Abstract: A method and an apparatus for producing a product having a magnetically formed pattern, capable of forming any desired pattern in diversely different shapes with a clear visual recognizability, at high speed, by a simple procedure, and a painted product produced by these method and apparatus. The product is produced by forming a paint layer from a paint medium mixed with magnetic non-spherical particles, and applying a magnetic field containing the lines of magnetic field in a shape corresponding to the desired pattern to be formed.

Abstract: Particleboard is produced by coating the particles of wood furnish with an adhesive comprising a foamed mixture of 96-98 percent by weight urea formaldehyde and 2-4 percent by weight dried animal blood, the mixture being foamed to about 5-15 times the volume of the liquid resin to provide a urea formaldehyde resin solids content of 45-70 percent by weight. The foamed adhesive mixture is coated onto the wood particles of the furnish, as by means of a blender, to provide the finished particleboard with a resin solids content of 5-10 percent by weight.

Abstract: A fusible phenolic resin and a dialkyl-N, N-bis (hydroxyalkyl) aminoalkyl phosphonate are condensed to form a water-insoluble resin having fire retardant properties. Fire resistant materials are made by causing the condensation to occur in situ when a normally flammable material and the reactants are mixed and the mixture is heated at 250.degree. F. to 480.degree. F. Wooden articles such as molded hardboard roofing shingles of this invention do not lose their fire resistance after being soaked with rain repeatedly.

Abstract: The invention is a board of non-timber hardwood-replacement lumber. The primary constituent is rinds of a grass selected from the group of grasses consisting of sugarcane and sorghum. The board has an integral mass of parallel elongate flattened rinds aligned along the length of the board, parallel to a board surface and joined together by adhesive bonding. A "cant" (from which the boards are made) is also disclosed and like the boards sawed from it, the cant is substantially void-free and of substantially constant density throughout its cross-section. The board is furniture-grade and exhibits grain characteristics very closely similar to natural hardwood.

Abstract: An improved structural panel made from the rinds of sugarcane and other similar grasses. The panel is formed of a pile of rind fiber-bundle strands randomly oriented in substantially parallel planes. The strands are substantially straight and of length such that most have a stalk node thereon. Each strand has a multiplicity of contact points with other strands of the pile, and a binder coats the strands and interconnects them at the contact points to form a substantially rigid structure, the coated strands defining voids within the pile.

Abstract: Amino resins, e.g., urea-formaldehyde and melamine-formaldehyde thermosetting resins, are cured with a latent catalyst which is a thermally-decomposable adduct of an aromatic sulfonic acid (e.g., p-toluene sulfonic acid) and a bicyclic oxazolidines (e.g., 1-aza-3,7-dioxa-5-ethylbicyclo (3.3.0) octane. The coating compositions can contain other conventional co-reactants, such as polyols, polyacids, alkyd resins, polyester resins, epoxies, acrylics and the like. Coatings containing the amino resin, co-reactant, and latent catalyst have an acceptable viscosity stability, cure rapidly at temperatures lower than some other latent catalysts, and produce films with no wrinkles.

Abstract: Process for the production of aminoplast resins. The process entailing the addition of ureido-2-diamino-4,6-triazine-1,3,5, and optionally melamine, to aminoplast resin. Preferably the triazine is added in a proportion of at least 10% by weight. The resultant aminoplasts can be used to make panels from particles.

Abstract: A composition for a formaldehyde scavenger is provided which consists of a water-soluble blend of a substituted or unsubstituted polyhydric alcohol and an active methylene compound selected from the group consisting of dialkyl malonate and alkylacetoacetate.

Abstract: A method of forming a flitch and producing novel sheets of veneer which includes the steps of joining a plurality of veneer sheets in a face-to-face relationship, applying pressure to bond the sheets and form the flitch, coating the ends of the formed flitch to resist checking and splitting, heating the flitch in an oven and thereafter cooking the flitch in a water bath for a period of time sufficient to place it in condition for slicing. The flitch is then removed from the bath, cooled for a period of time, prepared for the slicing operation, and sliced into thin sheets of veneer which are passed through a dryer thus resulting in a new veneer sheet having a novel texture and surface pattern. This manufactured flitch when sliced vertically will yield veneer sheets having a quarter grain or striped pattern. Veneer of varying patterns can be obtained by placing a substantially circular rod longitudinally under the formed flitch to provide an upper exterior surface curvature.

Abstract: An anti-skid coating composition for coating various substrates including structural panel board surfaces, comprises a binder made of urea formaldehyde resin, polyvinyl acetate, ammonium chloride and a dispersant. The binder is used in conjunction with an aggregate, such as walnut shells. A method is also provided for coating the substrates to impart slip resistance thereto.

Abstract: The present invention is directed to a method of using non-resinous melamine to safen urea formaldehyde-wood composites and the product produced thereby. The method involves incorporation of non-resinous melamine into a urea formaldehyde-wood composite in a manner which leaves most of the melamine free to serve as a flame retardant and formaldehyde scavenger. The non-resinous melamine is incorporated into the urea formaldehyde-wood composite prior to curing the urea formaldehyde resin.

Abstract: This invention relates to ethyleneurea-glutaraldehyde resins, urea-ethyleneurea-glutaraldehyde resins, their synthesis, as well as their application as an adhesive for wood panel manufacture. Molar ratio of ethyleneurea to glutaraldehyde can range from 0.3 to 3.5. Urea incorporated into ethyleneurea-glutaraldehyde resin can be high as two times the moles of glutaraldehyde used in the formulation and can be introduced at any stage during the reaction course, simply post added, or any combination of the above.

Abstract: Disclosed are compositions useful as surface coatings for nonwoven substrates which compositions are reaction products of a melamine formaldehyde compound, long chain saturated alcohols and long chain saturated or unsaturated polyethoxylated alcohols. The invention compositions when used to surface size paper impart oil, water and polar solvent resistance thereto. The compositions may be used alone or as substantial replacements for anionic or non-ionic fluorocarbon based surface sizes that are typically used to impart oil resistance to paper.

Abstract: The invention is a solution of highly advanced phenolic resin with improved inherent foamability that is made from the reaction of phenol, aldehyde, water and alkali the improved foamability being brought about by the incorporation of up to 1.0% by weight, anhydrous basis, lime (calcium hydroxide) into the early stages of the reaction mix. In another embodiment, the invention is a plywood glue composition comprising a solution of lime-containing highly advanced phenolic resin, dried animal blood and preferably an aldehyde glue viscosity-lowering agent.

Abstract: Ethylenically unsaturated carbamates prepared by addition of unsaturated isocyanates to the hydroxy groups of polyvinyl acetals are formulated with allylic monomers and optionally unsaturated co-reactants selected from (meth)-acryloyl monomers and oligomers, maleates and fumarates to provide air-dry- and heat-curable coating compositions.

Abstract: A process is provided for forming a fire retardant composition useful for treating cellulosic materials to impart both fire retardant properties and improved thermal stability under high temperature and humidity conditions. The process comprises reacting a solution of orthophosphoric acid, urea and water having a weight ratio from about 0.1 to about 15 orthophosphoric acid per part urea for a time of about 15 minutes to about 3 hours at a temperature from about 25.degree. C. to about 90.degree. C.; adding hydroxide in an amount sufficient to adjust the pH of the solution from about 6.0 to about 9.0; reacting the solution with formaldehyde having a weight ratio from about 1.0 to about 56 total initial orthophosphoric acid per part formaldehyde for a time of about 5 minutes to about 1.5 hours at a temperature from about 25.degree. C. to about 90.degree. C., and adjusting the final pH of the solution from about 7.0 to about 8.5 with ammonium hydroxide.

Abstract: A process for the preparation of a urea-formaldehyde resin exhibiting reduced gel time and improved stability, wherein the resin contains not more than 10% melamine, which is added during the first stage of the reaction with the other reactants, and wherein the reaction is conducted at an acidic pH.

Abstract: The preparation of aminoplastic resins containing melamine, having very low rates of formaldehyde emission, and being particularly useful for the production of particle boards. In a second stage of the process for preparing the resin, additional NH.sub.2 (melamine and urea) is added to a conventional condensate solution at an increased pH between 6 and 9 so as to lower the F/NH.sub.2 molar ratio to between 0.5 and 0.9. Urea is added in a third stage to obtain an F/NH.sub.2 of between 0.30 and 0.50, with the optional addition of borax.

Abstract: A thermosetting resin decorative laminated sheet faced with a resin-impregnated sheet layer obtained by impregnating a sheetlike material with a resin composition containing an amino resin (I) produced by the reaction of formaldehyde with an amino compound (A) having as an essential component thereof at least one carboguanamine (a) selected from the group consisting of cyclohexanecarboguanamine and norbornanecarboguanamine and curing the resultant impregnated sheetlike material excels in flexibility, crack resistance, light resistance, and chemical resistance. A decorative overlaid plywood enjoying similarly desirable properties is obtained by integrating the aforementioned sheet layer with a substrate.

Abstract: Described is a titanium dioxide-containing resin saturable paper sheet in which from about 5 to about 40 weight percent of the titanium dioxide filler is replaced with amorphous precipitated silica having an essentially neutral to slightly alkaline, e.g., 6.5 to 8.5, pH and a medium agglomerate particle size of less than 30 micrometers, e.g., 3 to 10 micrometers. The BET surface area of the silica may vary from about 25 to about 200 m.sup.2 /g, e.g., 50 to 100 m.sup.2 /g. Also described are decorative laminates in which the core of the laminate contains at least one of such saturable paper sheets.

Abstract: A temporary support with a transferable film composition coated on its surface is used in the manufacture of heat and pressure consolidated laminates to produce laminates of improved surface strength and functional properties. The film is composed of polyvinyl butyral resin and melamine resin. Additives may be included in the film composition for functional purposes and appearance.

Abstract: The invention relates to a composition of matter comprising an ammoniated urea-formaldehyde resin and a water soluble dried urea-formaldehyde resin powder wherein the ratio of ammoniated to dried urea-formaldehyde resins is from approximately 20:1 to 1:20 weight. A process for adhering paper to a lignocellulosic substrate using the composition of matter is provided. By this invention, high solids, shelf stable adhesive compositions containing low levels of free formaldehyde are provided which, when catalyzed, will cure under heat and/or pressure, to adhere decorative paper to a lignocellulosic substrate.

Abstract: Composites are made from cellulose fibers dispersed in a matrix of polyethylene and an isocyanate and bonded thereto during subsequent extrusion and or molding. The isocyanate improves adhesion between the cellulose fibers and the polyethylene. The improved adhesion results in improved tensile properties in the composite.

Abstract: A formaldehyde binder containing at least one organic hydroxy compound, at least one amide, and water. This binder is suitable for use in preparing boards from lignocellulosic materials using adhesive based on formaldehyde.

Abstract: In a composite panel with a core plate (1), a cover plate (2) glued to the upper side of core plate (1), an edge strip glued to an edge (4) of the core plate (1) and a protective sheet (3) or the like glued to the underside of the core plate (1) in which a drip groove (7), running essentially parallel to the edge (4), is provided on the underside of core plate (1) at a certain distance from its edge (4), considerable production simplification and, simultaneously, a considerably improved protection from water drops running in on the underside of the composite panel are attained, by drip groove (7) being put directly into core plate (1), by the cover plate (2) being pulled around to the underside of core plate (1) and/or protective sheet (3) or the like glued to the underside being pulled into drip groove (7) as far as possible and by the area of the drip groove (7) that is not covered by the cover plate (2) and/or protective sheet (2) or the like, including the free edges of the cover plate (2) and/or the prot

Abstract: Substitute lumber pieces having strengths and densities substantially equivalent to lumber are cut from single layer panels of over about 1 and normally less than 4 inches thickness made from wood wafers. The wafers are oriented with their lengths having a mean deviation to the longitudinal length of the panel measured in the major plane of the panel in the range of 0 to 10 degrees and a mean deviation measured in a minimum longitudinal plane perpendicular to the major plane from 0 to about 5 degrees and have an average effective length of at least 8 inches (200 mm), and preferably an average thickness less than 0.15 inches (4 mm) and a width of at least 0.25 inches (6 mm). Lumber is made by cutting the panel longitudinally. Preferably the panels are formed to have a substantially uniform density profile throughout their thicknesses.

Abstract: Process for the assembly of wooden components in which the wooden components are coated with a thermosetting resin containing formaldehyde and the resin-coated components are then treated with a peroxide and are then pressed together while heat is applied. Assembly of wooden components obtained by said process.

Abstract: The disclosure relates to difficulty flammable wooden articles, especially chip boards comprising solid and pipe boards, prepared by extrusion from wooden chips and/or woody fibrous materials. The articles contain as a flame-retarding addend a product of(a) 50 to 99.5 weight % of a flame-retarding agent physically and chemically stable under extrusion conditions, preferably 75 to 99.5 weight % of a pulverulent, free-flowing ammonium polyphosphate of the general formulaH.sub.(n-m)+2 (NH.sub.4).sub.m P.sub.n O.sub.3n+1in which n stands for a whole number with an average value of about 20 to 800 and the ratio of m/n is about 1, and(b) about 0.5 to 50 weight % of a cured water-insoluble artificial resin encapsulating the individual particles of the flame-retarding agent or ammonium polyphosphate.The disclosure also relates to difficulty flammable boards veneered with wood or a laminate.

Abstract: A system is described for processing an entire tree into wood fiber material for molding the constituent wood elements into custom molded wood products. A delimber removes limbs and leaves from the trunk, a debarker removes bark from the trunk of the delimbed tree, and a splitter separating sequence is constructed and arranged for separating the debarked trunk into elongate pieces of substantially equal cross-sectional area. A graduated roller mill having a sequence of pairs of compressor rollers with the rollers of each pair spaced successively closer together receives the elongate pieces of wood and extrudes and delivers thin sheets of wood at the output end. Liquid squeezed from the wood sheets is collected and separated into resins and water. A shredder shreds and fragments the wood sheet wood fibers into a loosely bonded mat of substantially separate striated wood fibers. The mat is cut or chopped into wood fibers of substantially uniform length.

Abstract: N,N',N"-tris-(2-hydroxyethyl)-melamine, if required, as a mixture with N-mono- and N,N'-bis-(2-hydroxyethyl)-melamine, is prepared by reacting melamine with ethanolamine in the presence of an acidic catalyst by a method in which the reaction is carried out at from 120.degree. to 250.degree. C. using an excess of ethanolamine, and the molar ratio of free ethanolamine to the sum of free and converted melamine is not permitted to fall below 4:1 during the entire reaction time, and the stated (2-hydroxyethyl)-melamines are used as modifiers in the prepartion of aminoplast resins which are suitable for laminating surfaces.

Abstract: A fire retardant composition in a stable liquid form comprises the reaction product of an aqueous aldehyde, preferably formaldehyde, solution, at least one alcohol solvent, an alkanolamine, an organic catalyst, ammonium hydroxide, urea and an aqueous phosphoric acid solution. The aldehyde and urea are included in an approximately 1:1 weight ratio. A method of forming the reaction product comprises adding urea to a mixture of aldehyde, alcohol, alkanolamine, organic catalyst and ammonium hydroxide, and heating the resultant mixture to at least 150.degree. F.

Abstract: Wood surfaces are bonded together by heating and pressing with a bonding composition containing, on a bonding agent solids basis, from 10-70% of one or more sugars and from 90-30% of an aminoplast, and the bonding composition being used in an amount equal to the amount of straight condensation resin which would normally be used, i.e. the sugar replaces a quantity of condensation resin normally used thereby reducing the total quantity of condensation resin, thereby reducing cost and formaldehyde emissions and without any disadvantages.

Abstract: A composite wood product, such as waferboard, is treated during manufacture with preservative chemicals to improve resistance to decay and insect organisms. The process avoids having to treat a finished product and is not limited to only surface protection. Molten slack wax is first applied to wood particles having a moisture content not greater than about 10%, the wax coated wood particles are then sprayed with an ammoniacal copper arsenate solution having a concentration of at least about 11% followed by blending with adhesive resin and forming a composite wood product.

Abstract: A waferboard panel is made from long wafers to have the same strength properties as plywood. The panel comprises at least three layers of wood wafers having an initial aggregate specific gravity, less than about 0.6 oven dry weight with volume at 12% moisture content, the panel having face layers on outside surfaces and at least one core layer. The wafers in the face layers have a mean orientation not greater than about 10.degree., and lengths of at least about 6 inches, preferably 12 inches. Average widths of the wafers in the face layers are in the range of about 0.3 to 2.0 inches and the panel has an oven dry wood density in the range of about 28 to 45 lbs. per cu. ft. with an MOR to density ratio of at least about 120 and an MOE (M) to density ratio of at least about 40.

Abstract: A method of manufacturing a lignosulfonate-phenol-formaldehyde resin includes heating a mixture of phenol, formaldehyde, lignosulfonate and alkali at a temperature of 60.degree. C. to 100.degree. C. and a pH of 8-13. The lignosulfonate comprises about 5 to about 80 percent of the total weight of phenol, formaldehyde and lignosulfonate and the lignosulfonate is mixed with said phenol and formaldehyde before substantial reaction between said phenol and said formaldehyde. Also disclosed are fibrous articles manufactured using this resin as a binder, such as fiberboards, particle board, plywood, oriented strand board, and waferboard.

Abstract: Fire retardant compositions in the form of a powder are produced from the following components:______________________________________ Component Parts by Weight ______________________________________ Aldehyde 70-140 Ammonium phosphate 50-250 Ammonium, alkali metal or 50-250 alkaline earth metal compound or salt Urea reactant 70-190 Hydroxy reactant 20-60 Phosphoric acid 150-250 ______________________________________Also provided are retardant compositions containing the powder and methods for treating substrates, such as paper or wood, as well as cotton, wool, and synthetic textiles to impart fire retardant properties thereto.

Abstract: A process for bonding lignocellulose raw materials using an isocyanate group-containing urethane-modified diphenylmethane diisocyanate mixture having a viscosity of 120 to 1000 mPas at 25.degree. C. and an isocyanate content of 15 to 33.6 percent by weight which is obtained by reacting a diphenylmethane diisocyanate mixture containing 10 to 75 percent by weight of 2,4'-diphenylmethane diisocyanate with 0.05 to 0.5 hydroxyl equivalents of a polyol per equivalent isocyanate group.

Abstract: A melamine-urea-formaldehyde resin characterized by a low rate of formaldehyde emission when cured. Made by a process where the initial reaction mixture has an F/U molar ratio of from about 3:1 to about 1:1, and undergoes a methylolation reaction at an alkaline pH. Preferably at least some of the melamine is present in the initial reaction mixture. The subsequent condensation is at a substantially neutral pH. Has a final F/U molar ratio of 1.3:1 to 0.9:1, a final F/Ueq molar ratio of 1.3:1 to 0.7:1, and a melamine content of from 0.15% to 40% by weight, dry solids basis. Useful for adhesive purposes, particularly as a particleboard binder characterized by low emission rate.

Abstract: A laminated wood coupling arrangement for fabricating unitary laminated wood joints. Two sets of multiple layers of thin wood strips placed at a 90.degree. angle to each other overlap ends in alternating layers. Glue placed between all adjacent surfaces retains the laminate together. The bottom layer has two strips. One strip butts against the end of the side of the other strip. The second layer above also has two strips with one crossing over the butt joint of the first layer. The other strip in the second layer butts against the end of the side of the cross over strip. Additional layers may be added in this alternating arrangement to achieve any desired strength or aesthetic appearance.

Abstract: Modified aminoplast resin comprising:(a) 60 to 99.5% by weight of an aminoplast precondensate which has been etherified with a lower alkanol to an extent not exceeding 10% and(b) 0.5 to 40% by weight of a modifying agent which comprises a mixture of (i) a water-soluble polyester prepared from carboxylic acids with at least one carboxyl and dihydric or polyhydric alcohols, and (ii) sufficient free diol or polyol whereby the mixture has a ratio of the sum of free and esterified hydroxyls of 0.8 to 4.5 moles for each mole of the sum of free and esterified carboxyls which resins are useful in impregnating webs for producing laminates and panels of wood-based materials.

Abstract: A method for producing board materials of cellulose containing components using formaldehyde-based curable glues. By treatment of at least one part of the components at a low moisture content with a formaldehyde absorbing agent the board materials obtained after pressing get a low content of free formaldehyde and very good strength properties. The moisture content of the components at the treatment is lower than 12 percent by weight. the formaldehyde absorbing agent is preferably urea.

Abstract: A modified phenol-formaldehyde binding resin is particularly useful in the formation of man-made boards including bonded fibers, fibrous particles, and a plurality of uniformly, or randomly shaped pieces, masses or sheets bonded together with the modified phenol-formaldehyde binding resin. The resin binder is especially adapted to bonding wood fibers and particles, comprising the condensation product of a phenol, formaldehyde and a water-soluble carbohydrate-phenol complex from steam digestion of wood chips, and the production thereof. Various objects can be manufactured using these resins, such as particle objects and objects or sheet materials made by bonding together a plurality of uniformly or randomly shaped masses, for example, fiberboards such as hardboard and insulation board; particle board; plywood; oriented strand board; and waferboard.

Abstract: An improved method for the preparation of particleboard wherein a cellulose-containing particulate material is provided with a urea formaldehyde resin bonding agent and thereafter shaped and hardened at an elevated temperature and pressure. The bonding agent used is a urea-formaldehyde resin solution additionally containing melamine in an amount of 1.0 and 10 percent by weight, relative to the total amount of resin solids. The molar ratio of formaldehyde to mole equivalents of amino groups in the bonding agent is in the range of between 0.500:1 and 0.575:1.

Abstract: Tree foliage extracts, their extraction processes, and the use of such extracts in formulating resins suitable for use in plywood adhesives and as wood bonding agents.

Abstract: A method and particle board composition which employs urea formaldehyde resin adhesive, but which is formaldehyde suppressed by adding to the formaldehyde resin, a small but suppression effective amount of a weak acid and calcium metal silicate.

Abstract: A panel suitable as a bowling lane surface comprising a melamine impregnated protective layer bonded under heat and pressure to a hardboard substrate. The melamine impregnated protective layer is comprised of one or more melamine resin impregnated decorative fibrous print sheets. The surface of the bowling lane so produced is characterized by a falling ball impact resistance of at least 60 inches, a wear rate of between about 0.02 and 0.05 and a Taber abrasion resistance at least about 400 cycles.

Abstract: Granular sorbent material comprising a granular high surface area support impregnated with a water soluble, essentially non-volatile primary or secondary amine with equivalent weight less than about 400 and bearing either zero or two carbonyl substituents attached directly to the amino nitrogen atom is disclosed. The resulting material can be used as the filtration media in respirators, powered air purifiers, room air purifiers, ventilation filters, exhaust filters, process gas filters and the like to reduce the formaldehyde content of air.

Abstract: This application discloses a phenol-formaldehyde binding resin formed from phenol and formaldehyde in mole ratio of one mole of phenol to 2 to 3 moles of formaldehyde, the resin being modified by replacing from 5% to 50% of the phenol by an equivalent amount of a concentrated aqueous complex of phenolic and carbohydrate components from the process water from the steam digestion of wood chips without chemical addition, said resin being formed by heating said mixture of phenol, formaldehyde and aqueous complex with aqueous alkali to a temperature not exceeding about 100.degree. C. until a resin having a Brookfield viscosity of at least 35 centipoises is produced, all weights being determined on a dry basis; and a method of producing said resin by reacting a concentrated aqueous extract obtained from the steam digestion of wood chips with phenol and formaldehyde under alkaline conditions at a temperature not exceeding about 100.degree. C.

Abstract: Compositions of matter having properties that make them strong adhesives to various substrates and especially for extrusion adhesion to various polar substrates. These compositions comprise blends of a graft copolymer of a polyethylene backbone grafted with at least one grafting monomer comprising one or more polymerizable ethylenically unsaturated carboxylic acids or the anhydrides of such acids blended with a blending resin that is a mixture of one or more high density polyethylenes and one or more polypropylenes. The disclosure also includes composite structures and their method of making comprising one or more substrates and a blend of the above as the adhesive in contact with and united with the substrate or substrates.

Abstract: Substitute lumber pieces having strengths and densities substantially equivalent to lumber are cut from single layer panels of over about 1 and normally less than 4 inches thickness made from wood wafers. The wafers are oriented with their lengths having a mean deviation to the longitudinal length of the panel measured in the major plane of the panel in the range of 0 to 10 degrees and a mean deviation measured in a minimum longitudinal plane perpendicular to the major plane from 0 to about 5 degrees and have an average effective length of at least 8 inches (200 mm), and preferably an average thickness less than 0.15 inches (4 mm) and a width of at least 0.25 inches (6 mm). Lumber is made by cutting the panel longitudinally. Preferably the panels are formed to have a substantially uniform density profile throughout their thicknesses.