Abstract: A carbon material of an embodiment includes: a columnar structure in which a carbon compound having a graphene skeleton is laminated, the graphene skeleton whose some of carbon atoms are substituted with nitrogen atoms. In the carbon material, a graphene skeleton surface of the carbon compound is inclined at an angle of 5 degrees or more and 80 degrees or less with respect to a column axial direction of the columnar structure.

Abstract: Disclosed is an electrolytic manganese dioxide having an alkali potential of at least 310 mV, a full width at half maximum of the (110) plane in the XRD measurement using the CuK? line as the light source of from 2.2o to 3.0o, and a (110)/(021) peak intensity ratio in the X-ray diffraction spectrum of from 0.5 to 0.80. Also disclosed is a method for producing electrolytic manganese dioxide by electrolysis in an aqueous solution of a sulfuric acid/manganese sulfate mixture.

Abstract: Printed electronics are increasingly becoming an important industry, thus innovations to integrate the various components and processes would be very useful to expand this industry. Disclosed are innovational concepts that would be very useful to accelerate this industry. Webs of printed electronics, antennas, power sources (cells/batteries), and assembly substrates can be merged together to form a completed electronic assembly that could be, for example, in label form or in a stand alone electronic device.

Abstract: The present invention provides a lithium secondary battery having a great output power in a low SOC range and a positive electrode active material for use in the battery The battery comprises a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode comprises a positive electrode active material in a form of secondary particles as aggregates of primary particles of a lithium transition metal oxide. The positive electrode active material comprises at least one species of Ni, Co and Mn, and further comprises W and Mg. The W is present, concentrated on surfaces of the primary particles while the Mg is present throughout the primary particles. The Mg content in the positive electrode active material is higher than 50 ppm relative, to the total amount of the active material based on the mass.

Abstract: The present application discloses a lithium-rich anode material, a lithium battery anode, and a lithium battery, where the structural formula of the lithium-rich anode material is as follows: z[xLi2MO3.(1-x)LiMeO2].(1-z)Li3-2yM?2yPO4, where 0<x<1, 0<y<1, 0<z<1; M is at least one of elements Mn, Ti, Zr, and Cr, Me is at least one of elements Mn, Co, Ni, Ti, Cr, V, Fe, Al, Mg, and Zr, and M? is at least one of elements Fe, Co, Ni, V, Mg, and Mn. Both the lithium battery anode and the lithium battery include the lithium-rich anode material. Because of the high capability of withstanding high voltages, the high initial charge-discharge efficiency, and the safety of the lithium-rich anode material, the lithium battery has excellent energy density, discharge capacity, cycle life, and rate performance.

Abstract: A secondary battery includes: a cathode; an anode; and an electrolytic solution. The anode includes a lithium composite oxide represented by following Formula (1), LiwZnxSnyMzO4??(1) where M is one or more of Co, Mg, Ni, Ca, Al, Ti, V, Cr, Mn, Fe, Cu, and Ag; and w to z satisfy 0.3?w?1, 0.3?x?1, 0.8?y?1.2, and (w+x+y+z)=3.

Abstract: According to one embodiment, a non-aqueous electrolyte battery includes an outer case, a negative electrode, a positive electrode including a current collector and a positive electrode layer formed on surface of the current collector and opposed to the negative electrode layer, and a non-aqueous electrolyte, wherein the positive electrode layer includes a layered lithium nickel cobalt manganese composite oxide and a lithium cobalt composite oxide, the positive electrode layer has a pore volume with a pore diameter of 0.01 to 1.0 ?m, the pore volume being 0.06 to 0.25 mL per 1 g of a weight of the positive electrode layer, and a pore surface area within the pore volume range is 2.4 to 8 m2/g.

Abstract: A method for preparing a lithium manganese oxide positive active material for a lithium ion secondary battery, which has spherical spinel-type lithium manganese oxide particles having two or more different types of sizes, the method including uniformly mixing manganese oxide having two or more different types of sizes with a lithium containing compound, and heat treating the resultant mixture to obtain lithium manganese oxide.

Abstract: The present invention provides a positive electrode material for a lithium secondary battery comprising a compound represented by the following Formula 1: LiMn1-xMxP1-yAsyO4??[Formula 1] wherein 0<x?0.1, 0<y?0.1, and M is at least one metal selected from the group consisting of magnesium (Mg), titanium (Ti), nickel (Ni), cobalt (Co), and iron (Fe). Positive electrode materials of the present invention, when used as a positive electrode material in a lithium secondary battery, provides increased discharge potential of the battery due to its high discharge capacity, excellent cycle characteristics and charge/discharge efficiency, and high discharge potential with respect to lithium.

Abstract: Disclosed is a secondary battery including a cathode, an anode, a membrane and an electrolyte, wherein the cathode contains a mixture of a first cathode material defined herein and a second cathode material selected from the group consisting of a second-(a) cathode material defined herein and a second-(b) cathode material defined herein, and a combination thereof, wherein a mix ratio of the two cathode materials (first cathode material: second cathode material) is 50:50 to 90:10, and the membrane is an organic/inorganic composite porous membrane including (a) a polyolefin-based membrane substrate and (b) an active layer in which one or more areas selected from the group consisting of the surface of the substrate and a portion of pores of the substrate are coated with a mixture of inorganic particles and a binder polymer, wherein the active layer has a structure in which the inorganic particles are interconnected and fixed through a binder polymer and porous structures are formed by the interstitial volume bet

Abstract: A composite cathode active material, a method of preparing the composite cathode active material, and a cathode and a lithium battery each including the composite cathode active material. The composite cathode active material includes a core including a lithium intercalatable oxide which enables intercalation and deintercalation of lithium; and a coating layer disposed on at least a portion of the core, wherein the conductive layer includes a lithium metal oxide which is an inactive lithium ion conductor, and wherein the lithium metal oxide contains a metal which has an atomic weight of 27 Daltons or more and is selected an element of Groups 3 to 14 of the Periodic Table of the Elements.

Abstract: This invention related to an electrode for lithium secondary batteries, which enables high-rate charging and discharging and is capable of maintaining high battery capacity retention ratio even under large charge and discharge current conditions; a lithium secondary battery; and a method for producing an electrode for lithium secondary batteries. The electrode for lithium secondary batteries includes a metal foil, a coating layer that is provided on the surface of the metal foil and an electrode mixture laminated on the surface of the coating layer, and wherein the coating layer contains a binder and conductive particles; and the electrode mixture contains an electrode active material and 0 to 1.4 mass % of a conductive additive with respect to the electrode mixture.

Abstract: The present invention provides a nonaqueous electrolyte electricity storage device including a separator that can be produced by a method in which use of a solvent that places a large load on the environment can be avoided and in which control of parameters such as the pore diameter is relatively easy, the nonaqueous electrolyte electricity storage device being capable of trapping ions of metals that tend to form a complex other than lithium. The present invention is a nonaqueous electrolyte electricity storage device including a cathode, an anode, a separator disposed between the cathode and the anode, and an electrolyte having ion conductivity. The cathode and/or the anode is formed of a material containing at least one metal element selected from the group consisting of transition metals, aluminum, tin, and silicon.

Abstract: According to one embodiment, an active material is provided. The active material includes orthorhombic system oxide represented by the following formula: LixM1M22O6. In this formula, 0?x?5, M1 is at least one selected from the group consisting of Fe and Mn, and M2 is at least one selected from the group consisting of Nb, Ta and V.

Abstract: A lithium ion secondary battery according to the present invention uses a cathode material obtained by mixing a first cathode active substance represented by a compositional formula: Lix1Nia1Mnb1COc1O2 (in which 0.2?x1?1.2, 0.6?a1?0.9, 0.05?b1?0.3, 0.05?c1?0.3, and a1+b1+c1=1.0); and a second cathode active substance represented by a compositional formula: Lix2Nia2Mnb2COc2MdO2 (in which 0.2?x2?1.2, 0.7?a2?0.9, 0.05?b2?0.3, 0.05?c2?0.3, M=Mo, W, 0?d?0.06, and a2+b2+c2+d=1.0).

Abstract: The present invention discloses a high compact density nickel-cobalt-manganese multi-element lithium ion battery cathode material with dopants and methods of its preparation. A preparation method of this battery cathode material is as follows: (A) preparing a nickel-cobalt-manganese multi-element intermediate with dopants by co-precipitation or chemical synthesis; (B) preparing a mixture by mixing said multi-element intermediate with a lithium salt; (C) pre-treating the said mixture, then adding into it polyvinyl alcohol and mixing uniformly; (D) pressing the resulting material into lumps, calcining the lumps at 800˜950° C., cooling after its removal from the furnace, crushing, passing through a 400 mesh sieve; (E) calcining the resulting power at 700˜800° C., cooling after its removal from the furnace, crushing and sieving to obtain a product. The lithium battery cathode material obtained using the above-described method has the formula LiNixCoyMnzM(1-x-y-z)O2.

Abstract: A Ni—, Co—, and Mn— multi-element doped positive electrode material for lithium ion batteries and its preparation method are provided. The method for preparing said material consists of: first forming a Ni—, Co—, and Mn— multi-element doped intermediate compound by coprecipitation or chemical synthesis; mixing said multi-element intermediate compound with lithium salt and pre-processing the resulting mixture; adding polyvinyl alcohol into the mixture and mixing uniformly, then pressing the resulting mixture into blocks, and calcining these at 800˜930° C.; cooling outside the furnace, crushing and passing through a 400-mesh sieve; calcining the resulting powder at 700˜800° C., cooling outside the furnace and crushing to obtain the product. The positive electrode material obtained by the method described is in the form of non-agglomerated monocrystal particles, with a particle diameter of 0 5˜30 ?m, the chemical formula LiNixCoyMnzM(1-x-y-z)O2, a compacted density of up to 3.

Abstract: A lithium metal oxide composite for a lithium secondary battery includes a core portion formed of a Mn metal compound and a shell portion formed of a three-component system metal compound at an outside of the core portion. A method of preparing a lithium metal oxide composite for a lithium secondary battery includes: mixing an Mn metal salt aqueous solution, a chelate agent, and a pH regulator to precipitate a first precursor; thermally treating the obtained first precursor; mixing the thermally treated first precursor with a three component system metal salt aqueous solution, a chelate agent, and a pH regulator to precipitate a second precursor; and mixing the obtained second precursor with a lithium-containing compound to synthesize a powder via a firing.

Abstract: An electroactive material for use in an electrochemical cell, like a lithium-ion battery, is provided. The electroactive material comprises lithium titanate oxide (LTO) and has a surface coating with a thickness of less than or equal to about 30 nm that suppresses formation of gases within the electrochemical cell. Methods for making such materials and using such materials to suppress gas formation in electrochemical cells are likewise provided.

Abstract: To provide a process for producing a cathode active material for a lithium ion secondary battery, a cathode for a lithium ion secondary battery, and a lithium ion secondary battery. A production process which comprises contacting a lithium-containing composite oxide containing Li element and a transition metal element with a composition (1) {an aqueous solution containing cation M having at least one metal element (m)} and a composition (2) {an aqueous solution containing anion N having at least one element (n) selected from the group consisting of S, P, F and B, forming a hardly soluble salt when reacted with the cation M}, wherein the total amount A (mL/100 g) of the composition (1) and the composition (2) contacted per 100 g of the lithium-containing composite oxide is in a ratio of 0.1<A/B<5 based on the oil absorption B (mL/100 g) of the lithium-containing composite oxide.

Abstract: To provide a cathode active material for a lithium ion secondary battery, and its production process. A lithium-containing composite oxide containing a transition metal element and a composition (1) are contacted to obtain particles (I) having a compound containing a metal element (M) attached, which are mixed with a compound which generates HF by heating, and the mixture is heated to obtain particles (III) having a covering layer (II) containing the metal element (M) and fluorine element formed on the surface of the lithium-containing composite oxide. Composition (1): a composition having a compound containing no Li element and containing at least one metal element (M) selected from Mg, Ca, Sr, Ba, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Fe, Co, Ni, Pb, Cu, Zn, Al, In, Sn, Sb, Bi, La, Ce, Pr, Nd, Gd, Dy, Er and Yb dissolved or dispersed in a solvent.

Abstract: An electrode material for a secondary battery includes crystal primary particles of an electrode active material which releases or absorbs cations of a monovalent or divalent metal when subjected to electrochemical oxidation or reduction and which has a crystal lattice in which the cations can move only in a one-dimensional movable direction during the process of oxidation or reduction. The electrode material also includes an ion-conductive substance and conductive carbon which coexist on the surface of the primary particles, in which the ion-conductive substance has a property which allows two or three-dimensional movement of the cations, and the cations are movable via a layer in which the ion-conductive substance and the conductive carbon coexist.

Abstract: An electrochemical cell has an electrode which includes a zinc-indium alloy as electrochemically active material, wherein the alloy is present in the form of particles and the entirety of the particles is composed of at least two particle fractions differing in indium concentration.

Abstract: An electrode material containing an electrode active material, and a carbonaceous coating film which covers the electrode active material and contains sulfur; and an electrode material including a secondary particle including a plurality of primary particles as the electrode active material, wherein the primary particles are covered with a carbonaceous coating film so that the carbonaceous coating film is interposed between the primary particles and the carbonaceous coating film contains sulfur.

Abstract: A transition metal composite hydroxide can be used as a precursor to allow a lithium transition metal composite oxide having a small and highly uniform particle diameter to be obtained. A method also is provided for producing a transition metal composite hydroxide represented by a general formula (1) MxWsAt(OH)2+?, coated with a compound containing the additive element, and serving as a precursor of a positive electrode active material for nonaqueous electrolyte secondary batteries. The method includes producing a composite hydroxide particle, forming nuclei, growing a formed nucleus; and forming a coating material containing a metal oxide or hydroxide on the surfaces of composite hydroxide particles obtained through the upstream step.

Abstract: A positive active material including: a lithium-containing oxide, and a lithium-intercalatable phosphate compound disposed on the lithium-containing oxide.

Abstract: A lithium ion battery includes a positive electrode comprising carbon fibers, a binder composition with conductive carbon, and a lithium rich composition. The lithium rich composition comprises at least one selected from the group consisting of Li1+x(My MzII MwIII)O2 where x+y+z=1, and xLi2MnO3(1?x)LiMO2, where x=0.2-0.7, and where M, MII and MIII are interchangeably manganese, nickel and cobalt, and LiM2?xMxIIO4 , where M and MII are manganese and nickel, respectively, with x=0.5. A negative electrode comprises carbon fibers having bound thereto silicon nanoparticles, and a mesophase pitch derived carbon binder between the silicon nanoparticles and the carbon fibers. An electrolyte is interposed between the positive electrode and the negative electrode. Methods of making positive and negative electrodes are also disclosed.

Abstract: Lithium ion secondary batteries are described that have high total energy, energy density and specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. The improved batteries are based on high loading of positive electrode materials with high energy capacity. This capability is accomplished through the development of positive electrode active materials with very high specific energy capacity that can be loaded at high density into electrodes without sacrificing performance. The high loading of the positive electrode materials in the batteries are facilitated through using a polymer binder that has an average molecular weight higher than 800,000 atomic mass unit.

Abstract: This disclosure provides a positive electrode active lithium-excess metal oxide with composition LixMyO2 (0.6?y?0.85 and 0?x+y?2) for a lithium secondary battery with a high reversible capacity that is insensitive with respect to cation-disorder. The material exhibits a high capacity without the requirement of overcharge during the first cycles.

Abstract: Embodiments of the present application provide a lithium-enriched solid solution anode composite material, which includes xLi2MnO3.(1-x)MO and a LiMePO4 layer that is clad on a surface of xLi2MnO3.(1-x)MO, where x<1, M is one or more selected from: Ni, Co, Mn, Ti, and Zr, and Me is one or more selected from: Co, Ni, V, and Mg. The lithium-enriched solid solution anode composite material has high stability in an electrolyte, may improve a cycle life, discharge capacity, rate performance, and initial charge-discharge efficiency of a lithium-ion battery, and is applicable in a condition of a high voltage greater than 4.6V. The embodiments of the present application further provide a preparation method for the lithium-enriched solid solution anode composite material, a lithium-ion battery anode plate containing the lithium-enriched solid solution anode composite material, and a lithium-ion battery containing the lithium-ion battery anode plate.

Abstract: Compositions and methods of making are provided for surface modified electrodes and batteries comprising the same. The compositions may comprise a base composition having an active material capable of intercalating the metal ions during a discharge cycle and deintercalating the metal ions during a charge cycle, wherein the active material is selected from the group consisting of LiCoO2, LiMn2O4, Li2MnO3, LiNiO2, LiMn1.5Ni0.5O4, LiFePO4, Li2FePO4F, Li3CoNiMnO6, Li(LiaNixMnyCoz)O2, LiaMn1.5-bNi0.5-cMdO4-x, and mixtures thereof. The compositions may also comprise an annealed composition covering a portion of the base composition, formed by a reaction of the base composition in a reducing atmosphere. The methods of making comprise providing the base composition and annealing the base electrode in a reducing atmosphere.

Abstract: Provided are: a solid electrolyte battery using a novel positive electrode active material that functions in an amorphous state; and a novel positive electrode active material that functions in an amorphous state. The solid electrolyte battery includes: a positive electrode layer including a positive electrode active material layer; a negative electrode layer; and a solid electrolyte layer formed between the positive electrode layer and the negative electrode layer, and the positive electrode active material includes a lithium-boric acid compound in an amorphous state, which contains Li, B, any element M1 selected from Cu, Ni, Co, Mn, Au, Ag, and Pd, and O.

Abstract: The present disclosure relates to a nanocomposite cathode active material for a lithium secondary battery, a method for preparing same, and a lithium secondary battery including same. More particularly, the present disclosure relates to a nanocomposite cathode active material for a lithium secondary battery including: a core including LiMn2O4; and LiMn(PO3)3 distributed on the surface of the core. In accordance with the present disclosure, the time and cost for manufacturing a lithium secondary battery can be reduced and the manufactured lithium secondary battery has superior electrochemical properties.

Abstract: Compositions and methods of making are provided for coated electrodes and batteries comprising the same. The compositions may comprise a base composition having an active material selected from the group consisting of LiCoO2, LiMn2O4, Li2MnO3, LiNiO2, LiMn1.5Ni0.5O4, LiFePO4, Li2FePO4F, Li3CoNiMnO6, Li(LiaNixMnyCoz)O2, and mixtures thereof. The compositions may also comprise a coating composition that covers at least a portion of the base composition, wherein the coating composition comprises a non-metal or metalloid element. The methods of making comprise providing the base composition and a doped carbon coating composition, and mixing the coating composition with the base electrode composition at an elevated temperature in a flowing inert gas atmosphere.

Abstract: The problem of the present invention is to provide a sodium ion battery system with high charge and discharge efficiency. The present invention solves the above-mentioned problem by providing a sodium ion battery system comprising a sodium ion battery and a charge control unit, wherein the anode active material is an active material having an Na2Ti6O13 crystal phase, the anode active material layer contains a carbon material as a conductive material, and the above-mentioned charge control unit controls electric potential of the above-mentioned anode active material higher than electric potential in which an Na ion is irreversibly inserted into the above-mentioned carbon material.

Abstract: A positive electrode for a lithium secondary battery includes a positive activation material mixture that intercalates and de-intercalates lithium ions, wherein a first positive activation material having an average particle diameter D50 of from 12.5 ?m to 22 ?m and a second positive activation material having an average particle diameter D50 of from 1 ?m to 5 ?m are mixed with a weight ratio of from 95:5 to 60:40.

Abstract: A nonaqueous secondary battery having a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode contains, as an active material, a lithium-containing transition metal oxide containing a metal element selected from the group consisting of Mg, Ti, Zr, Ge, Nb, Al and Sn, the positive electrode mixture layer has a density of 3.5 g/cm3 or larger, and the nonaqueous electrolyte contains a compound having two or more nitrile groups in the molecule.

Abstract: Solid state, thin film, electrochemical devices (10) and methods of making the same are disclosed. An exemplary device 10 includes at least one electrode (14) and an electrolyte (16) deposited on the electrode (14). The electrolyte (16) includes at least two homogenous layers of discrete physical properties. The two homogenous layers comprise a first dense layer (15) and a second porous layer (16).

Abstract: Carbon nanotube-based electrode materials for rechargeable batteries have a vastly increased power density and charging rate compared to conventional lithium ion batteries. The electrodes are based on a carbon nanotube scaffold that is coated with a thin layer of electrochemically active material in the form of nanoparticles. Alternating layers of carbon nanotubes and electrochemically active nanoparticles further increases the power density of the batteries. Rechargeable batteries made with the electrodes have a 100 to 10000 times increased power density compared to conventional lithium-ion rechargeable batteries and a charging rate increased by up to 100 times.

Abstract: A lithium secondary battery includes an anode part having lithium powder, a cathode part having a non-lithiated active material and a gel-polymer electrolyte. Thus, an effective surface area of an electrode involved in a battery reaction can increase, a dendrite growth using a gel-polymer electrode can be suppressed and a high capacity and long service life can be achieved by using a non-lithiated cathode instead of a conventional lithiated cathode.

Abstract: A process to induce polymerization of an organic electronically conductive polymer in the presence of a partially delithiated alkali metal phosphate which acts as the polymerization initiator.

Abstract: At least one of an aqueous solution A containing lithium, an aqueous solution B containing iron, manganese, cobalt, or nickel, and an aqueous solution C containing a phosphoric acid includes graphene oxide. The aqueous solution A is dripped into the aqueous solution C, so that a mixed solution E including a precipitate D is prepared. The mixed solution E is dripped into the aqueous solution B, so that a mixed solution G including a precipitate F is prepared. The mixed solution G is subjected to heat treatment in a pressurized atmosphere, so that a mixed solution H is prepared, and the mixed solution H is then filtered. Thus, particles of a compound containing lithium and oxygen which have a small size are obtained.

Abstract: A cathode composite material includes a cathode active material and a coating layer coated on a surface of the cathode active material. The cathode active material includes a layered type lithium transition metal oxide. A material of the coating layer is a lithium metal oxide having a crystal structure belonging to C2/c space group of the monoclinic crystal system. The present disclosure also relates to a lithium ion battery including the cathode composite material.

Abstract: A cathode material for a lithium secondary battery, including fibrous carbon and a plurality of cathode active material particles bonded to a surface of the fibrous carbon. The cathode active material particles are composed of olivine-type LiMPO4 where M represents one or more kinds of elements selected from Fe, Mn, Ni, and Co. Also disclosed is a method of producing the cathode material and a lithium secondary battery.

Abstract: A cathode composite material includes a cathode active material and a coating layer coated on a surface of the cathode active material. The cathode active material includes a spinel type lithium manganese oxide. The coating layer comprises a lithium metal oxide having a crystal structure belonging to C2/c space group of the monoclinic crystal system. The present disclosure also relates to a lithium ion battery including the cathode composite material.

Abstract: A cathode composite material includes a cathode active material and a coating layer coated on a surface of the cathode active material. A material of the coating layer is a lithium metal oxide having a crystal structure belonging to C2/c space group of the monoclinic crystal system. The present disclosure also relates to a lithium ion battery including the cathode composite material.

Abstract: The invention relates to a positive electrode/electrolyte pair for lithium batteries operating at a voltage above 4.2 V versus Li+/Li. The electrolyte of the lithium battery used in the invention includes at least a first additive chosen from optionally substituted, cyclic or acyclic, carboxylic or dicarboxylic anhydrides and carboxylic or dicarboxylic acids, and mixtures thereof, and optionally a second additive which is a lithium salt, the total content of additive(s) being greater than or equal to 0.01% by weight and less than or equal to 30% by weight, relative to the total weight of electrolyte, and the positive electrode is made of a material having a spinel structure. The lithium batteries of the invention are applicable in particular in the field of portable equipment, such as telephones, computers, camcorders, cameras and tooling.

Abstract: A non-aqueous electrolyte secondary battery including a unit cell including a positive electrode, a negative electrode, a separator disposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte, the positive electrode capacity being greater than the negative electrode capacity, and at least a portion of the non-aqueous electrolyte is gasified during charging.

Abstract: The positive electrode of the lithium ion secondary battery includes active material particles containing a lithium composite oxide represented by: LivNi1-w-x-y-zCowCaxMgyMzO2 (0.85?v?1.25, 0<w?0.75, 0<x?0.1, 0<y?0.1, 0?z?0.75, 0<w+x+y+z?0.80, and element M is an element other than Co, Ca, and Mg), and (i) when 0<z, element M includes element Me of at least one selected from the group consisting of Mn, Al, B, W, Nb, Ta, In, Mo, Sn, Ti, Zr, and Y; and element Mc of at least one selected from the group consisting of Ca, Mg, and element Me is distributed more in the surface layer portion compared with the inner portion of the active material particles, and (ii) when 0=z, element Mc of at least one selected from the group consisting of Ca and Mg is distributed more in the surface layer portion compared with the inner portion of the active material particles.

Abstract: A cylindrical battery gasket that will not functionally deteriorate in absorbing stress caused by the gasket extending radially upon the battery being sealed is provided with a boss part with a central hole through which a negative electrode collector is inserted, a canister contact part that is affixed in place and in contact with a cathode canister, a disk-shaped part that is provided to connect the boss part to the canister contact part, and a stress buffering part that is provided on the way to the disk-shaped pat. The stress buffering part has a first bent part and a second bent part, both of an acute angle, and is set nearer the center of the cathode canister than to the positive electrode mixture, upon the gasket being installed in the cathode canister.