Abstract: This invention describes compositions and methods of using non-covalently crosslinked resin coatings for lithographic applications. These materials are designed to undergo, after coating, a change that provides solvent resistance and, with some materials, simultaneous aqueous-base solubility. Non-covalent interactions allow for easier removal of these coatings than of covalently crosslinked materials. These types of materials are well-suited for trench and gap fill applications, as well as for anti-reflective coatings, spin-on carbon layers, and etch masks.

Abstract: A self-developing diffusion transfer photographic film unit which includes a latent image which becomes visible upon photographic processing of the film unit. The latent image is formed with a chemical compound such as an indicator dye and the visible image formed from the latent image as a result of photographic processing may be transient or permanent. Also described are diffusion transfer photographic methods.

Abstract: A self-developing diffusion transfer photographic film unit which includes a latent image which becomes visible upon photographic processing of the film unit. The latent image is formed with a chemical compound such as an indicator dye and the visible image formed from the latent image as a result of photographic processing may be transient or permanent. Also described are diffusion transfer photographic methods.

Abstract: There is disclosed a novel color-developing agent of a 1,2,4-thiadiazol-5-yl hydrazine type. There is also disclosed a silver halide photographic light-sensitive material which gives sufficient color formation by development and forms an image excellent in image quality and image storability, by using the color-developing agent. Further, there is disclosed an image-forming method using the light-sensitive material.

Abstract: A color imaging element comprising a dye formed upon a reaction of an oxidation product of a compound represented by formula (I) shown below together with at least one water-soluble compound represented by formula (II) shown below on a support: wherein Z represents a carbamoyl group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfonyl group or a sulfamoyl group; and Q represents an atomic group necessary for forming an unsaturated ring together with the carbon atom; wherein X represents a hydrogen atom, a hydroxy group, an aliphatic group, an acyl group, an aliphatic oxy group, an aliphatic oxycarbonyl group or an aryloxycarbonyl group; Y1 and Y2, which may be the same or different, each represents a hydrogen atom or a substituent, or Y1 and Y2 may be combined with each other to form a 5-membered or 6-membered ring; Z1 represents a simple bond, a methylene group which may be substituted or an ethylene group which may be substituted; Z2 represents a

Abstract: There is disclosed a silver halide color photographic light-sensitive material having at least one photographic constitutional layer coated on a support, wherein at least one of the photographic constitutional layers contains at least one reducing agent for color formation represented by formula (I), at least one coupler for forming a diffusive dye, and at least one mordant. The material is capable of reducing the amount of developer and to be replenished or discharged after processing, and of reducing the occurrence of stain after development during storage of the material. There is also disclosed an image-forming method using the material. ##STR1## wherein C.alpha. represents a carbon atom; Z represents a carbamoyl, acyl, alkoxycarbonyl, or aryloxycarbonyl group; and Q represents a group of atoms to form, together with C.alpha., an unsaturated ring.

Abstract: There are described image-recording materials which include an image dye-providing compound comprising a novel naphthol azo cyan dye having a 3-aminobenzoisothiazole moiety. The image dye-providing compound includes a diffusion control moiety such as a hydroquinonyl developer group, a precursor thereof or a thiazolidine moiety and, may be diffusible or nondiffusible as a function of the diffusion control moiety.Image-recording materials according to the invention including those which contain high potential developers such as aminoreductone allow sufficient cyan chromophore to diffuse to the image-receiving layer to provide an acceptable photograph and result in no appreciable reduction of the 3-aminobenzoisothiazole moiety of the novel naphthol azo cyan dye.

Abstract: (1) Dicyanoimidazole compound derivative represented by the formula [I] ##STR1## [R.sup.1, R.sup.2 : alkyl group, alkoxyalkyl group, hydroxyalkyl group, .beta.-cyanoethyl group, .beta.-chloroethyl group, aralkyl group, aryl group; X: hydrogen atom, lower alkoxy group, methyl group, halogen atom; Y: hydrogen atom, methyl group, methoxy group, formylamino group, alkylcarbonylamino group, alkylsulfonylamino group, alkoxycarbonylamino group; --Q--: --(CR.sub.2).sub.n --[n: integer of 1 to 12, R: hydrogen atom, alkyl group], ##STR2## --CH.dbd.CH--, --CH.sub.2 CH.dbd.CHCH.sub.2 --, --CH.sub.2 --CH.dbd.CH--]. (2) Magenta toner for color electrophotography containing at least one kind of the dicyanoimidazole compound derivative represented by the formula [I] as a coloring agent.(3) Colored resin and resin color filter containing at least one kind of the dicyanoimidazole compound derivative represented by the formula [I] in solution.

Abstract: A color image forming method comprises bringing a developer into contact with a recording material comprising a support and a recording layer containing at least two kinds of leuco dyes being capable of forming colors different in hue from each other on contact with the developer. The leuco dyes are a yellow color forming leuco dye, a magenta color forming leuco dye and/or a cyan color forming leuco dye. The equilibrium constants of the reactions between these dyes contained in the recording layer and the developer are not lower than 0.05.

Abstract: A color photosensitive material and a process for producing an image using such a material are disclosed. The color photosensitive material comprises a support having thereon a silver halide and a dye releasing compound represented by formula (A). ##STR1## wherein Ar and Ar', which may be the same or different, each represents an aromatic group or a heterocyclic group, Ar and Ar' may be joined together to form a ring, and R represents an aromatic group, a heterocyclic group or a sulfonyl group.

Abstract: Dye releasing compounds which release dyes corresponding to formula I ##STR1## wherein R.sup.1 denotes alkyl, aryl, arylamino, alkoxy or aryloxy,R.sup.2 denotes H or halogen,R.sup.3 denotes alkyl with 2-4 carbon atoms,R.sup.4 denotes H or one or more substituents such as alkyl, alkoxy, acylamino or halogen, including a substituent in the ortho-position to the group ##STR2## which together with R.sup.5 completes a cyclic amino group, R.sup.5 denotes alkyl with up to 4 carbon atoms or a group which together with a subsituent denoted by R.sup.4 or together with R.sup.6 completes a cyclic amino group, andR.sup.6 denotes alkyl with up to 4 carbon atoms or a group which together with R.sup.5 completes a cyclic amino groupare suitable for the production of light-stable cyan colour images.

Abstract: Color correction of negative images resulting from diffusion transfer photographic recording materials is obtained through use of two dye image-providing compounds, each of which is capable of releasing a diffusible dye. One of the dye image-providing compounds releases a diffusible dye as a result of silver halide development whereas the other compound releases dye in areas where no development occurs.

Abstract: Metal complexes, particularly copper and nickel complexes of azo dyes corresponding to general formula (I) are suitable as color dyes for the production of color images by the dye diffusion transfer process. The dyes are (in non-metallized form), in the form of so-called "dye-releasers", bound to a redox-active carrier radical provided with a ballast group, which dye-releasers are associated to a light-sensitive silver halide emulsion layer. During development, the metallizable dyes are image-wise released and are converted, after diffusion into a light-receiving layer, into the corresponding metal complexes ##STR1## wherein E represents an electron acceptor radical; andK represents the radical of an azo coupler component, derived from an open-chain or closed ring ketomethylene compound, a cyclic enamine compound or a phenolic compound.

Abstract: Dyes corresponding to formula I may be released imagewise from dye releasers in the dye diffusion transfer process. The dyes obtained are lightfast cyan dyes with improved spectral properties and reduced sensitivity to reducing agents ##STR1## the meanings of symbols given in formula I (A, A', G, R.sup.1, R.sup.2, R.sup.3 and R.sup.4) are indicated in the description.

Abstract: Photographic products and processes for the imagewise generation of a dye from a color shifted dye precursor of a preformed image dye, said precursor having at least one ##STR1## group, wherein R is hydrogen, alkyl, provided that the .alpha.- carbon does not have a hydrogen atom attached thereto, aryl such as phenyl or substituted phenyl, e.g. p-nitrophenyl, or heterocyclic such as pyridine; R.sub.1 -R.sub.6 are hydrogen, alkyl, preferably having from 1 to 6 carbon atoms, or aryl; n is 0 or 1; and T is a moiety containing a thiazolidin-2-yl group which upon silver-assisted cleavage of said thiazolidin-2-yl group results in the formation of a ##STR2## group, which may be protonated under the reaction conditions, followed by cleavage of said ##STR3## which cleavage is anchimerically assisted or accelerated by said ##STR4## to provide after protonation, an ##STR5## group in a dye chromophore. In a preferred embodiment the precursor is a substantially colorless compound.

Abstract: Azo dyes corresponding to the formula (II): ##STR1## wherein G represents a group capable of forming a 5-membered chelate ring and R.sup.5 represents aryl or a thienyl group, combined with metal ions, in particular copper or nickel ions, to form stable azo dye-metal complexes which have advantageous spectral properties. They are therefore particularly suitable for the production of highly light-fast cyan images, e.g. by the Ink-Jet process, in which they may be used directly in the form of colored inks, or by the dye diffusion transfer process, in which they are released image-wise from corresponding dye-releasers in the course of development and transferred to a dye-absorbent layer.

Abstract: Monoazo dyes corresponding to the following formula ##STR1## are suitable for use as light-stable cyan image dyes stable to reducing agents for the dye diffusion transfer process.In the above formula:Q represents the remainder of the molecule required to complete a fused benzene or thiophene ring, which contains additional electron acceptor groups, or to complete a fused pyridine, pyrimidine, pyridazine, pyrazine or thiazole ring;G represents --OH, acyloxy;R.sup.1 represents H or one or two identical or different radicals selected from the group consisting of halogen, acyl, acylamino and --CN;Y represents H, --OH, an amino group optionally substituted by alkyl or aryl, a cyclic amino group or a group of the formula --NH--SO.sub.2 --R.sup.2 ;R.sup.2 represents alkyl, aryl, an amino group optionally substituted twice by alkyl or a cyclic amino group;n=0, 1 or 2.

Abstract: Azo dyes corresponding to the formula (I): ##STR1## wherein R.sup.1 represents a releasable group, R.sup.2 represents H, halogen or sulphonyl, R.sup.3 and R.sup.4 represent H or groups not capable of chelate formation, and Q represents a group for completing a phenyl or naphthyl group,combine with nickel ions to form stable azo dye-metal complexes which have advantageous spectral properties. They are therefore particularly suitable for the production of highly light-fast magenta images, e.g. by the ink jet process, in which they may be used directly in the form of colored inks, or by the dye diffusion transfer process, in which they are released imagewise from suitable dye-releasers in the course of development and transferred to a dye-receptive layer.

Abstract: A photographic light-sensitive element having at least one light-sensitive silver halide layer and a dye image forming non-diffusible material which, upon a redox reaction under alkaline conditions releases a diffusible cyan dye or precursor thereof wherein said material is ##STR1## wherein Car represents a carrier component having at least on Ball group as a part thereof which alone or together with other such groups in said Car renders said compound non-diffusible during development in alkaline processing solution, said Car being capable of releasing from said compound a diffusible dye or the precursor thereof as the result of a redox reaction under alkaline conditions:R represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms;R.sup.1 is ##STR2## wherein R.sup.2 and R.sup.3 are independently selected from a hydrogen atom, or an alkyl, a cycloalkyl or an aryl group having from 1 to 30 carbon atoms, and R.sup.2 and R.sup.

Abstract: In a photographic material suitable as image receptor element for the dye diffusion transfer process, a dye absorbent layer arranged on a layer support contains nickel chelates or copper-II chelates of a compound corresponding to the following general formula I as metallizing agents for the formation of colored complexes from colorless or colored organic complex formers. The chelatable image dyes transferred imagewise to the dye adsorbent layer in the course of development give rise to the corresponding nickel or copper-II complexes with improved light stability. ##STR1## wherein R.sup.1 represents a hydrocarbon group having up to 30 carbon atoms optionally interrupted by --O--;R.sup.2, R.sup.3 represents H, alkyl having up to 5 carbon atoms or aryl having from 6 to 10 carbon atoms; andR.sup.4, R.sup.4' represents alkyl or alkoxy having from 1 to 4 carbon atoms, aralkyl or OH.

Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety comprising a 1,3-sulfur-nitrogen group, said 1,3-sulfur-nitrogen group (a) being capable of undergoing cleavage in the presence of silver ion and/or soluble silver complex, and (b) possessing an amide substituent on the carbon atom in the 2-position that undergoes an intramolecularly accelerated cleavage reaction following the cleavage of said 1,3-sulfur-nitrogen group, which moiety maintains said precursor in its colorless form at least until the 1,3-sulfur-nitrogen group undergoes said cleavage. In a further embodiment, the cleavage of the amide substituent following the cleavage of the 1,3-sulfur-nitrogen group is used to provide an imagewise distribution of a photographically useful reagent, which reagent may be, for example, a photographically active reagent.

Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety comprising a 1,3-sulfur-nitrogen group that undergoes cleavage in the presence of silver ion and/or soluble silver complex, which moiety maintains said precursor in its colorless form at least until the 1,3-sulfur-nitrogen group undergoes cleavage imagewise to correspond to the imagewise distribution of silver ion and/or soluble silver complex made available as a function of development.

Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety containing a thiazolidinyl group, said thiazolidinyl group (a) being capable of undergoing cleavage imagewise in the presence of an imagewise distribution of silver ion and/or soluble silver complex and (b) possessing a substituent on the carbon atom in the 2-position which upon cleavage of said thiazolidinyl group, undergoes a .beta.-elimination reaction followed by an intramolecularly accelerated nucleophilic displacement reaction, which moiety maintains the precursor in its colorless form at least until said thiazolidinyl group undergoes said cleavage. In a further embodiment, this sequence of reactions is used to release an imagewise distribution of a photographically useful reagent which reagent may be, for example, a photographically active reagent.

Abstract: This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety containing a thiazolidinyl group, said thiazolidinyl group (a) being capable of undergoing cleavage imagewise in the presence of an imagewise distribution of silver ion and/or soluble silver complex and (b) possessing a substituent on the carbon atom in the 2-position that undergoes a .beta.-elimination reaction upon said imagewise cleavage, which moiety maintains the precursor in its colorless form at least until said thiazolidinyl group undergoes said cleavage. In a further embodiment, an imagewise distribution of a photographically useful reagent, which reagent may be, for example, a photographically active reagent, is released as a carbamic acid by a .beta.-elimination reaction following the cleavage of a thiazolidinyl group whereby said reagent is provided with a solubilizing group at least during the initial stages of processing.

Abstract: A method for the formation of a color photographic image comprising exposure and development of a photographic element, said photographic element comprising at least one silver halide emulsion layer, a compound capable of releasing a diffusible azo dye compound during development, and at least one mordant layer arranged on a support. The color image formation is effected by the reaction of multivalent metallic ions with an azo dye compound having the formula: ##STR1## wherein G.sup.1 is an alkoxy or a thioalkoxy metallic chelating group; G.sup.2 is a metallic chelating group in which an oxygen atom is involved in the chelate formation; and Z.sup.1 and Z.sup.2 each is a group of atoms necessary to form an aromatic carbocyclic ring or a heterocyclic ring. The azo dye compound and the metallic ions form a metal complex by coordination of the azo group and the G.sup.1 and G.sup.2 groups of the azo dye compound with the multivalent metallic ions.

Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible magenta dye moiety comprising a 4-(2-heterocyclylazo)phenol having a heterocyclic ring fused thereto, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered heterocyclic ring;(b) Y represents the atoms necessary to complete a 5- or 6-membered heterocyclic fused ring;(c) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(d) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.

Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound capable of releasing at least one diffusible cyan dye moiety comprising a 6-heterocyclylazo-3-pyridinol, the compound having the formula: ##STR1## wherein: (a) Y represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) CAR represents a ballasted carrier moiety capable of releasing the diffusible cyan dye moiety as a function of development of a silver halide emulsion layer under alkaline conditions;(c) R represents a hydroxy group, a salt thereof, or a hydrolyzable precursor thereof, or CAR which is linked to the dye moiety through an oxygen atom thereon; and(d) n is 0, 1 or 2 with the proviso that when n is 0, then R is CAR which is linked to the dye moiety through an oxygen atom thereon.

Abstract: Photographic elements, diffusion transfer assemblages, coordination complexes and processes are described which employ a novel nondiffusible compound having a releasable yellow dye moiety or precursor thereof, the compound having the formula: ##STR1## wherein: (a) X represents the atoms necessary to complete a 5- or 6-membered aromatic heterocyclic fused ring;(b) Z represents alkyl, substituted alkyl, aryl or substituted aryl;(c) R represents CN or J--L;(d) J represents a bivalent ##STR2## group; (e) L represents alkyl, substituted alkyl, aryl, substituted aryl, or can be taken together with Z to complete a carbonyl-containing 5- or 6-membered heterocyclic or carbocyclic ring;(f) Z.sup.

Abstract: Photographic elements, multicolor filters and receivers are disclosed having supports providing microvessels for materials such as radiation-sensitive materials, imaging materials, mordants, silver precipitating agents and materials which are useful in conjunction with these materials. Processes of forming microvessels and introducing materials therein are also disclosed. Processes of forming images are disclosed employing microvessel containing elements. Image transfer processes are disclosed for producing one or a combination of silver and multicolor subtractive primary images alone or in combination with multicolor additive primary images.

Abstract: Diffusion transfer photographic color processes and products are described utilizing novel image dye-providing materials which provide image dyes having the chromophoric system represented by the formula ##STR1## wherein X is ##STR2## or --SO.sub.2 --R.sub.1 ; Z is H, alkyl or aryl; R is H, alkyl or aryl; DYE is any dye moiety; R.sub.1 is H, alkyl, aryl, --NH.sub.2, --NHR.sub.2, --N(R.sub.2).sub.2 or --OR.sub.2 ; R.sub.2 is H, alkyl or aryl; and m is 1 or 2. The image dye providing material includes a diffusion control moiety such as a hydroquinonyl group or a precursor thereof and may be diffusible or nondiffusible as a function of the diffusion control moiety.

Abstract: Sulfilimine compounds of formula I ##STR1## in which R.sup.3 is the residue of a diffusible photographically active compound can be split reductively to release the residue together with a group --SO.sub.2 --NH.sub.2. When R.sup.3 represents the radical of a dye or dye precursor the sulfilimines are useful as color providing compounds in dye diffusion transfer processes.

Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable, 2-(2-pyridylazo)-4,5-bis(tertiary amino)phenol black dye moiety or precursor thereof, such as: ##STR1## wherein: (a) R represents hydrogen, a hydrolyzable moiety or CAR;(b) R.sup.1 and R.sup.2 each independently represents an alkyl group of 1 to about 6 carbon atoms, CAR, or can be taken together with the nitrogen atom to which they are attached to complete a 5- or 6-membered heterocyclic ring;(c) R.sup.3 and R.sup.4 each independently represents an alkyl group of 1 to about 6 carbon atoms, CAR, or can be taken together with the nitrogen to which they are attached to complete a 5- or 6-membered heterocyclic ring;(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible black dye moiety or precursor thereof under alkaline conditions; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then at least one of R, R.sup.1, R.sup.2, R.sup.

Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable, pyridylazo(dialkylamino)phenol magenta dye moiety or precursor thereof, having the formula: ##STR1## wherein: (a) R represents hydrogen, a hydrolyzable moiety, or may be taken together with the NHSO.sub.2 group to which it is attached to form CAR;(b) R.sup.1 represents hydrogen, a hydrolyzable moiety or CAR;(c) R.sup.2 and R.sup.3 each independently represents hydrogen, CAR, an alkyl group of 1 to about 6 carbon atoms, or they can be taken together with the nitrogen to which they are attached to form a 5- or 6-membered heterocyclic ring, or one of R.sup.2 and R.sup.3 can be an aryl group having from 6 to about 10 carbon atoms; and(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible magenta dye moiety or precursor thereof under alkaline conditions;with the proviso that at least one of R, R.sup.1, R.sup.2 and R.sup.3 is CAR.

Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable, bridged, azoaminophenol magenta dye moiety or precursor thereof having the formula: ##STR1## wherein: (a) R represents hydrogen, a hydrolyzable moiety or CAR;(b) R.sup.1 represents hydrogen;(c) R.sup.2 represents an alkyl group of 1 to about 6 carbon atoms or CAR; or R.sup.1 and R.sup.2 represent an alkylene group which can be taken together with the atoms to which they are attached to complete a 5- or 6-membered heterocyclic ring;(d) R.sup.3 represents an alkyl group of 1 to about 6 carbon atoms or CAR;(e) R.sup.4 represents hydrogen; or R.sup.3 and R.sup.

Abstract: A process for the production of a photographic image which comprises(a) imagewise exposing a photographic assembly which comprises at least during a silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a layer substantive hydroxypyridone azamethine compound of the general formula ##STR1## wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl, amino or heterocyclic radical, Y represents hydrogen or hydroxy, --CN, --COOR.sup.1, --CONR.sup.1 R.sup.2 or --COR.sup.1 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical and Z is hydrogen or is --CN, --COOR.sup.3, --CONR.sup.3 R.sup.4, --SO.sub.3 H, --SO.sub.3.sup.- or --COR.sup.3, where R.sup.1, R.sup.2, R.sup.3 and R.sup.

Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable 6-(2-thienylazo)-3-pyridinol cyan dye moiety or precursor thereof, the compound containing:(a) in the 3-position of the thienylazo moiety a carboxy group, a salt thereof or a hydrolyzable precursor thereof; and(b) a ballasted carrier moiety which is capable of releasing the diffusible 6-(2-thienylazo)-3-pyridinol dye moiety or precursor thereof under alkaline conditions.

Abstract: A new method to produce photographic images is provided which comprises:(a) imagewise exposing a photographic assembly which contains at least during the silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a substantive azamethine compound and a photobase, there being optionally one or more interlayers between each of said components(b) treating the exposed photographic assembly with an aqueous processing bath so as to provide in the silver halide emulsion layer or layers a solution or dispersion of a bleach developer compound, thereby to develop the latent silver image in the silver halide emulsion(s), and(c) in the non-latent image areas allowing the bleach developer compound to diffuse in a counter-imagewise manner from the silver halide emulsion layer (s) to the layer containing substantive azamethine compound and there to bleach the compound to form a dye image.

Abstract: A color photographic material and a method of forming a color photographic image which utilizes a 5-pyrazolone magenta coupler shown by the following general formula (I): ##STR1## wherein R represents an acylamino group, an anilino group or a ureido group; R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an alkoxy group, an aryloxy group, a carboxy group, an aryl group or a heterocyclic group (which groups may be substituted) and R.sub. and R.sub.2 may combine to form a 2-indazolyl group, provided that R.sub.1, R.sub.2 and R.sub.3 are not hydrogen atoms at the same time; and Ar represents a phenyl group which may be substituted with one or more halogen atoms, alkyl groups, alkoxy groups or cyano groups.

Abstract: Photographic elements, diffusion transfer assemblages and processes are described which employ a novel nondiffusible compound having a releasable 6-arylazo-3-pyridinol magenta dye moiety or precursor thereof having the formula: ##STR1## wherein: (a) R represents hydroxy or amino;(b) R.sup.1 represents hydrogen, a hydrolyzable moiety or CAR;(c) G represents carboxy; a hydrolyzable ester or a sulfamoyl group;(d) CAR represents a ballasted carrier moiety capable of releasing the diffusible 6-arylazo-3-pyridinol dye moiety or precursor thereof under alkaline conditions; and(e) n is 0, 1 or 2, with the proviso that when n is 0, then R.sup.1 is CAR.

Abstract: Novel electron donor precursors have the structure: ##STR1## where: R is an alkali labile group;Y is an aliphatic or aromatic group; andZ is an electron withdrawing group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.

Abstract: A new method to produce photographic images is provided which comprises(a) imagewise exposing a photographic assembly which contains at least during the silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a modifiable image substance and a photobase, there being optionally one or more interlayers between each of said components(b) treating the exposed photographic assembly with an aqueous processing bath so as to provide in the silver halide emulsion layer or layers a solution or dispersion of an image substance modifying/silver halide developing compound (dymodev compound), thereby to develop the latent silver image in the silver halide emulsion(s), and(c) in the non-latent image areas allowing the dymodev compound to diffuse in a counter-imagewise manner from the silver halide emulsion layer(s) to the layer containing the modifiable image substance and there to modify reductively the image substance.

Abstract: Diffusion transfer color processes and products are disclosed employing image-dye providing materials providing magenta image dyes having the chromophoric system represented by the formula ##STR1## wherein each R is the same or different and is an alkyl group, and each X is the same or different and is hydrogen or an alkyl group (including substituted alkyl). The dye image-providing material includes a diffusion control moiety, such as a hydroquinonyl group, and may be diffusible or nondiffusible as a function of the diffusion control moiety.

Abstract: Novel electron donor precursors have the structure: ##STR1## wherein: Z represents the atoms to complete a mono-, bi- or tricyclic ring system, each ring of which contains 5 to 6 nuclear atoms;n is 1 or 2;R.sup.1 is a monovalent aromatic group when n is 1 and a bivalent aromatic group when n is 2; andR.sup.2 represents hydrogen, an alkyl group, an aryl group, an acyl group, an ester group or an amido group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.

Abstract: For the production of cyan and magenta images by the dye diffusion transfer process dye-providing compounds of the formula I are suitable ##STR1## in which A=an oxydizable carrier residue containing a diffusion-preventing radical;n= 0 or 1;P=a monocyclic aromatic radical;M=hydrogen, halogen, alkyl sulfonyl, aryl sulfonyl or sulfamoyl;Q=acylamino;R.sup.1 =hydrogen or a hydrolyzable radical.

Abstract: A photographic element comprising a support, a layer containing an image dye ligand or dye ligand forming material and a layer containing a dye mordant, wherein the mordant layer has associated therewith:(1) a polymer containing groups which form coordination complexes with metal ions; and(2) a source of metal ions.The polymer holds the metal ions in the vicinity of the dye mordant so that the metal ions can metallize the dye or dye forming material at the image receiving layer. These complexes, elements, and receiving elements are particularly useful in diffusion transfer processes. Novel polymers are also described.

Abstract: Shifted photographic dyes which have good storage stability, yet rapidly unblock under processing conditions contain a blocked hydroxy group and a neighboring group that anchimerically assists the hydrolytic cleavage of the blocking group under processing conditions.