser desorption/ionization mass spectrometry.

Abstract: Polyurethane powder coating compositions containing uretdione groups and curing at low temperatures are provided, along with processes for preparing such compositions, and their use as powder coatings, wherein the compositions generally contain: A) a uretdione-containing powder coating hardener derived from aliphatic, (cyclo)aliphatic, cycloaliphatic or aromatic polyisocyanates and hydroxyl-containing compounds, and having a melting point from 40 to 130° C., a free NCO content of less than 5% by weight, and a uretdione content of 6-18% by weight; B) a hydroxyl-containing polymer having a melting point from 40 to 130° C., and an OH number between 20 and 200 mg KOH/gram, and C) a catalyst of the formula [NR1R2R3R4]+[R5]?, in which R1-R4 simultaneously, or independently of one another, are alkyl, aryl, aralkyl, heteroaryl or alkoxyalkyl radicals, and each R1-R4 is aromatic, linear or branched, unbridged or bridged with other radicals, R1-R4.

Abstract: A process is provided for producing a transparent pane structure for motor vehicles, especially a transparent cover for motor vehicle roofs, in which under an outside pane there is a multilayer electrochrome element for influencing the transparency of the pane structure. In the process, the inside of the outer pane is coated with a complete, functional electrochrome package. Furthermore, a transparent pane structure produced using this process is provided.

Abstract: A laminated safety glass windscreen, which can also be used as a reflector in a HUD system, comprises at least first and second panes and a thermoplastic intermediate layer which joins these panes together. The cross-section of the intermediate layer is in the shape of a wedge, decreasing in thickness from top to bottom. The thermoplastic intermediate layer may be composed of two sheets, one of which is provided with a colored filtering strip and has a wedged cross-section conditioned by the appearance of this filtering strip. The other sheet has a wedged cross-section such that the two sheets together have the prescribed convergence angle for using the windscreen as a reflector.

Abstract: A flexible laminate is disclosed which includes a flexible support as a first layer and glass having a thickness in the range from 10 ?m to 500 ?m as a second layer and wherein the first or the second layer is a non-continuous, segmented layer. In the embodiment of the figure, a plastic foil 1 is provided with a plurality of thin adjacent glass segments 2, which are separated by a space 3. The laminate can be provided with functional layers, e.g. using a web coating or printing process, and can then be cut easily in the space between the segments so as to obtain a plurality of glass laminates.

Abstract: A bonded vehicular glass assembly utilizes a urethane adhesive to attach a dynamic load-bearing attachment member to a glass substrate to form a joint suitable for use on a vehicle. Related methods of forming, and methods of attaching components to glass are disclosed.

Abstract: Coatings are provided in which biopolymers may be covalently linked to a substrate. Such biopolymers include those that impart thromboresistance and/or biocompatibility to the substrate, which may be a medical device. Coatings disclosed herein include those that permit coating of a medical device in a single layer, including coatings that permit applying the single layer without a primer. Suitable biopolymers include heparin complexes, and linkage may be provided by a silane having isocyanate functionality.

Abstract: The present invention provides an one-part moisture-curable urethane composition which exhibits excellent adhesion particularly to a coated steel plate difficult to bond with no-primer and is useful in the bonding of automobile window glass. The urethane composition of the present invention comprises an isocyanate-terminated urethane prepolymer as the main component, to which (A) a compound having solubility parameter value of 6.0 to 9.

Abstract: The subject of the invention is glazing which incorporates at least one electrically controllable system having variable optical and/or energy properties, especially in the form of a system comprising one or more reversible-insertion materials of the electrochromic-system type, in the form of an optical-valve or viologen-based system or in the form of a liquid-crystal or cholesteric-gel system. This glazing also includes at least one means for adjusting the optical appearance conferred on the said glazing by the said system, these means comprising at least one coating having antireflection properties in the visible.

Abstract: The invention relates to a glass-plastic composite film, especially for use in electronic components and devices, such as displays. The inventive film consists of a glass film which is between 10 &mgr;m and 500 &mgr;m thick, and is characterised in that a polymer layer with a thickness of between 1 &mgr;m and 200 &mgr;m f is applied directly to at least one of the side faces of said film and in that at least one side on the surface of the film has a waviness of less than 100 nm and a roughness RT<30 nm.

Abstract: The present invention provides NCO prepolymers comprising the reaction product of (1) an allophanate-modified diphenylmethane diisocyanate having an NCO group content of 12 to 32.5% by weight and comprising the reaction product of, (a) an aliphatic alcohol or an aromatic alcohol; and (b) diphenylmethane diisocyanate comprising: (i) from 10 to 60% by weight of 2,4′-diphenylmethane diisocyanate, (ii) less than 6% by weight of 2,2′-diphenylmethane diisocyanate, and (iii) the balance being 4,4′-diphenylmethane diisocyanate, wherein the sum of the percentages by weight of (1)(b)(i), (1)(b)(ii), and (1)(b)(iii) total 100% by weight of (1)(b), and (2) a polyether polyol having a molecular weight of 134 to 10,000, an OH number of 420 to 14, and a functionality of at least 1.8. The NCO prepolymers of the present invention find use in preparing elastomeric coatings, adhesives, sealants, and the like.

Abstract: To realize uniform heat distribution by adhering a radiating sheet tightly to a radiating element such as a PDP glass panel, and a heat sink such as an aluminum chassis, transfer heat smoothly to the heat sink such as the aluminum, and release foams entrapped between the radiating sheet and radiating element or heat sink efficiently. The radiating sheet is composed by impregnating a radiating material selected from the group consisting of a radiating gel and a radiating grease in a radiating base material having continuous foams, and layers excellent in heat releasing properties such as a silicone gel or an luminum foil may be formed further on the radiating sheet, or cuts may be made into these layers.

Abstract: The present invention describes the use of poly-o-hydroxy amides (PHAs) for adhesively bonding articles or materials, especially components used in the semiconductor industry, such as chips and wafers, a process for adhesively bonding materials, especially chips and/or wafers, chip and/or wafer stacks produced by the process, and adhesive compositions which comprise the poly-o-hydroxy amides of the formula (I).

Abstract: Disclosed is a toner composition for an inorganic black matrix used for a color filter that is an important part of TFT-LCD by dispersing the fine particles of an inorganic pigment such as carbon black powder in a block copolymer solution having a high molecular weight and containing a pigment affinity group, and a preparation method thereof. It is the recent trend of the worldwide market to use a toner composition prepared by the pigment dispersion method in the manufacture of the organic black matrix. Thus the present invention provides a toner composition necessary to the manufacture of an organic black matrix and its preparation method using the pigment dispersion method, which involves mixing a block copolymer solution having a high molecular weight and containing a specific pigment affinity group, a inorganic pigment having electrical properties such as conductivity and optical density, a solvent and a dispersion adjuvant and applying optimized dispersion-mixing and dispersion equipment.

Abstract: The invention relates to polyurethane-polyurea dispersions, also called PU dispersion, which contain aralkylamine-blocked isocyanate groups, and to their preparation and use. This blocking agent ahs a significantly lower deblocking temperature as compared with the prior art. Coatings produced from this dispersion have high hydrolysis resistances. The arylamine-blocked isocyanate groups are composed of polyisocyanates, polymeric polyols having average molar weights of 400 to 6000, at least one blocking agent, and either or both of nonionically hydrophilicizing compounds or compounds having at least one ionic or potentially ionic group.

Abstract: The fire-resistant glazing includes one or more glass pane, at least one of which consists of glass containing nucleating agents so that the glass pane is at least partially ceramicized when subjected to high thermal stress sufficient to cause ceramicizing, for example during a fire. The glass may be tempered and contains, in percent by weight based on oxide content SiO2, 55 to 69; Al2O3, 19 to 25 and Li2O, 3.2 to 5.0. This glass pane combines the advantages of the strength of tempered glass at low temperature with the stability and long-term resistance to thermal stress of glass-ceramic material at high temperature. The fire-resistant glazing can also include at least one other glass pane made of a conventional glass and at least one plastic layer of PVB film.

Abstract: The subject of the invention is glazing which incorporates at least one electrically controllable system having variable optical and/or energy properties, especially in the form of a system comprising one or more reversible-insertion materials of the electrochromic-system type, in the form of an optical-valve or viologen-based system or in the form of a liquid-crystal or cholesteric-gel system. This glazing also includes at least one means for adjusting the optical appearance conferred on the said glazing by the said system, these means comprising at least one coating having antireflection properties in the visible.

Abstract: Abrasion resistant pipes of this invention comprise a structural wall formed from a filament wound fiberglass-reinforced material, and an elastomeric abrasion resistant material disposed along the inside and/or outside surface of such pipe. In a preferred embodiment, the structural pipe wall is formed from a filament wound fiberglass-reinforced epoxy resin material, and the abrasion resistant material is formed from a polyurea elastomer. Abrasion resistant pipes of this invention are manufactured using existing filament winding processes by first coating a mandrel with the elastomeric abrasion resistant material, and than winding the resin impregnated filament therearound. Pipes prepared according to principles of this invention have improved properties of toughness, temperature resistance, chemical resistance, and abrasion resistance when compared to conventional fiberglass-reinforced pipes that either have no protective liner or have liners formed from other elastomeric materials.

Abstract: A laminated glass having a surface density of at most 12 kg/m2 and comprising a plurality of glass sheets laminated one on another with an interliner provided between the respective adjacent glass sheets, wherein the interliner has an ability to shield infrared rays and an ability to insulate sounds having a frequency of 5,000 Hz.

Abstract: A static resistant reticle comprises a substrate and a patterning layer and is covered by an antistatic conductive film of quaternary amine (R4N)+Cl−. A pellicle structure comprising an optically transparent membrane tightly stretched on a frame is also coated by an antistatic electro conductive film of a similar material. The reticle with the pellicle form a shielded structure isolating the reticle from ESD.

Abstract: The present invention relates to articles having a printed surface as well as flexible coating and film compositions that are printable in combination with exhibiting stain resistance. The composition comprises a hard component having an elongation of less than about 150%, a soft component having an elongation of greater than about 200%, and a cross-linking agent. The hard component preferably comprises a thermoplastic polyurethane, acrylic polymer, polymeric polyol or mixture thereof. The soft component preferably comprises a thermoplastic urethane, polymeric polyol, or mixture thereof; whereas the cross-linking agent is preferably an isocyanate.

Abstract: The present invention relates to a thermosetting resin composition with excellent electrical properties comprising (a) one or more terminally unsaturated urethane resins, (b) styrene, and (c) brominated styrene. The aforementioned composition finds great utility as a printed circuit board laminate suitable for use at microwave frequencies.

Abstract: This invention relates to chemical compositions comprising one or more urethane oligomers of at least two repeating units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers. These urethane oligomers comprise the reaction product of (a) one or, more polyfunctional isocyanate compounds; (b) one or more polyols; (c) one or more monoalcohols selected from the group consisting of fluorochemical monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof; (d) one or more silanes; and optionally (e) one or more water-solubilizing compounds comprising one or more water-solubilizing groups and at least one isocyanate-reactive hydrogen containing group. The chemical compositions of the present invention can be applied as coatings and these coatings can impart stain-release characteristics and resist being worn-off due to wear and abrasion.

Abstract: The present invention relates to a process for the preparation of an aqueous dispersion of an anionic polyurethane. According to the invention, a tertiary amine functional urethane polymer or oligomer acts as acid neutralizing agent. The process of the invention comprises the steps of: dispersion of an anionic isocyanate functional polyurethane prepolymer in water in the presence of a tertiary amine functional urethane polymer or oligomer and chain extension of the anionic polyurethane prepolymer with a reactive hydrogen functional material during or after the dispersion in water.

Abstract: The present invention relates to a thermosetting resin composition with excellent electrical properties comprising (a) one or more terminally unsaturated urethane resins, (b) styrene, and (c) brominated styrene. The aforementioned composition finds great utility as a printed circuit board laminate suitable for use at microwave frequencies.

Abstract: A composite interlayer suitable for using laminated glass includes a layer of plasticized polyvinyl butyral sandwiched between second and third polymeric layers. In a preferred embodiment, at least one and preferably both of the second and third layers are less than 5 mils thick and formed of polyurethane.

Abstract: A glazing assembly is provided made of at least one transparent substrate having a stack thereon that includes an alternation of n functional layers and n−1 coatings, wherein the functional layers have reflection properties in the infrared and/or solar radiation and where n≧1 and where, in order to maintain the quality of the stack when the substrate is subjected to a heat treatment step, at least one of the following must be satisfied: the coating placed on top of at least one of the functional layers includes at least one barrier layer providing a barrier to at least oxygen and water; and at least one absorbent or stabilizing layer made of a material capable of absorbing or stabilizing the consituent material of the functional layer forms a part of either the coating placed on top of the functional layer and under the barrier layer or the coating placed beneath the functional layer; and a method for production of the glazing assembly.

Abstract: The invention relates to a safety glass construction for safety motor vehicles whose body parts are lined with bullet-proof matting or other bullet-proof material in a direction toward the passenger area. The motor vehicle has an armored pane in which at least one pane (3.1) made of safety glass or one pane packet comprises of at least two bonded panes (3.1 and 3.2) also made of safety glass is connected to the outer pane (2). A strip (1) made of a bullet-proof material is arranged between the outer pane (2) and the pane packet (3) and/or between at least two panes (3.1, 3.2) of the pane packet (3) and/or on the pane of the packet (3) pointing toward the passenger area. Said strip overlaps the area up to the bullet-proof matting (5) or to the bullet-proof material of the connecting body parts (7).

Abstract: The present invention provides the following adhesive which is good in durability in bonding a glass plate and a resin composition containing a butyl type rubber. The present invention provides the following adhesive which is particularly suitable as an adhesive for bonding a glass plate and a resin composition containing a butyl type rubber, for a double glazing employing a spacer comprising a resin composition containing a butyl type rubber.

Abstract: A method for installing a vehicle window assembly in a vehicle includes selecting a vehicle interior accessory member from the group including a storage system, a lighting system, an instrument display system, an electrical power system, a temperature controlled air system, a system control panel, a window panel shade system, an interior trim component, a hand grip, and a sun visor assembly, forming the window assembly by securing the selected vehicle interior accessory to a predetermined area of the inner surface of a window panel, and installing the vehicle window assembly over or within a window opening of the vehicle after securing the interior accessory to the window panel such that the interior accessory is accessible to an occupant of the vehicle from the vehicle interior after installation.

Abstract: A fire-resistant laminated glass pane assembly comprises a glass-ceramic pane resistant to high temperatures and having rough light-diffusing surfaces, the said pane being joined, on each of its two faces, to a silicate glass pane by means of transparent intermediate layers having a refractive index corresponding to the refractive index of the glass and the glass-ceramic. Transparent intermediate plies consist of a thermoplastic polymer having a high splinter fixation effect, and the silicate glass panes consist of tempered float glass. Fire-retarding glasses of this type not only have a high fire-retarding effect, but also withstand the so-called extinguishing water test and, moreover, have safety glass properties with increased safety in respect of injuries caused by splinters.

Abstract: A laminated glass having a surface density of at most 12 kg/m2 and comprising a plurality of glass sheets laminated one on another with an interliner provided between the respective adjacent glass sheets, wherein the interliner has an ability to shield infrared rays and an ability to insulate sounds having a frequency of 5,000 Hz.

Abstract: The present invention relates to a substrate with at least one section having a surface decoration and a coating between the surface and the decoration. The coating can be peeled from the surface, and is prepared from an aqueous anionic polyurethane-polyurea dispersion which are free from co-solvents.

Abstract: The present invention provides a glass mat thermoplastic comprising a glass mat impregnated with an engineering thermoplastic polyurethane (ETPU) having a Tg of at least 50° C. The glass mat thermoplastic can be prepared, for example, by a) contacting a continuous glass mat with ETPU film or sheet, or between ETPU films or sheets, with sufficient pressure and heat to form a multilayered structure which contains a wetted out glass mat layer sandwiched between an ETPU layer and a glass mat layer, b) thermoforming or compression molding the multilayered structure with sufficient heat to substantially completely wet out the glass mat with the ETPU; and c) cooling the substantially wetted out thermoformed glass mat to a temperature below the Tg of the ETPU. The efficiency with which the depolymerizable and repolymerizable ETPU can be impregnated into the glass mat matrix results in a GMT with excellent physical properties.

Abstract: An optically active film composite including a polymeric film substrate coated with a layer of resin having a thickness of less than 6 microns and a pencil hardness of at least 2H, and which includes 30-60% by weight of nanoparticles of ATO or ITO, and nanoparticles of a second metallic compound being an inorganic compound and absorbing light having a wavelength in the range of 700-1100 nm. The composite preferably has a VLT of at least 50% and a % TSER of at least 35% with a weighted UV absorption of less than 1%.

Abstract: A retroreflective article 10 includes retroreflective elements 12 partially embedded in a binder layer 14 that comprises a polyurethane polymer. The polyurethane polymer is a reaction product of (i) a polyether polyol having a number average molecular weight of at least 2,000 and (ii) a polyisocyanate. A retroreflective article that employs a binder layer of this kind demonstrates extraordinary laundering durability under harsh wash conditions.

Abstract: The present invention is embodied in a polyurethane composition suitable for coating, casting or laminating, which incorporates a prescribed additive selected to increase the composition's electrical conductivity without adversely affecting the composition's transparency and percent haze and without adversely affecting its adhesion to an underlying substrate or its environmental durability, especially with regard to humidity resistance. The prescribed additive is an ionizable metal salt of a perfluoroalkylsulfonimide, in a weight percent of 0.5 to 5.0, with the metal being an alkali metal and the preferred perfluoroalkylsulfonimide being trifluoromethanesulfonimide. The most preferred salt is lithium trifluoromethanesulfonimide. The preferred polyurethane include both aliphatic polyetherurethanes and aliphatic polyesterurethanes.

Abstract: A glazing assembly is provided made of at least one transparent substrate having a stack thereon that includes an alternation of n functional layers and n−1 coatings, wherein the functional layers have reflection properties in the infrared and/or solar radiation and where n≧1 and where, in order to maintain the quality of the stack when the substrate is subjected to a heat treatment step, at least one of the following must be satisfied:

Abstract: In one embodiment the invention is An adhesive composition comprising a) a polymer having a flexible backbone and a reactive moiety capable of cross-linking, b) a particle comprising an active agent encapsulated in an encapsulating agent wherein the active agent comprises a catalyst for cross-linking of the reactive moiety, a curing agent for the reactive moiety, an accelerator for the curing reaction or a mixture thereof; and the encapsulating agent comprises a side chain crystallizable polymer wherein the active agent is not substantially extractable from the particle at ambient conditions in a first extraction after particle formation. This composition is used in binding two subtracters together.

Abstract: A primer for the metallization of substrate surfaces by chemical reduction, comprising a) from about 3 to about 40% by weight of a film or matrix former, b) from about 0.1 to about 15% by weight of an additive having a molecular mass of 500 to 20,000, c) from about 0.1to about 15% by weight of an ionic and/or colloidal metal or its organometallic covalent compound or complex compound with organic ligands, d) from about 0.5 to about 30% by weight of an organic and/or inorganic filler, e) from about 0.05 to about 5% by weight of a hydrophilic swelling material comprising finely divided particles containing silanol groups and/or partly modified silanol groups having a diameter of from 7 to 40 nm and a specific surface area of 50 to 380 m2/g, and f) from about 50 to about 90% by weight of organic solvents, in which all amounts by weight being based on the overall primer formulation, offers advantages at low bath loadings.

Abstract: A glazing assembly is provided made of at least one transparent substrate having a stack thereon that includes an alternation of n functional layers and n-1 coatings, wherein the functional layers have reflection properties in the infrared and/or solar radiation and where n≳1 and where, in order to maintain the quality of the stack when the substrate is subjected to a heat treatment step, at least one of the following must be satisfied: the coating placed on top of at least one of the functional layers includes at least one barrier layer providing a barrier to at least oxygen and water; and at least one absorbent or stabilizing layer made of a material capable of absorbing or stabilizing the consituent material of the functional layer forms a part of either the coating placed on top of the functional layer and under the barrier layer or the coating placed beneath the functional layer; and a method for production of the glazing assembly.

Abstract: The present invention relates to radiation-curable compositions that after cure provide reduced discoloration, or reduced color degradation, and/or high elongation while maintaining other desirable qualities of radiation-cured compositions. These radiation-curable compositions include at least one radiation-curable oligomer and at least one transesterified and/or high-purity monomer. These compositions can be formulated, for example, to serve as protective coatings for substrates manufactured from a wide variety of including glass, plastic, ceramic, metal and wood. The compositions of the present invention are preferably designed for use as an optical fiber coating (including inner primary and, colored or uncolored, outer primary coatings as well as other coatings which include inks, matrix materials and the like) or related optical fiber protective materials.

Abstract: Bonded vehicular glass assemblies utilizing two-component urethane adhesives to attach dynamic load-bearing attachment members to glass substrates to form a joint suitable for use on a vehicle, and related methods of forming are described herein. In addition, methods of attaching components to glass by use of these adhesives are disclosed. The two-component urethane adhesives utilized in this invention have been found to provide surprisingly strong bonds between glass and other materials which meet or exceed OEM requirements, and be particularly well suited for use in vehicles.

Abstract: A product and method of restoring a defaced or scratched window using a polyurethane film applied prior or subsequent to the damage to the window. The polyurethane fills in the scratches to the window and restores optical clarity. The polyurethane may be an aliphatic polyester polyurethane or aliphatic acrylic polyurethane. A further method is described which provides a protective coating to a window including a polyurethane film applied before the window is defaced. The film may be removed and reapplied easily to provide restored optical clarity.

Abstract: An intrusion resistant laminated glazing, suitable for automotive use, comprises an impact resistant ply of rigid thermoplastic polyurethane sensitive to ultra-violet radiation and, outside said ply, an ultra-violet absorbing or reflecting ply. The ultra-violet absorbing ply may be of thermoplastic polyurethane interlayer material which serves to bond the rigid thermoplastic polyurethane ply to outer glass plies. By using interlayer materials of low modulus to bond the rigid thermoplastic ply to outer glass plies, a product with good impact resistance and intrusion resistance is achieved.

Abstract: A two component type polyurethane adhesive is provided for fiberglass reinforced plastics which requires no cleaning, preparation or treatment of the surface, and the like. The curative component is a nitrogen-free liquid polyether or polyester in an amount such that in association with a urethane prepolymer component containing free NCO groups, the ratio of the free NCO groups in the prepolymer component to the OH groups in said curative component is at least 1.2 and desirably at least 1.35. Such high NCO/OH ratios have unexpectedly been found to provide good adhesion and especially good humidity adhesion and peel strength adhesion to fiberglass reinforced plastics or metal surfaces which are free from any surface treatment.