Manganese Component Is Active Material Patents (Class 429/224)
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Publication number: 20140205905Abstract: An electrode material for use in an electrochemical cell, like a lithium-ion battery, is provided. The electrode material may be a negative electrode comprising graphite, silicon, silicon-alloys, or tin-alloys, for example. By avoiding deposition of transition metals, the battery substantially avoids charge capacity fade during operation. The surface coating is particularly useful with negative electrodes to minimize or prevent deposition of transition metals thereon in the electrochemical cell. The coating has a thickness of less than or equal to about 40 nm. Methods for making such materials and using such coatings to minimize transition metal deposition in electrochemical cells are likewise provided.Type: ApplicationFiled: January 18, 2013Publication date: July 24, 2014Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Xingcheng Xiao, Junghyun Kim, Zhongyi Liu
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Patent number: 8784770Abstract: Provided is a lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 (M, x and y are as defined in the specification) having mixed transition metal oxide layers (“MO layers”) comprising Ni ions and lithium ions, wherein lithium ions intercalate into and deintercalate from the MO layers and a portion of MO layer-derived Ni ions are inserted into intercalation/deintercalation layers of lithium ions (“reversible lithium layers”) thereby resulting in the interconnection between the MO layers. The lithium mixed transition metal oxide of the present invention has a stable layered structure and therefore exhibits improved stability of the crystal structure upon charge/discharge. In addition, a battery comprising such a cathode active material can exhibit a high capacity and a high cycle stability.Type: GrantFiled: March 13, 2013Date of Patent: July 22, 2014Assignee: LG Chem, Ltd.Inventors: Hong Kyu Park, Sun sik Shin, Sin young Park, Ho suk Shin, Jens M. Paulsen
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Publication number: 20140199597Abstract: The present disclosure provides an embodiment of an integrated structure that includes a first electrode of a first conductive material embedded in a first semiconductor substrate; a second electrode of a second conductive material embedded in a second semiconductor substrate; and a electrolyte disposed between the first and second electrodes. The first and second semiconductor substrates are bonded together through bonding pads such that the first and second electrodes are enclosed between the first and second semiconductor substrates. The second conductive material is different from the first conductive material.Type: ApplicationFiled: January 15, 2013Publication date: July 17, 2014Applicant: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Chyi-Tsong Ni, I-Shi Wang, Yi Hsun Chiu, Ching-Hou Sue
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Patent number: 8778536Abstract: Provided are a lithium manganese oxide positive active material for a lithium ion secondary battery and a lithium ion secondary battery including the same. The lithium manganese oxide positive active material includes a spinel lithium manganese oxide of three or more types of particles having different sizes mixed therein, wherein first type particles have an average diameter of 5 ?m or greater, second type particles have an average diameter of 1 ?m or less, third type particles have an average diameter of 200 nm or less, and the average diameter of the second type particles is greater than that of the third type particles.Type: GrantFiled: September 5, 2012Date of Patent: July 15, 2014Assignee: Samsung Fine Chemicals Co., Ltd.Inventors: Shin Jung Choi, Sung Nim Jo
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Publication number: 20140193714Abstract: A cathode active material including a lithium metal oxide composite having a first domain and a second domain and represented by Formula 1: x[Li2-y(M1)1-z(M2)y+zO3]-(1?x)[LiMeO2]??Formula 1 wherein 0<x<1, 0?y<1, 0?z<1, 0<y+z<1, M1 includes at least one transition metal, M2 includes at least one metal selected from magnesium (Mg), aluminum (Al), vanadium (V), zinc (Zn), molybdenum (Mo), niobium (Nb), lanthanum (La), and ruthenium (Ru), and Me includes at least one metal selected from nickel (Ni), cobalt (Co), manganese (Mn), iron (Fe), chromium (Cr), titanium (Ti), copper (Cu), aluminum (Al), magnesium (Mg), zirconium (Zr), and boron (B).Type: ApplicationFiled: July 30, 2013Publication date: July 10, 2014Applicants: Samsung Fine Chemicals Co., Ltd., Samsung SDI Co., Ltd.Inventors: Myung-hoon KIM, Jae-gu YOON, Min-sik PARK, Jin-hwan PARK
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Publication number: 20140193708Abstract: In an aspect, a positive active material composition for a rechargeable lithium battery including a positive active material coated with a vanadium pentaoxide (V2O5) and an aqueous binder, a positive electrode including the same, and a rechargeable lithium battery including the positive electrode is disclosed.Type: ApplicationFiled: May 6, 2013Publication date: July 10, 2014Applicant: Samsung SDI Co., Ltd.Inventors: Seung-Hun Han, Myung-Duk Lim, Chae-Woong Cho
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Patent number: 8771873Abstract: A lithium secondary battery includes an electrode assembly having a positive electrode (1), a negative electrode (2) having a negative electrode current collector and a negative electrode active material layer formed on a surface of the negative electrode current collector and composed of a binder and negative electrode active material particles containing silicon and/or a silicon alloy, and a separator (3) interposed between the electrodes. The electrode assembly is impregnated with a non-aqueous electrolyte. The binder contains a polyimide resin represented by the following chemical formula (1): where R contains at least a benzene ring, and n is within the range of from 10 to 100,000, and the negative electrode active material particles have an average particle size of 5 ?m or greater.Type: GrantFiled: June 29, 2007Date of Patent: July 8, 2014Assignee: SANYO Electric Co., Ltd.Inventors: Atsushi Fukui, Hiroshi Minami, Mariko Torimae, Yasuyuki Kusumoto
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Patent number: 8771875Abstract: A substance includes an oxide including at least one element selected from the group including cobalt Co, nickel Ni, manganese Mn, iron Fe, and copper Cu; and silicon Si chemically bonded to the surface of the oxide. Also, a battery includes a cathode, an anode, and an electrolyte, wherein the cathode includes an oxide including at least one selected from the group including cobalt Co, nickel Ni, manganese Mn, iron Fe, and copper Cu; and a substance including silicon Si chemically bonded to the surface of the oxide.Type: GrantFiled: August 28, 2008Date of Patent: July 8, 2014Assignee: Sony CorporationInventors: Yoshinori Gamoh, Hiroshi Imoto
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Publication number: 20140186711Abstract: In an alkaline secondary battery including a gelled negative electrode containing zinc alloy powder, an aspect ratio of a particle of the zinc alloy powder is within a range of 2.0-2.4, and the zinc alloy contains 150-350 ppm of bismuth, and 600-1500 ppm of indium.Type: ApplicationFiled: December 5, 2011Publication date: July 3, 2014Inventors: Jun Nunome, Fumio Kato, Machiko Tsukiji
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Publication number: 20140186707Abstract: A method is provided for fabricating a battery using an anode preloaded with consumable metals. The method forms an ion-permeable membrane immersed in an electrolyte. A preloaded anode is immersed in the electrolyte, comprising MeaX, where X is a material such as carbon, metal capable of being alloyed with Me, intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. Me is a metal such as alkali metals, alkaline earth metals, and combinations of the above-listed metals. A cathode is also immersed in the electrolyte and separated from the preloaded anode by the ion-permeable membrane. The cathode comprises M1YM2Z(CN)N.MH2O. After a plurality of initial charge and discharge operations are preformed, an anode is formed comprising MebX overlying the current collector in a battery discharge state, where 0?b<a.Type: ApplicationFiled: March 6, 2014Publication date: July 3, 2014Applicant: Sharp Laboratories of America, Inc.Inventors: Yuhao Lu, Long Wang, Jong-Jan Lee
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Publication number: 20140186716Abstract: A protected active metal electrode and a device with the electrode are provided. The protected active metal electrode includes an active metal substrate and a protection layer on a surface of the active metal substrate. The protection layer at least includes a metal thin film covering the surface of the active metal substrate and an electrically-conductive thin film covering a surface of the metal thin film. A material of the metal thin film is Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W. A material of the electrically-conductive thin film is selected from nitride of a metal in the metal thin film, carbide of a metal in the metal thin film, a diamond-like carbon (DLC), and a combination thereof.Type: ApplicationFiled: December 25, 2013Publication date: July 3, 2014Applicant: Industrial Technology Research InstituteInventors: Jin-Bao Wu, Li-Duan Tsai, Jia-Jen Chang, Ming-Sheng Leu, Jenn-Yeu Hwang, Chun-Lung Li
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Publication number: 20140186700Abstract: A battery has an anode, a separator adjacent the anode, and a cathode adjacent the separator opposite the anode, the cathode comprising interdigitated stripes of materials, one of the materials forming a pore channel.Type: ApplicationFiled: December 27, 2012Publication date: July 3, 2014Applicant: PALO ALTO RESEARCH CENTER INCORPORATEDInventors: CHANG-JUN BAE, ERIC J. SHRADER, CORIE LYNN COBB
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Publication number: 20140186706Abstract: A method is presented for fabricating an anode preloaded with consumable metals. The method provides a material (X), which may be one of the following materials: carbon, metals able to be electrochemically alloyed with a metal (Me), intercalation oxides, electrochemically active organic compounds, and combinations of the above-listed materials. The method loads the metal (Me) into the material (X). Typically, Me is an alkali metal, alkaline earth metal, or a combination of the two. As a result, the method forms a preloaded anode comprising Me/X for use in a battery comprising a M1YM2Z(CN)N·MH2O cathode, where M1 and M2 are transition metals. The method loads the metal (Me) into the material (X) using physical (mechanical) mixing, a chemical reaction, or an electrochemical reaction. Also provided is preloaded anode, preloaded with consumable metals.Type: ApplicationFiled: March 6, 2014Publication date: July 3, 2014Applicant: Sharp Laboratories of America, Inc.Inventors: Long Wang, Yuhao Lu, Jong-Jan Lee
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Patent number: 8765305Abstract: The present invention relates to a cathode active material for a lithium secondary battery and a process for preparing the same. In accordance with the present invention, the cathode active material having a high packing density was designed and synthesized and thus provided is a cathode active material for a lithium secondary battery exhibiting structural stability such as improved characteristics for charge/discharge, service life and high-rate and thermal stability, by modifying surface of the electrode active material with amphoteric or basic compounds capable of neutralizing acid produced around the cathode active material.Type: GrantFiled: November 17, 2004Date of Patent: July 1, 2014Assignee: Industry-University Cooperation Foundation, Hanyang UniversityInventors: Yang Kook Sun, Myoung Hun Lee, Yoon Jung Kang, Gil Ho Kim
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Patent number: 8765304Abstract: According to one embodiment, a non-aqueous electrolyte battery includes an outer case, a negative electrode, a positive electrode including a current collector and a positive electrode layer formed on surface of the current collector and opposed to the negative electrode layer, and a non-aqueous electrolyte, wherein the positive electrode layer includes a layered lithium nickel cobalt manganese composite oxide and a lithium cobalt composite oxide, the positive electrode layer has a pore volume with a pore diameter of 0.01 to 1.0 ?m, the pore volume being 0.06 to 0.25 mL per 1 g of a weight of the positive electrode layer, and a pore surface area within the pore volume range is 2.4 to 8 m2/g.Type: GrantFiled: June 18, 2013Date of Patent: July 1, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Yoshiyuki Isozaki, Hidesato Saruwatari, Yoshinao Tatebayashi, Takashi Kuboki, Norio Takami
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Patent number: 8765306Abstract: Improved cycling of high voltage lithium ion batteries is accomplished through the use of a formation step that seems to form a more stable structure for subsequent cycling and through the improved management of the charge-discharge cycling. In particular, the formation charge for the battery can be performed at a lower voltage prior to full activation of the battery through a charge to the specified operational voltage of the battery. With respect to management of the charging and discharging of the battery, it has been discovered that for the lithium rich high voltage compositions of interest that a deeper discharge can preserve the cycling capacity at a greater number of cycles. Battery management can be designed to exploit the improved cycling capacity obtained with deeper discharges of the battery.Type: GrantFiled: March 26, 2010Date of Patent: July 1, 2014Assignee: Envia Systems, Inc.Inventors: Shabab Amiruddin, Subramanian Venkatachalam, Herman A. Lopez, Sujeet Kumar
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Publication number: 20140178749Abstract: In an aspect, a positive active material for a rechargeable lithium battery that includes a first positive active material; and a second positive active material including LiaMn1-xMxO2 (M is selected from Co, Ni, Mn, Fe. Cu, V, Si, Al, Sn, Pb, Sn, Ti, Sr, Mg, Ca or a combination thereof; x is 0?x?1.0; and a is 0.9?a?1.1) is disclosed.Type: ApplicationFiled: July 23, 2013Publication date: June 26, 2014Applicant: SAMSUNG SDI CO., LTD.Inventors: Jung-Woo AN, Sumihito ISHIDA
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Publication number: 20140178758Abstract: Disclosed is a device for producing an electric current and a method for making the same. The device for producing an electric current, comprising: an anode comprising a stack formed by alternately stacking of at least one Si layer and at least one carbon material layer, and a LiPON layer on the stack; a cathode; and an electrolyte between the anode and the cathode.Type: ApplicationFiled: December 24, 2012Publication date: June 26, 2014Applicant: EPISTAR CORPORATIONInventors: Chih-Jung CHEN, Shu-Fen HU, Ru-Shi LIU, Tai-Feng HUNG
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Publication number: 20140178759Abstract: A composition comprising at least one graphene-supported metal oxide monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds, wherein the graphene sheets are coated by at least one metal oxide such as iron oxide or titanium oxide. Also provided is an electrode comprising the aforementioned graphene-supported metal oxide monolith, wherein the electrode can be substantially free of any carbon-black and substantially free of any binder.Type: ApplicationFiled: March 15, 2013Publication date: June 26, 2014Applicant: LAWRENCE LIVERMORE NATIONAL SECURITY, LLCInventor: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
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Publication number: 20140170493Abstract: The disclosure is related to battery systems. More specifically, embodiments of the disclosure provide a nanostructured conversion material for use as the active material in battery cathodes. In an implementation, a nanostructured conversion material is a glassy material and includes a metal material, one or more oxidizing species, and a reducing cation species mixed at a scale of less than 1 nm. The glassy conversion material is substantially homogeneous within a volume of 1000nm3.Type: ApplicationFiled: June 19, 2013Publication date: June 19, 2014Inventors: Timothy Holme, Jagdeep Singh, Rainer Fasching, Joseph Han, Weston Arthur Hermann, Cheng Chieh Chao, Bradley O. Stimson, Karl Brown
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Publication number: 20140170492Abstract: Provided is a positive electrode material for a lithium battery with an atomic ratio expressed by the formula (I) Lia(MxMn2-x)(O4-yZy) for 0.8?a?1.2, 0?x?1 and 0?y?1 in which M is one or more of Li, Na, K, Ca, Mg, Al, Ti, Sc, Ge, V, Cr, Zr, Co, Ni, Zn, Cu, La, Ce, Mn, Hf, Nb, Ta, Mo, W, Ru, Ag, Sn, Pb and Si and Z is one or more of OH, halogens, N, P, S and O, and the primary particles of the positive electrode material have a spheroidal topography. The adjacent (111) family planes of the primary particles are connected by curved surfaces without obvious edges. A preparing method of a positive electrode material for a lithium battery and a lithium battery are also provided. The positive electrode material of the present invention provides a good high-temperature cycling performance and filling capability.Type: ApplicationFiled: May 23, 2011Publication date: June 19, 2014Inventors: Yonggao Xia, Zhaoping Liu, Yaletu Saixi
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Publication number: 20140170481Abstract: It is an object of this exemplary embodiment to provide a lithium ion battery using a lithium manganese complex oxide, in which the dissolution of manganese and resistance increase are inhibited, and which is excellent in life characteristics at high temperature. One aspect of this exemplary embodiment is a lithium ion battery comprising at least a positive electrode comprising a positive electrode active material, and an electrolytic solution, wherein the positive electrode active material is a lithium manganese complex oxide, the positive electrode comprises a bismuth oxide, and a metal compound attached to part of a surface of the lithium manganese complex oxide, and a dissolution rate of a metal of the metal compound in the electrolytic solution is lower than a dissolution rate of manganese of the lithium manganese complex oxide.Type: ApplicationFiled: June 13, 2012Publication date: June 19, 2014Inventor: Akinobu Nakamura
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Publication number: 20140170494Abstract: The invention provides a cathode active material for use in a rechargeable battery, comprising a coated lithium nickel oxide powder or a coated lithium nickel manganese oxide powder, the powder being composed of primary particles provided with a glassy lithium silicate surface coating. A method for preparing the cathode active material comprises the steps of: providing a lithium transition metal based oxide powder, providing an alkali mineral compound comprising a Li2?xSiO3?0.5x compound, wherein 0<x<2, mixing the lithium transition metal based oxide powder and the alkali mineral compound to form a powder-mineral compound mixture, and heat treating the mixture at a temperature T whereby lithium is extracted from the surface of the metal based oxide powder to react with the alkali mineral compound, and a glassy surface coating is formed comprising a Li2?x?SiO3?0.5x? compound, wherein x<x?<2.Type: ApplicationFiled: March 20, 2012Publication date: June 19, 2014Applicant: UMICOREInventors: Jens Paulsen, Randy De Palma, JiHye Kim
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Patent number: 8753533Abstract: Provided are a mixed cathode active material including lithium manganese oxide expressed as Chemical Formula 1 and a stoichiometric spinel structure Li4Mn5O12 having a plateau voltage profile in a range of 2.5 V to 3.3 V, and a lithium secondary battery including the mixed cathode active material. The mixed cathode material and the lithium secondary battery including the same may have improved safety and simultaneously, power may be maintained more than a required value by allowing Li4Mn5O12 to complement low power in a low state of charge (SOC) range. Therefore, a mixed cathode active material able to widen an available SOC range and a lithium secondary battery including the mixed cathode active material may be provided and properly used in a plug-in hybrid electric vehicle (PHEV) or electric vehicle (EV).Type: GrantFiled: May 9, 2012Date of Patent: June 17, 2014Assignee: LG Chem, Ltd.Inventors: Jung Hwan Park, Song Taek Oh, Geun Chang Chung, Su Hwan Kim, Juichi Arai
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Patent number: 8753777Abstract: Disclosed is a secondary battery including a cathode, an anode, a membrane and an electrolyte, wherein the cathode contains a mixture of a first cathode material defined herein and a second cathode material selected from the group consisting of a second-(a) cathode material defined herein and a second-(b) cathode material defined herein, and a combination thereof, wherein a mix ratio of the two cathode materials (first cathode material:second cathode material) is 50:50 to 90:10, and the membrane is an organic/inorganic composite porous membrane including (a) a polyolefin-based membrane substrate and (b) an active layer in which one or more areas selected from the group consisting of the surface of the substrate and a portion of pores of the substrate are coated with a mixture of inorganic particles and a binder polymer, wherein the active layer has a structure in which the inorganic particles are interconnected and fixed through a binder polymer and porous structures are formed by the interstitial volume betwType: GrantFiled: March 8, 2013Date of Patent: June 17, 2014Assignee: LG Chem, Ltd.Inventors: Seungeun Choi, Eungyoung Goh, Hyang Mok Lee, Heegyoung Kang, Sangbaek Ryu, Kiwoong Kim
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Publication number: 20140162125Abstract: The current disclosure relates to an anode material with the general formula MySb-M?Ox—C, where M and M? are metals and M?Ox—C forms a matrix containing MySb. It also relates to an anode material with the general formula MySn-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySn. It further relates to an anode material with the general formula Mo3Sb7-C, where —C forms a matrix containing Mo3Sb7. The disclosure also relates to an anode material with the general formula MySb-M?Cx—C, where M and M? are metals and M?Cx—C forms a matrix containing MySb. Other embodiments of this disclosure relate to anodes or rechargeable batteries containing these materials as well as methods of making these materials using ball-milling techniques and furnace heating.Type: ApplicationFiled: February 18, 2014Publication date: June 12, 2014Inventors: Arumugam Manthiram, Danielle Applestone, Sukeun Yoon
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Publication number: 20140162126Abstract: The present invention relates to a cathode active material for a lithium secondary battery, a method for preparing the same, and a lithium secondary battery including the same, and provides a cathode active material including Li2MnO3 having a layered structure, and doped with one or more elements with a multiple oxidation state selected from the group consisting of W, Mo, V, and Cr, and a fluoro compound.Type: ApplicationFiled: November 27, 2013Publication date: June 12, 2014Applicant: SAMSUNG FINE CHEMICALS CO., LTDInventors: Yunju Cho, Jongseok Moon, Misun Lee, Taehyeon Kim, Sunghoon Lee, Eui Ho Kim, Pilsang Yun
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Publication number: 20140162127Abstract: The present invention relates to a cathode active material for a lithium secondary battery, a method for preparing the same, and a lithium secondary battery including the same, and provides a cathode active material including: a lithium manganese-excess layered structure composite oxide represented by Formula Li[Lix-z(NiaCobMnc)1-x]O2-yFy (here, a+b+c=1, 0.05?x?0.33, 0?y?0.08, and 0<z?0.05); a metal fluoride coating layer coated on a surface of the composite oxide; and a metal phosphate coating layer coated on the metal fluoride coating layer.Type: ApplicationFiled: December 3, 2013Publication date: June 12, 2014Applicant: SAMSUNG FINE CHEMICALS CO., LTDInventors: Jiyoon Kim, Kitae Kim, Dongwook Shin, Hyung Cheoul Shim, Hayeon Lee, SungNim Jo, Haein Cho
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Publication number: 20140162128Abstract: A positive active material for a rechargeable lithium battery is disclosed. The positive active material includes a lithium manganese oxide-based solid solution having a specific surface area of about 3 m2/g to about 12 m2/g and a crystallite diameter of about 40 nm to about 120 nm. In addition, a positive electrode for rechargeable lithium battery and rechargeable lithium battery including a positive active material is also disclosed.Type: ApplicationFiled: December 10, 2013Publication date: June 12, 2014Applicant: Samsung SDI Co., Ltd.Inventors: Masatsugu NAKANO, Yuki TAKEI
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Publication number: 20140162119Abstract: A positive active material for a rechargeable lithium battery is disclosed. The positive material includes including a lithium-manganese oxide-based solid solution including primary particles and secondary particles having a particle diameter (D50) in the range of about 1 ?m to about 5 ?m, a particle diameter (D90) in the range of less than about 8 ?m, and a crystallite diameter of less than or equal to about 150 nm.Type: ApplicationFiled: December 11, 2013Publication date: June 12, 2014Applicant: Samsung SDI Co., Ltd.Inventors: Yuki Takei, Masatsugu Nakano
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Publication number: 20140162124Abstract: A cathode active material capable of increasing a capacity and improving high temperature characteristics or cycle characteristics, a method of manufacturing it, a cathode using the cathode active material, and a battery using the cathode active material are provided. In a cathode active material contained in a cathode, a coating layer is provided on at least part of complex oxide particle containing at least lithium (Li) and cobalt (Co). The coating layer is an oxide which contains lithium (Li) and at least one of nickel (Ni) and manganese (Mn).Type: ApplicationFiled: February 14, 2014Publication date: June 12, 2014Applicant: Sony CorporationInventors: Haruo Watanabe, Kenji Ogisu, Koji Morita, Masanori Soma, Yosuke Hosoya, Hideto Azuma, Tomoyo Ooyama
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Patent number: 8748041Abstract: Disclosed is a positive electrode active material that provides an improved capacity density. Specifically disclosed is a positive electrode active material for a lithium ion battery with a layered structure represented by Lix(NiyM1-y)Oz (wherein M represents at least one element selected from a group consisting of Mn, Co, Mg, Al, Ti, Cr, Fe, Cu, and Zr; x is in the range from 0.9 to 1.2; y is in the range from 0.3 to 0.95; and z is in the range from 1.8 to 2.4), wherein, when a value obtained by dividing an average of peak intensities observed between 1420 and 1450 cm?1 and between 1470 and 1500 cm?1 by the maximum intensity of a peak appearing between 520 and 620 cm?1 in an infrared absorption spectrum obtained by FT-IR is represented by A, A satisfies the following relational formula: 0.20y?0.05?A?0.53y?0.06.Type: GrantFiled: March 3, 2010Date of Patent: June 10, 2014Assignee: JX Nippon Mining & Metals CorporationInventors: Hirohito Satoh, Yoshio Kajiya, Ryuichi Nagase
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Patent number: 8741483Abstract: In a non-aqueous electrolyte secondary battery including a positive electrode 1, a negative electrode 2 and a non-aqueous electrolyte, a positive electrode active material wherein a particle of at least one compound selected from Er hydroxide, Er oxyhydroxide, Yb hydroxide, Yb oxyhydroxide, Tb hydroxide, Tb oxyhydroxide, Dy hydroxide, Dy oxyhydroxide, Ho hydroxide, Ho oxyhydroxide, Tm hydroxide, Tm oxyhydroxide, Lu hydroxide, and Lu oxyhydroxide is dispersed and adhered on a surface of a positive electrode active material particle containing Li is used.Type: GrantFiled: July 7, 2009Date of Patent: June 3, 2014Assignee: SANYO Electric Co., Ltd.Inventors: Takeshi Ogasawara, Naoki Imachi
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Patent number: 8741484Abstract: Positive electrode active materials comprising a dopant in an amount of 0.1 to 10 mole percent of Mg, Ca, Sr, Ba, Zn, Cd or a combination thereof are described that have high specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. Some materials of interest have the formula Li1+xNi?Mn?-?Co?A?X?O2?zFz, where x ranges from about 0.01 to about 0.3, ? ranges from about 0.001 to about 0.15, and the sum x+?+?+?+?+? can approximately equal 1.0. The materials can be coated with a metal fluoride to improve the performance of the materials especially upon cycling. The materials generally can have a tap density of at least 1.8 g/mL. Also, the materials can have an average discharge voltage of around 3.6 V.Type: GrantFiled: April 2, 2010Date of Patent: June 3, 2014Assignee: Envia Systems, Inc.Inventors: Deepak Kumaar Kandasamy Karthikeyan, Subramaninan Venkatachalam, Shabab Amiruddin, Herman A. Lopez, Sujeet Kumar
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Patent number: 8741455Abstract: A secondary hybrid aqueous energy storage device includes an anode electrode, a cathode electrode which is capable of reversibly intercalating sodium cations, a separator, and a sodium cation containing aqueous electrolyte, wherein an initial active cathode electrode material comprises an alkali metal containing active cathode electrode material which deintercalates alkali metal ions during initial charging of the device.Type: GrantFiled: August 29, 2011Date of Patent: June 3, 2014Assignee: Carnegie Mellon UniversityInventor: Jay Whitacre
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Patent number: 8741485Abstract: Lithium rich and manganese rich lithium metal oxides are described that provide for excellent performance in lithium-based batteries. The specific compositions can be engineered within a specified range of compositions to provide desired performance characteristics. Selected compositions can provide high values of specific capacity with a reasonably high average voltage. Compositions of particular interest can be represented by the formula, x Li2MnO3.(1?x) Li Niu+?Mnu??CowAyO2. The compositions undergo significant first cycle irreversible changes, but the compositions cycle stably after the first cycle.Type: GrantFiled: February 12, 2013Date of Patent: June 3, 2014Assignee: Envia Systems, Inc.Inventors: Herman A. Lopez, Subramanian Venkatachalam, Deepak Kumaar Kandasamy Karthikeyan, Sujeet Kumar
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Patent number: 8741480Abstract: The non-aqueous secondary battery of the present invention comprises a positive electrode containing a lithium-containing composite oxide as an active material, a negative electrode, a separator, and a non-aqueous electrolyte. The non-aqueous electrolyte contains polyvalent organic lithium salt, and the content of the polyvalent organic lithium salt is 0.001 parts by mass or more and 1 part by mass or less with respect to 100 parts by mass of all of the components of the non-aqueous electrolyte other than the polyvalent organic lithium salt.Type: GrantFiled: May 17, 2012Date of Patent: June 3, 2014Assignee: Hitachi Maxell, Ltd.Inventors: Akira Yano, Katsunori Kojima
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Patent number: 8734994Abstract: A cathode active material including a lithium metal oxide represented by Formula 1 below: Li[LixMeyM?z]O2+d??Formula 1 wherein x+y+z=1, 0<x<0.33, 0.05?z?0.15, 0?d?0.1, Me includes at least one metal selected from the group consisting of manganese (Mn), vanadium (V), chromium (Cr), iron (Fe), cobalt (Co), nickel (Ni), aluminum (Al), and boron (B), and M? includes at least one metal selected from the group consisting of germanium (Ge), ruthenium (Ru), tin (Sn), titanium (Ti), niobium (Nb), and platinum (Pt).Type: GrantFiled: January 6, 2011Date of Patent: May 27, 2014Assignee: Samsung Electronics Co., Ltd.Inventors: Min-sik Park, Jae-gu Yoon
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Patent number: 8734993Abstract: In one aspect, an electrode assembly comprising a positive electrode, a negative electrode and a separator, wherein the positive electrode further comprises a first positive electrode active material layer, and a second positive electrode active material layer formed on one surface of the first positive electrode active material layer, the first positive electrode active material layer further comprises a first positive electrode active material containing manganese (Mn), and the second positive electrode active material layer further comprises a second positive electrode active material containing cobalt (Co) and a lithium battery comprising the same are provided.Type: GrantFiled: August 8, 2012Date of Patent: May 27, 2014Assignee: Samsung SDI Co., Ltd.Inventor: Inseop Byun
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Patent number: 8734992Abstract: Disclosed is an electrolytic manganese dioxide having an alkali potential of at least 310 mV, a full width at half maximum of the (110) plane in the XRD measurement using the CuK? line as the light source of from 2.2° to 3.0°, and a (110)/(021) peak intensity ratio in the X-ray diffraction spectrum of from 0.5 to 0.80. Also disclosed is a method for producing electrolytic manganese dioxide by electrolysis in an aqueous solution of a sulfuric acid/manganese sulfate mixture.Type: GrantFiled: February 4, 2008Date of Patent: May 27, 2014Assignee: Tosoh CorporationInventors: Kazumasa Suetsugu, Shin Kumagai, Hiroshi Miura
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Patent number: 8734995Abstract: A nonaqueous electrolyte battery includes a negative electrode including a current collector and a negative electrode active material having a Li ion insertion potential not lower than 0.4V (vs. Li/Li+). The negative electrode has a porous structure. A pore diameter distribution of the negative electrode as determined by a mercury porosimetry, which includes a first peak having a mode diameter of 0.01 to 0.2 ?m, and a second peak having a mode diameter of 0.003 to 0.02 ?m. A volume of pores having a diameter of 0.01 to 0.2 ?m as determined by the mercury porosimetry is 0.05 to 0.5 mL per gram of the negative electrode excluding the weight of the current collector. A volume of pores having a diameter of 0.003 to 0.02 ?m as determined by the mercury porosimetry is 0.0001 to 0.02 mL per gram of the negative electrode excluding the weight of the current collector.Type: GrantFiled: June 12, 2013Date of Patent: May 27, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Hiroki Inagaki, Norio Takami
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Patent number: 8734980Abstract: Printed electronics are increasingly becoming an important industry, thus innovations to integrate the various components and processes would be very useful to expand this industry. Disclosed are innovational concepts that would be very useful to accelerate this industry. Webs of printed electronics, antennas, power sources (cells/batteries), and assembly substrates can be merged together to form a completed electronic assembly that could be, for example, in label form or in a stand alone electronic device.Type: GrantFiled: April 25, 2012Date of Patent: May 27, 2014Assignee: Blue Spark Technologies, Inc.Inventor: Gary R. Tucholski
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Publication number: 20140141331Abstract: The present invention relates to a cathode active material for a lithium secondary battery, a method for preparing the same, and a lithium secondary battery including the same. Provided is a cathode active material composed of a lithium-excess lithium metal composite compound including Li2MnO3 having a layered structure, and doped with a fluoro compound, wherein an FWHM (half value width) value is within a range from 0.164 degree to 0.185 degree.Type: ApplicationFiled: November 19, 2013Publication date: May 22, 2014Applicant: SAMSUNG FINE CHEMICALS CO., LTDInventors: Misun Lee, Jongseok Moon, Taehyeon Kim, Shin Jung Choi
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Publication number: 20140141332Abstract: Provided is a cathode material for a lithium ion secondary battery that includes a composite grain formed of lithium iron silicate crystals or lithium manganese silicate crystals and a carbon material. The composite grain has a sea-islands structure in which the lithium iron silicate crystals or lithium manganese silicate crystals are scattered like islands in the carbon material, and the islands have an average value of circle-equivalent diameter of smaller than 15 nm.Type: ApplicationFiled: July 2, 2012Publication date: May 22, 2014Applicant: SHOEI CHEMICAL INC.Inventors: Atsushi Nemoto, Yuki Matsuda, Hirokazu Sasaki
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Publication number: 20140141333Abstract: A process for preparing an at least partially lithiated transition metal oxyanion-based lithium-ion reversible electrode material, which includes providing a precursor of said lithium-ion reversible electrode material, heating said precursor, melting same at a temperature sufficient to produce a melt including an oxyanion containing liquid phase, cooling said melt under conditions to induce solidification thereof and obtain a solid electrode that is capable of reversible lithium ion deinsertion/insertion cycles for use in a lithium battery. Also, lithiated or partially lithiated oxyanion-based-lithium-ion reversible electrode materials obtained by the aforesaid process.Type: ApplicationFiled: January 3, 2014Publication date: May 22, 2014Inventors: Laurent GAUTHIER, Michel GAUTHIER, Donald LAVOIE, Christophe MICHOT, Nathalie RAVET
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Patent number: 8728669Abstract: A nonaqueous electrolyte battery includes a positive electrode, a negative electrode and a nonaqueous electrolyte. The positive electrode contains active material particles and a coating material. The active material particles are represented by any one of the following formulae (1) to (3): LixM1yO2??(1) LizM22wO4??(2) LisM3tPO4??(3) and have an average particle diameter of 0.1 to 10 ?m. The coating material comprises at least particles having an average particle diameter of 60 nm or less or layers having an average thickness of 60 nm or less. The particles or the layers contain at least one element selected from the group consisting of Mg, Ti, Zr, Ba, B and C.Type: GrantFiled: February 21, 2013Date of Patent: May 20, 2014Assignee: Kabushiki Kaisha ToshibaInventors: Norio Takami, Hiroki Inagaki, Keigo Hoshina
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Patent number: 8728652Abstract: Provided is a cylindrical alkaline battery in which the packing density Dc of the manganese dioxide in the positive electrode is 2.8 to 3.0 g/cm3 and the packing density Da of zinc or a zinc alloy in the negative electrode is 2.0 to 2.3 g/cm3. The packing density Dc of the manganese dioxide, the packing density Da of the zinc or zinc alloy, the thickness Tc of the positive electrode in a radial direction, and the thickness Ta of the negative electrode in a radial direction satisfy one of the following relational formulas (1) to (3): ?1.975×(Tc/Ta)+2.745<Dc/Da<?1.690×(Tc/Ta)+2.734??(1) ?11.652×(Tc/Ta)2+14.470×(Tc/Ta)?3.095<Dc/Da<11.652×(Tc/Ta)2?18.420×(Tc/Ta)+8.585??(2) ?8.895×(Tc/Ta)2+12.864×(Tc/Ta)?3.258<Dc/Da<8.895×(Tc/Ta)2?16.244×(Tc/Ta)+8.726??(3).Type: GrantFiled: December 9, 2010Date of Patent: May 20, 2014Assignee: Panasonic CorporationInventors: Tadaya Okada, Yasuhiko Syoji
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Publication number: 20140134500Abstract: An anode and a battery, which have a high capacity and can improve battery characteristics such as large current discharge characteristics and low temperature discharge characteristics are provided. An anode has an anode current collector and an anode active material layer provided on the anode current collector. The density of the anode active material layer is in the range from 1.5 g/cm3 to 1.8 g/cm3. Further, the anode active material layer contains a granulated graphite material which is obtained by granulating a flat graphite particle in nodular shape and mesocarbon microbeads. Thereby, the granulated graphite material is prevented from being destroyed, and diffusion path of lithium ions is secured.Type: ApplicationFiled: January 17, 2014Publication date: May 15, 2014Applicant: SONY CORPORATIONInventor: Gentaro KANO
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Publication number: 20140134491Abstract: Provided is a lithium containing composite oxide powder suitable for the positive electrode active material of the non-aqueous electrolysis solution secondary battery such as the lithium ion secondary battery, and a manufacturing process for the same. A lithium containing composite oxide powder includes a single crystal particle containing a lithium containing composite oxide that is manufactured by a molten salt method and that includes at least lithium and another one or more metal elements and in which a crystal structure belongs to a lamellar rock salt structure, wherein an average primary particle diameter is greater than or equal to 200 nm and smaller than or equal to 30 ?m. The lithium containing composite oxide powder is grown by reacting the metal containing ingredient in the molten salt of the lithium hydroxide at a reaction temperature of higher than or equal to 650° C. and lower than or equal to 900° C.Type: ApplicationFiled: June 22, 2012Publication date: May 15, 2014Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Yuki Sugimoto, Naoto Yasuda, Fumiya Kanetake, Hideaki Shinoda, Manabu Miyoshi, Kyoichi Kinoshita, Toru Abe
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Publication number: 20140134493Abstract: Manganese oxide nanoparticles having a chemical composition that includes Mn3O4, a sponge like morphology and a particle size from about 65 to about 95 nanometers may be formed by calcining a manganese hydroxide material at a temperature from about 200 to about 400 degrees centigrade for a time period from about 1 to about 20 hours in an oxygen containing environment. The particular manganese oxide nanoparticles with the foregoing physical features may be used within a battery component, and in particular an anode within a lithium battery to provide enhanced performance.Type: ApplicationFiled: June 1, 2012Publication date: May 15, 2014Applicant: CORNELL UNIVERSITYInventors: Héctor D. Abruña, Jie Gao, Michael A. Lowe