Carbocyclic Patents (Class 430/441)
  • Patent number: 4710451
    Abstract: A high contrast silver metal image can be formed in an exposed photographic silver halide emulsion layer material, the silver halide of which is at least 90 mole percent silver bromide, with the balance being silver chloride and/or silver iodide by developing the same in a developing medium in the presence of hydroquinone as sole developing agent, a large amount of sulphite derived from an inorganic sulphite compound, a nitro-indazole anti-fogging agent, and a polyoxyethylene polymer, and an inorganic alkaline compound to impart to the medium a pH of at least 10.5 provided the amounts of these ingredients meets certain requirements.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: December 1, 1987
    Assignee: AGFA-Gevaert N.V.
    Inventor: Richard A. Ooms
  • Patent number: 4681836
    Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: July 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
  • Patent number: 4619886
    Abstract: A process for forming a high contrast negative image by developing an exposed substantial surface latent image type silver halide photographic light-sensitive material in the presence of hydrazines, which comprises using a developing solution having a pH value of 10.5 to 12.3 and containing at least(1) a developing agent,(2) 0.25 mol/l or more of sulfite, and(3) a compound represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5, which may be the same or different, each represents a hydrogen atom, a hydroxyl group, an alkyl group, an alkoxy group or a substituted alkyl group. According to the process, the development processing time required is shortened in the case of forming a high contrast negative image with a stable developing solution using hydrazines.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: October 28, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Eiichi Okutsu
  • Patent number: 4617258
    Abstract: A silver halide photographic material is disclosed. It contains per 100 g of silver at least 40 mg of a water-soluble compound comprising an element of group VIII of the periodic table and having a molecular weight of at least 100, and 1.2 to 120 mg of a black-and-white silver halide developing agent. The material has improved gradation characteristics and is subject to minimum variation in photographic characteristics.
    Type: Grant
    Filed: March 25, 1986
    Date of Patent: October 14, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Menjo, Nobuo Sakamoto, Yoshikazu Watanabe
  • Patent number: 4546071
    Abstract: A photographic image was produced by storing a geranium leaf in darkness and then projecting a light image on the leaf for a sufficient time to produce a suitable latent starch image, the leaf then being treated to extract the chlorophyll and then flooded with an iodine solution to stain the starch and develop the photographed image. Alternatively, instead of the leaf, a photographic medium may be employed including a film of a starch free, water, carbon dioxide and light permeable matrix, such as gelatin, having dispersed therein chloroplast containing algae or photosynthetic bacteria.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: October 8, 1985
    Inventor: David Fox
  • Patent number: 4510229
    Abstract: A lithographic photosensitive material which comprises a support having thereon at least one silver halide emulsion layer and that, contains as a lithographic development accelerating agent a compound represented by the following general formula (I) in its silver halide emulsion layer or another hydrophilic colloidal layer: ##STR1## wherein R.sub.1 to R.sub.5 may be the same or different, and they each represent hydrogen, a halogen atom, an alkyl group, an alkoxy group, an aryl group, ##STR2## (wherein R.sub.6 and R.sub.7 each represents hydrogen or an alkyl group, or they may combine with each other to form a 5- or 6-membered nitrogen containing saturated hetero ring), --NH--CO--R.sub.8 or --NHSO.sub.2 --R.sub.9 (wherein R.sub.8 and R.sub.9 each represents an alkyl group, an aryl group or an aralkyl group), or R.sub.3 and R.sub.4, or R.sub.4 and R.sub.5 may combine with each other to form a benzene ring and that, it is necessary to said compound that at least one of substituents R.sub.1, R.sub.3 and R.sub.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: April 9, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yutaka Oka, Naomi Saeki, Yoshiharu Fuseya
  • Patent number: 4481286
    Abstract: Novel compounds which are capable of forming a coordination complex with a metal and which include a silver halide developing substituent or a precursor thereof. The compounds are useful as silver halide developing agents and as intermediates for dye developers which are utilized in photographic applications.
    Type: Grant
    Filed: October 29, 1982
    Date of Patent: November 6, 1984
    Assignee: Polaroid Corporation
    Inventors: Patrick F. King, Stephen G. Stroud
  • Patent number: 4467029
    Abstract: A silver halide light-sensitive photographic material comprises a support and a Lippmann emulsion layer on the support containing a silver halide and at least one compound of the following formula in a quantity of at least 3.5.times.10.sup.-3 mole per mole of the silver halide of the Lippmann emulsion layer: ##STR1## wherein Z represents an atomic group necessary to form a heterocyclic ring; Y is a hydrogen atom or --S--R.sub.1 group; R and R.sub.1 are each a hydrogen atom, an alkali-metal atom, ammonium or an alkyl group; X and X.sub.1 are each a divalent organic group; m and m.sub.1 are each 0 or 1; and n is an integer of up to 3, provided if n is 0, Y is --S--R.sub.1 group.The silver halide light-sensitive photographic material is developed in a developer containing at least 0.6 mole per liter of sulfurous ions.
    Type: Grant
    Filed: March 8, 1983
    Date of Patent: August 21, 1984
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Toshikazu Nishide, Akio Kobayashi, Tamio Kitahata
  • Patent number: 4452882
    Abstract: A silver halide photographic light-sensitive material and a developing process used in connection with that material are disclosed. The material is comprised of a support having thereon a silver halide emulsion layer containing a silver halide emulsion in which at least 80 mole % of the whole silver halide is composed of silver chloride, the mean grain size thereof is less than 0.4 .mu.m, and which contains more than 1.times.10.sup.-6 mole of a water-soluble rhodium salt per mole of silver at an optional period before finishing the first ripening in the production step for the silver halide emulsion. The material also contains 1.times.10.sup.-5 to 1.times.10.sup.-2 mole of polyalkylene oxide having a molecular weight of at least 600 or a derivative thereof per mole of silver. The process involves imagewise exposing the material and processing it in a developer containing 0.05 to 0.5 mole/liter of a dihydroxybenzene series developing agent, 0 to 0.05 g/liter of an auxiliary developing agent, at least 0.
    Type: Grant
    Filed: April 29, 1983
    Date of Patent: June 5, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshitaka Akimura, Eiichi Okutsu, Shigenori Moriuchi, Naomi Saeki, Taiji Hashimura, Hiroyuki Mifune
  • Patent number: 4446216
    Abstract: Photographic material which comprises in at least one silver halide emulsion layer or a layer or layers adjacent thereto at least one substituted hydroquinone compound of the formula ##STR1## where R is hydrogen or optionally substituted alkyl, aryl or a heterocyclic group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each hydrogen, halogen or optionally substituted alkyl,x is 0 or 1,y is 0 or 1,and R.sub.1 is hydrogen or a group of the formula ##STR2## where R, x and y are as just defined.
    Type: Grant
    Filed: November 23, 1982
    Date of Patent: May 1, 1984
    Inventors: Norman A. Smith, Stephen R. Postle, William E. Long
  • Patent number: 4429031
    Abstract: A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.
    Type: Grant
    Filed: October 3, 1980
    Date of Patent: January 31, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Motohiko Tsubota, Masakazu Morigaki, Tsutomu Hamaoka, Nobutaka Ohki
  • Patent number: 4414304
    Abstract: Forehardened photographic elements, particularly radiographic elements, intended to produce silver images are disclosed including among hydrophilic colloid layers at least one emulsion layer containing thin tabular silver halide grains. When developed in less than 1 minute to produce a viewable silver image, these photographic elements exhibit increased covering power.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: November 8, 1983
    Assignee: Eastman Kodak Company
    Inventor: Robert E. Dickerson
  • Patent number: 4391900
    Abstract: A process for development-processing a silver halide photographic light-sensitive material is described, comprising processing with a developing solution containing 0.1 mol/liter or more of sulfite ion and at least one compound represented by formula (I) ##STR1## wherein n represents an integer of from 2 to 6; each of R.sub.1 and R.sub.2 represents hydrogen or an alkyl group having from 1 to 6 carbon atoms; and M represents hydrogen or an alkali metal atom.According to the process, the generation of silver sludge and the formation of fog are prevented when a black-and-white photographic light-sensitive material is processed with a developing solution containing sulfates in a high concentration.
    Type: Grant
    Filed: January 13, 1982
    Date of Patent: July 5, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Toyoda, Tadao Shishido, Teruaki Tsujikawa
  • Patent number: 4385108
    Abstract: A method of forming negative dot images which comprises imagewise exposing through a contact screen a silver halide photographilic light-sensitive material of substantially the surface latent image type containing in a silver halide emulsion layer or another hydrophilic colloidal layer(a) a hydroquinone developing agent, and(b) a compound represented by the formula, R.sup.1 NHNHCOR.sub.2, wherein R.sup.1 is an aryl group which may be substituted, and R.sup.2 is a hydrogen atom, an alkyl group which may be substituted, or an aryl group which may be substituted, and thereafter processing the thus exposed light-sensitive material with an activator aqueous solution having a pH of 11.5 or more.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: May 24, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshihiro Takagi, Yoshitaka Akimura, Hiroyuki Mifune, Eiichi Okutsu
  • Patent number: 4383023
    Abstract: A gelatino-silver halide film is exposed and then developed with a tanning developer bearing a positively or negatively charged substituent, e.g., a quaternary amine-substituted hydroquinone, to produce a charged matrix in the gelatin. To enhance the image the film is then processed to mordant an oppositely charged species, e.g., an anionic dye, to the charged matrix.
    Type: Grant
    Filed: October 1, 1981
    Date of Patent: May 10, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Frank L. Schadt, III
  • Patent number: 4377634
    Abstract: A method for forming a high contrast negative photographic image, which comprises imagewise exposing a photographic material comprising a support having thereon at least one photographic silver halide emulsion layer with the photographic silver halide emulsion layer or at least one hydrophilic colloid layer of the photographic material containing a compound of the general formula (I)R.sup.1 --NHNHCO--R.sup.2 (I)wherein R.sup.1 represents an aryl group, and R.sup.2 represents a hydrogen atom, a phenyl group, or an unsubstituted alkyl group containing 1 to 3 carbon atoms, and then developing the imagewise exposed material in the presence of a hydroquinone compound of the general formula (II) ##STR1## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6, which may be the same or different, each represents a hydrogen atom, a sulfo group, an alkyl group, an aryl group, an aralkyl group, a heterocyclic group, or a group of the formula --O--R.sup.7 or --S--R.sup.7 where R.sup.
    Type: Grant
    Filed: March 11, 1980
    Date of Patent: March 22, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Yoshiharu Fuseya
  • Patent number: 4366234
    Abstract: Photographic solutions containing hydroquinone monosulphonate are prepared by a process comprising forming hydroquinone monosulphonate by reacting in solution hydroquinone, a salt of sulphurous acid and hydrogen peroxide. The reaction may be effected in the presence of one or more chemicals required for a photographic developer or after the formation of hydroquinone monosulphonate such material may be added. The invention is useful for making sodium or potassium hydroquinone monosulphonate and may be used in the preparation of a first developer for processing color reversal film, such as by the Kodak E6 process.
    Type: Grant
    Filed: May 29, 1981
    Date of Patent: December 28, 1982
    Assignee: Staveley Chemicals Limited
    Inventors: John B. Wheatcroft, Edward N. Wall
  • Patent number: 4330617
    Abstract: The compounds represented by the general formula (I) or (II) as defined in the specification are novel and useful developing agent precursors in silver halide photographic light sensitive materials.
    Type: Grant
    Filed: February 4, 1981
    Date of Patent: May 18, 1982
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Minoru Ohashi, Katsuaki Iwaosa
  • Patent number: 4323643
    Abstract: A silver halide photographic light-sensitive material is described, comprising at least one silver halide photographic emulsion layer, wherein at least one layer contains a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents hydrogen, an aliphatic group, an aromatic group, or a heterocyclic group;R.sup.3 represents hydrogen or an aliphatic group, andX represents a divalent aromatic group.The light-sensitive material provides high-contrast negative images and good dot image quality.
    Type: Grant
    Filed: November 6, 1980
    Date of Patent: April 6, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano, Yoshitaka Akimura
  • Patent number: 4294915
    Abstract: There are described novel compounds which include a silver halide developing function, a colorless ligand which is a radical of an iminodiacetic acid and a radical containing an onium group. The compounds are useful in photography as silver halide developing agents and also may be complexed with metals to form dye developers.
    Type: Grant
    Filed: July 11, 1980
    Date of Patent: October 13, 1981
    Assignee: Polaroid Corporation
    Inventor: Elbert M. Idelson
  • Patent number: 4278750
    Abstract: Novel electron donor precursors have the structure: ##STR1## where: R is an alkali labile group;Y is an aliphatic or aromatic group; andZ is an electron withdrawing group.The compounds are useful in photographic elements, film units and processes to provide electrons to immobile compounds which must accept at least one electron before releasing a diffusible dye or photographic reagent.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: July 14, 1981
    Assignee: Eastman Kodak Company
    Inventor: Chung Y. Chen
  • Patent number: 4272614
    Abstract: A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer comprising substantially surface latent image type silver halide grains, and containing in said photographic emulsion layer or at least one of other hydrophilic colloid layers a compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; Ar represents a divalent aromatic group which may be substituted; Y represents a divalent linking group; n represents 0 or 1; R.sup.2 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; and Z represents a nonmetallic atomic group necessary to form a 5-membered or 6-membered heterocyclic ring together with the ##STR2## linkage.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: June 9, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shigeo Hirano
  • Patent number: 4272606
    Abstract: A method of forming an extremely high-contrast negative photographic image which comprises image-wise exposing a photographic light-sensitive material comprising a support having thereon a mono-disperse silver halide emulsion layer containing surface latent image type silver halide grains and also containing a compound represented by the following general formula (1):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group, R.sup.2 represents a hydrogen atom, a phenyl group or an unsubstituted alkyl group having 1 to 3 carbon atoms, and then processing the exposed light-sensitive material in the presence of a compound having a thioamido moiety in the molecule thereof.
    Type: Grant
    Filed: February 1, 1980
    Date of Patent: June 9, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Yoshiharu Fuseya
  • Patent number: 4250249
    Abstract: For developing residual-moisture photographs according to the wet-film technique, a pre-treatment with a first solution of about 5% ethanolic NaOH is performed first at about 13.degree. C. After the alkali exchange, the exposed film passes through a bath at a bath temperature of 50.degree. C. with a hydroquinone-containing photographic developer. This "Two-bath wet developing method" takes place in daylight. The developed, fixed, rinsed and dried film can be evaluated directly.
    Type: Grant
    Filed: August 25, 1978
    Date of Patent: February 10, 1981
    Assignee: Siemens Aktiengesellschaft
    Inventor: Bernhard Montag
  • Patent number: 4237214
    Abstract: A process for forming a very contrasty negative photographic image which comprises developing a photographic light-sensitive material comprising a support having thereon at least one layer of a negative image monodispersed silver halide photographic emulsion comprising substantially surface latent image type silver halide grains, wherein the average grain size of the silver halide grains is 0.7 micron or less, with the silver halide photographic emulsion containing a binder in an amount of 250 g or less per mol of silver halide, and at least one hydrographic colloid layer containing a compound represented by the following general formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an aryl group and R.sup.2 represents a hydrogen atom, a phenyl group or an alkyl group having 1 to 3 carbon atoms, in the presence of a compound represented by the following general formula (II) or (III): ##STR1## wherein Z.sup.1 and Z.sup.
    Type: Grant
    Filed: July 5, 1979
    Date of Patent: December 2, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroyuki Mifune, Shunji Takada, Yoshitaka Akimura, Nobuyuki Tsujino
  • Patent number: 4192682
    Abstract: Process of forming a high-contrast silver image which process comprises treating a light-sensitive silver halide photographic material comprising a support, a silver halide emulsion layer coated thereon and another hydrophilic colloidal layer, at least one of which contains a substantially non-diffusible compound having oxidation power on a hydroquinone developing agent, with a developer containing no hydroquinone developing agent after exposed imagewise.
    Type: Grant
    Filed: January 16, 1978
    Date of Patent: March 11, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yoshio Nishina, Syunji Matsuo, Toshio Nagatani, Kazuo Takahashi, Takeshi Habu