Cr-base Component Patents (Class 428/666)
  • Patent number: 7601431
    Abstract: In one embodiment, a coated turbine article comprising a uniform enhanced coating on at least a portion of the turbine article, wherein the enhanced coating comprises a coating material and a structural enhancer, wherein the structural enhancer is selected from the group consisting of oxide, carbide, nitride, intermetallic material, and combinations comprising at least one of the foregoing, wherein the structural enhancer has an average particle size, as measured along a major axis, of about 0.01 ?m to about 100 ?m.
    Type: Grant
    Filed: November 21, 2005
    Date of Patent: October 13, 2009
    Assignee: General Electric Company
    Inventors: Vinod Kumar Pareek, David A. Helmick
  • Patent number: 7585572
    Abstract: A ball stud having a ball at one end of a rod-shaped stud. The ball stud comprises: a metal plating film formed on the surface of the stud; and a trivalent chromate film continuously formed over both the surface of the metal plating film formed on the stud and the surface of the ball, whereby rust is inhibited in the boundary of the metal plating film. An externally threaded portion is also coated, if formed in the ball stud, on its surface with the metal plating film and the trivalent chromate film.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: September 8, 2009
    Assignee: Kyoritsu Seiki Co., Ltd.
    Inventor: Hirotaka Hattori
  • Patent number: 7556866
    Abstract: Vapor turbine operating with geothermal vapors containing corrosive agents such as chlorides and/or sulfides in particular. The turbine comprises a series of sealing laminas made of a nickel alloy containing a quantity of nickel ranging from 54% to 58% by weight to avoid the washing of the geothermal vapors, maintaining a high useful life of the series of sealing laminas and vapor turbine.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: July 7, 2009
    Assignee: Nuovo Pignone S.p.A.
    Inventors: Carlo Cortese, Eugenio Giorni, Paolo Bendinelli, Marco De Iaco, Vincenzo Vecchiarino
  • Patent number: 7553555
    Abstract: Vapor turbine operating with geothermal vapors containing corrosive agents such as chlorides and/or sulfides in particular. The turbine comprises a series of stator blades made of a nickel alloy containing a quantity of nickel ranging from 54% to 58% by weight to avoid the washing of the geothermal vapors, maintaining a high useful life of the series of stator blades and vapor turbine.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: June 30, 2009
    Assignee: Nuovo Pignone S.p.A.
    Inventors: Carlo Cortese, Paolo Bendinelli, Vincenzo Vecchiarino, Maria Pilar Amoroso
  • Patent number: 7514157
    Abstract: A reaction control turbine blade is formed by applying a reaction control material to the surface of an Ni-base superalloy before applying aluminum diffusion coating to the Ni-base superalloy. The reaction control material is Co, Cr or Ru, or an alloy of which main component is selected from a group consisting of Co, Cr, Ru. Thereby, it is possible to enhance the oxidation resistance of the Ni-base superalloy, and to control formation of a secondary reaction zone.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: April 7, 2009
    Assignee: IHI Corporation
    Inventors: Yasuhiro Aoki, Akihiro Sato
  • Patent number: 7498087
    Abstract: Vapor turbine operating with geothermal vapors containing corrosive agents such as chlorides and/or sulfides in particular. The turbine comprises a series of rotor blades made of a nickel alloy containing a quantity of nickel ranging from 55% to 59% by weight to avoid the washing of the geothermal vapors, maintaining a high useful life of the series of rotor blades and vapor turbine.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: March 3, 2009
    Assignee: Nuovo Pignone S.p.A.
    Inventors: Carlo Cortese, Paolo Bendinelli, Marco De Iaco, Lorenzo Cosi, Marco Anselmi
  • Publication number: 20080274373
    Abstract: An engine part according to the present invention includes: a metal substrate; a chromium plating layer covering at least a portion of a surface of the metal substrate, the chromium plating layer being formed from a trivalent chromium plating solution. The chromium plating layer includes a boron content of no less than 0.05 mass % and no more than 0.3 mass %, and the chromium plating layer has a thickness or 0.7 ?m or less.
    Type: Application
    Filed: October 17, 2005
    Publication date: November 6, 2008
    Applicant: YAMAHA HATSUDOKI KABUSHIKI KAISHA
    Inventor: Naohisa Takahashi
  • Publication number: 20080268281
    Abstract: The invented shield components are used for a plasma processing system to adhere deposition materials or process residuals during wafer processing, thus preventing excessive wafer contamination, even when exposed to high temperatures. One embodiment of the invented shields consists of a reaction barrier layer to separate the underlying substrate from the overlying spray coating to prevent solid-state chemical reaction between the substrate and the coating. Another embodiment of the invented shields consists of a substrate and a coating with a substrate-coating combination chosen to allow no new solid-state phase to form at the interface. The invented shields have well-bonded materials interfaces that preserve thermal and mechanical stability under high temperature conditions in a plasma processing system for the containment of deposition contaminates.
    Type: Application
    Filed: April 27, 2007
    Publication date: October 30, 2008
    Inventors: Quan Bai, Patrick Rymer, Jose Gonzalez, Gary Groshong
  • Patent number: 7422797
    Abstract: In forming a plating layer for a sliding portion, which comprises Cr that is electrolytically-deposited in a plating bath containing Cr, the plating bath contains organic sulfonic acid. Accordingly, micro-cracks are formed at the plating layer. The plating layer for a sliding portion has the superior low friction and lubricating property.
    Type: Grant
    Filed: December 19, 2005
    Date of Patent: September 9, 2008
    Assignee: Mazda Motor Corporation
    Inventors: Yoshio Tanita, Shinji Kadoshima, Satoshi Nanba
  • Publication number: 20080171217
    Abstract: According to one aspect, an interventional medical device includes a first wire disposed at a distal end and made of an alloy containing Ti and a transition metal other than Ti and Cr, and a second wire disposed at a proximal end of the first wire and made of an alloy containing Cr and a transition metal other than Cr and Ti. The device may include the first wire and the second wire being brazed to each other by a brazing material. The brazing material contains a metal whose ionization tendency is more basic than Ti and Cr. The brazing material is preferably an Ag—Mg alloy or an Ni—Mg alloy, and preferably has a composition near the eutectic point.
    Type: Application
    Filed: September 27, 2007
    Publication date: July 17, 2008
    Inventor: Katsuro Mishima
  • Patent number: 7396597
    Abstract: A stainless steel pipe includes a base metal containing 20-35 mass % of Cr, and a Cr-depleted zone is formed in the surface region of the pipe. The Cr concentration in the Cr-depleted zone is at least 10%, and the thickness of the Cr-depleted zone is at most 20 micrometers. A Cr-based oxide scale layer having a Cr content of at least 50% and a thickness of 0.1-15 micrometers may be provided on the outer side of the Cr-depleted zone. An Si-based oxide scale layer with an Si content of at least 50% may be provided between the Cr-based oxide scale layer and the Cr-depleted zone. The pipe is particularly suitable for use in petroleum refineries or petrochemical plants, such as for use as a pipe of a cracking furnace of an ethylene plant.
    Type: Grant
    Filed: July 16, 2004
    Date of Patent: July 8, 2008
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Yoshitaka Nishiyama, Yoshimi Yamadera
  • Patent number: 7364801
    Abstract: An environmental coating suitable for use on turbine components, such as turbine disks and turbine seal elements, formed of alloys susceptible to oxidation and hot corrosion. The environmental coating is predominantly a solid solution phase of nickel, iron, and/or cobalt. The coating contains about 18 weight percent to about 60 weight percent chromium, which ensures the formation of a protective chromia (Cr2O3) scale while also exhibiting high ductility. The coating may further contain up to about 8 weight percent aluminum, as well as other optional additives. The environmental coating is preferably sufficiently thin and ductile to enable compressive stresses to be induced in the underlying substrate through shot peening without cracking the coating.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: April 29, 2008
    Assignee: General Electric Company
    Inventors: Brian Thomas Hazel, Michael James Weimer
  • Publication number: 20080081214
    Abstract: A diffusion barrier alloy film has a diffusion barrier layer which has more excellent diffusion barrier properties than an Re—Cr alloy film, and can stand usage at higher temperatures (e.g., 1150° C. or higher). The diffusion barrier layer 18 is made of an Re—W alloy ? phase containing 12.5 to 56.5% of. W in terms of atomic composition and the remainder of Re excluding unavoidable impurities. A metal base 10 has a surface coated with a diffusion barrier layer 18. If required, the diffusion barrier layer 18 has a surface coated with a diffusion alloy layer 20 containing 10% or greater and less than 50% of Al, Cr, or Si in terms of atomic composition, providing a high-temperature apparatus member.
    Type: Application
    Filed: January 14, 2005
    Publication date: April 3, 2008
    Inventors: Toshio Narita, Hiroshi Yakuwa
  • Patent number: 7318963
    Abstract: A composite chromium plating film containing hard particles in network-shaped microcracks, a surface-occupying ratio of the microcracks being 10 to 20% by area, a distribution density of the microcracks being 1,200 to 2,500/cm, and the amount of the above hard particles being 1 to 15% by mass per 100% by mass of the above entire plating film. This composite chromium plating film has excellent wear resistance and scuffing resistance with small attacking ability to a mating member.
    Type: Grant
    Filed: January 28, 2005
    Date of Patent: January 15, 2008
    Assignee: Kabushiki Kaisha Riken
    Inventors: Takeo Oshimi, Kiyotaka Oku, Katsumi Takiguchi
  • Publication number: 20070287027
    Abstract: A method is provided for depositing a hard wear resistant surface onto a porous or non-porous base material of a medical implant. The wear resistant surface of the medical implant device may be formed by a Laser Based Metal Deposition (LBMD) method such as Laser Engineered Net Shaping (LENS). The wear resistant surface may include a blend of multiple different biocompatible materials. Further, functionally graded layers of biocompatible materials may be used to form the wear resistant surface. Usage of a porous material for the base may promote bone ingrowth to allow the implant to fuse strongly with the bone of a host patient. The hard wear resistant surface provides device longevity, particularly when applied to bearing surfaces such as artificial joint bearing surfaces or a dental implant bearing surfaces. An antimicrobial material such as silver may be deposited in combination with a metal to form an antimicrobial surface deposit.
    Type: Application
    Filed: January 17, 2007
    Publication date: December 13, 2007
    Applicant: MedicineLodge, Inc.
    Inventors: Daniel F. Justin, Brent E. Stucker, Durga Janaki Ram Gabbita, David William Britt
  • Patent number: 7291401
    Abstract: A steel material that has on its surface a non-hexavalent-chromium type corrosion-resistant coating film formed by a composite of a metal layer and a resin layer. The steel material having or not having a copper layer is formed with 1) a Zn and/or Zn-based alloy layer, 2) a Zn/Ni alloy layer which is on this Zn and/or Zn-based alloy layer, 3) a de-Zn layer which is on the Zn/Ni alloy layer and is obtained by chemically treating the surface of the Zn/Ni alloy layer, and 4) at least one resin covering layer which is on this de-Zn layer, which are successively formed to make a corrosion-resistant coating film, the corrosion-resistant coating film, which is superior in adhesion between the metal layer and resin layer, being obtained by way of taking into account the use of a trivalent chromium type chromate layer instead of a hexavalent chromium type chromate layer (which is a substance that places a burden on the environment).
    Type: Grant
    Filed: September 4, 2002
    Date of Patent: November 6, 2007
    Assignee: USUI Kokusai Sangyo Kabushiki Kaisha, Ltd.
    Inventors: Kazuo Suzuki, Iyoshi Watanabe
  • Patent number: 7285337
    Abstract: A composite resistive to high-temperature corrosion and abnormal oxidization, maintains original excellent high-temperature characteristics of Ni alloys over a long period of time, and suitable for applications in a high-temperature such as gas turbines, jet engines, and elements for exhaust-gas systems. A heat-resistant Ni-alloy composite has excellent high-temperature oxidation resistance, including a Ni-alloy substrate that has been subjected to an Al-diffusing treatment. The surface coat has a multi-layer structure including an inner layer composed of an ?-Cr phase and an outer layer composed of a ? phase (Ni—Al—Cr) and a ?? phase (Ni3Al(Cr)) on the substrate surface. The Al content in the outer layer is at least 20 atomic percent. The ?-Cr phase functions as a diffusion-barrier layer. The outer layer retains and secures a high Al content required for self-regeneration of a defective portion of the Al2O3 layer damaged in an operating condition.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: October 23, 2007
    Assignee: Japan Science and Technology Agency
    Inventors: Toshio Narita, Daisuke Yoshida
  • Patent number: 7267889
    Abstract: The present invention provides a sprayable composition comprising a ceramic particulate including albite, illite, and quart, and a metallic composition, including nickel, chromium, iron, and silicon. The sprayable composition may be a composite particle, a blend, or a cored wire. The present invention further provides an abradable coating formed on a metal substrate according to a method comprising the step of depositing the abradable coating on the metal substrate by thermal spraying of a sprayable composition comprising a ceramic particulate including albite, illite, and quartz, and a metallic composition, including nickel, chromium, iron and silicon. The sprayable composition may be a composite particle, a blend, or a cored wire. The abradable coating may be applied to a metal substrate such as steel, nickel-based alloys, and titanium.
    Type: Grant
    Filed: October 1, 2002
    Date of Patent: September 11, 2007
    Assignee: Sulzer Metco (Canada) Inc.
    Inventors: Karel Hajmrle, Anthony Peter Chilkowich
  • Patent number: 7250224
    Abstract: A coating system and coating method for damping vibration in an airfoil of a rotating component of a turbomachine. The coating system includes a metallic coating on a surface of the airfoil, and a ceramic coating overlying the metallic coating. The metallic coating contains metallic particles dispersed in a matrix having a metallic and/or intermetallic composition. The metallic particles are more ductile than the matrix, and have a composition containing silver and optionally tin. The method involves ion plasma cleaning the surface of the airfoil before depositing the metallic coating and then the ceramic coating.
    Type: Grant
    Filed: October 12, 2004
    Date of Patent: July 31, 2007
    Assignee: General Electric Company
    Inventors: Ramgopal Darolia, Matthew Mark Weaver, Dennis Martin Corbly, Boris Alexeevich Movchan, Anatolii Ivanovich Ustinov
  • Patent number: 7192655
    Abstract: Disclosed is a ReCrNi alloy coating for diffusion barrier, such as a high-temperature equipment member, consisting essentially of a ternary alloy and having, except for inevitable impurities, an atomic composition of 20% to 80% Re, an atomic composition of 20% to 60% Cr, and an atomic composition of 5% to 40% Ni. Even if the alloy coating for diffusion barrier includes a diffusion layer containing at least one of the group consisting of Al, Si and Cr, a desired alloy composition of the alloy coating for diffusion barrier can be assured by a surface coating process and diffused components from the substrate while substantially preventing the diffusion of the elements of the diffusion layer during a homogenizing heat treatment. The alloy coating for diffusion barrier may include a Re-containing-alloy stress relief layer inserted between the film and the substrate.
    Type: Grant
    Filed: September 13, 2002
    Date of Patent: March 20, 2007
    Assignees: Japan Science and Technology Agency, Ebara Corporation
    Inventors: Toshio Narita, Shigenari Hayashi, Takayuki Yoshioka, Hiroshi Yakuwa
  • Patent number: 7150921
    Abstract: A bi-layer bond coating for use on metal alloy components exposed to hostile thermal and chemical environment, such as a gas turbine engine, and the method for applying such coatings. The preferred coatings include a bi-layer bond coat applied to the metal substrate using high velocity oxy-fuel (HVOF) thermal spraying. Bi-layer bond coatings in accordance with the invention consist of a dense first inner layer (such as iron, nickel or cobalt-based alloys) that provides oxidation protection to the metal substrate, and a second outer layer having controlled porosity that tends to promote roughness, mechanical compliance, and promotes adherence of the thermal barrier coating (TBC). Preferably, the outer, less dense layer of the bi-layer bond coat is formed from a mixture of metallic powder and polyester to adjust and control the porosity, but without sacrificing mechanical compliance.
    Type: Grant
    Filed: May 18, 2004
    Date of Patent: December 19, 2006
    Assignee: General Electric Company
    Inventors: Warren Arthur Nelson, Jon Conrad Schaeffer, Sharon Trombly Swede, David Vincent Bucci, Joseph Debarro, Terry Howard Strout, Tyrone Robert Mortensen
  • Patent number: 7147932
    Abstract: A coated steel strip product with a dense and hard abrasion resistant coating on one side or both sides of said strip. The thickness of said coating is in total maximally 25 ?m, the hardness of said coating is at least 600 HV and the tensile strength of the steel strip substrate is at least 1200 MPa. The coating is preferably applied by electron beam evaporation and the coating may be, e.g., of Al2O3. The coated metal strip is useful for the manufacturing of doctor and coater blades for paper and printing industry.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: December 12, 2006
    Assignee: Sandvik Intellectual Property AB
    Inventors: Anna Hultin Stigenberg, Mikael Schuisky
  • Patent number: 7147931
    Abstract: A coated steel strip product with a dense and hard abrasion resistant coating on one side or both sides of said strip substrate is provided. The thickness of said coating is in total maximally 25 ?m, the hardness of said coating is at least 600 HV and the tensile strength of the steel strip substrate is at least 1200 MPa. The coating is preferably applied by electron beam evaporation and the coating may be, e.g., of Al2O3. The coated metal strip is suitable for shaving equipment, medical instruments, utility and industrial knives as well as saw applications.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: December 12, 2006
    Assignee: Sandvik Intellectual Property AB
    Inventors: Anna Hultin Stigenberg, Mikael Schuisky
  • Patent number: 7108923
    Abstract: A copper foil for a printed circuit board has a rust preventing layer formed by a trivalent chromium chemical conversion treatment on a surface of the copper foil that the copper foil is bonded to a base material for the printed circuit board. T copper foil is of copper or copper alloy, and the rust preventing layer contains 0.5 to 2.5 ?g/cm2 of chromium converted into metallic chromium.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: September 19, 2006
    Assignee: Hitachi Cable, Ltd.
    Inventors: Yasuyuki Ito, Katsuyuki Matsumoto, Kenji Yokomizo, Yasuhiro Kusano, Shinichiro Shimizu, Muneo Kodaira, Katsumi Nomura
  • Patent number: 7063898
    Abstract: A method including forming a first layer comprising a chemical conversion coating on a metal surface; and forming a second layer on the first layer through a sol gel process. An apparatus including a metal component having at least one surface; a first layer comprising a chemical conversion coating on the at least one surface; and a second layer derived from a sol gel composition on the first layer.
    Type: Grant
    Filed: January 30, 2004
    Date of Patent: June 20, 2006
    Assignee: Allfast Fastening Systems, Inc.
    Inventor: Robert J. Dees
  • Patent number: 7060366
    Abstract: A coated article has a metallic substrate with a substrate composition, and a metallic coating overlying and contacting the metallic substrate. The metallic coating has a metallic-coating composition different from the substrate composition. A protective coating overlies and contacts the metallic coating. The protective coating includes a chromium aluminide layer overlying and contacting the metallic coating, and optionally a thermal barrier coating overlying and contacting the chromium aluminide layer. This structure may be used to restore a key dimension of an article that has previously been in service and to protect the article as well.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: June 13, 2006
    Assignee: General Electric Company
    Inventors: Bhupendra Kumar Gupta, Wayne Ray Grady, Lyle Timothy Rasch, Thomas Joseph Kelly, Nripendra Nath Das
  • Patent number: 7049007
    Abstract: A peelable composite foil includes a metallic carrier foil, a first barrier layer on one side of the metallic carrier and a second metallic layer on the first barrier layer. The second metallic layer includes a combination of a metal selected from the group including zinc, molybdenum, antimony and tungsten, and an electrodeposited, ultra-thin metal foil on the second metallic layer.
    Type: Grant
    Filed: July 10, 2002
    Date of Patent: May 23, 2006
    Assignee: Circuit Foil Luxembourg Sarl
    Inventors: Raymond Gales, Michel Streel, Rene Lanners
  • Patent number: 7026057
    Abstract: A new article of manufacture, for example a faucet or other article of hardware, has a specified decorative color, and is resistant to corrosion, abrasion and attack by chemicals. The article includes a substrate, one or more corrosion resistant layers applied to the substrate, a thin transition layer having a composition that varies systematically from a first composition to a second composition and in which the first composition has, at least in part, the function of corrosion protection, and in which the second composition determines the visible color or that portion of the substrate to which the transition layer is applied.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: April 11, 2006
    Assignee: Moen Incorporated
    Inventors: James G. Sheek, Jarek Grembowicz, Inho Song, Timothy J. O'Brien
  • Patent number: 7001670
    Abstract: The invention relates to a wear protection layer for piston rings in internal combustion engines consisting essentially of chromium carbides, wolfram carbide, chromium and nickel. The wear protection layer is formed from a mixture of powders in which the first powder consists of at least the alloy components chromium carbide, chromium and nickel, in the form of an agglomerated and sintered powder, and which has not been subjected to any secondary heat treatment that would make the powder brittle, such as plasma refinement, the carbides in the powder having an average diameter of essentially not more than 3 ?m. A second powder, also in the form of an agglomerated and sintered powder, contains wolfram carbide and is applied to at least one peripheral surface of the piston rings by thermal injection, so that two distinctive coating areas are produced in the wear protection layer. A first area, predominantly rich in chromium, and a second area, mainly rich in wolfram carbide are formed.
    Type: Grant
    Filed: November 17, 2001
    Date of Patent: February 21, 2006
    Assignee: Federal-Mogul Burscheid GmbH
    Inventor: Christian Herbst-Dederichs
  • Patent number: 7001672
    Abstract: A method of depositing a hard wear resistant surface onto a porous or non-porous base material of a medical implant. The medical implant device formed by a Laser Based Metal Deposition (LBMD) method. The porous material of the base promotes bone ingrowth allowing the implant to fuse strongly with the bone of a host patient. The hard wear resistant surface provides device longevity when applied to bearing surfaces such as artificial joint bearing surface or a dental implant bearing surface.
    Type: Grant
    Filed: March 26, 2004
    Date of Patent: February 21, 2006
    Assignee: Medicine Lodge, Inc.
    Inventors: Daniel F. Justin, Brent E. Stucker
  • Patent number: 6994920
    Abstract: A fusion welding method is provided for fusion welding at juxtaposed interface surfaces a first member, for example made of a first metal based on at least one of Ru, Rh, Pd, and Pt, with a second member made of a second metal, for example a high temperature alloy based on at least one of Fe, Co, and Ni, including at least one identified element, for example Al, that can form a continuous layer of a brittle intermetallic compound with the first metal that is free of such element. With the interface surfaces disposed in contact, energy is generated at the interface surfaces in a combination of an amount and for a first time selected to be sufficient to heat the interface surfaces to a fusion welding temperature. However, the first time is less than a second time that enables formation at the fusion welding temperature of the continuous layer of the brittle intermetallic compound at the interface surfaces.
    Type: Grant
    Filed: October 31, 2003
    Date of Patent: February 7, 2006
    Assignee: General Electric Company
    Inventor: Gary Edward Trewiler
  • Patent number: 6989087
    Abstract: A method of forming a surface finish of trivalent chromium on metal or plastics substrates by electrodeposition from an aqueous plating solution of trivalent chromium ions in which the trivalent chromium is deposited on a layer of silver or silver alloy whereby the color and/or corrosion resistance of the trivalent chromium is comparable to surface finishes of hexavalent chromium. The invention avoids the health and safety risks associated with the electrodeposition of hexavalent chromium surface finishes.
    Type: Grant
    Filed: December 10, 2001
    Date of Patent: January 24, 2006
    Assignee: Kohler Mira Ltd.
    Inventors: Paul Averell William Lansdell, John Peter George Farr
  • Patent number: 6956233
    Abstract: In plating on an Si substrate, it has been strongly demanded to apply a treatment for providing an excellent adhesion so as to resist a post-processing such as polishing and for facilitating plating. Then, provided is a plated substrate adapted for hard disk medium comprising an Si single crystal; an amorphous layer on the substrate, the amorphous layer having thickness of 2 to 200 nm and containing Si and one or more metals selected from a group consisting of Ni, Cu and Ag; a multicrystal layer on the amorphous layer, the multicrystal layer having thickness of 5 to 1000 nm and containing Si and one or more metals selected from a group consisting of Ni, Cu and Ag.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: October 18, 2005
    Assignee: Sin-Etsu Chemical Co., Ltd.
    Inventors: Toshihiro Tsumori, Masatoshi Ishii, Naofumi Shinya, Yu Hamaguchi, Yukimi Jyoko
  • Patent number: 6924045
    Abstract: It is disclosed a bond or overlay MCrAlY-coating for the use within a high temperature environment for the protection of the base alloy of turbine blades and vanes. The MCrAlY-coating having a ? or ?/??-structure comprises a dispersion of ?-NiAl and/or ?/?-MCrAlY particles. This provides a reservoir of aluminum reservoir to coatings wherein the reservoir replenish the aluminum lost due to oxidation and interdiffusion during service. The ?-NiAl and/or ?/?-MCrAlY is the aluminum reservoir and is applied by mixing appropriate powders with ? or ?/?? powders.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: August 2, 2005
    Assignee: ALSTOM Technology LTD
    Inventors: Abdus S. Khan, Maxime Konter, Robert Schmees
  • Patent number: 6923625
    Abstract: A method for preventing contamination, oxidation and gas absorption of reactive materials, and articles formed thereby. The method generally entails depositing a first layer of a reactive material and a second layer of a substantially nonreactive material so that the second layer protects the first layer from a surrounding atmosphere. For example, the first and second layers may be deposited to form a film on a surface within a chamber that is desired to be maintained in a vacuum during use of the article. The second layer is sufficiently thin such that appropriately heating the first and second layers causes the reactive material of the first layer to become interdiffused with the nonreactive material of the second layer, to the extent that at least a portion of the reactive material is able to react and getter gases from the surrounding atmosphere.
    Type: Grant
    Filed: January 7, 2003
    Date of Patent: August 2, 2005
    Assignee: Integrated Sensing Systems, Inc.
    Inventor: Douglas Ray Sparks
  • Patent number: 6921586
    Abstract: A coating system for an article comprising a substrate formed of a metal alloy that is prone to the formation of a deleterious secondary reaction zone (SRZ) as a result of containing more than three weight percent rhenium and at least one additional refractory metal. The coating system comprises an aluminum-containing overlay coating and a diffusion barrier coating between the overlay coating and the substrate. The diffusion barrier coating consists of, in atomic percent, about 20% to about 90% ruthenium, about 2% to about 60% chromium, optionally up to about 50% aluminum, optionally up to about 20% of a platinum-group metal, and the balance at least one of nickel, cobalt, and iron and incidental impurities. The diffusion barrier coating sufficiently inhibits diffusion of aluminum from the overlay coating into the substrate, such that the substrate remains essentially free of SRZ.
    Type: Grant
    Filed: October 31, 2003
    Date of Patent: July 26, 2005
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Jeffrey Allan Pfaendtner, Christine Govern, Melvin Robert Jackson
  • Patent number: 6913837
    Abstract: A perpendicular magnetic recording medium and method thereof, includes a nonmagnetic substrate; a soft magnetic under layer; an intermediate layer; a bilayer magnetic recording layer; a protective layer; and a liquid lubricant layer. According to a following order, the soft magnetic under layer, the intermediate layer, the bilayer magnetic recording layer, the protective layer, and the liquid lubricant layer are sequentially stacked on the nonmagnetic substrate. The bilayer magnetic recording layer includes a first magnetic layer including a CoCr alloy crystalline film, and a second magnetic layer including a rare earth-transition metal alloy noncrystalline film.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: July 5, 2005
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yasushi Sakai, Hiroyuki Uwazumi, Kazuo Enomoto, Sadayuki Watanabe
  • Patent number: 6887585
    Abstract: The invention relates to a wear-resistant coating used for bearing surfaces and flanks of piston rings in internal combustion engines. The wear-resistant inventive coating is obtained by mechanically alloying powders which form a metallic matrix with hard material dispersoids and lubricant material dispersoids. The coating is then thermally applied to the workpieces, especially by means of high velocity oxygen fuel spraying (HVOF). The workpieces coated are bearing surfaces and parts of flanks pertaining to piston rings in internal combustion engines.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: May 3, 2005
    Assignee: Federal-Mogul Burscheid GmbH
    Inventor: Christian Herbst-Dederichs
  • Patent number: 6884524
    Abstract: A low cost chromide and chromide/aluminide process for moderate temperature applications. A gas turbine engine component is cleaned and coated with a layer of metal, generally chromium or chromium and aluminum, containing paint. The metal containing paint layer is heated to a first temperature for a first period of time in an air environment to volatilize the solvents in the paint. The metal containing paint layer is heated to a second temperature for a second period of time in an oxygen-free atmosphere to volatilize the solvents in the paint. The now metal layer and component are heated to a third temperature for a third period of time to interdiffuse the metal and the metal of the component. The component and diffusion layer are then cooled to ambient temperature.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: April 26, 2005
    Assignee: General Electric Company
    Inventors: John F. Ackermann, Paul V. Arszman, Andrew J. Skoog
  • Patent number: 6884520
    Abstract: A perpendicular magnetic recording medium has a nonmagnetic substrate, a nonmagnetic underlayer, a magnetic layer, a protective film, and a liquid lubrication layer sequentially laminated on the substrate. The nonmagnetic layer is composed of a metal or alloy having a hcp crystal structure. The magnetic recording layer consists of ferromagnetic crystal grains and a nonmagnetic grain boundary phase mainly composed of an oxide surrounding the grains. A seed layer of a metal or alloy having a fcc crystal structure can be provided under the nonmagnetic underlayer, and a nonmagnetic alignment control layer can be provided under the seed layer. The recording medium can provide high output and low noise by improving the alignment of the magnetic recording layer, reducing the initial growth layer in the magnetic recording layer, and minimizing the grain size of the magnetic recording layer.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: April 26, 2005
    Assignee: Fuji Electric Co., Ld.
    Inventors: Tadaaki Oikawa, Hiroyuki Uwazumi, Shunji Takenoiri, Miyabi Nakamura
  • Patent number: 6881499
    Abstract: A bonded member includes a ceramic base material and a metal member solid-phase bonded via a soldering material. An active metal is placed on a surface of the ceramic base material and the soldering material, which includes Au, is placed on the active metal, and the active metal and the soldering material are heated so as to form a precoat layer. The metal member is placed on the surface of the precoat layer via a barrier layer, which is capable of inhibiting diffusion of a metal constituting the metal member, and the precoat layer and the metal member are pressurized heated so as to be solid-phase bonded. The production method of the bonded member is also disclosed.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: April 19, 2005
    Assignee: NGK Insulators, Ltd.
    Inventors: Masayuki Shinkai, Takahiro Ishikawa, Masahiro Kida
  • Patent number: 6878459
    Abstract: A magnetic recording medium was a high normalized coercive force and superior thermal stability. The magnetic recording medium comprises a non-magnetic base material, and a ferromagnetic metal layer of cobalt based alloy formed on top of this base material with a metal underlayer disposed therebetween, and displays a coercive force Hc of at least 2000 (Oe) and an anisotropic magnetic field Hkgrain of at least 10,000 (Oe). Furthermore, magnetic recording media in which the aforementioned metal underlayer and/or the ferromagnetic metal layer are fabricated in a film fabrication chamber with an ultimate vacuum at the 10?9 Torr level are preferred. A magnetic recording medium according to the present invention can be ideally applied to hard disks, floppy disks, and magnetic tapes and the like.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: April 12, 2005
    Assignees: Anelva Corporation, Fuji Electric Co., Ltd., Showa Denko K.K.
    Inventors: Migaku Takahashi, David Djayaprawira, Kazuya Komiyama, Satoru Yoshimura
  • Patent number: 6878463
    Abstract: A low cost, durable mask for use in structuring anodically bondable glass materials and other structurable glass materials.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: April 12, 2005
    Assignee: Honeywell International, Inc.
    Inventor: Amy V. Skrobis
  • Patent number: 6875330
    Abstract: A process is provided for coating metallic workpieces with a bearing material, wherein the workpiece first receives a hard chromium plating having a pearl or columnar structure type surface. A predominantly silver layer is then galvanically deposited, which fills in and smooths the pearl or columnar structure type surface of the hard chromium plating. Optionally, additional hard chromium platings and predominantly silver-containing layers may be applied, preferably galvanically. The predominantly silver layer may advantageously contain a graphite component.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: April 5, 2005
    Assignee: Duralloy AG
    Inventor: Marco Santini
  • Patent number: 6858321
    Abstract: A corrosion resistant member has a chemical conversion treatment film with a two-layer structure formed atop a metal substrate plated with zinc or zinc alloy plating. The two-layer structure comprises a lower layer containing Cr formed on the surface of the plating and an upper layer containing SiO2.
    Type: Grant
    Filed: September 23, 2002
    Date of Patent: February 22, 2005
    Assignee: Yuken Industry Co., Ltd.
    Inventors: Nobuaki Wada, Yasuhiro Nagaya, Mitsuhiro Ito, Naruhisa Kamiya, Makoto Sakakibara
  • Patent number: 6855437
    Abstract: The subject of the invention is a layer system for the decorative coating of galvanizable work pieces. In order to have a layer system which meets strict requirements with regard to corrosion resistance and which, at the same time, has a high abrasion resistance and, in addition, provides a high degree of freedom with regard to decorative coloration, the invention proposes a layer system which is formed by galvanic deposition and comprises a base coat consisting of at least one bright layer and one discontinuous chrome layer as well as a cover coat of mechanically resistant materials deposited by the PVD process.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: February 15, 2005
    Assignee: Enthone Inc.
    Inventors: Hiltrud Tolls, Elmar Tolls
  • Patent number: 6852210
    Abstract: To provide a plating method, which enables wide industrial use of the redox system electroless plating method having excellent characteristics, and a plating bath precursor which is preferable for the plating method. The plating method comprises a process oxidizing first metal ions of a redox system of a plating bath from a lower oxidation state to a high oxidation state, and second metal ions of said redox system are reduced and deposited onto the surface of an object to be plated, wherein a process is provided in which by supplying the electrical current to the plating bath, the first metal ions are reduced from said lower oxidation state to thereby activate the plating bath. The plating bath precursor is formed stabilizing the plating bath so that reduction and deposition of the second metal ions substantially do not occur in order to improve its storing performance.
    Type: Grant
    Filed: January 7, 2002
    Date of Patent: February 8, 2005
    Assignees: Daiwa Fine Chemicals Co., Ltd., Sumitomo Electric Industries, Ltd.
    Inventors: Keigo Obata, Dong-Hyun Kim, Takao Takeuchi, Seiichiro Nakao, Shinji Inazawa, Ayao Kariya, Masatoshi Majima, Shigeyoshi Nakayama
  • Patent number: 6837980
    Abstract: Aqueous electroplating solutions and methods are provided for the codeposition of zinc and chromium. The solutions include effective amounts of zinc, chromium, and hydroxyl ions. The solutions further include an effective amount of one or more ions of alkali metals, alkaline earth metals, or a combination thereof other than sodium and potassium, to in major part balance the hydroxyl ions. A preferred alkali metal is rubidium.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: January 4, 2005
    Assignee: Olin Corporation
    Inventors: Szuchain F. Chen, Leonard R. Howell
  • Patent number: 6838190
    Abstract: A protected article includes a nickel-base superalloy substrate, an interlayer overlying the substrate, and a protective layer overlying the interlayer. The protective layer has a composition comprising at least one of rhodium, platinum, palladium, and ruthenium. In one composition, palladium is present in an amount of from about 1 to about 41 atomic percent; platinum is present in an amount of about (40+atomic percent palladium) atomic percent for palladium ranging from about 1 atomic percent to about 14 atomic percent and up to about 54 atomic percent for palladium ranging from about 15 atomic percent up to about 41 atomic percent; rhodium is present in an amount of at least about 24 atomic percent; zirconium, hafnium, titanium, and mixtures thereof are present in an amount of from zero up to about 5 atomic percent; and ruthenium is present in an amount of from zero up to about 5 atomic percent, balance impurities.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: January 4, 2005
    Assignee: General Electric Company
    Inventors: Ching-Pang Lee, Melvin Robert Jackson, Stephen Joseph Ferrigno, Gary Edward Trewiler, Mark Daniel Gorman
  • Patent number: RE39070
    Abstract: A wear resistant coating for protecting surfaces undergoing sliding contact is disclosed. The wear resistant coating is applied by high velocity oxygen-fuel (HVOF) deposition of a powdered blend of the coating constituents. The powdered blend includes a nickel-chromium alloy, chromium carbide, and molybdenum. The disclosed coating should find use as a bearing surface on piston rings, cylinder liners, and other components of a power cylinder assembly of an internal combustion engine.
    Type: Grant
    Filed: December 31, 2003
    Date of Patent: April 18, 2006
    Assignee: Dana Corporation
    Inventors: Thomas C. Stong, Thomas J. Smith, Peter J. Einberger