Abstract: This invention relates to a light-sensitive laminate comprising a light-sensitive layer of photoresist, a support therefor, and an intermediate protective layer preferably of a light-transmitting material disposed between said photoresist layer and said support. In use, the photoresist layer of the laminate is adhered to a base material and the support stripped therefrom, thereby leaving a composite comprising the base material, photoresist layer and intermediate protective layer disposed over said photoresist layer. The intermediate layer serves to protect the photoresist layer from damage such as by abrasion or otherwise during processing, thereby permitting storage of the so-formed composite prior to use. Since the intermediate layer may be of a light-transmitting material, photo-imaging may take place through the intermediate layer with the intermediate layer subsequently removed by contact with a solvent that is a non-solvent for those areas of photoresist left after development.
Abstract: As a stripper for a radiosensitive resist formed of a poly(fluoroalkyl .alpha.-haloacrylate) or a copolymer thereof, there is used a solution which contains 0.1 to 40 wt. % of an alkali metal alkoxide, an alkali metal hydroxide or a tetraalkylammonium hydroxide in a substantially non-aqueous polar solvent of dimethyl sulfoxide.
Abstract: Photographic elements, assemblages and processes are described for producing a monochromatic dye image. The assemblage comprises:(a) a photosensitive element comprising a support having thereon a layer of nondiffusible dye image-providing material, a stripping layer, an opaque layer and a silver halide emulsion layer;(b) a transparent cover sheet; and(c) opaque processing composition for application between the element and cover sheet. A dye mordant layer may also be present on the element or cover sheet.After exposure and processing, the layer of nondiffusible dye image-providing material on a support is stripped away to provide a monochromatic retained dye image without the need for bleaching and fixing.
Abstract: A photosensitive element is provided by an actinic radiation-transmissive film-forming polymeric material which contains photolabile blocked surfactant capable upon exposure to actinic radiation of releasing a detectable quantity of surfactant in actinic radiation exposed areas in areas not exposed to actinic radiation and unblocked surfactant in an image-wise pattern in the actinic radiation exposed areas. An imaging process is also provided comprising providing the actinic radiation-sensitive element and exposing the actinic radiation-sensitive element to actinic radiation in an image-wise pattern at an intensity and for a time sufficient to release an image-wise pattern of released surfactant in the exposed area.
Type:
Grant
Filed:
May 3, 1982
Date of Patent:
August 21, 1984
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: A method for producing an information carrier in the form of a card, such as an identification card or pass, as well as an information carrier produced in accordance with this method. The information carrier comprises a plurality of plastic layers combined with one another into a block, at least one of which contains a photograph of the bearer and/or his fingerprint and/or other readable or machine-readable data in the form of a photographic layer. This photographic layer is produced and incorporated into the sandwich of plastic layers making up the identification card in that a specially prepared film is exposed to light, developed, fixed and dries, and then the carrier layer of this film sandwich is removed from the emulsion after the emulsion has entered into an adhesive bond with a first plastic carrier layer, this adhesion being substantially greater than the adhesion of the emulsion to the film's auxiliary carrier, which is to be removed.
Abstract: A process for forming a desired metal pattern on a substrate which comprises, forming a mask of a thermally depolymerizable polymer on the substrate with a pattern of openings complementary to the desired metal pattern, blanket coating the substrate and the mask with a metal, heating the substrate to depolymerize the depolymerizable polymer, cooling the surface of the metal to thereby delaminate the metal coated in areas where thermally depolymerizable polymer is present, removing the delaminated metal where necessary, and optionally plasma ashing the depolymerized polymer, if residue thereof remains, to remove the same from said substrate.
Type:
Grant
Filed:
July 26, 1983
Date of Patent:
June 26, 1984
Assignee:
International Business Machines Corporation
Inventors:
Herbert R. Anderson, Jr., Constance J. Araps, Catherine A. Lotsko
Abstract: A kit for preparing a mountable plate having an image thereon, such as a nameplate, includes light sensitive film and a colored adhesive mounting element. The film includes a polymeric base, a clear polymeric protective overlay, and a light sensitive layer between the base and the overlay. The mounting element includes a clear adhesive layer for attaching to the film and a colored layer that provides color to the assembled nameplate. The mounting element can also include pressure-sensitive adhesive so that the nameplate can be attached to a surface.There is also described a method for preparing a nameplate using this kit.
Abstract: Method of preparing a fade-resistant and abrasion-resistant colored photographic image and a novel color photographic paper therefor. A photograph on the paper is coated with adhesive, bonded to a substrate and the paper backing stripped away, leaving a low density polyethylene foil covering the reversed image.
Abstract: A diffusion transfer film unit comprising a support, a photosensitive silver halide emulsion layer, an image-receiving layer and, intermediate said silver halide emulsion layer and said image-receiving layer, a release layer which comprises a water-soluble polymer and a styrenated acid functional acrylic resin. In a preferred embodiment, the film unit is a silver diffusion transfer film unit.
Abstract: A stripping sheet adapted for use with a diffusion transfer film unit to remove at least the photosensitive layer from said film unit subsequent to processing is disclosed, as well as methods for using said stripping sheet, wherein said stripping sheet comprises a support, carrying in order, a water-absorbing layer, and a layer capable of conversion from substantial liquid processing composition impermeability to a condition of substantial liquid processing composition permeability.
Type:
Grant
Filed:
June 26, 1981
Date of Patent:
November 16, 1982
Assignee:
Polaroid Corporation
Inventors:
Raymond B. Hanselman, Karl J. Schreiber
Abstract: A dry-developing dry film resist is provided comprising a photopolymerizable layer preferably sandwiched between a support sheet and a cover sheet, the layer comprising polymerizable monomer in excess of the absorptive capacity of the layer, photopolymerization initiator, and binder component of a plurality of polymers, at least one of these polymers being incompatible so as to be present as a dispersion in the layer to reduce the cohesive strength of the layer. The layer is developed by peeling away the support sheet, the unexposed area of the layer adhering to the support sheet and the exposed area adhering to the substrate to which it was laminated to form a resist image against such treatments as etching, plating and soldering, especially to make a printed circuit.
Abstract: Improved process for forming multicolor proofs by laminating to a receptor a positive-working photopolymer element having an electrical discharge treated polyethylene terephthalate support bearing a photopolymerizable layer containing a monomeric component of or mixture of monomeric components as defined; a compatible polymeric acrylate binder and optionally a polyvinyl acetate binder, the weight ratio of polyvinyl acetate to acrylate binder being less than 4 to 3, and an initiator or initiator system; exposing the layer imagewise; removing the support, applying and distributing colorant, removing the colorant in the exposed areas and repeating the steps at least once with another photopolymer element, the lamination being to the previously laminated element.
Abstract: A photosensitive silver halide element comprising a support carrying photosensitive silver halide grains in a predetermined spaced array is prepared by a method which comprises at least partially coalescing fine-grain silver halide in a plurality of spaced depressions in a hydrophobic layer, superposing said layer with a hydrophilic layer during or subsequent to said coalescence, and then separating said hydrophilic layer and said hydrophobic layer whereby said coalesced silver halide grains are retained on said hydrophilic layer in a pattern corresponding substantially to the pattern of said spaced depressions.
Type:
Grant
Filed:
September 2, 1981
Date of Patent:
October 12, 1982
Assignee:
Polaroid Corporation
Inventors:
Arthur M. Gerber, Warren D. Slafer, Vivian K. Walworth
Abstract: A process for the production of a photographic image which comprises(a) imagewise exposing a photographic assembly which comprises at least during a silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a layer substantive hydroxypyridone azamethine compound of the general formula ##STR1## wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl, amino or heterocyclic radical, Y represents hydrogen or hydroxy, --CN, --COOR.sup.1, --CONR.sup.1 R.sup.2 or --COR.sup.1 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical and Z is hydrogen or is --CN, --COOR.sup.3, --CONR.sup.3 R.sup.4, --SO.sub.3 H, --SO.sub.3.sup.- or --COR.sup.3, where R.sup.1, R.sup.2, R.sup.3 and R.sup.
Type:
Grant
Filed:
February 23, 1981
Date of Patent:
October 12, 1982
Assignee:
Ciba-Geigy AG
Inventors:
Terence C. Webb, Patrick D. P. Thomas, William E. Long
Abstract: A photopolymerizable composition of matter useful for photopolymeric printing surfaces is disclosed. Printing surfaces prepared from the composition are strong and wear well, resist solvents and abrasives, and are suitable for intaglio or gravure printing.
Abstract: A new method to produce photographic images is provided which comprises:(a) imagewise exposing a photographic assembly which contains at least during the silver halide developing step, in order optionally a supercoat layer, at least one silver halide emulsion layer, a layer containing a substantive azamethine compound and a photobase, there being optionally one or more interlayers between each of said components(b) treating the exposed photographic assembly with an aqueous processing bath so as to provide in the silver halide emulsion layer or layers a solution or dispersion of a bleach developer compound, thereby to develop the latent silver image in the silver halide emulsion(s), and(c) in the non-latent image areas allowing the bleach developer compound to diffuse in a counter-imagewise manner from the silver halide emulsion layer (s) to the layer containing substantive azamethine compound and there to bleach the compound to form a dye image.
Abstract: A method of manufacturing a water-release transfer is disclosed in which a design in a photopolymerizable ink is applied to a substrate having a water-soluble release coating and the design is subjected to photopolymerizing radiation, e.g. ultra-violet light, to cause the ink to polymerize to a solid state. Preferably the ink comprises a mixture of a liquid unsaturated monomer and a viscous or solid prepolymer, and one or both of the monomer and prepolymer contain acryloyl or methacryloyl groups. The invention includes water-release transfers manufactured using photopolymerizable inks.
Abstract: A dry release transfer is disclosed in which a releasable layer is adhered to a carrier sheet and a stress-resisting transferable design layer is printed on the releasable layer. The releasable layer is normally pre-stressed so that when an external force is applied to the carrier sheet , e.g. by rubbing with a stylus, this force is transmitted to the releasable layer. Since the releasable layer cannot yield to the applied force by stretching, because it is held by the stress-resisting layer, the adhesive bond between the releasable layer and the carrier sheet is weakened or is ruptured or partial or complete cohesive failure occurs within the releasable layer, thereby facilitating transfer of the design layer. A method of producing such transfers is also disclosed.
Abstract: Thermally coalescible acrylic resin dispersions comprising particles of single-phase, surfactant-free, random acrylic polymers or copolymers, containing at least 80% by weight of acrylic units, dispersed in a surfactant-free medium that comprises a compatible liquid plasticizer that is nonvolatile at room temperature and is not a monomer of any of the polymeric components. Incorporation of a photopolymerizable, ethylenically unsaturated compound provides photosensitive dispersions useful for making relief and planographic printing plates, photoresists, and the like.
Abstract: A photographic processing sleeve is provided for receiving and processing a dye donating instant film sheet to produce a photographic print. The sleeve comprises a film retaining sheet that is folded over along its lateral edges to form channels which slidably receive the film sheet, and edge strips, sometimes called side rails, which space the film sheet from the image-receiving sheet. After processing, at least a major portion of the image-receiving sheet, including the finished picture, is adapted to be peeled apart from the rest of the sleeve which can then be discarded.
Abstract: A photographic processing sleeve is provided for receiving and processing a dye donating instant film sheet to produce borderless photographic prints. The sleeve is constructed of first and second sheets coupled together to form a pocket therebetween for receiving the film sheet. One of the sheets includes a central section which carries materials for immobilizing the dyes donated by the film sheet to form a visible picture in the central section. A stripping sheet forms an outermost surface of one face of the sleeve and releasably couples the central section of the first sheet to the remainder of the sleeve so the stripping sheet and the picture in the central section can be stripped away from the remainder of the sleeve.
Abstract: A dry release transfer is disclosed in which the design layer is formed by printing one or more inks onto a carrier sheet, at least one of the inks being a photopolymerizable composition, and subjecting the design layer to ultra-violet radiation or an electron beam discharge in order to polymerize the photopolymerizable ink. By suitable selection of polymerizable components of the ink so that the photopolymerized ink has a high Young's modulus, a stress-resisting design layer is produced which will release readily from the carrier on mechanically stressing the carrier, e.g. by rubbing lightly with a ball-point pen.
Abstract: A method of making signs is disclosed in which a photographically sensitive material is imagewise exposed and developed. The developed image is so constituted that, under the action of heat and pressure, it may be made to adhere to a surface of a transparent or translucent sheet, e.g. of plastics or glass, to form a sign in which the legend is visible through and protected by the sheet. In order to render the legend more visible, a coating or layer may be applied over the legend which accordingly forms a background to the legend as viewed through the sheet.Production of the legend photographically gives very great flexibility in terms of letter size, spacing and the like and allows the production of "one off" signs on a rapid and economic basis. A simple hot press may be used to adhere the legend to the sign sheet.
Type:
Grant
Filed:
December 20, 1978
Date of Patent:
November 18, 1980
Assignee:
Letraset Corporation
Inventors:
Simon L. Scrutton, John V. Shepherd, John S. Thornley, Eric M. Sutton
Abstract: Cloth, such as cotton, burlap, or canvas, has a photographic emulsion laminated thereto, along with an outer protective film. The composite laminate formed is permanent, and sufficiently firmly affixed to the cloth that the cloth is machine washable without substantial damage or alteration of the laminated image. The method of making the cloth laminated with photographic emulsion comprises applying the photographic emulsion facedown on a protective film, coating with adhesive and applying the cloth, drying the emulsion and cloth and pressing between plates, at least one of which is heated. By dipping the emulsion in a stripping solution prior to applying to the protective film, adherence and permanence of the laminate formed is substantially increased.
Abstract: A marking transfer sheet comprising an imaging layer of pigment, binder and a color-forming, radiation-sensitive component on a carrier film and a process for its use comprising exposing the imaging layer to a pattern of radiation to form a mark, heating the imaging layer until adhesive, and contacting the imaging layer with a support more adherent to the imaging layer than the carrier film; and optionally separating the carrier film from the imaging layer.
Abstract: There is disclosed a dry system image producing element comprising a substrate, a thin metal layer and a photosensitive layer. After exposing the element to light through a desired pattern, the photosensitive layer is peeled off to obtain a light barrier pattern made from the metal on the substrate corresponding to the photosensitized portion.