Membrane Electrode Assembly (mea) Patents (Class 429/483)
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Patent number: 8470497Abstract: Methods for attaching a subgasket to an ionomer membrane, wherein the methods provide for the precise location of the subgasket relative to the other component edges of the fuel cell, such as the catalyst layers, so as provide the functionality required to extend the ionomer membrane life and prevent damage to the ionomer membrane during the assembly process.Type: GrantFiled: November 8, 2006Date of Patent: June 25, 2013Assignee: GM Global Technology Operations LLCInventors: Ronald L. James, Seth D. Valentine, James Liestra
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Publication number: 20130157170Abstract: Provided are a method for depositing a catalyst in a fuel cell, a fuel cell obtained by the method, and an apparatus for operating the fuel cell. The method for depositing a catalyst in a fuel cell includes: oxidizing a catalyst provided at the top of the cathode with air introduced to the cathode under the operating condition of the fuel cell; and depositing the oxidized catalyst gas at the reactive zone of the cathode. The method allows deposition of an activated catalyst ingredient at the cathode of a fuel cell by disposing a catalyst (such as Pt, Ag, Pd, Ru, etc.) highly reactive to reduction of oxygen at the side to which oxygen is introduced, and oxidizing and vaporizing the catalyst under an actual operating condition.Type: ApplicationFiled: April 9, 2012Publication date: June 20, 2013Inventors: Joong Myeon BAE, Sung Min Shin, Kun Ho Lee, Junhyun Kang
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Patent number: 8465882Abstract: A membrane-electrode assembly for a solid polymer electrolyte fuel cell includes a proton-conductive composite membrane including a reinforcing sheet and an electrolyte membrane. The reinforcing sheet has through-holes extending in a thickness direction of the reinforcing sheet. The through-holes are provided in a portion other than an edge of the reinforcing sheet in an in-plane direction. An anode electrode layer is provided on one surface of the proton-conductive composite membrane. A cathode electrode layer is provided on another surface of the proton-conductive composite membrane. At least one of an edge of the anode electrode layer and an edge of the cathode electrode layer in the in-plane direction is arranged outside in the in-plane direction with respect to the portion in which the plurality of through-holes are provided.Type: GrantFiled: May 27, 2010Date of Patent: June 18, 2013Assignee: Honda Motor Co., Ltd.Inventors: Akihiro Noda, Ryoji Takenawa, Akimasa Daimaru
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Patent number: 8455152Abstract: An integrated PEM fuel cell includes bipolar plate assemblies that utilize fiber groups that extend from the surfaces of gas impermeable plates to terminate in uncoated tips facing adjacent tips to form anodes and cathodes of an MEA assembly. The catalyst support and catalyst can be applied to the tips as beads or thin layers and joined with a membrane. The assembly can use a unified seal and include collector plates at the ends of the stacks, using similar fiber construction.Type: GrantFiled: October 22, 2009Date of Patent: June 4, 2013Assignee: EnerFuel, Inc.Inventor: Vesna Stanic
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Publication number: 20130130151Abstract: A metal alloy catalyst for the oxygen reduction reaction in fuel cells is disclosed. The catalyst contains the metals Pd, M1 and M2. M1 and M2 are different metals selected from Co, Fe, Au, Cr and W, excluding the combination PdCoAu.Type: ApplicationFiled: November 8, 2012Publication date: May 23, 2013Applicant: Ilika Technologies Ltd.Inventors: Karen Marie Brace, Brian Elliot Hayden, Christopher Edward Lee, Thierry Le Gall
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Patent number: 8445162Abstract: A cathode catalyst includes a carrier including Mo, S, and I, and an active metal supported on the carrier and including a material selected from the group consisting of Ru, Pt, Rh, and combinations thereof. It is shown that such a catalyst for a cathode has improved activity over platinum catalysts.Type: GrantFiled: March 16, 2007Date of Patent: May 21, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Alexey Alexandrovichserov, Chan Kwak, Si-Hyun Lee
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Publication number: 20130122397Abstract: A polymer electrolyte fuel cell according to the present invention includes: an electrolyte layer-electrode assembly (5); a first separator (6A) provided with a first reaction gas flowing region; and a second separator (6B) provided with a second reaction gas flowing region. In the first separator (6A), among one or more first turn portions (28), at least one first turn portion (28) is provided with a first recess (48) and first projections (58). In the second separator (6B), among one or more second turn portions (29), at least one second turn portion (29) is provided with a second recess (49) and second projections (59). When seen in the thickness direction of the first separator (6A), an overlap area is less than or equal to 5% of a gross area, the overlap area being a total overlap area between the first and second recesses (48, 49), the gross area being the total of the following areas: the area of all the first recesses (48); and the area of all the second recesses (49).Type: ApplicationFiled: March 2, 2012Publication date: May 16, 2013Applicant: PANASONIC CORPORATIONInventor: Shinsuke Takeguchi
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Patent number: 8440364Abstract: A membrane electrode assembly includes an solid polymer electrolyte membrane, an anode, and a cathode. The cathode has a stacked body of a catalyst layer and a gas diffusion layer. The catalyst layer has platinum-cobalt-supporting carbon particles and an ion conductor. The ratio (P2/P1) of the pore volume P2 (ml/g) per gram of catalyst layer in a second micro-pore diameter, ranging from 0.1 ?m to less than 1 ?m, over the pore volume P1 per gram of catalyst layer in a first micro-pore diameter, ranging from 0.01 ?m to less than 0.1 ?m, is in a range of 3.8 to 8.3.Type: GrantFiled: March 6, 2009Date of Patent: May 14, 2013Assignee: Sanyo Electric Co., Ltd.Inventor: Koji Matsuoka
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Patent number: 8440366Abstract: Disclosed is a solid polymer electrolyte fuel cell membrane comprising an anion exchange membrane that contains a hydrocarbon-based anion exchange resin, wherein the water permeability at 25° C. is 1400 g m?2 hr?1 or greater, the anion exchange capacity is 0.2 to 5.0 mmol·g?1, the percentage of water content at 25° C. is 7% by weight or greater, and the thickness is 3 to 50 ?m. It is especially preferable as a solid polymer electrolyte fuel cell membrane when said anion exchange membrane is an ion exchange membrane with a 5 to 15 ?m-thick porous membrane substrate, wherein the voids in said porous membrane are filled with a hydrocarbon-based anion exchange resin.Type: GrantFiled: December 17, 2008Date of Patent: May 14, 2013Assignee: Tokuyama CorporationInventors: Kenji Fukuta, Takenori Isomura, Hiroyuki Yanagi
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Patent number: 8431285Abstract: Edge designs, especially for ePTFE-reinforced membranes for proton exchange membrane (PEM) fuel cells, wherein the designs provide a proton barrier at the electrode edge of the PEM fuel cell membrane electrode assembly (MEA) to provide, among other things, resistance to membrane chemical degradation. A portion of the ePTFE layer is imbibed with a proton-impermeable polymer at the electrode edge. The polymer can include, without limitation, B-staged epoxides, B-staged phenolics, hot melt thermoplastics, and/or thermosets or thermoplastics cast from liquid dispersions.Type: GrantFiled: November 3, 2006Date of Patent: April 30, 2013Assignee: GM Global Technology Operations LLCInventors: William H. Pettit, Michael K. Budinski, Wenbin Gu
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Patent number: 8426078Abstract: A first transport system moves a web comprising a subgasketed CCM layer and an application system applies a crosslinkable resin to at least a subgasketed portion of the subgasketed CCM layer. The crosslinkable resin preferably comprises a photocurable cationic crosslinkable resin. A first curing apparatus subjects an exposed surface of the crosslinkable resin to a photo curing process to initiate curing of the crosslinkable resin. A second transport system moves a GDL into adhering contact with a partially cured exposed surface of the crosslinkable resin of the CCM layer so as to form an MEA layer. A second curing apparatus subjects the GDL, partially cured crosslinkable resin, and CCM layer structure to a thermal curing process to substantially complete curing of the crosslinkable resin. A converting system is configured to receive the MEA layer and produce a plurality of discrete MEAs from the MEA layer.Type: GrantFiled: December 21, 2007Date of Patent: April 23, 2013Assignee: 3M Innovative Properties CompanyInventors: Michael A. Yandrasits, Michael T. Hicks, Daniel M. Pierpont
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Patent number: 8426076Abstract: A fuel cell includes a membrane electrode assembly (MEA), a fuel delivery system distributing fuel to an anode side of the MEA, and a flow distributor delivering an oxidizer to a cathode side of the MEA. The flow distributor includes at least one serpentine channel through which the oxidizer is delivered to the cathode side of the MEA. Each portion of the serpentine channel delivers oxidizer to a portion of the cathode side of the MEA in contact, directly or through a porous diffuser, with the channel portion. The channel portion transfers water with the portion of the MEA in contact with the channel portion and also transfers water between adjacent channel portions via a water-permeable, gas impermeable material that defines at least a portion of the channel.Type: GrantFiled: May 9, 2007Date of Patent: April 23, 2013Assignee: Bose CorporationInventors: Lifun Lin, Jean-Pei Jeanie Cherng
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Publication number: 20130095409Abstract: The present invention relates to a method for the conditioning of membrane electrode assemblies for fuel cells in which the output of the membrane electrode assemblies used can be increased and therefore the efficiency of the resulting polymer electrolyte membrane fuel cells can be improved.Type: ApplicationFiled: October 24, 2012Publication date: April 18, 2013Applicant: BASF Fuel Cell GmbHInventor: BASF Fuel Cell GmbH
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Patent number: 8420274Abstract: A membrane electrode assembly for a fuel cell, includes: an electrolyte membrane, and cathode and anode that are respectively disposed on opposing surfaces of the electrolyte membrane, wherein the anode comprises an anode catalyst layer, an anode micro-porous layer and an anode diffusion support that are sequentially disposed on one surface of the electrolyte membrane, wherein the thickness ratio of the anode catalyst layer to the anode micro-porous layer is in a range of 1:0.82 to 1:3.28, and the thickness ratio of the anode catalyst layer to the anode diffusion support is in a range of 1:5 to 1:7.05.Type: GrantFiled: December 18, 2008Date of Patent: April 16, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Yoonhoi Lee, Daejong Yoo, Chanho Pak
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Patent number: 8420275Abstract: Electro membrane assemblies are formed respectively in openings provided in a substrate. Each membrane electrode assembly is provided with an electrolyte membrane, an anode catalyst layer, and a cathode catalyst layer. A protective layer is provided on the substrate disposed between the adjacent anode catalyst layers. The other protective layer is provided on the substrate disposed between the adjacent cathode catalyst layers. The protective layer and the other protective layer preferably contain a resin whose number of C—F bonds is greater than that of the substrate.Type: GrantFiled: March 30, 2010Date of Patent: April 16, 2013Assignee: Sanyo Electric Co., Ltd.Inventors: Yuko Nowatari, Takahiro Isono
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Publication number: 20130089805Abstract: A membrane electrode assembly (MEA) includes an ion exchange membrane having a polymer, and a first porous layer on its cathode side including a first material different from the polymer having at least one electroactive species providing a reduction potential between 0V and 1V vs. a standard hydrogen electrode at 25° C. adsorbed thereto. A cathode catalyst is on the first porous layer, and an anode catalyst is on the anode side of the ion exchange membrane.Type: ApplicationFiled: October 8, 2012Publication date: April 11, 2013Applicant: University of Central Florida Research Foundation, Inc.Inventor: University of Central Florida Research Foundation,
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Patent number: 8415071Abstract: An electrolyte membrane (11) includes: a filler (20); and a polymer electrolyte (22). A thickness of the electrolyte membrane (11) is 1 micrometer to 500 micrometer, a moisture content thereof is 10 mass % or more, and a ratio of a swelling ratio in a membrane surface direction (xy) thereof and a swelling ratio in a membrane thickness direction (z) thereof satisfies following Expression 1: where Lambda z is the swelling ratio in the membrane thickness direction (z), and Lambda xy is the swelling ratio in the membrane surface direction (xy). ? ? ? xy ? ? ? z < 0.3 [ Math .Type: GrantFiled: June 4, 2008Date of Patent: April 9, 2013Assignee: Nissan Motor Co., Ltd.Inventors: Shiro Tanaka, Hiroshi Tabata, Shuguo Zhang
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Patent number: 8415012Abstract: A membrane electrode assembly (MEA) for a fuel cell comprising a catalyst layer and a method of making the same. The catalyst layer can include a plurality of catalyst nanoparticles, e.g., platinum, disposed on buckypaper. The catalyst layer can have 1% or less binder prior to attachment to the membrane electrode assembly. The catalyst layer can include (a) single-wall nanotubes, small diameter multi-wall nanotubes, or both, and (b) large diameter multi-wall nanotubes, carbon nanofibers, or both. The ratio of (a) to (b) can range from 1:2 to 1:20. The catalyst layer can produce a surface area utilization efficiency of at least 60% and the platinum utilization efficiency can be 0.50 gPt/kW or less.Type: GrantFiled: July 17, 2009Date of Patent: April 9, 2013Assignee: Florida State University Research Foundation, Inc.Inventors: Jian-ping Zheng, Zhiyong Liang, Ben Wang, Chun Zhang, Wei Zhu
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Patent number: 8404610Abstract: It is an object of the present invention to provide a production process which can produce a fuel cell catalyst having excellent durability and high oxygen reducing activity. The process for producing a fuel cell catalyst including a metal-containing oxycarbonitride of the present invention includes a grinding step for grinding the oxycarbonitride using a ball mill, wherein the metal-containing oxycarbonitride is represented by a specific compositional formula; balls in the ball mill have a diameter of 0.1 to 1.0 mm; the grinding time using the ball mill is 1 to 45 minutes; the rotating centrifugal acceleration in grinding using the ball mill is 2 to 20 G; the grinding using the ball mill is carried out in such a state that the metal-containing oxycarbonitride is mixed with a solvent containing no oxygen atom in the molecule; and when the ball mill is a planetary ball mill, the orbital centrifugal acceleration mill is 5 to 50 G.Type: GrantFiled: July 14, 2010Date of Patent: March 26, 2013Assignee: Showa Denko K.K.Inventors: Yasuaki Wakizaka, Ryuji Monden, Toshikazu Shishikura, Takuya Imai, Kenichiro Ota
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Patent number: 8404391Abstract: A polymer electrolyte fuel cell includes a cathode, an anode, and an electrolyte membrane sandwiched between the cathode and the anode. A plurality of projections each having a height of 5 to 15 ?m or a plurality of depressions each having a depth of 5 to 15 ?m are formed on a surface of the electrolyte membrane, the surface being opposed to the cathode. The cathode is constituted by a catalyst layer formed to tightly contact the surface of the electrolyte membrane and having a maximum thickness that is one to three times the height of the projection or the depth of the depression. An oxygen-containing gas having a relative humidity of 10% or less is supplied to the cathode, and electric power is generated by using the polymer electrolyte fuel cell.Type: GrantFiled: January 26, 2012Date of Patent: March 26, 2013Assignee: Panasonic CorporationInventors: Hisaaki Gyoten, Masato Aizawa, Akira Taomoto
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Patent number: 8399146Abstract: A free-standing membrane electrolyte electrode assembly (ESC) comprises an electrolyte, an anode electrode formed at one end face of the electrolyte, and a cathode electrode formed at the other. The electrolyte is a single crystal having a surface along with oxide ions move or a direction in which the ions move or a polycrystal oriented along a surface along which oxide ions move or in a direction in which the ions move. The surface or the direction is parallel to the thickness direction. The thickness of the electrolyte is 50 to 800 ?m and the quotient of the division of the total thickness of the anode electrode and the cathode electrode by the thickness of the electrolyte is 0.1 or less,. The thickness of the ESC is 1 mm or less.Type: GrantFiled: November 27, 2008Date of Patent: March 19, 2013Assignee: Honda Motor Co., Ltd.Inventors: Yoshikatsu Higuchi, Yuji Saito, Teruaki Komiya, Ushio Harada
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Patent number: 8399145Abstract: A membrane electrode assembly having a peripheral edge region and a central region. The membrane electrode assembly comprises an ion-conducting membrane, first and second electrocatalyst layers disposed either side of the ion-conducting membrane, and first and second gas diffusion layers disposed either side of the first and second electrocatalyst layers respectively. The membrane electrode assembly further comprises an edge protection member, the edge protection member comprising a film layer, a bonding layer, and one or more additives selected from the group consisting of free radical decomposition catalyst, self regenerating antioxidant, hydrogen donors (H-donor) primary antioxidant, free radical scavenger secondary antioxidant, oxygen absorbers (oxygen scavenger) and elemental palladium.Type: GrantFiled: September 18, 2008Date of Patent: March 19, 2013Assignee: Johnson Matthey Fuel Cells LimitedInventors: David Edward Barnwell, Thomas Robertson Ralph, Peter Anthony Trew
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Patent number: 8399144Abstract: A membrane-electrode assembly for a direct oxidation fuel cell includes an electrolyte membrane, and an anode and a cathode sandwiching said electrolyte membrane. The cathode includes a catalyst layer in contact with the electrolyte membrane and a diffusion layer formed on the catalyst layer, and the catalyst layer contains 2 to 20% by volume of pores. A direct oxidation fuel cell including this membrane-electrode assembly has excellent power generating performance and durability.Type: GrantFiled: December 16, 2008Date of Patent: March 19, 2013Assignee: Panasonic CorporationInventors: Hideyuki Ueda, Hiroaki Matsuda, Takashi Akiyama
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Patent number: 8399151Abstract: An oxygen-containing gas flow field is formed on a surface of a cathode side metal separator of a fuel cell. The oxygen-containing gas flow field is connected between an oxygen-containing gas supply passage and an oxygen-containing gas discharge passage. A coolant flow field is formed on the other surface of the cathode side metal separator, on the back of the oxygen-containing gas flow field. The cathode side metal separator has linear guide ridges protruding from an intermediate height area toward the oxygen-containing gas flow field to form a continuous guide flow field, and bosses protruding from the intermediate height area toward the coolant flow field to form an embossed flow field.Type: GrantFiled: June 4, 2010Date of Patent: March 19, 2013Assignee: Honda Motor Co., Ltd.Inventors: Seiji Sugiura, Yasuhiro Watanabe, Takahiro Takai, Shuji Sato
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Patent number: 8399153Abstract: In a method for the production of a membrane electrode assembly comprising a membrane, electrodes and a catalyst, the catalyst is pressed into the membrane material, e.g. when forming the material in situ.Type: GrantFiled: June 16, 2005Date of Patent: March 19, 2013Assignee: ITM Power (Research) LimitedInventors: Donald James Highgate, Jonathan Anthony Lloyd, Simon Bourne, Rachel Louise Smith
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Patent number: 8399149Abstract: A composition showing enhanced proton conductivity comprising at least a polymer with an ionizable group (A) containing a proton and carbon nanostructures functionalized with ionizable group (B) containing a proton is disclosed where A and B are same or different.Type: GrantFiled: February 12, 2009Date of Patent: March 19, 2013Assignee: Council of Scientific and Industrial ResearchInventors: Vijayamohanan Pillai, Bhalchandra A. Kakade, R. Kannan
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Patent number: 8394551Abstract: The invention relates to a membrane-electrode assembly (MEA) for electrochemical devices, in particular for membrane fuel cells. The membrane-electrode assembly has a semi-coextensive design and comprises an ion-conducting membrane, two catalyst layers and gas diffusion layers of differing sizes on the front side and rear side. The first gas diffusion layer has smaller planar dimensions than the ion-conducting membrane, while the second gas diffusion layer has essentially the same planar dimensions as the ion-conducting membrane. As a result, the ion-conducting membrane has a surface which is not supported by a gas diffusion layer on the front side. The membrane-electrode assembly has, owing to the particular construction, a stable structure which can be handled readily and displays advantages in the sealing of the reactive gases from one another and also in terms of the electrical properties. In particular, the hydrogen penetration current is significantly reduced.Type: GrantFiled: July 14, 2004Date of Patent: March 12, 2013Assignee: Umicore AG & Co. KGInventors: Ralf Zuber, Sandra Wittpahl, Klaus Schaack, Holger Dziallas, Peter Seipel, Günther Vulpius, Bernd Dillmann
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Publication number: 20130059228Abstract: A flow field plate comprises a first flow field; an opposing second flow field; and at least one flow channel formed in the first flow field, the at least one flow channel comprising: a first side and an opposing second side separated by an open-faced top and a bottom; and a first side channel formed in a portion of the open-faced top and in a portion of the first side along a continuous length of the at least one flow channel, the first side channel comprising a first side wall and a first bottom wall; wherein the first side wall of the first side channel and the first bottom wall of the first side channel form an obtuse angle in cross-section; and a depth of the bottom of the at least one flow channel is greater than a depth of the bottom wall of the first side channel.Type: ApplicationFiled: March 7, 2011Publication date: March 7, 2013Applicant: Ballard Power Systems Inc.Inventors: Jeffrey Dean Glandt, Bevan Hoskyn Moss, Daniel Brent Mackay
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Patent number: 8389639Abstract: A proton exchange membrane comprising modified hyper-branched polymer is disclosed. The proton exchange membrane includes 85-90 wt % of sulfonated tetrafluorethylene copolymer and 15-10 wt % of modified hyper-branched polymer. The modified hyper-branched polymer comprises the bismaleimide (BMI)-based hyper-branched polymer, and parts of the chain ends of the hyper-branched polymer are sulfonated by the sulfonic compound. Also, the modified hyper-branched polymer and sulfonated tetrafluorethylene copolymer are interpenetrated to form an interpenetrating polymer. Furthermore, the modification step could be performed before or after forming the interpenetrating polymer. For example, the sulfonation is proceeded after forming the interpenetrating polymer. Alternatively, the sulfonation of the hyper-branched polymer could be proceeded before the formation of the interpenetrating polymer.Type: GrantFiled: November 23, 2009Date of Patent: March 5, 2013Assignee: Industrial Technology Research InstituteInventors: Chung-Liang Chang, Ya-Ting Hsu, Jing-Pin Pan
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Patent number: 8389177Abstract: A combined subgasket and membrane support for a fuel cell is provided. The combined subgasket and membrane support includes a substantially fluid impermeable feed region circumscribing a porous membrane support region. The membrane support region is integrally formed with the feed region. At least one of the membrane support region and the feed region is at least partially formed by a radiation-cured structure. A method for fabricating the subgasket and membrane support for the fuel cell is also provided.Type: GrantFiled: December 22, 2008Date of Patent: March 5, 2013Assignee: GM Global Technology OperationsInventors: Gerald W. Fly, Yeh-Hung Lai, Jeffrey A. Rock, Keith E. Newman, Ping Liu, Alan J. Jacobsen, William B. Carter, Peter D. Brewer
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Publication number: 20130052561Abstract: To provide a polymer electrolyte membrane and a membrane/electrode assembly for a polymer electrolyte fuel cell, excellent in the durability to hydrogen peroxide or peroxide radicals. A polymer electrolyte membrane 15 comprising an ion exchange resin having cation exchange groups, which contains cerium element and at least one member selected from cesium element and rubidium element; and a membrane/electrode assembly 10, comprising an anode 13 having a catalyst layer 11 containing a catalyst and an ion exchange resin, a cathode 14 having a catalyst layer 11 containing a catalyst and an ion exchange resin, and a polymer electrolyte membrane 15 disposed between the anode 13 and the cathode 14, wherein the polymer electrolyte membrane 15 contains cerium element and at least one member selected from cesium element and rubidium element.Type: ApplicationFiled: August 2, 2012Publication date: February 28, 2013Applicant: Asahi Glass Company, LimitedInventors: Satoru HOMMURA, Junichi Tayanagi, Tetsuji Shimohira
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Patent number: 8383286Abstract: A metal oxide thin film structure for a solid oxide fuel cell, prepared by a method comprising dispersing a metal oxide nanopowder in a metal oxide salt solution and subsequent coating of the resulting metal oxide powder dispersed sol and the metal oxide salt solution on a porous substrate, has excellent gas impermeability, excellent phase stability, and is devoid of cracks or pinholes.Type: GrantFiled: August 11, 2009Date of Patent: February 26, 2013Assignee: Korea Institute of Science and TechnologyInventors: Hae-Weon Lee, Jong Ho Lee, Eun Oak Oh, Ji-Won Son, Hae-Ryoung Kim, Hyoungchul Kim, Kyung-ryul Lee
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Patent number: 8367266Abstract: A porous catalyst layer formed from discrete particles of unsupported metal, wherein at least 80%, suitably at least 90%, of the discrete particles have a mass of from 1 to 1000 zeptograms, and wherein the catalyst layer has a metal volume fraction of less than 30% and a metal loading of less than 0.09 mg/cm2 is disclosed. The catalyst layer is suitable for use in fuel cells and other electrochemical applications.Type: GrantFiled: June 19, 2008Date of Patent: February 5, 2013Assignee: Johnson Matthey Fuel Cells LimitedInventors: Ian Roy Harkness, Jonathan David Brereton Sharman, Edward Anthony Wright
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Patent number: 8367265Abstract: A solid oxide fuel cell includes an anode layer, an electrolyte layer over the anode layer, and a cathode layer over the electrolyte layer. At least one of the anode layer and the cathode layer defines a gas manifold. The gas manifold includes a gas inlet, defined by an edge of the anode layer or cathode layer, a gas outlet, defined by the same or a different edge of the anode layer or cathode layer, and a plurality of gas flow channels in fluid communication with the gas inlet and gas outlet. The gas flow channels can have diameters that conduct flow of gas from the gas inlet at substantially equal flow rates among the gas flow channels.Type: GrantFiled: December 15, 2009Date of Patent: February 5, 2013Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventors: James A. Salvatore, Vignesh Rajamani, Abhijit Dutta
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Patent number: 8367271Abstract: A fuel cell device includes a housing containing a fuel processor that generates fuel gas and a fuel cell having electrodes forming an anode and cathode, and an ion exchange electrolyte positioned between the electrodes. The housing can be formed as first and second cylindrically configured outer shell sections that form a battery cell that is configured similar to a commercially available battery cell. A thermal-capillary pump can be operative with the electrodes and an ion exchange electrolyte, and operatively connected to the fuel processor. The electrodes are configured such that heat generated between the electrodes forces water to any cooler edges of the electrodes and is pumped by capillary action back to the fuel processor to supply water for producing hydrogen gas. The electrodes can be formed on a silicon substrate that includes a flow divider with at least one fuel gas input channel that can be controlled by a MEMS valve.Type: GrantFiled: March 31, 2009Date of Patent: February 5, 2013Assignee: STMicroelectronics, Inc.Inventor: Anthony M. Chiu
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Publication number: 20130029248Abstract: A fuel cell including a single fuel cell which includes a membrane electrode including a polymer electrolyte membrane, an anode electrode on one surface of the polymer electrolyte membrane, and a cathode electrode on another surface of the polymer electrolyte membrane, the anode electrode including an anode catalyst layer and a gas diffusion layer and the cathode electrode including a cathode catalyst layer and a gas diffusion layer. At least one of the anode cathode catalyst layers includes core-shell type catalyst particles, each having a core and a shell covering the core and including a shell metallic material. At least one of the polymer electrolyte membrane, anode catalyst layer, gas diffusion layer at the anode side, cathode catalyst layer and gas diffusion layer at the cathode side includes metallic nanoparticles having an average particle diameter different from that of the core-shell type catalyst particles and including the shell metallic material.Type: ApplicationFiled: April 7, 2010Publication date: January 31, 2013Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Tatsuya Arai, Naoki Takehiro, Atsuo Iio, Koshi Sekizawa, Hiroko Kimura
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Patent number: 8361674Abstract: The invention relates to the field of electrochemical cells and fuel cells, more specifically to polymer-electrolyte-membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC). A multi-layer membrane-electrode-assembly (ML-MEA) comprising two electrically conductive bipolar plates and a membrane-electrode-assembly (MEA) bonded together by means of an electrically insulating adhesive material is disclosed. The adhesive material, preferably a polyurethane-based system, is in direct contact with the protective film layers attached to front side and the back side of the MEA, thus contamination of the ionomer membrane and/or the electrode layers with adhesive components is avoided. Multi-layer MEAs with improved long term stability and life time are obtained. The products are used for the manufacture of low temperature PEMFC and DMFC stacks.Type: GrantFiled: April 12, 2005Date of Patent: January 29, 2013Assignee: Umicore AG & Co. KGInventors: Ralf Zuber, Knut Fehl, Peter Seipel, Sven Bornbaum
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Patent number: 8361670Abstract: The invention relates to a fuel cell, having a first electrode, a second electrode, and a membrane element, in which the membrane element is disposed between the first electrode and the second electrode. At least one of the electrodes has a flow field plate and at least one flow conduit, through which a reactant can be conducted, extends in at least one outer surface of the flow field plate. According to the invention, it is provided that the flow field plate has at least one microreaction chamber, and the microreaction chamber is disposed in the outer surface and on the flow conduit. A catalyst is disposed on at least a part of the microreaction chamber in such a way that the catalyst has contact simultaneously with the membrane element and the inflowing reactant.Type: GrantFiled: December 18, 2008Date of Patent: January 29, 2013Assignee: Robert Bosch GmbHInventors: Norman Krings, Juergen Hackenberg, Alexander Reitzle
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Patent number: 8354200Abstract: A method of adjusting a fuel distribution includes: adjusting a distribution of a fuel supply amount to a membrane electrode assembly so that a temperature distribution in the membrane electrode assembly becomes substantially uniform by a membrane provided in a fuel supply side of the membrane electrode assembly of a fuel cell. A membrane adjusts a fuel distribution, which is provided in a fuel supply side of a membrane electrode assembly of a fuel cell. The membrane is provided with openings so that a temperature distribution in the membrane electrode assembly becomes substantially uniform.Type: GrantFiled: September 21, 2007Date of Patent: January 15, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Takahiro Terada, Yasutada Nakagawa, Yuji Sasaki, Yuichi Yoshida
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Patent number: 8354137Abstract: The present invention provides a method for manufacturing an electrode catalyst layer for a fuel cell which includes a polymer electrolyte, a catalyst material and carbon particles, wherein the electrode catalyst layer employs a non-precious metal catalyst and has a high level of power generation performance. The electrode catalyst layer is used as a pair of electrode catalyst layers in a fuel cell in which a polymer electrolyte membrane is interposed between the pair of the electrode catalyst layers which are further interposed between a pair of gas diffusion layers. The method of the present invention has such a feature that the catalyst material or the carbon particles are preliminarily embedded in the polymer electrolyte.Type: GrantFiled: September 8, 2011Date of Patent: January 15, 2013Assignee: Toppan Printing Co., Ltd.Inventors: Hiroyuki Morioka, Haruna Kurata, Saori Okada, Kenichiro Oota
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Patent number: 8354011Abstract: An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A?yBO(3-?), wherein 0<x<1, 0?y?0.5, and 0.8?z?1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.Type: GrantFiled: November 19, 2010Date of Patent: January 15, 2013Assignee: Ceramatec, Inc.Inventors: S. Elangovan, Joseph J. Hartvigsen, Feng Zhao
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Patent number: 8349521Abstract: A membrane electrode assembly includes a fuel electrode, an oxidizing agent electrode, and an electrolyte membrane provided between the fuel electrode and the oxidizing agent electrode with at least one of the fuel electrode and the oxidizing agent electrode contains a proton conductive inorganic oxide, which includes an oxide carrier containing Ti, Zr, Si and/or Al; and W, Mo, Cr and/or V oxide particles supported on a surface of the oxide carrier.Type: GrantFiled: July 20, 2005Date of Patent: January 8, 2013Assignee: Kabushiki Kaisha ToshibaInventors: Jun Tamura, Yoshihiko Nakano, Hideo Oota
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Patent number: 8349512Abstract: Disclosed is a multi-MEA test station capable of simultaneously testing and activating a plurality of MEAs and a multi-MEA test method using the same. The multi-MEA test station includes a chamber capable of receiving a plurality of MEAs; a first multi cell body including a first channel for supplying an oxidant to a cathode electrode of the MEA, and a second multi cell body including a second channel for supplying fuel to an anode electrode of the MEA; a pressing means closely adhering the first multi cell body, the second multi cell body and the MEA positioned therebetween by applying force in a direction that the first multi cell body and the second multi cell body are opposed to each other; a reactant supply means for supplying the oxidant to the first channel and supplying the fuel to the second channel; and a multi-loader controlling the environment of a test and activation on the plurality of MEAs and performing the test and the activation.Type: GrantFiled: January 15, 2008Date of Patent: January 8, 2013Assignee: Samsung SDI Co., Ltd.Inventor: Chan Gyun Shin
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Patent number: 8349994Abstract: Disclosed is an electrode electrolyte for solid polymer fuel cells, which uses a polymer electrolyte containing a polyarylene copolymer containing a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —(O(CH2)hSO3H or —O(CF2)hSO3H (wherein h represents an integer of 1-12). By having such a constitution, the electrode electrolyte for solid polymer fuel cells can be produced at a low cost, while being excellent in proton conductivity, dimensional stability, hydrothermal resistance and mechanical strength. In addition, this electrode electrolyte for solid polymer fuel cells enables to recover a catalyst metal.Type: GrantFiled: May 16, 2008Date of Patent: January 8, 2013Assignees: JSR Corporation, Honda Motor Co., Ltd.Inventors: Toshiaki Kadota, Yoshitaka Yamakawa, Fusao Nakagawa, Nagayuki Kanaoka, Takaki Nakagawa
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Patent number: 8349513Abstract: A polymer electrolyte membrane comprising as a main ingredient a block copolymer which comprises, as its constituents, a polymer block (A) having as a main unit an aromatic vinyl compound unit and a polymer block (B) forming a flexible phase, and has ion-conducting groups on the polymer block (A), said aromatic vinyl compound unit being such that the hydrogen atom bonded to the ?-carbon atom is non-replaced or replaced with an alkyl group or an aryl group optionally having substituent(s), and at least one of hydrogen atoms directly bonded to the aromatic ring is replaced with an alkyl group; and a membrane electrode assembly and a polymer electrolyte fuel cell both of which uses it. The polymer block (A) can have a restraining phase, and/or can be cross-linked.Type: GrantFiled: February 5, 2007Date of Patent: January 8, 2013Assignee: Kuraray Co., Ltd.Inventors: Tomohiro Ono, Shinji Nakai, Hiroyuki Ogi, Takeshi Nakano
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Patent number: 8343321Abstract: The invention relates to membrane-electrode assemblies for the electrolysis of water (electrolysis MEAs), which contain an ion-conducting membrane having a front and rear side; a first catalyst layer on the front side; a first gas diffusion layer on the front side; a second catalyst layer on the rear side, and a second gas diffusion layer on the rear side. The first gas diffusion layer has smaller planar dimensions than the ion-conducting membrane, whereas the second gas diffusion layer has essentially the same planar dimensions as the ion-conducting membrane (“semi-coextensive design”). The MEAs also comprise an unsupported free membrane surface that yields improved adhesion properties of the sealing material. The invention also relates to a method for producing the MEA products. Pressure-resistant, gastight and cost-effective membrane-electrode assemblies are obtained, that are used in PEM water electrolyzers, regenerative fuel cells or in other electrochemical devices.Type: GrantFiled: July 13, 2011Date of Patent: January 1, 2013Assignee: Umicore AG & Co. KGInventors: Ralf Zuber, Klaus Schaack, Sandra Wittpahl, Holger Dziallas, Peter Seipel, Pia Braun, Lutz Rohland
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Patent number: 8343683Abstract: A fuel cell stack including a plurality of fuel cells each formed by stacking separators and an electrolyte membrane-electrode assembly. The electrolyte membrane-electrode assembly includes an electrolyte membrane provided with a pair of electrodes on the opposite sides thereof. A stacked body formed by stacking the fuel cells is provided with a pair of end plates at the opposite ends thereof in a stacking direction. The end plates are integrally fixed by fastening members with the distance between the end plates maintained. A load measurement mechanism including a plurality of load sensors integrally connected to a connector member is provided between one of the end plates and the stacked body. The one of the end plates is provided with a pressure mechanism. The pressure mechanism presses the load measurement mechanism toward the stacked body to thereby apply a tightening load to the stacked body via the load sensors.Type: GrantFiled: November 12, 2010Date of Patent: January 1, 2013Assignee: Honda Motor Co., Ltd.Inventors: Go Morimoto, Tadashi Nishiyama, Hiroyuki Tanaka
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Patent number: 8343672Abstract: A catalyst coated electrolyte membrane including an anode catalyst layer and a cathode catalyst layer at opposite sides thereof, respectively, wherein micro cracks of the anode catalyst layer or cathode catalyst layer occupy 0.01-1 area % of the total area of the respective anode catalyst layer or cathode catalyst layer, a fuel cell including the same, and a method of preparing the catalyst coated electrolyte membrane. In the catalyst coated electrolyte membrane, micro cracks of the cathode catalyst layer or the anode catalyst layer can be minimized and thus the resistance between the electrode catalyst layer and an electrolyte membrane can be minimized, and crossover of a fuel, such as methanol, ethanol, other alcohols, methane, etc., to a cathode electrode can be minimized, and thus the catalyst coated electrolyte membrane has improved performance and durability.Type: GrantFiled: June 1, 2006Date of Patent: January 1, 2013Assignee: Samsung SDI Co., Ltd.Inventors: Ji-rae Kim, Seung-jae Lee, Hyuk Chang
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Patent number: 8343681Abstract: Bipolar plates and a fuel cell stack having the bipolar plates. The fuel cell stack includes membrane electrode assemblies (MEAs), and first and second bipolar plates sequentially stacked between the MEAs. The bipolar plates include: flow channels formed on opposing surfaces thereof; four manifolds connected to the flow channels; and through holes to connect to the manifolds of the bipolar plates adjacent thereto.Type: GrantFiled: July 21, 2008Date of Patent: January 1, 2013Assignee: Samsung Electronics Co., Ltd.Inventors: Jie Peng, Jae-young Shin, Seung-jae Lee, Tae-won Song
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Patent number: 8338054Abstract: There are provided: a proton transporting material that improves mechanical characteristics of a sulfonated liquid crystalline polymer material, can be kept as a membrane even though it is made a solid state while maintaining a molecular arrangement of a liquid crystalline state, and is suitable for electrolyte membranes of fuel cells etc.; an ion exchange membrane, a membrane electrolyte assembly (MEA), and a fuel cell that use the proton transporting material; a starting material for the proton transporting material. The proton transporting material has a molecular structure produced by crosslinking the sulfonated liquid crystalline polymer material with a crosslinking agent having two or more functional groups in sites except that of the sulfonic acid group.Type: GrantFiled: March 3, 2009Date of Patent: December 25, 2012Assignees: University of Yamanashi, Toppan Printing Co., Ltd.Inventors: Yuichiro Haramoto, Kohei Shiramizu, Masashi Oota