Abstract: The present invention relates to electrochemical storage devices containing a non-aqueous lithium based electrolyte with high ionic conductivity, low impedance, and high thermal stability. More particularly, this invention relates to the design, synthesis and application of novel fluorinated arylboron oxalate based compounds which act as anion receptors and/or additives for non-aqueous batteries. When used as an anion receptor for non-aqueous battery electrolytes, the fluorinated arylboron oxalate enhances conductivity, lithium ion transference number and Solid Electrolyte Interface (SEI) formation capability during the formation cycling.

Abstract: The gas generation and the decrease in battery capacity during high temperature storage of a lithium secondary battery are suppressed. The electrolyte contains a polymerizable compound or a polymer, the polymerizable compound contains a compound having an aromatic functional group and a polymerizable functional group and a compound having a complex-forming functional group forming a complex with a metal ion and a polymerizable functional group, and the polymer has the complex-forming functional group, the aromatic functional group and a residue of the polymerizable functional group.

Abstract: Disclosed is a lithium secondary battery including a positive electrode comprising a combination of positive active materials. The combination includes a material represented by one or both of Formulae 1 and 2; and a material of Formula 3 as follows: LiaNibMncMdO2??(Formula 1) where 0.90?a?1.2; 0.5?b?0.9; 0<c<0.4; 0?d?0.2; LiaNibCocMndMeO2??(Formula 2) where 0.90?a?1.2, 0.5?b?0.9, 0<c<0.4, 0<d<0.4, and 0?e?0.2; LiaCoMbO2??(Formula 3) where 0.90?a?1.2 and 0?b?0.2; and each M of Formulae 1-3 is independently selected from the group consisting of Mg, Ca, Sr, Ba, Ra, Sc, Y, Ti, Zr, Hf, Rf, V, Nb, Ta, Db, Cr, Mo, W, Sg, Tc, Re, Bh, Fe, Ru, Os, Hs, Rh, Ir, Pd, Pt, Cu, Ag, Au, Zn, Cd, B, Al, Ga, In, Tl, Si, Ge, Sn, P, As, Sb, Bi, S, Se, Te, Po, and combinations.

Abstract: Electrolyte for lithium secondary batteries and battery packs includes a lithium salt, a non-aqueous solvent, and an additive. The additive includes two or more members selected from the group consisting of substances A, B and C, wherein A includes one or more fused ring compounds and fused heterocyclic compounds, B includes an alkoxy aromatic compound, and C includes halogenated borane-based salt.

Abstract: An electrolytic solution including: a magnesium salt; a non-aqueous organic solvent; and an anion receptor, wherein the anion receptor comprises at least one compound selected from the group consisting of compounds represented by Formulae 1 and 2 below: where A, m, p1, P2, P3, q1, RA, Ra, R1 through R6, and Ry are the same as described in the detailed description section.

Abstract: Disclosed are a nonaqueous electrolytic solution of an electrolyte dissolved in a nonaqueous solvent, which contains a carboxylate represented by the following general formula (I) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution; and an electrochemical element using it.

Abstract: The battery includes an electrolyte activating one or more cathodes and one or more anodes. The electrolyte includes one or more salts in a solvent. The solvent includes one or more organic solvents and one or more silanes and/or one or more siloxanes.

Abstract: A surface-enabled, metal ion-exchanging battery device comprising a cathode, an anode, a porous separator, and a metal ion-containing electrolyte, wherein the metal ion is selected from (A) non-Li alkali metals; (B) alkaline-earth metals; (C) transition metals; (D) other metals such as aluminum (Al); or (E) a combination thereof; and wherein at least one of the electrodes contains therein a metal ion source prior to the first charge or discharge cycle of the device and at least the cathode comprises a functional material or nano-structured material having a metal ion-capturing functional group or metal ion-storing surface in direct contact with said electrolyte, and wherein the operation of the battery device does not involve the introduction of oxygen from outside the device and does not involve the formation of a metal oxide, metal sulfide, metal selenide, metal telluride, metal hydroxide, or metal-halogen compound.

Abstract: An electrolyte for a lithium secondary battery, which includes a lithium salt, a nonaqueous organic solvent and at least one additive selected from the group consisting of vitamin G (vitamin B2, riboflavin), vitamin B3 (niacinamide), vitamin B4 (adenine), vitamin B5 (pantothenic acid), vitamin H (vitamin B7, biotin), vitamin M (vitamin B9, folic acid), vitamin BX (4-aminobenzoic acid), vitamin D2 (ergocalciferol), vitamin D3 (cholecalciferol), vitamin K1 (phylloquinone), ascorbyl palmitate, and sodium ascorbate.

Abstract: An organic electrolyte solution includes a lithium salt; an organic solvent including a high permittivity solvent and a low boiling solvent; and a vinyl-based compound represented by Formula 1 below, wherein m and n are each independently integers of 1 to 10; X1, X2, and X3 each independently represent O, S, or NR9; and R1, R2, R3, R4, R5, R6, R7, R8, and R9 are represented in the detailed description. The organic electrolyte solution of the present invention and a lithium battery using the same suppress degradation of an electrolyte, providing improved cycle properties and life span thereof.

Abstract: A lithium-free, anion based charge transport electrochemical system that uses fluoride ion transporting electrolytes, including ionic liquids, with and without various additives to improve performance, is described. The fluoride ion transporting electrolyte can be wholly or partly an ionic liquid that is typically liquid at temperatures less than 200 degrees Celsius. In other embodiments, electrolytes that remain liquid at less than 100 degrees Celsius are useful.

Abstract: The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte. A-N?C?O In the above formula, A represents an element or a group other than hydrogen.

Abstract: To provide a power storage device having a solid electrolyte, in which a charge-discharge capacity can be increased, and a method for manufacturing the power storage device. The power storage device includes a positive electrode, a negative electrode, and an electrolyte provided between the positive electrode and the negative electrode, and the electrolyte includes an ion-conductive high molecular compound, an inorganic oxide, and a lithium salt, and the inorganic oxide is included in the electrolyte at more than 30 wt % and 50 wt % or less to the total of the ion-conductive high molecular compound and the inorganic oxide.

Abstract: The present invention provides an electrolyte solution and a lithium ion secondary battery which maintain for a long period high battery characteristics represented by the discharge capacity retention rate after the charge/discharge cycle, and simultaneously achieve also the high safety represented by the flame retardation. The present invention provides an electrolyte solution containing a nonaqueous solvent, an electrolyte, a specific compound having a perfluoroalkyl group in the molecule, and an additive having a fluorine atom and/or a phosphorus atom in the molecule.

Abstract: A method of manufacturing a lithium-ion secondary battery includes an electrolytic solution making step of making an electrolytic solution by mixing at least an organic solvent and an electrolytic salt together, an electrode insertion step of inserting an anode and a cathode into an outer case, and a liquid injection step of injecting the electrolytic solution into the outer case; wherein the electrolytic solution making step or the liquid injection step adds a compound having an alkyl group with a carbon number of 10 or greater and an epoxy, vinyl, or silanol group at a terminal to the electrolytic solution.

Abstract: Provided are an electrolyte additive represented by the following formula (1), an electrolyte solution containing the electrolyte additive, and a lithium secondary battery including the electrolyte solution: The electrolyte solution containing the electrolyte additive can enhance the normal-temperature and high-temperature lifetime characteristics of the battery to be equivalent or superior to the characteristics of conventional batteries, and can extend the service life of the battery.

Abstract: A non-aqueous electrolyte secondary battery having a negative electrode, a non-aqueous electrolyte, and a positive electrode having a positive electrode active material comprising sodium oxide, is characterized in that the sodium oxide contains lithium, and the molar amount of the lithium is less than the molar amount of the sodium.

Abstract: Disclosed is a positive active material for a rechargeable lithium battery, which includes an active material capable of reversibly intercalating/deintercalating lithium and lithium polysulfide.

Abstract: The electrolyte includes one or more salts and a silane. The silane has a silicon linked to one or more first substituents that each include a poly(alkylene oxide) moiety or a cyclic carbonate moiety. The silane can be linked to four of the first substituents. Alternately, the silane can be linked to the one or more first substituents and one or more second substituents that each exclude both a poly(alkylene oxide) moiety and a cyclic carbonate moiety.

Abstract: A non-aqueous electrolyte secondary battery is produced using a non-aqueous electrolyte including: a non-aqueous solvent that primarily contains a solvent mixture of ethylene carbonate and propylene carbonate and includes a fluorine-substituted ether having a divalent group represented by a formula: —CFX—CH(CH3)—O—, where X is a hydrogen atom or fluorine atom, in a molecule thereof; and a lithium salt that is dissolved in the non-aqueous solvent. The non-aqueous electrolyte has favorable wettability towards a polyolefin separator, and improves the cycle characteristics and the load characteristics of the non-aqueous electrolyte secondary battery.

Abstract: An electrolyte for a lithium secondary battery, the electrolyte comprising: a lithium salt, a non-aqueous organic solvent, and an additive represented by Formula 1 below: wherein R1, R2, R3, and R4 are the same as defined in the detailed description.

Abstract: To provide a functional material which forms a high-resistance layer to interrupt an electric current, thereby ensuring the safety of a battery during overcharge. A polymerizable compound including a polymerizable functional group having an aromatic functional group, a polymerizable compound including a polymerizable functional group having a highly polar functional group, and a polymerizable compound including a polymerizable functional group having a less polar functional group, or a polymer obtained by polymerizing these polymerizable compounds are added into an electrolytic solution of a lithium secondary battery.

Abstract: A method of producing a non-aqueous electrolyte secondary battery having a negative electrode, a non-aqueous electrolyte, and a positive electrode having a positive electrode active material comprising sodium oxide, characterized in that: the sodium oxide contains lithium; and the molar amount of the lithium is less than the molar amount of the sodium.

Abstract: The present invention provides a lithium secondary battery having high-capacity as well as good cycle characteristics. The lithium secondary battery includes a positive electrode comprising a positive active material, a negative electrode comprising a negative active material and an electrolyte. The negative active material includes graphite particles combined to Si particulate. The electrolyte includes a solvent, a polyether modified silicone oil where a linear polyether chain is linked to a polysiloxane chain, and a solute comprising a lithium salt.

Abstract: One example of the disiloxanes include a backbone with a first silicon and a second silicon. The first silicon is linked to a first substituent selected from a group consisting of: a first side chain that includes a cyclic carbonate moiety; a first side chain that includes a poly(alkylene oxide) moiety; and a first cross link links the disiloxane to a second siloxane and that includes a poly(alkylene oxide) moiety. In some instance, the second silicon is linked to a second substituent selected from a group consisting of: a second side chain that includes a cyclic carbonate moiety, and a second side chain that includes a poly(alkylene oxide) moiety.

Abstract: An electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive comprising a) a compound represented by the following Formula (1), and b) a compound selected from the group consisting of a sulfone-based compound, a poly(ester)(metha)acrylate, a polymer of poly(ester)(metha)acrylate, and a mixture thereof: wherein R1 is a C1 to C10 alkyl, a C1 to C10 alkoxy, or a C6 to C10 aryl, and preferably a methyl, ethyl, or methoxy, X is a halogen, and m and n are integers ranging from 1 to 5, where m+n is less than or equal to 6.

Abstract: An electrochemical device, having an anode containing magnesium; a cathode stable to a voltage of at least 3.2 V relative to a magnesium reference; and an electrolyte containing a solvent and a LiCl complex of a magnesium halide salt of a sterically hindered secondary amine is provided. In a preferred embodiment the electrolyte contains tetrahydrofuran and 2,2,6,6-tetramethylpiperidinyl-magnesium chloride-lithium chloride complex.

Abstract: Provided is a lithium rechargeable battery including: a cathode plate including a cathode current collector layer and a cathode layer; an anode plate spaced from the cathode plate, the cathode plate including an anode current collector layer and an anode layer; and a polymer electrolyte disposed between the cathode plate and the anode plate, wherein at least one of the cathode layer and the anode layer includes a mixed cathode active material or a mixed anode active material.

Abstract: It is an object to provide, as a nonaqueous electrolyte solution using a solvent comprising a specific compound such as a polyethylene glycol dialkyl ether, an electrolyte solution for a chargeable device and an electrolyte solution for a lithium ion secondary battery exhibiting excellent cycle characteristics, and a secondary battery using the electrolyte solution. An electrolyte solution for a chargeable device, which comprises a fluorinated lithium salt and a solvent comprising a specific compound such as a polyethylene glycol dialkyl ether, and as an optional component, a hydroxy group-containing organic compound, wherein the amount of the hydroxy group-containing organic compound is at most 100 mg per 1 kg of the specific compound. Particularly, an electrolyte solution for a lithium secondary battery. Further, a lithium secondary battery using the electrolyte solution for a lithium secondary battery.

Abstract: Provided are novel electrode material composite structures containing high capacity active materials formed into porous base structures. The structures also include shells that encapsulate these porous base structures. During lithiation of the active material, the shell mechanically constrains the porous base structure. The shell allows lithium ions to pass through but prevents electrolyte solvents from interacting with the encapsulated active material. In certain embodiments, the shell contains carbon, while the porous base structure contains silicon. Although silicon tends to swell during lithiation, the porosity of the base structure and/or void spaces inside the shell helps to accommodate this additional volume within the shell without breaking it or substantially increasing the overall size of the composite structure.

Abstract: Electrolyte compositions suitable for use in batteries, such as a lithium ion battery, are disclosed The electrolyte compositions include functionalized metal oxide particles In several embodiments the compositions utilize the presence of solvent or a scavenger Methods of making and using electrolyte compositions are also disclosed Articles of manufacture containing an electrolyte composition are also disclosed

Abstract: An electrolyte solution for a secondary lithium battery, the electrolyte solution including: a lithium salt, a non-aqueous organic solvent, and a phenanthroline-based compound having a polar substituent. The electrolyte solution enables production of a secondary lithium battery having good high-temperature lifetime characteristics and good high-temperature preservation characteristics.

Abstract: There can be provided an energy storage device comprising a positive electrode comprising a nitroxyl compound having a nitroxyl cation partial structure in an oxidized state and having a nitroxyl radical partial structure in a reduced state; a negative electrode comprising a carbon material which lithium ions can be reversibly intercalated into and deintercalated from; and an electrolytic solution comprising a lithium salt and an aprotic organic solvent, wherein the negative electrode is a negative electrode comprising the carbon material which lithium ions are previously intercalated into, apart from lithium ions associated with a capacity A of lithium capable of being intercalated and deintercalated in charge and discharge, thereby allowing the energy storage device to simultaneously achieve high energy density, high output characteristics, low environmental load, and high stability in charge and discharge cycles.

Abstract: Gas generation of a non-aqueous electrolyte battery having a negative active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium as negative electrode is suppressed. A non-aqueous electrolyte battery comprising a non-aqueous electrolyte containing an electrolyte salt and a non-aqueous solvent, a positive electrode and a negative electrode is characterized in that the main active material of said negative electrode is an active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium and the auxiliary active material of said negative electrode is an active material that at least intercalates lithium ions at a potential lower than 1.

Abstract: A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

Abstract: In accordance with one embodiment, an electrochemical cell includes a negative electrode including a form of lithium, a positive electrode spaced apart from the negative electrode and configured to use a form of oxygen and carbon dioxide as reagents in a reversible electrochemical reaction wherein Li2CO3 is formed and consumed at the positive electrode, a separator positioned between the negative electrode and the positive electrode, and an electrolyte including a salt.

Abstract: Protected anode architectures for active metal anodes have a polymer adhesive seal that provides an hermetic enclosure for the active metal of the protected anode inside an anode compartment. The compartment is substantially impervious to ambient moisture and battery components such as catholyte (electrolyte about the cathode), and prevents volatile components of the protected anode, such as anolyte (electrolyte about the anode), from escaping. The architecture is formed by joining the protected anode to an anode container. The polymer adhesive seals provide an hermetic seal at the joint between a surface of the protected anode and the container.

Abstract: Provided is a lithium secondary battery comprising an anode, a cathode and a non-aqueous electrolyte, wherein the anode includes an aqueous binder, and the non-aqueous electrolyte contains (a) a cyclic anhydride or a derivative thereof; and (b) any one anion receptor selected from the group consisting of a borane compound, a borate compound and mixtures thereof. According to the present invention, a stable SEI film is formed on the anode, and the life characteristics of the battery are improved by controlling the LiF content in the SEI film.

Abstract: Disclosed are an organic electrolyte for a lithium-ion battery and a lithium-ion battery comprising the same, wherein the electrolyte includes a base electrolyte containing a lithium salt dissolved in an organic solvent, and diphenyloctyl phosphate added thereto in an amount of 0.1 to 20 wt %. As compared to a conventional organic electrolyte using only a carbonate ester-based solvent, such as ethylene carbonate, ethyl methyl carbonate, etc., the lithium-ion battery employing the organic electrolyte can improve thermal stability of an electrolyte solution, high-rate performance, and charge/discharge cyclability of a battery, while maintaining battery performance of the base electrolyte.

Abstract: Li-based anodes for use in an electric current producing cells having long life time and high capacity are provided. In certain embodiments, the Li-based anode comprises at least one anode active Li-containing compound and a composition comprising at least one polymer, at least one ionic liquid, and optionally at least one lithium salt. The composition may be located between the at least one Li-containing compound and the catholyte used in the electric current producing cell. In some embodiments, the at least one polymer may be incompatible with the catholyte. This configuration of components may lead to separation between the lithium active material of the anode and the catholyte. Processes for preparing the Li-based anode and to electric current producing cells comprising such an anode are also provided.

Abstract: An electrode mixture comprising a lithium nickel manganese composite metal oxide having an average particle diameter of 1 ?m or less, an electrically conductive material and an overcharge inhibition material. The electrode mixture in which the overcharge inhibition material is an aromatic compound. The electrode mixture in which the overcharge inhibition material is one or more members selected from the group consisting of an aramid, a polyether, a polysulfone and a polyethersulfone. An electrode comprising the electrode mixture. A nonaqueous electrolyte secondary battery comprising a positive electrode, a negative electrode capable of being doped and dedoped with lithium ions, a separator and a nonaqueous electrolytic solution, wherein the positive electrode is the electrode described above.

Abstract: Spiro ammonium salts as an additive for electrolytes in electric current producing cells, in particular electric current producing cells comprising a Li-based anode, are provided. In some embodiments, the electric current producing cell comprises a cathode, a Li-based anode, and at least one electrolyte wherein the electrolyte contains at least one spiro ammonium salt.

Abstract: A battery capable of improving cycle characteristics is provided. A separator arranged between a cathode and an anode is impregnated with an electrolytic solution. The electrolytic solution includes: a solvent; and an electrolytic salt, in which the solvent includes a compound having a difluoroalkene structure. The content of the compound having a difluoroalkene structure in the solvent is within a range from 1 wt % to 5 wt % both inclusive.

Abstract: The present invention relates to a nonaqueous electrolyte solution containing new additives and a lithium secondary battery including the same. More particularly, the invention relates to a nonaqueous electrolyte solution containing a lithium salt, an electrolyte compound, a first additive compound with an oxidation initiation potential of more than 4.2 V, and a second additive compound with an oxidation initiation potential of more than 4.2 V, which is higher in oxidation initiation potential than the first additive, and deposits oxidative products or form a polymer film, in oxidation, as well as a lithium secondary battery including the same. The present invention can provide a lithium secondary battery excellent in both the battery performance and the battery safety in overcharge by the combined use of the first additive and the second battery as additives to the nonaqueous electrolyte solution.

Abstract: The present invention relates to a phosphate-based acrylate crosslinking agent for polymer electrolyte and a polymer electrolyte composition comprising the phosphate-based acrylate crosslinking agent, and in particular to a phosphate-based acrylate crosslinking agent where a phosphate-based compound is introduced with a polyalkylene oxide group and an acrylate group and a polymer electrolyte composition comprising the phosphate-based acrylate crosslinking agent. The polymer electrolyte composition can be applied to electrolyte thin film and polymer electrolyte of small and large capacity lithium-polymer secondary battery due to its superior ionic conductivity and electrochemical and thermal stability, where the physical properties of electrolyte composition may be controlled by means of the length of polyalkylene oxide of the crosslinking agent.

Abstract: A non-aqueous electrolyte battery includes a non-aqueous electrolyte containing an electrolytic salt and a non-aqueous solvent, a positive electrode, and a negative electrode having a negative active material that intercalates/deintercalates lithium ions at a potential not lower than 1.2 V relative to the potential of lithium, wherein a film coat having a carbonate structure and a thickness of not less than 10 nm exists on the surface of the negative electrode. A non-aqueous electrolyte battery is operated in a region of potential of the negative electrode higher than 0.8 V relative to the potential of lithium.

Abstract: According to one embodiment, a nonaqueous electrolyte secondary battery includes a nonaqueous electrolytic solution, a positive electrode and a negative electrode is provided. The nonaqueous electrolytic solution comprises a nonaqueous solvent. The nonaqueous solvent comprises from 50 to 95% by volume of a sulfone-based compound represented by the following formula 1: wherein R1 and R2 are each an alkyl group having 1 to 6 carbon atoms and satisfy R1?R2. The positive electrode comprises a composite oxide represented by Li1-xMn1.5-yNi0.5-zMy+zO4. The negative electrode comprises a negative electrode active material being capable of absorbing and releasing lithium at 1 V or more based on a metallic lithium potential.

Abstract: The disclosure relates a niobium oxide useful in anodes of secondary lithium ion batteries. Such niobium oxide has formula LixM1?yNbyNb2O7, wherein 0?x?3, 0?y?1, and M represents Ti or Zr. The niobium oxide may be in the form of particles, which may be carbon coated. The disclosure also relates to an electrode composition containing at least one or more niobium oxides of formula LixM1?yNbyNb2O7. The disclosure further relates to electrodes, such as anodes, and batteries containing at least one or more niobium oxides of formula LixM1?yNbyNb2O7. Furthermore, the disclosure relates to methods of forming the above.

Abstract: Disclosed herein is an electrode structure for an energy storage apparatus. The electrode structure according to an exemplary embodiment of the present invention includes a current collector; and an active material layer formed in the current collector, wherein the active material layer includes: an active material; and a conductive material having a relatively higher content than that of the active material as being away from the current collector.

Abstract: A non-aqueous electrolyte secondary cell can be charged at a high voltage of 4.3V or more and has excellent cycle characteristics and excellent high-temperature storage characteristics. The cell includes positive and negative electrodes capable of inserting and extracting lithium, and a non-aqueous electrolyte. The non-aqueous electrolyte contains a non-aqueous solvent, 1,3-dioxane and a dinitrile compound additives, and an electrolyte salt. The non-aqueous solvent contains ethylene carbonate in the range of 25% to 40% by volume under the conditions of 25° C. and 1 atm.