Nickel Component Is Active Material Patents (Class 429/223)
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Patent number: 11050053Abstract: The present invention relates to a battery, comprising a positive electrode plate, a separator and a negative electrode plate, wherein the positive electrode plate comprises a positive electrode current collector and at least two layers of positive active materials on at least one surface of the positive electrode current collector in which the underlying positive active material layer in contact with the positive electrode current collector comprises a first positive active material, a first polymer material, and a first conductive material and in which the upper positive active material layer comprises a second positive active material, a second polymer material, and a second conductive material and the first polymer material comprises an oil-dispersible polymer material having a solubility in NMP at 130° C. for 5 minutes, which is 30% or less of the solubility of PVDF under the same conditions. The battery exhibits good safety performance and improved electrical performance.Type: GrantFiled: May 24, 2019Date of Patent: June 29, 2021Assignee: Contemporary Amperex Technology Co., LimitedInventors: Wei Li, Haihao Shi, Huihui Liu, Chao Jin, Tianyi Gao, Jianbao Xu, Shisong Li, Chao Guo
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Patent number: 11038361Abstract: In one aspect, a battery includes at least one anode, at least one cathode, and electrolyte between the at least one anode and at least one cathode. The at least one cathode comprises at least a first charging material and at least a second charging material different from the first material.Type: GrantFiled: March 16, 2015Date of Patent: June 15, 2021Assignee: Lenovo (Singapore) Pte. Ltd.Inventors: Bouziane Yebka, Joseph Anthony Holung, Tin-Lup Wong, Philip John Jakes
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Patent number: 11038168Abstract: Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation.Type: GrantFiled: February 9, 2018Date of Patent: June 15, 2021Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Atsushi Fukui, Katsuya Inoue, Shuhei Oda, Hiroyuki Toya
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Patent number: 11038159Abstract: The present invention relates to a positive electrode active material for a lithium secondary battery including a lithium cobalt oxide having a core-shell structure, wherein the lithium cobalt-doped oxide of the core and the lithium cobalt-doped oxide of the shell include each independently three kinds of dopants and satisfy specific conditions, a method for producing the same, and a positive electrode and a secondary battery containing the positive electrode active material.Type: GrantFiled: January 26, 2018Date of Patent: June 15, 2021Inventors: Chi Ho Jo, Sungbin Park, Jiyoung Park, Bo Ram Lee, Jungmin Han, Hyuck Hur, Wang Mo Jung
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Patent number: 11018338Abstract: Provided is a positive electrode active material for nonaqueous electrolyte secondary batteries that is represented by the general formula (1): LiaNi1-x-yCoxMyWzO2+? (where 0?x?0.35, 0?y?0.35, 0.0008?z?0.030, 0.97?a?1.25, and 0???0.20, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti, and Al) and is constituted by a Li-metal composite oxide composed of primary particles and secondary particles formed by aggregation of the primary particles, wherein a compound including Li and W is formed on the surface of the primary particles of the composite oxide and the amount of W contained in the compound is such that the number of atoms of W is 0.08 to 0.30 at % with respect to the total number of atoms of Ni, Co, and M contained in the positive electrode active material.Type: GrantFiled: June 21, 2016Date of Patent: May 25, 2021Inventors: Yuki Furuichi, Jun Suzuki, Tetsufumi Komukai
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Patent number: 11011774Abstract: There is provided a lithium ion secondary battery having excellent cycle characteristics at a high temperature and comprising lithium nickel composite oxides, in which the Ni content is high, in a positive electrode. The present invention relates to a lithium ion secondary battery having a positive electrode, a negative electrode and an electrolyte solution, wherein the positive electrode comprises a lithium nickel complex oxide denoted by the general formula, LiNixCoyMnzO2, wherein x, y, and z are respectively 0.75?x?0.85, 0.05?y?0.15, and 0.10?z?0.20.Type: GrantFiled: December 11, 2015Date of Patent: May 18, 2021Assignee: NEC CORPORATIONInventor: Takeshi Azami
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Patent number: 11011740Abstract: A battery includes a positive electrode, a negative electrode, and an electrolyte. The positive electrode includes LixAl2(OH)7-y.zH2O where 0.9<x<1.1, ?0.1<y<0.1, 0?z<2.1.Type: GrantFiled: March 26, 2019Date of Patent: May 18, 2021Assignee: Murata Manufacturing Co., Ltd.Inventor: Naoki Hayashi
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Patent number: 11011751Abstract: A compound having a layered structure that is used for a positive electrode active material for a lithium ion secondary battery achieves both a high energy density and a high cyclability. The positive electrode active material for a lithium ion secondary battery contains a compound having a layered structure belonging to a space group R-3m, in which the compound having a layered structure is represented by a compositional formula: Li1+aM1O2+? wherein M1 represents a metal element or metal elements other than Li, and contains at least Ni, ?0.03?a?0.10, and ?0.1<?<0.1, a proportion of Ni in M1 is larger than 70 atom %, and a site occupancy of a transition metal or transition metals at a 3a site obtained by structural analysis by a Rietveld method is less than 2%, and a content of residual lithium hydroxide in the positive electrode active material is 1 mass % or less.Type: GrantFiled: October 2, 2015Date of Patent: May 18, 2021Assignee: HITACHI METALS, LTD.Inventors: Akira Gunji, Tatsuya Toyama, Shin Takahashi, Takashi Nakabayashi, Shuichi Takano, Xiaoliang Feng, Sho Furutsuki, Hisato Tokoro
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Patent number: 10985427Abstract: The invention relates to a method for producing an electrode stack for a battery cell, comprising the following steps: providing a strip-shaped anode element (45) comprising an anodic current discharger (31) to which an anodic active material (41) is applied; providing a strip-shaped cathode element (46) comprising a cathodic current discharger (32) to which a cathodic active material (42) is applied; providing at least one strip-shaped separator element (16); introducing grooves (70) into the cathodic active material (42) around segmentation lines (S); generating a strip-shaped composite element (50) by applying the cathode element (46) onto the anode element (45), with the interposition of the at least one separator element (16); cutting the composite element (50) into plate-shaped composite segments at the segmentation lines (S); and stacking the composite segments.Type: GrantFiled: September 15, 2017Date of Patent: April 20, 2021Assignee: Robert Bosch GmbHInventors: Johannes Proell, Thomas Kretschmar, Thomas Juestel
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Patent number: 10978708Abstract: The invention relates to doped nickelate-containing compounds comprising AaM1VM2WM3XM4yM5ZO2-c wherein A comprises either sodium or a mixed alkali metal in which sodium is the major constituent; M1 is nickel in oxidation state greater than 0 to less than or equal to 4+, M2 comprises a metal in oxidation state greater than 0 to less than or equal to 4+, M3 comprises a metal in oxidation state 2+, M4 comprises a metal in oxidation state greater than 0 to less than or equal to 4+, and M5 comprises a metal in oxidation state 3+ wherein 0?a<1, v>0, at least one of w and y is >0 x?0, z?0 wherein c is determined by a range selected from 0<c?0.1 and wherein (a, v, w, x, y, z and c) are chosen to maintain electroneutrality.Type: GrantFiled: January 8, 2015Date of Patent: April 13, 2021Assignee: FARADION LIMITEDInventors: Jeremy Barker, Richard Heap
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Patent number: 10978737Abstract: The present invention relates to an electrolyte solution comprising a supporting salt, a nonaqueous solvent containing a compound having a viscosity of 1.0 mPa-s or less in an amount of more than 50% by volume in the nonaqueous solvent, and a halogenated cyclic acid anhydride. According to the present invention, an electrolyte solution capable of suppressing gas generation is provided.Type: GrantFiled: June 23, 2015Date of Patent: April 13, 2021Assignee: NEC CorporationInventors: Noboru Yoshida, Ikiko Shimanuki, Shinsaku Saitho, Hitoshi Ishikawa
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Patent number: 10978694Abstract: A method for producing a positive electrode material for non-aqueous secondary batteries includes: performing a heat treatment on zirconium boride particles in an oxygen-containing atmosphere at a heat treatment temperature of not less than 220° C. and not more than 390° C., thereby obtaining heat-treated particles; and mixing the heat-treated particles with a positive electrode active material which contains a lithium transition metal complex oxide particles including at least one of cobalt and nickel in a composition thereof and having a layered structure, such that a content of the heat-treated particles relative to the lithium transition metal complex oxide particles is, as zirconium, not less than 0.25 mol % and not more than 2.2 mol %, thereby obtaining a positive electrode material for non-aqueous secondary batteries.Type: GrantFiled: April 23, 2020Date of Patent: April 13, 2021Assignee: NICHIA CORPORATIONInventor: Keisuke Fujihara
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Patent number: 10950855Abstract: A positive electrode active material for a nonaqueous electrolyte secondary battery is provided, which can establish both high capacity and high output when used for a positive electrode material. A positive electrode active material for a nonaqueous electrolyte secondary battery comprises primary particles of a lithium-nickel composite oxide represented by the following general formula (1) and secondary particles composed by aggregation of the primary particles, wherein a 1-nm to 200-nm thick film containing W and Li is present on the surface of the primary particles, and a c-axis length in the LiNi composite oxide crystal ranges from 14.183 to 14.205 angstroms. General formula: LibNi1-x-yCoxMyO2??(1) (In the formula, M is at least one type of element selected from Mg, Al, Ca, Ti, V, Cr, Mn, Nb, Zr and Mo, and 0.95?b?1.03, 0<x?0.15, 0<y?0.07, and x+y?0.16 are satisfied.Type: GrantFiled: October 3, 2016Date of Patent: March 16, 2021Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Tetsufumi Komukai, Yuki Furuichi
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Patent number: 10944105Abstract: The present invention provides a positive electrode active material includes a first lithium transition metal oxide represented by formula Lia(NibCocMnd)1-eMeO2 or Lia(NibCocAld)1-eM?eO2, wherein 0.9<a<1.1, 0.6?b<0.9, 0.1?c<0.4, 0.05?d<0.4, 0?e?0.1, b+c+d=1, M is at least one of Al, Mg, Ti, Zr, M? is at least one of Mg, Ti, Zr, and a second lithium transition metal oxide represented by formula LixNiyCozM?sO2, wherein 0.9<x<1.1, 0.4?y<0.6, 0.2?z<0.5, 0.2?s<0.5, y+z+s=1, M? is at least one of Mn, Al, Mg, Ti, Zr, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Nb, Mo, Sr, Sb, W, Bi. The positive electrode active material for a lithium ion battery of the present invention shows a high compacted density. The present invention also provides a lithium ion battery using the positive electrode active material of the present invention. The lithium ion battery has high gram capacity, high energy density, good storage performance, and good cycle stability.Type: GrantFiled: July 25, 2018Date of Patent: March 9, 2021Assignee: Contemporary Amperex Technology Co., LimitedInventor: Hui Liu
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Patent number: 10930901Abstract: Provided herein are a battery cell of a battery pack to power electric vehicles. The battery cell can include a housing. The housing can define an inner region. An electrolyte can be disposed in the inner region defined by the housing. The battery cell can include a lid. A gasket can couple the lid with the first end of the housing to seal the battery cell. The gasket can include a first gasket surface and a second gasket surface. The first end of the housing can have a crimped edge disposed about the first gasket surface to couple the gasket with the first end of the housing and position the second gasket surface adjacent to the electrolyte. The crimped edge can have a first crimped surface having a predetermined pattern for wire bonding and a second crimped surface disposed adjacent to the first gasket surface.Type: GrantFiled: October 5, 2018Date of Patent: February 23, 2021Assignee: SF Motors, Inc.Inventors: Yifan Tang, Chien-Fan Chen, Ying Liu
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Patent number: 10916755Abstract: The present invention provides a nonaqueous electrolyte secondary battery insulating porous layer having an excellent withstand voltage property and an excellent leakage resistance characteristic. The nonaqueous electrolyte secondary battery insulating porous layer having a trabecular structure including voids, which trabecular structure has an anisotropy value of 1.30 to 2.10, the anisotropy value being calculated from a three-dimensional image showing a void part and a solid content part on respective two gradation levels, the three-dimensional image being prepared by analyzing images of cross sections obtained by making observation at intervals of 20 nm in a thickness direction from a surface of the nonaqueous electrolyte secondary battery insulating porous layer with use of a FIB-SEM having a magnification of 6500 times.Type: GrantFiled: May 12, 2017Date of Patent: February 9, 2021Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Ichiro Arise, Syusaku Hara, Junji Suzuki, Hiroki Hashiwaki
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Copper substituted compound, cathode of battery comprising same, and battery comprising such cathode
Patent number: 10910645Abstract: There is provided a compound for use as material in cathode of a battery. The compound has i) at least sodium or ii) sodium and lithium as a first ingredient, copper as a second ingredient, at least a first transition metal in a third ingredient (M) selected from a group including manganese, nickel, iron, copper, zinc, chromium, vanadium, titanium, molybdenum and tungsten, niobium; and oxygen as a fourth ingredient; and wherein the compound has a chemical formula of NayCuxM1-xO2, or LiaNabCuxM1-xO2.Type: GrantFiled: September 14, 2015Date of Patent: February 2, 2021Assignee: CITY UNIVERSITY OF HONG KONGInventors: Yau Wai Denis Yu, Wenpei Kang, Chun Sing Lee -
Patent number: 10894723Abstract: Provided is a cobalt precursor for preparing a lithium cobalt oxide of a layered structure which is included in a positive electrode active material, wherein the cobalt precursor is cobalt oxyhydroxide (CoM?OOH) doped with, as dopants, magnesium (Mg) and M? different from the magnesium.Type: GrantFiled: December 20, 2017Date of Patent: January 19, 2021Inventors: Chi Ho Jo, Sungbin Park, Jiyoung Park, Bo Ram Lee, Hyuck Hur, Wang Mo Jung
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Patent number: 10892471Abstract: A method of preparing a positive electrode active material precursor for a lithium secondary battery by using a batch-type reactor, which includes the steps of 1) forming positive electrode active material precursor particles while continuously adding a transition metal-containing solution including a transition metal cation, an aqueous alkaline solution, and an ammonium ion-containing solution to a batch-type reactor, 2) sedimenting the positive electrode active material precursor particles formed; 3) discharging a supernatant formed after the sedimentation of the positive electrode active material precursor particles to an outside; 4) adjusting a pH to 10 to 12 by adding the ammonium ion-containing solution; and 5) growing the positive electrode active material precursor particles while continuously again adding the transition metal-containing solution to the batch-type reactor, and a method of preparing a positive electrode active material using the same.Type: GrantFiled: February 6, 2018Date of Patent: January 12, 2021Inventors: Sang Soon Choi, Hyun Ah Park, Won Sig Jung
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Patent number: 10892463Abstract: A secondary battery includes a positive electrode current collector attached to an electrode group, a sealing body including a lid plate and a positive electrode terminal, and a current collecting lead interposed between the positive electrode current collector and the sealing body, and joined to the positive electrode current collector and the sealing body. The current collecting lead has a top wall located on a side of the sealing body, a bottom wall facing the top wall, and located on a side of the positive electrode current collector, and a pair of side walls and extending between a side edge of the top wall and a side edge of the bottom wall, and facing each other. The top wall includes faced parts and facing the bottom wall, and extension parts extending outward from the faced parts, and the extension parts are joined to the lid plate.Type: GrantFiled: September 18, 2019Date of Patent: January 12, 2021Assignee: FDK CORPORATIONInventors: Tomomi Yokosawa, Yusuke Fukuda, Hiroyuki Shibaoka
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Patent number: 10886537Abstract: A current collector for use in an electrochemical cell is provided. The current collector comprises: a reticulated core comprising a polymer and having continuous porosity; a first reticulated surface; a second reticulated surface opposite said first reticulated surface; and a thin metal film disposed on at least one of said first and second reticulated surfaces, wherein said current collector has continuous porosity. A high temperature resistant polymer is preferred for the reticulated core where the current collector may be exposed to high temperatures during production or use. The continuous porosity of the reticulated core 12 and the current collector allows for passage of electrolyte and ions, as necessary for operation of an electrochemical device that includes the current collector.Type: GrantFiled: April 6, 2017Date of Patent: January 5, 2021Assignee: Rutgers. The State University of New JerseyInventors: Glenn G. Amatucci, Anna B. Halajko, Linda Wu Sung
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Patent number: 10879521Abstract: A method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.Type: GrantFiled: March 10, 2017Date of Patent: December 29, 2020Assignee: HYDRO-QUEBECInventors: Karim Zaghib, Michel Armand, Abdelbast Guerfi, Michel Perrier, Elisabeth Dupuis, Patrick Charest
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Patent number: 10879530Abstract: The present invention provides an anode material of nano-silicon. The anode material has multilayer-graphene as a carrier and is coated with silicon suboxide and with an amorphous carbon layer. The anode material has multilayer-graphene to serve as a carrier, nano-silicon which is adsorbed on the multilayer-graphene and both the multilayer-graphene and the nano-silicon serve as a core, silicon suboxide and the amorphous carbon layer to cover the multilayer-graphene and the nano-silicon, and a plurality of buffering holes which are disposed on the anode material to provide buffering space. An anode material of high quality is realized by coating multilayer-graphene which serves as a carrier of nano-silicon with silicon suboxide and with the amorphous carbon layer.Type: GrantFiled: December 13, 2018Date of Patent: December 29, 2020Assignee: National Chung-Shan Institute of Science and TechnologyInventors: Po-Han Lee, Biing-Jyh Weng, Chuen-Ming Gee, Bo-Wen Chen
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Patent number: 10873077Abstract: A lithium ion secondary battery is disclosed that can inhibit generation of gas due to decomposition of a non-aqueous electrolyte solution. The lithium ion battery includes a cathode, a non-aqueous electrolyte solution and an anode, wherein the cathode includes a conductive material, a layered niobium-containing oxide that coats a surface of the conductive material, and a lithium-containing oxide active material having an upper-limit potential to a redox potential of metal lithium of no less than 4.5 V (vs. Li/Li+).Type: GrantFiled: March 29, 2019Date of Patent: December 22, 2020Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yohei Shindo, Yoshitomo Takebayashi, Sho Ando, Yusuke Shimo
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Patent number: 10873104Abstract: The present invention provides a positive electrode active material for a secondary battery, the positive electrode active material being a secondary particle that includes a primary particle having a rectangular parallelepiped shape, the rectangular parallelepiped having at least one portion of vertices and edges formed in a round shape that is convex outward, wherein 1% to 40% of a total surface area of the secondary particle has open porosity, and the primary particle includes a lithium composite metal oxide of Formula 1 herein so that intercalation and deintercalation of lithium are facilitated, elution of an active material-constituting metal element is suppressed, and excellent structural stability is exhibited, thereby decreasing resistance and improving output and lifespan characteristics when applied to a battery, and a secondary battery comprising the same.Type: GrantFiled: November 30, 2016Date of Patent: December 22, 2020Inventors: Sang Min Park, Wang Mo Jung, Byung Chun Park, Ju Kyung Shin, Ji Hoon Ryu, Sang Wook Lee
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Patent number: 10868300Abstract: A positive active material for a rechargeable lithium battery including a core including at least one selected from a nickel-based composite oxide represented by Chemical Formula 1 or a lithium manganese oxide represented by Chemical Formula 2; and a coating layer on a surface of the core and including a lithium metal oxide represented by Chemical Formula 3, the positive active material having a peak at a 2? value of about 19° to about 22° and another peak at a 2? value of about 40° to about 45° in an X-ray diffraction pattern using a CuK? ray, is disclosed. A method of preparing the same, and a rechargeable lithium battery including the same, are also disclosed. LiNixCoyMn1-x-yO2??Chemical Formula 1 LiaMnbOc??Chemical Formula 2 Li2MO3??Chemical Formula 3 In Chemical Formulae 1 to 3, x, y, a, b, c, and M are the same as in the detailed description.Type: GrantFiled: May 19, 2014Date of Patent: December 15, 2020Assignee: Samsung SDI Co., Ltd.Inventors: Ming-Zi Hong, Do-Hyung Park, Seon-Young Kwon, Joong-Ho Moon, Ji-Hyun Kim, Han-Eol Park, Min-Han Kim, Myong-A Woo, Ki-Hyun Kim, Jong-Seo Choi
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Patent number: 10858265Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery that improves the cycling characteristic and high-temperature storability without impairing the charge/discharge capacity and the output characteristics. A nickel cobalt containing composite hydroxide is obtained by using a batch type crystallization method in which a raw material aqueous solution that includes Ni, Co and Mg is supplied in an inert atmosphere to a reaction aqueous solution that is controlled so that the temperature is within the range 45° C. to 55° C., the pH value is within the range 10.8 to 11.8 at a reference liquid temperature of 25° C., and the ammonium-ion concentration is within the range 8 g/L to 12 g/L. An Al-coated composite hydroxide that is expressed by the general formula: Ni1-x-y-zCoxAlyMgz(OH)2 (where, 0.05?x?0.20, 0.01?y?0.06, and 0.01?z?0.Type: GrantFiled: April 27, 2016Date of Patent: December 8, 2020Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Takehide Honma, Koji Yamaji, Ryozo Ushio
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Patent number: 10862156Abstract: The present invention relates to a positive electrode active material for a secondary battery and a secondary battery including the same, wherein the positive electrode active material includes a core, a shell disposed to surround the core, and a buffer layer which is disposed between the core and the shell and includes pores and a three-dimensional network structure connecting the core and the shell, wherein the core, the shell, and the three-dimensional network structure of the buffer layer each independently includes a polycrystalline lithium composite metal oxide of Formula 1 including a plurality of grains, and the grains have an average grain diameter of 50 nm to 150 nm.Type: GrantFiled: September 28, 2016Date of Patent: December 8, 2020Inventors: Sang Wook Lee, Wang Mo Jung, Byung Chun Park, Ju Kyung Shin, Ji Hoon Ryu, Sang Min Park
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Patent number: 10854874Abstract: This invention discloses a lithium metal oxide powder for a cathode material in a rechargeable battery, consisting of a core and a surface layer, the core having a layered crystal structure comprising the elements Li, M and oxygen, wherein M has the formula M=(Niz(Ni1/2Mn1/2)yCox)1-kAk, with 0.15?x?0.30, 0.20?z?0.55, x+y+z=1 and 0?k?0.1, wherein A is a dopant, wherein the Li content is stoichiometrically controlled with a molar ratio 0.95?Li:M?1.10; and wherein the surface layer comprises the elements Li, M? and oxygen, wherein M? has the formula M?=(Niz?(Ni1/2Mn1/2)y?Cox?)1-k?Ak?, with x?+y?+z?=1 and 0?k??0.1, and wherein y?/(y?+2z?)?1.1*[y/(y+2z)]. The surface layer may also comprise at least 3 mol % Al, the Al content in the surface layer 10 being determined by XPS.Type: GrantFiled: January 20, 2016Date of Patent: December 1, 2020Assignees: Umicore, Umicore Korea Ltd.Inventors: Xin Xia, Jens Paulsen, Shinichi Kumakura, Song-Yi Han
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Patent number: 10847796Abstract: Provided are a lithium nickel metal complex oxide powder having low alkalinity and excellent cycle characteristics, a lithium ion battery positive electrode active material containing the same, a lithium ion battery positive electrode using the active material, and a lithium ion battery having the positive electrode. A lithium nickel metal complex oxide exhibiting excellent cycle characteristics and low alkalinity is successfully produced by controlling the crystal grain size and composition ratio in a lithium nickel metal complex oxide powder.Type: GrantFiled: January 18, 2018Date of Patent: November 24, 2020Assignee: UmicoreInventors: Taku Kojima, Kanichiro Inui
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Patent number: 10840558Abstract: A method for lithiation of an electrode includes providing a roll including an electrode to be lithiated, providing a piece of lithium metal with predetermined weight attached to a conductive material, attaching the conductive material to a current collector of the electrode to be lithiated or to a metal tab connected to or from the electrode to be lithiated, placing the roll, the piece of lithium, and the conductive material in a container, and filling the container with an electrolyte containing a lithium salt.Type: GrantFiled: January 18, 2019Date of Patent: November 17, 2020Assignee: LICAP NEW ENERGY TECHNOLOGY (TIANJIN) CO., LTD.Inventors: Kathleen Qiu, Linda Zhong, Martin Zea, David Kim
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Patent number: 10840510Abstract: Provided is a positive electrode active material that is capable of improving output characteristics when used as positive electrode material for a non-aqueous electrolyte secondary battery. A lithium mixture that is obtained by adding and mixing a lithium compound to a transition metal composite hydroxide that was obtained from a crystallization reaction undergoes calcination in an atmosphere having an oxygen concentration of 4% by volume or greater. In this calcination process, carbon dioxide gas concentration in the atmosphere while the temperature is maintained at a calcination temperature is kept at 10% by volume or less, and preferably kept at 0.01% by volume to 10% by volume. As a result, positive electrode active material is obtained that includes a lithium transition metal composite oxide that is composed of secondary particles that are formed from aggregates of plural primary particles, and that has a carbon content of 0.010% by mass to 0.100% by mass.Type: GrantFiled: July 30, 2015Date of Patent: November 17, 2020Assignee: SUMITOMO METAL MINING CO., LTD.Inventor: Syuhei Oda
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Patent number: 10833329Abstract: Provided are a nickel-based active material for a lithium secondary battery, a method of preparing the nickel-based active material, and a lithium secondary battery including a positive electrode including the nickel-based active material. The nickel-based active material includes at least one secondary particle that includes at least two primary particle structures, the primary particle structures each including a porous inner portion and an outer portion having a radially arranged structure, and the secondary particle including at least two radial centers.Type: GrantFiled: December 1, 2017Date of Patent: November 10, 2020Assignee: Samsung SDI Co., Ltd.Inventors: Jinhwa Kim, Hyunbeom Kim, Jongmin Kim, Wooyoung Yang, Donggyu Chang, Jangsuk Hyun
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Patent number: 10829385Abstract: Provided are a positive electrode active material for nonagueous secondary batteries, the material having a narrow particle-size distribution and a monodisperse property and being capable of increasing a battery capacity; an industrial production method thereof; and a nonaqueous secondary battery using the positive electrode active material and having excellent electrical characteristics. The positive electrode active material is represented by a general formula: Li1+uNixCoyMnzMtO2+? (wherein, 0.05?u?0.95, x+y+z+t=1, 0?x?0.5, 0?y?0.5, 0.5?z<0.8, 0?t?0.1, and M is an additive element and at least one element selected from Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W), has an average particle diameter of 3 to 12 um, and has [(d90?d10)/average particle diameter], an index indicating a scale of particle-size distribution, of 0.60 or less.Type: GrantFiled: May 30, 2012Date of Patent: November 10, 2020Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Satoshi Matsumoto, Shuhei Oda, Katsuya Inoue, Hiroyuki Toya
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Patent number: 10833366Abstract: The embodiment relates to the field of electrolyte selection in lithium ion cells which may employ Li4Ti5O12 compounds as negative electrode material and LiPF6 as the ionic salt component in the cell electrolyte solution. The embodiment further relates to improvements in lithium ion cell performance as a result of selection of specific formulation of electrolyte for lithium ion cells.Type: GrantFiled: April 30, 2013Date of Patent: November 10, 2020Assignee: Altairnano, Inc.Inventors: Mike Coleman, Veselin Manev
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Patent number: 10833328Abstract: A powderous positive electrode material for a lithium secondary battery, the material having the general formula Li1+x[Ni1?a?b?cMaM?bM?c]1?xO2?z; M being either one or more elements of the group Mn, Zr and Ti, M? being either one or more elements of the group Al, B and Co, M? being a dopant different from M and M?, x, a, b and c being expressed in mol with ?0.02?x?0.02, 0?c?0.05, 0.10?(a+b)?0.65 and 0?z?0.05; and wherein the powderous material is characterized by having a BET value ?0.37 m2/g, a Dmax<50 ?m, and a hardness strength index ??(P) of no more than 100%+(1?2a?b)×160% for P=200 MPa, wherein (Formula I) (I) with D 10p=0 being the D10 value of the unconstrained powder (P=0 M Pa), r°(D 10p=0) being the cumulative volume particle size distribution of the unconstrained powder at D 10p=0, and ?p(D 10p=0) being the cumulative volume particle size distribution at D10p=0 of the pressed samples with P being expressed in M Pa.Type: GrantFiled: June 1, 2015Date of Patent: November 10, 2020Assignees: Umicore, Umicore Korea Ltd.Inventors: Maxime Blangero, Da-In Choi, WooRam Cho, JiHye Kim
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Patent number: 10826122Abstract: The present disclosure provides a lithium-ion battery, which comprises: a positive electrode plate containing a positive electrode active material, a negative electrode plate containing a negative electrode active material and an electrolyte. The positive electrode active material comprises: a core and a coating layer coating a surface of the core and comprising boron. The electrolyte comprises a lithium salt, a non-aqueous organic solvent and an electrolyte additive, the electrolyte additive comprises an organic titanium compound. The coating layer of the positive electrode active material of the lithium-ion battery according to the present disclosure contains boron, and the electrolyte of the lithium-ion battery contains the organic titanium compound, under the combined effect of the coating layer containing boron and the electrolyte containing the organic titanium compound, the lithium-ion battery has excellent high temperature cycle performance and excellent high temperature storage performance.Type: GrantFiled: May 16, 2018Date of Patent: November 3, 2020Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITEDInventors: Yingjie Zhan, Jian Yan, Songjun Shi, Lan Xie, Wenhao Liu
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Patent number: 10818912Abstract: A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including a lithium hexafluorophosphate and an additive. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): LixMeyO?F?. The additive is at least one selected from the group consisting of difluorophosphates, tetrafluoroborates, bis(oxalate)borate salts, bis(trifluoromethanesulfonyl)imide salts, and bis(fluorosulfonyl)imide salts.Type: GrantFiled: November 16, 2017Date of Patent: October 27, 2020Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Takayuki Nakatsutsumi, Ryuichi Natsui, Nobuhiko Hojo
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Patent number: 10818916Abstract: Provided are a positive electrode active material for a secondary battery which may exhibit excellent capacity and life characteristics when used in the battery by including a core, and a surface treatment layer disposed on a surface of the core, wherein the core is a secondary particle including a plurality of primary particles, the primary particles include a polycrystalline lithium composite metal oxide of Formula 1 having an average grain diameter of 50 nm to 200 nm, and the surface treatment layer includes a lithium oxide including lithium and at least one metal selected from the group consisting of boron (B), tungsten (W), hafnium (Hf), niobium (Nb), tantalum (Ta), molybdenum (Mo), silicon (Si), tin (Sn), and zirconium (Zr), and a secondary battery including the same, LiaNi1-x-yCoxM1yM3zM2wO2??[Formula 1] (in Formula 1, M1, M2, M3, a, x, y, z, and w are the same as those defined in the specification).Type: GrantFiled: November 30, 2016Date of Patent: October 27, 2020Assignee: LG Chem, Ltd.Inventors: Ju Kyung Shin, Wang Mo Jung, Byung Chun Park, Ji Hoon Ryu, Sang Min Park, Sang Wook Lee
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Patent number: 10811671Abstract: A positive-electrode active material contains a compound that has a crystal structure belonging to a space group FM3-M and that is represented by the composition formula (1): LixAyMezO?F???(1) wherein A denotes Na or K, Me denotes one or two or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr, and the following conditions are satisfied. 1.7?x+y?2.2 0?y?0.2 0.8?z?1.3 1???2.5 0.Type: GrantFiled: November 14, 2017Date of Patent: October 20, 2020Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Ryuichi Natsui, Kensuke Nakura
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Patent number: 10811676Abstract: Provided is a precursor of transition metal oxide represented by chemical formula 1 below.Type: GrantFiled: November 2, 2015Date of Patent: October 20, 2020Assignee: LG Chem, Ltd.Inventors: Ho-Suk Shin, Byung-Chun Park, Jae-Hyun Lee
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Patent number: 10797802Abstract: An optical receiver includes a transimpedance amplifier that converts a current signal corresponding to an optical signal into a voltage signal. The transimpedance amplifier includes an input terminal receiving the current signal, an output terminal outputting the voltage signal, an inverting circuit including a pull-up device that pull-up drives the voltage signal of the output terminal according to the current signal, and a pull-down device that pull-down drives the voltage signal of the output terminal according to the current signal, a feedback resistor electrically connected between the input and output terminals, a first resistor electrically connected between the input terminal and the pull-up device, and a second resistor electrically connected between the input terminal and the pull-down device.Type: GrantFiled: March 22, 2019Date of Patent: October 6, 2020Assignees: SK hynix Inc., KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATIONInventors: Chul Woo Kim, Hyun Su Park, Jin Cheol Sim, Choong Hwan Lee
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Patent number: 10797302Abstract: Provided is a method for producing the positive electrode active material for nonaqueous electrolyte secondary batteries, including a first step of mixing a Li-metal composite oxide powder which is represented by the general formula: LizNi1-x-yCoxMyO2 (where 0?x?0.35, 0?y?0.35, and 0.97?z?1.30 are satisfied, and M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti and Al) and constituted by primary particles and secondary particles, to an alkaline solution with a W compound dissolved therein, and immersing a resulting mixture, followed by solid-liquid separation, to obtain a W mixture with W uniformly dispersed on the surface of the primary particles of the composite oxide, and a second step of heat-treating the W mixture to thereby form a compound containing W and Li on the surface of the primary particles of the composite oxide powder.Type: GrantFiled: April 15, 2016Date of Patent: October 6, 2020Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Yuki Furuichi, Tetsufumi Komukai, Hiroyuki Toya
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Patent number: 10784499Abstract: A positive active material for a rechargeable lithium battery includes a compound represented by Chemical Formula 1, LiaNixCoyMezM1kM2pO2 wherein, 0.9?a?1.1, 0.7?x?0.93, 0<y?0.3, 0<z?0.3, 0.001?k?0.006, 0.001?p?0.005, x+y+z+k+p=1, Me is Mn or Al, M1 is a divalent element, and M2 is a tetravalent element.Type: GrantFiled: April 14, 2017Date of Patent: September 22, 2020Assignee: SAMSUNG SDI CO., LTD.Inventors: Dae-Hoe Lee, Do-Hyung Park, Yong-Chan You, Min-Han Kim
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Patent number: 10784500Abstract: In one aspect, a method for producing a positive electrode active material for a nonaqueous electrolyte secondary battery, includes mixing first lithium nickel composite oxide particles containing lithium tungstate and second lithium nickel composite oxide particles not containing lithium tungstate. The first lithium nickel composite oxide particles have a composition represented by Liz1Ni1-x1-y1Cox1M1y1O2, and include a core material containing secondary particles each corresponding to an aggregation of a plurality of primary particles, and the lithium tungstate existing on at least a part of a surface of the primary particles on a surface of and inside the first lithium nickel composite oxide particles. The second lithium nickel composite oxide particles have a composition represented by Liz2Ni1-x2-y2Cox2M2y2O2, and include secondary particles each corresponding to an aggregation of a plurality of primary particles.Type: GrantFiled: May 1, 2017Date of Patent: September 22, 2020Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Kentaro Kondo, Jun Yokoyama, Yuki Furuichi
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Patent number: 10777815Abstract: A cathode active material that is able to improve storage characteristics without deteriorating charging and discharging capacity is provided. By mixing lithium nickel containing composite oxide particles comprising a layered rock-salt type crystal structure, a lithium compound, and an alkali metal compound; calcining the mixed powder at a temperature range of 800° C. to 1000° C.; washing and removing alkali metal other than lithium; mixing washed calcined particles with a lithium compound again; calcining the mixture in an oxidizing atmosphere at a temperature range of 600° C. to 800° C., lithium nickel containing composite oxide comprising a layered rock-salt type crystal structure and a peak intensity ratio of (003) plane with respect to (104) plane of 1.2 or more that are obtained by X-ray powder diffraction using Cu-K? ray as an X-ray source is obtained.Type: GrantFiled: October 11, 2016Date of Patent: September 15, 2020Assignees: SUMITOMO METAL MINING CO., LTD., SHINSHU UNIVERSITYInventors: Satoshi Kanada, Katsuya Teshima, Nobuyuki Zettsu, Takeshi Kimijima
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Patent number: 10763504Abstract: To provide a transition metal-containing hydroxide, which is a precursor of a lithium-containing composite oxide, with which it is possible to obtain a lithium ion secondary battery excellent in the discharge capacity and cycle characteristics, by using as a cathode active material a lithium-containing composite oxide obtained from the hydroxide. A transition metal-containing hydroxide, which is a precursor of a lithium-containing composite oxide, wherein in a distribution of the logarithmic derivative pore specific surface area relative to the pore size, obtained by BJH method, the proportion of the sum of the logarithmic derivative pore specific surface areas with pore sizes of 10 nm or larger, to 100% of the sum of the logarithmic derivative pore specific surface areas in the entire distribution, is at least 23%.Type: GrantFiled: February 3, 2017Date of Patent: September 1, 2020Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Tomohiro Sakai
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Patent number: 10763507Abstract: The present invention provides a precursor for the production of a positive electrode active material for a secondary battery comprising: a core composed of transition metal hydroxides including nickel(Ni) and manganese(Mn) and further including anions other than hydroxyl groups(OH), or transition metal hydroxides including nickel(Ni), manganese(Mn) and cobalt(Co) and further including anions other than hydroxyl groups(OH); and a shell composed of transition metal hydroxides including cobalt(Co) and further including anions other than hydroxyl groups(OH), and a positive electrode active material for lithium secondary battery produced using the same.Type: GrantFiled: September 9, 2016Date of Patent: September 1, 2020Assignee: LG Chem, Ltd.Inventors: Min Kyu You, Ho Suk Shin
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Patent number: 10756329Abstract: A lithium battery as a secondary battery has a battery cell including a first current collector which has a first face and a second face, a positive electrode active material particle which pierces the first current collector and is exposed from the first face and the second face, an electrolyte layer which covers the positive electrode active material particle exposed from the first face and the second face of the first current collector, a negative electrode as an electrode which is in contact with the electrolyte layer, and a second current collector which is in contact with the negative electrode. The battery cell is hermetically enclosed in a package in a state where one end portion which is a portion of the first current collector is exposed.Type: GrantFiled: October 29, 2018Date of Patent: August 25, 2020Assignee: SEIKO EPSON CORPORATIONInventor: Tomofumi Yokoyama
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Patent number: 10749205Abstract: Disclosed are a method for manufacturing a lithium secondary battery positive active material exhibiting a concentration gradient and a lithium secondary battery positive active material exhibiting a concentration gradient, manufactured by the method, and more particularly, a method for manufacturing a lithium secondary battery positive active material exhibiting a concentration gradient and a lithium secondary battery positive active material exhibiting a concentration gradient, manufactured by the method, the method being characterized by forming a barrier layer so as to maintain a concentration gradient layer even in case of thermal diffusion by a subsequent thermal treatment process.Type: GrantFiled: June 22, 2017Date of Patent: August 18, 2020Assignee: ECOPRO BM CO., LTD.Inventors: Moon Ho Choi, Jik Soo Kim, Jin Kyeong Yun, Suk Yong Jeon, Jae Yong Jung, Yong Chul Sung