Abstract: New lithium ion conducting materials comprise porphyrin rings. These materials function as sites through which the lithium ion passes. In one aspect of the invention, an electrolyte composition consists essentially of a major amount of a lithium porphyrin complex and a minor amount of a polymer binder. In another aspect, an electrolyte composition consists essentially of aligned and spaced lithium porphyrin complex rings, wherein alignment and spacing of the porphyrin rings is achieved through the use of ladder type polymers, comb-like polymers, or crystalline polymers.
Type:
Grant
Filed:
May 26, 1998
Date of Patent:
January 4, 2000
Assignee:
United States of America as represented by the Secretary of the Air Force
Inventors:
Lawrence G. Scanlon, Jr., Wlodzimierz T. Krawiec, Emmanuel P. Giannelis
Abstract: The present invention relates to an ionically conductive polymeric gel electrolyte for batteries having high ionic conductivity and sufficiently high solid strength. The invention has an object to provide a solid battery which prevents internal short-circuiting even if no diaphragm is used and which has high reliability, by using the ionically conductive polymeric gel electrolyte. Disclosed is an ionically conductive polymeric gel electrolyte, containing at least a polymer matrix, a non-aqueous electrolytic solution and an electrolytic salt, wherein at least one kind of a halogen-substituted carbonic ester is contained as a solvent of the non-aqueous electrolytic solution. Also disclosed is a solid battery having the ionically conductive polymeric gel electrolyte as a constituent.
Abstract: An ionically conductive material which contains at least one ionic compound in solution in an aprotic solvent, wherein the ionic compound is selected from the group consisting of compounds of the formulae (1/mM).sup.61 ((ZY)2N).sup..crclbar., (1/mM).sup..sym. ((ZY).sub.3 C).sup..crclbar., or (1/mM).sup..sym. ((ZY).sub.2 CQ).sup..crclbar., wherein M, Z, Y and Q are as defined herein.
Type:
Grant
Filed:
November 21, 1995
Date of Patent:
June 29, 1999
Assignees:
Centre National De La Recherche Scientifique, Hydro-Quebec
Inventors:
Christophe Michot, Michel Armand, Jean-Yves Sanchez, Yves Choquette, Michel Gauthier