Refractory Metal Salt Or Oxide Patents (Class 428/472)
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Patent number: 8475930Abstract: A composite coated metal sheet comprising a coated film having a low environmental impact prepared free from hexavalent chromium, and having good corrosion resistance equivalent to that provided by chromate treatment and excellent adhesiveness between the coated film and a resin layer formed on the coated film. Also, a treatment agent and a method of manufacturing the composite coated metal sheet with the treatment agent is described. The composite coated metal sheet comprises a coated film formed on a surface of a plated metal sheet or metal sheet, the coated film contains an oxide and/or a hydroxide of metal other than chromium, and an organic component comprising modified and/or unmodified functional group(s).Type: GrantFiled: December 5, 2006Date of Patent: July 2, 2013Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiromasa Shoji, Hiroshi Kajiro
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Publication number: 20130164511Abstract: A thermochromic substrate that has a thermochromic thin film, and a method of manufacturing the same. The thermochromic substrate includes a base substrate, an oxide or nitride thin film formed on the base substrate, a vanadium dioxide (VO2) thin film formed on the oxide or nitride thin film, and a photochromic thin film formed on the VO2 thin film.Type: ApplicationFiled: December 21, 2012Publication date: June 27, 2013Applicant: Samsung Corning Precision Materials Co., Ltd.Inventor: Samsung Corning Precision Materials Co., Ltd.
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Patent number: 8470458Abstract: A workpiece, such as a turbine engine component, comprises a substrate, a thermal barrier coating on the substrate, and a hard erosion barrier deposited over the thermal barrier coating. The erosion barrier preferably has a Vickers hardness in the range of from 1300 to 2750 kg/mm2. The erosion barrier may be formed from aluminum oxide, silicon carbide, silicon nitride, or molybdenum disilicide. The erosion barrier may be formed using either an electrophoretic deposition process or a slurry process.Type: GrantFiled: December 9, 2010Date of Patent: June 25, 2013Assignee: United Technologies CorporationInventors: Joshua Persky, David A Litton, David A Lambert
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Patent number: 8470460Abstract: A multilayer thermal barrier coating (TBC) may include a plurality of layers selected to provide properties to the multilayer TBC. For example, a multilayer TBC may include a first layer deposited over a substrate, a second layer deposited over the first layer and a third layer deposited over the second layer. The first layer may be selected to provide thermal cycling resistance, the second layer may be selected to provide low thermal conductivity and the third layer may be selected to provide at least one of erosion resistance and CMAS degradation resistance. The multilayer TBC may also include two layers, or more than three layers.Type: GrantFiled: November 24, 2009Date of Patent: June 25, 2013Assignee: Rolls-Royce CorporationInventor: Kang N. Lee
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Publication number: 20130155822Abstract: A method of manufacturing a decorative article, including a first coating formation step of forming a first coating of primarily TiN on a substrate; a second coating formation step of forming a second coating on the first coating by means of a dry plating method using a target containing 70.0 wt %?85.0 wt % Au and 15.0 wt %?30.0 wt % Cu; a heat treatment step of promoting formation of a solid solution of the constituents of the second coating by applying a heating process that heats the substrate on which the first coating and the second coating are disposed to 300° C.?395° C. and then applying a cooling process; and an acid treatment step that, of the constituents of the second coating to which the heating process was applied, removes the constituents not forming a solid solution by applying an acid treatment.Type: ApplicationFiled: November 27, 2012Publication date: June 20, 2013Applicant: SEIKO EPSON CORPORATIONInventor: SEIKO EPSON CORPORATION
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Patent number: 8460796Abstract: A composite body that is spall resistant and comprises a substantially discontinuous cermet phase in a substantially continuous metal rich matrix phase. The composite body is typically bonded to a substrate to form a hardfacing on the substrate. The composite body exhibits ductile phase toughening with a strain to failure of at least about 2 percent, a modulus of elasticity of less than about 46 million pounds per square inch, and a density of less than about 7 grams per cubic centimeter. The metal rich matrix phase between the ceramic rich regions in the composite body has an average minimum span of about 0.5 to 8 microns to allow ductility in the composite body. The composite body has a Vicker's hardness number of greater than approximately 650. The discontinuous cermet phase is in the form of ceramic rich regions embedded within the composite body, and it includes ceramic particles and a cermet binder. The ceramic particles having a Moh's hardness of at least approximately 7.Type: GrantFiled: February 3, 2010Date of Patent: June 11, 2013Assignee: Mesocoat, Inc.Inventor: Andrew J. Sherman
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Patent number: 8455116Abstract: The present invention relates to PVD coated cemented carbide cutting tool inserts semifinishing and finishing metal cutting operations. The cemented carbide cutting tool insert comprises a substrate and a wear resistant coating. The substrate comprises in addition to WC, from about 5.5 to about 8.5 wt-% Co and Cr such that the Cr/Co weight ratio is from about 0.08 to about 0.12 and also small amounts of Ti and Ta. The wear resistant coating is a homogeneous AlxTi1?xN-layer with x equals from about 0.6 to about 0.67. The thickness of this layer is from about 1 to about 3.8 ?m.Type: GrantFiled: May 29, 2008Date of Patent: June 4, 2013Assignee: Sandvik Intellectual Property ABInventors: Pierre Donnadieu, Susanne Norgren
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Patent number: 8449994Abstract: A thermal barrier coating is formed over the substrate. A majority of the thermal barrier coating comprises a multi-phase material comprising a polycrystalline material including two or more phases. Each phase forms an individual grain, adjacent individual grains are separated by grain boundaries, each phase comprises an oxide compound, the multi-phase material is formed from three or more constituents, the three or more constituents consist of different materials that are not completely soluble in each other, and the two or more phases are not completely soluble in each other and do not form only one compound.Type: GrantFiled: June 30, 2009Date of Patent: May 28, 2013Assignee: Honeywell International Inc.Inventor: Vladimir K. Tolpygo
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Patent number: 8450607Abstract: An electronic device housing is provided. The electronic device housing includes a substrate, a metallic-appearing coating formed on the substrate, and a top coating formed on the metallic-appearing coating. The top coating contains nano-titanium dioxide powder and fluorocarbon resin. The electronic device housing has self-cleaning and anti-fingerprint properties.Type: GrantFiled: November 19, 2010Date of Patent: May 28, 2013Assignees: Shenzhen Futaihong Precision Industry Co., Ltd., FIH (Hong Kong) LimitedInventors: Qi-Jian Du, Chwan-Hwa Chiang
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Patent number: 8449993Abstract: Articles coated with wetting resistant materials are presented. One embodiment is an article comprising a substrate and a coating having low surface connected porosity disposed on the substrate. The coating comprises an oxide, which comprises aluminum, yttrium, and at least one rare earth element according to the following atomic proportions: (RxY1-x)3Al5O12 where x is in the range from about 0.001 to about 0.999, and where R is at least one of the rare earth elements, Y is yttrium, O is oxygen, and Al is aluminum.Type: GrantFiled: August 31, 2009Date of Patent: May 28, 2013Assignee: General Electric CompanyInventors: Molly Maureen Gentleman, James Anthony Ruud
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Publication number: 20130122317Abstract: A coated substrate including a substrate having a surface, a bond coat proximate to the substrate surface, a yttrium stabilized zirconia (YSZ) thermal barrier layer opposite the substrate surface, and at least one interlayer disposed between the bond coat and the thermal barrier layer, wherein the interlayer contains an alloy having a nanocrystalline grain structure. A method for coating a substrate to be exposed to high in service temperatures and/or temperature cycles including depositing a bond coating on substrate surface, depositing at least one nanocrystalline interlayer on the bond coat opposite the substrate surface, and depositing a yttrium stabilized zirconia (YSZ) thermal barrier coating on the nanocrystalline interlayer opposite the bond coat, wherein the service life of the YSZ thermal barrier coating is extended relative to a substrate coated with the bond coating and the thermal barrier without the interlayer disposed therebetween.Type: ApplicationFiled: May 4, 2012Publication date: May 16, 2013Applicant: Electric Power Research Institute, Inc.Inventors: Narayana Sastry CHERUVU, Ronghua WEI
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Patent number: 8440314Abstract: The present disclosure is directed to cutting tools. The disclosed cutting tools may have a wear resistant coating on a substrate. The substrate may have hard particles cemented in a binder phase. The binder may have a near-surface concentration gradient of at least one platinum group element and/or rhenium. Processes for producing cutting tools are also disclosed.Type: GrantFiled: August 25, 2009Date of Patent: May 14, 2013Assignee: TDY Industries, LLCInventors: Craig W. Morton, Dewitt Dortch, John Bost, David J. Wills
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Publication number: 20130113013Abstract: Provided is a metal foil laminate that: has heat resistance; has high reflectance in the visible light range; has little decrease in reflectance in environments with a high-temperature thermal load; is compatible with large surface areas; and can be used for printed circuit boards for mounting LEDs that have excellent adhesion with metals. The metal foil laminate is characterized in that: a laminate has metal foil on at least one side of a resin layer (A) containing a polyorganosiloxane and an inorganic filler; the 90° peel strength between said resin layer (A) and said metal foil is at least 0.95 kN/m, and the mean reflectance at wavelengths of 400 to 800 nm on the surface that is exposed when the resin layer (A) is exposed by peeling and removing said metal foil is at least 80%; and the decrease in the reflectance at a wavelength of 470 nm after being treated with heat for 10 minutes at 260° C. is not more than 5%.Type: ApplicationFiled: July 26, 2011Publication date: May 9, 2013Applicant: MITSUBISHI PLASTICS INCInventors: Jun Matsui, Tomohiko Terai, Syuuji Suzuki
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Publication number: 20130114059Abstract: A metal component (262M, 300M) is designed for use in an EUV lithography apparatus, for example as a spectral purity filter (260) or a heating element (300) in a hydrogen radical generator. An exposed surface of the metal is treated (262P, 300P) to inhibit the formation of an oxide of said metal in an air environment prior to operation. This prevents contamination of optical components by subsequent evaporation of the oxide during operation of the component at elevated temperatures.Type: ApplicationFiled: June 6, 2011Publication date: May 9, 2013Applicant: ASML Netherlands B.V.Inventors: Martin Jacobus Johan Jak, Vadim Yevgenyevich Banine, Wouter Anthon Soer, Andrei Mikhailovich Yakunn, Maarten Van Kampen, Gerard Frans Jozef Schasfoort
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Patent number: 8435649Abstract: A white film structure includes a combining layer and a color layer. The combining layer is formed on a surface of a substrate and is made of chromium nitride. The color layer is formed on the combining layer and is made of a mixture of alumina and titanium oxide. A weight percent of the aluminum in the color layer is more than that of the titanium in the color layer.Type: GrantFiled: November 19, 2010Date of Patent: May 7, 2013Assignee: Hon Hai Precision Industry Co., Ltd.Inventor: Hsin-Chin Hung
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Patent number: 8435651Abstract: Provided is a wood cutting tool with improved wear resistance and corrosion resistance. A hard fundamental layer (18) of chromium nitride (CrN) is subjected to PVD to be coated on a rake face (16) of a substrate (12) formed of a cemented carbide alloy or a tool steel. The hard fundamental layer (18) has a five-layer structure having a first layer (18a) to a fifth layer (18e) disposed in order from the substrate (12) side. A hard main layer (20) of chromium oxide (Cr2O3) is coated on the outer surface of the fifth layer (18e) of the hard fundamental layer (18). The hard main layer (20), like the hard fundamental layer (18), is formed by PVD. The hard fundamental layer (18) is coated with the hard main layer (20) to suppress corrosion, thereby improving the wear resistance and corrosion resistance of a cemented carbide replaceable knife (10).Type: GrantFiled: April 22, 2009Date of Patent: May 7, 2013Assignee: Kanefusa Kabushiki KaishaInventors: Toru Minami, Satoru Nishio
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Patent number: 8435626Abstract: A WC—Co material or polycrystalline diamond-Co material that has a gradient in the grain size of the particles. Specifically, the material may have a top layer that has coarse grains that is designed to dissipate the heat caused by friction (and thus prevent thermal cracking). The material will then have a bulk substrate that is made up of finer grains and provide adequate hardness for the material. The top layer is positioned on top of the bulk substrate.Type: GrantFiled: March 6, 2009Date of Patent: May 7, 2013Assignee: University of Utah Research FoundationInventor: Zhigang Zak Fang
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Publication number: 20130099187Abstract: A multilayer structure is disclosed that includes a conductive layer, a layer of a negative differential resistance (NDR) material disposed above the conductive layer, a layer M2 disposed above the NDR material, a second layer of NDR material disposed above layer M2, and a conductive layer disposed above the second NDR layer. Layer M2 can include a conductive material interspersed with regions of a dielectric material or a layer of the dielectric material and regions of the conductive material disposed above and below the dielectric material.Type: ApplicationFiled: October 25, 2011Publication date: April 25, 2013Inventors: Matthew D. Pickett, R. Stanley Williams, Gilberto M. Ribeiro, Warren Jackson
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Publication number: 20130084450Abstract: The present invention relates to a corrosion resistant member including: a substrate composed of a ceramic or a metal, and at least one layer of a corrosion resistant film formed on a surface of at least a region of the substrate to be exposed to plasma or a corrosive gas, in which the corrosion resistant film contains yttria as a main component and further also contains at least one of tantalum and niobium in an amount of 0.02 to 10 mol % in terms of pentoxide relative to the yttria, and a non-melted portion is not present in the corrosion resistant film.Type: ApplicationFiled: September 7, 2012Publication date: April 4, 2013Applicant: Covalent Materials CorporationInventors: Yukitaka MURATA, Hitoshi SASAKI, Shintaro MATSUMOTO
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Publication number: 20130066425Abstract: The present invention provides polymeric substrates comprising a biocompatible coating and methods of preparation thereof. In particular, the coating may be a ceramic material, especially a calcium phosphate material, which may be functionally graded. The invention provides the ability to apply high quality coatings to polymeric substrates without damaging the substrate (e.g., melting the polymeric material). The functionally graded coating can provide crystalline calcium phosphate near the coating interface with the substrate and provide amorphous calcium phosphate at the outer surface of the coating.Type: ApplicationFiled: November 9, 2012Publication date: March 14, 2013Applicant: North Carolina State UniversityInventor: North Carolina State University
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Publication number: 20130065048Abstract: A multilayer coating includes a bond coat layer, a first barrier layer applied on the bond coat layer, and a second barrier layer applied on the first barrier layer. The first barrier layer has a compositional gradient comprising a majority of a first rare earth stabilized zirconia material proximate the bond coat layer to a majority of a second rare earth stabilized zirconia material away from the bond coat layer. The first and second rare earth stabilized zirconia materials are different. The second barrier layer has a compositional gradient comprising a majority of the second rare earth stabilized zirconia material to 100 wt % of a third rare earth stabilized zirconia material away from the first barrier layer.Type: ApplicationFiled: November 12, 2012Publication date: March 14, 2013Applicant: UNITED TECHNOLOGIES CORPORATIONInventor: United Technologies Corporation
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Patent number: 8394503Abstract: Disclosed is a resin-metal bonded article which is improved in adhesion between a copper component and a PPS or PBT resin. Also disclosed is a method for producing such a resin-metal bonded article. The resin-metal bonded article is obtained by bonding the resin component onto the surface of the copper component through a copper component bonding surface where there is copper oxide in the following range: 10%?Cu2O/(Cu2O+CuO)?75%. Preferably, this resin-metal bonded article further contains a triazine thiol derivative in the resin-component-side bonding surface of the copper component.Type: GrantFiled: December 15, 2008Date of Patent: March 12, 2013Assignee: Toadenka CorporationInventors: Masumi Kuroyama, Kazuo Kato, Tomonori Ishikawa, Yaeko Sasaki, Setsuko Sato, Masayuki Nakamura, Shuhei Miura
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Patent number: 8394469Abstract: An exhaust pipe for an internal combustion engine includes a metal tube enclosing a passage through which an exhaust gas from an internal combustion engine passes, and a ceramic film covering the metal tube from the outside. The ceramic film contains no more than about 0.5 atomic % of a metallic element which is dominantly present in a surface of the metal tube.Type: GrantFiled: July 8, 2005Date of Patent: March 12, 2013Assignee: Yamaha Hatsudoki Kabushiki KaishaInventor: Naohisa Takahashi
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Patent number: 8383239Abstract: A bearing comprises at least one inner ring and at least one outer ring. At least a part of the surfaces of the inner ring and/or the outer ring is coated with a layer consisting of or containing fullerene-like carbon nitride (FL-CNx), and wherein an inter-layer of chromium (Cr) or aluminum (Al) or molybdenum (Mo) or titanium (Ti) or tungsten (W) or a diamond-like coating (DLC) or a metal-mix diamond-like coating (Me-DLC) is arranged between the surface of the inner ring and/or the outer ring and the layer.Type: GrantFiled: July 29, 2006Date of Patent: February 26, 2013Assignee: Aktiebolaget SKFInventors: Steuart Horton, Lars Hultman
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Publication number: 20130045374Abstract: The present invention discloses a nano-laminated film with transparent conductive property and water-vapor resistance function and method thereof. The nano-laminated film comprises a plurality of first metal oxide layers and a plurality of second metal oxide layers. Wherein, the first metal layers and the second metal layers are made of different materials, and there is a spinel phase formed between the first metal layers and the second metal layers.Type: ApplicationFiled: April 27, 2012Publication date: February 21, 2013Applicant: NATIONAL APPLIED RESEARCH LABORATORIESInventors: CHIH-CHIEH YU, MENG-YEN TSAI, CHI-CHUNG KEI, BO-HENG LIU, CHIEN-NAN HSIAO
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Patent number: 8377569Abstract: A coated article is described. The coated article includes a substrate, a bonding layer formed on the substrate, a plurality of nickel-chromium-nitrogen layers and a plurality of copper-silver-cerium alloy layers formed on the bonding layer. The bonding layer is a nickel-chromium layer. Each nickel-chromium-nitrogen layer interleaves with one copper-silver-cerium alloy layer. One of the nickel-chromium-nitrogen layers is directly formed on the bonding layer. A method for making the coated article is also described.Type: GrantFiled: August 4, 2011Date of Patent: February 19, 2013Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.Inventors: Hsin-Pei Chang, Wen-Rong Chen, Huann-Wu Chiang, Cheng-Shi Chen, Cong Li
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Publication number: 20130040150Abstract: An article includes a substrate with a plurality of independent taggant layers that each include metal oxide nanocrystals doped with at least one Lanthanide element. Each taggant layer includes metal oxide nanocrystals doped with a different Lanthanide element than each other taggant layer.Type: ApplicationFiled: August 3, 2012Publication date: February 14, 2013Applicant: THE JOHNS HOPKINS UNIVERSITYInventors: Morgana M. Trexler, Dajie Zhang, Lisa A. Kelly, Jennifer L. Sample, John M. Brupbacher
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Patent number: 8367225Abstract: A coating includes a deposited layer. The deposited layer is a nickel-titanium carbonitride layer.Type: GrantFiled: December 15, 2010Date of Patent: February 5, 2013Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.Inventors: Hsin-Pei Chang, Wen-Rong Chen, Huan-Wu Chiang, Cheng-Shi Chen, Chuang Ma
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Patent number: 8361639Abstract: A coating includes a nano-composite base comprising a number of films, the films stacked together one after another. Each film includes a nickel-titanium carbonitride layer and a titanium carbonitride layer.Type: GrantFiled: December 15, 2010Date of Patent: January 29, 2013Assignees: Hong Fu Jin Precision Industry (ShenZhen) Co., Ltd., Hon Hai Precision Industry Co., Ltd.Inventors: Hsin-Pei Chang, Wen-Rong Chen, Huan-Wu Chiang, Cheng-Shi Chen, Chuang Ma
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Patent number: 8337989Abstract: A multilayer coating includes a bond coat layer and a first barrier layer applied on the bond coat layer. The first barrier layer has a compositional gradient comprising a majority of a first rare earth stabilized zirconia material proximate the bond coat layer to a majority of a second rare earth stabilized zirconia material away from the bond coat layer. The first and second rare earth stabilized zirconia materials are different.Type: GrantFiled: May 17, 2010Date of Patent: December 25, 2012Assignee: United Technologies CorporationInventors: Peter F. Gero, Kevin W. Schlichting, James W. Neal
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Publication number: 20120321903Abstract: A hot-pressed member includes a steel sheet, a Ni-diffusion region present in a surface layer of the steel sheet, and an intermetallic compound layer and a ZnO layer which are provided in order on the Ni-diffusion region, the intermetallic compound layer corresponding to a ? phase present in a phase equilibrium diagram of a Zn—Ni alloy, wherein a spontaneous immersion potential indicated in a 0.5 M NaCl aqueous air-saturated solution at 25° C.±5° C. is ?600 to ?360 mV based on a standard hydrogen electrode.Type: ApplicationFiled: October 28, 2010Publication date: December 20, 2012Applicant: JFE Steel CorporationInventors: Hiroki Nakamaru, Seiji Nakajima, Tatsuya Miyoshi, Hiroyuki Masuoka, Shinji Ootsuka
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Publication number: 20120315564Abstract: A composite body includes a substrate containing Cr; and a first composite oxide layer disposed on at least a part of a surface of the substrate, the first composite oxide layer having a spinel type crystal structure, a first largest content and a second largest content among constituent elements excluding oxygen of the first composite oxide layer being Zn and Al in random order. Accordingly, the composite body can suppress diffusion of Cr from the substrate containing Cr to the first composite oxide layer, and has improved long-term reliability. A collector member and a gas tank, each of which is formed of the composite body, can have improved long-term reliability. A fuel cell device having excellent long-term reliability can be obtained using the collector member and the gas tank.Type: ApplicationFiled: February 25, 2011Publication date: December 13, 2012Applicant: KYOCERA CORPORATIONInventors: Tetsuro Fujimoto, Masahiko Higashi
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Patent number: 8323783Abstract: A coated cutting insert for removing material from a workpiece that includes a substrate is disclosed. A wear-resistant coating on the substrate that includes an ?-alumina layer and a Zr— or Hf— carbonitride outer layer deposited on the ?-alumina layer. The Zr— or Hf— carbonitride outer layer is subjected to a post-coat wet blasting treatment. The wet blasting changes the stress condition of the exposed alumina coating layer from an initial tensile stress condition to a compressive stress condition.Type: GrantFiled: November 10, 2009Date of Patent: December 4, 2012Assignee: Kennametal Inc.Inventors: Volkmar Sottke, Zhigang Ban, Hartmut Westphal, Yixiong Liu, Michael Frank Beblo
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Patent number: 8323807Abstract: The present invention provides a process for producing an alumina coating comprised mainly of ? crystal structure on a base material.Type: GrantFiled: March 12, 2009Date of Patent: December 4, 2012Assignee: Kobe Steel, Ltd.Inventors: Toshimitsu Kohara, Yoshimitsu Ikari, Hiroshi Tamagaki
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Patent number: 8318293Abstract: The present invention relates to a CVD-coated cutting tool insert with a TiCxNy-layer with a low tensile stress level of from about 50 to about 390 MPa and an ?-Al2O3-layer with a high surface smoothness with a mean Ra<0.12 ?m as measured by AFM-technique. This is obtained by subjecting the coating to an intensive wet blasting operation.Type: GrantFiled: June 16, 2006Date of Patent: November 27, 2012Assignee: Sandvik Intellectual Property ABInventors: Peter Littecke, Björn Ljungberg
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Patent number: 8313841Abstract: The present invention relates to a device comprising a substrate based essentially on nitinol and, arranged thereon at least partially, a covering or a coating based on at least one polyphosphazene derivative having the general formula (I), a process for its production, and the use of the device as an artificial implant, vascular or nonvascular stent, catheter, thrombolectomy or embolectomy catheter, fragmentation spindle or catheter, filter, vascular connector, hernia patch, oral, dental or throat implant or urether.Type: GrantFiled: January 23, 2012Date of Patent: November 20, 2012Assignee: CeloNova BioSciences Germany GmbHInventors: Andreas Schuessler, Michael Grunze, Roman Denk
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Patent number: 8313842Abstract: A Ti-based cermet 1 includes at least one of Co and Ni, at least one of titanium carbide, titanium nitride and titanium carbonitride including at least one selected from the metal elements of groups 4, 5 and 6 of the periodic table, and Ru.Type: GrantFiled: February 25, 2008Date of Patent: November 20, 2012Assignee: Kyocera CorporationInventors: Hideyoshi Kinoshita, Takashi Tokunaga
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Publication number: 20120280217Abstract: There are provided an electrode foil which has both the functions of a supporting base material and a reflective electrode and also has a superior thermal conductivity and heat resistance; and an organic device using the same. The electrode foil comprises a metal foil; a diffusion prevention layer for preventing diffusion of metal derived from the metal foil, the diffusion prevention layer being provided directly on the metal foil; and a reflective layer provided directly on the diffusion prevention layer.Type: ApplicationFiled: September 8, 2011Publication date: November 8, 2012Applicant: MITSUI MINING &SMELTING CO. LTDInventors: Yoshinori Matsuura, Nozomu Kitajima
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Publication number: 20120276349Abstract: An aluminum or aluminum alloy article is described. The aluminum or aluminum alloy article includes an aluminum or aluminum alloy substrate, a barrier layer formed on the substrate, a color layer formed on the barrier layer, and an insulation layer formed on the color layer. The barrier layer and the color layer are formed by vacuum sputtering. The barrier layer is a layer of chromium-oxygen-nitrogen, aluminum-oxygen-nitrogen, or titanium-oxygen-nitrogen. The insulation layer is an external layer of the aluminum or aluminum alloy article.Type: ApplicationFiled: July 5, 2011Publication date: November 1, 2012Applicants: HON HAI PRECISION INDUSTRY CO., LTD., HONG FU JIN PRECISION INDUSTRY (ShenZhen) CO., LTD .Inventors: HSIN-PEI CHANG, WEN-RONG CHEN, HUANN-WU CHIANG, CHENG-SHI CHEN, NAN MA
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Publication number: 20120270023Abstract: A composite material including a carrier g of aluminum, an optically effective multi-layer system applied to a side (A) of the carrier. The system having at least 2 dielectric and/or oxidic layers, namely an upper layer and a lower, light-absorbing layer. The lower, light-absorbing layer contains a titanium-aluminum mixed oxide TiAlqOx and/or a titanium-aluminum makes nitride TiAlqNy and/or a titanium-aluminum mixed oxynitride TiAlqOxNy, while the upper layer is an oxidic layer made of titanium, silicon or tin of the chemical composition TiOz, SiOw, or SnOv, where the indices q, v, w, y and z each denote a stoichiometric or nonstoichiometric ratio.Type: ApplicationFiled: July 16, 2010Publication date: October 25, 2012Inventors: Frank Templin, Dimitrios Peros, Tobias Titz, Harald Küster
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Publication number: 20120263943Abstract: A post-heat-treatable substrate with a thermochromic film. The post-heat-treatable substrate includes a base substrate, a thermochromic film coating the base substrate, an auxiliary film formed on at least one of the upper surface and the lower surface of the thermochromic film, and a sacrificial film formed between the thermochromic film and the auxiliary film. The sacrificial film is made of metal. Accordingly, the thermochromic material is prevented from agglomerating during post-heat-treatment of the substrate. The auxiliary film prevents oxygen and nitrogen from diffusing into the thermochromic film, so that high-temperature heat treatment, such as a process for tempering the substrate, a process for heat-strengthening the substrate and a process for forming the substrate to become curved, can be conducted on the substrate.Type: ApplicationFiled: April 18, 2012Publication date: October 18, 2012Inventors: Youngsoo JUNG, Donggun Moon, Myungi Shim, Sangryoun Ryu
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Publication number: 20120263898Abstract: Photo-regenerable oxygen scavenging packaging is generally disclosed. Some example embodiments may comprise tantalum oxide and/or manganese oxide arranged to act as a photo-regenerable oxygen scavenger. The tantalum oxide, if present, may operate as an oxygen scavenger when the tantalum oxide exists as tantalum (IV) oxide. Subjecting the tantalum oxide to light may transform at least a portion of the tantalum oxide existing as tantalum (V) oxide to tantalum (IV) oxide. The manganese oxide, if present, may operate as an oxygen scavenger when the manganese oxide exists as manganese (II) oxide. Subjecting the manganese oxide to light may transform at least a portion of the manganese oxide existing as manganese (III) oxide to manganese (II) oxide. Some example containers may include a structure defining an interior volume and a photo-regenerable oxygen scavenger disposed in fluidic communication with the interior volume.Type: ApplicationFiled: June 13, 2011Publication date: October 18, 2012Applicant: EMPIRE TECHNOLOGY DEVELOPMENT, LLCInventor: Thevasahayam Arockiadoss
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Patent number: 8282270Abstract: According to this process for manufacturing a ceramic element intended to be fitted onto a watch case, the visible surface of which has features, a soluble layer (2) is selectively deposited on said visible surface, the thickness of said soluble layer being at least equal to the height of said features, a first tie layer (3) of the Ti, Ta, Cr or Th type is vacuum-deposited by magnetron sputtering with a thickness of at least 100 nm by physical vapor deposition (PVD) on said surface thus selectively coated, followed, without venting atmosphere, by PVD deposition of said second layer (4) made of Au, Pt, Ag, Ni, Pd, TiN, CrN, ZrN or alloys thereof with a thickness of at least 100 nm, and then said soluble layer (2) is dissolved.Type: GrantFiled: October 22, 2009Date of Patent: October 9, 2012Assignee: Rolex S.A.Inventor: Eric Grippo
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Patent number: 8283048Abstract: A thermally sprayed coating, coating system and coated article are disclosed. The disclosed embodiments of the thermally sprayed coating, coating system and coated article use a customized ceramic powder comprising ceramic powder particles having an average particle size of about 25 to about 75 microns. In particular, the ceramic powder particles contain from about 70 to about 95 percent by weight of a zirconia-based component, with the balance being an (alumina+silica)-based component and wherein said ceramic powder particles comprise micronized sub-particles of the zirconia-based component and the (alumina+silica)-based component.Type: GrantFiled: August 4, 2011Date of Patent: October 9, 2012Assignee: Praxair S. T. Technology, Inc.Inventor: Thomas Alan Taylor
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Patent number: 8283058Abstract: The present invention relates to a cuffing insert for turning in heat resistant superalloys and stainless steels comprising a very fine grained hard substrate and a coating. The substrate comprises WC from about 5 to about 8 wt % Co and from about 0.3 to about 1.5 wt % Cr. In addition to that ppm levels of Ti and Ta are present. The ratio of Me/Co=(at-% Ti+ at-% Nb+ at-% Ta)/at-% Co is lower than or equal to about 0.014?(CW_Cr)*0.008 and higher than about 0.0005. The average sintered WC-grain size is from about 0.5 to about 0.95 ?m and CW_Cr from about 0.75 to about 0.95. The cemented carbide body is coated with a PVD TixAl1-xN-coating with an average composition of x being greater than about 0.4 but less than about 0.9, present as a single or multilayer coating with a total thickness of from about 1 to about 6 ?m.Type: GrantFiled: May 23, 2008Date of Patent: October 9, 2012Assignee: Sandvik Intellectual Property ABInventors: Malin Mårtensson, Kerstin Lundin, Susanne Norgren
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Publication number: 20120251742Abstract: The present invention relates to methods and compositions for reducing damaging oxidation of metals. In particular, the present invention relates to nanoparticle surface treatments and use of nanoparticle surface treatments to reduce the damaging oxidation and corrosion of stainless steel and other alloy components in oxidating and corrosive conditions.Type: ApplicationFiled: June 8, 2012Publication date: October 4, 2012Applicant: MATERIAL INTERFACE, INC.Inventor: Susan J. Kerber
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Patent number: 8273469Abstract: Disclosed is a piston ring comprising a supporting material and a wear-resistant coating. The wear-resistant coating is composed of a ternary system A-B—N which is applied using a PVD process and in which A and B each represent an element form the group encompassing Ti, Zr, Hf, V, Nb, Ta, Cr, Mo W, Al, Si and C, wherein A?B and N represents nitrogen. The thickness of the wear-resistant coating amounts to ?3 ?m.Type: GrantFiled: June 12, 2008Date of Patent: September 25, 2012Assignee: Federal-Mogul Burscheid GmbHInventors: Steffen Hoppe, Manfred Fischer, Christiane Bauer, Ralf Lammers
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Patent number: 8247085Abstract: Coatings suitable for use as protective oxide-forming coatings on Nb-based substrates exposed to high temperatures and oxidative environments. The coatings contain chromium and/or molybdenum, preferably contains silicon, and optionally contains niobium, titanium, hafnium, iron, rhenium, tantalum, and/or tungsten, which in combination form multiple intermetallic phases, which in combination form one or more intermetallic phases that promote the formation of a slow-growing oxide scale. Depending on the particular coating composition, the intermetallic phases may be: a silicon-modified Cr2Nb Laves phase and optionally a chromium solid solution phase, a CrNbSi intermetallic phase, and/or an M3Si intermetallic phase where M is niobium, titanium, and/or chromium; or M5Si3, MSi2 and/or M3Si2 where M is molybdenum, niobium, titanium, chromium, hafnium, iron, rhenium, tantalum, and/or tungsten.Type: GrantFiled: November 21, 2008Date of Patent: August 21, 2012Assignee: General Electric CompanyInventors: Bernard Patrick Bewlay, Pazhayannur Ramanathan Subramanian, Joseph David Rigney, Richard DiDomizio, Voramon Supatarawanich Dheeradhada
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Patent number: 8247080Abstract: A coating structure including an outer coating comprising aluminum; and an interlayer disposed between a substrate and the outer coating is provided. The interlayer may include a rare earth metal, a transition metal, or a noble metal. The interlayer may have one or more property of being less responsive to halogen etching relative to the outer coating; having a coefficient of thermal expansion that is greater than the coefficient of thermal expansion of the substrate and less than the coefficient of thermal expansion of the outer coating or vice versa; having a color different from the color of the outer coating; having a electrical conductivity different from the electrical conductivity of the outer coating. A method of making is article is provided. The method may include securing an interlayer to a substrate surface, and securing an outer coating to a surface of the interlayer opposite the substrate.Type: GrantFiled: October 12, 2005Date of Patent: August 21, 2012Assignee: Momentive Performance Materials Inc.Inventors: Charles Dominic Iacovangelo, Victor Lienkong Lou
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Patent number: 8241757Abstract: A multilayer substrate includes a base layer, a coating layer and an intermediate layer positioned between the base layer and the coating layer. The intermediate layer contains chromium and nitrogen. A content of the chromium in the intermediate layer gradually decreases from the base layer to the coating layer.Type: GrantFiled: October 27, 2009Date of Patent: August 14, 2012Assignee: Hon Hai Precision Industry Co., Ltd.Inventors: Chao-Tsang Wei, Chung-Pei Wang, Chien-Hao Huang, Wei-Cheng Ling, Chia-Ying Wu, Ga-Lane Chen