Direct Positive Process Patents (Class 430/378)
  • Patent number: 10994544
    Abstract: A cleaning liquid including a compound represented by the following formula (1): (CH3)3C—R—O(C4H8O)L—(C3H6O)m—(C2H4O)n—H??(1) and water; and a method of cleaning an ink-jet printer using the cleaning liquid. In the formula (1), R represents a linear or branched C1 to C5 hydrocarbon group, and L, m, and n each represent the average number of repeats, and L?0, m?0, n>0, and (L+m)/n=1.5/1 to 1/1.5.
    Type: Grant
    Filed: April 12, 2019
    Date of Patent: May 4, 2021
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Ha Sai, Hirotoshi Takahashi, Tetsuya Iwazaki
  • Patent number: 10185182
    Abstract: Cycloidal boundary conditions for aligning liquid crystalline materials are obtained by mechanical rubbing of a polymer coating. The rubbing is performed by a rubbing head rotating around an axis perpendicular to the rubbing plane while the alignment polymer film is being translated across the rubbing film such as only a linear portion of the alignment film touches the rubbing film at any given time.
    Type: Grant
    Filed: March 2, 2014
    Date of Patent: January 22, 2019
    Assignee: Beam Engineering for Advanced Measurements Co.
    Inventor: Nelson Tabirian
  • Patent number: 9617205
    Abstract: A method of fabricating a liquid crystal polymer film includes providing a support substrate having a surface having a shape arranged to define a form of a liquid crystal polymer film to be fabricated; applying a layer of a photoaligning material over the surface of the support substrate, the photoaligning material having an absorption band; exposing the layer of photoaligning material to a light having a linear polarization and the light comprising a wavelength within the absorption band to convert the layer of photoaligning material into a layer of photoaligned material; applying a layer of a polymerizable liquid crystal over the layer of photoaligned material; performing photopolymerization of the layer of polymerizable liquid crystal to form a liquid crystal polymer film; applying a solvent to the layer of photoaligned material, the solvent formulated to dissolve the photoaligned material to thereby release the liquid crystal polymer film from the support substrate; and removing the liquid crystal polymer
    Type: Grant
    Filed: July 28, 2015
    Date of Patent: April 11, 2017
    Assignees: Beam Engineering for Advanced Measurements Co., The United States of America as Represented by the Secretary of the Army
    Inventors: Nelson V. Tabirian, Sarik R. Nersisyan, Brian R. Kimball, Diane M. Steeves, Rafael O Vergara
  • Patent number: 7214464
    Abstract: The present invention is directed to a method of forming a positive image in a photothermographic assembly comprising a photothermographic material and an intensifying means for converting ionizing radiation, wherein the assembly has been imagewise exposed to ionizing radiation to form a latent image in the photothermographic material. The photothermographic material has at least one imaging layer comprising a potentially negative-working emulsion, wherein thermal development of unexposed silver salts in exposed areas relative to unexposed areas is inhibiting when thermally developing the imagewise exposed assembly, thereby producing a positive image. The present invention is also directed to a photothermographic assembly that can be used in the present process in which a positive image characterized by high speed and discrimination is formed when exposed and thermally heated above 150° C.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: May 8, 2007
    Assignee: Eastman Kodak Company
    Inventors: Michael R. Roberts, Kurt D. Sieber, Paul B. Gilman, Jr.
  • Publication number: 20040241595
    Abstract: A method and a device for determining imaging errors of an optical system in the production of a mask for semiconductor component fabrication, including detecting at least one parameter for the characterization of the mask selecting a stored correction data record from a correction database in a manner dependent on at least one parameter for the characterization of the mask, then determining optical measurable properties of the mask using a measuring system, combining the measurement results of the optical properties with the correction data record associated with the mask in a data processing device, and subsequently storing a measurement data record with the corrected measurement result in a database system. The measurement data record is then used for the correction of imaging errors.
    Type: Application
    Filed: April 2, 2004
    Publication date: December 2, 2004
    Applicant: Infineon Technologies AG
    Inventors: Thomas Schatz, Tanja Hagner
  • Patent number: 6605124
    Abstract: The subject of the invention is novel compounds derived from naphth-1-ol comprising at least one cationic group, their use as coupler for the oxidation dyeing of keratinous fibres, compositions for the oxidation dyeing of keratinous fibres, and in particular human keratinous fibres such as hair, containing them in combination with at least one oxidation base, as well as methods of oxidation dyeing using them.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: August 12, 2003
    Assignee: L'Oreal S.A.
    Inventors: Jean-Jacques Vandenbossche, Laurent Vidal, Jean-Baptiste Saunier, Alain LaGrange
  • Patent number: 6492100
    Abstract: A silver halide color photographic lightsensitive material comprising at least one photosensitive silver halide emulsion layer on a support, wherein the emulsion layer contains a magenta coupler represented by formula (M-1) below: wherein R1 represents a substituted or nonsubstituted alkyl group, each of L1 and L2 independently represents a substituted or nonsubstituted alkylene group, or substituted or nonsubstituted arylene group, in —L3—G, L3 represents —NH—SO2— or —SO2—NH—CO— (in these representations, bonding direction is not defined) and G represents a substituted or nonsubstituted alkyl group or substituted or nonsubstituted aryl group, alternatively —L3—G represents —COOH or OH, X represents a hydrogen atom or a group which splits off when coupling with an oxidized form of a developing agent, n represents 1 or 2, when L2 is an alkylene group, or n represents an integer from 1 to 5, when L2 is an arylene group, an
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: December 10, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Mikoshiba, Yoshio Shimura, Naoto Matsuda, Hiroshi Fukuzawa
  • Patent number: 6440650
    Abstract: A silver halide color reversal photosensitive material comprising at least one blue-sensitive emulsion layer, at least one green-sensitive emulsion layer, and at least one red-sensitive emulsion layer on a transparent support, and capable of forming a color image when the photosensitive material was subjected to color development in the presence of an aromatic primary amine color developing agent after the photosensitive material was subjected to first development of black-and-white development, wherein the silver halide content in the photosensitive material before the first development is 2.5 to 6.0 g in terms of silver per m2 of the photosensitive material, the silver halide content in an unexposed portion of the photosensitive material immediately before the color development is 1.0 to 2.5 g in terms of silver per m2 of the photosensitive material, and the maximum density of each of cyan, magenta, and yellow in the color image after the color development is 3.0 or more.
    Type: Grant
    Filed: November 9, 2000
    Date of Patent: August 27, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Matsuda, Hisashi Mikoshiba
  • Patent number: 6124082
    Abstract: Recovering the dye image on film in electronic film development following a latent holding stage obviates the problem common in prior art electronic film development of film image destruction. Recovery of the image is accomplished using a developing agent containing couplers to form a dye image. These dyes do not affect the infrared scans of the image. Upon complete development of the dye image, further dye formation is halted by the application of a coupler blocking agent, while silver development and electronic scanning may continue or halt. After halting dye formation, the film is stable for an arbitrary time in a latent stage and may be dried and stored. Following this latent stage, silver is removed from the film with a bleach-fix leaving a conventionally usable film image.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: September 26, 2000
    Assignee: Applied Science Fiction, Inc.
    Inventor: Albert D. Edgar
  • Patent number: 6114104
    Abstract: A direct positive silver halide photographic light sensitive material is disclosed, having yellow, magenta and cyan image forming units, wherein at least one of the color image forming units contains at least two internal latent image forming silver halide emulsions which are different in a factor of contribution to image formation, a silver halide emulsion having a lower factor of contribution to image formation having a part common to sensitivity of a silver silver halide emulsion contained in one of the other two image forming units, and the photographic material is subjected to exposure, based on digitized image information.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: September 5, 2000
    Assignee: Konica Corporation
    Inventors: Satoshi Masumi, Shigeo Tanaka
  • Patent number: 6033833
    Abstract: A new fogging photographic processing solution for a reversal process comprises a compound (I) and a bi-nucleophilic agent. Compound (I) corresponds to the following formula: ##STR1## wherein A is a group capable of being adsorbed to the silver halide surface, L is a linking group and r is 0 or 1, R.sub.1 and R.sub.2 are independently selected from an alkyl group, substituted or unsubstituted, and an aryl group substituted or unsubstituted. A process of producing a positive image by imagewise exposure of a reversal silver halide material comprises contacting the material with the above fogging solution or by imagewise exposure of such a material containing a compound (I) and contacting the material with a solution comprising a bi-nucleophilic agent.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: March 7, 2000
    Assignee: Eastman Kodak Company
    Inventors: Siu C. Tsoi, Peter J. Twist, David T. Southby
  • Patent number: 5723263
    Abstract: A multicolor negative photographic element comprises a support bearing a blue light-sensitive silver halide emulsion first layer and a green light-sensitized silver halide emulsion second layer wherein said second layer contains a dye sensitized to green light and wherein said first layer has associated therewith a hue correction coupler which upon coupling with oxidized developer produces a dye having a maximum absorbance in the range of 460 to 510 nm. so that the element has a D480/D440 density ratio which is greater than that exhibited by the element without the hue correction coupler. The invention also encompasses a blue sensitive silver halide emulsion layer associated with the hue correction coupler and a method of forming an image in the photographic element of the invention.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: March 3, 1998
    Assignee: Eastman Kodak Company
    Inventors: Stephen Paul Singer, Paul Barrett Merkel, Jeffrey Walter Schmoeger
  • Patent number: 5563027
    Abstract: A color reversal element having a red sensitive layer containing a cyan dye forming coupler, a green sensitive layer containing a magenta dye forming coupler, and a blue sensitive layer containing a yellow dye forming coupler, the red, green and blue sensitive layers each having a speed .gtoreq.120 as measured at a density of 0.3, a Dmax of .gtoreq.3.30 and a .increment.logE .ltoreq.1.85 measured from a density of 0.20 to 3.20, the Dmax and .increment.logE being measured following exposure and processing of the element. Daylight and tungsten balanced versions of the film are also provided. A method for processing such films and exposing them in electronic film writers is also provided. Film of the present invention allows a wide range of density values in an original film to be more faithfully reproduced and enable more faithful reproduction of colors recorded in the original scanned film.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: October 8, 1996
    Assignee: Eastman Kodak Company
    Inventors: Cheryl S. Johnston, John D. Baloga
  • Patent number: 5541040
    Abstract: Disclosed is a positive type color light sensitive material comprising a support having thereon a mainly yellow image forming layer, a mainly magenta image forming layer and a mainly cyan image forming layer;wherein, when an exposure quantity-gives minimum density of +0.2 on a first layer selected from said three layer after developing in the main spectra sensitivity region of the first layer, a second layer selected from said three layers is given lower density with said exposure than a density without said exposure.The positive type color light sensitive material is capable of providing a color proof improved in the approximation degrees of an image quality to a printed printer.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: July 30, 1996
    Assignee: Konica Corporation
    Inventors: Susumu Okawauchi, Yasuo Tosaka, Yoshiyuki Nonaka, Keiichi Hoshino
  • Patent number: 5449595
    Abstract: The present invention relates to a method for making direct-positive photographic images by developing light-sensitive materials in the presence of development nucleators which do not cause loss of sensitivity during exposure or unevenness of development. More specifically the invention relates to the formation of direct-positive images having a high maximum density and high exposure latitude and to photographic materials for use in said formation, which is accomplished by a method for making direct-positive images comprising:image-wise exposing a photographic light-sensitive silver halide material comprising a support and a layer of an internal latent image-type silver halide emulsion, the pAg of which has been adjusted to a pAg-value between 9.0 and 10.5 inclusive before coating, anddeveloping said exposed photographic silver halide material in a surface developer in the presence of a development nucleator with a group promoting adsorption to silver halide.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: September 12, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Jean-Marie Dewanckele, David Terrell, Kris Viaene
  • Patent number: 5436117
    Abstract: Disclosed is a positive type silver halide color photographic light-sensitive material comprising a support having thereon a mainly yellow image forming layer, a mainly magenta image forming layer and a mainly cyan image forming layer; wherein, when an exposure is conducted with 1/10 to 10 times an exposure amount giving minimum density of +0.2 on a first layer selected from said three layer after developing in the main spectra sensitivity region of the first layer, a second layer selected from said three layers is given lower density with said exposure than a density without said exposure; and after a photographic process comprising a color developing step, the mainly yellow, mainly magenta and mainly cyan image forming layers have the monochromatic yellow, magenta and cyan tones in toe portions thereof each of not less than 1.7. The silver halide color photographic light sensitive material is capable of providing a color proof improved in the approximation degrees of an image quality to a printed matter.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: July 25, 1995
    Assignee: Konica Corporation
    Inventors: Keiichi Hoshino, Susumu Ohkawauchi, Yasuo Tosaka, Yoshiyuki Nonaka
  • Patent number: 5436116
    Abstract: Disclosed is a silver halide color photographic light-sensitive material comprising a support having thereon a mainly yellow image forming layer, a mainly magenta image forming layer and a mainly cyan image forming layer; wherein, when an exposure is conducted within 1/10 to 10 times of an exposure amount giving minimum density of +0.2 on the first layer selected from said three layers after developing in the main spectra sensitivity region of the first layer, the second layer selected from said three layers is given lower density with said 1/10 to 10 times of exposure than a density without said 1/10 to 10 times of exposure; and reflection densities in 450 nm, 550 nm and 700 nm is not less than 0.8 respectively, before the developing.The silver halide color photographic light sensitive material is capable of providing a color proof improved in the approximation degrees of an image quality to a printed printer.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: July 25, 1995
    Assignee: Konica Corporation
    Inventors: Keiichi Hoshino, Susumu Ohkawachi, Yasuo Tosaka, Yoshiyuki Nonaka
  • Patent number: 5362621
    Abstract: A direct positive silver halide photographic material and a method for forming a high contrast image using the same are disclosed, in which a pre-fogged direct positive silver halide emulsion layer contains a salt of a nitrogen-containing compound having at least one pyridine nucleus and at least one pyridinium nucleus. The photographic material, after imagewise exposure, is developed with an alkaline developer containing a developing agent, preferably a reductance compound. The photographic material provides high contrast characteristics having a gamma exceeding 10.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: November 8, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Naoki Obi, Kiyoshi Suematsu, Yasuhiko Kojima, Masatoshi Katayama, Yasuo Shigemitsu
  • Patent number: 5336590
    Abstract: A silver halide color photographic photosensitive material is disclosed which comprises a transparent support on which there are provided at least one cyan color forming coupler containing layer, at least one magenta color forming coupler containing layer, and at least one yellow color forming coupler containing layer, and at least one light-insensitive layer, wherein a compound represented by formula (I), a compound represented by formula (IIa) or (IIb) or both, and an internal latent image forming silver halide grain are contained in the photographic material: ##STR1## wherein Z.sup.11 represents a group of non-metal atoms which is required to form a five or six membered heterocyclic ring, and Z.sup.11 may be substituted with substituent groups; R.sup.11 is an aliphatic group; and R.sup.12 is a hydrogen atom, an aliphatic group or an aromatic group; R.sup.11 and R.sup.12 may be substituted with substituent groups; R.sup.12 may be joined to the heterocyclic ring completed by Z.sup.
    Type: Grant
    Filed: September 28, 1992
    Date of Patent: August 9, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Akio Mitsui
  • Patent number: 5213952
    Abstract: A method of forming a direct positive color image by imagewise exposing a photographic material having at least one emulsion layer which contains previously non-fogged internal latent image-type silver halide grains, on a support, followed by color-developing the exposed material during or after fogging thereof, wherein the photographic material contains a color sensitizing dye and at least one compound or salt thereof which satisfies the condition-1 as defined in the specification. With the image formed by the method having an elevated maximum image density with a lowered minimum image density, and with the iamge-forming method displaying extremely excellent color reproducibility.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: May 25, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Kuwashima, Akihiko Ikegawa
  • Patent number: 5153107
    Abstract: A direct positive color photographic material having comprising a support at least one previously non-fogged internal latent image-type silver halide emulsion, in which at least one green-sensitive internal latent image-type silver halide emulsion layer contains a 2-equivalent yellow-coloring coupler and a magenta-coloring coupler of the following general formula (M-II) ##STR1## where R.sub.10 represents a hydrogen atom or a substituent;Y.sub.4 represents a hydrogen atom or a removing group;Za, Zb and Zc each represents a methine group, a substituted methine group, .dbd.N-- or --NH--;one of the Za--Zb bond and the Zb--Zc bond is a double bond and the other is a single bond; and when the Zb--Zc bond is a carbon-carbon double bond, it may be part of an aromatic ring; anda dimer or a polymer at the position of R.sub.10 or Y.sub.
    Type: Grant
    Filed: November 7, 1990
    Date of Patent: October 6, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Naoyasu Deguchi
  • Patent number: 5128238
    Abstract: A method for producing color images comprising developing a negative silver halide color photographic materials and an internal latent-image type direct positive silver halide color photogaphic material, with the same developer having a pH of 9.0 to 11.5, said direct positive photographic material containing at least one compound represented by formula (N-I) as nucleating agent and at least one compound represented by (I) or (II) as magenta coupler, thereby ensuring high color reproducibility to both photographic materials: ##STR1## wherein the symbols and substituents of said formulae are as defined in the specification.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: July 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Nakazyo, Shinji Ueda, Akira Abe, Noriyuki Inoue
  • Patent number: 5128237
    Abstract: Significant improvement in color reproduction can be achieved by a direct positive silver halide color photographic material having at least one each of a blue-sensitive, green-sensitive and a red-sensitive direct positive silver halide emulsion layer, in which material at least one of said direct positive silver halide emulsion layer contains both silver chloride or a silver halide composed of silver chlorobromide or silver chloroiodobromide containing no less than 50 mol % of AgCl, and a specific compound that is capable of reacting with the oxidation product of a developing agent to release a specific compound capable of scavenging said oxidation product or a precursor of said scavenging compound.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: July 7, 1992
    Assignee: Konica Corporation
    Inventors: Nariko Kimura, Tomomi Yoshizawa, Shigeto Hirabayashi, Toyoaki Masukawa
  • Patent number: 5112732
    Abstract: A direct positive silver halide photographic material is disclosed, comprising a support having thereon at least one internal latent image silver halide emulsion layer which has not been prefogged and another hydrophilic colloid layer wherein the grains in the internal latent image silver halide emulsion is formed in the presence of an iron complex compound. The direct positive silver halide photographic material is developed and then direct positive images may be obtained with this material, which feature a high D.sub.max and a low D.sub.min. The disclosed material has a broad range of applications, including as a COM film.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: May 12, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunori Hayashi, deceased, Masahiro Hayashi, heir, Masako Hayashi, heir
  • Patent number: 5079132
    Abstract: A method for forming a color positive image which comprises steps of:(a) exposing a color positive type silver halide material including a support having thereon at least two silver halide emulsion layers which have different spectral sensitivity distribution from each other, to light passed through a filter having at least one absorption band where light is absorbed in a sharp width; at least one absorption peak thereof being in a wavelength of from 480 to 520 nm or from 580 to 620 nm, the optical density of the absorption peak being at least 0.8; the 3/4 value width of the absorption peak, designated as W 3/4, being at least 5 nm and the 3/4 value width of the absorption peak and the 1/4 value width of the absorption peak, designated as W 1/4, satisfying the following relation:W3/4= W1/4.ltoreq.30 nm.and(b) developing the exposed material.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: January 7, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akio Mitsui, Nobuyuki Kimura, Junichi Tamano, Mitsugi Kawakami
  • Patent number: 5037726
    Abstract: A method for forming a direct positive image having a high Dmax and a low Dmin, which comprises image-wise exposing a photographic light-sensitive material having on a support at least one photographic emulsion layer containing unprefogged internal latent image-type silver halide grains and developing the photographic light-sensitive material after or while fogging to form direct positive image, wherein the aforesaid development is performed in the existence of at least one compound selected from the group consisting of compounds represented by formula (I), (II), (III), (IV), (V) or (VI), acid salts of compounds represented by formula (I) to (IV) provided substituents thereof contain an amino group, and acid salts of compound represented by formula (V) or (VI); ##STR1## wherein symbols are defined as in claim 1.
    Type: Grant
    Filed: December 7, 1988
    Date of Patent: August 6, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Noriyuki Inoue
  • Patent number: 5035984
    Abstract: A method for forming a direct positive image by the steps of:(a) imagewise exposing a photosensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer containing non-prefogged silver halide grains capable of forming an internal latent image; at least one of the light-sensitive emulsion layer or the other hydrophilic colloidal layer of the photosensitive material containing the following compound (a): ##STR1## (b) developing the exposed material in the presence of a developing agent and at least one nucleating agent; and(c) at least one of fixing and bleaching said developed photosensitive material to form a positive image.When used for making computer output images, the method according to the present invention provides rapid and stable formation of direct positive images with a high Dmax and a low Dmin, and prevents re-reversal negative formation during high illuminance exposure.
    Type: Grant
    Filed: November 6, 1989
    Date of Patent: July 30, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunoi Hayashi, deceased, Masahiro Hayashi, legal representative, Masako Hayashi, legal representative
  • Patent number: 4996137
    Abstract: A method for forming a direct positive image composed of the step of developing with a surface developer an imagewise exposed photosensitive material compose of support having thereon at least one photosensitive emulsion layer containing unprefogged silver halide grains capable of forming an internal latent image; the at least the photosensitive emulsion layer composed of hexagonal tabular silver halide grains in an amount of at least 30 wt %, based on the total silver amount of silver halide grains therein; the hexagonal tabular grains having two parallel hexagonal faces, the ratio of the longest side to the shortest side of the hexagon being at most 2; the aspect ratio of the hexagonal tabular grains being from 2 to 8; and the hexagonal tabular grains having a monodisperse size distribution. The method provides increases in processing speed, maximum density, and contrast in the toe portion, and an improvement in graininess, even when exhausted processing solutions are used.
    Type: Grant
    Filed: June 21, 1990
    Date of Patent: February 26, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Katsumi Hirano, Mitsuo Saitou
  • Patent number: 4994358
    Abstract: A direct positive color light-sensitive material is disclosed, which comprises a support having thereon at least one internal latent image-forming silver halide emulsion layer containing non-prefogged silver halide grains and which contains at least one color image-forming coupler capable of producing or releasing a non-diffusible or diffusible dye upon oxidative coupling with a color developing agent, with at least one layer different from the internal latent image-forming silver halide emulsion layer containing a surface latent image-forming, negative-working silver halide emulsion and with at least one of the negative-working silver halide emulsion layer and an interlayer adjacent thereto containing at least one compound capable of releasing a fogging agent, a fogging agent precursor, a development promoter or a development promoter precursor in proportion to the amount of developed silver of the negative-working silver halide emulsion upon development processing using an aromatic primary amine developing
    Type: Grant
    Filed: August 15, 1988
    Date of Patent: February 19, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyasu Deguchi, Shigeo Hirano
  • Patent number: 4990432
    Abstract: A silver halide photographic light-sensitive material comprising a reflective support having a transmission density of not more than 0.8, having thereon, a photographic component layer comprising a silver halide emulsion layer and a layer including at least one anti-halation layer formed closer to said support than said silver halide emulsion layer is disclosed. In the photographic material, degradation of image sharpness due to use of a reflective support having low transmission density is prevented.
    Type: Grant
    Filed: November 24, 1989
    Date of Patent: February 5, 1991
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hajime Komatsu, Susumu Ohkawachi, Yasuo Tosaka, Bunzo Ueda, Keiichi Hoshimo
  • Patent number: 4968592
    Abstract: A direct positive image forming method comprising development processing an imagewise exposed photographic light-sensitive material comprising a support having thereon at least on photographic emulsion layer containing internal latent image type silver halide grains not having been previously fogged in the presence of a nucleating agent, wherein the nucleating agent comprises at least two kinds of nucleating agents and a ratio of nucleating rates thereof is at least 2.0.In accordance with the method of the present invention, images having both a low minimum density and an extremely high maximum density can be rapidly and stably obtained using a small amount of nucleating agents.
    Type: Grant
    Filed: September 30, 1988
    Date of Patent: November 6, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyasu Deguchi, Satoshi Nagaoka, Noriyuki Inoue, Shigeo Hirano
  • Patent number: 4968596
    Abstract: A method for forming a direct positive image comprising the steps of:(a) imagewise exposing a photographic light-sensitive material composed of a support having thereon at least one unprefogged internal latent image type silver halide light-sensitive emulsion layer; and(b) developing the exposed photographic light-sensitive material to form a direct positive image in the presence of at least one nucleating agent represented by formula (N-I); ##STR1## wherein Z.sup.1 represents nonmetal atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring, a 5-membered or 6-membered heterocyclic ring fused with an aromatic ring, or a 5-membered or 6-member heterocyclic ring fused with another heterocyclic ring; R.sup.1 represents an aliphatic group; X represents ##STR2## Q represents a nonmetallic atomic group necessary for forming a 4-membered to 12-membered nonaromatic hydrocarbon ring or a 4-membered to 12-membered nonaromatic heterocyclic ring; provided that at least one of R.sup.1, Z.sup.
    Type: Grant
    Filed: November 2, 1988
    Date of Patent: November 6, 1990
    Assignee: Fuji Photo Film Co. Ltd.
    Inventors: Noriyuki Inoue, Shigeo Hirano, Tetsuro Kojima, Mitsura Yamamoto, Satoshi Nagaoka
  • Patent number: 4966833
    Abstract: A method for the formation of direct positive color images wherein after image-wise exposure of a direct positive color photosensitive material which comprises at least one internal latent image type silver halide emulsion layer which has not been pre-fogged and color image forming couplers on a support, the material is subjected to development after and/or during a fogging process, the development process being carried out using a development bath which contains at least one N-hydroxylalkyl substituted p-phenylenediamine derivative in the presence of at least one compound of general formula [I] and/or [II] as indicated below: ##STR1## wherein Q represents the group of atoms required to form a five- or six-membered heterocyclic ring, which heterocyclic ring may be condensed with a carbon aromatic ring or a heterocyclic aromatic ring,Y represents a divalent linking group consisting of at least one atom selected from the group consisting of, carbon atom, nitrogen atom, oxygen atom, sulfur atom, and R represents
    Type: Grant
    Filed: October 5, 1988
    Date of Patent: October 30, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Noriyuki Inoue
  • Patent number: 4965176
    Abstract: There is disclosed a method for processing a light-sensitive silver halide color photographic material, characterized in that the light-sensitive silver halide color photographic material contains a core-shell type-internal latent image type silver halide emulsion a shell of which contains at least silver chloride, and the light-sensitive silver halide color photographic material is processed with a color developing solution containing the compound represented by the following formula (A): ##STR1## wherein R.sub.1 and R.sub.2 each represent a hydrogen atom or an alkyl group having 1 to 5 carbon atoms which may have a substituent or substituents, or R.sub.1 and R.sub.2 may be combined to form a ring, provided that the case where R.sub.1 and R.sub.2 are hydrogen atoms at the same time is excluded.
    Type: Grant
    Filed: August 30, 1988
    Date of Patent: October 23, 1990
    Assignee: Konica Corporation
    Inventors: Masao Ishikawa, Satoru Kuse
  • Patent number: 4956267
    Abstract: A method for forming a direct positive color image by image-wise exposing to light a light-sensitive material having at least one internal latent image type silver halide emulsion layer which is unfogged and color image-forming couplers on a support; either (1) subjecting the resulting material to fogging exposure to light and/or processing it with a nucleating agent before development, and then developing the resulting material with a surface developing solution containing an aromatic primary amine type color developing agent, or (2) developing the material after the image-wise exposure with a surface developing solution containing an aromatic primary amine type color developing agent under fogging exposure and/or in the presence of a nucleating agent; and bleach-fixing the resulting material, wherein the color developing solution contains at least one compound selected from the group consisting of compounds represented by the following general formulae (I), (II), (III) and (IV): ##STR1## wherein X represent
    Type: Grant
    Filed: May 31, 1988
    Date of Patent: September 11, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Tatsuo Heki, Noriyuki Inoue, Takatoshi Ishikawa, Nobutaka Ohki, Morio Yagihara, Kiyoshi Morimoto, Hiroshi Fujimoto, Kazuto Andoh
  • Patent number: 4952483
    Abstract: The present invention relates to a direct positive silver halide photosensitive material and a method for forming a direct positive image. By the use of a novel nucleating agent having a specific structural formula, the present invention provides a direct positive silver halide photosensitive material with an increased Dmax value and a decreased Dmin value, as compared with the use of the conventional nucleating agents, even if a small amount of the novel nucleating agent is used, and does not substantially reduce the Dmax value, even if the photosensitive material is kept in a high-humidity state for a long time before exposure.
    Type: Grant
    Filed: March 21, 1988
    Date of Patent: August 28, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Morio Yagihara, Hisashi Okada, Tetunoti Matushita, Satoshi Nagaoka, Tetsuro Kojima
  • Patent number: 4948698
    Abstract: A heat-processible color photographic material having on a base support at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material represented by the following general formula (1) in disclosed. where A is a coupler site capable of dye formation by entering into a coupling reaction with the oxidized product of the reducing agent; L is a divalent linkage grop binding to A at the active point of the coupler site represented by A; B is a ballast group having a sufficient molecular size or shape to render the dye-providing material of the general formula (1) substantially immobile during thermal development; Dye is a dye site, n is 1, 2 or 3, part of the coupler site A optionally serving as part of the dye site Dye.
    Type: Grant
    Filed: October 10, 1989
    Date of Patent: August 14, 1990
    Assignee: Konica Corporation
    Inventor: Tawara Komamura
  • Patent number: 4943518
    Abstract: A direct positive type silver halide color photographic material and an image forming method are disclosed. A green sensitive emulsion layer of the photographic material comprises silver halide grains having at least two peaks on the size distribution curve thereof and the grain size corresponding to the smallest grain size peak among the peaks is not more than 0.3 .mu.m and a magenta coupler represented by the following Formula (M-I); ##STR1## wherein Z is a group of non-metal atoms necessary to complete a nitrogen-containing heterocyclic ring; X is a hydrogen atom or a split-off group and R is a substituent. The photographic material is developed with a color development in the presence of a fogging agent to directly form the positive image after imagewise exposure to light. Thus obtained image is improved in a increased maximum density, lowered minimum density and wider exposure latitude. Stability of gradation with respect to variation of development conditions is also improved.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: July 24, 1990
    Assignee: Konica Corporation
    Inventors: Tomomi Yoshizawa, Keiji Ogi, Yasuo Tosaka, Kazuya Kuramoto, Yoshiyuki Nonaka
  • Patent number: 4933265
    Abstract: A process for forming a direct positive color image is disclosed, the process comprising imagewise exposing a photosensitive material containing at least one emulsion layer of silver halide of internal latent image type, which has not been preliminarily fogged, and a color image-forming coupler; developing said material using a surface developing solution containing an aromatic primary amine color developing agent in the presence of a nucleating agent and/or in the condition that fogging exposure is carried out prior to the developing step or during the developing step; bleaching; and fixing, wherein said color coupler is a compound which is in itself substantially nondiffusible, and capable of forming or releasing a substantially nondiffusible dye upon oxidative coupling with said aromatic primary amine color developing agent and said development processing is carried out at a pH of 11.
    Type: Grant
    Filed: February 23, 1989
    Date of Patent: June 12, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Tatsuo Heki, Tetsuro Kojima, Shinji Ueda
  • Patent number: 4931378
    Abstract: Disclosed is a method for processing a silver halide photographic material having at least one silver halide emulsion layer on a support and containing at least one hydrazine derivative in said silver halide emulsion layer or in another hydrophilic colloid layer with a roller-conveying type automatic developing machine using a dihydroxybenzene developer containing a sulfite preservative in an amount of 0.15 mol/liter or more at pH of 10.5 to 12.3, which method is characterized in that at least the roller which is in contact with both the developer and air, among the rollers of the said developing machine, is continuously rotated at a determined speed during conveyance or processing of the material during a processing phase, and intermittently rotated during a stand-by phase. By the method, the photographic material may be processed stably and rapidly for a long period of time to give an image having a high contrast and a high blackened density.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: June 5, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Hirano, Eiichi Tadokoro
  • Patent number: 4925777
    Abstract: A direct positive color image forming method which comprises processing an imagewise exposed photographic light-sensitive material with a surface color developing solution containing an aromatic primary amine color developing agent, after fogging treatment and/or during fogging treatment, wherein the photographic light-sensitive material comprises a support having thereon at least one internal latent image type silver halide emulsion layer that has not been previously fogged, a color image forming coupler, colloidal silver, and at least one compound represented by general formula (II): ##STR1## wherein Z represents an atomic group necessary for completing a 5-membered or 6-membered nitrogen-containing heterocyclic ring; D and D', which may be the same or different, each individually represents an atomic group necessary for completing an acidic nucleus and D and D' may be bonded to each other to form a cyclic structure; R.sup.
    Type: Grant
    Filed: October 20, 1988
    Date of Patent: May 15, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Takashi Ozawa
  • Patent number: 4917991
    Abstract: A direct positive silver halide photographic material with an internal latent image-type silver halide emulsion layer that provides a direct positive image by a fogging treatment (for example, an overall exposure, or surface developing treatment in the presence of a fogging agent) after imagewise exposure. The silver halide particles which form the emulsion layer consist essentially of a core portion made of silver halide and having been chemically sensitized or doped with metal ions. There are provided a plural number of shell portions made of silver halide containing silver chloride. The chloride content of an inner shell adjacent to the outmost shell of the particles has a smaller amount of chloride content than that of the outermost shell. The photographic material is used by first imagewise exposing it to light, effecting overall fogging treatment on the silver halide particles and processing the exposed photographic material to produce the image.
    Type: Grant
    Filed: June 23, 1988
    Date of Patent: April 17, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yasuo Tosaka, Keiji Ogi, Atushi Kamitakahara
  • Patent number: 4914009
    Abstract: The present invention relates to a process for forming a direct positive color image, wherein bleaching time is reduced and color reproduction is not deteriorated. According to the present invention, there is provided a process for forming a direct positive color image comprising exposing a photosensitive material comprising, on a support, at least one photographic emulsion layer containing previously unfogged internal latent image-type silver halide grains and a color image-forming coupler, color-developing the same in the presence of a nucleating agent and/or fogging light, and then processing it with a processing solution having a bleaching effect, characterized in that a bleaching accelerator is incorporated into the processing bath having the bleaching effect or a pre-processing bath, or said bleaching accelerator is incorporated into the photosensitive material.
    Type: Grant
    Filed: June 26, 1987
    Date of Patent: April 3, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Tatsuo Heki, Noriyuki Inoue
  • Patent number: 4898807
    Abstract: A method for forming a direct positive color image by subjecting an inner latent image type light-sensitive silver halide color photographic material for formation of a direct positive color image, having at least one light-sensitive emulsion layer containing inner latent image type silver halide grains which have not been previously fogged on the grain surfaces to color developing processing after image exposure, which comprises developing an inner latent image type light-sensitive silver halide color photographic material for formation of a direct positive color image wherein a silver halide emulsion in at least one light-sensitive emulsion layer consists substantially of a silver chlorobromide emulsion with the use of a color developing solution containing an N-hydroxyalkyl-substituted-p-phenylenediamine derivative at 30.degree. C. or higher for not longer than 150 seconds.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: February 6, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kazuhiro Kobayashi, Shigeharu Koboshi, Kazuyoshi Miyaoka
  • Patent number: 4880727
    Abstract: A direct positive photographic material comprising a support having provided thereon one or more hydrophilic colloid containing layers, wherein at least one of said hydrophilic colloid containing layers is an internal latent image type silver halide emulsion which has not been previously fogged and at least one of said emulsion layer or other hydrophilic colloid containing layer contains a colloidal metal or a colloidal water-insoluble metallic sulfide, selenide or telluride, and a method for forming a direct positive from the direct positive photographic material in which a light-sensitive material contains at least two layers containing colloidal silver.
    Type: Grant
    Filed: September 28, 1987
    Date of Patent: November 14, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Noriyuki Inoue, Tatsuo Heki
  • Patent number: 4879203
    Abstract: A process for producing masked positive color images by the silver dye bleach process using a developer solution which contains 0.3 to 1.0 mol/l of a bromide.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: November 7, 1989
    Assignee: Ciba-Geigy AG
    Inventor: Urs J. Furholz
  • Patent number: 4863839
    Abstract: A process for forming direct positive color photographic image is disclosed whereby a color photographic material having on a support at least one previously unfogged internal latent image-type silver halide emulsion layer and at least color forming coupler is developed, after imagewise exposure, with a surface color developer containing an aromatic primary amine color developing agent while applying thereto a fogging treatment, with or without the presence of a nucleating agent, before or during the development step, and bleaching and fixing (or blixing) the color photographic material, whereinthe pH of the surface color developer is not higher than 11.2,the color image forming coupler is a compound which is substantially non-diffusible and forms and releases a dye causing oxidative coupling with the aromatic primary amine color developing agent,and the surface of the silver halide in the internal latent image-type silver halide has been gold-sensitized.
    Type: Grant
    Filed: August 14, 1987
    Date of Patent: September 5, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuo Heki, Noriyuki Inoue
  • Patent number: 4863838
    Abstract: A direct positive photographic material having a support and a silver halide emulsion layer thereon contains internal latent image type silver halide grains. These grains have a core/shell structure and have not been previously fogged. Each grain comprises a conversion type silver halide core and a silver halide shell over the core.The layer would produce, when exposed for a given time upto one second and developed at 20.degree. C. for 4 minutes with a certain internal developing solution, a maximum density which is at least five times that obtained when the layer is similarly exposed and developed with a particular surface developing solution.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: September 5, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Keiji Ogi, Yasuo Tosaka
  • Patent number: 4840879
    Abstract: The present invention relates to a process for forming a direct positive color image comprising(a) imagewise exposing a direct positive photosensitive silver halide color photographic material to light to yield an imagewise exposed material, said photographic material having a support and at least one silver halide emulsion layer thereon, said emulsion layer containing a coupler and internal latent image type silver halide crystals whose surfaces have not been fogged prior to said imagewise exposure, and(b) uniformly exposing to light the entire surface of said imagewise exposed photographic material before or during a development step and in the presence of a substance of Formula IV, a compound of formula I and a color-developing agent consisting of aromatic primary amino compounds selected from the group consisting of N-methyl-aminophenol, 4-amino-3-methyl-N-ethyl-N-(-methanesulfonamidoethyl) aniline,4-amino-3-methyl-N-ethyl-N-(-hydroxyethyl) aniline, 4-amino-3-methyl-N, N-diethyl-p-phenylenediamine, and 4-
    Type: Grant
    Filed: January 29, 1988
    Date of Patent: June 20, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Atushi Kamitakahara, Keiji Ogi
  • Patent number: H1119
    Abstract: Disclosed is a direct positive photographic material having an improved time-dependent storage stability. The material comprises a support having thereon at least one photographic emulsion layer containing previously non-fogged internal latent image type silver halide grains wherein the photographic emulsion layer contains at least one compound of formula (I): ##STR1## where R.sup.11 is an aryl group, R.sup.12 to R.sup.15 each are a hydrogen atom, or an aliphatic or aromatic group, and R.sup.11 to F.sup.15 may have substituent(s) and may form ring(s).
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: December 1, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Noriyuki Inoue