And Binder, Coating Aid, Solvent, Emulsifier, Hardener, Chemical Sensitizer, Or Optical Sensitizer Patents (Class 430/377)
  • Patent number: 4419441
    Abstract: Hydrophobic substances, particularly hydrophobic additive for photographic layers such as couplers may be dispersed in an aqueous medium in a two--or more--stage process using an oil-former. In a main dispersion stage the total quantity of the hydrophobic substance is dispersed in the aqueous medium without oil-former or with only part of the total quantity of oil-former. The residual portion of oil-former is dispersed in the aqueous medium without hydrophobic substance in at least one further dispersion stage preceding or following the main dispersion stage. The oil-former used is preferably a compound or a mixture of compounds selected from triaryl phosphates, dialkyl phthalates, monoesters of .alpha.-substituted succinic acid or of hydrogenated phthalic acids and aliphatic or cycloaliphatic alcohols of at least 10 carbon atoms. The process yields dispersions of improved stability of digestion.
    Type: Grant
    Filed: April 11, 1983
    Date of Patent: December 6, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Fritz Nittel, Helmut Mader
  • Patent number: 4418140
    Abstract: A process for the development of color photographic light-sensitive material is described. The process comprises color developing an exposed light-sensitive material in the presence of a compound of the general formula: ##STR1## wherein M is a hydrogen atom, an alkali metal atom, NH.sub.4 or a protective group for the mercapto group which undergoes cleavage by the action of an alkali; R is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and R' is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms. This process prevents the formation of color development fog without seriously reducing sensitivity.
    Type: Grant
    Filed: April 8, 1982
    Date of Patent: November 29, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shoji Ishiguro, Tadao Shishido, Tatsuo Nishimura
  • Patent number: 4410624
    Abstract: The invention relates to a process of dispersing oil-soluble photographic additives having a silver-halide base for information recording materials.According to the invention, compounds of the following general formula: ##STR1## are used as auxiliary dispersing agents. The symbolsR represents hydrogen, alkyl with 1 to 8 C atoms,M represents hydrogen, alkali metal, ammonium, andX represents OR or SO.sub.3 M.
    Type: Grant
    Filed: March 26, 1982
    Date of Patent: October 18, 1983
    Assignee: VEB Filmfabrik Wolfen
    Inventors: Dieter Plaschnick, Christoph Roth, Bernd Noll, Walter Kroha, Lothar Kuhnert
  • Patent number: 4404273
    Abstract: A process for the production of photographic color images by the silver dye bleach process, by exposure, silver development, dye formation, dye bleach, silver bleach and fixing of a photographic material which, in a light-sensitive silver halide emulsion layer or in an adjacent layer, contains, dispersed in oil, an oil-soluble triazene of the formula ##STR1## and an oil-soluble coupling component of the formula ##STR2## in which Ar.sub.1 is aryl or an aromatic heterocyclic radical, R.sub.1 is hydrogen, alkyl, aryl, hydroxyl, --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1 or --OL.sub.1, in which L.sub.1 is alkyl and r is 1, 2 or 3, or R.sub.1 is ##STR3## in which V is hydrogen or alkyl, and R.sub.2 is alkyl, aryl or --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1, or R.sub.1 and R.sub.2, conjointly with the nitrogen atom to which they are bonded, form a ring, A.sub.1 and A.sub.2 independently of one another are an amine of the formula --NT.sub.1 T.sub.2, in which T.sub.1 and T.sub.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: September 13, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Eddy Forte, Mario Fryberg, Gerald Jan
  • Patent number: 4401751
    Abstract: Silver halide emulsions, which have been precipitated in the presence of polymers having recurring units with a 8-hydroxy quinoline structure are suitable for the preparation of vesicular images.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: August 30, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
  • Patent number: 4395478
    Abstract: A radiation-sensitive emulsion for use in forming a direct-positive image is disclosed. The emulsion is comprised of core-shell silver halide grains. The shell portions of the grains contain polyvalent metal ions to reduce rereversal.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: July 26, 1983
    Assignee: Eastman Kodak Company
    Inventor: Harry A. Hoyen
  • Patent number: 4388403
    Abstract: Dispersions of hydrophobic substances in water are prepared by dissolving the hydrophobic substance together with an ionomeric polyaddition or condensation product in an organic, water-miscible solvent or a mixture of such a solvent with water, diluting the solution with water and removing the organic solvent. The dispersions are excellently suitable for the preparation of photographic recording materials.
    Type: Grant
    Filed: September 24, 1981
    Date of Patent: June 14, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Gunter Helling, Helmut Reiff, Wolfgang Himmelmann, Gunter Renner
  • Patent number: 4385110
    Abstract: A process for preparing a color photographic light-sensitive material, which comprises incorporating at least one oil soluble photographic additive into a hydrophilic colloid aqueous solution by dispersing in the presence of an anionic surface active agent having one or more hydrocarbon chain(s), at least one of which is a hydrophobic hydrocarbon chain of 4 to 18 carbon atoms wherein the hydrogen atoms of one or more of the hydrocarbon chain(s) are wholly or partly substituted with fluorine, and having 1 to 3 --SO.sub.3 M or OSO.sub.3 M groups (M being a hydrogen atom or a cation) as an anionic moiety.
    Type: Grant
    Filed: August 26, 1981
    Date of Patent: May 24, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Maskazu Yoneyama, Takeshi Mikami, Nobuo Tsuji
  • Patent number: 4379836
    Abstract: Process for the production of photographic emulsions consisting of water-immiscible or water-insoluble organic substances and an aqueous solution of an organic binder, characterized in that the hydrophilic and hydrophobic phases are heated separately, each to its particular temperature above its liquefaction point, and then continuously dosed into a dispersing chamber.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: April 12, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Hildegard Schnoring, Karl-Wilhelm Schranz, Gunther Koepke
  • Patent number: 4378425
    Abstract: The invention relates to a process for the production of photographic emulsates consisting of dispersions of water-immiscible or water-insoluble particles in aqueous binder solution, characterized in that the entire non-aqueous phase is initially introduced at a temperature above the liquefaction temperatures of the aqueous and non-aqueous phases, after which a relatively small volume of aqueous phase is emulsified continuously or in portions into the non-aqueous phase by known methods and then more aqueous phase is introduced while emulsification is continued in such a quantity that the viscosity of the emulsion passes through a maximum (indicating phase reversal into an emulsion of non-aqueous particles in aqueous dispersion medium (FIG. 1)).
    Type: Grant
    Filed: August 12, 1981
    Date of Patent: March 29, 1983
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Hildegard Schnoring, Karl-Wilhelm Schranz, Gunther Koepke
  • Patent number: 4368259
    Abstract: Hydrophilic color-forming compounds such as couplers and color-providing compounds for the dye diffusion transfer process may be emulsified with the aid of oil formers when they are in admixture with aliphatic tertiary hydroxy amino compounds as specified hereinafter.
    Type: Grant
    Filed: January 15, 1981
    Date of Patent: January 11, 1983
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Fritz Nittel, Hans Langen, Erwin Ranz
  • Patent number: 4353979
    Abstract: A silver halide photographic material containing a solution of a 5-pyrazolone type magneta coupler and a high-boiling organic solvent of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent an aliphatic or aromatic group with a carbon atom of R.sub.3 directly bonded to the phosphorus atom.
    Type: Grant
    Filed: July 16, 1980
    Date of Patent: October 12, 1982
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Sadatugu Terada, Hideaki Arai, Kenji Itoh, Hiroshi Sugita, Katsumi Matsuura, Thuneo Wada
  • Patent number: 4349455
    Abstract: A process for emulsification which comprises producing an oily phase solution of a hydrophobic material in a dissolving-emulsifying tank equipped with a high speed dispersing means by stirring the hydrophobic material directly or dissolving the hydrophobic material or a hydrophobic material and an emulsifying agent in an organic solvent with heating, forming a water-in-oil emulsion by adding water or water and an emulsifying agent to said solution of the hydrophobic material with stirring, continuing the addition of water or water and the emulsifying agent to form an oil-in-water emulsion by phase inversion, adding a water-soluble binder to said oil-in-water emulsion and stirring the emulsion to form the desired oil-in-water emulsion.
    Type: Grant
    Filed: March 27, 1980
    Date of Patent: September 14, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuo Yamamura, Motoaki Takeda
  • Patent number: 4297438
    Abstract: Color images are obtained by chromogenic development of a colorphotographic material comprising several differently spectrally sensitized silver halide emulsions and color couplers associated thereto, a hydrophobic cyan coupler being incorporated by means of a hydrophobic coupler solvent and a hydrophobic yellow coupler being incorporated without a coupler solvent, when a color developing composition is used comprising a hydrophilic and a hydrophobic color developer compound. The color images have good stability of the cyan partial image to tropical conditions and good lightfastness of the yellow partial image.
    Type: Grant
    Filed: July 27, 1979
    Date of Patent: October 27, 1981
    Assignee: AGFA-Gevaert Aktiengesellschaft
    Inventors: Helmut Haseler, Heinz Meckl, Karl Lohmer, Willibald Pelz
  • Patent number: 4291113
    Abstract: A method for dispersing an oil-soluble photographic additive into water or a hydrophilic colloid composition wherein an oil-soluble photographic additive is dispersed in water or a hydrophilic colloid composition in the presence of a polymer having a recurring unit represented by the following formula (I):--(A).sub.x -- --(B).sub.y -- (I)wherein A represents an ethylenically unsaturated monomer containing a sulfonic acid group; B represents a copolymerizable ethylenically unsaturated monomer; x is about 10 to 100 mol%; and y is about 0 to 90 mol%.
    Type: Grant
    Filed: February 21, 1980
    Date of Patent: September 22, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junji Minamizono, Masakazu Yoneyama, Jun Sasaki
  • Patent number: 4284709
    Abstract: A process for incorporating photographic additives which are sparingly soluble to insoluble in water into a free-flowing, aqueous preparation which contains a hydrophilic colloid and is used to prepare photographic layers, by mixing the photographic additives with a combination of at least one non-ionic alkylphenol/alkylene oxide or diphenolmethane/alkylene oxide adduct and at least one anionic esterification product of these adducts and, optionally, a water-immiscible solvent and then finely dispersing this mixture in an aqueous solution of the hydrophilic colloid, which solution contains further water-soluble or dispersed water-insoluble constituents optionally.Spontaneous emulsions of the photographic additives with good fine dispersion are obtained in this way without high expenditure of mechanical energy. The emulsions are suitable for the preparation of photographic layers, which are used in photographic materials with improved characteristics.
    Type: Grant
    Filed: May 8, 1980
    Date of Patent: August 18, 1981
    Assignee: Ciba-Geigy Aktiengesellschaft
    Inventor: Ivan Tomka
  • Patent number: 4275145
    Abstract: A method for dispersing an oil-soluble photographic additive into a hydrophilic colloid composition is disclosed wherein a solution of an oil-soluble photographic additive in an organic solvent or the melted oil-soluble photographic additive is dispersed in a hydrophilic colloid containing an anionic surface active agent and lecithin together with a gelatin derivative.
    Type: Grant
    Filed: December 11, 1979
    Date of Patent: June 23, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takeshi Mikami
  • Patent number: 4268617
    Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide emulsion layer, at least one of the layers of said photographic sensitive material containing at least one compound selected from the group consisting of those compounds represented by the formulae (I), (II), (III) and (IV):[Co(NH.sub.3).sub.6 ][R.sup.1 COO].sub.3 (I)[Co(NH.sub.3).sub.6 ][R.sup.2 OOCR.sup.3 COO].sub.3 (II)[Co(NH.sub.3).sub.5 (R.sup.4 COO)]X.sub.2 (III)[Co(NH.sub.3).sub.5 (R.sup.5 NH.sub.2)]X.sub.3 (IV)wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group having at least 3 carbon atoms or a fluorine-substituted alkyl group having at least 1 carbon atom; R.sup.3 is an alkylene group; R.sup.5 is an alkyl group having at least 1 carbon atom; X is a halogen atom, a nitrate ion, a sulfate ion, or a carboxylate ion is disclosed.
    Type: Grant
    Filed: September 27, 1979
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akio Mitsui, Yoshiaki Suzuki
  • Patent number: 4264717
    Abstract: Compounds of the formula ##STR1## are useful in photographic materials and processes for the color development.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: April 28, 1981
    Assignee: AGFA-Gevaert, A.G.
    Inventors: Helmut Haseler, Fritz Nittel
  • Patent number: 4239851
    Abstract: A silver halide photographic light-sensitive material and a process for preparing the same are disclosed wherein an oil-soluble photographic additive and, in particular, a cyan coupler is dissolved in an epoxy compound of the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group or substituted alkyl group containing 1 to 40 carbon atoms, an alkoxycarbonyl group or substituted alkoxycarbonyl group containing 1 to 40 carbon atoms, or a hydrogen atom, provided that R.sub.1, R.sub.2, R.sub.3 and R.sub.4 do not represent hydrogen atoms at the same time and that the sum of the number of carbon atoms of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 8 to 60, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and may combine to form a ring; or in an epoxy compound formed by linking two compounds of said formula (I) which may be the same or different through any of R.sub.1 to R.sub.4 or the ring formed by R.sub.1 to R.sub.4.
    Type: Grant
    Filed: February 1, 1979
    Date of Patent: December 16, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Aoki, Yukio Yokota
  • Patent number: 4232112
    Abstract: In a process of developing an imagewise exposed silver halide color photographic photosensitive material with a color developing solution and then bleach-fixing with a bleach-fixing solution, the improvement which comprises adding, to at least one of the color developing solution and the bleach-fixing solution, at least one whitening agent selected from 4,4'-diaminostilbenedisulfonic acid derivatives and at least one additive selected from sulfonic acid derivatives of benzene or naphthalene, optionally containing alkyl or alkenyl groups.
    Type: Grant
    Filed: February 5, 1979
    Date of Patent: November 4, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventor: Satoru Kuse
  • Patent number: 4211836
    Abstract: A method for dispersing oil-soluble photographic additives into a hydrophilic colloid composition is disclosed characterized by the use of lecithin in conjunction with an anionic surface active agent containing an --SO.sub.3 M or --OSO.sub.3 M moiety wherein M represents a cation and a hydrophobic group having 8 to 30 carbon atoms.
    Type: Grant
    Filed: January 18, 1979
    Date of Patent: July 8, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masakazu Yoneyama, Yasuo Mukunoki, Takeshi Mikami, Jun Sasaki
  • Patent number: 4199354
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photograhically useful group.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Paul B. Condit
  • Patent number: 4199363
    Abstract: An improved process is disclosed for uniformly dispersing hydrophobic materials through a hydrophilic colloid layer such as, for example, a photographically useful layer containing gelatin. The process over which the present invention is a valuable improvement comprises the steps:(a) forming an aqueous dispersion by intermixing the hydrophobic material and an aqueous polymeric latex, optionally including gelatin in the dispersion;(b) forming a wet layer by coating onto a suitable support the aqueous dispersion from step (a); and(c) thereafter removing a substantial proportion of the water from the wet layer through which the hydrophobic material is dispersed.The present process relates particularly to improvements in step (a), wherein the "aqueous dispersion" is formed by blending a loadable polymeric latex into a solution of the hydrophobic material dissolved in a water-miscible solvent using techniques which avoid coagulation of the hydrophobic material or the particles of the latex.
    Type: Grant
    Filed: November 3, 1978
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventor: Tsang J. Chen
  • Patent number: T102402
    Abstract: A water-insoluble organic photographic addendum is recovered from a dispersion of a mixture thereof and an oil-former in an aqueous medium containing a hydrophilic colloid and a surface active agent by adding a selected oleophilic non-ionic surface active agent.
    Type: Grant
    Filed: April 29, 1982
    Date of Patent: November 2, 1982
    Inventor: David J. Young