Hydroxylamine Patents (Class 430/250)
  • Patent number: 7022441
    Abstract: Silver-free, aqueous-based direct thermographic materials are designed to have image tone with near neutral density. Without the use of organic silver salts containing reducible silver ions, the image is formed using a color developing agent precursor that releases a color developing agent when heated to a temperature of at least 80° C., a combination of cyan, yellow and magenta dye-forming color couplers that provide cyan, yellow, and magenta dyes, and a substituted or unsubstituted benzoquinone as an oxidizing agent. No silver metal or silver ions are purposely added to these materials. This combination of components provides a means for controlling image tone without reliance upon conventional toning agents.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: April 4, 2006
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, Victor P. Scaccia
  • Patent number: 6962763
    Abstract: Silver-free, aqueous-based direct thermographic materials are designed to have image tone with near neutral density. Without the use of organic silver salts containing reducible silver ions, the image is formed using a color developing agent precursor that releases a color developing agent when heated to a temperature of at least 80° C., a combination of cyan, yellow and magenta dye-forming color couplers that provide cyan, yellow, and magenta dyes, and a hindered-amine N-oxyl as an oxidizing agent. No silver metal or silver ions are purposely added to these materials. This combination of components provides a means for controlling image tone without reliance upon conventional toning agents.
    Type: Grant
    Filed: February 25, 2004
    Date of Patent: November 8, 2005
    Assignee: Eastman Kodak Company
    Inventors: Joe E. Maskasky, Victor P. Scaccia
  • Patent number: 6726982
    Abstract: Thermal transfer articles of the invention comprising a carrier, optionally a release layer, a color layer releasably adhered thereto, and optionally an adherence layer on the bottom side of the color layer. Also graphic imaging compositions and methods for thermal transfer using such articles and compositions and graphic articles made by such methods. The transfer articles 1) exhibit thermoplastic, low cohesive properties during transfer such that good image resolution and transfer is achieved and 2) are radiation crosslinked after transfer such that a durable image is formed.
    Type: Grant
    Filed: January 9, 2001
    Date of Patent: April 27, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Paul D. Christian, Nancy H. Phillips
  • Patent number: 6057090
    Abstract: A silver halide photographic material is described, which contains the compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents a substituted or unsubstituted alkylene group having from 1 to 5 carbon atoms; X represents a water-soluble group; and R.sup.2 represents a substituted or unsubstituted alkyl group having the sum total of from 14 to 40 carbon atoms, an alkenyl group, an aryl group, an alkoxyl group, --NR.sup.3 R.sup.4 (R.sup.3 and R.sup.4 each independently represents an alkyl group having from 1 to 40 carbon atoms, a hydrogen atom, or an aryl group), a bicycloalkyl group, a bicycloalkenyl group, a cycloalkyl group, a cycloalkenyl group or a heterocyclic group, provided that when X represents a quaternary ammonium salt structure, R.sup.2 does not represent an alkyl group having from 14 to 17 carbon atoms.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: May 2, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Mikoshiba, Mamoru Sakurazawa, Masakazu Morigaki
  • Patent number: 6031130
    Abstract: A method for preparing N,N-disubstituted hydroxylamine compounds represented by the formula (II): HO--N(R.sup.1)(R.sup.2) wherein R.sup.1 and R.sup.2 may be the same or different, and independently represent a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aromatic heterocyclic group, which comprises the step of adding a rhenium catalyst and aqueous hydrogen peroxide to a mixture containing a secondary amine compound represented by the formula (I): HN(R.sup.1)(R.sup.2) wherein R.sup.1 and R.sup.2 have the same meanings as those defined above and a dehydrating agent.
    Type: Grant
    Filed: May 21, 1998
    Date of Patent: February 29, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masuji Motoki, Tadahisa Sato
  • Patent number: 5885393
    Abstract: A method for forming images by providing a first image formed with silver halide photographic material which has been imagewise exposed and developed according to conventional photographic processes. Thereafter, forming a second image by imagewise transferring ink of a heat fusible thermal transfer ink sheet onto the first image. The surface layer of the ink contacting the layer having the first image contains a resin having a hydrophilic group, the color tone of the second image has the relationships in the CIE coordinate, L*.ltoreq.30, -5.ltoreq.a*.ltoreq.+5 and +0.1.ltoreq.b*.ltoreq.+50, and glossiness measured according to JIS-Z8741-1983 is at least 100. The resulting image is a photographic image with a heat transfer image thereon.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: March 23, 1999
    Assignee: Konica Corporation
    Inventors: Shigeru Mano, Ichiroh Maeda, Shigeo Tanaka
  • Patent number: 5851754
    Abstract: A silver halide photographic material is disclosed, comprising a support having thereon at least one light-sensitive silver halide emulsion layer, wherein said silver halide photographic material contains a compound by formula (IA), or which contains at least one hydroxamic acid compound having a bicyclo ring as a partial structure and represented by formula (IB).
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: December 22, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Mikoshiba, Hiroo Takizawa, Junichiro Hosokawa, Yoshio Ishii, Keiji Mihayashi, Masakazu Morigaki, Mamoru Sakurazawa
  • Patent number: 5846687
    Abstract: A kit for preparing a processing liquid for use in the preparation of a lithographic printing plate according to the silver salt diffusion transfer process, and comprising all necessary active compounds for preparing said processing liquid, said active compounds including a hydrophobizing agent, said hydrophobizing agent being provided in a concentrated dissolved liquid state.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: December 8, 1998
    Assignee: Agfa-Gevaert N.V.
    Inventors: Lode Deprez, Jos Vaes
  • Patent number: 5830618
    Abstract: A silver halide photographic material is provided which comprises a support having thereon at least one light-sensitive silver halide emulsion layer wherein said light-sensitive layer or another hydrophilic colloidal layer provided on the support contains a compound represented by formula (I) and a hydrazine derivative represented by formula (II): ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydroxyl, hydroxylamino, amino, alkylamino, arylamino, aralkylamino, alkoxy, phenoxy, alkyl, aryl, alkylthio, or phenylthio group, ##STR2## wherein R.sup.3 represents an aliphatic or aromatic group; R.sup.4 represents a hydrogen atom, or an alkyl, aryl, alkoxy, aryloxy, amino or hydrazino group; G.sup.1 represents a --CO--, --SO.sub.2 --, --SO--, --P(O)R.sup.4, --CO--CO--, thiocarbonyl or iminomethylene group; and A.sup.1 and A.sup.2 each represents a hydrogen atom, or one of A.sup.1 and A.sup.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: November 3, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Tetsuo Yamaguchi
  • Patent number: 5763149
    Abstract: The present invention provides a kit of parts for preparing an alkaline processing liquid for use in preparing a lithographic printing plate according to the silver salt diffusion transfer process, and comprising all necessary active compounds for preparing said alkaline processing liquid, said active compounds being comprised in parts physically separated from each other, at least one of said parts comprising an inorganic alkali in solid form, at least one of said parts comprising an alkanolamine as silver halide solvent and at least one of said other parts comprising a hydrophobizing agent and being substantially free from inorganic and/or organic alkali.
    Type: Grant
    Filed: June 5, 1997
    Date of Patent: June 9, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventor: Lode Deprez
  • Patent number: 5624784
    Abstract: A kit of parts for preparing an alkaline processing liquid for use in preparing a lithographic printing plate according to the silver salt diffusion transfer process, and comprising all necessary active compounds for preparing said alkaline processing liquid, said active compounds being contained in parts physically separated from each other, at least one of said parts comprising an inorganic alkali in solid form and at least one of said other parts comprising a hydrophobizing agent and being substantially free from inorganic alkali.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: April 29, 1997
    Assignee: Afga-Gevaert N.V.
    Inventors: Jos Vaes, Renaat Ceulemans, Lode Deprez
  • Patent number: 5622809
    Abstract: A kit for preparing a processing liquid for use in preparing a lithographic printing plate according to silver salt diffusion transfer processing, and comprising all necessary active compounds for preparing said processing liquid, said active compounds including a solid hydrogensulphite amine complex or a solid sulphurdioxide amine complex, said amine of said complexes being capable of acting as a silver halide solvent.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: April 22, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Lode Deprez, Johan Loccufier, Jos Vaes
  • Patent number: 5618653
    Abstract: The present invention provides a kit for preparing a processing liquid for use in the preparation of a lithographic printing plate according to the silver salt diffusion transfer process, and comprising all necessary active compounds for preparing said processing liquid, said active compounds including a hydrophobizing agent being provided on the surface of solid particles, said solid particles being soluble in said processing liquid.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: April 8, 1997
    Assignee: Agfa-Gevaert N.V.
    Inventors: Jos Vaes, Renaat Ceulemans
  • Patent number: 5618652
    Abstract: An image formation method by silver salt diffusion transfer is described, which comprises subjecting a photosensitive element containing at least one photosensitive silver halide emulsion layer to image exposure, then developing the photosensitive element by use of an alkali processing composition containing a solvent for a silver halide to turn at least a part of unexposed silver halide of the photosensitive silver halide emulsion layer into a transferable silver complex salt, transferring at least a part of the transferable complex salt to a silver precipitating nucleus-containing image receiving layer to form an image on the silver precipitating nucleus-containing image receiving layer, and separating the silver precipitating nucleus-containing image receiving layer from the photosensitive element after image formation to obtain the image, wherein the image is formed in the presence of at least one compound represented by the following formula (I) and at least one compound represented by the following form
    Type: Grant
    Filed: March 14, 1996
    Date of Patent: April 8, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Hisashi Okada, Kazumi Nii
  • Patent number: 5545505
    Abstract: Hydroxylamine, alkanolamine, and ammonium phthalamate compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
    Type: Grant
    Filed: September 19, 1995
    Date of Patent: August 13, 1996
    Assignee: Minnesota Mining and manufacturing Company
    Inventor: Sharon M. Simpson
  • Patent number: 5326668
    Abstract: A method of image formation disclosed, which comprises a method of image formation comprising developing a photosensitive element comprising an image-wise exposed photosensitive silver halide emulsion layer using an alkaline processing element containing a silver halide solvent to convert at least a part of the unexposed silver halide in the emulsion layer to a transferrable silver complex salt, and transferring at least a portion of the silver complex salt onto an image-receiving element comprising an image-receiving layer containing silver precipitation nuclei to form an image in the image-receiving element, wherein the silver halide grain in the photosensitive silver halide emulsion layer comprises silver iodobromide or silver chloroiodobromide having a silver iodide content of from 0.5 to 3.5 mol %; and wherein silver bromide or silver iodobromide is formed after chemical sensitization on the surface of the grains in an amount of from 3 to 20% in terms of silver.
    Type: Grant
    Filed: March 25, 1993
    Date of Patent: July 5, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koukichi Waki
  • Patent number: 5290661
    Abstract: A method for sorting images by silver salt diffusion transfer comprisingimagewise exposing a light-sensitive element comprising a light-sensitive silver halide emulsion layer,developing the light-sensitive element in the presence of a silver halide solvent using an alkaline processing composition to turn at least a part of unexposed silver halide of the light-sensitive silver halide emulsion layer into a transfer silver halide complex salt, andtransferring at least a part of the silver halide complex salt to an image receiving layer comprising a silver precipitating agent to form images on the image receiving layer,wherein at least one compound represented by formula (I) is added to at least one of the light-sensitive element, an image receiving element comprising the image receiving layer, and the processing composition in an amount of at least 1.times.10.sup.-6 and less than 1.times.10.sup.-2 mol based on one mol of silver applied per unit area (m.sup.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: March 1, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Idota, Makoto Ishihara, Morio Yagihara
  • Patent number: 5236805
    Abstract: A method of image formation by silver salt diffusion transfer in which a photosensitive element which contains an imagewise exposed photosensitive silver halide emulsion layer is developed, in the presence of a silver halide solvent, using an alkaline processing composition, in which at least a portion of the unexposed silver halide in the emulsion layer is converted to a transferable silver complex salt, and in which at least a portion of the silver complex salt is transferred into a silver precipitant containing image forming layer to form an image in the image receiving layer wherein a hydroxylamine developing agent is included in the processing composition and at least two stabilizing compounds having two different heterocyclic rings which are represented by the general formula (I) indicated below are included in the silver halide emulsion layer: ##STR1## wherein Q represents a group of atoms which is required to form a five or six membered heterocyclic ring, and wherein the heterocyclic ring which is for
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: August 17, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Idota, Osami Tanabe, Morio Yatihara
  • Patent number: 4699868
    Abstract: An alkaline aqueous tanning developing solution for photographic image development comprising at least one hydroxylamine derivative. Preferred formulations may also contain at least one water-miscible polyhydroxy aliphatic organic solvent and/or a developing agent which comprises a polyhydroxybenzene compound having at least two hydroxy groups and at least one electron withdrawing and good leaving group suitable for nucleophilic addition.
    Type: Grant
    Filed: August 18, 1986
    Date of Patent: October 13, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Gebran J. Sabongi
  • Patent number: 4526857
    Abstract: In a process of forming an image by silver salt diffusion transfer comprising using a processing composition containing an alkali, a hydroxylamine developing agent, and a silver halide solvent, this process of forming an image comprises performing the diffusion transfer in the presence of a compound represented by the general formula: ##STR1## or both this compound and a compound represented by the general formula: ##STR2##
    Type: Grant
    Filed: April 12, 1984
    Date of Patent: July 2, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Idota
  • Patent number: 4514488
    Abstract: In a process for forming an image by diffusion transfer, this process for forming an image comprises performing the diffusion transfer by using a hydroxylamine represented by the formula: ##STR1## as a developing agent, and using a cyclic imide as a silver halide solvent in the presence of a 1-aryl-3-pyrazolidinone compound represented by the formula: ##STR2##
    Type: Grant
    Filed: March 28, 1984
    Date of Patent: April 30, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Idota, Noriyuki Inoue
  • Patent number: 4309499
    Abstract: A black-and-white negative image forming process is disclosed using a diffusion transfer type film unit. An exposed silver halide emulsion comprising internal latent image type silver halide grains which have substantially no fogging centers at their surface is processed with a composition comprising a silver halide solvent, a developing agent, a foggant, alkali and a fog promoting agent. The solvent for the silver halide characteristically possesses a solubilizing power for AgBr of from about 2.times.10.sup.-5 to 5.times.10.sup.-3 mol/l in a 0.002 molar aqueous solution.
    Type: Grant
    Filed: November 14, 1979
    Date of Patent: January 5, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Katsumi Hayashi