Forming Multicolor Image Patents (Class 430/391)
  • Publication number: 20110236838
    Abstract: Color silver halide photographic elements having a yellow dye image-forming unit comprises at least one blue-sensitive silver iodobromide emulsion layer that has silver iodobromide grains. The silver iodobromide grains have initially associated therewith at least two blue spectral sensitizing dye layers comprising: (a) an inner dye layer adjacent the silver iodobromide grains comprising at least one anionic blue spectral sensitizing Dye 1, and (b) an outer dye layer adjacent to the inner dye layer comprising at least one cationic blue spectral sensitizing Dye 2. Dye 2 absorbs light at equal or higher energy than Dye 1. The maximum energy emission wavelength of Dye 2 overlaps but is not exactly corresponding to the maximum energy absorption wavelength of Dye 1. The silver iodobromide grains also have initially associated therewith an amine borane compound and a thiosulfonate compound.
    Type: Application
    Filed: March 26, 2010
    Publication date: September 29, 2011
    Inventors: David R. Foster, Drake M. Michno
  • Publication number: 20100167218
    Abstract: Silver halide photographic elements that are color intermediate motion picture films have at least one green sensitive silver halide emulsion that includes a green sensitizing dye that is a cyanine dye having two oxazole groups in the molecule, and another green sensitizing dye having either two imidazole groups in the molecule or one oxazole group and one thiazole group in the molecule. The molar ratio of the first green sensitizing dye to the second green sensitizing dye is from about 4:1 to about 0.3:1. The magenta dye image forming unit has at least one green sensitive silver halide emulsion layer that comprises predominantly cubic silver iodobromide grains having at least 90 mol % bromide and at least 1 mol % iodide, which grains have an average equivalent spherical diameter (ESD) of less than 0.25 ?m.
    Type: Application
    Filed: March 8, 2010
    Publication date: July 1, 2010
    Inventor: Jeffrey C. Hansen
  • Publication number: 20090325108
    Abstract: Silver halide color photographic elements having multiple color imaging layers contain a permanent, pre-formed magenta dye that is present in an amount to provide a status M green density greater than 0.005 per mg/m2. This dye provides minimum density at lower cost and enables lower dye levels and a reduced organic load that may lead to improved film physical properties.
    Type: Application
    Filed: June 27, 2008
    Publication date: December 31, 2009
    Inventors: Paul L. Zengerle, John W. Harder, Drake M. Michno, James H. Reynolds, Steven P. Szatynski
  • Patent number: 7087365
    Abstract: A method for forming images on a silver halide color photographic photosensitive material having a substrate and photographic structural layers thereon, including, at least three silver halide color photosensitive layers having different photosensitive regions, respectively, and at least one non-photosensitive hydrophilic colloid layer is disclosed. At least one of the photosensitive layers contains 90 mol % or more of silver chloride. Shortly after the silver halide color photographic photosensitive material has been scan-exposed with laser beams, the material is rapid-processed with a low replenishing amount.
    Type: Grant
    Filed: February 13, 2004
    Date of Patent: August 8, 2006
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoto Ohshima, Akito Yokozawa, Naoya Shibata
  • Patent number: 6586167
    Abstract: A method for thermally forming images for plate making, which comprises forming an image for plate making by using a thermally processed image recording material comprising a silver salt of an organic acid, a reducing agent, a color image forming material and an organic binder on a support, wherein the image consists essentially of a developed silver image and a color forming dye image and the color forming dye image shows an absorbance for ultraviolet region higher than that for visible region and has a transmission density of 0.3 or more for the region of 360-450 nm. There are provided a thermally processed image recording material and method for thermally forming images that provide significant difference of ultraviolet absorption between image areas and non-image areas suitable for printing plate making.
    Type: Grant
    Filed: July 23, 2001
    Date of Patent: July 1, 2003
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Toyohisa Oya
  • Patent number: 6531270
    Abstract: This invention involves the use of ionic liquids as coupler solvents in a color or monochrome photothermographic system. The presence of an ionic liquid can increase the amount of density or dye formed. The ionic liquid may be combined with other coupler solvents.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: March 11, 2003
    Assignee: Eastman Kodak Company
    Inventors: Leif P. Olson, James H. Reynolds
  • Patent number: 6489088
    Abstract: A color diffusion-transfer photographic light-sensitive material provided with at least two light-sensitive silver halide emulsion layers, each of which is combined with a non-diffusive dye image forming compound forming or releasing a diffusive dye or its precursor in relation to silver development, or with a dye image forming compound whose diffusibility changes in relation to silver development, on a support, the light-sensitive material comprises a specific hydrazine compound and a specific compound improved in storability.
    Type: Grant
    Filed: March 14, 2001
    Date of Patent: December 3, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Fukagawa, Shinichi Ichikawa, Masaru Yoshikawa
  • Publication number: 20020086249
    Abstract: A method of processing a silver halide color photographic lightsensitive material. The material comprises a support and at least one lightsensitive silver halide emulsion layer containing a binder and lightsensitive silver halide grains comprising tabular grains on the support. The material further comprises a developing agent or its precursor, and a compound capable of forming a dye by a coupling reaction with the developing agent in an oxidized form. The method comprises (a) exposing the material under natural light of 2000-9000K color temperature or artificial light corresponding thereto, for {fraction (1/10)}-{fraction (1/1000)} sec, in an exposure amount such that 80-90% (numerical ratio) of the grains contained in the lightsensitive layer have at least one development initiating point per grain, and (b) color developing the exposed material so that the tabular grains have 3.0 or more (average) development initiating points per grain at the completion of the development.
    Type: Application
    Filed: May 2, 2001
    Publication date: July 4, 2002
    Inventors: Makoto Kikuchi, Yoshio Ishii, Toshio Kawagishi
  • Patent number: 6348302
    Abstract: An image-forming method using an exposure head having plural beam light sources that correspond to each exposure point and that emit each light with the same wavelength, to subject to exposure a light-sensitive material provided at least with a light-sensitive silver halide emulsion and a binder on a support, which method comprises arranging M sets of the beam light sources in a sub-scanning direction, perpendicular to a main scanning direction, along which the exposure head is moved, at predetermined intervals, and allowing the light-sensitive material to move in the sub-scanning direction, in steps of a distance of (the length of the exposure head in the aligned direction)/N (N≧2), to carry out superposing exposure N times, with an exposure time per exposure being 10−3 sec or less, thereby forming M×N pixels per exposure head in every M sets of exposure point, to form an image, wherein the silver halide emulsion contains Ir, in an amount to be added of 10−7 to 10−10 mol per mol of
    Type: Grant
    Filed: July 13, 2000
    Date of Patent: February 19, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Takuji Kosugi
  • Patent number: 6030755
    Abstract: Disclosed is an image forming method in which a light-sensitive element having at least three light-sensitive layers on a support is imagewisely exposed and the light-sensitive element is superposed on a processing element in the presence of water in an amount of from 0.1 to 1.0 times of the amount necessary for maximally swelling the total coated layers of the light-sensitive element and the processing element, and the both elements are heated to develop an image on the light-sensitive element. The formed image is outputted to a separate recording material. The developed light-sensitive element is superposed on a dye forming reaction inhibiting sheet and heated to stabilize the light-sensitive element.
    Type: Grant
    Filed: February 12, 1998
    Date of Patent: February 29, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuhiko Matsumoto, Masakazu Morigaki
  • Patent number: 5914225
    Abstract: A color negative photographic element is disclosed that a pair of fast green and red recording layer units coated to receive exposing radiation prior to at least one pair of slow green and red recording layer units. The green recording layer units together contain at least 1.0 g/m.sup.2 of silver with at least 60 percent of the silver in the green recording layer units being in a location other than the fast green recording layer unit, and the red recording layer units together contain at least 1.8 g/m.sup.2 of silver with at least 70 percent of the silver in the red recording layer units being in a location other than the fast red recording layer unit. When development times are reduced to 2 minutes or less during processing increased red speed, reduced granularity of the green record, and increased sharpness of the red record are observed.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: June 22, 1999
    Assignee: Eastman Kodak Company
    Inventor: John H. Becher
  • Patent number: 5837433
    Abstract: A color corrected display image can be rapidly provided by color developing an imagewise exposed, duplitized color photographic element, scanning the developed image to form digital signals, and digitally manipulating those signals to correct either interimage interactions and/or gamma mismatches among at least two color recording units. The color corrected image can be provided in any desired form. The duplitized elements have at least one light-sensitive silver halide imaging layer on each side of the support.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: November 17, 1998
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, John M. Buchanan, Richard P. Szajewski
  • Patent number: 5747228
    Abstract: A color corrected display image can be rapidly provided by color developing an imagewise exposed, duplitized color photographic element, scanning the developed image to form digital signals, and digitally manipulating those signals to correct either interimage interactions and/or gamma mismatches among at least two color recording units. The color corrected image can be provided in any desired form. The duplitized elements have at least one light-sensitive silver halide imaging layer on each side of the support.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: May 5, 1998
    Assignee: Eastman Kodak Company
    Inventors: Anne E. Bohan, John M. Buchanan, Richard P. Szajewski
  • Patent number: 5455146
    Abstract: A method for forming a color image of a color negative photographic material which comprises subjecting a color negative photographic material to a color development processing, said color negative photographic material comprising a support having provided thereon at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer, having a specific photographic sensitivity of 100 or more and having each of the gradients .gamma..sub.AR, .gamma..sub.AG and .gamma..sub.AB of 0.5 to 0.9 after standard color development processing within the range of from 3 minutes to 4 minutes of the color development time, said gradients .gamma..sub.AR, .gamma..sub.AG and .gamma..sub.AB each being a gradient of the red-sensitive, green-sensitive and blue-sensitive silver halide emulsion layers, respectively, obtained after conducting the standard color development processing, wherein each of the gradients .gamma..sub.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: October 3, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshihiro Nishikawa, Hiroshi Fujimoto
  • Patent number: 5320920
    Abstract: The method for producing a color filter of the present invention comprises the following steps: an inorganic active layer is formed on a transparent substrate, a first color is dyed on said inorganic active layer, a resist is formed on portions of the inorganic active layer other than portions where a second color is dyed, a decoloring treatment is conducted, the second color is dyed on the exposed inorganic active layer, the resist is removed, a resist is formed on portions of the inorganic active layer other than portions where a third color is dyed, a decoloring treatment is conducted, the third color is dyed on the exposed inorganic active layer, and then the resist is removed.
    Type: Grant
    Filed: March 29, 1990
    Date of Patent: June 14, 1994
    Assignee: Nissha Printing Co., Ltd.
    Inventors: Tenri Isoda, Masahiro Nishida, Takao Hashimoto, Kanji Suyama, Kenji Kishi, Yoshihide Inako, Yosuke Matsukawa
  • Patent number: 5310630
    Abstract: A silver halide color photographic photosensitive material which has been spectrally sensitized to light of wavelengths greater than of about 670 nm in which are highly sensitive to light of wavelength greater than about 670 nm and sufficiently insensitive to visible light having a shorter wavelength. The photosensitive materials comprises a silver halide photosensitive layer containing the yellow coupler, a silver halide photosensitive layer containing a magenta coupler, a silver halide photosensitive layer containing a cyan coupler and at least one non-photosensitive hydrophilic layer. Each of the photosensitive layers are spectrally sensitized such that they have different peak spectral sensitivities at light wavelengths greater than about 670 nm.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Yoshio Inagaki
  • Patent number: 5051341
    Abstract: There is described a process for recording a positive or negative continuous tone color copy having the same or lower contrast than a continuous tone original image, comprising the steps of:providing a photographic element comprising a support having thereon a silver halide emulsion unit capable of forming a yellow image, a silver halide emulsion unit capable of formign a cyan image, and a silver halide emulsion unit capable of forming a magnenta image, each image-forming unit having a maximum spectral sensitivity at a different wavelength of radiation, and at least one of the image-forming units having a gamma as described herein,receiving image data representing the densities of the yellow, magenta, and cyan records of the original image,modifying said image data and using it to control three exposure sources, each emitting radiation in the region of maximum spectral sensitivity for a corresponding one of the image-forming units, so that, after exposure, the recorded image density range for at least one of
    Type: Grant
    Filed: October 20, 1989
    Date of Patent: September 24, 1991
    Assignee: Eastman Kodak Company
    Inventors: Annabel A. Muenter, James C. Owens
  • Patent number: 4968587
    Abstract: The method for producing color prints having high quality which are available for long-period conservation by using a color positive filter to make plural color separation negatives and black and white positives before printing through color filters on silver dye bleach film.
    Type: Grant
    Filed: April 6, 1988
    Date of Patent: November 6, 1990
    Assignee: Kabushiki Kaisha Doi
    Inventor: Keiziro Sekine
  • Patent number: 4837133
    Abstract: There is disclosed a photographic four-color material for the silver dye bleach process, which material, in addition to containing the customary yellow, magenta and cyan image dyes, contains a black layer which is sensitive to infra-red light.The material is suitable e.g. for testing dotted or continuous tone color separation positives.
    Type: Grant
    Filed: December 9, 1986
    Date of Patent: June 6, 1989
    Assignee: Ciba-Geigy AG
    Inventor: Jakob Kuhn
  • Patent number: 4822724
    Abstract: In a reversal process for the formation of color photographic images which consists of a black and white development (first development) to obtain a first negative image, followed by exposure and/or uniform fogging of the residual silver halide and a further processing (including a second color development), to obtain a second visible (in transparency) color positive image, of a silver halide color multilayer material which comprises, coated on a support base, one or more red-sensitive silver halide emulsion layers associated with dispersed non-diffusing hydrophobic cyan couplers, one or more green-sensitive silver halide emulsion layers associated with dispersed non-diffusing hydrophobic magenta couplers and one or more blue-sensitive silver halide emulsion layers associated with dispersed non-diffusing hydrophobic yellow couplers, the improvement which consists of the reversal development of said magenta-forming layer being performed in the absence of a significant presence of oil.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: April 18, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Agostino Baldassarri, Marco Loiacano, Giuseppe Loviglio
  • Patent number: 4684602
    Abstract: A method of generating visible multicolor images using a single wavelength laser beam is disclosed.
    Type: Grant
    Filed: June 30, 1986
    Date of Patent: August 4, 1987
    Assignee: Eastman Kodak Company
    Inventors: Mark Lelental, James K. Lee, Alan P. VanKerkhove
  • Patent number: 4678740
    Abstract: A photographic matte for use in traveling matte photography is formed by recording a separation of a first screen-color separation of an image on a first film layer and recording a separation of a different second color on a second layer. Preferably, the second color is complementary to the screen color. One layer is developed to form a positive image and the other to form a negative image, these images reinforcing each other. One image is formed by black dye, using a coupler and a color developer and the other is formed by a black dye destruct technique in which the developed portion of the silver halide emulsion is removed. According to another aspect of the invention, a matte of increased density can be formed without commensurate image growth by combining a black dye image with a silver image.
    Type: Grant
    Filed: April 29, 1985
    Date of Patent: July 7, 1987
    Inventor: James N. Catania
  • Patent number: 4483916
    Abstract: Method of improving the color balance of a multicolor reversal image obtained in a photographic material itself or obtained by a diffusion transfer reversal process in an image receiving material is provided, wherein said method comprises, as illustrated in FIG. 3, the steps of:(1) providing a photographic silver halide material (4) capable of yielding in said material or in an image receiving layer a multicolor reversal image of average gradient of at least 1.8;(2) image-wise exposing said photographic material to or through a multi-color continuous tone original (2) while keeping in the optical path between the original and the photographic material a light-distribution means (3) dividing the light in line-like or dot-like portions over the exposed area of the photographic material,(3) developing and reversal-processing said photographic material, e.g. by dye diffusion transfer-processing, hereby producing a reversal image with average gradient of at most 1.50 and reduced color point spreading.
    Type: Grant
    Filed: February 2, 1983
    Date of Patent: November 20, 1984
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Christiaan G. Thiers
  • Patent number: 4458002
    Abstract: A process for the production of a multicolor reversal image with improved color balance is provided which process comprises the steps of directing incident image light dot- or linewise modulated by a light-distributing means onto a multicolor photographic silver halide emulsion material containing a blue-, a green- and a red-sensitive silver halide emulsion layer and processing said silver halide emulsion layers to form a color reversal image.In the maximum density part of the dots or lines of said light distributing means e.g. a contact screen the ratio of the absorption density for the light corresponding with the spectral sensitivity region of the silver halide emulsion layer being during the exposure most remote from the light-distributing means to the absorption density for the light of the whole visible spectrum (400-700 nm) is higher than the said ratio in any other density part of the dots or lines (see FIG. 1).
    Type: Grant
    Filed: May 17, 1983
    Date of Patent: July 3, 1984
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Wilhelmus Janssens, Christiaan G. Thiers, Wilfried F. Liekens
  • Patent number: 4416971
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein each R.sup.1 is the same and is selected from ##STR2## R.sup.2 is alkyl, R.sup.3 is an electron-withdrawing group positioned ortho, meta or para to said N atom, R.sup.4 is hydrogen, alkyl or an electron-withdrawing group positioned ortho, meta or para to said N atom; R.sup.5 is alkyl; X is hydrogen, an electron-withdrawing group or an electron-donating group; and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds, e.g., as photographic light-screening dyes.
    Type: Grant
    Filed: December 28, 1982
    Date of Patent: November 22, 1983
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Louis Cincotta, John W. Lee, Jr.
  • Patent number: 4391896
    Abstract: Curve shape control, especially for lower scale contrast, of a photographic element is achieved by employing with the silver halide emulsion layer two nondiffusible redox dye-releasing compounds of different relative reactivities, the reactivity of the compound which is more reactive being at least 1.5 times the reactivity of the compound which is less reactive. Preferred compounds are ballasted sulfonamido compounds, each of which has a color-providing moiety attached thereto through a sulfonamido group which is alkali-cleavable upon oxidation. Preferred more reactive sulfonamido compounds have a N,N-disubstituted carbamoyl ballast group. The color-providing moieties can be (1) transferred imagewise to an image-receiving layer to provide a useful image, or (2) can be merely diffused out of the element to provide a retained image therein which can be treated to form a color transparency or a motion picture film.
    Type: Grant
    Filed: September 20, 1978
    Date of Patent: July 5, 1983
    Assignee: Eastman Kodak Company
    Inventors: Thomas O. Maier, Jack L. Richards
  • Patent number: 4391884
    Abstract: A process for the production of a photographic color image by the silver dye bleach process, using a photographic material which comprises, on a base, at least one light-sensitive silver halide emulsion layer, which can contain a diffusion-resistant bleachable image dye, and immediately above this layer, on the side facing the light source, a silver halide-free layer containing a diffusion-resistant, bleachable image dye.The process gives very sharp photographic color images.
    Type: Grant
    Filed: April 17, 1981
    Date of Patent: July 5, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Armin Meyer, Carlo Boragine
  • Patent number: 4386144
    Abstract: A process for producing a multicolor optical filter which comprises the steps of (1) exposing a light-sensitive material and (2) developing the exposed light-sensitive material, the process employing a specific light-sensitive material including a silver halide emulsion layer (L1) and a silver halide emulsion layer (L2), each layer containing therein a specific compound or dye. Such a multicolor optical filter is useful in color pick-up tubes and color solid state pick-up devices.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: May 31, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiaki Aono
  • Patent number: 4374914
    Abstract: Negative color images are produced by the silver dye bleach process, by exposure of a photographic silver dye bleach material, silver developing, dye bleaching, silver bleaching and fixing, the silver bleaching being optionally carried out simultaneously with the dye bleaching and/or the fixing, in a single treatment bath.
    Type: Grant
    Filed: July 13, 1981
    Date of Patent: February 22, 1983
    Assignee: Ciba-Geigy Ltd.
    Inventors: Herbert Mollet, Dieter Wyrsch
  • Patent number: 4368256
    Abstract: Production of masked positive color images by the silver dye bleach process, by exposure of a photographic material for the silver dye bleach process, silver developing, dye bleaching, silver bleaching and fixing, optionally the silver bleaching is carried out simultaneously with the dye bleaching and/or the fixing, in a single processing bath.
    Type: Grant
    Filed: July 13, 1981
    Date of Patent: January 11, 1983
    Assignee: Ciba-Geigy AG
    Inventors: Herbert Mollet, Dieter Wyrsch
  • Patent number: 4342818
    Abstract: A process for forming a color filter, which comprises patternwise exposing a black-and-white silver halide emulsion layer of a photographic material comprising a support having thereon at least one black-and-white silver halide emulsion layer, developing the photographic material with a developing solution containing a color dye developer to form a pattern containing a color dye for a pattern containing at least one dye, and removing remaining silver and/or silver halide. The patternwise exposure and color coupler containing development steps can be repeated using different color couplers to produce patterns with additional color dyes.
    Type: Grant
    Filed: December 22, 1980
    Date of Patent: August 3, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Yokota, Masamichi Sato, Kenji Matsumoto
  • Patent number: 4316950
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein each R.sup.1 the same or different is hydrogen or alkyl, each R.sup.2 the same or different is alkyl or phenyl, R.sup.3 is phenyl or alkyl, Y is an electron-withdrawing group and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: February 23, 1982
    Assignee: Polaroid Corporation
    Inventors: Louis Cincotta, James W. Foley
  • Patent number: 4310612
    Abstract: Photographically useful compounds such as photographic reagents and photographic dyes are blocked with a grouping which, under alkaline conditions, is cleaved from the compound by an intramolecular nucleophilic displacement reaction. The compounds are resistant to unblocking under storage conditions, but are uniformly unblocked under conditions encountered during photographic processing.
    Type: Grant
    Filed: October 10, 1978
    Date of Patent: January 12, 1982
    Assignee: Eastman Kodak Company
    Inventors: Jared B. Mooberry, William C. Archie, Jr.
  • Patent number: 4310617
    Abstract: Production of masked positive color images by the silver dye bleach process, by exposing a photographic material for the silver dye bleach process, silver developing, dye-bleaching, silver-bleaching and fixing, optionally, the step of silver-bleaching is carried out in a combined treatment bath together with dye-bleaching and/or fixing.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: January 12, 1982
    Assignee: Ciba-Geigy AG
    Inventors: Herbert Mollet, Alfred Oetiker, Carlo Boragine
  • Patent number: 4304847
    Abstract: A color image forming process which comprises processing a photographic light-sensitive element comprising a support having thereon a layer containing imagewise distributed silver therein with an aqueous alkaline solution containing a stannous ion and in the presence of a dye and a bispyridinium compound represented by the following general formula: ##STR1## wherein R.sub.1 and R.sub.2 each represents a lower aliphatic hydrocarbon group or R.sub.1 and R.sub.2 are bonded each other to form a ring; n represents 0 or 1; and X.sup.- represents an anion; to bleach the dye in an imagewise manner. By the process of the present invention, color images which are stable to light, heat and moisture are formed using light-sensitive elements containing a reduced amount of silver salt and without using chemicals causing environmental pollution problems for the processing.
    Type: Grant
    Filed: November 13, 1979
    Date of Patent: December 8, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Isao Shimamura, Yukio Maekawa, Koichi Koyama, Shigeki Yokoyama
  • Patent number: 4258118
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein R' is alkyl; Y is an electron-withdrawing group and A is an anion. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: March 24, 1981
    Assignee: Polaroid Corporation
    Inventors: James W. Foley, Louis Locatell, Jr., Charles M. Zepp
  • Patent number: 4258119
    Abstract: In one embodiment, the present invention is concerned with novel xanthene compounds of the formula ##STR1## wherein X is ##STR2## wherein R' is alkyl, Y is an electron-withdrawing group and n is 0 or 1. In another embodiment, the present invention is concerned with photographic products and processes employing these xanthene compounds.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: March 24, 1981
    Assignee: Polaroid Corporation
    Inventors: Richard L. Cournoyer, James W. Foley
  • Patent number: 4255512
    Abstract: A multicolor diffusion transfer photographic system wherein development of an exposed multilayer photsensitive element is effected in the presence of a ligand which is represented by the formula ##STR1## wherein R is hydrogen, alkyl or hydroxyalkyl, m is an integer of from 3 to 10 and n is 0 or an integer of from 1 to 3 with the proviso that the sum of m and n is not greater than 10.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: March 10, 1981
    Assignee: Polaroid Corporation
    Inventors: George H. Nawn, Donald O. Rickter
  • Patent number: 4248955
    Abstract: A multicolor diffusion transfer photographic system wherein development of an exposed multilayer photosensitive element is effected in the presence of an oligomer which is represented by the formulaR.sub.1 O(CH.sub.2 CH.sub.2 O).sub.m R.sub.2wherein R.sub.1 and R.sub.2 each independently may be --CH.sub.3 or --C.sub.2 H.sub.5 and m is an integer of from 4 to 10.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: February 3, 1981
    Assignee: Polaroid Corporation
    Inventor: George H. Nawn
  • Patent number: 4235957
    Abstract: In a dry physical development photothermographic element for a dry thermal silver-dye bleach process wherein the element comprises a silver halide complexing concentration of a silver halide complexing agent improvements are provided when the complexing agent is an organic ammonium chloride, bromide or iodide. After imagewise exposure of the element, a dye image can be produced by uniformly heating the element. Improvements are also produced by providing a dry activator element for producing a dye image in a separate photographic element by means of a dry physical development thermal dye-bleach process, wherein the activator element comprises a support having thereon a layer comprising a synthetic hydrophobic polymeric binder, a silver halide complexing concentration of a silver halide complexing agent, as described, a bleachable dye and a thermal solvent.
    Type: Grant
    Filed: January 25, 1979
    Date of Patent: November 25, 1980
    Assignee: Eastman Kodak Company
    Inventors: Carl F. Kohrt, Roland G. Willis
  • Patent number: 4197123
    Abstract: The present invention provides a new process for the production of masked subtractive positive color images by the silver dye bleach process, which comprises the steps of exposure, silver developing, dye-bleaching, silver-bleaching and fixing.
    Type: Grant
    Filed: July 13, 1978
    Date of Patent: April 8, 1980
    Assignee: Ciba-Geigy AG
    Inventors: Alfred Oetiker, Christoph Chylewski, Max Marthaler
  • Patent number: H1112
    Abstract: A silver halide color photographic light-sensitive material improved in graininess, comprising a support having thereon a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer, wherein at least one of the red-sensitive emulsion layer and the green-sensitive emulsion layer has the three-layered structure, in which the low speed silver halide emulsion layer, medium speed silver halide emulsion layer and high speed silver halide emulsion layer are coated on the support in this order; and the coating amount of silver in the layer increases in the order of the medium speed layer, low speed layer and high speed layer.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: November 3, 1992
    Assignee: Konica Corporation
    Inventors: Atsuo Ezaki, Keisuke Tobita, Hiroshi Ikeda, Hideaki Haraga