Nickel Component Is Active Material Patents (Class 429/223)
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Patent number: 10044034Abstract: A negative electrode material for a nonaqueous electrolyte secondary battery of the embodiment include a granular composite product that includes: an organic resin composition; a metal dispersed in the organic resin composition or a metal and an oxide of the metal dispersed in the organic resin composition; an electroconductive carbonaceous material, wherein an elemental ratio A/B (mass/mass) of carbon (A) and hydrogen (B) is 1 or lower.Type: GrantFiled: September 15, 2015Date of Patent: August 7, 2018Assignee: Kabushiki Kaisha ToshibaInventors: Yasuyuki Hotta, Takashi Kuboki, Tomokazu Morita, Sara Yoshio
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Patent number: 10044066Abstract: Electrolyte compositions comprising novel fluorine-containing carboxylic acid ester solvents are described. The fluorine-containing carboxylic acid ester solvents are represented by the formula R1—C(O)O—R2, wherein R1 is CH3CH2— and R2 is —CH2CHF2, R1 is CH3— and R2 is —CH2CH2CHF2, R1 is CH3CH2— and R2 is —CH2CH2CHF2, R1 is CHF2CH2CH2— and R2 is —CH2CH3, or R1 is CHF2CH2— and R2 is —CH2CH3. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.Type: GrantFiled: March 8, 2013Date of Patent: August 7, 2018Assignee: Solvary SAInventors: Charles J. Dubois, George K. Kodokian, Barbara S Nyland
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Patent number: 10026957Abstract: Li-ion cathode materials with improved performance characteristics and precursors to prepare such materials are disclosed. The precursors consist of complex, mixed alkali transition metal oxides of the formula LixAy(MnaNibMc)O2+d, where M represents one or more selected from transition metal elements beside Ni and Mn, and the groups IIA and IIIA elements of the periodic table, x is between 1 and 1.4, y is between 0.1 and 0.5, and x+y is between 1.1 and 1.5, a+b+c=1, the value of d depends on the proportions and average oxidation states of the cation elements Li, A, Mn, Ni and M such that the combined positive charge of the cation elements is balanced by the number of oxygen anions, A represents one or more elements selected from Na, K and Cs. The Li-ion cathode materials are produced by exchange of element(s) A for Li under mild conditions to limit the degree of structural reorganization that occurs during the reaction.Type: GrantFiled: April 24, 2015Date of Patent: July 17, 2018Assignee: Farasis Energy (Ganzhou) Co., Ltd.Inventors: Keith D. Kepler, Hongjian Liu, Floris Tsang, Robbert Vermeulen, Phillip Hailey, Michael Slater
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Patent number: 10017875Abstract: Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.Type: GrantFiled: March 28, 2011Date of Patent: July 10, 2018Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Hiroyuki Toya, Kensaku Mori, Shin Imaizumi, Kenji Ikeuchi, Toshiyuki Osako
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Patent number: 10020498Abstract: A method for producing coated nickel hydroxide powder for a positive electrode of an alkaline secondary battery wherein the pH of a suspension of a nickel hydroxide powder is kept at 8 to 11.5, and an aqueous cobalt salt solution and an aqueous alkali solution are supplied to the suspension to coat the surface of nickel hydroxide particles with cobalt hydroxide. Then, the pH of a slurry of the cobalt hydroxide-coated nickel hydroxide powder is adjusted to 12.5 to 13.0, and oxygen is supplied to the slurry so that the total amount of oxygen supplied per mole of cobalt in the coating is 30 l/mol or more to oxidize the cobalt hydroxide.Type: GrantFiled: October 12, 2013Date of Patent: July 10, 2018Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Katsuya Kase, Ryuichi Kuzuo, Minoru Shiraoka, Hideo Sasaoka
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Patent number: 10008719Abstract: A positive electrode material includes Li2Ni?M1?M2?O4-?, where 0<(?+?)?2; 0??<0.5; 0<??2; 0???1; 1?(?+?+?)?2.1; 0.8<?/(?+?); M1 is Mn; M2 is at least one selected from Ge and Sn; and Ni and M1 has a local structure of six-coordination. The positive electrode material is used for a positive electrode for nonaqueous-electrolyte secondary battery and a nonaqueous-electrolyte secondary battery.Type: GrantFiled: March 20, 2015Date of Patent: June 26, 2018Assignee: DENSO CORPORATIONInventors: Yoshinori Satou, Shigeki Komine, Nobuo Yamamoto, Yuta Shimonishi, Yuki Tachibana
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Patent number: 10008715Abstract: A cathode material for a lithium-ion secondary battery made of agglomerated particles formed by agglomeration of a plurality of primary particles of a cathode active material represented by General Formula (1) below which are coated with a carbonaceous film, in which, in a case in which a cathode mixture layer including the cathode material, a conductive auxiliary agent, and a binding agent in a weight ratio (the cathode material/the conductive auxiliary agent/the binding agent) of 90:5:5 is calendered on a 30 ?m-thick aluminum current collector at a total applied pressure of 5 t/250 mm, a film thickness change percentage of the cathode mixture layer before and after the calendering is 30% or less, LixAyDzPO4??(1).Type: GrantFiled: March 16, 2017Date of Patent: June 26, 2018Assignee: SUMITOMO OSAKA CEMENT CO., LTDInventors: Ryuuta Yamaya, Susumu Murata, Hirofumi Yasumiishi
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Patent number: 9997776Abstract: Disclosed is an alloy powder for electrodes for nickel-metal hydride storage batteries having a high battery capacity and being excellent in life characteristics and high-temperature storage characteristics. The alloy powder includes a hydrogen storage alloy containing elements L, M, Ni, Co, and E. L includes La as an essential component. L includes no Nd, or when including Nd, the percentage of Nd in L is less than 5 mass %. The percentage of La in the hydrogen storage alloy is 23 mass % or less. M is Mg, Ca, Sr and/or Ba. A molar ratio ? to a total of L and M is 0.045???0.133. A molar ratio x of Ni to the total of L and M is 3.5?x?4.32, and a molar ratio y of Co is 0.13?y?0.5. The molar ratios x and y, and a molar ratio z of E to the total of L and M satisfy 4.78?x+y+z<5.03.Type: GrantFiled: February 19, 2014Date of Patent: June 12, 2018Assignee: Panasonic Intellectual Property Management Co., Ltd.Inventors: Akiko Okabe, Hideaki Ohyama, Shinichi Sumiyama, Yasushi Nakamura, Kiyoshi Hayashi, Hiroki Takeshima, Fumio Kato
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Patent number: 9991513Abstract: A positive active material represented by Formula 1 and a lithium secondary battery having a positive electrode that includes the positive active material are provided: Li1-aAaNixCoyMn1-x-yO2??Formula 1 wherein, in Formula 1, A is an alkali metal; 0.0025?a?0.02; 0.0<x?1.0; and 0.0?y?1.0.Type: GrantFiled: January 20, 2016Date of Patent: June 5, 2018Assignee: Samsung SDI Co., Ltd.Inventors: Jeonjin Choi, Minhan Kim, Joong-Ho Moon, Haneol Park, Kyounghyun Kim, Dohyung Park, Dongjin Kim, Gyuran Jeon, Sun-Ho Kang
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Patent number: 9991515Abstract: Disclosed is a rechargeable lithium battery that includes a positive electrode including a positive active material, a negative electrode including a negative active material, and a non-aqueous electrolyte, wherein the positive active material includes a compound represented by the following Chemical Formula 1, the negative active material includes a silicon-based compound, the compound represented by the above Chemical Formula 1 is included in an amount of about 3 wt % to about 30 wt % based on 100 wt % of the positive active material, and the silicon-based compound is included in an amount of about 3 wt % to about 10 wt % based on 100 wt % of the negative active material. Lix1CO1-yMyO2??Chemical Formula 1 In the above Chemical Formula 1, 1.05<x1<1.10, 0.03<y<0.05 and, M includes one selected from B, Mg, Ca, Sr, Ba, Ti, V, Cr, Fe, Cu, Al, and a combination thereof.Type: GrantFiled: April 30, 2015Date of Patent: June 5, 2018Assignee: Samsung SDI Co., Ltd.Inventors: Young-Ki Kim, Ick-Kyu Choi, Young-Hun Lee, Na-Ri Park, Soon-Rewl Lee, Yong-Chul Park, Hong-Kyu Choi
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Patent number: 9985278Abstract: Disclosed is a high energy density lithium secondary battery including a cathode. The cathode contains, as cathode active materials, a first cathode active material having a layered structure and a second cathode active material having a spinel structure. The amount of the first cathode active material is between 40 and 100 wt % based on the total weight of the cathode active materials. The high density lithium secondary battery further comprises an anode, including crystalline graphite having a specific surface area (with respect to capacity) of 0.005 to 0.013 m2/mAh as an anode active material, as well as a separator.Type: GrantFiled: November 22, 2013Date of Patent: May 29, 2018Assignee: LG Chem, Ltd.Inventors: Chang Joo Han, KyungHee Han, Su-min Park, JiEun Lee
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Patent number: 9979021Abstract: A lithium metal oxide powder for use as a cathode material in a rechargeable battery, consisting of a core material and a surface layer, the core having a layered crystal structure consisting of the elements Li, a metal M and oxygen, wherein the Li content is stoichiometrically controlled, wherein the metal M has the formula M=Co1-aM?a, with 0?a?0.05, wherein M? is either one or more metals of the group consisting of Al, Ga and B; and the surface layer consisting of a mixture of the elements of the core material and inorganic N-based oxides, wherein N is either one or more metals of the group consisting of Mg, Ti, Fe, Cu, Ca, Ba, Y, Sn, Sb, Na, Zn, Zr and Si.Type: GrantFiled: September 16, 2015Date of Patent: May 22, 2018Assignee: UmicoreInventors: Jens Paulsen, Maxime Blangero, Da-In Choi
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Patent number: 9966599Abstract: Provided is lithium titanate that is readily pulverized, and readily dispersed in a binding agent. The lithium titanate is characterized in that the value of a degree of pulverization Zd representing the ratio of the 50% cumulative diameter pre- and post-pulverization is 2 or greater. The lithium titanate is produced by the following steps (1)-(3). (1) a step in which titanyl sulfate or titanium sulfate is thermally hydrolyzed to produce metatitanic acid; (2) a step in which a slurry containing the metatitanic acid is prepared, and the slurry, subsequent to neutralization to bring the pH to 6.0-9.0, undergoes solid-liquid separation, to produce a metatitanic acid-containing titanium starting material having a BET specific surface area of 100-400 m2/g, and in which the sulfuric acid (SO4) content is 0.01-2.0 mass % with respect to the amount of metatitanic acid, on a TiO2-converted basis; and (3) a step in which the titanium starting material and a lithium compound are mixed and baked.Type: GrantFiled: May 30, 2014Date of Patent: May 8, 2018Assignee: ISHIHARA SANGYO KAISHA, LTD.Inventors: Hiroomi Horie, Naoya Nagahashi, Tsunehisa Takeuchi
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Patent number: 9954224Abstract: An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same. [Solution] A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.Type: GrantFiled: December 2, 2010Date of Patent: April 24, 2018Assignees: SUMITOMO METAL MINING CO., LTD., TOYOTA JIDOSHA KABUSHIKI KAISHInventors: Hiroyuki Toya, Shin Imaizumi, Kensaku Mori, Atsushi Fukui, Kenji Ikeuchi, Kazuomi Ryoshi, Toshiyuki Osako, Hiroki Nagai
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Patent number: 9935315Abstract: Certain nickel hydroxide active cathode materials for use in alkaline rechargeable batteries are capable of transferring >1.3 electrons per Ni atom under reversible electrochemical conditions. The specific capacity of the nickel hydroxide active materials is for example ?325 mAh/g. The cathode active materials exhibit an additional discharge plateau near 0.8 V vs. a metal hydride (MH) anode. Ni in an oxidation state of less than 2, such as Ni1+, is able to participate in electrochemical reactions when using the present cathode active materials. It is possible that up to 2.3 electrons, up to 2.5 electrons or more may be transferred per Ni atom under electrochemical conditions.Type: GrantFiled: February 5, 2015Date of Patent: April 3, 2018Assignee: BASF CorporationInventors: Kwo Young, Lixin Wang, William Mays, Benjamin Reichman, Hu Chao-Ian, Diana Wong, Jean Nei
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Patent number: 9923190Abstract: The present invention relates to a method for preparing a positive electrode active material precursor and a positive electrode material for a lithium secondary battery having a concentration-gradient layer using a batch reactor, and to a positive electrode active material precursor and a positive electrode material for a lithium secondary battery prepared by the method.Type: GrantFiled: January 14, 2011Date of Patent: March 20, 2018Assignee: ECOPRO BM CO., LTD.Inventors: Jong-Ryeol Yu, Moon-Ho Choi
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Patent number: 9923195Abstract: Supplemental lithium can be used to stabilize lithium ion batteries with lithium rich metal oxides as the positive electrode active material. Dramatic improvements in the specific capacity at long cycling have been obtained. The supplemental lithium can be provided with the negative electrode, or alternatively as a sacrificial material that is subsequently driven into the negative electrode active material. The supplemental lithium can be provided to the negative electrode active material prior to assembly of the battery using electrochemical deposition. The positive electrode active materials can comprise a layered-layered structure comprising manganese as well as nickel and/or cobalt.Type: GrantFiled: November 29, 2011Date of Patent: March 20, 2018Assignee: Zenlabs Energy, Inc.Inventors: Shabab Amiruddin, Subramanian Venkatachalam, Bing Li, Herman A. Lopez, Sujeet Kumar
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Patent number: 9911518Abstract: A cathode active material for lithium-ion battery is provided, which provides good battery characteristics such as cycle characteristics. The cathode active material for lithium-ion battery is expressed by the composition formula: LixNi1-yMyO?, wherein M is one or more selected from Ti, Cr, Mn, Fe, Co, Cu, Al, Sn, Mg and Zr; 0.9?x?1.2; 0<y?0.5; and 2.0???2.2, wherein the crystallite size obtained by analyzing the XRD pattern is 870 ? or more and the unit lattice volume is 101.70 ?3 or less.Type: GrantFiled: September 30, 2013Date of Patent: March 6, 2018Assignee: JX Nippon Mining & Metals CorporationInventors: Tatsuya Kameyama, Tomoya Tamura
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Patent number: 9911968Abstract: An electrode active material includes particles of a lithium-containing composite oxide represented by the general compositional formula: Li1+xMO2, where ?0.15?x?0.15, and M represents an element group of three or more elements including at least Ni, Co and Mn, wherein the ratios of Ni, Co and Mn to the total elements constituting M satisfy 45?a?90, 5?b?30, 5?c?30 and 10?b+c?55, where the ratios of Ni, Co and Mn are represented by a, b and c, respectively, in units of mol %, the average valence A of Ni in the whole particles is 2.2 to 3.2, the valence B of Ni on the surface of the particles has the relationship: B<A, the average valence C of Co in the whole particles is 2.5 to 3.2, the valence D of Co on the surface of the particles has the relationship: D<C, and the average valence of Mn in the whole particles is 3.5 to 4.2.Type: GrantFiled: March 10, 2010Date of Patent: March 6, 2018Assignee: MAXELL HOLDINGS, LTD.Inventors: Satoshi Kono, Mitsuhiro Kishimi, Atsushi Hatakeyama
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Patent number: 9905850Abstract: Provided are polycrystalline lithium manganese oxide particles represented by Chemical Formula 1 and a method of preparing the same: Li(1+x)Mn(2-x-y-f)AlyMfO(4-z)??<Chemical Formula 1> where M is sodium (Na), or two or more mixed elements including Na, 0?x?0.2, 0<y?0.2, 0<f?0.2, and 0?z?0.2. According to an embodiment of the present invention, limitations, such as the Jahn-Teller distortion and the dissolution of Mn2+, may be addressed by structurally stabilizing the polycrystalline lithium manganese oxide particles. Thus, life characteristics and charge and discharge capacity characteristics of a secondary battery may be improved.Type: GrantFiled: October 15, 2014Date of Patent: February 27, 2018Assignee: LG Chem, Ltd.Inventors: Ick Soon Kwak, Seung Beom Cho, Hwa Seok Chae
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Patent number: 9899674Abstract: [Object] Provided is a means which is capable, with respect to a non-aqueous electrolyte secondary battery, of suppressing a decrease in capacity when the battery is used for a long period of time, and improving cycle characteristics. [Solving Means] Provided is a positive electrode active substance for a non-aqueous electrolyte secondary battery, the positive electrode active substance being a lithium-nickel-manganese-cobalt composite oxide and having true density of 4.40 to 4.80 g/cm3.Type: GrantFiled: February 27, 2014Date of Patent: February 20, 2018Assignee: NISSAN MOTOR CO., LTD.Inventors: Tamaki Hirai, Manabu Kaseda, Osamu Shimamura, Kenji Ohara, Kousuke Hagiyama, Fumihiro Kawamura, Masanori Aoyagi
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Patent number: 9899676Abstract: Certain nickel hydroxide active cathode materials for use in alkaline rechargeable batteries are capable of transferring >1.3 electrons per Ni atom under reversible electrochemical conditions. The specific capacity of the nickel hydroxide active materials is for example ?325 mAh/g. The cathode active materials exhibit an additional discharge plateau near 0.8 V vs. a metal hydride (MH) anode. Ni in an oxidation state of less than 2, such as Ni1+, is able to participate in electrochemical reactions when using the present cathode active materials. It is possible that up to 2.3 electrons, up to 2.5 electrons or more may be transferred per Ni atom under electrochemical conditions.Type: GrantFiled: February 5, 2015Date of Patent: February 20, 2018Assignee: BASF CorporationInventors: Kwo Young, Lixin Wang, William Mays, Benjamin Reichman, Hu Chao-Ian, Diana Wong, Jean Nei
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Patent number: 9887047Abstract: The described embodiments provide an energy storage device that includes a positive electrode including an active material that can store and release ions, a negative electrode including an active material that is a lithiated nano-architectured active material including tin and at least one stress-buffer component, and a non-aqueous electrolyte including lithium. The negative electrode active material is nano-architectured before lithiation.Type: GrantFiled: December 11, 2013Date of Patent: February 6, 2018Assignee: IMRA AMERICA, INC.Inventors: Bing Tan, Zhendong Hu, Guanghui He, Yong Che
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Patent number: 9882246Abstract: An electrochemical energy storing device disclosed herein includes a positive electrode containing a positive-electrode active material, a negative electrode, and a nonaqueous electrolyte solution which is in contact with the positive electrode and the negative electrode. The positive-electrode active material in a discharged state contains at least one selected from the group consisting of an alkali metal chloride, an alkaline-earth metal chloride, and a quaternary alkylammonium chloride. The nonaqueous electrolyte solution contains, as a solvent, an ionic liquid including cations having an alkoxyalkyl group as a component.Type: GrantFiled: May 22, 2015Date of Patent: January 30, 2018Assignees: PANASONIC CORPORATION, KYOTO UNIVERSITYInventors: Toru Matsui, Toshiro Hirai, Jun-ichi Yamaki, Zempachi Ogumi
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Patent number: 9882204Abstract: A nickel composite hydroxide having a volume-average particle size of the secondary particles of 8.0 ?m to 50.0 ?m is obtained, by obtaining a nickel composite hydroxide slurry in a primary crystallization process by providing an aqueous solution having at least a nickel salt and a neutralizer into a reaction vessel while continuously stirring in a state of not containing a complex ion formation agent, and controlling the crystallization reaction so that the ratio of the volume-average particles size of secondary particles with respect to that of the secondary particles finally obtained is 0.2 to 0.6, and producing the nickel composite hydroxide in a secondary crystallization process by continuing the crystallization process while keeping the amount of the obtained slurry constant, continuously removing only the liquid component of the slurry, and performing control so that the slurry has a temperature of 70° C. to 90° C. and a pH value at a standard liquid temperature of 25° C. of 10.0 to 11.0.Type: GrantFiled: June 6, 2013Date of Patent: January 30, 2018Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Kazuomi Ryoshi, Kensaku Mori
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Patent number: 9882247Abstract: A lithium ion battery particularly configured to be able to discharge to a very low voltage, e.g. zero volts, without causing permanent damage to the battery. More particularly, the battery is configured to define a Zero Volt Crossing Potential (ZCP) which is lower than a Damage Potential Threshold (DPT).Type: GrantFiled: September 16, 2013Date of Patent: January 30, 2018Assignee: Quallion LLCInventors: Hisashi Tsukamoto, Clay Kishiyama, Mikito Nagata, Hiroshi Nakahara, Tiehua Piao
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Patent number: 9879344Abstract: Disclosed herein is an electrode active material for a secondary battery, and more particularly to an electrode active material comprising a porous silicon oxide-based composite and the method for preparing a porous silicon oxide-based composite.Type: GrantFiled: August 3, 2012Date of Patent: January 30, 2018Assignee: LG Chem, Ltd.Inventors: Yong Ju Lee, Yoon Ah Kang, Mi Rim Lee, Jung Woo Yoo, Je Young Kim
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Patent number: 9876222Abstract: A nonaqueous electrolyte secondary battery which can suppress the change in structure of a positive electrode active material at a high voltage is provided. The nonaqueous electrolyte secondary battery has a positive electrode including a positive electrode active material which absorbs and releases lithium ions; a negative electrode including a negative electrode active material which absorbs and releases lithium ions; and a nonaqueous electrolyte. The positive electrode active material has a surface to which a rare earth compound is adhered and includes a lithium cobalt composite oxide containing at least one type selected from the group consisting of Ni, Mn, Ca, Cu, Zn, Sr, Ge, Sn, Si, P, Nb, Mo, S, and W, and charge is performed so that the potential of the positive electrode is 4.53 V or more with reference to lithium.Type: GrantFiled: September 10, 2013Date of Patent: January 23, 2018Assignee: SANYO Electric Co., Ltd.Inventors: Yuu Takanashi, Kazuhiro Hasegawa, Sho Tsuruta, Atsushi Fukui
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Patent number: 9876227Abstract: The sealed nonaqueous electrolyte secondary battery includes a nonaqueous electrolyte containing a gas generator that is decomposed to generate a gas when a prescribed battery voltage is exceeded, and a battery case that includes a current interrupt device that operates when the pressure within the battery case rises accompanying the gas generation. A positive electrode (10) has a positive electrode mixture layer (14) that contains at least a positive electrode active material (16). This positive electrode mixture layer (14) contains, as conductive agents, electroconductive carbon particles (18) and an expanded graphite (17) that has an average pore diameter of 0.2 ?m to 0.5 ?m.Type: GrantFiled: October 15, 2013Date of Patent: January 23, 2018Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yutaka Oyama, Keiichi Takahashi
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Patent number: 9876228Abstract: Process for manufacturing nickel-cobalt composite represented by Ni1?x?yCoxMnyMz(OH)2 (where, 0.05?x?0.95, 0?y?0.55, 0?z?0.1, x+y+z<1, and M is at least one metal-element selected from Al, Mg, and the like), includes: forming seed particle, while reaction solution having mixed solution containing metal compounds and ammonia solution containing ammonium ion supply source at discharge head of an impeller from 50-100 m2/s2, the concentration of nickel ions is maintained within range 0.1-5 ppm by mass, whereby seed particles are formed; and growing seed particle wherein solution is obtained by supplying mixed and ammonium solutions to reaction solution is agitated with a concentration of nickel ions being maintained within range 5-300 ppm by mass and higher than the concentration of nickel ions in seed particle formation, whereby seed particles are grown up.Type: GrantFiled: October 5, 2016Date of Patent: January 23, 2018Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Katsuya Kase, Yasutaka Kamata
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Patent number: 9876210Abstract: As a nonaqueous electrolyte secondary battery porous layer having an excellent cycle characteristic, provided is a nonaqueous electrolyte secondary battery porous layer containing: an inorganic filler; and a polyvinylidene fluoride-based resin, the nonaqueous electrolyte secondary battery porous layer containing the inorganic filler in an amount of not less than 50% by weight relative to a total weight of the inorganic filler and the polyvinylidene fluoride-based resin, the polyvinylidene fluoride-based resin containing an ?-form polyvinylidene fluoride-based resin and a ?-form polyvinylidene fluoride-based resin, assuming that a sum of (i) an amount of the ?-form polyvinylidene fluoride-based resin and (ii) an amount of the ?-form polyvinylidene fluoride-based resin is 100 mol %, the amount of the ?-form polyvinylidene fluoride-based resin being not less than 45 mol %.Type: GrantFiled: January 4, 2017Date of Patent: January 23, 2018Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Toshihiko Ogata, Chikara Murakami
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Patent number: 9859550Abstract: A lithium metal oxide powder for use as a cathode material in a rechargeable battery, consisting of a core material and a surface layer, the core having a layered crystal structure consisting of the elements Li, a metal M and oxygen, wherein the Li to M molar ratio is between 0.98 and 1.01, and preferably between 0.99 and 1.00, wherein the metal M has the formula M=Co1-aM?a, with 0?a?0.05, wherein M? is either one or more metals of the group consisting of Al, Ga and B; and the surface layer consisting of a mixture of the elements of the core material and inorganic N- and N?-based oxides, wherein N is either one or more metals of the group consisting of Mg, Ti, Fe, Cu, Ca, Ba, Sn, Sb, Na, Zn, and Si; and wherein N? is either one or more metals of the group consisting of Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, Sc, Ce, Pr, Nd, Gd, Dy, and Er.Type: GrantFiled: November 12, 2013Date of Patent: January 2, 2018Assignees: Umicore, Umicore Korea Ltd.Inventors: Maxime Blangero, KyuBo Kim, Da-In Choi
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Patent number: 9847525Abstract: A precursor of a modified ternary material for a lithium ion battery positive material belongs to the technical field of application of lithium ion battery positive materials. A molecular formula of the precursor is: (Ni1/3Co1/3Mn1/3)(OH)2, and the precursor consists of three layers. An inner layer of the precursor is a ternary material with the Co content of more than ? and equal Ni and Mn content, and the molecular formula of the inner layer of the precursor is: (Ni1/3?xCol/3+2xMn1/3?x(OH)2, where 0<x<?. An outer layer of the precursor is a ternary material with the Co content of greater than 0 to ? and equal Ni and Mn content, and the molecular formula of the outer layer of the precursor is: (Ni0.5?yCo2yMn0.5?y)(OH)2, where 0<y<?. An intermediate layer of the precursor is a concentration gradient composite material of the two materials of the inner layer and the outer layer of the precursor.Type: GrantFiled: October 26, 2012Date of Patent: December 19, 2017Assignee: Hubei ZTE Advanced Materials Co., Ltd.Inventors: Jun Zhang, Jian Guo, Lianqi Zhang, Ruijuan Yang, Peiyu Hou
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Patent number: 9843044Abstract: According to one embodiment, a positive electrode includes a positive electrode layer and a positive electrode current collector. The positive electrode layer includes a positive electrode active material including a first oxide represented by the following formula (?) and/or a second oxide represented by the following formula (?). The positive electrode layer has an intensity ratio falling within a range of 0.25 to 0.7. The ratio is represented by the following formula (1) in an X-ray diffraction pattern obtained by using CuK? radiation for a surface of the positive electrode layer.Type: GrantFiled: March 10, 2017Date of Patent: December 12, 2017Assignee: KABUSHIKI KAISHA TOSHIBAInventors: Hidesato Saruwatari, Takuya Iwasaki, Koji Takazawa, Norio Takami
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Patent number: 9825287Abstract: An active material for an electrochemical device wherein a surface of the active material is modified by a surface modification agent, wherein the surface modification agent is an organometallic compound.Type: GrantFiled: June 19, 2015Date of Patent: November 21, 2017Assignee: UCHICAGO ARGONNE, LLCInventors: Zonghai Chen, Khalil Amine, Ilias Belharouak
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Patent number: 9822015Abstract: The present invention provides a method of producing a lithium mixed metal oxide, a lithium mixed metal oxide and a nonaqueous electrolyte secondary battery. The method includes a step of calcining a mixture of one or more compounds of M wherein M is one or more elements selected from the group consisting of nickel, cobalt and manganese, and a lithium compound, in the presence of one or more inactive fluxes selected from the group consisting of a fluoride of A, a chloride of A, a carbonate of A, a sulfate of A, a nitrate of A, a phosphate of A, a hydroxide of A, a molybdate of A and a tungstate of A, wherein A is one or more elements selected from the group consisting of Na, K, Rb, Cs, Ca, Mg, Sr and Ba. The lithium mixed metal oxide contains nickel, cobalt and manganese, has a BET specific surface area of from 3 m2/g to 15 m2/g, and has an average particle diameter within a range of 0.1 ?m or more to less than 1 ?m, the diameter determined by a laser diffraction scattering method.Type: GrantFiled: December 2, 2010Date of Patent: November 21, 2017Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Satoshi Shimano, Kenji Nakane, Cedric Pitteloud, Kenji Takamori, Yuichiro Imanari
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Patent number: 9825291Abstract: A method of preparing a positive active material for a lithium secondary battery represented by the following Chemical Formula 1 (LiwNixCoyMn1-x-y-zMzO2) includes: (a) preparing a metal salt aqueous solution including a lithium raw material, a manganese raw material, a nickel raw material, and a cobalt raw material; (b) wet-pulverizing the metal salt aqueous solution using beads having a particle diameter of 0.05 to 0.30 mm at 2000 to 6000 rpm for 2 to 12 hours to prepare a slurry; (c) adding a carbon source to the slurry; (d) spray-drying the slurry of the step (c) to prepare a mixed powder; and (e) heat-treating the mixed powder.Type: GrantFiled: September 21, 2012Date of Patent: November 21, 2017Assignee: KOREA ELECTRONICS TECHNOLOGY INSTITUTEInventors: Jun Ho Song, Young Jun Kim, Jae-Hun Kim, Kyoung Joon Lee, Min-Woo Lee
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Patent number: 9825289Abstract: Stabilized lithium powder according to an embodiment of this disclosure contains lithium particles and transition metal. Each lithium particle has a stabilized film on a surface thereof; the stabilized film contains an inorganic compound; and main transition metal, which is contained the most in the transition metal, is contained by 0.5 ×10?3 wt % or more and 11.5×10?3 wt % or less.Type: GrantFiled: December 7, 2015Date of Patent: November 21, 2017Assignee: TDK CORPORATIONInventors: Masahiro Tsuchiya, Tomohiko Hasegawa, Yuji Yamamoto, Kazuma Akimoto
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Patent number: 9819012Abstract: Methods of making high-energy cathode active materials for primary alkaline batteries are described. The primary batteries include a cathode having an alkali-deficient nickel(IV)-containing oxide including one or more metals such as Co, Mg, Al, Ca, Y, Mn, and/or non-metals such as B, Si, Ge or a combination of metal and/or non-metal atoms as dopants partially substituted for Ni and/or Li in the crystal lattice; an anode; a separator between the cathode and the anode; and an alkaline electrolyte solution.Type: GrantFiled: December 28, 2016Date of Patent: November 14, 2017Assignee: DURACELL U.S. OPERATIONS, INC.Inventors: Jennifer Anne Nelson, Paul Albert Christian, Kirakodu S. Nanjundaswamy, Fan Zhang
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Patent number: 9812702Abstract: To provide a lithium ion secondary battery capable of suppressing thermal run-away when internal short circuiting occurs. The lithium ion secondary battery includes: a positive electrode including a current collector, a positive electrode active material layer that is formed on the current collector and that contains a lithium-containing complex oxide having a layered rock salt structure and being represented by general formula: LiaNibCocMndDeOf (0.2?a?1; b+c+d+e=1; 0?e<1; D is at least one element selected from Li, Fe, Cr, Cu, Zn, Ca, Mg, S, Si, Na, K, and Al; 1.7?f?2.1), and a thermal run-away suppressing layer formed on the positive electrode active material layer and containing a lithium transition metal silicate; and a negative electrode including a negative electrode active material. A ratio of the mass of the lithium-containing complex oxide with respect to the mass of the lithium transition metal silicate in the positive electrode is not lower than 1.5.Type: GrantFiled: July 17, 2014Date of Patent: November 7, 2017Assignees: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI, NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGYInventors: Yuta Ikeuchi, Toshikatsu Kojima, Tetsuo Sakai, Tatsuya Eguchi, Hitoshi Aikiyo, Akira Kojima
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Patent number: 9812709Abstract: A lithium secondary battery includes a positive electrode, a negative electrode, and an electrolyte solution. The positive electrode contains a positive electrode active material including element M2 incorporated in a crystal structure in a surface layer area of a complex oxide, the oxide including the element M1 and being represented by the following formula (1), M2 being different from M1. The element M2 is at least one kind selected from the group consisting of magnesium Mg, calcium Ca, titanium Ti, zirconium Zr, sulfur S, fluorine F, iron Fe, copper Cu, boron B, aluminum Al, phosphorus P, carbon C, manganese Mn, nickel Ni, and cobalt Co. Li1+a(MnbCocNi1?b?c)1?aM1dO2?e??(1) M1 is at least one kind of aluminum, magnesium, zirconium, titanium, barium Ba, boron, silicon Si, and iron, a satisfies 0<a<0.25, b satisfies 0.5?b<0.7, c satisfies 0?c<1?b, d satisfies 0.01?d?0.2, and e satisfies 0?e?1.Type: GrantFiled: December 14, 2011Date of Patent: November 7, 2017Assignee: SONY CORPORATIONInventors: Kazuaki Endoh, Akira Takamuku, Masaharu Senoue, Guohua Li, Kenichi Kawase, Yosuke Hosoya
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Patent number: 9806339Abstract: An electrode active material comprising in major proportions a monoclinic titanium-niobium composite oxide represented by the formula TiNbxO(2+5x/2), wherein X is from 1.90 or more to less than 2.00.Type: GrantFiled: February 20, 2015Date of Patent: October 31, 2017Assignees: TITAN KOGYO KABUSHIKI KAISHA, KABUSHIKI KAISHA TOSHIBAInventors: Kiyoshi Nakahara, Toshimasa Seki, Hidenori Ishioka, Wataru Mino, Yasuhiro Harada, Norio Takami, Hiroki Inagaki
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Patent number: 9786953Abstract: Provided is a non-aqueous electrolyte secondary battery combining excellent input/output performance with great durability (cycle characteristics) and an assembly thereof. The present invention provides a non-aqueous electrolyte secondary battery assembly. The positive electrode has a maximum operating voltage of 4.3 V or higher relative to lithium metal, comprising a positive electrode active material and an ion-conductive inorganic phosphate compound. The non-aqueous electrolyte solution comprises a supporting salt, an oxalatoborate-type compound, and a non-aqueous solvent. The non-aqueous solvent is formed of a non-fluorinated solvent. This invention also provides a non-aqueous electrolyte secondary battery obtained by charging the non-aqueous electrolyte secondary battery assembly.Type: GrantFiled: April 13, 2015Date of Patent: October 10, 2017Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Takeshi Abe, Toshiyuki Kawai, Akira Koyama
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Patent number: 9786898Abstract: A secondary battery and a secondary battery array are disclosed. In one aspect, the secondary battery includes an electrode assembly and a battery case accommodating the electrode assembly. The battery also includes a plurality of lead terminals comprising a first pair of lead terminals having opposite polarities and outwardly extending from the electrode assembly to protrude from a first side of the battery case and a second pair of lead terminals having opposite polarities and outwardly extending from the electrode assembly to protrude from a second side of the battery case opposing the first side. The battery further includes a plurality of insulation members respectively extending along the first and second pairs of lead terminals to at least partially cover the lead terminals.Type: GrantFiled: July 9, 2015Date of Patent: October 10, 2017Assignee: Samsung SDI Co., Ltd.Inventor: Sangdo Heo
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Patent number: 9786902Abstract: An electrode for battery has an electrode mixture containing a binder and an active material particle selected from at least one of a carbonaceous material, a metal particle and a metal oxide particle formed on a current collector. When cutting strength of an interface between the current collector and the electrode mixture is represented by “a” and cutting strength in a horizontal direction within the electrode mixture is represented by “b”, the “a” and “b” satisfy a relation of a/b<1.Type: GrantFiled: March 14, 2014Date of Patent: October 10, 2017Assignee: Kabushiki Kaisha ToshibaInventors: Yasuyuki Hotta, Takashi Kuboki, Tomokazu Morita
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Patent number: 9780369Abstract: The present invention is to provide a cathode active material configured to increase, when used in a lithium battery, the discharge capacity of the lithium battery higher than conventional lithium batteries, and a lithium battery including the cathode active material. Presented is a cathode active material for lithium batteries, wherein the cathode active material is represented by the following composition formula (1) and has a rock salt type crystal structure including formula (1): Li2Ni1-x-yCoxMnyTiO4 wherein x and y are real numbers that satisfy x>0, y>0 and x+y<1.Type: GrantFiled: November 12, 2013Date of Patent: October 3, 2017Assignees: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Shigeto Okada, Ayuko Kitajou, Ryuichi Tsuji, Jun Yoshida, Shinji Nakanishi
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Patent number: 9778212Abstract: A method for determining an amount of lithium in a lithium-ion battery electrode sample includes a step of determining powder X-ray diffraction peaks of the lithium-ion battery electrode sample. The powder X-ray diffraction peaks of the lithium-ion battery electrode sample are compared with a set of lithium-containing samples having pre-determined lithium concentrations to determine the amount of lithium in the lithium-ion battery electrode sample.Type: GrantFiled: October 31, 2014Date of Patent: October 3, 2017Assignee: GM Global Technology Operations LLCInventors: Misle M. Tessema, Michael P. Balogh
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Patent number: 9774036Abstract: A method for manufacturing a positive active material for a nonaqueous electrolyte secondary battery having both thermal stability and charge-discharge capacity at a high level as well as excellent cycle characteristics. The method for manufacturing a positive active material for a nonaqueous electrolyte secondary battery includes: a step of adding a niobium salt solution and an acid simultaneously to a slurry of a nickel-containing hydroxide, and controlling the pH of the slurry at between 7 and 11 on a 25° C. basis to obtain a nickel-containing hydroxide coated with a niobium compound; a step of mixing the nickel-containing hydroxide coated with the niobium compound with a lithium compound to obtain a lithium mixture; and a step of firing the lithium mixture in an oxidizing atmosphere at 700° C. to 830° C. to obtain a lithium-transition metal composite oxide.Type: GrantFiled: August 13, 2013Date of Patent: September 26, 2017Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Masanori Takagi, Haruki Kaneda, Hiroko Oshita, Kensaku Mori
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Patent number: 9764962Abstract: The present invention provides lithium composite compound particles having good high-temperature storage property and excellent cycle characteristics as an active substance for a non-aqueous electrolyte secondary battery, and a secondary battery using the lithium composite compound particles. The Li—Ni composite oxide particles for a non-aqueous electrolyte secondary battery according to the present invention have a BET specific surface area of 0.05 to 0.8 m2/g; an atomic ratio (Ma/Ni) of a concentration of an amphoteric metal to a concentration of Ni on an outermost surface of the respective Li—Ni composite oxide particles is 2 to 6; and the concentration of the amphoteric metal on the outermost surface of the respective Li—Ni composite oxide particles is higher than a concentration of the amphoteric metal at a position spaced by 50 nm from the outermost surface toward a center of the respective Li—Ni composite oxide particles.Type: GrantFiled: April 12, 2012Date of Patent: September 19, 2017Assignee: TODA KOGYO CORPORATIONInventors: Taiki Imahashi, Hiroyasu Watanabe, Kazuhiko Kikuya, Hideaki Sadamura
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Patent number: 9761868Abstract: There is provided a lithium-transition metal oxide powder with a coating layer containing lithium niobate formed on a part or the whole part of a surface of a lithium-transition metal oxide particle and having a low powder compact resistance, and a positive electrode active material for a lithium ion battery containing the lithium-transition metal oxide powder. Specifically, there is provided the lithium-transition metal oxide powder composed of a lithium-transition metal oxide particle with a part or the whole part of a surface coated with a coating layer containing lithium niobate, wherein a carbon-content is 0.03 mass % or less.Type: GrantFiled: September 21, 2011Date of Patent: September 12, 2017Assignee: DOWA HOLDINGS CO., LTD.Inventor: Akira Nagatomi