By Milling, Grinding, Crushing, Or Comminuting Patents (Class 430/137.18)
  • Patent number: 11860618
    Abstract: The embodiments are and include at least an apparatus, system and method for forming print material particles for additive manufacturing (AM) printing. The apparatus, system and method include at least a melt chamber comprising a polymer melt; a vertical extruder that fluidically receives the polymer melt; an atomizer that atomizes the polymer melt from the vertical extruder and that distributes the atomized polymer melt; a fall chamber comprising a plurality of zones into which the atomized polymer melt is distributed; and a collector to receive the print material particles formed of the atomized polymer melt after falling through the plurality of zones.
    Type: Grant
    Filed: July 21, 2022
    Date of Patent: January 2, 2024
    Assignee: JABIL INC.
    Inventors: Nicholas J. Dippel, Thomas Gardner, Daryn York
  • Patent number: 10669383
    Abstract: Spheroid polymer particles are prepared from non-spheroid particles by heating the non-spheroid particles in a liquid medium to a temperature that is above the glass transition temperature or the melting temperature of the polymer and then cooling.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: June 2, 2020
    Assignee: Evonik Corporation
    Inventors: Jason N. Campbell, Bruce W. Hudson
  • Patent number: 9529294
    Abstract: In accordance with various embodiments of the invention, a method of forming an ultraviolet security toner for use in printing hardware originally designed to use chemically prepared toner includes melt-blending binder resin particles and optionally a charge-control agent, a colorant and a releasing agent. The fluorescent pigment is then admixed to the melt-blended particles to form a fluorescent pre-toner. A first inorganic material is then blended with the fluorescent pre-toner, coating the particles of the fluorescent pre-toner with the first inorganic material. A second inorganic material is then blended with the coated pre-toner, adding another layer of coating to the fluorescent pre-toner. The first inorganic material has an average particle diameter size that is less than the average particle diameter size of the fluorescent pigment particles and the second inorganic material has an average particle diameter size less than that of the first inorganic material.
    Type: Grant
    Filed: September 17, 2015
    Date of Patent: December 27, 2016
    Assignee: TROY GROUP, INC.
    Inventors: Kevin L. Heilman, Michael R. Riley
  • Patent number: 9304418
    Abstract: A system for pigment milling includes a pulsing direct current (DC) source that generates a DC pulse, an electromagnetic field generating subunit that includes an electromagnetic coil coupled to the pulsing DC source to receive the DC pulse and to generate a magnetic field, and a rotating container subunit that includes a container for holding magnetic particles and ink pigment particles in an ink carrier, and a rotating subunit to rotate the container. A portion of the container is disposed within the electromagnetic coil and generation of the magnetic field causing motion of the magnetic particles thereby dispersing the ink pigment particles within the ink carrier.
    Type: Grant
    Filed: July 24, 2014
    Date of Patent: April 5, 2016
    Assignee: XEROX CORPORATION
    Inventors: Harry P. Latchman, Ke Zhou, Frank Ping-Hay Lee
  • Publication number: 20150111144
    Abstract: Composite materials such as composite particles have a solid non-elastomeric continuous phase made of an organic polymer having a glass transition temperature of at least 25° C. Dispersed within this solid non-elastomeric continuous phase are many multi-compartment porous chemically crosslinked elastomeric particles that have a mode particle size of at least 1 ?m and up to and including 10 ?m. The composite particles can be used as toner particles in electrophotographic imaging methods to provide fused toner images and especially stacked fused toner images.
    Type: Application
    Filed: October 18, 2013
    Publication date: April 23, 2015
    Inventors: Mridula Nair, Joseph Salvatore Sedita, Peter David Rollinson
  • Publication number: 20150111143
    Abstract: A method for producing a positively chargeable toner, including: step 1: melt-kneading a toner raw material composition containing a resin binder, a positively chargeable charge control agent, and fine fluororesin particles, and a recycled powder; step 2: cooling a melt-kneaded mixture obtained in the step 1, and pulverizing a cooled mixture; and step 3: classifying a pulverized product obtained in the step 2, wherein the resin binder in the toner raw material composition contains 50% by mass or more of a polyester having a softening point of 125° C. or higher and 170° C. or lower. The positively chargeable toner obtainable by the method of the present invention is suitably used in developing latent images formed in, for example, an electrophotographic method, an electrostatic recording method, an electrostatic printing method, or the like.
    Type: Application
    Filed: October 6, 2014
    Publication date: April 23, 2015
    Applicant: Kao Corporation
    Inventors: Kohei KATAYAMA, Masahito YAMAZAKI
  • Publication number: 20150044607
    Abstract: A method for manufacturing carrier core particles for electrophotographic developer that include manganese, magnesium, and iron as a core composition. The method includes a granulation step (A) of granulating a mixture of raw materials containing manganese, magnesium, and iron with a reducing agent added at a ratio of 0.10% to 1.00% by mass to a total mass of the raw materials containing manganese, magnesium, and iron, and a firing step of firing the granular material granulated in the granulation step. The firing step includes a first heating step (C) of applying heat at a constant temperature ranging from 500° C. to 800° C. in an atmosphere with an oxygen concentration of 1000 ppm to 15000 ppm for a predetermined period of time and a second heating step (D) of applying heat at a temperature higher than 800° C. for a predetermined period of time after the first heating step.
    Type: Application
    Filed: November 30, 2012
    Publication date: February 12, 2015
    Inventor: Takeshi Kawauchi
  • Patent number: 8940467
    Abstract: A toner is provided that, even in a small amount thereof, gives a satisfactory image density and that is free of image problems, e.g., fogging and offset resistance, even during long-term use and in a high-temperature, high-humidity environment. The toner contains a binder resin, a pigment, and a prescribed azo compound wherein, designating as (A) the solubility of the azo compound in a toluene-hexane solubility test and as (B) the solubility of the binder resin constituting the toner in the toluene-hexane solubility test, the (A) and the (B) satisfy the relationship |(B)?(A)|?60.
    Type: Grant
    Filed: February 26, 2013
    Date of Patent: January 27, 2015
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Hashimoto, Takayuki Toyoda, Masashi Kawamura, Naotaka Ikeda, Hidekazu Fumita, Emi Watanabe, Yuhei Terui
  • Patent number: 8927186
    Abstract: A toner for use in developing an electrostatic latent image is provided. The toner includes a colored particulate material including at least a binder resin and a colorant; and an external additive present on a surface of the colored particulate material and including a particulate crystalline hydroxyapatite. The particulate crystalline hydroxyapatite has an average aspect ratio of not less than 3 and less than 30.
    Type: Grant
    Filed: November 23, 2010
    Date of Patent: January 6, 2015
    Assignee: Ricoh Company, Limited
    Inventors: Masayuki Ishii, Toyoshi Sawada
  • Publication number: 20140363208
    Abstract: The present invention relates to a liquid electrophotographic ink comprising a carrier liquid, a pigmented resin composite dispersed in the carrier liquid, and about 0.15 to about 10% (w/w) of an organic wax. The liquid electrophotographic ink is typically formulated for printing in a liquid electrophotographic printer.
    Type: Application
    Filed: December 19, 2011
    Publication date: December 11, 2014
    Applicant: Hewlett-Packard Indigo B.V.
    Inventors: Stella Stolin Roditi, Haim Cohen, Getahun Biadglin, Femanda Orilik, Nava Klein, Albert Teishev
  • Publication number: 20140349232
    Abstract: A method for producing a toner that comprises toner particles, each of which comprises a binder resin, which comprises a resin (A) capable of forming a crystalline structure, and a colorant, the method including: a pressure holding step of, after preparing toner particles, holding the toner particles for 5 minutes or more at a pressure of 2.0 MPa or more under conditions of a temperature T1 (° C.) represented by formula (1): 20?T1?Tp2??(1) (wherein, Tp2 represents the onset temperature of the maximum endothermic peak derived from the resin (A)), wherein a peak temperature Tp1 of the maximum endothermic peak derived from the resin (A) during the first temperature rise of the toner particles as determined by differential scanning calorimetric measurement is 50° C. to 90° C.
    Type: Application
    Filed: May 21, 2014
    Publication date: November 27, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Tetsuya Kinumatsu, Shuntaro Watanabe, Kenji Aoki, Atsushi Tani, Yoshihiro Nakagawa, Takaaki Kaya, Toshifumi Mori, Yusuke Kosaki, Takashige Kasuya
  • Patent number: 8895220
    Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.
    Type: Grant
    Filed: August 29, 2013
    Date of Patent: November 25, 2014
    Assignee: Lexmark International, Inc.
    Inventors: Michael James Bensing, Craig Michael Bartelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
  • Publication number: 20140342279
    Abstract: A method for making polymer-encapsulated metallic ink particles is disclosed herein. An ethylene-based polymeric resin powder is formed, and is mixed with a metallic pigment powder to form a powder mixture. The powder mixture is melted to form a metallic polymer melt. A non-polar carrier is added to the metallic polymer melt to form a slurry. The slurry is processed in a microfluidizer.
    Type: Application
    Filed: January 5, 2012
    Publication date: November 20, 2014
    Inventors: Doris Chun, Hou T. Ng, Albert Teishev
  • Patent number: 8877420
    Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to plasticize the pressure plastic material; applying a shear force to the compressive fluid and the plasticized pressure plastic material, between which an interface exists, in the presence of a surfactant to granulate the pressure plastic material in the compressive fluid, so as to produce particles.
    Type: Grant
    Filed: March 9, 2011
    Date of Patent: November 4, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Chiaki Tanaka, Ryota Inoue, Taichi Nemoto, Yoshitaka Yamauchi
  • Publication number: 20140314449
    Abstract: The present disclosure provides for a liquid electrophotographic (LEP) ink comprising a carrier fluid, a pigment, a high melt viscosity ethylene acrylic acid copolymer resin, and a high acid ethylene acrylic acid copolymer resin. The high acid ethylene acrylic acid copolymer resin can have an acid content of at least 15 wt % and a viscosity of at least 8,000 poise. Additionally, the LEP ink can have a total resin acidity of at least 15 wt % and a total resin melt viscosity of at least 20,000 poise.
    Type: Application
    Filed: January 31, 2011
    Publication date: October 23, 2014
    Applicant: Hewlett-Packard Development Company, L.P.
    Inventors: Stella Stolin Roditi, Haim Cohen, Neta Filip-Granit, Roi Liraz, Eyal Bodinger, Marc Klein, Nava Klein, Eyal Bachar, Swissa Shay, Albert Teishev, Yaron Grinwald, Fernanda Orlik, Ilanit Mor
  • Patent number: 8852841
    Abstract: A method for producing a toner for electrostatic image development containing at least a resin binder and a charge control agent, including step 1: melt-kneading components containing a resin binder and a charge control agent to provide a melt-kneaded product; and step 2: pulverizing the melt-kneaded product, and classifying a pulverized product, wherein the resin binder contains a polyester A obtained by polycondensing an alcohol component containing 1,2-propanediol and a carboxylic acid component containing a rosin compound and an aliphatic dicarboxylic acid compound having 6 to 10 carbon atoms, wherein 1,2-propanediol is contained in the alcohol component of the polyester A in an amount of 85% by mol or more. The toner for electrostatic image development obtained by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: October 7, 2014
    Assignee: Kao Corporation
    Inventors: Takeshi Ashizawa, Shogo Watanabe, Takashi Kubo, Norihiro Hirai
  • Patent number: 8846289
    Abstract: A method of manufacturing toner including melting, mixing, and kneading a releasing agent and a coloring agent with at least part of a polyester binder resin, and suspending and granulating an oil phase comprising the binder resin, the coloring agent, and the releasing agent in an aqueous medium.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: September 30, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Satoshi Ogawa, Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Masana Shiba, Junichi Awamura
  • Publication number: 20140287357
    Abstract: The present disclosure provides for compositions, methods, and systems directed towards a liquid electrophotographic ink comprising a carrier fluid, a pigment, a first resin, and a stable cross-linkable resin that is solvated or swellable with the carrier fluid, where the stable cross-linkable resin does not undergo cross-linking until a temperature of at least 110° C. and, once cross-linked, does not melt until a temperature of at least 300° C.
    Type: Application
    Filed: October 25, 2011
    Publication date: September 25, 2014
    Inventors: Doris Chun, Hou T. Ng, Albert Teishev
  • Patent number: 8828285
    Abstract: A particulate production apparatus, including a droplet discharger to discharge a liquid including a particulate element which is solidified to become a particulate; and a pressure controller to feed the liquid including a particulate element to the droplet discharger at a pressure within a desired range.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: September 9, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Kiyotada Katoh, Minoru Masuda, Yasutada Shitara, Yoshihiro Norikane, Satoshi Takahashi
  • Patent number: 8815488
    Abstract: A method for producing a toner including the step of melt-kneading a mixture containing a resin binder and a wax with a twin-screw kneader, wherein the resin binder contains three kinds of a resin R1, a resin R2 and a resin R3 having different softening points to each other, wherein the wax contains at least two kinds of a wax W2 and a wax W3 having different melting points to each other, wherein the softening points of R1, R2 and R3 and the melting point W2 meet certain relationships, and wherein the mixture is supplied to the twin-screw kneader in an amount of from 1.3 to 5.0 kg/hr·cm2 per unit cross-sectional area of the screw. The toner obtainable by the method of the present invention can be suitably used in, for example, the development or the like of latent image formed in electrophotography, an electrostatic recording method, an electrostatic printing method, or the like.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: August 26, 2014
    Assignee: Kao Corporation
    Inventor: Takeshi Ashizawa
  • Patent number: 8765343
    Abstract: An electrostatic latent image developing toner contains a binder resin, a colorant, europium, and bismuth.
    Type: Grant
    Filed: February 8, 2012
    Date of Patent: July 1, 2014
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yuki Takamiya, Eisuke Iwazaki, Satoshi Yoshida, Satoshi Inoue
  • Publication number: 20140134531
    Abstract: A yellow toner is provided which is much more improved in color development and chroma, and much more improved in light resistance. The yellow toner contains, at least, a binder resin, a wax, and a coloring agent. The coloring agent is a compound represented by the following general formula (1).
    Type: Application
    Filed: January 23, 2014
    Publication date: May 15, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Shosei Mori, Takeshi Sekiguchi, Taichi Shintou, Takeshi Miyazaki
  • Patent number: 8703378
    Abstract: A method of manufacturing toner including mixing mother toner particles containing a binder resin and a coloring agent and first particles having an average primary particle diameter of from 100 nm to 1 ?m to using a mixer including a rotary shaft member, multiple stirring members provided to the surface of the shaft member, and a casing to cover the multiple stirring members, wherein the cross section of the inner periphery of the casing relative to a direction perpendicular to the rotation axis of the shaft member is circular around the rotation axis with a substantially constant distance between the inner periphery and the rotation axis. The casing covers the multiple stirring members and a cooling jacket is provided to at least part of the outer periphery of the casing. The weight ratio of the particles to the mother toner particles is from 1.5% to 10%.
    Type: Grant
    Filed: September 16, 2011
    Date of Patent: April 22, 2014
    Assignee: Ricoh Company, Ltd.
    Inventors: Kohsuke Satoh, Tetsuya Tanaka, Masahiro Kawamoto, Natsuko Matsushita
  • Patent number: 8685607
    Abstract: The continuous process for manufacturing toners disclosed herein includes continuously feeding components of a toner composition into a feed section of a screw extruder at a controlled rate. The continuous process for manufacturing toners may include feeding the components of a toner composition into the feed section of a screw extruder without performing an external or secondary dispersion step. That is to say, the components of the toner composition may be fed directly into the extruder without using dispersions of individual components as used in batch processes. Rather, the toner components are added to the extruder in dry form, melt-mixed, and may be dispersed in aqueous form in the extruder. The process may produce micron-sized toner particles, thus no further size reduction may be necessary.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: April 1, 2014
    Assignee: Xerox Corporation
    Inventors: Joo T. Chung, Chieh-Min Cheng, Zhen Lai, Mark E. Mang, Eugene F. Young, Brian Andaya, Joseph Leonardo
  • Publication number: 20140080045
    Abstract: A method of preparing a developer includes mixing a carrier and a powder with each other while falling with gravity.
    Type: Application
    Filed: August 7, 2013
    Publication date: March 20, 2014
    Inventors: Kousuke Suzuki, Yuuki Mizutani, Shinichiro Yagi
  • Patent number: 8673532
    Abstract: A method for producing dry toner particles that have similar particle size and shape characteristics as chemically produced toners. The method includes melt-mixing a toner resin with a colorant and, optionally, a wax, to form a toner; grinding the toner to form toner particles; classifying the toner particles into particles averaging 4 to 10 microns in size; blending the classified toner particles with additives in a high-speed blender; and then processing the mixture with optional additional surface additives in a conical mixer. The method produces toner particles that have high circularity and sharper particle size distribution. The surface processing of the toner particles does not affect the internal constituents of the toner particles.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: March 18, 2014
    Assignee: Xerox Corporation
    Inventors: Paul Casalmir, Bryan L. Norcott
  • Patent number: 8614041
    Abstract: Disclosed is a toner for electrophotography containing at least a binder resin. This toner for electrophotography is characterized in that (a) the tetrahydrofuran (THF) soluble content in the toner has a first peak in the molecular weight region of not less than 2,000 but less than 5,000 and a second peak in the molecular weight region of not less than 100,000 but less than 200,000 in the chromatogram obtained by gel permeation chromatography (GPC); (b) the binder resin contains at least a carboxyl group-containing vinyl resin (C) and a glycidyl group-containing vinyl resin (E); and (c) the mass ratio of the styrene monomer to the acrylic monomer in the binder resin, namely (S/A), is not less than 4.6 but less than 8.5.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: December 24, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Matsuoka, Kazuya Sakata, Hiroyuki Takei, Kenji Uchiyama, Ichiro Sasaki
  • Patent number: 8609313
    Abstract: A toner containing a resin binder and a colorant, wherein the resin binder contains a crystalline resin and an amorphous resin, the crystalline resin containing a composite resin containing: a polycondensation resin component obtained by polycondensing an alcohol component containing an aliphatic diol having 2 to 10 carbon atoms, and a carboxylic acid component containing an aromatic dicarboxylic acid compound, and a styrenic resin component, and the amorphous resin containing a polyester obtained from an alcohol component containing an aliphatic diol in an amount of 60% by mol or more, and a carboxylic acid component. The toner of the present invention is suitably used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: May 13, 2011
    Date of Patent: December 17, 2013
    Assignee: Kao Corporation
    Inventors: Akihiro Eida, Shogo Watanabe, Takashi Kubo
  • Patent number: 8603373
    Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to produce a melt of the pressure plastic material; and discharging the melt of the pressure plastic material by differential pressure to a space, so as to form particles, wherein the discharging includes at least one of (A) discharging the melt of the pressure plastic material while a compressive fluid is supplied to the melt of the pressure plastic material, and (B) discharging the melt of the pressure plastic material through one or more through-holes, to which vibration is applied, so as to change the shape of the melt of the pressure plastic material from a columnar shape, through the columnar shape with constrictions, into a particle shape.
    Type: Grant
    Filed: October 31, 2011
    Date of Patent: December 10, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Shinji Ohtani, Chiaki Tanaka
  • Patent number: 8592127
    Abstract: A method for producing a toner, comprising the step of feeding raw materials containing a resin binder and a colorant to an open-roller type kneader, and melt-kneading the raw materials, wherein the resin binder contains a crystalline polyester and an amorphous polyester, and wherein the crystalline polyester and the amorphous polyester fed to the open-roller type kneader are in a weight ratio, i.e. crystalline polyester/amorphous polyester, of from 5/95 to 30/70, and have a ratio of average particle sizes of crystalline polyester/amorphous polyester of from 1.5 to 4.0. The toner obtained according to the present invention is used in, for example, the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: November 26, 2013
    Assignee: Kao Corporation
    Inventor: Akihiro Eida
  • Publication number: 20130280648
    Abstract: A toner composition including at least one phosphorescent pigment that absorbs energy released by natural or artificial light, and is able to be seen in a dark environment through luminescence of a certain color created by the energy released as light, and a method of forming and using the toner are described. The phosphorescent toner has a particle size in the range of about 15-40 microns, which allows the toner to have the ability to absorb and then release the needed amount of light energy to be noticeable in a dark environment.
    Type: Application
    Filed: April 18, 2012
    Publication date: October 24, 2013
    Applicant: TROY GROUP, INC.
    Inventors: Carrie A. Gilson, Kevin L. Heilman, Michael R. Rlley
  • Patent number: 8551681
    Abstract: An emulsion aggregation toner formulation for electrophotography and a method for preparation thereof. The emulsion aggregation toner formulation includes a polyester resin emulsion formed using an extruded polyester binder resin having a broad molecular weight distribution. The extruded polyester binder resin is formed using a plurality of polyester binder resins. Further, the emulsion aggregation toner formulation comprises at least one colorant dispersion and a wax dispersion.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: October 8, 2013
    Assignee: Lexmark International, Inc.
    Inventors: Michael James Bensing, Craig Michael Bertelsen, John Joseph Kraseski, Bryan Patrick Livengood, Jing X. Sun, Vincent Wen-Hwa Ting
  • Publication number: 20130244165
    Abstract: A toner is provided that, even in a small amount thereof, gives a satisfactory image density and that is free of image problems, e.g., fogging and offset resistance, even during long-term use and in a high-temperature, high-humidity environment. The toner contains a binder resin, a pigment, and a prescribed azo compound wherein, designating as (A) the solubility of the azo compound in a toluene-hexane solubility test and as (B) the solubility of the binder resin constituting the toner in the toluene-hexane solubility test, the (A) and the (B) satisfy the relationship |(B)?(A)|?60.
    Type: Application
    Filed: February 26, 2013
    Publication date: September 19, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yasuhiro Hashimoto, Takayuki Toyoda, Masashi Kawamura, Naotaka Ikeda, Hidekazu Fumita, Emi Watanabe, Yuhei Terui
  • Patent number: 8501381
    Abstract: The invention relates to a liquid developer composition comprising a dispersant, and toner particles dispersed in said dispersant. The liquid developer composition can be used for printing onto a substrate. The binder resin in the toner particles is curable, e.g. by UV-light.
    Type: Grant
    Filed: March 19, 2008
    Date of Patent: August 6, 2013
    Assignee: Hologi Hitec-Imaging GmbH
    Inventors: Hans-Josef Humpert, Serge Tavernier, Kerstin Hymon
  • Patent number: 8455172
    Abstract: A method for producing a toner, containing: dispersing, in an aqueous medium, an oil phase which contains an organic solvent, and a binder resin component contained in the organic solvent, where the binder resin component contains a crystalline polyester resin and an amorphous polyester resin; and removing the organic solvent from the dispersion to obtain the toner, in which the dispersing further contains heating and dissolving the crystalline polyester and the amorphous polyester in the organic solvent to obtain a solution, cooling the solution so as to recrystallize the crystalline polyester resin, and mechanically pulverizing the recrystallized crystalline polyester resin so as to obtain a crystalline polyester dispersion.
    Type: Grant
    Filed: September 27, 2010
    Date of Patent: June 4, 2013
    Assignee: Ricoh Company, Ltd.
    Inventors: Junichi Awamura, Hiroshi Yamashita, Teruki Kusahara, Tsuyoshi Sugimoto, Tomomi Suzuki
  • Patent number: 8445170
    Abstract: Provided is a binder resin for color toners which comprises at least a carboxyl group-containing vinyl resin (C), a glycidyl group-containing vinyl resin (E) and a reaction product thereof, and contains both a tetrahydrofuran (THF) soluble portion and a THF insoluble gel portion, wherein the THF soluble portion has a main peak in the molecular weight region of not less than 10,000 and less than 15,000 in the chromatogram obtained by gel permeation chromatography (GPC), the content of the THF insoluble gel portion is less than 1 mass %, and the softening point is not more than 130 degrees centigrade.
    Type: Grant
    Filed: August 27, 2008
    Date of Patent: May 21, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuya Sakata, Hiroshi Matsuoka, Hiroyuki Takei, Kenji Uchiyama, Ichirou Sasaki
  • Patent number: 8435714
    Abstract: A process for making toner particles is provided. In embodiments, a suitable process includes melt mixing a resin in the absence of an organic solvent, optionally adding a surfactant to the resin, adding to the resin at least one colorant and other optional toner additives, adding to the resin a basic agent and water to form a mixture, and subjecting the mixture to acoustic mixing at a suitable frequency to form to form an emulsion. A phase inversion may then be performed to create a phase inversed emulsion including a disperse phase comprising molten resin and the optional ingredients of the toner composition, at which time toner-sized droplets may be solidified from the disperse phase into toner particles, which can be recovered for use.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: May 7, 2013
    Assignee: Xerox Corporation
    Inventors: Zhen Lai, Chieh-Min Cheng, Shigang Qiu, Emily L. Moore, Tie Hwee Ng
  • Publication number: 20130084521
    Abstract: The carrier core particles for electrophotographic developer include a core composition expressed by a general formula Fe3O4 as a main ingredient and 30 ppm to 400 ppm Na. Such carrier core particles can reduce environmental dependency thereof, while optimizing the resistivity.
    Type: Application
    Filed: May 17, 2011
    Publication date: April 4, 2013
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MSTERIALS CO., LTD
    Inventor: Takeshi Kawauchi
  • Publication number: 20130034808
    Abstract: A pulverizer including a solid-gas mixer to mix a compressed gas and particles of a raw material to be pulverized to prepare a solid-gas mixture; a particle path controlling nozzle connected with the solid-gas mixer to feed the solid-gas mixture fed from the solid-gas mixer while accelerating the solid-gas mixture and controlling the particles of the raw material so as to choose different flow paths based on particle diameters of the particles of the raw material; a collision member; and an accelerating tube connected with the particle path controlling nozzle to further accelerate the solid-gas mixture fed from the particle path controlling nozzle while maintaining the flow paths of the particles and ejecting the accelerated solid-gas mixture toward the collision member to pulverize the raw material.
    Type: Application
    Filed: July 24, 2012
    Publication date: February 7, 2013
    Inventor: Keisuke YAGOME
  • Patent number: 8362198
    Abstract: There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a polyester (p1) not containing an aromatic ring or a polyester (p2) containing an aromatic ring, and produced by polycondensation of a polyol component and a polycarboxylic acid component, and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0?H2/H1?0.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: January 29, 2013
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Yasuhiro Shindo, Sho Kim
  • Patent number: 8362197
    Abstract: There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a polyester (p1) not containing an aromatic ring or a polyester (p2) containing an aromatic ring, and produced by polycondensation of a polyol component and a polycarboxylic acid component, and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0?H2/H1?0.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: January 29, 2013
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Yasuhiro Shindo, Sho Kim
  • Publication number: 20130011781
    Abstract: A carrier core particle for an electrophotographic developer includes a composition expressed by a general formula: MnxFe3?xO4+y (0<x?1, 0<y), a full width at half maximum z of the most intense peak (311) plane in a powder X-ray diffraction pattern satisfying 0.16 (degree)?z, and a magnetization of 50 emu/g or higher in an external magnetic field of 1000 Oe.
    Type: Application
    Filed: March 8, 2011
    Publication date: January 10, 2013
    Applicants: DOWA IP CREATION CO., LTD., DOWA ELECTRONICS MATERIALS CO., LTD.
    Inventors: Takeshi Kawauchi, Sho Ogawa
  • Publication number: 20120322005
    Abstract: A method for producing particles, including: bringing a compressive fluid into contact with a pressure plastic material, so as to plasticize the pressure plastic material; applying a shear force to the compressive fluid and the plasticized pressure plastic material, between which an interface exists, in the presence of a surfactant to granulate the pressure plastic material in the compressive fluid, so as to produce particles.
    Type: Application
    Filed: March 9, 2011
    Publication date: December 20, 2012
    Inventors: Chiaki Tanaka, Ryota Inoue, Taichi Nemoto, Yoshitaka Yamauchi
  • Patent number: 8329375
    Abstract: A toner for developing an electrostatic charge image includes: an amorphous polyester resin; a crystalline polyester resin; and a releasing agent, an amount of the releasing agent in the toner being from 5 to 15% by weight; an amount of the releasing agent present at a surface of the toner being from 10 to 35% by weight; and the toner showing at least one endothermic peak in each of a temperature range from 45 to 60° C., a temperature range from 65 to 80° C., and a temperature range from 85 to 100° C. in a temperature-rise process of differential scanning calorimetry of the toner.
    Type: Grant
    Filed: April 22, 2009
    Date of Patent: December 11, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hiroshi Nakazawa, Masanobu Ninomiya, Hirokazu Hamano
  • Patent number: 8329371
    Abstract: A non-magnetic toner, including a binder resin; a wax present dispersing in the toner in the shape of a particle; and a colorant, wherein the wax having a particle diameter not less than 2.0 ?m and less than 3.0 ?m is not less than 20% and less than 40% by number based on total number thereof; the wax has a mode value not less than 1.5 ?m and less than 2.0 ?m in a frequency distribution of 0.1 ?m width; and the following relationship is satisfied: 45<XZ/Y<62 wherein X represents a softening point (° C.) of the toner; Y represents a volume-average particle diameter (?m) of the toner; and Z represents a total parts by weight of the wax included in 100 parts by weight of the toner.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: December 11, 2012
    Assignee: Ricoh Company, Ltd.
    Inventors: Yoshihiro Mikuriya, Hideaki Yasunaga, Hiroaki Katoh, Kazuoki Fuwa, Masayuki Hagi, Masahide Inoue
  • Publication number: 20120295195
    Abstract: The carrier core particles 11 for electrophotographic developer contain lithium as a core composition. When the carrier core particles 11 are immersed in pure water at a weight ratio of 1 part core particles 11 to 10 parts pure water and shaken, the amount of lithium that leaches out to the pure water is 0.10 ppm or lower.
    Type: Application
    Filed: January 25, 2011
    Publication date: November 22, 2012
    Applicants: Dowa IP Creation Co., Ltd., Dowa Electronics Materials Co., Ltd.
    Inventor: Takeshi Kawauchi
  • Patent number: 8309681
    Abstract: There is provided a method for producing a resin particle capable of unprecedentedly realizing both excellent heat resistant keeping property and melting property. The present invention is a method for producing a resin particle (X) comprising the step of treating a resin particle (B) containing a resin (A) composed of a crystalline part (a) containing, as an essential constitutional component, a lactone ring-opening polymer (p), and a noncrystalline part (b), with liquid or supercritical carbon dioxide (C), and removing (C), wherein a heat of fusion measured by differential scanning calorimetry (DSC) of the obtained (X) satisfies the following relational formula (1): 0?H2/H1?0.9??(1) [in the relational formula (1), H1 represents a measurement value of a heat of fusion (J/g) at the time of the initial temperature elevation measured by DSC; and H2 represents a measurement value of a heat of fusion (J/g) at the time of the second temperature elevation measured by DSC].
    Type: Grant
    Filed: July 22, 2009
    Date of Patent: November 13, 2012
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Takao Mukai, Koji Ota
  • Patent number: 8293447
    Abstract: An object of the present invention is to provide a toner which allows fixation at low temperatures, which is excellent in anti-offset ability, and which provides a high quality image at high and low humidities in a stable manner without causing any image defect over time. Provided is a toner, containing at least a binder resin and a colorant in which: the binder resin in the toner contains 60% by mass or more of a styrene/acryl resin and a THF-insoluble fraction A which is an extraction residue obtained by carrying out Soxhlet extraction with tetrahydrofuran (THF) for 16 hours; the THF-insoluble fraction A contains a TOL-insoluble fraction B which is an extraction residue obtained by carrying out Soxhlet extraction with toluene (TOL) for 16 hours; and a mass ratio (B/A) between the THF-insoluble fraction A and the TOL-insoluble fraction B is in the range of 0.1?B/A?0.5.
    Type: Grant
    Filed: June 22, 2011
    Date of Patent: October 23, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Katsuhisa Yamazaki, Masami Fujimoto, Masaaki Taya
  • Publication number: 20120264044
    Abstract: Disclosed is a negative-chargeable erasable electrophotographic toner including a binder resin, a near infrared absorption dye, a decolorizing agent, a charge controlling agent, and fluororesin particles. The toner is obtained by adding 5 to 20 parts by mass of the fluororesin particles to 100 parts by mass of the binder resin.
    Type: Application
    Filed: April 12, 2012
    Publication date: October 18, 2012
    Applicants: CASIO COMPUTER CO., LTD., CASIO ELECTRONICS MANUFACTURING CO., LTD.
    Inventors: Hideki IKEDA, Hideyoshi Niinuma, Toshiaki Kanamura
  • Patent number: 8288069
    Abstract: Provided is a toner including: toner particles each containing at least a binder resin and a wax; and an external additive, in which surfaces of the toner particles have an average surface roughness (Ra) measured with a scanning probe microscope of 1.0 nm or more and 30.0 nm or less; and the toner has a surface tension index I for a 45-vol % aqueous solution of methanol measured by a capillary suction time method and calculated from the following equation (1) of 5.0×10?3 N/m or more and 1.0×10?1 N/m or less: I=P?/(A×B×106)??Eq. (1) where I represents the surface tension index (N/m) of the toner, P? represents a capillary pressure (N/m2) of the toner for the 45-vol % aqueous solution of methanol, A represents a specific surface area (m2/g) of the toner, and B represents a true density (g/cm3) of the toner.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: October 16, 2012
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroyuki Fujikawa, Kunihiko Nakamura, Nozomu Komatsu, Yoshiaki Shiotari, Takeshi Ohtsu, Takayuki Itakura