Including Polyene Monomers (e.g., Butadiene, Etc.) Patents (Class 428/462)
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Patent number: 5681643Abstract: Provided is a composition curable by active energy rays, comprising a cationic polyacryloyl compound having two or more acryloyl groups and one or more cation groups in a molecule, represented by any of General Formulae (1) to (6) ##STR1## wherein Z.sub.1 to Z.sub.6 represent independently a residue derived from a polyhydric alcohol or a polyepoxide,K.sub.1 represents independently a radical of the formula ##STR2## K.sub.2 represents a radical of the formula ##STR3## R.sub.1 presents independently a radical of the formula ##STR4## wherein R.sub.3 is independently H-- or CH.sub.3 --, andR.sub.2 represents independently a radical of the formulaCH.sub.2 .dbd.CHCOO--, or CH.sub.2 .dbd.C(CH.sub.3)COO--.Type: GrantFiled: October 12, 1995Date of Patent: October 28, 1997Assignee: Canon Kabushiki KaishaInventors: Hiromichi Noguchi, Makiko Kimura, Masato Katayama, Akio Kashiwazaki, Yoshie Nakata, Yuko Nishioka
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Patent number: 5681652Abstract: The present invention provides a prooess for forming by extrusion a profile of extrudable material having a hard skin surface on a portion of the profile and a decorative enhancement on another portion of the profile. The decorative enhancement is formed integrally with the profile by use of an embossment technique on the profile before the extrusion material sets and hardens. The profile may be used in applications such as picture frames as well as door, wall and window moldings.Type: GrantFiled: April 3, 1996Date of Patent: October 28, 1997Assignee: Marley Mouldings Inc.Inventor: Carroll W. Cope
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Patent number: 5674628Abstract: Disclosed is a water-based adhesive with enhanced effectiveness for bonding metal and rubber substrates for uses such as vibration damping devices. The adhesive is formulated from a latex which includes at least one conjugated diene and a macromonomer containing at least two ethylene oxide repeat units.Type: GrantFiled: May 15, 1996Date of Patent: October 7, 1997Assignee: GenCorp Inc.Inventors: I. Glen Hargis, John P. Kovalchin, Satish C. Sharma, Raymond J. Weinert, John A. Wilson
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Patent number: 5674613Abstract: Elastomeric polymers including ethylene, alpha-olefin and vinyl norbornene are shown to have improved extrusion characteristics, improved electrical properties, improved cure characteristics compared to ethylene, alpha-olefin, non-conjugated diene elastomeric polymers containing non-conjugated dienes other than vinyl norbornene. The elastomeric polymers containing vinyl norbornene generally have a branching index below 0.5.Type: GrantFiled: June 14, 1995Date of Patent: October 7, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Narayanaswami Raja Dharmarajan, Periagaram S. Ravishankar
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Patent number: 5656355Abstract: Disclosed is an elastic metallized film composed of an elastic film and a metallic coating substantially covering at least a portion of at least one side of the film. The elastic film may be formed from a thermoset elastic material, a thermoplastic elastic material or a naturally occurring polymeric elastic material. The film may also be microporous and/or micropertured. The elastic metallized film has a metallic coating with an thickness ranging from about 1 nanometer to about 5 microns and which remains on the film when the film is stretched at least about 25 percent. The elastic metallized film may be joined with other materials to form multi-layer materials. Also disclosed is a process of making an elastic metallized film.Type: GrantFiled: June 7, 1995Date of Patent: August 12, 1997Assignee: Kimberly-Clark CorporationInventor: Bernard Cohen
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Patent number: 5648135Abstract: An information recording medium has a recording layer which comprises a composition containing:I) at least one organic polymer selected from the group consisting of:(a) conjugated polymers whose conformations change by thermal energy, for example, polythiophene, and(b) polymers containing as a component a diene monomer and/or an aromatic-ring-containing vinyl monomer, for example, polystyrene; andII) a dye having light-absorbing ability, for example, naphthalocyanine. Despite the recording layer is of the organic type that features non-toxicity and low manufacturing cost as advantages, the recording layer makes it possible to produce a rewritable optical disc which can be recorded by a semiconductor laser (830,780 nm) employed widely.Type: GrantFiled: June 7, 1995Date of Patent: July 15, 1997Assignee: Hitachi Chemical Company, Ltd.Inventors: Itsuo Watanabe, Atsushi Kuwano, Jun Taketatsu, Nobuaki Takane, Mitsuo Yamada, Seiji Tai
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Patent number: 5635302Abstract: A sterically-hindered monomer is used to make a polymer which in turn is useful in coating compositions. The resulting residue of the sterically-hindered monomer is present in the polymer, as well as in a cured coating (preferably an automotive coating) produced using a coating composition having the polymer therein. The presence of the residue of the sterically-hindered monomer imparts in the cured coating a resistance to environmental etching.Type: GrantFiled: June 1, 1995Date of Patent: June 3, 1997Assignee: BASF CorporationInventors: Anna M. Budde, James A. Laugal, Walter H. Ohrbom, Marvin L. Green, Mark R. Montagne
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Patent number: 5624764Abstract: A composite material comprising a rubber composition and a metal material, wherein the rubber composition contains, per 100 parts by weight of rubber, a cobalt salt of an organic acid in an amount up to 0.5 parts by weight, 3 to 6 parts by weight of sulfur, and N-oxydiethylene-2-benzothiazolylsulfenamide or N-tert-butyl-2-benzothiazolylsulfenamide as a vulcanization accelerator, and the metal material is provided with a plating of a ternary alloy consisting of copper, zinc, and nickel.Type: GrantFiled: June 5, 1995Date of Patent: April 29, 1997Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kiyoshige Muraoka, Mamoru Uchida, Takafumi Taguchi
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Patent number: 5593752Abstract: A boron/carbon fiber laminate comprising a boron fiber layer and a carbon fiber layer having a balanced pair of carbon fiber plies embedded in a plastic resin matrix has a Coefficient of Thermal Expansion between .+-.0.54 .mu.m/m/.degree.C., a Coefficient of Moisture Expansion between .+-.20.0 .mu.m/m/%.DELTA.M, and a specific modulus greater than 1.64.times.10.sup.6 meter. The laminate is useful for optical mounting structures.Type: GrantFiled: November 28, 1995Date of Patent: January 14, 1997Assignee: Eastman Kodak CompanyInventors: David J. Pollatta, Thomas N. Quinzi
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Patent number: 5585187Abstract: The present invention relates to;a method for surface treating a polypropylene resin composition molded article, which comprises irradiating a molded article with ultraviolet light having an irradiation wavelength of 300 nm or less, said molded article being obtained from a polypropylene resin composition which comprises:(A) 15-92% by weight of a crystalline propylene-ethylene block copolymer resin,(B) 5-40% by weight of an ethylene-propylene copolymer rubber,(C) 1-15% by weight of a hydroxyl group-containing propylene oligomer, and(D) 2-30% by weight of an inorganic filler;a method for paint-coating a polypropylene resin composition molded article, which comprises irradiating a molded article with ultraviolet light having an irradiation wavelength of 300 nm or less and coating the irradiated surface with a paint, said molded article being obtained from a polypropylene resin composition which comprises said components (A), (B), (C) and (D) above-mentioned; anda paint-coated article obtained by said method forType: GrantFiled: May 12, 1995Date of Patent: December 17, 1996Assignee: Sumitomo Chemical Company, LimitedInventors: Hideo Shinonaga, Satoru Sogabe
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Patent number: 5569545Abstract: A copper clad laminate having a bonded side ensuring powerful adhesion between the copper foil and insulating layer, without providing protrusions on the copper foil or making roughing treatment or black treatment, by designing such a configuration that the copper foil has a metal layer on the side to be bonded with the insulating layer and the metal layer and insulating layer are cross-linked with each other by chemical bonds through sulfur atoms. Further, there is provided a multilayer printed circuit board which has a bonded side ensuring a powerful adhesion of the circuit copper foil and insulating layer, by designing such a configuration that the alternating metal layers and insulating layers are cross-linked with each other by chemical bonds through sulfur atoms.Type: GrantFiled: December 28, 1994Date of Patent: October 29, 1996Assignee: Nippon Denkai Ltd.Inventors: Hitoshi Yokono, Haruki Yokono, Masahiro Mikamo, Ryouichi Narushima, Takuya Iida, Yasuhiro Endo
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Patent number: 5567494Abstract: 05567494An inexpensive roll for electrostatic charge having the simple layer structure not affected by working environmental conditions, not developing exuding phenomena such as bleeding and blooming, generating no leaks and being able to conduct a uniform, stable electrostatic charge, which comprises a core member, and a conductive elastomer layer and a surface layer laminated thereon in this order, the surface layer having a conductive material dispersed therein, wherein the surface layer has a higher electrical resistance in an outermost surface region thereof and formed of a thermosetting binder resin containing carbon black dispersed therein by electrostatic deposition.Type: GrantFiled: July 5, 1994Date of Patent: October 22, 1996Assignee: Fuji Xerox Co., Ltd.Inventors: Kentaro Ageishi, Ryuji Watanabe, Tsutomu Sugimoto
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Patent number: 5556697Abstract: Vulcanizable semiconductive shield compositions contain a linear, single-site catalyzed polymer formed by polymerizing ethylene with at least one comonomer selected from C.sub.3 to C.sub.20 alpha-olefins; a carbon black selected from furnace carbon blacks that contain ash and sulfur in amounts of 50 ppm or less and have crystal dimensions L.sub.a and L.sub.c of 30 .ANG. or less, acetylene carbon blacks, and furnace carbon blacks having an ASTM grade of N-351; and a crosslinking agent. The compositions may be used to manufacture semiconductive shields for electrical conductors, such as power cables. The semiconductive shields exhibit improved processability, low water vapor transmission and low shrinkback, without abrading or corroding extrusion equipment.Type: GrantFiled: March 24, 1994Date of Patent: September 17, 1996Assignee: BICC Cables CorporationInventor: Cindy L. Flenniken
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Patent number: 5554688Abstract: A thermoplastic resin composition comprising (A) 100 parts by weight of a diene rubber-containing styrene resin, (B) from 1 to 50 parts by weight of a vinyl resin-containing acrylic rubber polymer obtained by polymerizing from 1 to 200 parts by weight of at least one vinyl monomer in the presence of 100 parts by weight of an acrylic rubber polymer, and (C) from 0 to 48 parts by weight of a polymer of a vinyl monomer having a weight average molecular weight of at least 200,000, provided that the sum of components (B) and (C) is from 1 to 60 parts by weight.Type: GrantFiled: August 3, 1995Date of Patent: September 10, 1996Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Hiroyuki Yashima, Katsuji Horio
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Patent number: 5547502Abstract: Uniquely dispersible precipitated silica particulates, e.g., beads, powders and granulates/extrudates, very well suited for the reinforcement of elastomer/rubber matrices, e.g., tires for the automotive industry, have characteristic particle sizes, BET and CTAB specific surface areas, DOP oil absorption values, total pore volumes and pore size distributions, and reduced degree of attrition.Type: GrantFiled: November 16, 1994Date of Patent: August 20, 1996Assignee: Rhone-Poulenc ChimieInventors: Yvonick Chevallier, Michel Rabeyrin
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Patent number: 5543224Abstract: A high molecular electret film which comprises an electret film of a blend of a poly(2,6-dialkyl-1,4-phenylene oxide) consisting of a recurring unit represented by the following general formula (1), ##STR1## wherein R is an alkyl group having not more than 4 carbon atoms, and a styrene resin. The electret film exhibits vary favorable electric charge-retaining property and favorable adhesiveness to metals. The film is very effectively used for a developing sleeve in an electrophotographic apparatus, for a cleaning device, for a transfer device, etc. and exhibits desired effects stably and for extended periods of time.Type: GrantFiled: April 10, 1995Date of Patent: August 6, 1996Assignee: Mita Industrial Co., Ltd.Inventors: Toshihisa Sakai, Masanori Kawasumi
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Patent number: 5518817Abstract: A resin laminate comprising layer of styrene-based polymer having mainly syndiotactic configuration and a thermoplastic resin layer, a metallized laminate comprising a layer of the styrene-based polymer described above and a metal layer, and process for producing these laminates are disclosed. In the laminate, the styrene-based polymer layer and the thermoplastic resin layer may be biaxially stretched.The laminates are expected to be utilized for electrostatic capacitors, hot stamping foils, flexible printed circuit board substrates, food wrapping films, and other functional films including magnetic tapes, and ornament films.Type: GrantFiled: July 11, 1994Date of Patent: May 21, 1996Assignee: Idemitsu Kosan Co, Ltd.Inventors: Komei Yamasaki, Keisuke Funaki
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Patent number: 5508103Abstract: The present invention provides a process for forming by extrusion a profile of extrudable material having a hard skin surface on a portion of the profile and a decorative enhancement on another portion of the profile. The decorative enhancement is formed integrally with the profile by use of an embossment technique on the profile before the extrusion material sets and hardens. The profile may be used in applications such as picture frames as well as door, wall and window moldings.Type: GrantFiled: January 30, 1995Date of Patent: April 16, 1996Assignee: Marley Mouldings Inc.Inventor: Carroll W. Cope
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Patent number: 5503939Abstract: The invention relates to a process for the production of two-coat finishes, in which a pigmented aqueous basecoat is applied, the basecoat obtained is coated over with a clearcoat, and basecoat and clearcoat are baked together. The process according to the invention is distinguished in that the aqueous basecoat contains an emulsion polymer which has been prepared in the presence of a reaction product (A), the reaction product (A) being obtained by reacting(i) a butadiene homo- or copolymer,(ii) at least one fatty acid of a drying oil or at least one drying oil or a mixture of at least one fatty acid of a drying oil and at least one drying oil, and(iii) maleic anhydridein a mass ratio of (i):(ii):(iii)=1.0:0.1 to 0.6:0.1 to 0.6 and, after adding a basic aqueous solution, converting the reaction product to an aqueous dispersion.Type: GrantFiled: December 9, 1994Date of Patent: April 2, 1996Assignee: BASF Lacke + Farben, AGInventors: Heinz P. Rink, Susanne Piontek, Bernhard Lettmann, Stefan Wieditz, Birgit Peitz, Achim Gast
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Patent number: 5491031Abstract: A coating composition for application to primed metal substrates as a topcoat is disclosed. The coating composition is especially useful on metal closures for vacuum-packed food products. The coating composition is free of a halide-containing vinyl polymer and comprises: (a) an epoxy novolac resin, (b) a phenolic resin, (c) a polyester, and (d) an elastomer, in (e) a nonaqueous carrier.Type: GrantFiled: November 14, 1994Date of Patent: February 13, 1996Assignee: The Dexter CorporationInventor: Lawrence P. Seibel
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Patent number: 5478654Abstract: An adhesive composition using as the primary binder an emulsion of butadiene-vinylidene chloride copolymer is disclosed. The composition is particularly suited for binding rubber to metal in a variety of uses such as vibration damping devices. The adhesive composition has resistance to hot water and or water glycol solutions.Type: GrantFiled: May 6, 1994Date of Patent: December 26, 1995Assignee: GenCorp Inc.Inventors: I. Glen Hargis, Richard A. Miranda, John A. Wilson
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Patent number: 5470657Abstract: Disclosed is a heat-resistant, high-voltage insulated lead wire for direct current, which meets the demand for higher heat resistance, and its insulating coating over the conductor is formed by a polyolefin resin composition. The polyolefin resin composition is a flame-retarded resin composition comprising of a mixture of a polyethylene whose crystalline component has melting point higher than 125.degree. C. and a copolymer of ethylene and .alpha.-olefin, which contains a multifunctionalized monomer having unsaturated carbon-carbon bond moiety in the molecule as an indispensable component. The insulating coating made of this resin composition is irradiated by an ionizing radiation to give a heat-resistant, high-voltage lead wire for direct current, which has a perpendicular flame resistance (VW-1) acceptable in the UL Standards and has a temperature rating of higher than 125.degree. C.Type: GrantFiled: July 28, 1994Date of Patent: November 28, 1995Assignee: Sumitomo Electric Industries, Ltd.Inventor: Hiroshi Hayami
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Patent number: 5464690Abstract: A holographic article and method for forming permits the party producing the final document to print the holographic image directly on the final document thereby permitting such party to retain and maintain control of its own embossing shim on which the hologram has been formed and which is utilized for embossing the holographic image on the document. A film upon which a holographic image can be directly stamped upon the final document includes a layer of metal having a thickness in the range of 20 millimicrons to 100 millimicrons, a lacquer coating having a thickness in the range of 0.5 microns to 3 microns and a heat activatible adhesive. The metal layer lacquer coating and heat activatible adhesive are caused to be adhered to the substrate forming the final document during a stamping operation which releases said metal layer, lacquer coating and heat activatible adhesive from a plastic carrier film to which had initially been applied.Type: GrantFiled: April 4, 1994Date of Patent: November 7, 1995Assignee: NovaVision, Inc.Inventor: David R. Boswell
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Patent number: 5464673Abstract: An information recording medium has a recording layer which comprises a composition containing:I) at least one organic polymer selected from the group consisting of:(a) conjugated polymers whose conformations change by thermal energy, for example, polythiophene, and(b) polymers containing as a component a diene monomer and/or an aromatic-ring-containing vinyl monomer, for example, polystyrene; andII) a dye having light-absorbing ability, for example, naphthalocyanine. Despite the recording layer is of the organic type that features non-toxicity and low manufacturing cost as advantages, the recording layer makes it possible to produce a rewritable optical disc which can be recorded by a semiconductor laser (830, 780 nm) employed widely.Type: GrantFiled: August 5, 1992Date of Patent: November 7, 1995Assignee: Hitachi Chemical Co., Ltd.Inventors: Itsuo Watanabe, Atsushi Kuwano, Jun Taketatsu, Nobuaki Takane, Mitsuo Yamada, Seiji Tai
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Patent number: 5437932Abstract: Novel photosensitive compositions based on azlactone derived polymers are described. The polymers have a hydroearbyl backbone and pendant peptide groups with free-radically polymerizable functionality attached thereto, said polymer further comprising at least one oxyacid group or salt thereof, and optionally quaternary ammonium salt groups. A high speed durable printing plate having a mild pH aqueous developability is disclosed which incorporates these polymers in combination with a photoinitiator. The polymers are also useful as proofing films in graphic arts applications.Type: GrantFiled: May 13, 1994Date of Patent: August 1, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: M. Zaki Ali, Mahfuza B. Ali, Dean M. Moren
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Patent number: 5407471Abstract: Corrosion inhibitor compositions with improved activity are prepared from a neutral or overbased salt of an organic acid and another metal-containing corrosion inhibitor.Type: GrantFiled: June 21, 1994Date of Patent: April 18, 1995Assignee: The Lubrizol CorporationInventors: Eric L. Rohr, Leonard S. Cech, Barry M. Saltzman
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Patent number: 5405894Abstract: A corrosion protection composition comprising a thermoplastic elastomeric block copolymer, a colloidal size amorphous overbased sulphonate of an alkaline earth metal, a tackifier resin and optionally a plasticizer for the block copolymer.Type: GrantFiled: June 17, 1993Date of Patent: April 11, 1995Assignee: Exxon Chemical Patents Inc.Inventor: Robert D. M. Best
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Patent number: 5405677Abstract: A highly fluorinated benzene compound is reacted with acryloyl chloride to ield a fluorinated liquid product which is used to impregnate a reinforcing structure. Upon impregnation, the liquid material is polymerized at about 55.degree. C. to produce a reinforced polymeric structure, which can be a circuit board. The polymer has dielectric constant of about 2.1, which is very low compared to the polymers used presently.Type: GrantFiled: September 30, 1993Date of Patent: April 11, 1995Assignee: The United States of America as represented by the Secretary of the NavyInventors: James R. Griffith, Henry S. W. Hu
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Patent number: 5376424Abstract: A thermal insulating material is packed in a sealing bag composed of an obverse face material and a reverse face material, wherein each of the obverse face material and reverse face material is preferably made of a metal foil having a thickness in the range of 3 to 50 micrometers and which is sandwiched by a sealant layer of plastic film adhesively affixed to one side thereof and by a surface layer of plastic film adhesively affixed to the other side thereof (hereinafter termed a metal foil composite plastic film), and then a similarly constructed metal foil composite plastic film, or preferably one having a number of holes therein, is stuck on the outer surface or inner surface of the obverse face material, to thus obtain a vacuum thermal insulating panel. The vacuum thermal insulating panel thus obtained can prevent permeation of gas from the outside, reflect heat, and prevent heat conduction along the outer surface.Type: GrantFiled: October 1, 1992Date of Patent: December 27, 1994Assignee: Fujimori Kogyo Co., Ltd.Inventor: Hiroshi Watanabe
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Patent number: 5376448Abstract: Disclosed herein is a rubber covered roll comprising a metallic core and at least one covering rubber layer. The covering rubber layer is a vulcanized rubber layer formed by a rubber composition comprising an ethylenically unsaturated nitrile-conjugated diene type highly saturated copolymer rubber (A) having a conjugated diene unit content of the polymer chain of at most 25 wt. % and the zinc salt (B) of an ethylenically unsaturated carboxylic acid. A covering rubber layer coming into contact with the metallic core is at least a vulcanized rubber layer formed by a rubber composition comprising 100 parts by weight of a rubber component containing at least 50 wt. % of the highly saturated copolymer rubber (A) and 10-40 parts by weight of the zinc salt (B). A rubber composition for rubber covered rolls is also disclosed. It comprises 100 parts by weight of a rubber component containing 90-50 wt. % of the highly saturated copolymer rubber (A) and 50-10 wt.Type: GrantFiled: April 30, 1993Date of Patent: December 27, 1994Assignee: Nippon Zeon Co., Ltd.Inventors: Shigeru Suzuki, Motofumi Oyama
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Patent number: 5358764Abstract: Disclosed is a decorative trim assembly comprising an integrally molded T-shaped decorative trim comprised of a hard plastic leg portion with a top portion. A soft plastic tip portion is bound to the top of the leg, and a decorative metallic portion is molded to the top of the leg portion, and at the edge of the leg portion, a locking flange member. A multi-channel member having a first channel for insertion of glass and a second channel for insertion of the plastic stem portion therein in locking engagement is also disclosed.Type: GrantFiled: October 13, 1993Date of Patent: October 25, 1994Assignee: Color Custom, Inc.Inventors: Edward A. Roberts, Raymond C. Brautigam
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Patent number: 5354619Abstract: The invention provides pressure-sensitive adhesive (PSA) compositions comprising a graft copolymer of one or more of ethylene and C.sub.3 -C.sub.18 .alpha.-olefins and one or more of a new class of macromonomers. The adhesive composition comprises a blend of the graft copolymer with a tackifying resin. Sheet materials can be coated with layers of the adhesive composition to provide tapes and laminates.Type: GrantFiled: December 21, 1993Date of Patent: October 11, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventor: Gaddam N. Babu
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Patent number: 5342860Abstract: This invention relates to alk-1-enyl ether-polyester block prepolymers which are curable by cationically initiated radiation and which are defined by the formula ##STR1## wherein m has a value of from 1 to 25;A is C.sub.2 to C.sub.12 alkylene, C.sub.6 to C.sub.14 aryl, both groups optionally substituted with lower alkyl, halo lower alkyl, alkyleneoxy, halogen or aryl;R.sub.1 is alkylene containing from 1 to 6 carbon atoms;R.sub.2 is a saturated or unsaturated divalent radical containing from 1 to 14 carbon atoms and is selected from the group of alkylene, alkenylene and arylene, each group optionally substituted with oxygen, halogen, lower alkyl and/or hydroxy;R.sub.3 is hydrogen or C.sub.1 to C.sub.6 alkyl;R.sub.4 is C.sub.1 to C.sub.6 alkylene, C.sub.6 to C.sub.14 arylene, lower alkyl substituted phenylene or xylylene andR.sub.5 and R.sub.6 are independently hydrogen or C.sub.1 to C.sub.4 alkyl.Type: GrantFiled: August 18, 1993Date of Patent: August 30, 1994Assignee: ISP Investments Inc.Inventors: Jeffrey S. Plotkin, Mark M. Miller
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Patent number: 5338347Abstract: Corrosion inhibitor compositions with improved activity are prepared from a neutral or overbased salt of an organic acid and another metal-containing corrosion inhibitor.Type: GrantFiled: September 11, 1992Date of Patent: August 16, 1994Assignee: The Lubrizol CorporationInventors: Eric L. Rohr, Leonard S. Cech, Barry M. Saltzman
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Patent number: 5334450Abstract: A weatherable film for lamination to a non-weatherable substrate, including, for example a three-layer film structure including:at least one first surface layer of a weatherable polymer comprising (a) AES, ASA, SAN or mixtures thereof or (b) any of the polymers of (a) blended with PVC, CPE, aliphatic polyurethanes or saturated styrenic block copolymers; said layer having a 1 percent secant modulus of greater than about 150,000 psi;at least one second intermediate layer being a tie layer underlying the weatherable layer, said intermediate tie layer being adjacent to and adhered to the weatherable layer, said intermediate tie layer having a modulus of less than about 150,000 psi; said tie layer adherable to at least a third underlying layer; andat least one third layer underlying the tie layer, said third layer adjacent to and adhered to the tie layer said third layer having a modulus of less than about 150,000 psi.Type: GrantFiled: May 20, 1992Date of Patent: August 2, 1994Assignee: The Dow Chemical CompanyInventors: Vincent S. Zabrocki, Robert H. Kelch
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Patent number: 5330812Abstract: A composite material comprising a base liner with a release layer on at least one surface thereof, and a releasable face layer releasably adhered to the base liner through the release layer by a pressure sensitive adhesive, wherein the base liner has a skin layer on its surface proximate to the release layer which is more difficult to cut than the remainder of the base liner material, such that when the composite is subjected to die cutting or perforating to allow portions of the face layer to be selectively removed, the cutter will not penetrate into or through the base liner to any substantial extent.Type: GrantFiled: April 13, 1992Date of Patent: July 19, 1994Assignee: Mobil Oil Corp.Inventors: Anthony R. Knoerzer, Pang-Chia Lu, Conway F. Shields, Donald G. Whyman
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Patent number: 5318839Abstract: There is disclosed a laminate comprising (a) a layer of a styrenic polymer having a higher degree of syndiotactic configuration and a crystallinity of at least 25%, preferably 35%, (b) a layer of paper and optionally (c) an adhesive layer and (d) a barrier layer. The above laminate is excellent in heat resistance, hydrolytic resistance, tearability, dead foldability and gloss and can find a wide range of effective application.Type: GrantFiled: February 6, 1992Date of Patent: June 7, 1994Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Yosuke Arai, Yuichi Oki, Eiji Maemura, Keisuke Funaki
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Patent number: 5316835Abstract: A multi-layer insulation product which achieves low emissivity values by using at least one layer of metallic foil. The metallic foil (25, 29) is used at exterior locations of the insulation product by way of novel strengthening means positioned below said metallic foil. A central layer of foamed material (21) adds to the insulative effect. The strengthening features of the invention allow use of the insulation product on exterior locations which has not heretofore been possible in the art.Type: GrantFiled: November 16, 1992Date of Patent: May 31, 1994Inventors: Cory L. Groft, Thomas W. Dauber
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Patent number: 5306566Abstract: The method of inhibiting the reduction of the bond strength by water of a metal-thermoplastic polymer-metal sandwich, where the thermoplastic core contains carbon to carbon double bonds, by incorporating 0.01 to 1.0% of a fatty acid component which comprises at least one fatty acid as an additive.Type: GrantFiled: October 8, 1992Date of Patent: April 26, 1994Assignee: Hoogovens Groep B.V.Inventor: Jan Bottema
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Patent number: 5302460Abstract: A support material for photosensitive substances, useful in the production of offset-printing plates, is disclosed. The support material comprises mechanically, chemically or electrochemically roughened aluminum or an aluminum alloy in the form of a sheet, a foil or a web, and which is coated on at least one side with a hydrophilic polymer which comprises (a) at least 2 mol% of units having acidic side groups and (b) at least 2 mol% of units having basic side groups which are capable of being protonated.Type: GrantFiled: July 17, 1991Date of Patent: April 12, 1994Assignee: Hoechst AktiengesellschaftInventors: Engelbert Pliefke, Raimund J. Faust
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Patent number: 5300355Abstract: In order to provide a damping material exhibiting an excellent vibration damping property in a wide temperature range, according to the present invention, in a magnetic composite type damping material constructed by bonding an adhesive elastic sheet containing magnetic powder to a constraining plate such as a metal plate by using an adhesive, the adhesive elastic sheet is made of a composite material consisting of rubber elastomer, adhesive resin, plasticizer, magnetic powder, etc.Since not only is the damping material having a construction described above attracted by magnetic force against a vibration source, it also is provided with a superficial adhesiveness, and the excellent vibration damping property is exhibited in a wide temperature range by a synergistic effect of the magnetic force and the adhering force.Type: GrantFiled: May 20, 1992Date of Patent: April 5, 1994Assignees: Nichias Corporation, Railway Technical Research InstituteInventors: Naoto Mifune, Yasutaka Nagai, Masaaki Ashizawa, Kazuo Nishimoto, Takahiro Niwa, Shuji Ito, Masanori Hansaka
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Patent number: 5286574Abstract: A composite gasket material includes a fiber component (3-15% by wt.), an elastomeric binder component (3-15% by wt.), and a solid filer component (60-90% by wt.). The material may additionally include a phenolic or epoxy resin (up to 5 wt. %) and a silicone resin (up to 5 wt. %). The filler includes as a component a salt formed from a multivalent metal cation and a sterically hindered dicarboxylic acid. The salt ingredient typically comprises from about 20 to 80 wt. % of the filler. Gaskets made from this composite material exhibit improved sealability and thermal stability while retaining other desirable mechanical properties. These materials are able to withstand operating temperatures up to about 450.degree. C.Type: GrantFiled: June 11, 1993Date of Patent: February 15, 1994Assignee: Hollingsworth & Vose CompanyInventor: Richard P. Foster
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Patent number: 5284713Abstract: A composite material comprising a rubber composition and a metal material, wherein the rubber composition contains, per 100 parts by weight of rubber, 0 part by weight of a metal salt of an organic acid, 3 to 6 parts by weight of sulfur, and N-oxy-diethylene-2-benzothiazolylsulfenamide or N-tert-butyl-2-benzothiazolylsulfenamide as a vulcanization accelerator, and the metal material is provided with a plating of a ternary alloy consisting of copper, zinc, and nickel.Type: GrantFiled: May 18, 1992Date of Patent: February 8, 1994Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kiyoshige Muraoka, Mamoru Uchida, Takafumi Taguchi
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Patent number: 5279900Abstract: A bonded structure 1 including an aluminum alloy plate 3 and a rubber 7 of vibration proof rubber adhering to each other with an adhesive wherein the aluminum alloy plate 3 includes aluminum alloy containing no more than 12% by weight of silicon and no more than 2.2% by weight of copper and the application of such aluminum alloy to the bonded structure 1 decreases the total weight of the structure 1 and improves both corrosion resistance and adhesiveness under corrosive conditions wherein the bonded structure is favorably applied to damper pulleys and shock-absorbing body mounts of vehicles.Type: GrantFiled: September 27, 1991Date of Patent: January 18, 1994Assignee: Toyoda Gosei Co., Ltd.Inventors: Katsumasa Takeuchi, Hiroshi Yokoi, Hideyuki Imai
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Patent number: 5276093Abstract: Disclosed is a resin molding comprising a molding composed of a resin composition comprising 100 parts by weight of a substrate resin comprising 100 to 30% by weight of at least one propylene polymer selected from the group consisting of propylene/ethylene block copolymers having an ethylene content of 3 to 45% by weight and propylene/ethylene random copolymers having an ethylene content of 0.5 to 10% by weight and 0 to 70% by weight of an elastomer, and at least one member selected from the group consisting of (A) 0.01 to 10 parts by weight of a 1,3-diene polymer having at least one terminal hydroxyl group or a hydrogenation product thereof, (B) 0.01 to 40 parts by weight of a copolymer of ethylene with an unsaturated compound containing a carboxyl group (including an acid anhydride group) and (C) 0.Type: GrantFiled: January 31, 1992Date of Patent: January 4, 1994Assignee: Mitsubishi Petrochemical Company LimitedInventors: Sadao Kitagawa, Yuta Kumano
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Patent number: 5268209Abstract: The invention herein pertains to methods and materials for producing a nicotine maintenance pouch. Laminates comprising a nicotine barrier layer and a nicotine degradation agent barrier layer are disclosed. In a preferred embodiment, the nicotine barrier layer comprises a nitrile rubber modified acrylonitrilemethyl acrylate copolymer. An especially preferred nicotine barrier material comprises, by weight percent, 75% acrylonitrile, and 25% methyl acrylate with 10% butadiene (AN-MA/B). The nicotine degradation agent barrier layer is preferably aluminum foil. In an especially preferred embodiment, the laminate comprises a layer of AN-MA/B adhered to a layer of aluminum foil, which in turn is adhered to a layer of paper stock.Pouches comprising a self-sealed nicotine barrier layer and a nicotine degradation agent barrier layer are disclosed. These pouches are preferably formed from the laminates above.Type: GrantFiled: October 21, 1991Date of Patent: December 7, 1993Assignee: Alza CorporationInventors: James A. Hunt, James L. Osborne, John T. Dunn, Melinda K. Nelson, Nathan Roth
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Patent number: 5262484Abstract: Graft copolymers and processes for the preparation thereof are provided. The copolymers comprise a base polymer having grafted thereto a monomeric 2-alkenyl azlactone. The surface properties of the graft copolymers can be modified by binding thereto nucleophilic reagents comprising further functional groups with desired properties. Further, the amount of azlactone available at the surface of a graft copolymer for binding to such nucleophilic reagents can be controlled by selecting a surface against which the graft copolymer is formed. The graft copolymers exhibit desirable thermoplastic, melt flow, and adhesion properties and are particularly useful for immobilizing proteins. Methods of immunoassay based on the immobilization of proteins are also disclosed. Another utility of the graft copolymers involves the compatibilizing of immiscible polymer blends.Type: GrantFiled: September 9, 1992Date of Patent: November 16, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Patrick L. Coleman, Thomas A. Kotnour, Richard J. Rolando
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Patent number: 5259908Abstract: Heat-vulcanizable adhesives for the bonding of solids, the adhesive contains polybutadiene or a polybutadiene mixture and/or copolymers of butadiene with ethylenically unsaturated monomers and other vulcanizable components, and at least 0.5% by weight (based on the weight of vulcanizable components) of a metal salt as a hardening catalyst. The adhesive is particularly useful in vehicle assembly. The adhesive in less than 5 hours exposure to air forms a protective skin which imparts washer resistance to the adhesive.Type: GrantFiled: July 18, 1990Date of Patent: November 9, 1993Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Hans J. Buecken, Julius Herold, Peter Hofmann
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Patent number: 5258460Abstract: Polymeric reaction products useful as additions to electrocoating baths are obtainable fromA. a polyoxyalkylene which has an average molecular weight M.sub.n of from 140 to 10,000 and contains on average from 1.5 to 3.0 primary and/or secondary amino groups andB. a polymer which is based on a conjugated diene, has an average molecular weight M.sub.n of from 250 to 50,000, contains on average from 1.5 to 3.0 epoxy groups per molecule and is obtainable by reacting a hydroxyl- or carboxyl-containing polymer with a glycidyl compound.Type: GrantFiled: March 25, 1992Date of Patent: November 2, 1993Assignee: BASF Lacke+ Farben AktiengesellschaftInventors: Dieter Faul, Gerhard Hoffmann, Klaus Huemke, Ulrich Heimann, John A. Gilbert
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Patent number: H1482Abstract: A permanent, flexible coating for protecting and lubricating metal that is formed into articles by single step or multiple step bending or stamping deformation is disclosed. The coating comprises a block copolymer which is formed from selective hydrogenation of an (A-B).sub.n -A or (A-B).sub.n block copolymer. Monomers containing functional groups, preferably monocarboxylic or polycarboxylic acid compounds or their derivatives, are grafted onto the selectively hydrogenated block copolymer in an amount sufficient to improve adhesion of the polymer to the metal. The functionalized block copolymer can be crosslinked to improve resistance of the coating to organic solvents.Type: GrantFiled: September 7, 1993Date of Patent: September 5, 1995Assignee: Shell Oil CompanyInventors: David J. St. Clair, James R. Erickson, Michael J. Watkins