Identified Yellow Dye Color Patents (Class 430/388)
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Patent number: 7629112Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed yellow colorant that is present in an amount to provide a status M blue density greater than 0.003 per mg/m2. This colorant provides minimum density at lower cost and can be incorporated with minimal or no organic solvents and thus enable a reduced organic load that may lead to improved film physical properties.Type: GrantFiled: May 30, 2008Date of Patent: December 8, 2009Assignee: Eastman Kodak CompanyInventors: Paul L. Zengerle, Drake M. Michno, James H. Reynolds, Steven P. Szatynski, John W. Harder
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Patent number: 7183044Abstract: A silver halide color photographic light-sensitive material, having at least one each of blue-, green-, and red-sensitive emulsion layers containing yellow, magenta, and cyan couplers, respectively, on a support; wherein said blue-sensitive emulsion layer contains at least one coupler of formula (I); and wherein the light-sensitive material satisfies expression a-1) and/or b-1): wherein, Q forms a 5- to 7-membered ring with the —N?C—N(R1)—; R1 and R2 each are a substituent; m is 0 to 5; and X is a hydrogen atom, or a coupling split-off group; a-1): 0.5?Dmax(UV)/Dmin(UV)?1.1 wherein Dmax(UV)/Dmin(UV) is the smallest of the value in a wavelength range of 340 to 450 nm; b-1): 1300?(B-C)/A?20000 wherein B is yellow Dmax, C is yellow Dmin; and A is an amount mol/m2 of the coupler of formula (I).Type: GrantFiled: October 21, 2004Date of Patent: February 27, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Yoneyama, Akira Ikeda, Shin Soejima, Kiyoshi Takeuchi, Naoto Matsuda
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Patent number: 7175976Abstract: A silver halide color photographic light-sensitive material comprising at least one yellow color developable light-sensitive silver halide emulsion layer, at least one magenta color developable light-sensitive silver halide emulsion layer, and at least one cyan color developable light-sensitive silver halide emulsion layer, each of which is provided on a support: which comprises at least one yellow coupler of formula (I) and at least one cyan coupler of formula (A); wherein Q represents a group of non-metal atoms that form a 5- to 7-membered ring in combination with —N?C—N(R1)-, each of R1 and R2 represents a substituent, m represents an integer of 0 to 5, and X represents a hydrogen atom or a group capable of being split-off upon a coupling reaction; wherein R11 and R12 each represent an alkyl group or an aryl group, J represents an alkylene group, and X represents a hydrogen atom or a group that can split off upon a coupling reaction.Type: GrantFiled: October 21, 2004Date of Patent: February 13, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroyuki Yoneyama, Yasuaki Deguchi, Naoto Ohshima, Kiyoshi Takeuchi, Akira Ikeda, Naoto Matsuda
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Patent number: 7166422Abstract: Provided is a silver halide color photographic material having at least one yellow-coloring photosensitive silver halide emulsion layer, at least one magenta-coloring photosensitive silver halide emulsion layer, at least one cyan-coloring photosensitive silver halide emulsion layer, and at least one non-photosensitive non-coloring hydrophilic colloid layer on a reflective support, wherein, after being color developed, the reflection density A(?) at a wavelength of ? nm in the non-exposed portion of the material is at most 0.07 at 450 nm, at most 0.09 at 550 nm and at most 0.07 at 650 nm and the mean grain size of the silver halide grains in the yellow-coloring photosensitive silver halide emulsion layer in the material is at most 0.70 ?m.Type: GrantFiled: May 22, 2002Date of Patent: January 23, 2007Assignee: Fuji Photo Film Co., Ltd.Inventors: Shinichi Nakahira, Shin Soejima, Hiroyuki Yoneyama, Naoya Shibata, Naoto Ohshima
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Patent number: 6887657Abstract: A silver halide color photographic photosensitive material, which containes at least one specific compound containing at least one alkenylcarbonyl group, in at least one layer on a support; and an image-forming method using the same.Type: GrantFiled: May 11, 2004Date of Patent: May 3, 2005Assignee: Fuji Photo Film Co., Ltd.Inventors: Nobuo Seto, Toshiyuki Makuta, Hidekazu Sakai, Hiroyuki Yoneyama, Tomonori Ichinose
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Publication number: 20040180302Abstract: A method for forming images on a silver halide color photographic photosensitive material having a substrate and photographic structural layers thereon, including, at least three silver halide color photosensitive layers having different photosensitive regions, respectively, and at least one non-photosensitive hydrophilic colloid layer is disclosed. At least one of the photosensitive layers contains 90 mol % or more of silver chloride. Shortly after the silver halide color photographic photosensitive material has been scan-exposed with laser beams, the material is rapid-processed with a low replenishing amount.Type: ApplicationFiled: February 13, 2004Publication date: September 16, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Naoto Ohshima, Akito Yokozawa, Naoya Shibata
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Publication number: 20040115570Abstract: An image-forming method comprising:Type: ApplicationFiled: December 27, 2002Publication date: June 17, 2004Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Akito Yokozawa, Tatsuya Ishizaka, Katsuyuki Takada, Yoshiro Ochiai, Tetsuo Nakamura
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Publication number: 20020076661Abstract: The present invention provides a system of a digital color proof in which consistent images are obtained while minimizing density variation in spite of various variations of conditions due to the use of a silver halide light-sensitive color material, specifically, the present invention provides a method for forming proof images similar to printed images in terms of various characteristics such as the paper quality of silver halide light-sensitive materials, the dot gain, and the density.Type: ApplicationFiled: September 20, 2001Publication date: June 20, 2002Applicant: KONICA CORPORATIONInventors: Tomonori Kawamura, Shigeo Tanaka, Satoshi Nishino, Hirohide Ito, Naohito Naraoka, Naoyo Suzuki, Shinya Watanabe, Masataka Takimoto, Hideaki Sakata, Junichi Tanabe, Tetsuya Taniguchi, Naoki Nozaki, Yasushi Okubo, Koji Daifuku, Katsuji Kondo, Toshitsugu Suzuki
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Patent number: 6057087Abstract: Disclosed is a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler having Formula 1 ##STR1## wherein: X is hydrogen or a coupling-off group, and Y and Z are independently selected hydrogen or a substituent;R.sup.1 is a substituent; andeach R is an independently selected substituent with at least one R substituent located in the 2- or 5-position, and n is 1 to 3;provided that substituents may join to form a ring.Type: GrantFiled: April 29, 1998Date of Patent: May 2, 2000Assignee: Eastman Kodak CompanyInventors: Thomas R. Welter, James H. Reynolds
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Patent number: 6015658Abstract: The invention disclosed is a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler having Formula 1 wherein:X is hydrogen or a coupling-off group;Y and Z are each independently selected hydrogen or a substituent;R.sup.1 is a substituent; andeach R is an independently selected substituent located at any position other than the acylacetamido position, and n is 2 or 3;provided that substituents may join to form a ring.Type: GrantFiled: April 29, 1998Date of Patent: January 18, 2000Assignee: Eastman Kodak CompanyInventors: Thomas R. Welter, James H. Reynolds
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Patent number: 5834167Abstract: A photographic element comprising a light sensitive silver halide emulsion layer having associated therewith an open chain .alpha.-carbonyl acetanilide yellow dye-forming coupler having the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of alkyl, aryl, heterocyclic, and amino groups, provided that R.sub.1 may form a ring bonded to another carbon atom which is a member of Ring "A";each R.sub.Type: GrantFiled: June 25, 1997Date of Patent: November 10, 1998Assignee: Eastman Kodak CompanyInventors: Barbara B. Lussier, John DiCillo
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Patent number: 5747227Abstract: A method of forming colored images is disclosed. A silver halide color photographic photosensitive material which contains at least one yellow coupler represented by formula (I) in a yellow color forming silver halide emulsion layer which is established on a support is exposed using a scanning exposure system in which the exposure time per picture element is shorter than 10.sup.-4 seconds and then subjected to color development processing: ##STR1## wherein A represents ##STR2## X represents an organic group which is required to form, along with the nitrogen atom, a nitrogen containing heterocyclic ring, Y represents an aromatic group or a heterocyclic group, and Z represents a group which is eliminated on reaction of the coupler represented by formula (I) with an oxidation product of a developing agent.The method provides high quality hard copy both cheaply and quickly by means of a scanning exposure using high density light such as lasers for example.Type: GrantFiled: September 15, 1994Date of Patent: May 5, 1998Assignee: Fuji Photo Film Co., Ltd.Inventor: Kiyoshi Kawai
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Patent number: 5677114Abstract: A photographic element comprises a light sensitive silver halide emulsion layer having associated therewith an open chain .alpha.-carbonyl acetanilide yellow dye-forming coupler having the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of alkyl, aryl, heterocyclic, and amino groups, provided that R.sub.1 may form a ring bonded to another carbon atom which is a member of Ring "A";each R.sub.2 is independently selected from the group consisting of those substituents having a Hammett's sigma value of 0 or less, and m is from 0 to 4;each R.sub.3 and R.sub.4 for each of the n carbon atoms is independently selected from the group consisting of hydrogen, alkoxy, aryl, heterocyclic, aryloxy, and alkyl groups, and n is 0 to 16;each R.sub.5 is independently selected from the group consisting of amino, alkyl groups, and groups linked to the "B" ring by oxygen or sulfur, and p is 1 to 3, provided that two R.sub.Type: GrantFiled: July 15, 1996Date of Patent: October 14, 1997Assignee: Eastman Kodak CompanyInventors: Barbara Boland Lussier, John DiCillo
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Patent number: 5674667Abstract: The present invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler of formula (I): ##STR1## wherein X is H or a coupling-off group, R and R.sup.1 are independently selected from H and substituent groups; Y and Z are independently selected from H and alkyl, aryl or heteroaryl groups; provided that Y and Z taken together with the nitrogen atom may form a 5-10 membered heterocyclic ring group which may contain one or more further heteroatoms selected from N, O and S.Type: GrantFiled: June 24, 1996Date of Patent: October 7, 1997Assignee: Eastman Kodak CompanyInventors: Bernard Arthur Clark, Hamish McNab, Craig Cameron Sommerville
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Patent number: 5573892Abstract: Compounds of the formula I are suitable as photographic yellow couplers ##STR1## In formula I, Z.sub.1, Z.sub.2 mean residues to complete 5-, 6- or 7-membered rings of an aromatic or heteroaromatic nature; these rings may be substituted with substituents R.sup.1, R.sup.2, R.sup.3 and R.sup.4 ;X means H or a substituent which is released under chromogenic development conditions.Type: GrantFiled: October 25, 1995Date of Patent: November 12, 1996Assignee: AGFA-Gevaert AGInventor: G unther Schenk
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Patent number: 5541040Abstract: Disclosed is a positive type color light sensitive material comprising a support having thereon a mainly yellow image forming layer, a mainly magenta image forming layer and a mainly cyan image forming layer;wherein, when an exposure quantity-gives minimum density of +0.2 on a first layer selected from said three layer after developing in the main spectra sensitivity region of the first layer, a second layer selected from said three layers is given lower density with said exposure than a density without said exposure.The positive type color light sensitive material is capable of providing a color proof improved in the approximation degrees of an image quality to a printed printer.Type: GrantFiled: January 25, 1995Date of Patent: July 30, 1996Assignee: Konica CorporationInventors: Susumu Okawauchi, Yasuo Tosaka, Yoshiyuki Nonaka, Keiichi Hoshino
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Patent number: 5512103Abstract: The invention provides a cyan color producing silver halide emulsion layer or a magenta color producing silver halide emulsion layer wherein said at least one layer has an exposure range of at least 0.6 log E from the point where the instantaneous contrast is 1.0 and wherein the instantaneous contrast of said layer increases as a function of increasing exposure over at least 70 percent of said exposure range.Type: GrantFiled: January 19, 1995Date of Patent: April 30, 1996Assignee: Eastman Kodak CompanyInventors: James L. Edwards, Eric L. Bell, Benjamin T. Chen, Richard L. Parton
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Patent number: 5486450Abstract: A silver halide color photographic light sensitive material comprising a support which is both side coated with a polyolefin resin is disclosed. A hydrophilic colloidal layer containing a white pigment and a silver halide emulsion layer are provided on the support and the silver halide emulsion layer contains at least one of the compounds represented by the following Formula I, ##STR1## wherein R.sub.1 represents an alkyl group, a cycloalkyl group or an aryl group; R.sub.2 represents a fluorine atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamino group, an alkylthio group or an arylthio group; R.sub.3 represents a group substitutable to a benzene ring; n is an integer of 0 or 1; Z represents a hydrogen atom or a group capable of splitting off when coupling it to the oxidized product of a developing agent; and Y represents a monovalent organic group including a ballast group.Type: GrantFiled: October 11, 1994Date of Patent: January 23, 1996Assignee: Konica CorporationInventors: Yasuo Tosaka, Masayuki Sasagawa
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Patent number: 5470696Abstract: A photographic element comprising a support, at least one photosensitive silver halide layer and associated therewith a color coupler of the general formula (1) or (2): ##STR1## wherein A and B represent the same or different electron-withdrawing group,X is H or a group which splits off on coupling with oxidized color developer,R is an alkyl, cycloalkyl, aryl or heterocyclic which may be substituted, --COR.sup.1, --CSR.sup.1, SOR.sup.1, SO.sub.2 R.sup.1, --NHCOR.sup.1, --CONHR.sup.1, --COOR.sup.1, --COSR.sup.1, --NHSO.sub.2 R.sup.1 wherein R.sup.1 is an alkyl, cycloalkyl, or aryl group any of which are optionally substituted,and wherein two or more of A, B, R, and X optionally form part of a ring,Link is a linking group andn is 0, 1 or 2.Type: GrantFiled: June 1, 1993Date of Patent: November 28, 1995Assignee: Eastman Kodak CompanyInventor: Hugh M. Williamson
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Patent number: 5460925Abstract: A photographic element comprises a support, at least one photosensitive silver halide layer and in or adjacent said silver halide layer a color coupler of one of the general formulas: ##STR1## wherein R.sup.1 is a group substantially without any electron-withdrawing capability,R.sup.2 is a substituent not incompatible with the function of the compound,R.sup.3 is an alkyl, aryl or heterocyclic group any of which may be substituted,provided that R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3 may together form a cyclic group containing at least one heteroatom, andX is a coupling-off group.The invention also provides a coupler composition, a dye composition, and a method of forming an image in the element of the invention.Type: GrantFiled: May 4, 1994Date of Patent: October 24, 1995Assignee: Eastman Kodak CompanyInventor: Philip A. Allway
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Patent number: 5445924Abstract: There is disclosed a method for forming a color image using a silver halide color photographic material having three silver halide photosensitive layers on a support, comprising, in a cyan color-forming coupler-containing photosensitive layer, a cyan dye-forming coupler represented by formula (I) or (II), wherein said photographic material is exposed by a scanning exposure system and then is subjected to color development processing: ##STR1## wherein Za and Zb each represent --C(R.sub.3).dbd. or --N.dbd., provided that one of Za and Zb represents --N.dbd. and the other represents --C(R.sub.3).dbd.; R.sub.1 and R.sub.2 each represent an electron-attracting group; R.sub.3 represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a coupling-off group, provided that R.sub.1, R.sub.2, R.sub.3, or X may be a divalent group, to form a dimer or higher polymer, or to bond to a polymer chain to form a homopolymer or copolymer.Type: GrantFiled: February 19, 1993Date of Patent: August 29, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Kiyoshi Kawai
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Patent number: 5382506Abstract: A silver halide color photographic light sensitive material comprising a support which is both side coated with a polyolefin resin is disclosed. A hydrophilic colloidal layer containing a white pigment and a silver halide emulsion layer are provided on the support and the silver halide emulsion layer contains at least one of the compounds represented by the following Formula I, ##STR1## wherein R.sub.1 represents an alkyl group, a cycloalkyl group or an aryl group; R.sub.2 represents a fluorine atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, a dialkylamino group, an alkylthio group or an arylthio group; R.sub.3 represents a group substitutable to a benzene ring; n is an integer of 0 or 1; Z represents a hydrogen atom or a group capable of splitting off when coupling it to the oxidized product of a developing agent; and Y represents a monovalent organic group including a ballast group.Type: GrantFiled: August 20, 1993Date of Patent: January 17, 1995Assignee: Konica CorporationInventors: Yasuo Tosaka, Masayuki Sasagawa
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Patent number: 5380625Abstract: A method for processing a silver halide color photographic material, which comprises processing an image-wise exposed silver halide color photographic material comprising at least one silver halide emulsion layer and containing an N,N-substituted malondiamide type coupler with a color developer containing an aromatic primary amine color developing agent represented by the following general formula (D) or (E): ##STR1## In a preferred embodiment, the photographic light-sensitive material contains a cyan coupler represented by the following general formula (C): ##STR2##Type: GrantFiled: February 5, 1993Date of Patent: January 10, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Keiji Mihayashi, Masato Taniguchi, Naoki Saito
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Patent number: 5376508Abstract: Disclosed is a method for forming a silver halide color photographic image comprising:exposing a silver halide color photographic light-sensitive material for photographing which comprises a support and provided thereon at least one blue-sensitive silver halide emulsion layer (B layer), at least one green-sensitive silver halide emulsion layer (G layer) and at least one red-sensitive silver halide emulsion layer (R layer) to light to obtain a latent image; processing said latent image to obtain a color negative image;printing said color negative image on a silver halide color photographic light-sensitive material for printing which comprises a support and provided thereon a yellow color-forming layer (Y layer), a magenta color-forming layer (M layer) and a cyan color-forming layer (C layer) to obtain a color photographic image; wherein:(A) the spectral sensitivity distribution of the G layer S.sub.G (.lambda.) has a maximum value at a certain point .lambda..sub.Type: GrantFiled: September 20, 1993Date of Patent: December 27, 1994Assignee: Konica CorporationInventors: Yoshitaka Yamada, Satoru Shimba, Hiroshi Shimazaki
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Patent number: 5362617Abstract: A light-sensitive material comprising a support provided thereon at least one layer containing a coupler represented by the following Formula (I): ##STR1## wherein A represents a group represented by the following Formula (a), (b) or (c): ##STR2## wherein the groups are as defined in the specification provided that at least one of the groups represented by A, B and Z has at least one of the partial structures represented by the following Formulas (P-I) to (P-V): ##STR3## wherein the substituent groups are as defined in the specification.Type: GrantFiled: May 12, 1993Date of Patent: November 8, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Masakazu Morigaki, Kohzaburoh Yamada, Nobuo Seto, Yasuhiro Yoshioka
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Patent number: 5346809Abstract: A method of photographic color image formation is disclosed. The method gives a color photographic image having high preservability under a condition with a lowered replenishing amount of developer. The method comprises the following steps;(1) imagewise exposing to light a silver halide color photographic light-sensitive material which comprises a support having thereon a silver halide emulsion layer,(2) developing the exposed light-sensitive material with a color developer,(3) bleach-fixing the developed light-sensitive material with a bleach-fixer, and(4) washing the bleach-fixed light-sensitive material, In the above method, the silver halide emulsion layer contains a specified yellow coupler having a molecular weight of not more than 800 and a specified antifungal agent. The developing step is carried out for a time not more than 25 seconds and developer is replenished with a developer replenisher in a ratio of from 20 ml to 150 ml per square meter of light-sensitive material developed the developer.Type: GrantFiled: December 15, 1992Date of Patent: September 13, 1994Assignee: Konica CorporationInventors: Shun Takada, Satoshi Masumi
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Patent number: 5338654Abstract: A silver halide color photographic material containing at least one coupler compound of the formula (1) in at least one hydrophilic colloid layer which is provided on a support:R.sup.1 OCOCHXCONR.sup.2 R.sup.3 (1)where R.sup.1 represents a branched alkyl group including a cyclic alkyl group and a cyclic alkyl-substituted alkyl group, an aryl group or a heterocyclic group; R.sup.2 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; R.sup.3 represents an alkyl group, an aryl group or a heterocyclic group; X represents a group which splits off from the coupler compound when the coupler compound is reacted with an oxidation product of an aromatic primary amine developing agent; and R.sup.2 and R.sup.3 may be bonded to each other to form a ring. The coupler has a high dye-forming rate to give a dye having a high color density and a high color fastness. The material has improved sharpness and color fastness and an elevated sensitivity.Type: GrantFiled: May 10, 1993Date of Patent: August 16, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoki Saito, Takayoshi Kamio, Seiji Ichijima, Keiji Mihayashi
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Patent number: 5328812Abstract: A dye image-forming method comprising color developing an image wise exposed silver halide color photographic material comprising a support having thereon a layer containing an acylacetamide yellow coupler having an acyl group represented by a following formula (YI) ##STR1## wherein R.sub.1 represents a monovalent group; Q represents a group of atoms necessary to form 3- or 5-membered hydrocarbon ring or a 3- to 5-membered heterocylcic ring; provided that R.sub.1 is not a hydrogen atom and is not combined with Q to form a ring; with a developing solution containing at least one aromatic primary amine color developing agent represented by formula (D) or (E): ##STR2## wherein R.sub.4 represents a linear or branched alkyl group having 1 to 6 carbon atoms or a linear or branched hydroxyalkyl group having 3 to 6 carbon atoms; R.sub.5 represents a linear or branched alkylene group having 3 to 6 carbon atoms or a linear or branched hydroxyalkylene group having 3 to 6 carbon atoms; R.sub.Type: GrantFiled: February 18, 1993Date of Patent: July 12, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Akimitsu Haijima, Masato Taniguchi
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Patent number: 5296339Abstract: A method for processing an imagewise exposed silver halide color photographic material comprising color developing the silver halide color photographic material with a color developer and then processing the photographic material with a processing solution having bleaching activity, in which the photographic material contains a coupler represented by the following general formula (I) and the replenishment rate of the color developer is not more than 600 ml/m.sup.2 of photographic material: ##STR1## wherein R.sup.1 represents a group of nonmetallic atoms necessary for forming a 5-membered unsaturated heterocyclic ring together with a ##STR2## R.sup.2 represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group or a heterocyclic group; R.sup.3 represents an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, an alkoxy group, an aryloxy group, a heterocyclic oxy group or ##STR3## wherein R.sup.4 and R.sup.Type: GrantFiled: February 28, 1992Date of Patent: March 22, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Yoshihiro Fujita, Keiji Mihayashi
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Patent number: 5215872Abstract: A method of processing a silver halide color photographic material is disclosed, comprising a support having provided thereon at least one light-sensitive emulsion layer, which comprises the steps of color developing the material with a developer to which a replenisher is added and bleaching the developed material, wherein the material contains a coupler represented by the following general formula (I) and the amount of replenisher added to the color developer is 600 ml or less per m.sup.2 of the material: ##STR1## wherein A represents a coupler group, and when A is a phenol or naphthol coupler group, n is 1, and when A is any other coupler group, n is 0; and R represents an alkyl group having from 1 to 4 carbon atoms, or a pyridyl group. Images having excellent photographic characteristics are obtained by the method even though the amount of the replenisher is reduced.Type: GrantFiled: April 16, 1991Date of Patent: June 1, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Masatoshi Goto, Keiji Mihayashi
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Patent number: 5192646Abstract: A method of forming color in a silver halide photographic element wherein the silver halide is sensitized with a dye involves reacting an oxidized developing agent with a phenol or naphthol cyan dye-forming coupler or an acylacetamide yellow dye-forming coupler in a sulfoxide coupler solvent. The sulfoxide solvent reduces sensitizer dye staining with the cyan or yellow dye-forming coupler in processed photographic materials (films and papers) due to retained sensitizing dye.Type: GrantFiled: December 9, 1991Date of Patent: March 9, 1993Assignee: Eastman Kodak CompanyInventors: Paul B. Merkel, Edward Schofield, Tienteh Chen
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Patent number: 5188926Abstract: A method of forming color in a silver halide photographic element wherein the silver halide is sensitized with a dye involves reacting an oxidized developing agent with a phenol or naphthol cyan dye-forming coupler or an acylacetamide yellow dye-forming coupler in a carbonamide coupler solvent. The carbonamide solvent reduces sensitizer dye staining with the cyan or yellow dye-forming coupler in processed photographic materials (films and papers) due to retained sensitizing dye.Type: GrantFiled: December 9, 1991Date of Patent: February 23, 1993Assignee: Eastman Kodak CompanyInventors: Edward Schofield, Paul B. Merkel, Tienteh Chen
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Patent number: 5063143Abstract: A process for forming a color image wherein a color photographic material is developed with a processing solution containing a solvent for the silver halide in the presence of an aromatic primary amino color devloping agent. The color photographic material comprises, on a support, at least one layer containing (1) a coupler capable of forming a dye by reaction with an oxidized aromatic primary amino color developing agent and having a dye covering power of at least 0.75 and (2) a silver chlorobromide emulsion or silver chlorobromide emulsion containing at least 90 molar % of silver chloride.Type: GrantFiled: April 9, 1990Date of Patent: November 5, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Takeshi Hirose, Akira Abe, Kiyoshi Nakazyo
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Patent number: 5063142Abstract: A process for processing a silver halide color photographic material is disclosed, which comprises color developing and bleach-fixing the silver halide color photographic material, and then processing by at least one of washing the material with water and stabilizing the material, the silver halide color photographic material comprising a support having thereon at least one emulsion layer comprising a high silver chloride emulsion having a silver chloride content of 80 mol % or more and a used bleach-fixing solution which has been already used for the bleach-fixing, having a silver ion concentration of 0.02 mol/liter or more being used as a bleach-fixing solution for replenishment.Type: GrantFiled: May 21, 1990Date of Patent: November 5, 1991Assignee: Fuji Photo Film Co., Ltd.Inventor: Takatoshi Ishikawa
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Patent number: 4973545Abstract: A photographic coupler containing an aryloxysilyl group (--X--O--Y) wherein X is substituted or unsubstituted arylene and Y is a silyl group) is useful in photographic silver halide elements and processes. Such a photographic coupler enables improved dispersibility and improved photographic properties.Type: GrantFiled: September 14, 1989Date of Patent: November 27, 1990Assignee: Eastman Kodak CompanyInventor: Christopher P. Moore
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Patent number: 4842994Abstract: A silver halide photographic material is described, comprising a support having provided thereon at least one silver halide photographic emulsion layer and comprising a bleach accelerator-releasing coupler, wherein said bleach accelerator-releasing coupler is represented by formula (I)A--(TIME).sub.n --S--X--(Y).sub.m --(Z)l]a (I)wherein A represents a coupler residual group; TIME represents a timing group; n represents 0 or 1; X represents a cyclic aliphatic group or a saturated heterocyclic group; Y represents an aliphatic group having from 1 to 8 carbon atoms which may contain a group of --O--, a group of --S--, a group of --COO--, a group of --CO--, a group of ##STR1## a group of ##STR2## a group of --SO.sub.2 --or a group of ##STR3## in its chain; m represents an integer of from 0 to 3, and when m represents 2 or more, the two or more Y groups may be the same or different; Z represents a group of --OH, a group of --COOM, a group of --SO.sub.Type: GrantFiled: November 12, 1987Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kei Sakanoue, Seiji Ichijima
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Patent number: 4842979Abstract: A heat-sensitive recording material comprising a support having provided thereon a heat-sensitive layer containing microcapsules containing at least one diazonium salt capable of azo-coupling with 2-hydroxy-3-naphthoic acid anilide to develop a blue color, a 2-hydroxy-3-naphthoic acid amide derivative, a benzoylacetic amide derivative represented by the following formula and a basic substance: ##STR1## wherein X represents a hydrogen atom, a halogen atom, a lower alkyl group or an alkoxy, aralkyloxy, phenoxy or acylamino group having up to 18 carbon atoms; Y represents an alkyl or aralkyl group having from 7 to 18 carbon atoms, an alkoxy, aralkyloxy, phenoxy, naphthyloxy, alkylthio, aralkylthio or phenylthio group having from 6 to 18 carbon atoms, a naphthylthio group, a sulfonyloxy group, a sulfamoyl gorup, a ureido group, a thioureido group or an acylamino group; X' and Y' each represents a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group; and Y and Y' may combine to form a substitType: GrantFiled: November 30, 1987Date of Patent: June 27, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Sadao Ishige, Toshimasa Usami, Hiroshi Kamikawa, Toshiharu Tanaka
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Patent number: 4828970Abstract: There is disclosed a method for processing a light-sensitive silver halide color photographic material in which a light-sensitive silver halide color photographic material having at least one silver halide emulsion layer is exposed imagewise to light and then subjected to processing including at least a color development treatment or a color development treatment followed by a bleach-fixing treatment, the improvement wherein said at least one silver halide emulsion layer is a silver halide emulsion layer in which not less than 80 mole % of the total silver halide in the layer is silver chloride and the pH value of the bleach-fixing solution used in said bleach-fixing treatment is in the range of 4.5 to 6.8.Type: GrantFiled: April 15, 1987Date of Patent: May 9, 1989Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Satoru Kuse, Shigeharu Koboshi
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Photographic acetanilide couplers with novel ballast group and photographic elements containing them
Patent number: 4824771Abstract: Novel photographic acetanilide dye-forming couplers comprise a group comprising a stabilizer moiety represented by the formula: ##STR1## wherein R.sup.2 is halogen or alkoxy having 1 to 4 carbon atoms; R.sup.3 is hydrogen, halogen, alkyl or alkoxy; R.sup.4, R.sup.5, R.sup.6 and R.sup.7 are individually alkyl; ##STR2## R.sup.8 and R.sup.9 are individually hydrogen or alkyl; R.sup.10 is hydrogen, alkyl or aryl; and X is a linking group. Such couplers provide advantageous stability in dyes formed from the couplers. These couplers are useful in photographic silver halide materials and processes.Type: GrantFiled: October 30, 1987Date of Patent: April 25, 1989Assignee: Eastman Kodak CompanyInventors: Paul R. Buckland, John D. Goddard -
Patent number: 4758501Abstract: Novel photographic acetanilide dye-forming couplers comprise a group comprising a stabilizer moiety represented by the formula: ##STR1## wherein R is halogen or alkoxy having 1 to 4 carbon atoms; R.sub.1 is hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 are individually alkyl; and, X is a linking group. Such couplers provide advantageous stability in dyes formed from the couplers. These couplers are useful in photographic silver halide materials and processes.Type: GrantFiled: June 5, 1987Date of Patent: July 19, 1988Assignee: Eastman Kodak CompanyInventors: Paul R. Buckland, Siu C. Tsoi
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Patent number: 4687731Abstract: A method of processing a light-sensitive silver halide color photographic material comprising color developing an imagewise exposed light-sensitive silver halide color photographic material comprising a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer on a base, said blue-sensitive silver halide emulsion layer containing a high speed reactive yellow coupler having a relative coupling reaction rate of not less than 0.3, followed by processing with a processing solution having a fixing ability and then processing with a stabilizing solution without a substantial washing step, said stabilizing solution containing a sulfite in an amount of at least 1.times.10.sup.-3 mole per 1 liter of said stabilizing solution. The processed photographic material has superior stability of the dye image.Type: GrantFiled: November 4, 1985Date of Patent: August 18, 1987Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Masao Ishikawa, Shigeharu Koboshi, Satoru Kuse
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Patent number: 4481268Abstract: A method of forming a photographic azo or azamethine dye image in an exposed photographic silver halide element, the method of comprising the steps of (a) developing the imagewise exposed material to form an imagewise pattern of oxidized color developing agent, (b) reacting the oxidized color developing agent with a color coupler to produce an image dye, characterized in that at least one of the color developing agent and the color coupler possesses a metal chelating site such that the image dye is capable of forming a bi-, tri- or higher-dentate metallized dye, and (c) contacting the image dye with polyvalent metal ions to form a metallized dye image. Specified color developing agents include heterocyclic substituted hydrazides and specified couplers include benziso-oxazolones and 2H-pyrazolo-[3,4-b]pyridines in addition to more conventional compounds.Type: GrantFiled: April 29, 1983Date of Patent: November 6, 1984Assignee: Eastman Kodak CompanyInventors: Joseph Bailey, David Clarke, Michael W. Crawley, Peter D. Marsden, Jasbir Sidhu
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Patent number: 4410624Abstract: The invention relates to a process of dispersing oil-soluble photographic additives having a silver-halide base for information recording materials.According to the invention, compounds of the following general formula: ##STR1## are used as auxiliary dispersing agents. The symbolsR represents hydrogen, alkyl with 1 to 8 C atoms,M represents hydrogen, alkali metal, ammonium, andX represents OR or SO.sub.3 M.Type: GrantFiled: March 26, 1982Date of Patent: October 18, 1983Assignee: VEB Filmfabrik WolfenInventors: Dieter Plaschnick, Christoph Roth, Bernd Noll, Walter Kroha, Lothar Kuhnert
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Patent number: 4368255Abstract: A method of processing monochrome silver halide material which contains in at least one silver halide layer in addition to the normal image-forming color coupler or couplers a development inhibitor releasing compound which method comprises developing the exposed material in a color developing solution which comprises not more than 2.5 g/liter of a paraphenylene diamine color developing agent which is able to couple with the color coupler or couplers and D.I.R. compound present, the process further comprising silver halide fixing, silver image bleaching and washing steps. The developed photographic images exhibit a remarkable increase in sharpness.Type: GrantFiled: July 15, 1981Date of Patent: January 11, 1983Assignee: Ciba-Geigy AGInventor: Thomas G. Borg
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Patent number: 4315069Abstract: Color photographic material is described in which a yellowish image is formed which can be used to print black and white prints. Also present in the layer is a small amount of a more reactive coupler which produces a colored image to which black and white paper is not sensitive. This more reactive coupler reduces the fog in the highlight areas.Most preferably small amounts of other couplers are present which result in a green or brown image which makes it easier for the operator to focus the image.Type: GrantFiled: September 11, 1980Date of Patent: February 9, 1982Assignee: Ciba Geigy AGInventors: John G. V. Scott, Anthony K. Harvey
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Patent number: 4310618Abstract: Novel dye-forming couplers have the structure: ##STR1## wherein: Z represents the atoms to complete, with the attached oxygen atom, the same or different 5-pyrazolone dye-forming coupler moiety, phenol dye-forming coupler moiety or naphthol dye-forming coupler moiety, the * in the ring completed by Z representing the coupling position;R is hydrogen or a coupling-off group;Bl is a blocking group removable, during development, from the coupler moiety completed by Z to which it is directly attached; andn is an integer of 2 to 4.Type: GrantFiled: May 30, 1980Date of Patent: January 12, 1982Assignee: Eastman Kodak CompanyInventors: Jose M. Fernandez, Joseph P. Pepe
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Patent number: 4297438Abstract: Color images are obtained by chromogenic development of a colorphotographic material comprising several differently spectrally sensitized silver halide emulsions and color couplers associated thereto, a hydrophobic cyan coupler being incorporated by means of a hydrophobic coupler solvent and a hydrophobic yellow coupler being incorporated without a coupler solvent, when a color developing composition is used comprising a hydrophilic and a hydrophobic color developer compound. The color images have good stability of the cyan partial image to tropical conditions and good lightfastness of the yellow partial image.Type: GrantFiled: July 27, 1979Date of Patent: October 27, 1981Assignee: AGFA-Gevaert AktiengesellschaftInventors: Helmut Haseler, Heinz Meckl, Karl Lohmer, Willibald Pelz
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Patent number: 4294900Abstract: A process for producing a multicolor optical filter by exposing a multilayer color photographic material comprising:(1) a silver halide emulsion layer containing a colored coupler (1b) which has one of cyan, magenta or yellow colors and which forms a dye of one of the other two colors than the color of the colored coupler by a coupling reaction with the oxidation product of an aromatic primary amine color developing agent, and(2) a silver halide emulsion layer containing (i) a silver halide emulsion having a sufficiently high sensitivity that it can be exposed without exposing emulsion layer (1) and without increasing the color density in emulsion layer (1) and (ii) a colored coupler (2b) which has the same color as that of the dye formed by the coupling reaction of the colored coupler (1b) and which forms a cyan, magenta or yellow dye but not the color of the colored coupler (1b) or the color of the dye formed by the coupling reaction of the colored coupler (1b); the exposure is through a stripe or mosaic fiType: GrantFiled: February 22, 1980Date of Patent: October 13, 1981Assignee: Fuji Photo Film Co., Ltd.Inventor: Toshiaki Aono
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Patent number: 4277558Abstract: Silver halide photographic material containing hydroquinones and benzoquinones as anti-stain agents.Type: GrantFiled: May 21, 1980Date of Patent: July 7, 1981Assignee: Konishiroku Photo Industry Co., Ltd.Inventors: Shoji Kikuchi, Toshio Yajima, Kenichi Kishi, Takashi Sasaki, Keiichi Mori, Haruhiko Sato
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Patent number: H1112Abstract: A silver halide color photographic light-sensitive material improved in graininess, comprising a support having thereon a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, wherein at least one of the red-sensitive emulsion layer and the green-sensitive emulsion layer has the three-layered structure, in which the low speed silver halide emulsion layer, medium speed silver halide emulsion layer and high speed silver halide emulsion layer are coated on the support in this order; and the coating amount of silver in the layer increases in the order of the medium speed layer, low speed layer and high speed layer.Type: GrantFiled: October 16, 1990Date of Patent: November 3, 1992Assignee: Konica CorporationInventors: Atsuo Ezaki, Keisuke Tobita, Hiroshi Ikeda, Hideaki Haraga