Abstract: Disclosed is a volume phase hologram recording material of high sensitivity, high contrast, and excellent record retention properties and also disclosed is a volume phase hologram recording medium using the said material. The volume phase hologram recording material mainly contains a three-dimensional crosslinked polymer matrix, a radically polymerizable monomer, and a photoradical polymerization initiator. The three-dimensional crosslinked polymer matrix is formed from a matrix-forming compound having two photoradically polymerizable unsaturated groups and two non-photoradically polymerizable hydroxyl groups represented by the following general formula (1) and another matrix-forming compound having no photoradically polymerizable group.

Abstract: The invention relates to a method of generating a laser marking in a security document by means of at least one laser beam, the security document having at least one laser-markable layer and also at least one reflecting layer which overlaps at least partly with the at least one laser-markable layer and has opaque regions. The at least one reflecting layer has at least one transparent region and, at least visually, is not significantly altered by the laser treatment of the laser-markable layer.

Abstract: A method and apparatus for selecting a specific fraction from a heterogeneous fluid-borne sample using optical gradient forces in a microfluidic or fluidic system are presented. Samples may range in size from a few nanometers to at least tens of micrometers, may be dispersed in any fluid medium, and may be sorted on the basis of size, shape, optical characteristics, charge, and other physical properties. The selection process involves passive transport through optical intensity field driven by flowing fluid, and so offers several advantages over competing techniques. These include continuous rather than batch-mode operation, continuous and dynamic tunability, operation over a wide range of samples, compactness, and low cost.

Abstract: The present invention is a solution or colloid of fullerene, SWNTs, or graphene in cyclic terpenes, lactones, terpene-alcohol, fatty-acid alcohols, and lactones following ultrasonication and ultracentrifugation processing, for oil-energy, biological, electrical-thermal applications. The compositions are useful as fuel/oil/grease/gels (synthetic included), oil/fuel/additives/propellants, identification dyes, and heat-transfer fluids. Other functions are phase-change fluids for solar energy power plants, antifreeze, electronic dyes, electrolytic fluid/solvent, electrically-thermally conductive material for electrochemical, dielectric, filler/adhesive for semiconductor, eletro-optical, and liquid crystal substrates/coatings for touch sensitive transmissive or reflective displays. When combined with gelatin the formulations can function as dichroic-optical coatings for thin-films/waveguides/holograms.

Abstract: A hologram-recording medium containing: a recording layer containing a polymerizable monomer containing a structural framework represented by the following general formula (1). In general formula (1), X and Y are not the same, and X and Y are selected from hydrogen, iodine, bromine, and chlorine atoms and from methyl, ethyl, isopropyl, tert-butyl, phenyl, naphthyl, hydroxyl, methoxy, ethoxy, isopropoxy, tert-butoxy, phenoxy, naphthoxy, acetyl, carboxyl, acetoxy, thiophenyl, thionaphthyl, thiomethyl, thioethyl, thioisopropyl, thio-tert-butyl, and thiol groups; and W is selected from the group consisting of benzylvinyl, styryl, acryloyl, and methacryloyl groups.

Abstract: The invention relates to a method for selecting compounds which can be used as additives in photopolymer formulations for producing light holographic media, and to photopolymer formulations which contain at least one softener which are selected according to the claimed method. The invention also relates to the use of photopolymer formulations for producing holographic media.

Abstract: The invention relates to a photopolymer formulation comprising matrix polymers, writing monomers, and photoinitiators, to the use of the photopolymer formulation for producing optical elements, in particular for producing holographic elements and images, to a method for illuminating holographic media made of the photopolymer formulation, and to special fluorourethanes.

Abstract: The invention relates to a photopolymer formulation comprising matrix polymers, writing monomers, and photo initiators, comprising a combination of at least two different writing monomers. The invention further relates to the use of the photopolymer formulation for producing optical elements, in particular for producing holographic elements and images, to a method for producing the photopolymer formulation and to a method for illuminating holographic media made of the photopolymer formulation.

Abstract: A production method is provided by which a copied volume hologram from a multi-layer master is later customized by utilization of the color tuning properties of the light-curable materials used for the application onto personal documents. These holographic individual data, such as a passport photo, are also separately detectable, without the holographic elements copied from the master, that are visible under other viewing angles, impairing the visibility of the individual data. The volume hologram overlay obtained by this method is applied on personal and valuable documents to increase protection against forgery, possesses superimposed optically variable items of information that are separately visible under different viewing angles and give a defined color change under different view angles, wherein at least one of these items of optical information represents individual personal data, in particular a passport photograph.

Abstract: A system and method for producing a Bragg grating. A system and a method for apodization of gratings. The system and method for producing a grating include splitting a beam and reflecting one split beam an odd number of times and the other an even number of times before the two are allowed to interfere within a photosensitive target. When the original beam is scanned in predetermined directions, the split beams scan the target while interfering within the target. The original beam is scanned such that an intersection point of the reflected split beams moves along a bisector of the two split beams. In the system and method for apodizing, scanning of the interfering beams along a length of the target may be controlled to yield a substantially uniform average refractive index for the apodized grating that is being recorded in the photosensitive target medium.

Abstract: The invention relates to a novel non-crystallizing methacrylate and a method for the production thereof. The invention further relates to a photopolymer formulation comprising the methacrylate of the invention as well as to use of said photopolymer formulation for producing holographic media.

Abstract: The invention relates to a method for producing a holographic film, wherein a photopolymer formulation comprising matrix polymers, writing monomers, photoinitiator system, and optionally auxiliary materials and additives is provided, the photopolymer formulation is applied as a film to the surface of a substrate, and the film is dried, wherein a photopolymer formulation having a plateau module G0 of =0.03 MPa is used. The invention further relates to a holographic medium that can be obtained by means of the method according to the invention.

Abstract: The subject matter of the invention is a method for producing illuminated, holographic media comprising a photopolymer formulation having the adjustable mechanical modulus GUV. A further subject matter of the invention is an illuminated, holographic medium that can be obtained by means of the method according to the invention.

Abstract: The invention relates to a method for producing holographic media, wherein a photopolymer formulation comprising matrix polymers, writing monomers, a photoinitiator system, and optionally auxiliary materials and additives as components is provided, the photopolymer formulation is applied as a coating on the surface of a carrier film and the photopolymer formulation is dried on the carrier film at a temperature XX<T>YY DEG C., wherein only those compounds having TGA 95 values >100 DEG C. and at least 30 DEG C. above the temperature T are selected as components for the photopolymer formulation. The invention further relates to a holographic medium that can be obtained by means of the method according to the invention.

Abstract: The invention relates to a method for producing holographic films, in which a photopolymer formulation is provided which comprises as constituents matrix polymers, writing monomers, a photoinitiatior system, optionally a non-photopolymerizable component and optionally catalysts, radical stabilizers, solvents, additives and other auxiliaries and/or additives. The photopolymer formulation is applied in a planar manner and in the form of a film on a support film and the photopolymer formulation is dried on the support film at a temperature 60<T<120 DEG C, wherein only compounds are selected as components for the photopolymer formulation, the TGA 95 values of which are >100 DEG C and are above the temperature T by at least 30 DEG C, and a photopolymer formulation having a plateau module of =0.030 MPa is used.

Abstract: A method for manufacturing an optical element that has a function to polarize and split incident light includes: a) forming a grid portion on a face of a substrate in a plural number with a predetermined pitch; b) forming a diffractive structure resist pattern on the face of the substrate; c) forming the diffractive structure by etching the substrate anisotropically in a thickness direction with the diffractive structure resist pattern; and d) forming a fine line on the grid portion by depositing a reflective material from an oblique direction onto the face of the substrate where the diffractive structure is provided.

Abstract: There is provided volume holographic data recording media having a recording layer which is capable of recording interference fringes generated by interference of light having excellent coherence as fringes having different refractive indexes and undergoes holographic data recording by an amount of spatial shift distance of not more than 3 ?m which is smaller than that of conventional media.

Abstract: A method is described for recording a volume reflection holographic image that is viewable when illuminated by light at a wavelength Wv.

Abstract: Articles for recording a holographic image are described. The articles include a holographic recording medium having a plurality of surfaces, having a transparent polymeric binder and a photochemically active dye, the holographic recording medium having a holographic image recorded therein formed by exposed areas of the photochemically active dye and unexposed areas of the photochemically active dye; and a first light-blocking layer or material over a first surface of the holographic recording medium from which surface the holographic image is viewed, the light blocking layer or material absorbing light in the wavelength range to which the photochemically active dye is sensitive and allowing transmission of light in a different wavelength range for viewing the holographic image.

Abstract: A sensor for the detection of an analyte, comprising a holographic element comprising a medium and a hologram disposed throughout the volume of the medium, wherein an optical characteristic of the hologram changes as a result of a variation of a physical property occurring throughout the volume of the medium, wherein the medium is obtainable by formation in situ in the presence of a pore-forming agent, wherein the agent is not present in the sensor or does not react with the analyte and the sensor.

Abstract: An optical medium is provided. The optical medium comprises: a diffusion-controlling matrix framework; at least one photoactive monomer attached to the diffusion-controlling matrix framework in a first state of the optical medium, wherein the at least one photoactive monomer is released from the diffusion-controlling matrix framework by photo cleavage, producing a second state of the optical medium, in which diffusion of the photoactive monomer through the optical medium is possible; and wherein the at least one photoactive monomer is then polymerized or reattached to the diffusion-controlling matrix, giving a third state of the optical medium, when exposed to photo-polymerizing light.

Abstract: The invention provides a hologram in which a visually unidentifiable microtext or other micropattern of the order of 10 ?m is recorded, and a process for the fabrication of the same. A volume hologram recording material 2 is located on the side of a reflection type volume hologram master 1 onto which copying illumination light 11 is incident, and the copying illumination light 11 incident onto the recording material 2 and light 12 diffracted through the master 1 interfere together in the volume hologram recording material 2 thereby copying the reflection type volume hologram master.

Abstract: The present invention pertains to compounds and polymers which incorporate a boronic acid sensor group (SG) of the formula (I): wherein: J is independently —CH2— or —CH2CH2—; n is independently 0, 1, 2, or 3; and each RR, if present, is independently a ring substituent; and wherein the ring attachment (i.e., where sensor group is attached) is via the 3-, 4-, 5-, or 6-ring position. Such compounds and polymers are useful in the selective chemical detection and/or quantitation of alpha-hydroxy carboxylic acids, such as lactic acid/lactate and malic acid/malate. The present invention also pertains to methods of preparing such compounds and polymers; methods and assays which employ these compounds and polymers; devices (e.g., holographic sensors) and kits for use in such methods and assays, etc.

Abstract: The present invention refers to the manufacturing method of a holographic film and its development; the compositions of the films used in this invention are substantially solid and applied on a substrate in film or glass form; the photopolymerizable layer consists of a thickness of about 10 to 100 ?m (microns), consisting of: a) 70% to 90% over the total weight of a thermoplastic “polymer”, b) 10% to 30% over the total weight of a preferably mono-functional photopolymerizable monomer reactive to light and, c) 1% to 10% per weight of an expansion agent that when heated at a minimum of 75° C. produces a gas in the unhardened or monomer polymerized areas of the hologram; furthermore, the composition contains a photoinitiator system sensitive to visible light, surfactants, plasticizers, etc.; photopolymerizable monomers used in this invention contains at least one part unsaturated ethylene with a boiling temperature equal or higher than 100° C.

Abstract: A method of manufacturing an article for display of a holographic image is described that includes thermally fusing a holographic recording medium containing a photochemically active dye dispersed in a transparent thermoplastic polymer binder to another layer or material; and then exposing the holographic film to intersecting beams of coherent light to form a holographic image therein formed by photoreacted areas of the photochemically active dye and unreacted areas of the photochemically active dye.

Abstract: A metal identification platelet equipped with an identification code, while the identification code comprises a hologram. A method of producing the identification platelet with the identification code, including the following steps: A shield from an electro-insulation material is formed on a shim with a holographic motif. Then, the shim is galvanized in the places not covered by the shield from the electro-insulation material. And the completed metal identification platelets are removed from the shim.

Abstract: A method of forming a security device comprises: a) providing an undeveloped photoresist layer on an electrically conductive layer; b) forming a first diffractive pattern in the undeveloped photoresist layer using optical-interferometry; c) forming a second diffractive pattern in the undeveloped photoresist layer using electron beam lithography; and d) thereafter developing the photoresist layer.

Abstract: The invention provides an authentication hologram using a Lippmann hologram that enables a 3D object image having a vertical and horizontal field of vision as well as planar, added information viewable at a specific angle alone are viewable, as shown in FIG. 5. In that authentication hologram, a hologram for reconstructing a 3D object image and a hologram mirror pattern that is formed at a pattern portion corresponding to added information and comprising planar interference fringes placed one upon another and parallel at a constant spacing are recorded in a superposing fashion.

Abstract: An organic-inorganic hybrid material comprising (a) at least one soluble organic polymer and (b) at least one mono- or polynuclear metal complex having at least one ligand which comprises at least one photochemically and/or thermally polymerizable functional group. Also disclosed is an optical component which is made by using the hybrid material.

Abstract: An active chiral photonic metamaterial having a dynamically controllable photonic material parameter is employed in a system and a method of polarization rotation. The active chiral photonic metamaterial includes a first chiral photonic element formed in a first metal layer, a second chiral photonic element formed in a second metal layer, and an active material layer disposed between the first and second metal layers. The active material layer includes the photonic material parameter that is dynamically controllable. A coupling between the first chiral photonic element and the second chiral photonic element is a function of the photonic material parameter of the active material layer. The system further includes a means for controlling the dynamically controllable photonic material parameter. The method includes illuminating the active chiral photonic metamaterial with an optical signal and applying a control signal to vary the dynamically controllable photonic material parameter.

Abstract: The present invention provides a fluorine-containing volume holographic data recording material making it unnecessary to provide a step of eliminating a specific solvent even in the case of a thick film, and having high hologram performance and good dynamic range. There is provided a composition comprising a base polymer (a), a liquid monomer (b) and a photo-initiator (c), wherein the base polymer (a) is an amorphous polymer comprising a fluorine-containing monomer as a structural unit and having a fluorine content of 26 to 80% by mass, the liquid monomer (b) comprises at least one liquid monomer (b1) initiating polymerization by means of activated species generated from the photo-initiator (c), the photo-initiator (c) is a compound causing the liquid monomer (b1) to initiate polymerization by exposure to light having excellent coherence and, and a refractive index of the liquid monomer (b) is higher than an average refractive index of a mixture of the base polymer (a) and the photo-initiator (c).

Abstract: The present invention relates to a system, as well as articles and holographic recording medium comprising the system, where the system comprises: a polymerizable component comprising at least one photoactive polymerizable material; and a photoinitiator component comprising at least one photoinitiator for causing the polymerizable component to polymerize to thereby form a plurality of holographic gratings when activated by exposure to a photoinitiating light source; wherein when a portion of the polymerizable component has been polymerized to form at least one holographic grating, the unpolymerized portion of the polymerizable component is resistant to further polymerization when not exposed to the photoinitiating light source. The present invention also provides methods for forming at least one holographic grating in a holographic recording medium having such a photopolymerizable system.

Abstract: An optical recording material and methods of making such material is provided. The material comprises of a dewar benzene monomer, with at least two cross-linkable groups, a sensitizer, a cross-linker, and an initiator. The material does not require a binder or a co-sensitizer. The material can be fabricated by an exceedingly easy technique that offers high photosensitivity, high diffraction efficiency, millimeter thickness, and high dynamic range.

Abstract: Described is a process for the production of a multi-layer body having a volume hologram with at least two different items of image information, wherein a photosensitive layer (46) of the multi-layer body is directly or with the interposition of a transparent optical medium (44s, 45) brought into contact with the front side of a master (44), in which interlaced regions with different asymmetrical surface structures or kinoform structures are shaped, which embody the at least two different items of image information. The photosensitive layer (46) and the master are exposed with a coherent light beam (47) whereby a volume hologram is formed in the photosensitive layer (46). Also described are a master for the production of the multi-layer body and a security element having said multi-layer body.

Abstract: A data storage device including: a plastic substrate having a plurality of volumes arranged in tracks along a plurality of vertically stacked, laterally extending layers therein; and, a plurality of micro-holograms each contained in a corresponding one of the volumes; herein, the presence or absence of a micro-hologram in each of the volumes is indicative of a corresponding portion of data stored.

Abstract: There are provided optical data storage media and methods of optical data storage using the same. The optical data storage media comprises a non-linear sensitizer capable of absorbing actinic radiation to cause upper triplet energy transfer to a reactant that undergoes change upon triplet excitation. The refractive index change (?n) of the medium is at least about 0.005, or even at least about 0.05.

Abstract: A method of forming a hologram image comprising the steps of forming an electrophotographic image by forming an electrophotographic image area on an image support via an electrophotographic image forming method using a toner containing at least a thermoplastic resin; laminating an emboss hologram transferring member over the electrophotographic image so that a surface on which a corrugation profile is formed of the emboss hologram transferring member is in contact with the electrophotographic image area heating the electrophotographic image and the emboss hologram transferring member at a temperature not lower than a softening temperature of the toner while pressurizing the emboss hologram transferring member onto the electrophotographic image; cooling the electrophotographic image and the emboss hologram transferring member, and peeling the emboss hologram transferring member from the electrophotographic image, whereby the corrugation profile of the emboss hologram transferring member is transferred onto the

Abstract: An optical data storage medium is provided. The optical data storage medium includes a polymer matrix; a reactant capable of undergoing a change upon triplet excitation, thereby causing a refractive index change; and a non-linear sensitizer capable of absorbing actinic radiation to cause upper triplet energy transfer to said reactant. The refractive index change capacity of the medium is at least about 0.1. The reactant comprises polyvinyl chlorocinnamate, polyvinyl methoxycinnamate, or a combination thereof.

Abstract: A molded product having a phase separation structure formed by photopolymerization of a photopolymerizable composition and imparting a sharp diffraction spot at a high diffraction efficiency, and a method for manufacturing same are provided. The molded product (1) comprises a matrix (2) and a multiple columnar structures (3) disposed within the matrix (2) and having an index of refraction different from the matrix (2), wherein the half width of a diffraction spot is 0.6° or less and diffraction efficiency is 10% or greater in an angular spectrum obtained by irradiation with a laser beam having an intensity distribution of standard normal distribution and a half width of the intensity distribution of 0.5°. The multiple columnar structures (3) are oriented in approximately the same direction, and are aligned in a regular lattice on a plane perpendicular to said orientation direction.

Abstract: Disclosed is a volume phase hologram recording material characterized by excellent photosensitivity, low cure shrinkage, high transparency, and particularly good storage stability and also disclosed is a recording medium prepared therefrom. Further disclosed is a photosensitive resin composition for volume phase hologram recording that comprises a soluble aromatic copolymer (A), a photoradically polymerizable compound (B) capable of copolymerizing with the soluble aromatic copolymer (A), a photopolymerization initiator (C), and a polymer binder (D). The soluble aromatic copolymer (A) has a structural unit of a divinyl aromatic compound and a structural unit of a monovinyl aromatic compound, comprises 10 to 90 mol % of a structural unit represented by the following formula (a1), has a hydroxyl equivalent of 100 to 30,000 g/equiv, a number average molecular weight (Mn) of 400 to 30,000, and a molecular weight distribution (Mw/Mn) of 10 or less, and accounts for 5 to 60 wt % of the composition.

Abstract: The present invention relates to a system, as well as articles and holographic recording medium comprising the system, where the system comprises: a polymerizable component comprising at least one photoactive polymerizable material; and a photoinitiator component comprising at least one photoinitiator for causing the polymerizable component to polymerize to thereby form a plurality of holographic gratings when activated by exposure to a photoinitiating light source; wherein when a portion of the polymerizable component has been polymerized to form at least one holographic grating, the unpolymerized portion of the polymerizable component is resistant to further polymerization when not exposed to the photoinitiating light source. The present invention also provides methods for forming at least one holographic grating in a holographic recording medium having such a photopolymerizable system.

Abstract: An all-polymer grating microstructure device that exhibits a zero-order reflection under white light comprises a first polymer having a first refractive index and configured as a microstructure embedded within a second polymer having a second refractive index, each of the polymers of the first and second polymers at least translucent to white light with the proviso that the refractive index of the first polymer is at least 0.05 greater than the refractive index of the second polymer.

Abstract: A coating composition containing a coating base resin and a C4-C10 alcohol as a main solvent, and a method for forming a fine contact of a semiconductor device including the steps of preparing the coating composition, forming a photoresist film on a semiconductor substrate having an underlying layer, performing exposure with a contact mask and developing processes to form a photoresist pattern for contact on the photoresist film, and coating the coating composition on the photoresist pattern to form a coating film.

Abstract: A three-dimensional holographic display device includes a holographic display medium constituted by a photorefractive organic composition, and an optical system for recording and reproducing a holographic image using the holographic display medium. The photorefractive organic composition includes a photorefractive organic polymer having a tri-alkyl amino side-chain group.

Abstract: Stamps and methods of making stamps for applications in anti-counterfeiting and authentication. The stamps are relatively small in size and feature nanoscale and microscale identification regions and features. High throughput manufacturing and high resolution methods are used to make the stamps including electron beam lithography and optical lithography. Anti-fouling coatings can be applied.

Abstract: There are provided compositions, optical data storage media and methods of using the optical data storage. The compositions comprise a non-linear sensitizer comprising one or more platinum ethynyl complexes capable of absorbing actinic radiation to cause upper triplet energy transfer to a reactant that undergoes a photochemical change upon triplet excitation.

Abstract: Hybrid white-light viewable holograms and methods for making them. The holograms are hybrid reflection holograms made using the diffractive structures or gratings of a holographic object such as a transmission hologram or holographic optical element (HOE). The wavefronts of the diffractive structures are converted into a reflection hologram by scanning them with a coherent light source having a profiled narrow beam. The hybrid reflection hologram can exhibit display parameters including the multiple colors, solidity, and color stability of white light reflection holograms, the diffractive color shifting of a white light transmission hologram, three dimensional imaging and a wide variety of dynamic changes. Different areas or images with each of these effects can be combined in a single hologram. These hybrid reflection holograms are ideal for security and forgery prevention applications.

Abstract: Provided is a transmission-type volume hologram recording medium for use in a two-beam hologram recording system, which has a high diffraction efficiency and is capable of significantly reducing the intensity of higher-order diffracted light, which causes a noise, than first-order diffracted light. The transmission-type volume hologram recording medium includes two facing substrates of dissimilar materials and, held between them, a volume hologram recording layer of a volume hologram recording photosensitive composition. The substrates holding the volume hologram recording layer therebetween preferably have transparency in the visible light region and have thicknesses each from 2 to 2000 ?m. The difference in refractive index between the two substrates holding the volume hologram recording layer therebetween is preferably from 0.001 to 0.5. The difference in thickness between the two substrates holding the volume hologram recording layer therebetween is preferably from 1 to 1500 ?m.

Abstract: A holographic sensor comprising a thin film polymer matrix that undergoes a change in response to a substance to be sensed, the matrix containing within its volume a set of two or more holographic recordings, each recording providing a holographic image when the sensor is illuminated, wherein the presence or appearance of each image is visible to the eye as a function of the response of the sensor to the substance to be sensed. The images provide the dynamic range of the sensor. Such a sensor can be used to provide a visible image that changes or appears to the eye in response to an analyte.

Abstract: The present invention is provided to enhance security of a volume hologram by recording therein individualized information such as information of character, numerical character, picture pattern, biometric matter and/or the like by irradiating laser light to the volume hologram thereby modifying the same physically or chemically, and is related to a laser marking hologram comprising a volume hologram layer 2 including interference fringes recorded therein, wherein the volume hologram layer 2 includes information of character, numerical character, picture pattern, biometric matter, and/or the like recorded therein having a contrast between an irradiated portion and a non-irradiated portion thereof provided by selectively irradiating laser light 10 to the volume hologram layer 2 in a manner to modify 11 the irradiated portion.