Active Material In Solution Patents (Class 429/105)
  • Patent number: 11955677
    Abstract: One embodiment is a redox flow battery system that includes an anolyte; a catholyte; an anolyte tank configured for holding at least a portion of the anolyte; a catholyte tank configured for holding at least a portion of the catholyte; a primary redox flow battery arrangement, and a second redox flow battery arrangement. The primary and secondary redox flow battery arrangements share the anolyte and catholyte tanks and each includes a first half-cell including a first electrode in contact with the anolyte, a second half-cell including a second electrode in contact with the catholyte, a separator separating the first half-cell from the second half-cell, an anolyte pump, and a catholyte pump. The peak power delivery capacity of the secondary redox flow battery arrangement is less than the peak power delivery capacity of the primary redox flow battery arrangement.
    Type: Grant
    Filed: June 29, 2021
    Date of Patent: April 9, 2024
    Assignee: COUGAR CREEK TECHNOLOGIES, LLC
    Inventors: Liyu Li, Qingtao Luo
  • Patent number: 11952672
    Abstract: A series of cells for use in an electrochemical device, such as an electrochemical cell or battery, that can operate in a single bulk electrolyte solution shared among the cells. Methods of producing hydrogen or both hydrogen and electricity in appreciable quantifies and in various ratios, and vehicles or other devices and applications powered by electrochemical devices comprising the series.
    Type: Grant
    Filed: September 11, 2019
    Date of Patent: April 9, 2024
    Assignee: IFBattery Inc.
    Inventor: John H. Cushman
  • Patent number: 11942808
    Abstract: The energy storage apparatus includes an energy storage device, a circuit breaker connected in series with the energy storage device, a reception unit that receives a discharge instruction to discharge remaining electric power of the energy storage device, and a management unit. The management unit executes protection processing of opening, when a state of charge of the energy storage device drops below a predetermined threshold value, the circuit breaker to protect the energy storage device from overdischarging, and protection release processing of releasing protection of the energy storage device when the discharge instruction is received by the reception unit.
    Type: Grant
    Filed: May 16, 2019
    Date of Patent: March 26, 2024
    Assignee: GS YUASA INTERNATIONAL LTD.
    Inventor: Yuki Imanaka
  • Patent number: 11926236
    Abstract: A system is provided for performing an automated power charging process for one or more electric vehicles using a processor. Included in the processor is a charge controller that calculates a capacity of a power grid system by communicating with the power grid system via a network, and a power demand level of the one or more electric vehicles to satisfy one or more mission requirements of each electric vehicle. The power demand level of the one or more electric vehicles is compared with the capacity of the power grid system. In response to the comparison, at least one charging mode is selected from an override mode and an internal combustion engine mode for performing the automated power charging process. The charge controller automatically charges the one or more electric vehicles based on the selected at least one charging mode.
    Type: Grant
    Filed: September 20, 2019
    Date of Patent: March 12, 2024
    Assignee: Cummins Inc.
    Inventors: Jennifer K. Light-Holets, Julie Furber, Thomas A. Dollmeyer, Vivek A. Sujan, Vinoo Thomas
  • Patent number: 11916201
    Abstract: The present disclosure pertains to motion-generating particles for desulfation of lead-acid batteries, lead-acid batteries including such motion-generating particles, and methods of making and using the same. For example, the present disclosure provides a lead-acid battery including one or more electroactive plates disposed within a casing; an electrolyte disposed within the casing and surrounding the electroactive plates; a plurality of ferromagnetic particles disposed with the electrolyte within the casing; and one or more electromagnets. The one or more electromagnets may be configured to direct a magnetic field towards the electrolyte to selectively cause movement of the plurality of ferromagnetic particles so as to agitate the electrolyte.
    Type: Grant
    Filed: December 11, 2020
    Date of Patent: February 27, 2024
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Dorel M. Sala, Mahmoud Abd Elhamid, Dave G. Rich
  • Patent number: 11894544
    Abstract: A method for renovation of a consumed anode in a metal-air cell without dismantling the cell according to embodiments of the present invention comprising circulating electrolyte through the cell to evacuate used slurry from the cell, circulating electrolyte with fresh slurry into the cell and allowing sedimentation of the fresh slurry inside the cell to form an anode and compacting the slurry to reduce the gaps between its particles.
    Type: Grant
    Filed: October 19, 2021
    Date of Patent: February 6, 2024
    Assignee: PHINERGY LTD.
    Inventors: Aviv Tzidon, Vital Peretz, Avraham Yadgar, Dekel Tzidon
  • Patent number: 11876187
    Abstract: Provided is a terminal assembly for an electrochemical battery comprising a terminal connector; a conductive flat-plate with an electrically conducting perimeter; an electrically insulating tape member; and a terminal bipolar electrode plate. The electrically insulating tape member is in between the conductive flat-plate and the terminal bipolar electrode plate such that the electrically insulating tape member does not cover the entire surface area of the conductive flat-plate. The electrically conducting perimeter enables bi-directional uniform current flow through the conductive flat-plate between the terminal connector and the terminal bipolar electrode plate. Also provided is a battery frame member for a static rechargeable battery comprising a liquid diversion system; a gutter; a sealing member; a gas channel; and a ventilation hole.
    Type: Grant
    Filed: August 24, 2021
    Date of Patent: January 16, 2024
    Assignee: Eos Energy Technology Holdings, LLC
    Inventors: George W. Adamson, Sara S. Bowers, Francis W. Richey, Daniel Friberg, Fabian Bruegger, Mateo S. Williams
  • Patent number: 11876188
    Abstract: The present disclosure relates to an electrolyte comprising: a) a sodium salt; b) an additive comprising at least one additional metallic/metalloid cation having a standard reduction potential which is at least 2.5V more positive than that of sodium cation; wherein said sodium salt and said additive are dispersed in a solvent comprising at least one alkyl carbonate, and wherein the concentration of said metallic/metalloid cation in the electrolyte is 15 mM to 250 mM. The present disclosure also relates to a sodium-sulfur cell comprising a sodium anode, a microporous sulfur cathode, and the electrolyte as described herein. The present disclosure further provides a method of improving cycling life of a sodium-sulfur cell, wherein the sodium-sulfur cell comprising a sodium anode, a sulfur cathode, and an electrolyte containing a sodium salt dispersed in an alkyl carbonate solvent.
    Type: Grant
    Filed: October 26, 2020
    Date of Patent: January 16, 2024
    Assignee: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH
    Inventors: Vipin Kumar, Zhi Wei Seh
  • Patent number: 11831017
    Abstract: The present invention relates to novel combinations of redox active compounds for use as redox flow battery electrolytes. The invention further provides kits comprising these combinations, redox flow batteries, and method using the combinations, kits and redox flow batteries of the invention.
    Type: Grant
    Filed: February 13, 2019
    Date of Patent: November 28, 2023
    Assignee: CMBlu Energy AG
    Inventors: Jan Hartwig, Peter Geigle, Evgeny Larionov
  • Patent number: 11824158
    Abstract: A gel electrolyte composite containing a nonvolatile electrolyte and a zwitterionic polymer scaffold in which the non-volatile electrolyte is a non-lithium-containing ionic liquid, a sodium-containing ionic liquid, or a lithium-containing ionic liquid and the zwitterionic polymer scaffold is formed from one or more zwitterionic monomers only or both one or more zwitterionic monomers and one or more non-zwitterionic monomers. The zwitterionic polymer scaffold contains 8 mol % or higher of zwitterions relative to the total content of the gel electrolyte composite when the nonvolatile electrolyte is a non-lithium-containing ionic liquid, and contains 1 mol % or higher of zwitterions relative to the total content of the gel electrolyte composite when the nonvolatile electrolyte is a sodium-containing ionic liquid or a lithium-containing ionic liquid. Also disclosed are a method of preparing the above-described gel electrolyte composite and an electrochemical energy storage device containing same.
    Type: Grant
    Filed: September 28, 2018
    Date of Patent: November 21, 2023
    Assignee: Trustees of Tufts College
    Inventors: Anthony J. D'Angelo, Morgan Taylor, Matthew Panzer, Huan Qin
  • Patent number: 11791454
    Abstract: Systems, articles, and methods generally related to the electrochemical formation of layers comprising halogen ions on substrates are described.
    Type: Grant
    Filed: June 23, 2020
    Date of Patent: October 17, 2023
    Assignee: Massachusetts Institute of Technology
    Inventors: Betar Gallant, Haining Gao
  • Patent number: 11715840
    Abstract: In one example, a system for a flow cell for a flow battery, comprising: a first flow field; and a polymeric frame, comprising: a top face; a bottom face, opposite the top face; a first side; a second side, opposite the first side; a first electrolyte inlet located on the top face and the first side of the polymeric frame; a first electrolyte outlet located on the top face and the second side of the polymeric frame; a first electrolyte inlet flow path located within the polymeric frame and coupled to the first electrolyte inlet; and a first electrolyte outlet flow path located within the polymeric frame and coupled to the first electrolyte outlet. In this way, shunt currents may be minimized by increasing the length and/or reducing the cross-sectional area of the electrolyte inlet and electrolyte outlet flow paths.
    Type: Grant
    Filed: October 14, 2021
    Date of Patent: August 1, 2023
    Assignee: ESS Tech, Inc
    Inventors: Craig Evans, Yang Song
  • Patent number: 11705584
    Abstract: Alkaline electrochemical cells are provided, wherein an organic additive is included in at least one component of the cell in order to increase electron discharge of the cathode, so as to improve the specific capacity of the cell. Methods for preparing such cells are also provided.
    Type: Grant
    Filed: February 22, 2018
    Date of Patent: July 18, 2023
    Assignee: Energizer Brands, LLC
    Inventor: Guanghong Zheng
  • Patent number: 11684284
    Abstract: The present disclosure provides a device for carrying out magnetic resonance imaging compatible optogenetics; and methods for using the device.
    Type: Grant
    Filed: July 20, 2016
    Date of Patent: June 27, 2023
    Assignee: The Board of Trustees of the Leland Stanford Junior University
    Inventors: Jin Hyung Lee, Ben A. Duffy
  • Patent number: 11664518
    Abstract: A redox flow battery includes a redox flow cell and a supply and storage system external of the redox flow cell. The supply and storage system includes first and second electrolytes for circulation through the redox flow cell. The first electrolyte is a liquid electrolyte having electrochemically active manganese species with multiple, reversible oxidation states in the redox flow cell. The electrochemically active manganese species may undergo reactions that cause precipitation of manganese oxide solids. The first electrolyte includes an inhibitor that limits the self-discharge reactions. The inhibitor includes an oxoanion compound.
    Type: Grant
    Filed: May 21, 2021
    Date of Patent: May 30, 2023
    Assignee: RAYTHEON TECHNOLOGIES CORPORATION
    Inventors: Timothy Davenport, James D. Saraidaridis, Robert Mason Darling
  • Patent number: 11658354
    Abstract: Described herein are embodiments of methods and apparatus for determining the SoC and SoH a lithium ion battery and for restoring capacity to a lithium ion battery. Some embodiments provide a method and apparatus including an ultrasound transducer designed to measure characteristics of a lithium ion battery in order to determine the SoC and SoH of the lithium ion battery, and to disrupt the SSEI layer inside the lithium ion battery. Several other methods for determination of SoC and SoH and disruption of the SSEI layer are also described. Use of such methods and apparatus may be advantageous in assessing a state of the lithium ion battery, as well as rejuvenating a lithium ion battery and increasing its life span.
    Type: Grant
    Filed: May 30, 2018
    Date of Patent: May 23, 2023
    Assignee: TITAN ADVANCED ENERGY SOLUTIONS, INC.
    Inventors: Shawn Murphy, Ashish Sreedhar, Vincent Yuan-Hsiang Lee, Steven Africk
  • Patent number: 11637298
    Abstract: A redox flow battery includes first and second cells. Each cell has electrodes and a separator layer arranged between the electrodes. A first circulation loop is fluidly connected with the first electrode of the first cell. A polysulfide electrolyte solution has a pH 11.5 or greater and is contained in the first recirculation loop. A second circulation loop is fluidly connected with the second electrode of the second cell. An iron electrolyte solution has a pH 3 or less and is contained in the second circulation loop. A third circulation loop is fluidly connected with the second electrode of the first cell and the first electrode of the second cell. An intermediator electrolyte solution is contained in the third circulation loop. The cells are operable to undergo reversible reactions to store input electrical energy upon charging and discharge the stored electrical energy upon discharging.
    Type: Grant
    Filed: June 29, 2021
    Date of Patent: April 25, 2023
    Assignee: RAYTHEON TECHNOLOGIES CORPORATION
    Inventor: Michael L. Perry
  • Patent number: 11637341
    Abstract: Multi-phase electrochemical cells and related systems and methods are generally described.
    Type: Grant
    Filed: February 12, 2021
    Date of Patent: April 25, 2023
    Assignee: Massachusetts Institute of Technology
    Inventors: Yet-Ming Chiang, Andres Badel, Fei Wang
  • Patent number: 11563228
    Abstract: A benthic microbial fuel cell comprising: a nonconductive frame having an upper end and a lower end; a plurality of anodes, wherein each anode is a conductive plate having a top section and a bottom edge; a plurality of conductive, threaded rods disposed perpendicularly to the anode plates and configured to secure the top sections of the anodes to the lower end of the frame and to hold the plates in a substantially parallel orientation with respect to each other such that none of the plates are in direct contact with each other; and a plurality of cathodes, wherein each cathode is made of carbon cloth connected to the upper end of the frame.
    Type: Grant
    Filed: January 25, 2021
    Date of Patent: January 24, 2023
    Assignee: United States of America as represented by the Secretary of the Navy
    Inventors: Matthew Lanford Bond, Yolanda Meriah Arias-Thode, Lewis Hsu, David Bart Chadwick
  • Patent number: 11552325
    Abstract: A flow battery includes a negative electrode, a positive electrode, a first liquid in contact with the negative electrode, a second liquid in contact with the positive electrode, and a lithium-ion-conductive film disposed between the first liquid and the second liquid. At least one of the first liquid or the second liquid contains a redox species and lithium ions. The lithium-ion-conductive film includes an inorganic member containing zeolite.
    Type: Grant
    Filed: November 4, 2020
    Date of Patent: January 10, 2023
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Takahiro Kurabuchi, Honami Sako, Masahisa Fujimoto
  • Patent number: 11532830
    Abstract: A flow battery includes a positive electrode, a positive electrode electrolyte, a negative electrode, a negative electrode electrolyte, and a polymer electrolyte membrane interposed between the positive electrode and the negative electrode. The positive electrode electrolyte includes water and a first redox couple. The first redox couple includes a first organic compound which includes a first moiety in conjugation with a second moiety. The first organic compound is reduced during discharge while during charging the reduction product of the first organic compound is oxidized to the first organic compound. The negative electrode electrolyte includes water and a second redox couple. The second couple includes a second organic compound including a first moiety in conjugation with a second moiety. The reduction product of the second organic compound is oxidized to the second organic compound during discharge.
    Type: Grant
    Filed: February 10, 2020
    Date of Patent: December 20, 2022
    Assignee: University of Southern California
    Inventors: Sri Narayan, Surya G. K. Prakash, Bo Yang, Lena Hoober-Burkhardt, Sankarganesh Krishnamoorthy
  • Patent number: 11522175
    Abstract: In conventional arts, it is impossible to form a good solid-solid interface in cathode mixture layers of all-solid-state batteries, which significantly deteriorates resistance of the all-solid-state battery after the charge/discharge cycle, which is problematic. A cathode slurry is produced by a method including: a first step of dispersing a conductive additive constituted of carbon in a solvent to obtain a first slurry; a second step of dispersing a sulfide solid electrolyte in the first slurry to obtain a second slurry; and a third step of dispersing a cathode active material in the second slurry to obtain a third slurry, to be used to form a cathode mixture layer. This may suppress agglomeration of the cathode active material as using the conductive additive as a core, and may lower the proportion of agglomerate present in the cathode mixture layer.
    Type: Grant
    Filed: February 4, 2020
    Date of Patent: December 6, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Shingo Komura
  • Patent number: 11522216
    Abstract: A solid electrolyte material is represented by the following compositional formula (1): Li3-3?-2aY1+?-aMaCl6-x-yBrxIy where, M is at least one selected from the group consisting of Ta and Nb; and ?1<?<1, 0<a<1.2, 0<(3?3??2a), 0<(1+??a), 0?x?6, 0?y?6, and (x+y)?6 are satisfied.
    Type: Grant
    Filed: June 27, 2020
    Date of Patent: December 6, 2022
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Yusuke Nishio, Tetsuya Asano, Akihiro Sakai, Masashi Sakaida, Akinobu Miyazaki, Shinya Hasegawa
  • Patent number: 11515603
    Abstract: A separator plate arrangement for an electrochemical system, comprising a first metal sheet and a second metal sheet. The first metal sheet has a first circumferential sealing structure for sealing off an electrochemically active region, a first cutout arranged outside of the first circumferential sealing structure, and a first embossed structure arranged outside of the first circumferential sealing structure. The second metal sheet has a second circumferential sealing structure for sealing off an electrochemically active region, a second cutout arranged outside of the second circumferential sealing structure, and a second embossed structure arranged outside of the second circumferential sealing structure.
    Type: Grant
    Filed: January 22, 2021
    Date of Patent: November 29, 2022
    Assignee: Reinz-Dichtungs-GmbH
    Inventors: Claudia Kunz, Sebastian Schaefer
  • Patent number: 11476542
    Abstract: Disclosed is a rechargeable lithium battery including a positive electrode including a positive active material; a negative electrode including a negative active material; an electrolyte solution including a lithium salt and a non-aqueous organic solvent; and a separator between the positive and the negative electrodes, the separator including a porous substrate and a coating layer positioned on at least one side of the porous substrate. The negative active material includes a Si-based material; the non-aqueous organic solvent includes cyclic carbonate including ethylene carbonate, propylene carbonate, or combinations thereof, the cyclic carbonate being included in an amount of about 20 volume % to about 60 volume % based on the total amount of the non-aqueous organic solvent; and the coating layer includes a fluorine-based polymer, an inorganic compound, or combinations thereof. The rechargeable lithium battery has improved cycle-life and high temperature storage characteristics.
    Type: Grant
    Filed: November 15, 2019
    Date of Patent: October 18, 2022
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Kwang-Jo Cheong, Yong-Beom Lee, Myung-Ro Lee, Su-Min Lee
  • Patent number: 11456485
    Abstract: Disclosed is an electrochemical cell, which may be used for advanced rechargeable batteries. The electrochemical cell comprises two or more electrodes within an electrolyte solution, where the electrolyte solution containing (i) an aliphatic or cyclic sulfone and (ii) a metal perfluoroalkylsulfonylimide salt.
    Type: Grant
    Filed: April 16, 2020
    Date of Patent: September 27, 2022
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Judith A. Kim, Marshall A. Schroeder, Arthur von Wald Cresce, Kang Xu, Lin Ma
  • Patent number: 11374236
    Abstract: A redox flow battery may include: a membrane interposed between a first electrode positioned at a first side of the membrane and a second electrode positioned at a second side of the membrane opposite to the first side; a first flow field plate comprising a plurality of positive flow field ribs, each of the plurality of positive flow field ribs contacting the first electrode at first supporting regions on the first side; and the second electrode, including an electrode spacer positioned between the membrane and a second flow field plate, the electrode spacer comprising a plurality of main ribs, each of the plurality of main ribs contacting the second flow field plate at second supporting regions on the second side, each of the second supporting regions aligned opposite to one of the plurality of first supporting regions. As such, a current density distribution at a plating surface may be reduced.
    Type: Grant
    Filed: May 22, 2017
    Date of Patent: June 28, 2022
    Assignee: ESS TECH, INC.
    Inventors: Craig E. Evans, Sean Casey, Yang Song
  • Patent number: 11289728
    Abstract: A segmented frame plate is provided, which may be used in a frame plate assembly of a redox flow battery cell stack. A plurality of segmented frame plates may couple together around a perimeter of a cell plate. Each segmented frame plate may provide fluidic communication from/to a redox flow reservoir and/or another frame plate assembly to a cell plate of the frame plate assembly.
    Type: Grant
    Filed: August 31, 2018
    Date of Patent: March 29, 2022
    Assignee: STRYTEN CRITICAL E-STORAGE LLC
    Inventor: Garrett Scott Kato
  • Patent number: 11283077
    Abstract: A redox flow battery is characterized in that the anolyte comprises a zinc salt as redox-active component and preferably a 2.2.6.6-tetramethylpiperidinyloxyl (TEMPO)-based cathode is used.
    Type: Grant
    Filed: November 14, 2016
    Date of Patent: March 22, 2022
    Assignee: JENA BATTERIES, GMBH
    Inventors: Jan Winsberg, Tobias Janoschka, Ulrich Sigmar Schubert, Bernhard Häupler, Martin Hager
  • Patent number: 11264632
    Abstract: The flow battery according to the present disclosure comprises an anode and a cathode. The cathode comprises a first electrode, a first liquid, a first active material, and a first circulation mechanism. The first liquid is in contact with the first active material and the first electrode. The first circulation mechanism is configured to circulate the first liquid between the first electrode and the first active material. The first liquid includes perylene or the derivative thereof.
    Type: Grant
    Filed: March 4, 2020
    Date of Patent: March 1, 2022
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventor: Honami Sako
  • Patent number: 11239483
    Abstract: The invention relates to a stack of several electrochemical cells stacked on top of one another in a stacking direction. The stack comprises at least: a first electrochemical cell, a second electrochemical cell, and an intercalary plate. Each cell includes an upper frame housing a first electrode and a lower frame housing a second electrode, the first electrode and the second electrode being separated from one another by a membrane. The second electrode of the first electrochemical cell and the first electrode of the second electrochemical cell are separated by an intercalary plate. The stack includes an intercalary frame arranged on the periphery of the intercalary plate.
    Type: Grant
    Filed: August 30, 2019
    Date of Patent: February 1, 2022
    Assignee: KEMIWATT
    Inventor: Florent Beille
  • Patent number: 11233299
    Abstract: In one example, a system for a flow cell for a flow battery, comprising: a first flow field; and a polymeric frame, comprising: a top face; a bottom face, opposite the top face; a first side; a second side, opposite the first side; a first electrolyte inlet located on the top face and the first side of the polymeric frame; a first electrolyte outlet located on the top face and the second side of the polymeric frame; a first electrolyte inlet flow path located within the polymeric frame and coupled to the first electrolyte inlet; and a first electrolyte outlet flow path located within the polymeric frame and coupled to the first electrolyte outlet. In this way, shunt currents may be minimized by increasing the length and/or reducing the cross-sectional area of the electrolyte inlet and electrolyte outlet flow paths.
    Type: Grant
    Filed: August 22, 2019
    Date of Patent: January 25, 2022
    Assignee: ESS TECH, INC.
    Inventors: Craig Evans, Yang Song
  • Patent number: 11217818
    Abstract: The present disclosure relates to a sodium-ion storage material and an electrode material for a sodium-ion battery, an electrode material for a seawater battery, an electrode for a sodium-ion battery, an electrode for a seawater battery, a sodium-ion battery, and a seawater battery, which include the sodium-ion storage material. Specifically, the sodium-ion storage material may include one or more materials selected from the group consisting of CuxS, FeS, FeS2, Ni3S, NbS2, SbOx, SbSx, SnS and SnS2, wherein 0<x?2. When the sodium-ion storage material according to the present disclosure is used, it may exhibit high discharge capacity, and when the sodium-ion storage material is applied to a sodium-ion battery which is a secondary battery, it may exhibit excellent charge/discharge cycle characteristics.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: January 4, 2022
    Inventors: Jong Min Yuk, Jae Yeol Park, Sung Joo Kim
  • Patent number: 11183701
    Abstract: The flow battery comprises a first semi-cell (2), wherein a first electrolyte is fed through a first electrode (21); a second semi-cell (3), wherein a second electrolyte is fed through a second electrode (31); a partition membrane (4) disposed between the first electrode (21) and second electrode (31) in order to prevent them from reciprocally contacting with each other, and suitable to enable ions to permeate; and at least one porous barrier material layer (5) disposed between the first electrode (21) and second electrode (31), and suitable to block an undesired flow of ions of one or both the electrolytes through the partition membrane (4), the barrier material layer (5) having zones with different selectivities towards the ions whose flow is undesired.
    Type: Grant
    Filed: March 15, 2019
    Date of Patent: November 23, 2021
    Assignee: POLITECNICO DI MILANO
    Inventors: Matteo Zago, Andrea Casalegno
  • Patent number: 11177505
    Abstract: An electrolyte composition including (i) at least one aprotic organic solvent; (ii) at least one conducting salt; (iii) at least one pyridine-SO3 complex of formula (I) wherein R is selected independently at each occurrence from F, C1 to C10 alkyl, C2 to C10 alkenyl, and C2 to C10 alkynyl, wherein alkyl, alkenyl, and alkynyl may be substituted by one or more substituents selected from F and CN; and n is an integer selected from 1, 2, 3, 4, and 5; and (vi) optionally one or more additives; and its use in electrochemical cells.
    Type: Grant
    Filed: January 2, 2018
    Date of Patent: November 16, 2021
    Assignee: BASF SE
    Inventors: Frederick Francois Chesneau, Arnd Garsuch, Michael Schmidt, Brett Lucht, Julien Demeaux, Yingnan Dong, Bo Zhang
  • Patent number: 11145886
    Abstract: Redox flow battery 1 includes cell stack 2, first positive-electrode tank 11, second positive-electrode tank 12, first negative-electrode tank 21, and second negative-electrode tank 22. Cell stack 2 is divided into a plurality of cell groups 3, each of which consists of a plurality of cells 4. The plurality of cell groups 3 are connected to first and second positive-electrode tanks 11, 12 such that a positive-electrode fluid containing positive-electrode active material flows in parallel through the plurality of cell groups 3, and are connected to first and second negative-electrode tanks 21, 22 such that a negative-electrode fluid containing negative-electrode active material flows in parallel through the plurality of cell groups 3. The plurality of cells 4 in each cell group 3 are connected to each other such that the positive-electrode fluid flows in series through a plurality of positive cells 5 and such that the negative-electrode fluid flows in series through a plurality of negative cells 6.
    Type: Grant
    Filed: September 10, 2018
    Date of Patent: October 12, 2021
    Assignee: Toyo Engineering Corporation
    Inventors: Takato Nakao, Uma Jaya Ravali Theeda
  • Patent number: 11056705
    Abstract: Organic anolyte materials for redox flow batteries and redox flow batteries containing organic anolyte materials are disclosed.
    Type: Grant
    Filed: June 8, 2016
    Date of Patent: July 6, 2021
    Assignees: THE REGENTS OF THE UNIVERSITY OF MICHIGAN, THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
    Inventors: Melanie S. Sanford, Christo Slavov Sevov, Rachel Brooner, Etienne Chénard
  • Patent number: 11050047
    Abstract: A method of manufacturing a secondary battery using lithium metal as a negative electrode, and more particularly, a method of manufacturing a secondary battery capable of removing an oxide film formed on a lithium metal by performing some initial discharges during the initial period of the activation process to thereby improve the cycling performance of the battery by allowing lithium to be uniformly precipitated. The result minimizes the reduction of ion conductivity by removing the oxide film formed on the surface of the lithium metal through the initial partial discharge and improves the battery cycle performance since the precipitation reaction of lithium becomes uniform.
    Type: Grant
    Filed: June 29, 2018
    Date of Patent: June 29, 2021
    Assignee: LG CHEM, LTD.
    Inventors: Kyung Hwa Woo, Jae Hyun Lee, Jong Keon Yoon, Hoe Jin Hah
  • Patent number: 11011747
    Abstract: A lithium metal oxide powder for a cathode material in a rechargeable battery, consisting of a core and a surface layer, the surface layer being delimited by an outer and an inner interface, the inner interface being in contact with the core, the core having a layered crystal structure comprising the elements Li, M and oxygen, wherein M has the formula M=(Niz (Ni1/2 Mn1/2)y Cox)1-k Ak, with 0.15?x?0.30, 0.20?z?0.55, x+y+z=1 and 0<k?0.1, wherein the Li content is stoichiometrically controlled with a molar ratio 0.95?Li:M?1.10; wherein A is at least one dopant and comprises Al; wherein the core has an Al content of 0.3-3 mol % and a F content of less than 0.05 mol %; and wherein the surface layer has an Al content that increases continuously from the Al content of the core at the inner interface to at least 10 mol % at the outer interface, and a F content that increases continuously from less than 0.
    Type: Grant
    Filed: January 20, 2016
    Date of Patent: May 18, 2021
    Assignees: Umicore, Umicore Korea Ltd.
    Inventors: Xin Xia, Jens Paulsen, JiHye Kim, Song-Yi Han
  • Patent number: 10950879
    Abstract: A redox flow battery includes a positive electrolyte tank container which houses a positive electrolyte tank for storing a positive electrolyte; a negative electrolyte tank container which houses a negative electrolyte tank for storing a negative electrolyte; and a battery container which houses a battery cell including a positive electrode, a negative electrode, and a membrane, a positive electrolyte circulation mechanism configured to supply and circulate the positive electrolyte to the battery cell, and a negative electrolyte circulation mechanism configured to supply and circulate the negative electrolyte to the battery cell.
    Type: Grant
    Filed: November 2, 2017
    Date of Patent: March 16, 2021
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Atsuo Ikeuchi, Kiyoaki Hayashi
  • Patent number: 10923744
    Abstract: An electrochemical system that can serve as a heat engine or heat pump is disclosed. The electrochemical system comprises a first electrode assembly, a second electrode assembly, a first electrolyte and a second electrolyte. The first electrode assembly, configured to operate at a first temperature, includes a first electrode set and a second electrode set. The second electrode assembly, configured to operate at a second temperature different from the first temperature, includes a first electrode set and a second electrode set. The first electrolyte is configured to circulate between the first electrode set of the first electrode assembly and the first electrode set of the second electrode assembly. The second electrolyte is configured to circulate between the second electrode set of the first electrode assembly and the second electrode set of the second electrode assembly.
    Type: Grant
    Filed: January 7, 2016
    Date of Patent: February 16, 2021
    Assignee: KD INNOVATION LTD.
    Inventors: Krassen Dimitrov, Angel Giancarlo Miranda, Pei-Hsuan Chiang
  • Patent number: 10847780
    Abstract: In some embodiments, a battery, a cathode for a battery, and a method for making a cathode and a battery are provided. The method comprises the steps of at least combining an electrode active material, one or more conductive diluents, a binder and a solvent to form an electrode active mixture having a first solvent to powder weight ratio, reducing a solvent to powder weight ratio to form a paste, feeding the paste into a plastic tube; and calendering the plastic tube. A dry cathode mixture is provided. The dry cathode mixture includes a cathode active material, a conductive diluent and a polymeric binder. A solvent is mixed with the dry mixture to form a slurry. Solvent is removed from the slurry to form a doughy composition. The doughy composition is calender sheeted to form a sheet. The sheet is baked at a temperature of 30° C. to 120° C. for 15 minutes to 6 hours to form a dry sheet. The dry sheet is cut into coupons. The coupons are pressed to form a pressed coupon.
    Type: Grant
    Filed: September 18, 2017
    Date of Patent: November 24, 2020
    Assignee: Pacesetter, Inc.
    Inventors: Xiaofei Jiang, Russell Bruch, Joseph Beauvais
  • Patent number: 10777811
    Abstract: A liquid catholyte for a Li—S battery comprises a non-aqueous solution of at least one lithium polysulfide of formula Li2Sx (wherein x is selected from 4, 6, and 8) and an anion receptor compound capable of complexing with polysulfide anion. The non-aqueous solution typically is composed of the Li2Sx and the anion receptor compound dissolved in a non-aqueous solvent (e.g., one or more organic ether or fluorinated ether solvents). The anion receptor compound typically is present in the catholyte at a concentration of about 0.1 M to about 4 M. Li—S batteries comprise a metallic lithium anode; a porous conductive substrate; a separator membrane between the anode and the porous conductive substrate; and the liquid catholyte composition within pores of the substrate.
    Type: Grant
    Filed: March 2, 2018
    Date of Patent: September 15, 2020
    Assignee: UCHICAGO ARGONNE, LLC
    Inventors: Zhengcheng Zhang, Zheng Xue, Feng Zhao
  • Patent number: 10763536
    Abstract: Embodiments of the claimed invention are directed to a device, comprising: an anode that includes a lithiated silicon-based material and a sulfur-based cathode, wherein the anode and the cathode are designed to have mesoporous structures. In certain embodiments, the sulfur-based cathode is a mesoporous carbon structure comprising sulfur within the mesopores. A further embodiment of the invention is directed to a device comprising a semi-liquid lithium-sulfur battery comprising a lithium anode and a sulfur cathode. In certain embodiments, the sulfur cathode comprises a liquid catholyte, which is housed within a reservoir that is a carbon nanotube sponge. An additional embodiment of the invention is directed to a method for producing a lithiated silicon anode and a sulfur-based cathode.
    Type: Grant
    Filed: July 15, 2015
    Date of Patent: September 1, 2020
    Assignee: The Texas A&M University System
    Inventors: Choongho Yu, Xiong Pu
  • Patent number: 10665877
    Abstract: A redox flow battery is illustrated and described, having at least one cell frame enclosing a cell interior and having at least one supply line provided outside the cell frame for supplying electrolyte to the cell interior and/or at least one disposal line provided outside the cell frames for removing electrolyte from the cell interior. In order to provide greater degrees of freedom in the design of the cell so as to make available redox flow batteries with improved properties, it is envisaged that the supply line for supplying electrolyte to the cell interior and/or the disposal line for removing electrolyte from the cell interior is in fluid contact with the cell interior via a plurality of separate flow channels in the cell frame.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: May 26, 2020
    Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    Inventors: Christian Dotsch, Sascha Berthold, Thorsten Seipp
  • Patent number: 10615432
    Abstract: A cell frame includes a bipolar plate in contact with an electrode constituting a battery cell; and a frame body surrounding a periphery of the bipolar plate, wherein the frame body includes a liquid supply manifold through which an electrolyte is supplied into the battery cell, the bipolar plate includes, in a surface facing the electrode, a plurality of main groove portions that are arranged adjacent to one another and through which the electrolyte flows, at least one of the frame body and the bipolar plate includes a supply flow directing portion configured to distribute, in a direction in which the main groove portions are arranged adjacent to one another, the electrolyte supplied through the liquid supply manifold, to supply the electrolyte to each of the main groove portions, and each of widths Wi of electrolyte inlets of the main groove portions, and a width Wr of the supply flow directing portion in a direction orthogonal to the direction in which the main groove portions are arranged adjacent to one
    Type: Grant
    Filed: November 16, 2016
    Date of Patent: April 7, 2020
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Takashi Kanno
  • Patent number: 10522875
    Abstract: An improved lead acid battery (LAB) battery may provide high charge acceptance and may be suitable for a wide range of applications, including a variety of new applications. The new battery can sustain 67% of the maximum capacity even at a very high charging rate of IOC. This battery may decrease the use of lead in comparison to prior lead acid battery designs by up to 50%.
    Type: Grant
    Filed: May 20, 2016
    Date of Patent: December 31, 2019
    Assignee: UNIVERSITY OF HOUSTON SYSTEM
    Inventors: Yan Yao, Yanliang Liang, Saman Gheytani, Yan Jing
  • Patent number: 10522849
    Abstract: The present invention relates to an electrochemical cell having a channel-type flow-electrode unit. The channel-type flow-electrode structure according to the present invention, which has at least two channel-type flow-electrode units, can significantly reduce manufacturing costs and installation space by reducing the number of parts while extending the electrode capacity to be suitable for large-scale plants for electricity generation, energy storage, desalination, etc. In addition, the channel-type flow-electrode structure can be applied not only to a capacitive flow-electrode device and/or a redox flow battery device, but also to all of the devices for electricity generation, energy storage, and desalination while moving ions or protons.
    Type: Grant
    Filed: September 1, 2017
    Date of Patent: December 31, 2019
    Assignee: KOREA INSTITUTE OF ENERGY RESEARCH
    Inventors: Dong-Kook Kim, Sung-Il Jeon, Ko-Yeon Choo, Younghyun Cho, Jeong-Gu Yeo, Jong-Soo Park, SeungCheol Yang, Ji Yeon Choi, Hong Ran Park, Ki Sook Lee, Young Jik Youn, Jung Hyun Lee, Hee-Yeon Kim
  • Patent number: 10468706
    Abstract: A REDOX flow battery or fuel battery includes a reactant storing and collecting unit for preventing leakage of a reactant. The battery includes two end plates and a stack that is disposed between the end plates and includes one or more unit cells. The reactant storing and collecting unit for preventing leakage of a reactant is disposed inside or outside the stack. According to the present invention, sealing reliability of the REDOX battery or fuel battery is dramatically improved. In addition, although a reactant or a product leaks from the stack, the reactant or the product may not leak to an outside of the battery but is collected before leaking to the outside. Therefore, the battery according to the present invention has an advantage of easy maintenance.
    Type: Grant
    Filed: December 31, 2014
    Date of Patent: November 5, 2019
    Assignee: STANDARD ENERGY CO., LTD.
    Inventors: Bu Gi Kim, Da Young Kim
  • Patent number: 10439197
    Abstract: In one example, a system for a flow cell for a flow battery, comprising: a first flow field; and a polymeric frame, comprising: a top face; a bottom face, opposite the top face; a first side; a second side, opposite the first side; a first electrolyte inlet located on the top face and the first side of the polymeric frame; a first electrolyte outlet located on the top face and the second side of the polymeric frame; a first electrolyte inlet flow path located within the polymeric frame and coupled to the first electrolyte inlet; and a first electrolyte outlet flow path located within the polymeric frame and coupled to the first electrolyte outlet. In this way, shunt currents may be minimized by increasing the length and/or reducing the cross-sectional area of the electrolyte inlet and electrolyte outlet flow paths.
    Type: Grant
    Filed: March 31, 2017
    Date of Patent: October 8, 2019
    Assignee: ESS Tech, Inc.
    Inventors: Craig Evans, Yang Song