Identified Nondye Image Forming Developing Agent, Silver Halide Development Accelerator Or Retarder, Or Dye Image Forming Accelerator Or Retarder Containing Patents (Class 430/218)
  • Patent number: 4551411
    Abstract: Photographic assemblages are described employing metallizable redox dye-releasers and a sequestering agent which is gluconic acid, N[CH.sub.2 --P--(O)(OH).sub.2 ].sub.3 or (HO).sub.2 P(O)--C(CH.sub.3)(OH)--P(O)(OH).sub.2.
    Type: Grant
    Filed: December 28, 1984
    Date of Patent: November 5, 1985
    Assignee: Eastman Kodak Company
    Inventors: David P. Brust, Stephen M. Neumann, Edward Weissberger
  • Patent number: 4547452
    Abstract: A color diffusion transfer photographic element containing a compound having a sulfinic acid group or a slat thereof is disclosed. The element is comprised of a photosensitive element and an alkaline processing composition element. The sufinic acid group or a salt thereof includes a compound represented by the general formula (Y-SO.sub.2).sub.n M wherein M is a hydrogen atom, an alkyl metal atom, an alkaline earth metal atom, an ammonium group, or an organic base; Y is an alkyl group, a substituted alkyl group, an aryl group or a substituted aryl group, and n is 1 or 2. By utilizing the compound within the processing solution it is possible to prevent the deterioration of processing composition which occurs when the material is stored for a long period of time.
    Type: Grant
    Filed: September 29, 1983
    Date of Patent: October 15, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Ichizo Toya
  • Patent number: 4543317
    Abstract: There is described a photographic system wherein development of an exposed photosensitive element with an aqueous alkaline processing composition is effected in the presence of a compound which is a salt of a radical of a substituted phenylmercaptoazole complexed with a radical of a quaternary. The salts are either insoluble or have extremely low solubility in water and become soluble, and photographically active, in alkaline environment.
    Type: Grant
    Filed: December 19, 1984
    Date of Patent: September 24, 1985
    Assignee: Polaroid Corporation
    Inventors: Avinash C. Mehta, Lloyd D. Taylor
  • Patent number: 4542086
    Abstract: A color diffusion transfer photographic element comprising (a) a light sensitive component containing at least one light sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b) and (c) containing a diffusible hydroquinone type compound having the half wave potential of polarography in the range of from -300 mV to -380 mV measured using a saturated calomel electrode as a reference electrode in a buffer solution having a pH of 13.0.degree. at 25.degree. C. The diffusible hydroquinone type compound has excellent gradation control properties and is particularly suitable for controlling gradation of the toe part in a photographic characteristic curve of a color diffusion transfer photograph.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: September 17, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Ohki, Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka
  • Patent number: 4537853
    Abstract: Photographic silver halide material containing a ballasted electron-donor precursor compound yielding by alkaline hydrolysis an electron-donor compound (ED-compound) capable (1) of donating electrons to an oxidized electron-accepting silver halide developing agent e.g. for scavenging it, said electron-donor precursor compound corresponding to the following general formula: ##STR1## wherein: R represents hydrogen or a substituent, e.g. an acyl group, which on hydrolytic removal allows the replacement of R by H,R.sup.1, R.sup.2 and R.sup.3 (same or different) are hydrocarbon substituents or R.sup.3 is H, andZ and Y represent the necessary atoms to close a benzene ring that may be substituted or form a fused ring system.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: August 27, 1985
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Christian C. Van de Sande, Andre Verhecken, Wilhelmus Janssens
  • Patent number: 4533622
    Abstract: A photographic element for a color diffusion transfer process comprising a support having thereon at least one silver halide emulsion layer and associated therewith a non-diffusible redox compound capable of releasing a diffusible dye or a precursor thereof as the result of treatment with an alkaline processing solution in the presence of a silver halide developing agent after exposure to light, the alkaline processing solution containing a compound represented by the following general formula (I): ##STR1## wherein R represents an alkyl group, an alkoxy group, an aromatic group or an alkylthio group, and each of these groups has 12 or less carbon atoms; and M represents a cation.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: August 6, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Mitsugu Tanaka
  • Patent number: 4517286
    Abstract: A color diffusion transfer process light-sensitive element is disclosed. The element is comprised of a support having coated thereon a light-sensitive silver halide emulsion layer which is associated with a dye image-providing compound. The dye image-providing compound is dispersed in a copresent state with a compound represented by the general formula (I): ##STR1## wherein the substituents within the general formula (I) are defined within the specification. The element has improved maximum image density and by utilizing the compound of the general formula (I) it is possible to obtain improved dispersion stability.
    Type: Grant
    Filed: December 2, 1983
    Date of Patent: May 14, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Noguchi, Masakazu Morigaki
  • Patent number: 4503139
    Abstract: There are described novel photographic products and processes which utilize compounds which release a photographic reagent in the presence of alkali. The compounds include an imidazole blocking group and cleave in alkali to release the photographic reagent. Also described are novel compounds.
    Type: Grant
    Filed: May 9, 1983
    Date of Patent: March 5, 1985
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Roger A. Boggs, Anthony J. Puttick, Nancy M. Sofen
  • Patent number: 4500636
    Abstract: A silver halide photographic light-sensitive material which comprises a light-sensitive silver halide emulsion layer having associated therewith a blocked photographic agent, said blocked photographic agent being represented by the following general formula (I): ##STR1## wherein A represents a photographic agent moiety which is attached to a blocking moiety through a hetero atom; Z represents a divalent linkage group; p represents 0 or 1; X and Y each represents a substituent: m represents an integer of 0 to 4: and n represents an integer of 0 to 5.
    Type: Grant
    Filed: January 27, 1984
    Date of Patent: February 19, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mitsunori Ono, Isamu Itoh, Keiji Mihayashi, Yukio Karino
  • Patent number: 4499181
    Abstract: A photographic recording material. On a support are provided a silver emulsion halide layer and a photographic layer. The photographic layer contains an indole compound represented by the general formula (I): ##STR1## wherein PUG represents a photographically useful group, Ball represents an organic group which has enough molecular weight and/or disposition to render the compound non-diffusible during processing of the photographic recording material with an alkaline medium and wherein the Ball contains a nitrogen atom which is directly attached to the 5th or 6th position of the indole ring. R.sub.1 represents a halogen atom or a monovalent organic group. R.sub.2 represents a hydrogen atom or a low molecular group attached, through a carbon atom, to the 2nd position of the indole ring. "m" represents an integer of zero to 3.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: February 12, 1985
    Assignee: Konishiroku Photo Ind., Co., Ltd.
    Inventors: Kazumasa Watanabe, Hidetaka Deguchi, Shunji Suginaka
  • Patent number: 4496645
    Abstract: A photographic color diffusion transfer process comprising the steps:(1) image-wise photo-exposing a photographic material which contains on a support at least one waterpermeable silver halide emulsion layer, the silver halide of which essentially consists of silver chloride, and in operative contact therewith at least one non-diffusing ballasted dye or dye precursor which when contacted with an aqueous alkaline liquid remains immobile in a waterpermeable colloid layer, and in reduced state is capable of releasing (a) dye(s) or dye precursor(s),(2) treating the photographic material with an alkaline processing liquid in the presence of a silver halide developing agent,(3) maintaining said photographic material in contact with the alkaline processing liquid in the presence of said developing agent to release said dye or dye precursor in diffusible state; and(4) transferring at least a portion of said released dye or dye precursor to a non-light-sensitive layer and carrying out the development in the presence o
    Type: Grant
    Filed: October 26, 1983
    Date of Patent: January 29, 1985
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Wilhelmus Janssens, Daniel A. Claeys
  • Patent number: 4495270
    Abstract: A color diffusion transfer photographic element comprising(a) a photosensitive element containing at least one photosensitive silver halide emulsion layer combined with a dye releasing redox compound,(b) a dye image receiving element, and(c) an alkaline processing composition element where the alkaline processing composition element contains(1) a developing agent having a one-electron oxidation-reduction potential of -80 mV to -200 mV with respect to a saturated calomel electrode at a pH of 11.0, and(2) at least one of the compounds represented by the following general formula (I): ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group, a substituted alkyl group, an alkenyl group, an aryl group or a substituted aryl group, and X.sup.- represents an anion.
    Type: Grant
    Filed: November 29, 1982
    Date of Patent: January 22, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Motohiko Tsubota, Masakazu Moriguchi
  • Patent number: 4486528
    Abstract: A color diffusion transfer photographic element which comprises (a) a light-sensitive element containing at least one light-sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving element and (c) an alkaline processing composition element, wherein the improvement comprises said alkaline processing composition element containing (1) a developing agent having one-electron oxidation reduction potential in the range of from -80 mV to -200 mV with respect to a saturated calomel electrode at a pH of 11.0 and (2) at least one compound selected from the group consisting of compounds represented by following general formula (I) or (II) ##STR1## wherein A and B each represents a non-metallic atomic group necessary to form a 5-, 6- or 7-membered ring; R.sub.1, R.sub.3 and R.sub.4 each represents an alkyl group, a substituted alkyl group, an alkenyl group, an aryl group or a substituted aryl group, R.sub.1 may further represent ##STR2## and R.sub.
    Type: Grant
    Filed: February 28, 1983
    Date of Patent: December 4, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Morigaki, Motohiko Tsubota
  • Patent number: 4483919
    Abstract: A silver halide photographic light-sensitive material containing at least one compound represented by the general formula (I): ##STR1## is disclosed. The compound of the invention has good stability over time. The material has improved developability and makes it possible to carry out simple and rapid processing. The material has good resistance with respect to fogging, stains and desensitization.
    Type: Grant
    Filed: December 23, 1983
    Date of Patent: November 20, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Isamu Itoh, Yasuhiro Yoshioka, Keiji Mihayashi, Noriyuki Inoue
  • Patent number: 4481277
    Abstract: This invention is concerned with producing color images of improved quality in photographic processes employing silver ion assisted cleavage reactions to provide a dye image by scavenging, i.e., rendering inert substantially all of the silver ion and/or soluble silver complex in the photographic system when image formation is substantially complete.
    Type: Grant
    Filed: February 2, 1983
    Date of Patent: November 6, 1984
    Assignee: Polaroid Corporation
    Inventor: William J. Pfingston
  • Patent number: 4481286
    Abstract: Novel compounds which are capable of forming a coordination complex with a metal and which include a silver halide developing substituent or a precursor thereof. The compounds are useful as silver halide developing agents and as intermediates for dye developers which are utilized in photographic applications.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: November 6, 1984
    Assignee: Polaroid Corporation
    Inventors: Patrick F. King, Stephen G. Stroud
  • Patent number: 4473631
    Abstract: A heat-developable color photographic material is disclosed. The material is comprised of a support having thereon at least a light-sensitive silver halide, a hydrophilic binder, a dye releasing compound reductive and capable of releasing a hydrophilic dye and a compound represented by the following general formula (A): ##STR1## wherein A.sub.1, A.sub.2, A.sub.3, and A.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent selected from an alkyl group, a substituted alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, a substituted aryl group and a heterocyclic group, or A.sub.1 and A.sub.2 or A.sub.3 and A.sub.4 may combine with each other to form a ring.The heat-developable color photographic material can easily provide in a short time a clear and stable color image having a high color density and low fog by imagewise exposure and heat development procedure.
    Type: Grant
    Filed: November 4, 1983
    Date of Patent: September 25, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Hirai, Hideki Naito, Hiroshi Hara, Kozo Sato
  • Patent number: 4471045
    Abstract: Photographic elements, film units, processes and alkaline processing compositions are described wherein certain 4-hydroxyalkyl-substituted 3-pyrazolidinones are employed as electron transfer agents in black-and-white and color image transfer materials. The silver halide electron transfer agents or precursors thereof have the following formula: ##STR1## wherein: n is 1 or 2;R represents hydrogen or a hydrolyzable moiety;R.sup.1 represents an alkyl or substituted alkyl group of 1 to about 6 carbon atoms, an aryl or substituted aryl group of 6 to about 10 carbon atoms, or an aralkyl group of 6 to about 10 carbon atoms;R.sup.2 and R.sup.3 each independently represents hydrogen, an alkyl or substituted alkyl group of 1 to about 6 carbon atoms, an aryl or substituted aryl group of 6 to about 10 carbon atoms, or an aralkyl group of 6 to about 10 carbon atoms; andR.sup.4 represents hydrogen or one or more alkyl or alkoxy groups having from 1 to about 4 carbon atoms, methylenedioxy groups or ethylenedioxy groups.
    Type: Grant
    Filed: August 4, 1983
    Date of Patent: September 11, 1984
    Assignee: Eastman Kodak Company
    Inventors: George B. Bodem, Drake M. Michno
  • Patent number: 4463081
    Abstract: Photographic elements, film units, processes and alkaline processing compositions are described wherein certain 4-hydroxyalkyl-substituted 3-pyrazolidinones are employed as electron transfer agents in black-and-white and color image transfer materials. The silver halide electron transfer agents or precursors thereof have the following formula: ##STR1## wherein: n is 0, 1 or 2;R represents hydrogen or a hydrolyzable moiety;R.sup.1 and R.sup.2 each independently represents hydrogen, an alkyl or substituted alkyl group of 1 to about 6 carbon atoms, an aryl or substituted aryl group of 6 to about 10 carbon atoms, or an aralkyl group of 6 to about 10 carbon atoms, with the proviso that when n is 0, then either R.sup.1 or R.sup.2, but not both, may be hydrogen; andR.sup.3 represents at least one alkyl or alkoxy group having from 1 to about 6 carbon atoms, methylenedioxy group or ethylenedioxy group.
    Type: Grant
    Filed: August 4, 1983
    Date of Patent: July 31, 1984
    Assignee: Eastman Kodak Company
    Inventor: Drake M. Michno
  • Patent number: 4460682
    Abstract: A novel silver halide photographic element which contains a nondiffusible complex capable of releasing a diffusible, photographically useful material is disclosed.Said nondiffusible complex becomes active for ligand exchange upon reduction under alkalin conditions to release a diffusible, photographically useful material, said complex being represented by the following formula: ##STR1## wherein La is a quadridentate ligand group; Lb is a didentate ligand group; BALL is a ballast group; PHOTO is a photographically useful material group; Y is a counter ion; and r is the number of counter ions necessary for neutralizing the electric charge on the CO(III) complex.
    Type: Grant
    Filed: December 15, 1982
    Date of Patent: July 17, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Noboru Mizukura, Satoru Ikeuchi, Shunji Suginaka, Noriko Fujita
  • Patent number: 4450223
    Abstract: A photographic silver halide material comprising a compound which is capable of being reduced by a silver halide developing agent at a rate slower than that of image-wise developable silver halide and in reduced state is capable of releasing a photographically useful group, characterized in that said compound corresponds to the following formula: ##STR1## wherein: R.sup.10 and R.sup.20 (same or different)(1) represent an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group or an aralkyl group including said groups in substituted form,(2) represent an aryl group including a substituted aryl group, or(3) represent a heterocyclic ring residue including such residue in substituted form, orR.sup.10 and R.sup.20 are ringclosed, either R.sup.10 or R.sup.20 containing a ballasting group conferring diffusion resistance to the compound in hydrophilic colloid media when penetrated by an aqueous alkaline liquid;L.sup.1 and L.sup.2 (same or different) represent a ##STR2## --SO.sub.
    Type: Grant
    Filed: February 14, 1983
    Date of Patent: May 22, 1984
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raphael K. Van Poucke, Christian C. Van de Sande, Andree Verhecken
  • Patent number: 4440849
    Abstract: The invention relates to a process for the production of colored images by the dye diffusion transfer principle, in which a color photographic recording material containing negative silver halide emulsions and reducible color-providing compounds is developed with an alkaline developer preparation containing a combination of at least one compound from each of at least two of the groups of compounds (A, B, C) defined below as development accelerators. With combinations of this type, equal or higher maximum color densities are obtained for a smaller overall quantity of development accelerator.A: a 1,3-diol containing from 3 to 10 carbon atomsB: a cyclohexane dimethanol or cyclohexene dimethanolC: an aryl alkanol or aroxyalkanol containing from 7 to 12 carbon atoms.
    Type: Grant
    Filed: June 21, 1982
    Date of Patent: April 3, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Werner Krafft
  • Patent number: 4436810
    Abstract: Compounds corresponding to the formula: ##STR1## wherein Z represents a radical which completes a condensed aromatic ring system;R.sup.1 represents an n-valent aliphatic or aromatic radical;R.sup.2 represents H, alkyl or aryl,R.sup.3 represents one or more radicals to control the diffusion properties and the activation pH;andn represents 1 or 2,are suitable ED precursor compounds for use in color-photographic recording materials. They are preferably used in a combination with reducible dye-releasers. They are also suitable as so-called scavengers.
    Type: Grant
    Filed: April 29, 1983
    Date of Patent: March 13, 1984
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Karl Kuffner, Paul Marx, Wolfgang Lassig
  • Patent number: 4435495
    Abstract: Photographic reagents can be released, under alkaline conditions, from certain photographic reagent releasing compounds by means of oxidized 3-pyrazolidone developing agents. Particularly useful are acyclic and cyclic compounds in which the photographic reagent is linked, through a hetero atom, to a carbon atom which is adjacent to or in conjugation with a carbonyl group or an imino group. Upon reaction, under alkaline conditions, with an oxidized 3-pyrazolidone developing agent, the bond between the hetero atom and the carbon atom is cleaved. Photographic assemblages containing photographic reagent releasing compounds and processes of releasing photographic reagents in photographic elements and assemblages are described.
    Type: Grant
    Filed: January 22, 1982
    Date of Patent: March 6, 1984
    Assignee: Eastman Kodak Company
    Inventor: Philip T. S. Lau
  • Patent number: 4431728
    Abstract: There is disclosed a silver halide photographic light-sensitive material which comprises a support, a combination of an unfogged surface latent image type silver halide photographic emulsion and a material which is non-diffusible under alkali conditions and which is capable of releasing a diffusible development inhibitor or a precursor thereof as a result of cross oxidation with an oxidized product of a photographic developing agent; and a combination of an internal latent image type silver halide photographic emulsion whose silver halide grains contain therein, prior to development, fog nuclei and a dye image-forming material which is initially non-diffusible under alkaline conditions but which is capable of releasing a diffusible dye or a precursor thereof as a result of being oxidized by the oxidized product of said photographic developing agent.
    Type: Grant
    Filed: June 9, 1982
    Date of Patent: February 14, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takao Abe, Tatsuhiko Kobayashi
  • Patent number: 4429031
    Abstract: A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: January 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka, Nobutaka Ohki
  • Patent number: 4421846
    Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.
    Type: Grant
    Filed: December 23, 1981
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoru Ikeuchi, Masaru Kanbe, Jiro Takahashi, Ryuichiro Kobayashi, Shunji Suginaka, Noboru Mizukura
  • Patent number: 4420557
    Abstract: Compounds corresponding to the formula: ##STR1## wherein R.sup.1 represents an aromatic group, andR.sup.2 represents H, alkyl, alkenyl, aryl or acyl, are suitable ED precursor compounds for use in color photographic recording materials. They are preferably used in combination with reducible dye releasers. They are also suitable as so-called scavengers.
    Type: Grant
    Filed: October 25, 1982
    Date of Patent: December 13, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Paul Marx
  • Patent number: 4416970
    Abstract: Image transfer photographic assemblages, processes, compositions and cover sheets are described which employ a manganous compound. After processing, the manganous compound is capable of diffusing to the silver halide emulsion layer and a redox dye-releaser associated therewith to inhibit further dye release. Post-process D.sub.min stability is thereby improved.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: November 22, 1983
    Assignee: Eastman Kodak Company
    Inventor: Thomas O. Maier
  • Patent number: 4410618
    Abstract: .alpha.-Ketoimidomethyl blocked photographic reagents are useful in photographic elements, film units and processes. The blocked photographic reagents have the structure: ##STR1## wherein J represents ##STR2## X represents the atoms to complete a 5- or 6-membered ring or ring system; R represents alkyl of 1 to 30 carbon atoms or aryl of 6 to 30 carbon atoms; andPR represents the residue of an organic photographic reagent containing a heteroatom through which it is joined to the blocking group.
    Type: Grant
    Filed: June 11, 1982
    Date of Patent: October 18, 1983
    Assignee: Eastman Kodak Company
    Inventors: James P. Vanmeter, Chin H. Chen
  • Patent number: 4407941
    Abstract: A photographic element comprising a support provided thereon with at least one light-sensitive silver halide emulsion layer containing a nondiffusible compound which receives at least one electron in an alkaline condition to release a photographically useful material and a nondiffusible electron donor or a precursor thereof having the following formula (I) or (II): ##STR1## wherein R.sup.1 represents hydrogen, an alkyl, an aryl or a heterocyclic group, R.sup.2 represents hydrogen, an alkyl, an aryl, a heterocyclic, an amino, a carbamide, a sulfonamide, a sulfamoyl, a carbamoyl or a ureido group, R.sup.3 and R.sup.4 each is hydrogen, --COR.sup.5, --SO.sub.2 R.sup.6 or --CSR.sup.7 wherein R.sup.5 and R.sup.6 each is a substituted or unsubstituted, respectively, alkyl, alkenyl, aryl, heterocyclic, alkylamino, alkyloxy, aryloxy, alkylthio, arylthio, alkyloxycarbonyl or aryloxycarbonyl group, and R.sup.7 is a substituted or unsubstituted alkyllamino or arylamino group, said R.sup.
    Type: Grant
    Filed: March 8, 1982
    Date of Patent: October 4, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shunji Suginaka, Ryuichiro Kobayashi, Satoru Ikeuchi, Noboru Mizukura, Noriko Fujita
  • Patent number: 4396699
    Abstract: A process for the production of a multi-color dye image by dye diffusion transfer operating with a photographic multilayer multi-color material containing different non-diffusing dyes or dye precursor compounds that when contacted with an aqueous alkaline liquid remain immobile in an alkali-permeable colloid layer but are capable of being reduced by a developing agent at a rate slower than the reduction of image-wise developable silver halide and in reduced state under alkaline conditions are capable of releasing a diffusible dye or dye precursor moiety, and wherein as illustrated in the drawing dye images with higher color saturation are obtained by more extensive oxidation of developing agent in the image-wise photo-exposed area due to the use in the alkaline processing liquid of a silver halide solvent forming an alkali-soluble and reducible silver complex compound.
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: August 2, 1983
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Wilhelmus Janssens, Daniel A. Claeys
  • Patent number: 4377632
    Abstract: Diffusion transfer film units and a diffusion transfer process operative therein are described which are capable of providing relatively high resolution monochromatic dye developer transfer images.
    Type: Grant
    Filed: December 24, 1981
    Date of Patent: March 22, 1983
    Assignee: Polaroid Corporation
    Inventor: William J. Pflingston
  • Patent number: 4375506
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer for use with negative-working silver halide emulsions and positive-working redox dye-releasers. The outermost timing layer has a negative temperature coefficient and has a development accelerator associated therewith to increase the development of the silver halide emulsion at low temperatures. The timing layer next to the neutralizing layer has a greater penetration time by the alkaline processing composition so that the neutralizing layer is permeated only after silver halide development has been substantially completed. The temperature latitude of the system is thereby increased.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: March 1, 1983
    Assignee: Eastman Kodak Company
    Inventors: Edward P. Abel, Edward Weissberger
  • Patent number: 4371604
    Abstract: A photographic material for diffusion transfer photography containing a quinonoid compound, which is capable in reduced state and under alkaline conditions of releasing a photographically useful group and corresponds to one of the following general formulae: ##STR1## wherein: each of (Nuox).sup.1 and (Nuox).sup.2 (same or different) represents an oxidized nucleophilic group,Z represents a bivalent atom or bivalent atomic group, which is electro-negative,Q together with the group Z represents a releasable photographically useful group,Y.sup.1 and Y.sup.2 together represent the necessary atoms to close a p-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character,Y.sup.3 represents the necessary atoms to close a o-quinonoid ring substituted with (a) directly linked monovalent organic ring or ring system substituent(s) having aromatic character, andeach of R.sup.1 and R.sup.
    Type: Grant
    Filed: March 31, 1981
    Date of Patent: February 1, 1983
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Christian C. Van de Sande, Wilhelmus Janssens, Wolfgang Lassig, Ernst Meier
  • Patent number: 4371603
    Abstract: This invention relates to amino hydroxy cyclohexenones of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each are alkyl, usually containing 1 to 20 carbon atoms.In another embodiment, the present invention is directed to the use of the above-denoted compounds as photographic silver halide developing agents and to photographic processes, products and compositions employing the same.
    Type: Grant
    Filed: December 30, 1980
    Date of Patent: February 1, 1983
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Eva R. Karger
  • Patent number: 4366236
    Abstract: A diffusion transfer color photographic material having an improved interlayer between two silver halide photographic emulsion layers formed on a support. The interlayer contains a mixture of hydroquinone derivatives having solidifying points lower than 100.degree. C. and a water-insoluble organic solvent-soluble homopolymer or copolymer dispersed in a hydrophilic organic colloid.
    Type: Grant
    Filed: March 5, 1981
    Date of Patent: December 28, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Osamu Takahashi
  • Patent number: 4365085
    Abstract: The present invention relates to novel bicyclic compounds useful as photographic silver halide developing agents, to the preparation of these compounds and to photographic products, processes and compositions employing the same. The subject compounds may be represented by the formula ##STR1## wherein R.sub.1 and R.sub.2, the same or different, each represents hydrogen, a hydrocarbon moiety, preferably an alkyl group, --COOH or --COOR.sup.1 wherein R.sup.1 is an alkyl group; R.sub.3 and R.sub.4, the same or different, each represent hydrogen or an alkyl group, R.sub.5 represents hydrogen or --COR.sup.2 wherein R.sup.2 is an alkyl group; R.sub.6 represents hydrogen when R.sub.5 is hydrogen and represents hydrogen or --OCOR.sup.3 wherein R.sup.3 is an alkyl group the same as R.sup.2 when R.sub.5 represents --COR.sup.2 ; X represents --OH, --NH.sub.2 or --NHCOR.sup.4 wherein R.sup.4 represents an alkyl group the same as R.sup.2 ; Y represents --OH or --OCOR.sup.5 wherein R.sup.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: December 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Eva R. Karger
  • Patent number: 4362806
    Abstract: Photographic elements, multicolor filters and receivers are disclosed having supports providing microvessels for materials such as radiation-sensitive materials, imaging materials, mordants, silver precipitating agents and materials which are useful in conjunction with these materials. Processes of forming microvessels and introducing materials therein are also disclosed. Processes of forming images are disclosed employing microvessel containing elements. Image transfer processes are disclosed for producing one or a combination of silver and multicolor subtractive primary images alone or in combination with multicolor additive primary images.
    Type: Grant
    Filed: September 8, 1980
    Date of Patent: December 7, 1982
    Assignee: Eastman Kodak Company
    Inventor: Keith E. Whitmore
  • Patent number: 4360581
    Abstract: Electron donor compounds of the formula I are effective to reduce non-diffusing reducible color providing compounds which when reduced release under the photographic development conditions a diffusible dye.R.sup.1 (--L.sup.1 .dbd.L.sup.2).sub.n --NH--SO.sub.2 --X (I)in whichL.sup.1, L.sup.2 represent methine groups which may be part of a carbocyclic or heterocyclic ringR.sup.1 represents --OR.sup.2, --SR.sup.2 or --NHR.sup.3R.sup.2 represents H or a hydrolysable groupR.sup.3 represents H, alkyl, aryl, acyl including a group that together with L.sup.1 completes a ringn=1 or 2X represents a non-colored organic group.
    Type: Grant
    Filed: November 19, 1980
    Date of Patent: November 23, 1982
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Heinrich Odenwalder, Hans Vetter, Wilhelmus Janssens, Jan Jaeken
  • Patent number: 4358525
    Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: November 9, 1982
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, William C. Archie, Jr.
  • Patent number: 4353973
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets are described employing a neutralizing layer comprising about 75 to about 150 meq. of acid/m.sup.2 of element for neutralizing an alkaline processing composition. The neutralizing layer, timing layer or layer adjacent thereto also contains about 1 to about 10 meq./m.sup.2 of oxalic acid, or an acid salt thereof, to minimize sensitometric changes that occur with keeping.
    Type: Grant
    Filed: June 29, 1981
    Date of Patent: October 12, 1982
    Assignee: Eastman Kodak Company
    Inventor: Richard W. Wheeler
  • Patent number: 4353974
    Abstract: A process for the production of a photographic image which comprises(a) imagewise exposing a photographic assembly which comprises at least during a silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a layer substantive hydroxypyridone azamethine compound of the general formula ##STR1## wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl, amino or heterocyclic radical, Y represents hydrogen or hydroxy, --CN, --COOR.sup.1, --CONR.sup.1 R.sup.2 or --COR.sup.1 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical and Z is hydrogen or is --CN, --COOR.sup.3, --CONR.sup.3 R.sup.4, --SO.sub.3 H, --SO.sub.3.sup.- or --COR.sup.3, where R.sup.1, R.sup.2, R.sup.3 and R.sup.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: October 12, 1982
    Assignee: Ciba-Geigy AG
    Inventors: Terence C. Webb, Patrick D. P. Thomas, William E. Long
  • Patent number: 4353975
    Abstract: A dye-diffusion transfer process for producing (a) dye image(s) with improved dye density is provided, said process comprising the steps of:(1) image-wise photo-exposing a photographic color material, which contains at least one alkali-permeable silver halide hydrophilic colloid layer which contains in operative contact therewith or therein a non-diffusing dye or dye precursor compound that when contacted with an aqueous alkaline liquid remains immobile in an alkali-permeable colloid layer and is capable of being reduced by a silver halide developing agent at a rate slower than that of imagewise developable silver halide and in reduced state under alkaline conditions is capable of releasing a diffusible dye or dye precursor moiety, and(2) applying in the presence of a developing agent an aqueous alkaline liquid to said photoexposed material, characterized in that said liquid contains triisopropanolamine.
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: October 12, 1982
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Wilhelmus Janssens, Daniel A. Claeys
  • Patent number: 4339523
    Abstract: A new method to produce photographic images is provided which comprises:(a) imagewise exposing a photographic assembly which contains at least during the silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a substantive azamethine compound and a photobase, there being optionally one or more interlayers between each of said components(b) treating the exposed photographic assembly with an aqueous processing bath so as to provide in the silver halide emulsion layer or layers a solution or dispersion of a bleach developer compound, thereby to develop the latent silver image in the silver halide emulsion(s), and(c) in the non-latent image areas allowing the bleach developer compound to diffuse in a counter-imagewise manner from the silver halide emulsion layer (s) to the layer containing substantive azamethine compound and there to bleach the compound to form a dye image.
    Type: Grant
    Filed: March 21, 1980
    Date of Patent: July 13, 1982
    Assignee: Ciba-Geigy AG
    Inventors: Alexander Psaila, Katerina Kessler
  • Patent number: 4336322
    Abstract: A color photographic light-sensitive material is described containing a dye-releasing redox compound having the following formula: ##STR1## wherein G represents a hydroxy group or a group providing a hydroxy group by hydrolysis;Col represents a dye or a dye precursor;R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group or an aromatic group, and R.sup.1 and R.sup.2 together can form a ring;R.sup.3 represents hydrogen, an alkyl group or an aromatic group;R.sup.4 can represent an alkyl group or an aromatic group;R.sup.5 can represent an alkyl group, an alkoxy group, an alkylthio group, an arylthio group, a halogen atom or an acylamino group;n is 0, 1 or 2; andR.sup.4 and an R.sup.5 together can form a heterocyclic ring, R.sup.1 and R.sup.4 together can form a heterocyclic ring, R.sup.1 and an R.sup.5 together can form a ring, R.sup.1, R.sup.2 and R.sup.3 together can form an adamantyl ring, and the total number of carbon atoms of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sub.n.
    Type: Grant
    Filed: July 18, 1980
    Date of Patent: June 22, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinsaku Fujita, Koichi Koyama, Yoshio Inagaki, Kokichi Waki
  • Patent number: 4314020
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer. The outermost timing layer contains photographic addenda, such as development inhibitors, for substantially terminating development of the silver halide emulsion. The timing layer next to the neutralizing layer has a much longer breakdown time so that it is permeated by the alkaline processing composition only after silver halide development has been substantially terminated.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: February 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, Patrick H. Saturno, Gerald L. Ducharme
  • Patent number: 4294915
    Abstract: There are described novel compounds which include a silver halide developing function, a colorless ligand which is a radical of an iminodiacetic acid and a radical containing an onium group. The compounds are useful in photography as silver halide developing agents and also may be complexed with metals to form dye developers.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: October 13, 1981
    Assignee: Polaroid Corporation
    Inventor: Elbert M. Idelson
  • Patent number: 4287291
    Abstract: This invention relates to a light-sensitive color photographic material and more particularly to a diffusion transfer color photographic film unit, the processing composition of which contains a specific saturated aliphatic or saturated alicyclic alcohol.
    Type: Grant
    Filed: November 21, 1979
    Date of Patent: September 1, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventor: Kaoru Onodera
  • Patent number: 4282306
    Abstract: Diffusion transfer color processes employing dye developers have been found to give improved results by the inclusion in the processing composition of a 5- or 6-membered aromatic unsaturated diazole free of imino nitrogen atoms.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: August 4, 1981
    Assignee: Polaroid Corporation
    Inventor: Ronald F. Lambert