Migration Imaging, Process, Composition, Or Product, E.g., Electrosolography, Etc. Patents (Class 430/41)
  • Patent number: 4536457
    Abstract: An imaging method comprising providing a migration imaging member comprising a substrate and an electrically insulating softenable layer on the substrate, the softenable layer comprising migration marking material located at least at or near the surface of the softenable layer spaced from the substrate and a charge transport material in the softenable layer, electrostatically charging the member, exposing the member to activating radiation in an imagewise pattern, decreasing the resistance to migration of marking material in the softenable layer sufficiently to allow slight migration in depth of marking material towards the substrate in image configuration, and further decreasing the resistance to migration of marking material in the softenable layer sufficiently to allow nonmigrated marking material to agglomerate.
    Type: Grant
    Filed: January 3, 1984
    Date of Patent: August 20, 1985
    Assignee: Xerox Corporation
    Inventor: Man C. Tam
  • Patent number: 4532197
    Abstract: A method of forming an image on an electrophotographic film material is described. This involves a contact printing technique and comprises the following steps:(a) placing an image-bearing master in contact with the film;(b) exposing the film to light through the image-bearing master, the exposure being substantially greater than the minimum necessary to render conductive the photo-conductive layer of the electrophotographic film;(c) applying a substantially uniform charge to the surface of the film in the dark immediately after exposure;(d) leaving the film in the dark for a short time so as to allow the charge to migrate selectively; and(e) then developing the image.
    Type: Grant
    Filed: May 17, 1983
    Date of Patent: July 30, 1985
    Assignee: Comtech Research Unit Limited
    Inventors: Victor C. Humberstone, John H. Fisher
  • Patent number: 4496642
    Abstract: An imaging member comprising a substrate, an electrically insulating swellable, softenable layer on the substrate, the softenable layer having particulate migration marking material located at least at or near the surface of the softenable layer spaced from the substrate, and a protective overcoating comprising a film-forming resin, a portion of which extends beneath the surface of the softenable layer. This migration imaging member may be prepared with the aid of a material which swells at least the surface of the softenable layer to allow the film-forming resin to penetrate beneath the surface of the softenable layer.
    Type: Grant
    Filed: May 12, 1983
    Date of Patent: January 29, 1985
    Assignee: Xerox Corporation
    Inventors: Man C. Tam, Gregory J. Kovacs
  • Patent number: 4482622
    Abstract: A process for depositing particles within a softenable layer to form a migration imaging member wherein the layer is softened by heating, exposed in a first deposition zone to a high impingement rate of vapors of selenium or selenium alloy moving along in a line of sight path from a selenium or selenium alloy source to form a sub-surface monolayer of spherical particles comprising the selenium or selenium alloy, removed from the first deposition zone prior to a substantial dropoff in transmission optical density, exposed to a lower impingement rate of vapors of selenium or selenium alloy in a second deposition zone to increase the size of the spherical particles while maintaining a narrow particle size distribution and achieving a high surface packing density thereby increasing the transmission optical density of the imaging member, and thereafter removed from the second deposition zone prior to a substantial dropoff in transmission optical density.
    Type: Grant
    Filed: March 31, 1983
    Date of Patent: November 13, 1984
    Assignee: Xerox Corporation
    Inventors: Philip H. Soden, Paul S. Vincett
  • Patent number: 4391886
    Abstract: Disclosed are novel methine colorant materials having the structure ##STR1## Also disclosed is the use of such materials in electrophoretic migration imaging layers and processes.
    Type: Grant
    Filed: August 3, 1981
    Date of Patent: July 5, 1983
    Assignee: Eastman Kodak Company
    Inventors: Mark D. Frishberg, James J. Krutak, Sr.
  • Patent number: 4322487
    Abstract: The present invention provides novel composite electrically photosensitive particles. Each of said particle comprises a colorant and a polymeric binder comprising repeating units containing one or more structures selected from the classes consisting of triarylamines; p-aminotetraarylmethanes; 4,4'-bis(p-amino)triarylmethanes; 1,1-bis(p-aminoaryl)isobutanes; 1,1-bis(p-aminoaryl)cyclohexanes; N-alkyl-N,N-diarylamines; N,N-dialkyl-N-arylamines and heterocyclic nitrogen compounds having about 4 to 10 carbon atoms.
    Type: Grant
    Filed: August 8, 1979
    Date of Patent: March 30, 1982
    Assignee: Eastman Kodak Company
    Inventors: Stewart H. Merrill, Frederick A. Stahly, Ernest W. Turnblom, Beth G. Wright, Hal E. Wright
  • Patent number: 4281050
    Abstract: A migration imaging system including imaging members comprising a substrate overcoated with a softenable layer, and migration marking material, with the softenable layer having a thin surface skin of material having a higher viscosity than the remainder of the softenable material layer.
    Type: Grant
    Filed: January 29, 1970
    Date of Patent: July 28, 1981
    Assignee: Xerox Corporation
    Inventors: David A. Buckley, Roger N. Ciccarelli, Frank G. Belli
  • Patent number: 4256819
    Abstract: Electrophotosensitive materials having the structure ##STR1## wherein: Z.sup.1 and Z.sup.2 represent a basic type heterocyclic nucleus;Y represents N or a methine carbon C--G.sup.1 ;G.sup.1 and G.sup.2 may be the same or different and each is H, alkyl, or aryl or taken together complete a mononuclear or fused polynuclear carbocyclic ring;A.sup.1 and A.sup.2 represent alkyl, aryl, carboxy, alkoxycarbonyl, cyano, nitro or together form a heterocyclic nucleus;R.sup.1 and R.sup.2 may be the same or different and each may represent H, alkyl, aralkyl or aryl;R.sup.3 and R.sup.4 represent hydrogen, alkyl, aryl, cyano, or taken together with the atoms to which they are attached represent a 5 to 6 member carbocyclic ring;m and n may be the same or different and may be 0 or 1;p, q and r, which may be the same or different, represent 0, 1 or 2.
    Type: Grant
    Filed: July 28, 1978
    Date of Patent: March 17, 1981
    Assignee: Eastman Kodak Company
    Inventors: Frank G. Webster, Michael T. Regan
  • Patent number: 4255506
    Abstract: In general, materials having the structure ##STR1## wherein n equals 1 or 2;A represents phenylene, naphthylene, anthracenyl, anthracenediyl, and dibenzothien-diyl;R.sub.1 and R.sub.2 which may be the same or different when taken alone represent hydrogen, cyano, alkylcarbonyl and arylcarbamoyl, arylcarbonyl, cyanoaryl;R.sub.1 and R.sub.2, when taken together, represent sufficient atoms to form substituted and unsubstituted radicals selected from the group consisting of furanylidene, fluorenylidene, pyrimidinylidene, thiazolidinylidene, pyrrolinyl, and indenyl, isoxazolinylidene, pyrazolinylidene and indanylidene, wherein said substituents are selected from the group consisting of hydrogen, cyano, aryl, oxo, thioxo, nitro, alkyl, nitroaryl, carbamoyl and cyanoalkyl; andalkyl represents an alkyl group having from one to six carbon atoms; aryl represents an aromatic nucleus selected from the group consisting of benzene, naphthalene or anthracene, are useful in electrophoretic migration imaging processes.
    Type: Grant
    Filed: April 23, 1979
    Date of Patent: March 10, 1981
    Assignee: Eastman Kodak Company
    Inventors: James A. Van Allan, Louis J. Rossi, Melvin S. Bloom, Michael T. Regan, Hal E. Wright, Joseph Y. Kaukeinen
  • Patent number: 4241156
    Abstract: An imaging system wherein a migration-type imaging member comprising a softenable layer containing agglomerable migration marking material is provided, and the member is exposed to an image pattern of electromagnetic radiation of sufficient energy to cause a simultaneous imagewise migration at least in depth in the softenable layer and agglomeration of the agglomerable migration marking material in the imagewise exposed areas of the imaging member. In another embodiment, a microscopically discontinuous layer of imaging material in a stable substrate is agglomeration or evaporation imaged by the inventive system.
    Type: Grant
    Filed: October 26, 1977
    Date of Patent: December 23, 1980
    Assignee: Xerox Corporation
    Inventors: Werner E. L. Haas, James E. Adams, Bela Mechlowitz
  • Patent number: 4241157
    Abstract: Electrophotosensitive materials having the structure ##STR1## wherein: r and s may be zero, one two or three;R.sup.1 and R.sup.2 may be the same or different and each may represent hydrogen, alkyl, aryl, alkoxyalkyl or alkoxyaryl;Y represents O or S;L.sup.1, L.sup.2, L.sup.3, L.sup.4 and L.sup.5 may be the same or different, represent hydrogen, alkyl, aryl or aralkyl and in addition either L.sup.1 and L.sup.2 or any two of L.sup.3, L.sup.4 and L.sup.5, together with the atoms to which they are attached, may represent the elements needed to complete a carbocyclic ring;A.sup.1 and A.sup.2 represent a substituted or unsubstituted heterocyclic nucleus.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: December 23, 1980
    Assignee: Eastman Kodak Company
    Inventors: Frank G. Webster, Michael T. Regan
  • Patent number: 4230782
    Abstract: A migration imaging system wherein an imaging member comprising migration marking material contained in or contacting a softenable layer on a supporting substrate has a latent image formed thereon, and the latently imaged member is developed by passing it through one or more small meniscuses bonding at least in part a volume of liquid which is capable of changing the resistance of the softenable material, to migration of the migration marking material toward the substrate. Alternately, an imaged migration type imaging member, having marking material in a migrated image comfiguration and in a background configuration which is at least in part spaced apart in depth in the softenable layer from said image configuration, is further developed by the inventive system.
    Type: Grant
    Filed: May 15, 1978
    Date of Patent: October 28, 1980
    Assignee: Xerox Corporation
    Inventor: William L. Goffe
  • Patent number: 4230405
    Abstract: Electrically controlled color imaging with a mixture of electrophotosensitive particles of different color types is effected using a photoconductive insulator layer as a particle addressing electrode. A layer of such mixture adjacent the electrode is uniformly exposed by time-separated, different-color, light pulses and discrete portions of the photoconductor are selectively addressed, by activating radiation, in synchronization with the pulses and according to the image information of color image to be reproduced.
    Type: Grant
    Filed: June 28, 1979
    Date of Patent: October 28, 1980
    Assignee: Eastman Kodak Company
    Inventor: Clark N. Kurtz
  • Patent number: 4197120
    Abstract: An improved electrophoretic migration imaging process is disclosed wherein the improvement comprises the use of electrically photosensitive particles containing a colorant having an absorption maximum greater than about 410 nm. and having the formula: ##STR1## wherein n represents 0 or 1; m represents 1 or 2; Ar represents an aromatic group; Z represents the nonmetallic atoms to complete an aromatic group; and each of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 represents hydrogen, nitro, cyano, halogen, or one of various specified organo groups.
    Type: Grant
    Filed: February 2, 1977
    Date of Patent: April 8, 1980
    Assignee: Eastman Kodak Company
    Inventors: Hal E. Wright, Joseph Y. Kaukeinen