Identified Silver Halide Grain, Silver Halide Emulsion, Binder Other Than Nominally Defined Gelatin, Or Silver Halide Sensitizer Or Desensitizer Containing Patents (Class 430/230)
  • Patent number: 8085304
    Abstract: A photographic digital data archival apparatus includes an article of media that includes a substrate and one or more layers of silver-emulsion based light-sensitive material, the article of media being configured to store digital data in the one or more layers and including a human-readable portion that provides instructions on reading and interpreting the digital data using basic imaging and computing technologies that do not require a person reading the instructions to previously possess or first acquire, as a prerequisite, knowledge of a format or encoding scheme associated with the digital data.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: December 27, 2011
    Assignee: The Aerospace Corporation
    Inventors: Mark Alan Zurbuchen, Charles Thomas Hoskinson
  • Patent number: 7387824
    Abstract: A support for an image recording medium includes base paper, a polymer coating layer formed on both top and wire side surfaces, and a coating layer containing a pigment and an adhesive agent which is formed under the polymer coating layer on one or both side surfaces. The support has a water absorbence less than 20 mg in terms of cross section water absorption quantity given by the following expression: Cross section water absorption quantity (mg)=A?B where A is the mass of a 10×1.5 cm support after wiping off attached water after five minute immersion in a water bath at 20° C. and B is the mass of the paper base support before immersion.
    Type: Grant
    Filed: September 1, 2005
    Date of Patent: June 17, 2008
    Assignee: Fujifilm Corporation
    Inventors: Shigehisa Tamagawa, Hiroshi Yamamoto, Shinichi Teramae
  • Patent number: 7273266
    Abstract: A micro-fluid ejection assembly including a silicon substrate having accurately formed fluid paths therein. The fluid paths are formed by a deep reactive ion etching process conducted on a substrate having a surface characteristic before etching selected from the group consisting of a dielectric layer thickness of no more than about 5000 Angstroms, and a substantially dielectric material free pitted surface wherein a root mean square depth of surface pitting is less than about 500 Angstroms and a maximum surface pitting depth is no more than about 2500 Angstroms. Fluid paths in such substrates having improved flow characteristics for more reliable fluid ejection operations.
    Type: Grant
    Filed: April 14, 2004
    Date of Patent: September 25, 2007
    Assignee: Lexmark International, Inc.
    Inventors: John William Krawczyk, Andrew Lee McNees, James Michael Mrvos, Carl Edmond Sullivan
  • Patent number: 7179885
    Abstract: Silver halide emulsions for photographic uses contain a nucleation peptiser having at least one region A of up to 100 amino acids. Region A can either consist of (i) at least two silver-binding amino acids and up to 98 amino acids between the two silver-binding amino acids, or can consist of (ii) a stretch of from 9 to 100 amino acids having a polarity corresponding to an average transfer free energy ?F equal to or higher than +1.0 kcal/mol. The nucleation peptizer also has at least one region B (separated from region A) having at least 50 amino acids and having a polarity corresponding to an average transfer free energy equal to or lower than ?1.0 kcal/mol and not containing methionine residues. The emulsion may also contain a growth peptiser having similar characteristics to the nucleation peptiser, but having a longer A region and a greater overall length.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: February 20, 2007
    Assignee: Fuji Photo Film B.V.
    Inventors: Jan Bastiaan Bouwstra, Gertjan Bögels, Yuzo Toda
  • Patent number: 6889607
    Abstract: A method for mounting a printing master on a printing form cylinder includes readying a new print job with a printing-image length by releasing an unwinding spool, activating an unwinding spool drive for moving the printing master a length in circumferential direction of the cylinder on the circumferential surface by drawing the printing master to a rewinding spool and braking the unwinding spool for building tension. A preceding job image start is located on the surface facing the rewinding spool. A control device activates the unwinding spool drive and, before activation, data is produced in the control device regarding the length to be spooled forward, and the spools are fixed, after advancing the printing master a length, for insuring tension. A value is determined for the printing master length to be spooled forward, being at most the printing image length of the preceding print job plus a printing image spacing.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: May 10, 2005
    Assignee: Heidelberger Druckmaschinen AG
    Inventors: Peter Eisele, Gerhard Schlindwein, Andreas Schorpp
  • Patent number: 6878513
    Abstract: A modified gelatin obtained by reacting (A) a gelatin and (B) a compound which contains a nitrogenous aromatic ring having a mercapto group to form covalent bond with a reactive group in the gelatin, an introduction amount of the compound in the gelatin being 1.0×10?6 mol to 2.0×10?3 mol per 100 g of the gelatin.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: April 12, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Terukazu Yanagi, Mamoru Sakurazawa, Naohiro Takeda, Yoichi Maruyama, Katsuyuki Takada
  • Patent number: 6869743
    Abstract: There is disclosed a method of processing a light-sensitive material which comprises exposing a light-sensitive material having at least one light-sensitive layer on a support, and subjecting to development by a dipping system or a coating system, and then, peeling at least the light-sensitive layer off by bringing a peeling material into close contact with the light-sensitive material, wherein the peeling material is a material having a liquid-absorbing rate in which a liquid-absorption amount within 0.1 second after getting in contact with a liquid is 60% or more based on a liquid-absorption amount within 0.2 second after the same.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: March 22, 2005
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Shigeyoshi Suzuki, Yasuo Tsubai, Sadao Kuriu, Toshihito Maruyama, Kenji Hirata, Masato Asano, Masahiko Saikawa, Akira Furukawa
  • Patent number: 6803177
    Abstract: Novel silver compounds can include a primary core of a photosensitive silver halide and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. Other novel silver compounds are homogeneous silver salts of organic silver coordinating ligands throughout (non-core-shell). Still other silver compounds can include a primary core of a non-photosensitive metal salt and a shell covering the primary core. This shell includes one or more non-photosensitive silver salts, each silver salt including an organic silver coordinating ligand. These types of silver compounds can be used as sources of reducible silver ions in thermally developable imaging materials including thermographic and photothermographic materials.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: October 12, 2004
    Assignee: Eastman Kodak Company
    Inventors: Boris B. Bokhonov, Lilia P. Burleva, David R. Whitcomb, Nepal C. Howlader, Louis M. Leichter
  • Patent number: 6673508
    Abstract: A planographic printing plate material and a method of preparing a planographic printing plate are disclosed, the planographic printing plate material comprising a support and provided thereon, one or more structural layers containing light sensitive silver halide grains, organic silver salt grains, a reducing agent, a contrast-increasing agent and a physical developing nucleus.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: January 6, 2004
    Assignee: Konica Corporation
    Inventor: Takeshi Sampei
  • Patent number: 6541176
    Abstract: There is disclosed a process for making a lithographic printing plate, which comprises subjecting a lithographic printing material having at least a silver halide emulsion layer and a physical development nuclei layer on a support and having a sensitivity at a wavelength of 400 nm to 440 nm of 20 &mgr;J/cm2 or less, and having substantially no sensitivity at a wavelength of 450 nm or longer to scanning exposure by a scanning type exposure device on which a violet laser diode is mounted, and then subjecting to developing treatment.
    Type: Grant
    Filed: April 2, 2001
    Date of Patent: April 1, 2003
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Takashi Miyazaki, Satoshi Shimonodan, Etsuji Tanaka, Motozo Yamano
  • Publication number: 20030022096
    Abstract: There is disclosed a process for making a lithographic printing plate, which comprises subjecting a lithographic printing material having at least a silver halide emulsion layer and a physical development nuclei layer on a support and having a sensitivity at a wavelength of 400 nm to 440 nm of 20 &mgr;J/cm2 or less, and having substantially no sensitivity at a wavelength of 450 nm or longer to scanning exposure by a scanning type exposure device on which a violet laser diode is mounted, and then subjecting to developing treatment.
    Type: Application
    Filed: April 2, 2001
    Publication date: January 30, 2003
    Inventors: Takashi Miyazaki, Satoshi Shimonodan, Etsuji Tanaka, Motozo Yamano
  • Patent number: 6403279
    Abstract: A diffusion transfer photographic product is disclosed, comprising a photosensitive element, an image receiving element and a container having a processing composition, wherein the photosensitive element comprises a support having thereon at least a silver halide emulsion layer containing a silver halide emulsion comprising silver halide grains and at least 50% of total grain projected area is accounted for by silver halide regular crystal grains containing 5 mol % or less chloride and 0.5 mol % or more iodide and exhibiting a proportion of a (100) face per grain of not less than 50%, a variation coefficient of the proportion of a (100) face among grains being not more than 20%.
    Type: Grant
    Filed: November 2, 2000
    Date of Patent: June 11, 2002
    Assignee: Konica Corporation
    Inventor: Masaru Iwagaki
  • Patent number: 6261733
    Abstract: According to the present invention, there is provided a silver salt diffusion transfer material, comprising on a hydrophilic surface of a support in the order given (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) a top layer containing gelatin, said silver halide emulsion being spectrally sensitized with a dye with a sensitizing maximum between 380 and 430 nm, characterized in that said top layer comprises a compound I and/or a compound II
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: July 17, 2001
    Assignee: Agfa-Gevaert
    Inventors: Paul Coppens, Ludo Vervloet, Paul Callant
  • Patent number: 6146819
    Abstract: There is disclosed a silver halide photographic light-sensitive material which comprises a polyester film support, at least one subbing layer containing a self-emulsifiable isocyanate compound having an ethylene oxide recurring unit and two or more isocyanate groups on the support, and at least one silver halide emulsion layer provided on said subbing layer.
    Type: Grant
    Filed: November 29, 1999
    Date of Patent: November 14, 2000
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akira Furukawa, Daichi Miyake
  • Patent number: 6146808
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer, characterized in that said element before and/or after being coated with said image-receiving layer and before being coated with another layer is wetted with a fluidum with a conductivity of at least 1 .mu.S/cm at 25.degree. C. and then the wetted element is brought in contact with an earthed discharging means and dried before coating the following layer.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: November 14, 2000
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 6146807
    Abstract: According to the present invention there is provided a method for preparing a silver salt diffusion transfer imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer in water permeable relationship with said image receiving layer, characterized in that said aluminum support, provided with said image receiving layer, is kept at a relative humidity of at least 45% in an area of a machine, the said area being ahead of a coating head used for coating said photosensitive layer.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: November 14, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Marcus Jonkheere
  • Patent number: 6120971
    Abstract: There is disclosed an aluminum lithographic printing plate material which comprises an aluminum substrate, a silver halide emulsion layer and a physical development nuclei layer between the aluminum substrate and the silver halide emulsion layer, said silver halide emulsion layer contains photographic gelatin and gelatin having a weight average molecular weight of about 50,000 or less is contained in said silver halide emulsion layer and/or under said layer.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: September 19, 2000
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Motozo Yamano, Kunihiro Nakagawa, Toshiro Kondo
  • Patent number: 6040109
    Abstract: According to the present invention there is provided a method for preparing an imaging element comprising the steps of coating in the order given on a grained and anodized side of an aluminum support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer and (iii) optionally an antistress layer being in water permeable relationship with said image receiving layer comprising unhardened gelatin, characterized in that said aluminum support when being coated with said photosensitive layer is in contact with a guiding roller, heated at a temperature between 35 and 70.degree. C.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: March 21, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Paul Coppens, Marcus Jonckheere
  • Patent number: 6033823
    Abstract: New mutant .beta.-lactam Penicillin G acylases are provided, exhibiting altered substrate specificities. These Penicillin G acylases are obtained by expression of a gene encoding said Penicillin G acylase and having an amino acid sequence which differs at least in one amino acid from the wild-type Penicillin G acylase.
    Type: Grant
    Filed: April 5, 1999
    Date of Patent: March 7, 2000
    Inventors: Jan M. Van Der Laan, Adriana M. Riemens, Wilhelmus J. Quax
  • Patent number: 6017673
    Abstract: A lithographic printing plate that works according to the silver salt diffusion transfer reversal process is disclosed. The lithographic properties of said plate can be improved by incorporating a hydrophilic amphoteric block copolymer, comprising a non-ionic block of acrylic units with pendant nitrile groups and an acrylamid(in)e block which comprises units with pendant basic and acidic groups. The hydrophilic amphoteric block copolymer is preferentially present in the image receiving layer of the lithographic printing plate. In an alternative embodiment, said block copolymer may be present in a treating solution used for processing said plate or applied onto said plate while printing. The hydrophilicity of the printing plate's surface is improved without deteriorating the ink-acceptance in the printing areas.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: January 25, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Vanmaele, Lode Deprez, Frank Louwet
  • Patent number: 5989802
    Abstract: Recording materials and a method of manufacturing said materials by coating hydrophilic colloidal layer compositions on a support by slide-hopper or curtain-coating techniques, followed by drying, said materials comprising a support and one or more light-sensitive and/or heat-sensitive layer(s) having a hydrophilic colloidal coating composition comprising no gelatin(in the case of (photo)thermographic materials) or gelatin in low amounts in order to provide a ratio by weight of gelatin to silver halide expressed as an equivalent amount of silver nitrate in the range from 0.05 to 0.4 (in the case of a light-sensitive silver halide photographic material) and thickening agents composed of synthetic clay and anionic macromolecular polyelectrolytes and wherein said synthetic clay is present in an amount of at least 85% by weight versus a total amount of thickening agents.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: November 23, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Hubert Vandenabeele
  • Patent number: 5885393
    Abstract: A method for forming images by providing a first image formed with silver halide photographic material which has been imagewise exposed and developed according to conventional photographic processes. Thereafter, forming a second image by imagewise transferring ink of a heat fusible thermal transfer ink sheet onto the first image. The surface layer of the ink contacting the layer having the first image contains a resin having a hydrophilic group, the color tone of the second image has the relationships in the CIE coordinate, L*.ltoreq.30, -5.ltoreq.a*.ltoreq.+5 and +0.1.ltoreq.b*.ltoreq.+50, and glossiness measured according to JIS-Z8741-1983 is at least 100. The resulting image is a photographic image with a heat transfer image thereon.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: March 23, 1999
    Assignee: Konica Corporation
    Inventors: Shigeru Mano, Ichiroh Maeda, Shigeo Tanaka
  • Patent number: 5869217
    Abstract: A silver halide photographic material which has a layer containing a swellable inorganic stratifying compound.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: February 9, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiaki Aono
  • Patent number: 5712076
    Abstract: The present invention provides an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei, (ii) a photosensitive layer containing one or more silver halide emulsions being in water permeable relationship with said image receiving layer, characterized in that said one or more silver halide emulsions comprise substantially no silver bromide and that said imaging element comprises on top of said photosensitive layer an antistress layer, being in water permeable relationship with said photosensitive layer and comprising an unhardened gelatin in an amount ranging from 0.60 to 1.75 g/m.sup.2.
    Type: Grant
    Filed: October 29, 1996
    Date of Patent: January 27, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Bartholomeus Van Der Linden, Rene De Keyzer
  • Patent number: 5712077
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the following steps:image-wise exposing with a high intensity-short time exposure with light with a wavelength between 600 nm and 700 nm an imaging element comprising on a support (1) a photosensitive layer comprising at least one photosensitive silver halide emulsion sensitized to light by means of one or more cationic carbocyanine sensitizing dye having a maximum absorption between 600 nm and 700 nm, the silver halide crystals of said silver halide emulsion comprising more than 95 mole % of silver chloride per mole of silver halide and (2) an image receiving layer comprising physical development nuclei in a water permeable relationship with said photosensitive layer,developing said imaging element using an alkaline processing liquid in the presence of (a) developing agent(s) and (a) silver halide solvent(s),characterized in that said silver halide crystals conta
    Type: Grant
    Filed: January 27, 1997
    Date of Patent: January 27, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Lode Deprez, Paul Callant
  • Patent number: 5705311
    Abstract: A heat developable photosensitive image-recording element is described comprising photosensitive silver halide, either as the only source of silver present or in association with a substantially light-insensitive source of silver, a reducing agent, a silver solvent and an image-receiving layer including silver nucleating material. The total amount of silver present is arranged in two adjacent discrete layers, one of which includes the silver reducing agent and the other of which does not. The image-recording element provides an image having significantly increased image density upon exposure and photographic processing.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: January 6, 1998
    Assignee: Polaroid Corporation
    Inventor: Kent M. Young
  • Patent number: 5691104
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the following steps:image-wise exposing with a high intensity-short time exposure an imaging element comprising on a support a photosensitive layer comprising at least one photosensitive silver halide emulsion comprising a heterocyclic compound containing at least one nitrogen atom in the ring and an image receiving layer comprising physical development nuclei in water permeable relationship with said photosensitive layer,developing said imaging element using an alkaline processing liquid in the presence of (a) developing agent(s) and (a) silver halide solvent(s),characterized in that said heterocyclic compound containing at least one nitrogen atom in the ring comprises at least one mercapto- or thione group and one substituent comprising at least 5 carbon atoms selected from the group consisting of linear or branched alkyls, alkenyls, alkynyls, aralkyls and alkyl
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: November 25, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Lode Deprez
  • Patent number: 5672461
    Abstract: The present invention provides an imaging element comprising in the order given on a hydrophilic surface of a support (i) an image receiving layer containing physical development nuclei and (ii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer, characterized in that said photosensitive layer comprises a substituted or unsubstituted 1-phenyl-3-pyrazolidone in an amount between 0.2 mg/g and 15 mg/g of silver halide expressed as an equivalent amount of silver nitrate.
    Type: Grant
    Filed: May 29, 1996
    Date of Patent: September 30, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Paul Coppens, Eric Hoes, Jules Berendsen, Rik Vandenbruwaene
  • Patent number: 5637437
    Abstract: The present invention provides an imaging element comprising on a support in the order given (i) a base layer comprising a binder in an amount between 1 and 3 g/m.sup.2, (it) a photosensitive layer comprising a spectrally sensitised silver halide emulsion, said emulsion consisting principally of silver chloride but containing bromide ranging from 0.1 mole % to 40 mole % and iodide ranging from 0 to 2 mole % and (iii) a receiving layer containing physical development nuclei in water permeable relationship with said photosensitive layer, characterized in that the ratio by weight of gelatin to silver halide (expressed as an equivalent amount of AgNO.sub.3) in said photosensitive layer is at least 1.35.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: June 10, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5620829
    Abstract: The present invention provides a method for making a lithographic printing plate according to the silver salt diffusion transfer process comprising the steps of image-wise exposing an imaging element comprising on a support a photosensitive layer comprising silver halide emulsion(s) wherein less than 1 mole % of the silver halide is silver bromide and an image receiving layer containing physical development nuclei and developing said imaging element using an alkaline processing liquid with a pH lower than 11.5 in the presence of developing agent(s) and a meso-ionic compound.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: April 15, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Lode Deprez
  • Patent number: 5601963
    Abstract: This invention relates to photographic light-sensitive silver halide emulsions wherein the silver grains are spectrally sensitized to near infrared radiation at wavelengths above 700 nm with a particular class of cyanine dyes and to photographic elements and film units employing such emulsions.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: February 11, 1997
    Assignee: Polaroid Corporation
    Inventors: Michael P. Filosa, Zbigniew J. Hinz, Mark T. Spitler
  • Patent number: 5597676
    Abstract: The present invention provides a method for obtaining an imaging element suitable for use in a silver salt diffusion transfer process by the steps of:preparing an image receiving element by coating the anodized surface of an aluminum foil with an image-receiving layer comprising physical development nuclei,preparing a photosensitive layer packet by coating a temporary base with at least one photosensitive silver halide emulsion layer,pressing the thus formed photosensitive layer packet with its photosensitive silver halide emulsion coated side against said image receiving layer, which has been wet with an aqueous moistening liquid, andoptionally removing said temporary base, characterized in that between said temporary base and said at least one photosensitive silver halide emulsion layer a barrier layer is present which is substantially free of developing agents, is substantially unhardened, comprises one or more hydrophilic binders in an amount of at least 0.25 g/m.sup.
    Type: Grant
    Filed: August 17, 1995
    Date of Patent: January 28, 1997
    Assignee: AGFA-Gevaert. N.V.
    Inventors: Ludo Van Rompuy, Paul Coppens
  • Patent number: 5536817
    Abstract: A modified gelatin is disclosed wherein part of the free carboxyl groups is replaced by modifiers having more acid end-standing groups chosen from --SO.sub.3 M, --OSO.sub.3 M, --SSO.sub.3 M, ---OPO(OH).sub.2, --OPO(OH)(OR.sup.2), --PO(OH).sub.2, --PO(OH)(OR.sup.2).In a preferred embodiment such a modified gelatin is incorporated in a DTR photographic material which after processing can serve as a lithographic printing plate. Thanks to the more hydrophilic character of the modified gelatin the differentiation between printing and non-printing areas is improved and toning at printing start-up is reduced.
    Type: Grant
    Filed: August 30, 1995
    Date of Patent: July 16, 1996
    Assignee: AGFA-GEVAERT, N.V.
    Inventors: Eddy Michiels, Piet Kok, Johan Loccufier, Frank Michiels, Ludo Van Rompuy
  • Patent number: 5514517
    Abstract: A process for image formation by silver salt diffusion transfer which comprises developing an imagewise exposed photosensitive element containing a photosensitive silver halide emulsion layer with an alkaline processing element containing a silver halide solvent to thereby convert at least part of the silver halide present in the unexposed area of the emulsion layer into a transferable silver complex and then transferring at least part of the silver complex to an image-receiving element containing an image-receiving layer containing silver-precipitating nuclei to thereby form an image on the image-receiving element, said silver halide emulsion contained in the silver halide emulsion layer in the photosensitive element being a tabular grain emulsion which is obtained by chemically sensitizing tabular silver halide grains and depositing a silver iodobromide having a silver iodide content of from 2 to 15 mol % on the surface of the resulting grains in an amount of from 3 to 20 mol % and which has a total average
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: May 7, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koukichi Waki
  • Patent number: 5512413
    Abstract: The present invention provides an imaging element comprising on the same side of a support in the order given a base layer, a light sensitive layer containing a silver halide emulsion and a surface layer comprising physical development nuclei characterized in that said base layer and/or said light-sensitive layer comprises gelatin being hardened with a divinylsulfonyl hardener such that the time needed to completely brake down said base layer, light sensitive layer and surface layer using an aqueous solution of 0.14% by weight of NaOCl at 25.degree. C. is between 1000s and 1600s. A lithographic printing plate can be obtained with such imaging element according to the silver salt diffusion transfer process and exhibits an improved printing endurance.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: April 30, 1996
    Assignee: AGFA-Gevaert N.V.
    Inventors: Lode Deprez, Eddy Michiels
  • Patent number: 5508142
    Abstract: The present invention provides an imaging element comprising in the order given (i) a hydrophilic base, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion being in water permeable relationship with said image receiving layer, characterized in that said photosensitive layer or another optional layer being in water permeable relationship therewith contains at least one gelatin species whereof a 10% by weight aqueous solution at 36.degree. C. and pH 6 has a viscosity lower than 20 mPa.s at a shearing rate of 1000 s.sup.-1.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: April 16, 1996
    Assignee: AGFA-GEVAERT, N.V.
    Inventors: Paul Coppens, Eric Hoes, Ludovicus Vervloet
  • Patent number: 5501939
    Abstract: The present invention provides a photographic material with a pH at 25.degree. C. of at most 7, containing on a support at least one layer, comprising a prefogged direct-positive silver halide emulsion spectrally sensitized with one or more electron-accepting sensitizing dyes in a total amount of at least 0.15 mmole/mole silver halide, the silver halide crystals of said prefogged direct-positive silver halide emulsion containing silver chloride for at least 60 mole %, silver bromide in a range from 0.5 mole % to 39.98 mole % and silver iodide in a range from 0.02 mole % to 2 mole %, characterized in that said silver halide cristals contain silver iodide for at least 0.20 mmole/mole AgX in the outer 10% by weight of said cristals and said layer contains a gelatin species containing Ca.sup.2+ in an amount ranging from 0.2% to 1% by weight.
    Type: Grant
    Filed: June 13, 1995
    Date of Patent: March 26, 1996
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Paul Coppens
  • Patent number: 5456999
    Abstract: The present invention provides a photographic material comprising a silver halide emulsion layer sensitized to light above 700 nm by means of an infrared sensitizing dye having a maximum absorption between 700 nm and 850 nm characterized in that said silver halide emulsion further comprises a red sensitizing dye of the cationic type having a maximum absorption between 600 nm and 700 nm. The thus obtained photographic material shows an increased sensitivity in the infrared region. The material can be used in as silver salt diffusion transfer process to prepare a lithographic printing plate.
    Type: Grant
    Filed: November 17, 1992
    Date of Patent: October 10, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Jos Vaes, Luc Wabbes
  • Patent number: 5449585
    Abstract: The present invention provides a method for making an offset printing plate according to the silver salt diffusion transfer process having improved printing properties comprising the step of developing an imaging element comprising in the order given (i) a hydrophilic base, (ii) an image receiving layer containing physical development nuclei and (iii) a photosensitive layer containing a silver halide emulsion in the presence of a 1-phenyl-5-mercapto-tetrazole, being substituted by one or two substituents from the group consisting of:(i) a --COOM group with M representing hydrogen, a metal cation, or an ammonium group,(ii) a --SO.sub.3 M.sup.1 group, M.sup.1 representing hydrogen, a metal cation, or an ammonium group,(iii) an acylamido group,(iv) and a substituent containing at least one of the aforementioned substituents (i)-(iv).
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: September 12, 1995
    Assignee: Agfa-Gevaert
    Inventors: Paul Coppens, Ludovicus Vervloet, Eric Hoes
  • Patent number: 5427889
    Abstract: The present invention provides a lithographic printing plate material which comprises a grained and anodized aluminum support and a silver halide emulsion layer between which physical development nuclei are provided wherein said aluminum support have 500 or more pits having a diameter of 0.03-0.30 .mu.m and an average diameter of 0.05-0.20 .mu.m per 100 .mu.m.sup.2.
    Type: Grant
    Filed: August 12, 1994
    Date of Patent: June 27, 1995
    Assignee: Mitsubishi Paper Mills Ltd.
    Inventors: Masahiko Saikawa, Akira Kaneko, Keisuke Iguchi, Akio Yoshida, Yutaka Araki, Takenobu Yoshiki
  • Patent number: 5413897
    Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.
    Type: Grant
    Filed: May 4, 1994
    Date of Patent: May 9, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
  • Patent number: 5364734
    Abstract: A positive-working radiation-sensitive mixture is disclosed that contains(a) a compound that forms strong acid on exposure to actinic radiation that is an ester of a sulfonic acid or sulfonic acids of the formula R--SO.sub.3 H or R'(--SO.sub.3 H).sub.2 with 2,4-bistrichloromethyl-6-(mono- or dihydroxyphenyl)-1,3,5-triazine of the formulae I and/or II: ##STR1## where R is an optionally further substituted (C.sub.1 -C.sub.10) alkyl, (C.sub.5 -C.sub.10)cycloalkyl, (C.sub.6 -C.sub.10)aryl, (C.sub.6 -C.sub.10)aryl- (C.sub.1 -C.sub.10) alkyl or (C.sub.3 -C.sub.9)heteroaryl radical, R' is an optionally substituted (C.sub.1 -C.sub.10)alkylene, (C.sub.6 -C.sub.10)arylene or (C.sub.3 -C.sub.9)heteroarylene radical, and n is 1 or 2,(b) a compound that contains at least one acid-cleavable C--O--C or C--O--Si bond, and(c) a water-insoluble polymeric binder that is soluble or at least swellable in aqueous alkaline solutions.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: November 15, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Georg Pawlowski, Horst Roeschert, Walter Spiess, Klaus-Juergen Przybilla
  • Patent number: 5362620
    Abstract: The present invention discloses a photographic material comprising on a support a photosensitive layer containing a mixture of silver halide emulsions at least one of which is spectrally sensitized and at least one of which is not spectrally sensitized characterized in that the surface of the silver halide particles of the silver halide emulsion not being spectrally sensitized is loaded with a stabilizer having a mercapto group or the tautomeric thione group thereof such that the surface covered by one molecule of stabilizer is between 10 .ANG..sup.2 and 70 .ANG..sup.2. The loss of speed due to migration of the spectral sensitizer from the sensitized emulsion to the non sensitized emulsion is reduced and can even be inhibited.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: November 8, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Johan Lamotte, Jean-Marie Dewanckele
  • Patent number: 5348836
    Abstract: The present invention provides a photographic material comprising on a support photosensitive silver halide particles, and substantially light insensitive silver salt particles having a speed at least a factor 10 less under the same conditions of exposure and development of said photosensitive silver halide particles than said photosensitive silver halide particles and a releasing compound of formula (I) or (II) as specified in the claims capable of image-wise releasing sulphide or a sulphide under conditions for image-wise development of said photosensitive silver halide particles to silver. The present invention further provides a method for obtaining an image and a lithographic printing plate with said photographic material.
    Type: Grant
    Filed: April 22, 1993
    Date of Patent: September 20, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo Van Rompuy, Jean-Marie Dewanckele
  • Patent number: 5340692
    Abstract: The present invention provides an image receiving material comprising on a support an image receiving layer containing physical development nuclei characterised in that said image receiving material contains a nacreous pigment in said image receiving layer and/or in an optional layer between said support and said image receiving layer. Excellent contone images with an antique look can be obtained with such an image receiving material in a silver salt diffusion transfer process.
    Type: Grant
    Filed: September 13, 1993
    Date of Patent: August 23, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Leon Vermeulen, Robert Pauwels
  • Patent number: 5326668
    Abstract: A method of image formation disclosed, which comprises a method of image formation comprising developing a photosensitive element comprising an image-wise exposed photosensitive silver halide emulsion layer using an alkaline processing element containing a silver halide solvent to convert at least a part of the unexposed silver halide in the emulsion layer to a transferrable silver complex salt, and transferring at least a portion of the silver complex salt onto an image-receiving element comprising an image-receiving layer containing silver precipitation nuclei to form an image in the image-receiving element, wherein the silver halide grain in the photosensitive silver halide emulsion layer comprises silver iodobromide or silver chloroiodobromide having a silver iodide content of from 0.5 to 3.5 mol %; and wherein silver bromide or silver iodobromide is formed after chemical sensitization on the surface of the grains in an amount of from 3 to 20% in terms of silver.
    Type: Grant
    Filed: March 25, 1993
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koukichi Waki
  • Patent number: 5324622
    Abstract: The present invention provides a photographic material comprising on a support (i) photosensitive silver halide particles, (ii) substantially light insensitive silver salt particles having a speed at least a factor 10 less than said photosensitive silver halide particles under the same conditions of exposure and development of said photosensitive silver halide particles and (iii) a releasing compound capable of image-wise releasing under the conditions for image-wise development of said photosensitive silver halide to silver a chemical sensitizer, said chemical sensitizer rendering said substantially light insensitive silver salt particles developable. The present invention also provides a method for making an image therewith and a method for making a lithographic printing plate.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: June 28, 1994
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Ludo L. Van Rompuy, Jean-Marie O. Dewanckele, Jos A. Vaes, Marcel J. Monbaliu
  • Patent number: 5322759
    Abstract: A photographic donor material useful in forming continuous tone images in a silver salt diffusion transfer process is comprised of a support; a photosensitive silver halide emulsion layer in which the silver halide is at least 80% silver chloride and is substantially free of iodide; and, located between the photosensitive silver halide emulsion layer and the support, a silver halide emulsion layer which is non-photosensitive under the conditions in which the donor material is used.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: June 21, 1994
    Assignee: Eastman Kodak Company
    Inventors: Anthony M. Barnett, David A. Hallbery, Roger J. Owers
  • Patent number: 5308738
    Abstract: The present invention provides a photographic material comprising on a support an image-receiving layer containing physical development nuclei, a photosensitive silver halide emulsion layer and a substantially light insensitive layer containing silver salt characterized in that said photosensitive silver halide emulsion layer contains silver halide particles having an average diameter of at least 0.6 .mu.m, said photosensitive silver halide emulsion layer being located between said image-receiving layer and said substantially light insensitive layer and said substantially light insensitive layer having a speed of at least a factor 10 less than said photosensitive silver halide emulsion layer. The present invention also provides a method for making an image therewith. The photographic material of the present invention is of high speed and can yield direct positive image with a low density in the non-image areas.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: May 3, 1994
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Rene M. De Keyzer, Johan J. Lamotte
  • Patent number: 5290661
    Abstract: A method for sorting images by silver salt diffusion transfer comprisingimagewise exposing a light-sensitive element comprising a light-sensitive silver halide emulsion layer,developing the light-sensitive element in the presence of a silver halide solvent using an alkaline processing composition to turn at least a part of unexposed silver halide of the light-sensitive silver halide emulsion layer into a transfer silver halide complex salt, andtransferring at least a part of the silver halide complex salt to an image receiving layer comprising a silver precipitating agent to form images on the image receiving layer,wherein at least one compound represented by formula (I) is added to at least one of the light-sensitive element, an image receiving element comprising the image receiving layer, and the processing composition in an amount of at least 1.times.10.sup.-6 and less than 1.times.10.sup.-2 mol based on one mol of silver applied per unit area (m.sup.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: March 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Idota, Makoto Ishihara, Morio Yagihara