And Binder, Coating Aid, Solvent, Emulsifier, Hardener, Chemical Sensitizer, Or Optical Sensitizer Patents (Class 430/377)
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Patent number: 4419441Abstract: Hydrophobic substances, particularly hydrophobic additive for photographic layers such as couplers may be dispersed in an aqueous medium in a two--or more--stage process using an oil-former. In a main dispersion stage the total quantity of the hydrophobic substance is dispersed in the aqueous medium without oil-former or with only part of the total quantity of oil-former. The residual portion of oil-former is dispersed in the aqueous medium without hydrophobic substance in at least one further dispersion stage preceding or following the main dispersion stage. The oil-former used is preferably a compound or a mixture of compounds selected from triaryl phosphates, dialkyl phthalates, monoesters of .alpha.-substituted succinic acid or of hydrogenated phthalic acids and aliphatic or cycloaliphatic alcohols of at least 10 carbon atoms. The process yields dispersions of improved stability of digestion.Type: GrantFiled: April 11, 1983Date of Patent: December 6, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Fritz Nittel, Helmut Mader
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Patent number: 4418140Abstract: A process for the development of color photographic light-sensitive material is described. The process comprises color developing an exposed light-sensitive material in the presence of a compound of the general formula: ##STR1## wherein M is a hydrogen atom, an alkali metal atom, NH.sub.4 or a protective group for the mercapto group which undergoes cleavage by the action of an alkali; R is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms; and R' is a hydrogen atom or an alkyl group containing 1 to 3 carbon atoms. This process prevents the formation of color development fog without seriously reducing sensitivity.Type: GrantFiled: April 8, 1982Date of Patent: November 29, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Mifune, Shoji Ishiguro, Tadao Shishido, Tatsuo Nishimura
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Patent number: 4410624Abstract: The invention relates to a process of dispersing oil-soluble photographic additives having a silver-halide base for information recording materials.According to the invention, compounds of the following general formula: ##STR1## are used as auxiliary dispersing agents. The symbolsR represents hydrogen, alkyl with 1 to 8 C atoms,M represents hydrogen, alkali metal, ammonium, andX represents OR or SO.sub.3 M.Type: GrantFiled: March 26, 1982Date of Patent: October 18, 1983Assignee: VEB Filmfabrik WolfenInventors: Dieter Plaschnick, Christoph Roth, Bernd Noll, Walter Kroha, Lothar Kuhnert
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Patent number: 4404273Abstract: A process for the production of photographic color images by the silver dye bleach process, by exposure, silver development, dye formation, dye bleach, silver bleach and fixing of a photographic material which, in a light-sensitive silver halide emulsion layer or in an adjacent layer, contains, dispersed in oil, an oil-soluble triazene of the formula ##STR1## and an oil-soluble coupling component of the formula ##STR2## in which Ar.sub.1 is aryl or an aromatic heterocyclic radical, R.sub.1 is hydrogen, alkyl, aryl, hydroxyl, --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1 or --OL.sub.1, in which L.sub.1 is alkyl and r is 1, 2 or 3, or R.sub.1 is ##STR3## in which V is hydrogen or alkyl, and R.sub.2 is alkyl, aryl or --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1, or R.sub.1 and R.sub.2, conjointly with the nitrogen atom to which they are bonded, form a ring, A.sub.1 and A.sub.2 independently of one another are an amine of the formula --NT.sub.1 T.sub.2, in which T.sub.1 and T.sub.Type: GrantFiled: December 2, 1981Date of Patent: September 13, 1983Assignee: Ciba-Geigy AGInventors: Eddy Forte, Mario Fryberg, Gerald Jan
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Patent number: 4401751Abstract: Silver halide emulsions, which have been precipitated in the presence of polymers having recurring units with a 8-hydroxy quinoline structure are suitable for the preparation of vesicular images.Type: GrantFiled: September 28, 1981Date of Patent: August 30, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Edith Weyde, Harald von Rintelen, Wilhelm Saleck, Heinz-Horst Teitscheid
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Patent number: 4395478Abstract: A radiation-sensitive emulsion for use in forming a direct-positive image is disclosed. The emulsion is comprised of core-shell silver halide grains. The shell portions of the grains contain polyvalent metal ions to reduce rereversal.Type: GrantFiled: November 12, 1981Date of Patent: July 26, 1983Assignee: Eastman Kodak CompanyInventor: Harry A. Hoyen
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Patent number: 4388403Abstract: Dispersions of hydrophobic substances in water are prepared by dissolving the hydrophobic substance together with an ionomeric polyaddition or condensation product in an organic, water-miscible solvent or a mixture of such a solvent with water, diluting the solution with water and removing the organic solvent. The dispersions are excellently suitable for the preparation of photographic recording materials.Type: GrantFiled: September 24, 1981Date of Patent: June 14, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Gunter Helling, Helmut Reiff, Wolfgang Himmelmann, Gunter Renner
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Patent number: 4385110Abstract: A process for preparing a color photographic light-sensitive material, which comprises incorporating at least one oil soluble photographic additive into a hydrophilic colloid aqueous solution by dispersing in the presence of an anionic surface active agent having one or more hydrocarbon chain(s), at least one of which is a hydrophobic hydrocarbon chain of 4 to 18 carbon atoms wherein the hydrogen atoms of one or more of the hydrocarbon chain(s) are wholly or partly substituted with fluorine, and having 1 to 3 --SO.sub.3 M or OSO.sub.3 M groups (M being a hydrogen atom or a cation) as an anionic moiety.Type: GrantFiled: August 26, 1981Date of Patent: May 24, 1983Assignee: Fuji Photo Film Co., Ltd.Inventors: Maskazu Yoneyama, Takeshi Mikami, Nobuo Tsuji
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Patent number: 4379836Abstract: Process for the production of photographic emulsions consisting of water-immiscible or water-insoluble organic substances and an aqueous solution of an organic binder, characterized in that the hydrophilic and hydrophobic phases are heated separately, each to its particular temperature above its liquefaction point, and then continuously dosed into a dispersing chamber.Type: GrantFiled: August 24, 1981Date of Patent: April 12, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Hildegard Schnoring, Karl-Wilhelm Schranz, Gunther Koepke
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Patent number: 4378425Abstract: The invention relates to a process for the production of photographic emulsates consisting of dispersions of water-immiscible or water-insoluble particles in aqueous binder solution, characterized in that the entire non-aqueous phase is initially introduced at a temperature above the liquefaction temperatures of the aqueous and non-aqueous phases, after which a relatively small volume of aqueous phase is emulsified continuously or in portions into the non-aqueous phase by known methods and then more aqueous phase is introduced while emulsification is continued in such a quantity that the viscosity of the emulsion passes through a maximum (indicating phase reversal into an emulsion of non-aqueous particles in aqueous dispersion medium (FIG. 1)).Type: GrantFiled: August 12, 1981Date of Patent: March 29, 1983Assignee: Agfa Gevaert AktiengesellschaftInventors: Hildegard Schnoring, Karl-Wilhelm Schranz, Gunther Koepke
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Patent number: 4368259Abstract: Hydrophilic color-forming compounds such as couplers and color-providing compounds for the dye diffusion transfer process may be emulsified with the aid of oil formers when they are in admixture with aliphatic tertiary hydroxy amino compounds as specified hereinafter.Type: GrantFiled: January 15, 1981Date of Patent: January 11, 1983Assignee: Agfa-Gevaert AktiengesellschaftInventors: Fritz Nittel, Hans Langen, Erwin Ranz
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Patent number: 4353979Abstract: A silver halide photographic material containing a solution of a 5-pyrazolone type magneta coupler and a high-boiling organic solvent of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represent an aliphatic or aromatic group with a carbon atom of R.sub.3 directly bonded to the phosphorus atom.Type: GrantFiled: July 16, 1980Date of Patent: October 12, 1982Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Sadatugu Terada, Hideaki Arai, Kenji Itoh, Hiroshi Sugita, Katsumi Matsuura, Thuneo Wada
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Patent number: 4349455Abstract: A process for emulsification which comprises producing an oily phase solution of a hydrophobic material in a dissolving-emulsifying tank equipped with a high speed dispersing means by stirring the hydrophobic material directly or dissolving the hydrophobic material or a hydrophobic material and an emulsifying agent in an organic solvent with heating, forming a water-in-oil emulsion by adding water or water and an emulsifying agent to said solution of the hydrophobic material with stirring, continuing the addition of water or water and the emulsifying agent to form an oil-in-water emulsion by phase inversion, adding a water-soluble binder to said oil-in-water emulsion and stirring the emulsion to form the desired oil-in-water emulsion.Type: GrantFiled: March 27, 1980Date of Patent: September 14, 1982Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Yamamura, Motoaki Takeda
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Patent number: 4297438Abstract: Color images are obtained by chromogenic development of a colorphotographic material comprising several differently spectrally sensitized silver halide emulsions and color couplers associated thereto, a hydrophobic cyan coupler being incorporated by means of a hydrophobic coupler solvent and a hydrophobic yellow coupler being incorporated without a coupler solvent, when a color developing composition is used comprising a hydrophilic and a hydrophobic color developer compound. The color images have good stability of the cyan partial image to tropical conditions and good lightfastness of the yellow partial image.Type: GrantFiled: July 27, 1979Date of Patent: October 27, 1981Assignee: AGFA-Gevaert AktiengesellschaftInventors: Helmut Haseler, Heinz Meckl, Karl Lohmer, Willibald Pelz
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Patent number: 4291113Abstract: A method for dispersing an oil-soluble photographic additive into water or a hydrophilic colloid composition wherein an oil-soluble photographic additive is dispersed in water or a hydrophilic colloid composition in the presence of a polymer having a recurring unit represented by the following formula (I):--(A).sub.x -- --(B).sub.y -- (I)wherein A represents an ethylenically unsaturated monomer containing a sulfonic acid group; B represents a copolymerizable ethylenically unsaturated monomer; x is about 10 to 100 mol%; and y is about 0 to 90 mol%.Type: GrantFiled: February 21, 1980Date of Patent: September 22, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Junji Minamizono, Masakazu Yoneyama, Jun Sasaki
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Patent number: 4284709Abstract: A process for incorporating photographic additives which are sparingly soluble to insoluble in water into a free-flowing, aqueous preparation which contains a hydrophilic colloid and is used to prepare photographic layers, by mixing the photographic additives with a combination of at least one non-ionic alkylphenol/alkylene oxide or diphenolmethane/alkylene oxide adduct and at least one anionic esterification product of these adducts and, optionally, a water-immiscible solvent and then finely dispersing this mixture in an aqueous solution of the hydrophilic colloid, which solution contains further water-soluble or dispersed water-insoluble constituents optionally.Spontaneous emulsions of the photographic additives with good fine dispersion are obtained in this way without high expenditure of mechanical energy. The emulsions are suitable for the preparation of photographic layers, which are used in photographic materials with improved characteristics.Type: GrantFiled: May 8, 1980Date of Patent: August 18, 1981Assignee: Ciba-Geigy AktiengesellschaftInventor: Ivan Tomka
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Patent number: 4275145Abstract: A method for dispersing an oil-soluble photographic additive into a hydrophilic colloid composition is disclosed wherein a solution of an oil-soluble photographic additive in an organic solvent or the melted oil-soluble photographic additive is dispersed in a hydrophilic colloid containing an anionic surface active agent and lecithin together with a gelatin derivative.Type: GrantFiled: December 11, 1979Date of Patent: June 23, 1981Assignee: Fuji Photo Film Co., Ltd.Inventor: Takeshi Mikami
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Patent number: 4268617Abstract: A silver halide color photographic light-sensitive material comprising a support and at least one silver halide emulsion layer, at least one of the layers of said photographic sensitive material containing at least one compound selected from the group consisting of those compounds represented by the formulae (I), (II), (III) and (IV):[Co(NH.sub.3).sub.6 ][R.sup.1 COO].sub.3 (I)[Co(NH.sub.3).sub.6 ][R.sup.2 OOCR.sup.3 COO].sub.3 (II)[Co(NH.sub.3).sub.5 (R.sup.4 COO)]X.sub.2 (III)[Co(NH.sub.3).sub.5 (R.sup.5 NH.sub.2)]X.sub.3 (IV)wherein R.sup.1, R.sup.2 and R.sup.4 each represent an alkyl group having at least 3 carbon atoms or a fluorine-substituted alkyl group having at least 1 carbon atom; R.sup.3 is an alkylene group; R.sup.5 is an alkyl group having at least 1 carbon atom; X is a halogen atom, a nitrate ion, a sulfate ion, or a carboxylate ion is disclosed.Type: GrantFiled: September 27, 1979Date of Patent: May 19, 1981Assignee: Fuji Photo Film Co., Ltd.Inventors: Akio Mitsui, Yoshiaki Suzuki
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Patent number: 4264717Abstract: Compounds of the formula ##STR1## are useful in photographic materials and processes for the color development.Type: GrantFiled: October 17, 1979Date of Patent: April 28, 1981Assignee: AGFA-Gevaert, A.G.Inventors: Helmut Haseler, Fritz Nittel
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Patent number: 4239851Abstract: A silver halide photographic light-sensitive material and a process for preparing the same are disclosed wherein an oil-soluble photographic additive and, in particular, a cyan coupler is dissolved in an epoxy compound of the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group or substituted alkyl group containing 1 to 40 carbon atoms, an alkoxycarbonyl group or substituted alkoxycarbonyl group containing 1 to 40 carbon atoms, or a hydrogen atom, provided that R.sub.1, R.sub.2, R.sub.3 and R.sub.4 do not represent hydrogen atoms at the same time and that the sum of the number of carbon atoms of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 8 to 60, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and may combine to form a ring; or in an epoxy compound formed by linking two compounds of said formula (I) which may be the same or different through any of R.sub.1 to R.sub.4 or the ring formed by R.sub.1 to R.sub.4.Type: GrantFiled: February 1, 1979Date of Patent: December 16, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Kozo Aoki, Yukio Yokota
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Patent number: 4232112Abstract: In a process of developing an imagewise exposed silver halide color photographic photosensitive material with a color developing solution and then bleach-fixing with a bleach-fixing solution, the improvement which comprises adding, to at least one of the color developing solution and the bleach-fixing solution, at least one whitening agent selected from 4,4'-diaminostilbenedisulfonic acid derivatives and at least one additive selected from sulfonic acid derivatives of benzene or naphthalene, optionally containing alkyl or alkenyl groups.Type: GrantFiled: February 5, 1979Date of Patent: November 4, 1980Assignee: Konishiroku Photo Industry Co., Ltd.Inventor: Satoru Kuse
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Patent number: 4211836Abstract: A method for dispersing oil-soluble photographic additives into a hydrophilic colloid composition is disclosed characterized by the use of lecithin in conjunction with an anionic surface active agent containing an --SO.sub.3 M or --OSO.sub.3 M moiety wherein M represents a cation and a hydrophobic group having 8 to 30 carbon atoms.Type: GrantFiled: January 18, 1979Date of Patent: July 8, 1980Assignee: Fuji Photo Film Co., Ltd.Inventors: Masakazu Yoneyama, Yasuo Mukunoki, Takeshi Mikami, Jun Sasaki
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Patent number: 4199354Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photograhically useful group.Type: GrantFiled: December 20, 1974Date of Patent: April 22, 1980Assignee: Eastman Kodak CompanyInventors: Jerald C. Hinshaw, Paul B. Condit
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Patent number: 4199363Abstract: An improved process is disclosed for uniformly dispersing hydrophobic materials through a hydrophilic colloid layer such as, for example, a photographically useful layer containing gelatin. The process over which the present invention is a valuable improvement comprises the steps:(a) forming an aqueous dispersion by intermixing the hydrophobic material and an aqueous polymeric latex, optionally including gelatin in the dispersion;(b) forming a wet layer by coating onto a suitable support the aqueous dispersion from step (a); and(c) thereafter removing a substantial proportion of the water from the wet layer through which the hydrophobic material is dispersed.The present process relates particularly to improvements in step (a), wherein the "aqueous dispersion" is formed by blending a loadable polymeric latex into a solution of the hydrophobic material dissolved in a water-miscible solvent using techniques which avoid coagulation of the hydrophobic material or the particles of the latex.Type: GrantFiled: November 3, 1978Date of Patent: April 22, 1980Assignee: Eastman Kodak CompanyInventor: Tsang J. Chen
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Patent number: T102402Abstract: A water-insoluble organic photographic addendum is recovered from a dispersion of a mixture thereof and an oil-former in an aqueous medium containing a hydrophilic colloid and a surface active agent by adding a selected oleophilic non-ionic surface active agent.Type: GrantFiled: April 29, 1982Date of Patent: November 2, 1982Inventor: David J. Young