Comprising A Carbonate Patents (Class 429/478)
  • Patent number: 11374235
    Abstract: An anode of a fuel cell has an anode current collector defining an inlet configured to receive fuel gas and an outlet configured to output the fuel gas, a barrier that divides an active area of the anode current collector into a first area and a second area, and a flow passage configured to allow a flow of fuel gas from the inlet through the first area and the second area to the outlet. An obstacle is located in the flow passage in an inactive area of the anode current collector and is configured to change a flow direction of the fuel gas in the flow passage from the first area to the second area to achieve intra-cell mixing of the fuel gas.
    Type: Grant
    Filed: November 26, 2019
    Date of Patent: June 28, 2022
    Assignee: FuelCell Energy, Inc.
    Inventor: Hossein Ghezel-Ayagh
  • Patent number: 10985384
    Abstract: A cathode current collector is made from a composite material including a first metallic layer made of a first metal and a second metallic layer made of a second metal different from the first metal. The first metallic layer is cladded with the second metallic layer. The first metallic layer is configured to form a conductive oxide corrosion layer in the presence of oxygen, molten carbonate electrolyte, or a combination thereof. The second metallic layer is corrosion resistant.
    Type: Grant
    Filed: January 11, 2018
    Date of Patent: April 20, 2021
    Assignee: FuelCell Energy, Inc.
    Inventors: Ling Chen, Chao-Yi Yuh
  • Patent number: 10957918
    Abstract: A method of making an electrolyte matrix includes: preparing a slurry comprising a support material, a coarsening inhibitor, an electrolyte material, and a solvent; and drying the slurry to form an electrolyte matrix. The support material comprises lithium aluminate, the coarsening inhibitor comprises a material selected from the group consisting of MnO2, Mn2O3, TiO2, ZrO2, Fe2O3, LiFe2O3, and mixtures thereof, and the coarsening inhibitor has a particle size of about 0.005 ?m to about 0.5 ?m.
    Type: Grant
    Filed: July 24, 2020
    Date of Patent: March 23, 2021
    Assignee: FuelCell Energy, Inc.
    Inventors: Abdelkader Hilmi, Arun Surendranath, Chao-Yi Yuh, Mohammad Farooque
  • Patent number: 10494707
    Abstract: Provided is an austenitic stainless steel for a fuel cell including, in weight %, C: 0.05% to 0.09%, Si: 0.5% or less (0 excluded), Mn: 2.5% to 5.0%, Cr: 21% to 23%, Ni: 10% to 12%, Nb: 0.2% to 0.7%, N: 0.25% or less (0 excluded), Al: 0.2% or less (0 excluded), S: 0.003% or less (0 excluded), B: 0.01% or less (0 excluded), the remainder being Fe and unavoidable impurities.
    Type: Grant
    Filed: December 22, 2015
    Date of Patent: December 3, 2019
    Assignee: POSCO
    Inventors: Kwang Min Kim, Jong Hee Kim, Ki Hoon Jo, Bo Sung Seo
  • Patent number: 10455852
    Abstract: A defrosting tray includes a metal substrate, a thermal conductive ceramic coating formed on the top surface of the metal substrate, and an inorganic nanocoating formed on a top surface of the thermal conductive ceramic coating. The thermal conductive ceramic coating is configured to enhance a heat transfer capability of the metal substrate. In particular, the first ceramic coating and the first inorganic nanocoating together define a defrosting surface with sub-micron pyramidal arrays.
    Type: Grant
    Filed: April 13, 2016
    Date of Patent: October 29, 2019
    Inventor: Meng-Hsiu Hsieh
  • Patent number: 10381655
    Abstract: A novel method to modify the surface of lanthanum and strontium containing cathode powders before or after sintering by depositing layers of gadolinium doped ceria (GDC) and/or samarium doped ceria or similar materials via atomic layer deposition on the powders. The surface modified powders are sintered into porous cathodes that have utility enhancing the electrochemical performance of the cathodes, particularly for use in solid oxide fuel cells. Similar enhancements are observed for surface treatment of sintered cathodes.
    Type: Grant
    Filed: July 13, 2016
    Date of Patent: August 13, 2019
    Assignee: Sonata Scientific LLC
    Inventors: Jeffrey F. Roeder, Anthony F. Zeberoff, Peter C. Van Buskirk
  • Patent number: 10276875
    Abstract: An anode for a molten carbonate fuel cell (MCFC) having improved creep property by adding CeO2 and/or Cr for imparting creep resistance to nickel-aluminum alloy and nickel as materials for an anode is provided. Improved sintering property, creep property and increased mechanical strength of a molten carbonate fuel cell may be obtained accordingly.
    Type: Grant
    Filed: December 9, 2016
    Date of Patent: April 30, 2019
    Assignee: Korean Institute of Science and Technology
    Inventors: Hyung Chul Ham, Min-Jae Lee, Chang-Whan Lee, Seong Cheol Jang, Sun-Hee Choi, Hyun Seo Park, Chang Won Yoon, Sung Pil Yoon, Jonghee Han, Suk Woo Nam, Tae Hoon Lim, Jin Young Kim
  • Patent number: 9627728
    Abstract: A rechargeable electrochemical battery cell includes a molten carbonate salt electrolyte whose anion transports oxygen between a metal electrode and an air electrode on opposite sides of the electrolyte, where the molten salt electrolyte is retained inside voids of a porous electrolyte supporting structure sandwiched by the electrodes, and the molten salt includes carbonate including at least one of the alkaline carbonate including Li2Co2, NA2CO2, and K2CO2, having a melting point between 400° C. and 800° C.
    Type: Grant
    Filed: November 2, 2012
    Date of Patent: April 18, 2017
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventor: Chun Lu
  • Patent number: 9496576
    Abstract: The present invention relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material, at least one metal and a catalyst material, and wherein the overall thickness of the thin reversible cell is about 150 ?m or less, and to a method for producing same. The present invention also relates to a thin and in principle unsupported solid oxide cell, comprising at least a porous anode layer, an electrolyte layer and a porous cathode layer, wherein the anode layer and the cathode layer comprise an electrolyte material and a catalyst material, wherein the electrolyte material is doper zirconia, and wherein the overall thickness of the thin reversible cell is about 150 ?m or less, and to a method for producing same.
    Type: Grant
    Filed: November 23, 2007
    Date of Patent: November 15, 2016
    Assignee: Technical University of Denmark
    Inventors: Peter Halvor Larsen, Soeren Linderoth, Peter Vang Hendriksen
  • Patent number: 9225030
    Abstract: The present disclosure relates to a solid oxide fuel cell. The solid oxide fuel cell includes an electrolyte comprising a mixed proton and carbonate ion conductor. The mixed proton and carbonate ion conductor includes a proton conducting ceramic impregnated with impregnated with a molten carbonate.
    Type: Grant
    Filed: June 20, 2012
    Date of Patent: December 29, 2015
    Assignee: University of South Carolina
    Inventors: Kevin Huang, Xue Li
  • Patent number: 9160023
    Abstract: The present invention relates to an electrolyte-impregnated, reinforced matrix for molten carbonate fuel cells and a manufacturing method thereof. According to the invention, the electrolyte-impregnated matrix, which comprises both the electrolyte and the reinforcing particles including a metal and an oxide, is manufactured by adding the electrolyte, as required per unit cell of a fuel cell, and the reinforcing particles including the metal and the oxide, to a slurry during the matrix preparation step, and subjecting the resulting slurry to a tape casting process. By doing so, the matrix stacking operation is facilitated, and the matrix manufacturing process is simplified. In addition, cracking caused by the difference in thermal expansion coefficient between an electrolyte sheet and the matrix can be suppressed, and thermal shock occurring during operation of the fuel cell stack can be reduced, thus improving the performance and lifetime of the fuel cell.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: October 13, 2015
    Assignee: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD.
    Inventors: Mi Young Shin, Bo Hyun Ryu, Hwan Moon, Ju Young Youn, Chang Sung Jun, Tae Won Lee, Kil Ho Moon
  • Patent number: 9065127
    Abstract: Systems and methods for sintering and conditioning fuel cell stacks utilizing channel guides, baffles, and internal compression systems are provided. Sintering and conditioning may be performed utilizing a fuel cell column cartridge assembly and fuel cell stacks may be sintered and conditioned at the system level during the same annealing cycle on the same support.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: June 23, 2015
    Assignee: BLOOM ENERGY CORPORATION
    Inventors: Matthias Gottmann, Nathan Ben Erlin, Kurt Risic, Stephen Couse, David Edmonston
  • Patent number: 8999598
    Abstract: Disclosed is a molten carbonate fuel cell comprising a reinforced lithium aluminate matrix, a cathode, an anode, a cathode frame channel and an anode frame channel, wherein at least one of the cathode frame channel and the anode frame channel is filled with a lithium source. Disclosed also are a method for producing the same, and a method for supplying a lithium source. The molten carbonate fuel cell in which a lithium source is supplied to an electrode has high mechanical strength and maintains stability of electrolyte to allow long-term operation.
    Type: Grant
    Filed: January 18, 2012
    Date of Patent: April 7, 2015
    Assignee: Korea Institute of Science & Technology
    Inventors: Sung Pil Yoon, In Hwan Oh, Jong Hee Han, Suk Woo Nam, Seong Cheol Jang, Shin Ae Song, Tae Won Lee, In Gab Chang, Bo Hyun Ryu
  • Publication number: 20150093676
    Abstract: Systems and methods are provided for incorporating molten carbonate fuel cells into a heat recovery steam generation system (HRSG) for production of electrical power while also reducing or minimizing the amount of CO2 present in the flue gas exiting the HRSG. An optionally multi-layer screen or wall of molten carbonate fuel cells can be inserted into the HRSG so that the screen of molten carbonate fuel cells substantially fills the cross-sectional area. By using the walls of the HRSG and the screen of molten carbonate fuel cells to form a cathode input manifold, the overall amount of duct or flow passages associated with the MCFCs can be reduced.
    Type: Application
    Filed: July 8, 2014
    Publication date: April 2, 2015
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Paul J. Berlowitz, Timothy Andrew Barckholtz, Frank H. Hershkowitz
  • Patent number: 8936887
    Abstract: A composite electrolyte membrane for a fuel cell with a controlled phosphoric acid-based material retention ratio. The composite electrolyte membrane includes an electrolyte membrane containing a compound having a phosphoric acid-based material-containing functional group. Also disclosed are a method for manufacturing the composite electrolyte membrane, and a fuel cell including the composite electrolyte membrane.
    Type: Grant
    Filed: February 3, 2012
    Date of Patent: January 20, 2015
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Seong-woo Choi, Dae-jong Yoo, Ki-hyun Kim
  • Patent number: 8932779
    Abstract: A device for a solid oxide fuel cell or a solid oxide electrolysis cell includes an integral one-piece construction of a current collector and a manifold. The device eliminates the need for a brazing or thermal bonding process for joining the manifold with the current collector, and thus makes it possible to prevent breakdown of the junction formed between the manifold and the current collector, which can lead to gas leakage through the junction, and thus can be used for a long period of time.
    Type: Grant
    Filed: August 15, 2012
    Date of Patent: January 13, 2015
    Assignee: Korea Institute of Energy Research
    Inventors: Sun-Dong Kim, Doo-Won Seo, In-Sub Han, Ji-Haeng Yu, Se-Young Kim, Sang-Kuk Woo
  • Patent number: 8557468
    Abstract: A high-performance carbonate electrolyte for use in a molten carbonate fuel cell comprising a cathode electrode, an anode electrode, an electrolyte matrix and at least a cathode current collector abutting said cathode electrode, the high-performance carbonate electrolyte comprising: a first carbonate electrolyte stored in at least the cathode electrode of the molten carbonate fuel cell comprising a mixture of eutectic Li/Na carbonate electrolyte doped with one or more additive materials and one or more lithium precursors, wherein the additive materials include one or more of Rb2CO3, Cs2CO3, BaCO3, La2O3, Bi2O3, Ta2O5 and mixtures thereof, and a second carbonate electrolyte stored in at least the cathode current collector, the second carbonate electrolyte having a composition that is the same or different from the first carbonate electrolyte.
    Type: Grant
    Filed: July 21, 2010
    Date of Patent: October 15, 2013
    Assignee: FuelCell Energy, Inc.
    Inventors: Abdelkader Hilmi, Chao-Yi Yuh, Mohammad Farooque
  • Publication number: 20130224621
    Abstract: A molten carbonate fuel cell, which makes a separator unnecessary, cuts down the number of components, and markedly reduces the costs, is provided. In the cell, a cathode, an electrolyte plate holding an electrolyte, and an anode are provided concentrically with a tube body, the electrolyte plate is held by the anode, and the electrolyte plate is sandwiched between the anode and the cathode, so that the cell is constructed without the use of a separator.
    Type: Application
    Filed: February 26, 2013
    Publication date: August 29, 2013
    Applicant: CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRY
    Inventor: CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRY
  • Publication number: 20130143142
    Abstract: The present invention discloses a novel BZCYYb-carbonate composite electrolyte and method for making the same. The BZCYYb is porous, and the lithium-potassium carbonate is infiltrated or entrained within the pores of the BZCYYb to have better conductivity at the phase boundaries.
    Type: Application
    Filed: August 28, 2012
    Publication date: June 6, 2013
    Applicants: GEORGIA TECH RESEARCH CORPORATION, PHILLIPS 66 COMPANY
    Inventors: Mingfei LIU, Meilin LIU, Ting HE
  • Patent number: 8435694
    Abstract: A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.
    Type: Grant
    Filed: January 12, 2004
    Date of Patent: May 7, 2013
    Assignee: FuelCell Energy, Inc.
    Inventors: Abdelkader Hilmi, Chao-Yi Yuh
  • Patent number: 8383283
    Abstract: A fuel cell includes an electrolyte matrix having a cathode side with a cathode disposed thereon and an anode side with an anode receiving portion and a sealing portion positioned peripherally to the anode receiving portion. The anode receiving portion has an anode disposed thereon. A fuel conduit has one or more one sealing platforms and having an opening extending through the fuel conduit. The anode is positioned in the opening. The fuel cell includes one or more devices for preventing the occurrence an electrical short circuit between the cathode and the sealing platform. The device for preventing the electrical short circuit is aligned with the sealing portion and sealing platform and is positioned on the electrolyte matrix, the cathode and/or the sealing platform.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: February 26, 2013
    Assignee: FuelCell Energy, Inc.
    Inventors: Chao-yi Yun, Mohammad Farooque, Abdelkader Hilmi, Richard Johnsen, Gengfu Xu
  • Patent number: 8367265
    Abstract: A solid oxide fuel cell includes an anode layer, an electrolyte layer over the anode layer, and a cathode layer over the electrolyte layer. At least one of the anode layer and the cathode layer defines a gas manifold. The gas manifold includes a gas inlet, defined by an edge of the anode layer or cathode layer, a gas outlet, defined by the same or a different edge of the anode layer or cathode layer, and a plurality of gas flow channels in fluid communication with the gas inlet and gas outlet. The gas flow channels can have diameters that conduct flow of gas from the gas inlet at substantially equal flow rates among the gas flow channels.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: February 5, 2013
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: James A. Salvatore, Vignesh Rajamani, Abhijit Dutta
  • Patent number: 8338041
    Abstract: To provide a reformer that uses a relatively inexpensive granular catalyst and can provide a more uniform temperature distribution in a catalyst bed while suppressing increase in the size of the reformer and the required power and size of an auxiliary machine, and a more compact indirect internal reforming high temperature fuel cell while suppressing increase in cost. A reformer that produces a hydrogen-containing gas from a hydrocarbon-based fuel by a steam reforming reaction has a reactor vessel and a reforming catalyst bed packed with a granular catalyst having steam reforming activity in the reactor vessel, the reformer has a partition plate that divides the reforming catalyst bed into at least two sections, the partition plate has a thermal conductivity higher than effective thermal conductivity of the catalyst bed, and the partition plate extends in the reactor vessel from a part which is at a higher temperature in a rated operation to a part which is at a lower temperature in rated operation.
    Type: Grant
    Filed: May 15, 2008
    Date of Patent: December 25, 2012
    Assignee: Nippon Oil Corporation
    Inventor: Susumu Hatada
  • Patent number: 8283078
    Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.
    Type: Grant
    Filed: December 16, 2011
    Date of Patent: October 9, 2012
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: John F. Cooper, Nerine Cherepy
  • Publication number: 20120231364
    Abstract: Provided is a cathode for molten carbonate fuel cells, including a porous nickel-based electrode containing nickel particles, and metal particles coated on the electrode, wherein at least a part of the metal particles are attached to the surface of the nickel particles. A method for preparing the same is also provided. The cathode for molten carbonate fuel cells accelerates the cathodic oxygen reduction and reduces polarization resistance occurring at the cathode, thereby providing a fuel cell with improved performance even at low temperature. Additionally, it is possible to improve the service life of a molten carbonate fuel cell due to such low operation temperature.
    Type: Application
    Filed: January 19, 2012
    Publication date: September 13, 2012
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Jong Hee HAN, Shin Ae SONG, Sung Pil YOON, Suk Woo NAM, Tae Hoon LIM, In Hwan OH, Dae Ki CHOI, Seong Ahn HONG, Chang Won YOON
  • Patent number: 8182962
    Abstract: The present invention relates to a fuel cell separator plate comprising at least one separator sheet and at least one flange suitable to be fixed on the side of the separator sheet by means of shape-coupling. The invention also relates to a fuel cell comprising said separator sheet, preferably a molten carbonate fuel cell (MCFC). The invention also relates to a stack of these fuel cells being electrically coupled to each other.
    Type: Grant
    Filed: April 21, 2005
    Date of Patent: May 22, 2012
    Assignee: Ansaldo Fuels S.p.A.
    Inventors: Sergio Fasce, Lorenzo Tosonotti, Maurizio Zappaterra
  • Patent number: 8163437
    Abstract: A molten carbonate fuel cell anode comprising a porous anode body, which comprises a nickel-based alloy and at least one ceramic additive dispersed throughout the anode body. The amount of the ceramic additive in the anode body is between 5 and 50% by volume. The nickel-based alloy is Ni—Cr or Ni—Al, and the ceramic additive is one of CeO2, yttrium doped ceria, yttrium doped zirconia, TiO2, Li2TiO3, LiAlO2 and La0.8Sr0.2CoO3.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: April 24, 2012
    Assignee: FuelCell Energy, Inc.
    Inventors: Abdelkader Hilmi, Chao-Yi Yuh, Mohammad Farooque
  • Patent number: 8110314
    Abstract: A system and a method for suppressing the build up of metal carbonates in the electrolyte, using a porous cell separator is used to allow the use of different electrolyte compositions around the anode (anolyte) and the cathode (catholyte). This cell configuration enables the oxygen cathode to operate in a molten hydroxide electrolyte, and the carbon anode to operate in mixed carbonate-hydroxide melt, so that most of the advantages of using a molten hydroxide electrolyte will be retained.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: February 7, 2012
    Assignee: Scientific Applications and Research Associates, Inc.
    Inventors: Strahinja Zecevic, Edward Patton, Parviz Parhami
  • Publication number: 20120021328
    Abstract: A high-performance carbonate electrolyte for use in a molten carbonate fuel cell comprising a cathode electrode, an anode electrode, an electrolyte matrix and at least a cathode current collector abutting said cathode electrode, the high-performance carbonate electrolyte comprising: a first carbonate electrolyte stored in at least the cathode electrode of the molten carbonate fuel cell comprising a mixture of eutectic Li/Na carbonate electrolyte doped with one or more additive materials and one or more lithium precursors, wherein the additive materials include one or more of Rb2CO3, Cs2CO3, BaCO3, La2O3, Bi2O3, Ta2O5 and mixtures thereof, and a second carbonate electrolyte stored in at least the cathode current collector, the second carbonate electrolyte having a composition that is the same or different from the first carbonate electrolyte.
    Type: Application
    Filed: July 21, 2010
    Publication date: January 26, 2012
    Inventors: ABDELKADER HILMI, Chao-Yi Yuh, Mohammad Farooque
  • Patent number: 8101305
    Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: January 24, 2012
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: John F. Cooper, Nerine Cherepy
  • Publication number: 20110287333
    Abstract: The present invention relates to an electrolyte-impregnated, reinforced matrix for molten carbonate fuel cells and a manufacturing method thereof. According to the invention, the electrolyte-impregnated matrix, which comprises both the electrolyte and the reinforcing particles including a metal and an oxide, is manufactured by adding the electrolyte, as required per unit cell of a fuel cell, and the reinforcing particles including the metal and the oxide, to a slurry during the matrix preparation step, and subjecting the resulting slurry to a tape casting process. By doing so, the matrix stacking operation is facilitated, and the matrix manufacturing process is simplified. In addition, cracking caused by the difference in thermal expansion coefficient between an electrolyte sheet and the matrix can be suppressed, and thermal shock occurring during operation of the fuel cell stack can be reduced, thus improving the performance and lifetime of the fuel cell.
    Type: Application
    Filed: October 29, 2009
    Publication date: November 24, 2011
    Applicant: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD.
    Inventors: Mi Young Shin, Bo Hyun Ryu, Hwan Moon, Ju Young Youn, Chang Sung Jun, Tae Won Lee, Kil Ho Moon
  • Publication number: 20110250521
    Abstract: Disclosed herein is a method of manufacturing an anode for in-situ sintering for a molten carbonate fuel cell, in which an anode green sheet is prepared using a slurry, and then a reinforcing layer is placed on the anode green sheet and then pressed, thereby improving the mechanical stability of a fuel cell stack and the long term stability of an anode, and an anode manufactured using the method.
    Type: Application
    Filed: February 26, 2009
    Publication date: October 13, 2011
    Applicant: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD
    Inventors: Hwan Moon, Bo Hyun Ryu, Jang Yong You, Ju Young Youn, Mi Young Shin, Woon Yong Choi, Tae Won Lee, In Gab Chang, Kil Ho Moon
  • Patent number: 7998627
    Abstract: A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: August 16, 2011
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: John F. Cooper, Nerine Cherepy
  • Publication number: 20110177422
    Abstract: Reaction mechanisms in a fuel cell device are disclosed. In one aspect of the present disclosure, the fuel cell includes a composite cathode element that is vertically oriented. The composite cathode element further comprises a porous matrix holding electrolyte, a cathode, and/or a cathode current collector. One embodiment of the fuel cell further includes, an anode chamber coupled to the composite cathode element, the anode chamber being vertically oriented. During operation, fuel injected into the fuel cell is oxidized in the anode chamber by oxidizer ions are generated from oxidizer gas. The oxidizer gas can include a mixture of oxygen and carbon dioxide or just oxygen.
    Type: Application
    Filed: January 15, 2010
    Publication date: July 21, 2011
    Applicant: 4D Power, LLC
    Inventors: Ronald H. Wolk, Iouri I. Balachov, J. Robert Selman
  • Patent number: 7981563
    Abstract: A direct carbon fuel cell having an anode electrode of carbon particles pre-wetted with carbonate, a cathode electrode, and an electrolyte layer disposed between the anode electrode and the cathode electrode and containing a molten carbonate. The fuel cell includes a wicking feature whereby excess carbonate produced during the operation of the fuel cell is removed. The use of carbonate pre-wetted carbon particles as the anode provides a network of empty voids, facilitating the removal of CO2 gas from the cell, thereby enhancing fuel cell performance.
    Type: Grant
    Filed: November 26, 2007
    Date of Patent: July 19, 2011
    Assignee: Gas Technology Institute
    Inventors: Estela T. Ong, Kevin Krist, Chakravarthy Sishtla
  • Publication number: 20110151349
    Abstract: A double-electrolyte fuel-cell is presented for generating electrical energy from chemical fuel. The fuel-cell includes an anode, a cathode as well as both an anion-conducting electrolyte and a cation-conducting electrolyte. A fuel-cell stack is also presented consisting of a plurality of double-electrolyte fuel-cells.
    Type: Application
    Filed: June 10, 2009
    Publication date: June 23, 2011
    Applicant: TECHNION RESEARCH & DEVELOPMENT FOUNDATION LTD.
    Inventor: Yoed Tsur
  • Patent number: 7919214
    Abstract: Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of Perovskite AMeO3, wherein A is at least one of lanthanum and a combination of lanthanum and strontium and Me is one or more of transition metals, lithiated NiO (LixNiO, where x is 0.1 to 1) and X-doped LiMeO2, wherein X is one of Mg, Ca, and Co.
    Type: Grant
    Filed: May 25, 2005
    Date of Patent: April 5, 2011
    Assignee: FuelCell Energy, Inc.
    Inventors: Gengfu Xu, Chao-Yi Yuh
  • Patent number: 7914946
    Abstract: Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La0.8Sr0.2CoO3) and lithiated NiO (LixNiO, where x is 0.1 to 1).
    Type: Grant
    Filed: June 15, 2004
    Date of Patent: March 29, 2011
    Assignee: FuelCell Energy, Inc.
    Inventors: Gengfu Xu, Chao-Yi Yuh
  • Patent number: 7862938
    Abstract: A fuel cell and heat engine hybrid system using a high-temperature fuel cell having an anode compartment adapted to receive fuel from a fuel supply path and to output anode exhaust gas and a cathode compartment adapted to receive oxidant gas and to output cathode exhaust gas. A heat engine assembly is adapted to receive oxidant gas and a further gas comprising one of the anode exhaust gas and a gas derived from the anode exhaust gas and to cause oxidation of the further gas and generate output power, the heat engine also generating heat engine exhaust including oxidant gas. The heat engine exhaust is then used to provide oxidant gas to the cathode compartment of the fuel cell.
    Type: Grant
    Filed: April 10, 2007
    Date of Patent: January 4, 2011
    Assignee: FuelCell Energy, Inc.
    Inventor: Hossein Ghezel-Ayagh
  • Publication number: 20100196778
    Abstract: The present invention provides a method of manufacturing a porous metal electrode for a molten carbonate fuel cell using a dry process. According to the method of manufacturing a porous metal electrode of the present invention, in the press process for controlling the thickness of dry-cast metal powder and rearranging the dry-cast metal powder, the microstructure of the porous metal electrode can be controlled, and the uniformity of the thickness of the porous metal electrode can also be controlled. Therefore, the method of manufacturing a porous metal electrode according to the present invention can be used to manufacture both an anode and a cathode.
    Type: Application
    Filed: December 29, 2008
    Publication date: August 5, 2010
    Applicant: DOOSAN HEAVY INDUSTRIES & CONSTRUCTION CO., LTD.
    Inventors: Ju Young Youn, Bo Hyun Ryu, Jang Yong Yoo, Mi Young Shin, Hwan Moon, Woon Yong Choi, Tae Won Lee, In Gab Chang, Kil Ho Moon
  • Patent number: 7767359
    Abstract: A device for producing water on board an aircraft includes at least one high temperature fuel cell entirely or partially integrated into a combustion chamber arrangement of a gas turbine aircraft engine. The combination of at least one fuel cell and a gas turbine engine is adapted to operate exclusively with hydrogen and atmospheric oxygen, and is embodied in an aircraft propulsion engine and/or an auxiliary power unit used for producing compressed air for a cabin and a power supply of the aircraft. The at least one high temperature fuel cell is fed with pure hydrogen on an anode side and with air on a cathode side. The combustion chambers of the turbine engine are fed with an air-hydrogen mixture, whereby at least the hydrogen supply can be regulated or completely shut off.
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: August 3, 2010
    Assignee: Airbus Deutschland GmbH
    Inventors: Claus Hoffjann, Hans-Juergen Heinrich