Amino Substituent On Carbocyclic Ring Patents (Class 430/442)
  • Patent number: 6770406
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a residue of removing a hydrogen from wherein X, Y, and Z represent substituents selected independently from the groups hydrogen, alkyl group of 1 to 6 carbon atoms, cyclopropyl, aryl, arylalkyl, and heterocyclic groups, wherein at least one of X, Y, and Z is an aryl group and one of X, Y, Z, which may or may not be an aryl group, is attached in the direction of the backbone, and the other substituents are as defined in the specification. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.
    Type: Grant
    Filed: January 9, 2003
    Date of Patent: August 3, 2004
    Assignee: Eastman Kodak Company
    Inventors: James H. Reynolds, Douglas R. Robello, David H. Levy
  • Patent number: 6759187
    Abstract: This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein: the substituents are as defined in the application.
    Type: Grant
    Filed: July 11, 2000
    Date of Patent: July 6, 2004
    Assignee: Eastman Kodak Company
    Inventors: Wojciech K. Slusarek, Xiqiang Yang, Mark E. Irving, David H. Levy, Jared B. Mooberry, James J. Seifert, James H. Reynolds, Lyn M. Irving
  • Publication number: 20040126716
    Abstract: Rapid development of silver bromoiodide color negative photographic films and formation of high quality negative images suitable for scanning to produce display images of excellent quality is made possible by a novel developer solution composition and method of development. The solution is characterized by containing, in addition to the color developer compound and conventional photographic developer solution components, a water soluble pyrrolidone polymer, a high concentration of sulfite ion and a low concentration, or the absence of, bromide ion. In the novel method the developer composition contacts the exposed film at elevated temperature, e.g., 40 to 66° C., for a short development time, e.g., 20 to 90 seconds. The developed image has image quality suitable for scanning and digital manipulation to produce a digital record for forming a color display image of high quality.
    Type: Application
    Filed: July 24, 2003
    Publication date: July 1, 2004
    Inventors: Robert A. Arcus, Peter N. Bacel, John A. Weldy
  • Publication number: 20040063043
    Abstract: A method is provided that is suitable fur use in processing a digitally exposed translucent or transparent display material. The method includes exposing a translucent or transparent material to light emitted from a light source. The material contains at least one silver halide having a silver content of at least about 1 g/m2 based on the area of the material.
    Type: Application
    Filed: September 20, 2002
    Publication date: April 1, 2004
    Inventors: Hai-Xing Wan, Robert S. Harvey
  • Publication number: 20030148231
    Abstract: A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of the formula (I) 1
    Type: Application
    Filed: November 20, 2002
    Publication date: August 7, 2003
    Inventors: Christophe Bulliard, Georges Metzger, Sonia Megert
  • Patent number: 6599684
    Abstract: The present invention is directed to a photothermographic element comprising at least one imaging layer with a pyrrolotriazole coupler and a developing agent, or precursor thereof, the combination of which is capable of forming an image record in the infrared region of the light spectrum in response to a selected hue of visible light. This expedient leads to the formation of high quality images, especially when scanning photothermographic elements in which the silver halide, metallic silver, and/or any organic silver salts have not been removed. Also disclosed is a method for photothermographically forming a developed image comprising an infrared image record.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: July 29, 2003
    Assignee: Eastman Kodak Company
    Inventors: James H. Reynolds, Leif P. Olson, Wojciech K. Slusarek, David H. Levy
  • Publication number: 20030082490
    Abstract: Rapid development of silver bromoiodide color negative photographic films and formation of high quality negative images suitable for scanning to produce display images of excellent quality is made possible by a novel developer solution composition and method of development. The solution is characterized by containing, in addition to the color developer compound and conventional photographic developer solution components, a water soluble pyrrolidone polymer, a high concentration of sulfite ion and a low concentration, or the absence of, bromide ion. In the novel method the developer composition contacts the exposed film at elevated temperature, e.g., 40 to 66° C., for a short development time, e.g., 20 to 90 seconds. The developed image has image quality suitable for scanning and digital manipulation to produce a digital record for forming a color display image of high quality.
    Type: Application
    Filed: May 20, 2002
    Publication date: May 1, 2003
    Inventors: Robert A. Arcus, Peter N. Bacel, John A. Weldy
  • Patent number: 6506546
    Abstract: This invention comprises an imaging element comprising an imaging layer having associated therewith a compound of Structure I: wherein PUG is a photographically useful group; LINK 1 and LINK 2 are linking groups; TIME is a timing group; T represents t independently selected substituted or unsubstituted alkyl or aryl groups, t is 0, 1, or 2 and if t is 2, the T groups can form a ring; HET is a heterocyclic group which optionally can form a ring with a T group; R12 is hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or R12 can form a ring with a T group or with HET; 1 is 0 or 1; m is 0, 1, or 2; and n is 0 or 1.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: January 14, 2003
    Assignee: Eastman Kodak Company
    Inventors: Zbyslaw R. Owozarczyk, Xiqiang Yang, David T. Southby
  • Patent number: 6500590
    Abstract: The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80° C.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: December 31, 2002
    Assignee: Eastman Kodak Company
    Inventors: Mark E. Irving, David T. Southby
  • Patent number: 6479199
    Abstract: A method of processing a silver halide photographic material is disclosed, comprising on a support a light sensitive silver halide emulsion layer, wherein the light-sensitive layer contains a spectral-sensitizing dye represented by formula (1-a); a developer solution contains a developing agent represented by formula (A); and the replenishing rate of a processing solution is determined based on the proportion of an exposed area per unit area of the photographic material to perform replenishment.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: November 12, 2002
    Assignee: Konica Corporation
    Inventor: Junichi Fukawa
  • Publication number: 20020086249
    Abstract: A method of processing a silver halide color photographic lightsensitive material. The material comprises a support and at least one lightsensitive silver halide emulsion layer containing a binder and lightsensitive silver halide grains comprising tabular grains on the support. The material further comprises a developing agent or its precursor, and a compound capable of forming a dye by a coupling reaction with the developing agent in an oxidized form. The method comprises (a) exposing the material under natural light of 2000-9000K color temperature or artificial light corresponding thereto, for {fraction (1/10)}-{fraction (1/1000)} sec, in an exposure amount such that 80-90% (numerical ratio) of the grains contained in the lightsensitive layer have at least one development initiating point per grain, and (b) color developing the exposed material so that the tabular grains have 3.0 or more (average) development initiating points per grain at the completion of the development.
    Type: Application
    Filed: May 2, 2001
    Publication date: July 4, 2002
    Inventors: Makoto Kikuchi, Yoshio Ishii, Toshio Kawagishi
  • Publication number: 20020076661
    Abstract: The present invention provides a system of a digital color proof in which consistent images are obtained while minimizing density variation in spite of various variations of conditions due to the use of a silver halide light-sensitive color material, specifically, the present invention provides a method for forming proof images similar to printed images in terms of various characteristics such as the paper quality of silver halide light-sensitive materials, the dot gain, and the density.
    Type: Application
    Filed: September 20, 2001
    Publication date: June 20, 2002
    Applicant: KONICA CORPORATION
    Inventors: Tomonori Kawamura, Shigeo Tanaka, Satoshi Nishino, Hirohide Ito, Naohito Naraoka, Naoyo Suzuki, Shinya Watanabe, Masataka Takimoto, Hideaki Sakata, Junichi Tanabe, Tetsuya Taniguchi, Naoki Nozaki, Yasushi Okubo, Koji Daifuku, Katsuji Kondo, Toshitsugu Suzuki
  • Publication number: 20020055072
    Abstract: A multicolor negative image capture film element comprises multiple silver halide emulsion layers that together exhibit a more gradually sloped density to exposure relationship than is customary while providing a combination of improved latitude and desirable overexposure printing density reduction.
    Type: Application
    Filed: June 27, 2001
    Publication date: May 9, 2002
    Inventors: John F. Sawyer, Sharon R. Lunt
  • Publication number: 20020018956
    Abstract: This invention relates to packaged photographic film that is capable of being alternately processed, according to individual consumer choice, by either (1) a traditional wet-chemistry process with a developer solution followed by desilvering in one or more subsequent solutions to obtain a color negative film, or (2) a dry thermal process without the use of aqueous solutions in which a blocked developing agent located within the photographic element is thermally activated or unblocked, optionally followed by electronic scanning of the developed film without desilvering. This invention enables a single film stock to be developed in both a conventional deep tank process and in a dry thermal process.
    Type: Application
    Filed: May 25, 2001
    Publication date: February 14, 2002
    Inventors: David H. Levy, James H. Reynolds, David T. Southby, Paul D. Zimmerman, Mark E. Irving
  • Publication number: 20010031432
    Abstract: A processing composition for a silver halide photographic material, which comprises at least one compound selected from the group consisting of compounds represented by the following general formulae (I) and (II): 1
    Type: Application
    Filed: January 29, 2001
    Publication date: October 18, 2001
    Inventors: Yasufumi Nakai, Keizo Kimura, Shigeaki Tanaka, Yoshiharu Yabuki
  • Patent number: 6048674
    Abstract: The invention provides photographic element comprising a first light sensitive silver halide emulsion layer having associated therewith a cyan dye-forming coupler, a second light sensitive silver halide emulsion layer having associated therewith a magenta dye-forming coupler, and a third light sensitive silver halide emulsion layer having associated therewith a yellow dye-forming coupler,wherein the normalized spectral transmission density distribution curve of the dye formed by the cyan coupler upon development with a p-phenylenediamine developer has a density between 0.7 and 0.78 at 600 nm and a density between 0.8 and 0.91 at 610 nm. Such an element enables an increase in the color gamut for imaging.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: April 11, 2000
    Assignee: Eastman Kodak Company
    Inventors: Elizabeth McInerney, Patti L. Bushnell
  • Patent number: 6043006
    Abstract: 4-(N,N-Dialkylamino)aniline compounds of the following general formula (I): ##STR1## wherein R.sup.1 represents an alkyl group, an aryl group or a heterocyclic group, R.sup.2 to R.sup.5 each represent a hydrogen atom or a substituent, and R.sup.2 and R.sup.3, R.sup.1 and R.sup.2, or R.sup.4 and R.sup.5 may form a ring together; a processing composition for color photography, which contains at least one of these compounds; and a color image-forming method wherein at least one of these aniline compounds is used.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: March 28, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Kimura, Shigeo Hirano, Hiroshi Kawamoto
  • Patent number: 5994040
    Abstract: A processing composition for silver halide photographic light-sensitive material, which comprises at least one compound represented by the following formula (A), (A-I) or (A-II) and at least one compound represented by the following formula (B): ##STR1## Also disclosed are a developer prepared from the processing composition, and a processing method using the developer.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: November 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinnichi Morishima, Kohzaburoh Yamada, Seiji Yamashita, Minoru Sakai, Kouta Fukui, Eiichi Okutsu
  • Patent number: 5888708
    Abstract: A development processing method comprising developing a silver halide photographic material with a developing solution, (i) wherein the silver halide photographic material comprises a support having thereon at least one light-sensitive silver halide emulsion layer and contains: (a) at least two kinds of light-sensitive silver halide emulsions which are each spectrally sensitized and have sensitivities different from each other with respect to a certain exposure wavelength; and (b) at least one hydrazine derivative in at least one of the silver halide emulsion layer and other hydrophilic colloidal layers, and (ii) wherein the developing solution is substantially free from a dihydroxybenzene compound, has a pH of from 9.0 to 10.5 and contains: (1) at least one ascorbic acid developing agent and (2) at least one auxiliary developing agent represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.
    Type: Grant
    Filed: January 28, 1998
    Date of Patent: March 30, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kouta Fukui, Senzo Sasaoka
  • Patent number: 5773203
    Abstract: Disclosed are 4-(N,N-dialkylamino)aniline compounds having a 4-N substituent which is a polyethyleneoxy group and which forms a condensed ring with benzene ring, such as aniline compounds having the following structure, a processing composition containing such a compound and a method for forming a color image with the processing solution. The aniline compound is useful as a color developing agent capable of having a low fog density and sufficient yellow and cyan image densities and suitable for the rapid process.
    Type: Grant
    Filed: May 14, 1997
    Date of Patent: June 30, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Kimura, Shigeo Hirano, Hiroshi Kawamoto
  • Patent number: 5773208
    Abstract: The invention relates to an emulsion comprising silver halide grains, said grains being tabular and comprising sensitizing dye(s) and silver salt epitaxial deposits, and addenda that includea tetraazaindene and a hexose reductone represented by Formula I: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or an alkyl group with a solubilizing group such as --OH, sulfonamide, sulfamoyl, or carbamoyl. Alternatively, R.sub.1 and R.sub.2 may be joined to complete a heterocyclic ring such as aziridinyl, azetidinyl, pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl, or pyridinyl, R.sub.4 and R.sub.5 are H, OH, alkyl, aryl, cycloalkyl, or may together represent an alkylidene group, n is 0,1, or 2 and R.sub.3 is H, alkyl, aryl, or CO.sub.2 R.sub.6 where R.sub.6 is alkyl.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: June 30, 1998
    Assignee: Eastman Kodak Company
    Inventors: Jeffrey L. Hall, James H. Reynolds
  • Patent number: 5763146
    Abstract: The invention relates to a silver halide photographic emulsion comprising silver halide grains and the reductone of Formula I ##STR1## wherein R.sub.1 and R.sub.2 are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or an alkyl group with a solubilizing group such as --OH, sulfonamide, sulfamoyl, or carbamoyl, R.sub.1 and R.sub.2 may be joined to complete a heterocyclic ring such as aziridinyl, azetidinyl, pyrrolidinyl, piperidinyl, morpholinyl, piperazinyl, or pyridinyl, R.sub.4 and R.sub.5 are H, OH, alkyl, aryl, cycloalkyl, or may together represent an alkylidene group, n is 1 or 2 and R.sub.3 is H, alkyl, aryl, or CO.sub.2 R.sub.6 where R.sub.6 is alkyl, andwherein the logarithm of the partition coefficient for the reductone when equilibrated as a solute between n-octanol and water (logP) is less than 0.293.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: June 9, 1998
    Assignee: Eastman Kodak Company
    Inventors: James H. Reynolds, Steven P. Szatynski, Jeffrey L. Hall, Norma B. Platt
  • Patent number: 5763145
    Abstract: The invention provides a multicolor photographic element comprising a support bearing at least two silver halide emulsion layers having different sensitivities to blue light, a silver halide emulsion layer sensitive to green light, and a silver halide emulsion layer sensitive to red light, wherein:(1) the element comprises a compound of formula (I): ##STR1## wherein R.sub.1 and R.sub.2, independently represent H, an alkyl group or an aryl group, provided that R.sub.1 and R.sub.2 may be joined to form a ring;R.sub.3 is selected from the group consisting of H, alkyl, aryl, and acyl groups;R.sub.4 and R.sub.5 are independently selected from the group consisting of H, OH, alkyl, and aryl groups;n is 1 or 2;and(2) the silver halide emulsion layer of the element that is most sensitive to blue light contains a silver halide grain population such that from 3 to 20 wt % of the total silver halide grains in the emulsion layer have a size (equivalent circular diameter) less than 0.2 micrometers.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: June 9, 1998
    Assignee: Eastman Kodak Company
    Inventor: Hans G. Ling
  • Patent number: 5721093
    Abstract: A method for forming a color image comprises the step of developing an image-wise exposed silver halide color photographic photosensitive material at the presence of the following color developing agent or its analogue. According to this method, the rapid process can be attained, forming an image having only a slight fog, sufficient yellow and cyan image densities and a high image fastness.
    Type: Grant
    Filed: March 6, 1996
    Date of Patent: February 24, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keizo Kimura, Shigeo Hirano
  • Patent number: 5716772
    Abstract: Provided is a silver halide photographic material excellent in discrimination, which comprises on a support at least one compound represented by formula (1): ##STR1## wherein R.sub.1 to R.sub.4 each represents a hydrogen atom or a substituent, with the proviso that the sum of the Hammett substituent constants .sigma..sub.p values of R.sub.1 to R.sub.4 is 0 or more; and R.sub.5 to R.sub.9 each represents a hydrogen atom or a substituent and at least one of R.sub.5 and R.sub.9 is a substituent, wherein R.sub.1 and R.sub.2, R.sub.5 and R.sub.6, R.sub.6 and R.sub.7, R.sub.7 and R.sub.8, or R.sub.8 and R.sub.9 may combine with each other to form a ring.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: February 10, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiki Taguchi
  • Patent number: 5702865
    Abstract: Relief images can be formed in photographic elements having a tanning developing agent incorporated therein. The tanning developing agents have the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each an alkyl group of at least 3 carbon atoms, or an aryl group,After exposure, the material is treated with an alkaline solution and unhardened areas are removed.
    Type: Grant
    Filed: October 10, 1996
    Date of Patent: December 30, 1997
    Assignee: Eastman Kodak Company
    Inventor: Michael John Simons
  • Patent number: 5700630
    Abstract: A silver halide photographic material is disclosed which comprises a support having thereon at least one light-sensitive silver halide emulsion layer containing silver halide grains, a surface protective layer as an uppermost layer, and a hydrophilic colloid layer other than said at least one light-sensitive silver halide emulsion layer and said surface protective layer, wherein the sum of the silver amount contained in each of said at least one light-sensitive silver halide emulsion layer is from 0.8 g/m.sup.2 to 1.5 g/m.sup.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: December 23, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Rikio Inoue, Sumito Yamada
  • Patent number: 5645962
    Abstract: A method is provided for manufacturing a multicolor filter array element, firmly associated with a transparent electrode layer in a multicolor liquid crystal display device, comprising the steps of:(i) exposing a silver halide color photographic (print) material comprising a plurality of differently spectrally sensitive silver halide emulsion layers on a glass support, with a single step multicolor pixelwise exposure,(ii) color processing said exposed print material producing thereby in each silver halide emulsion layer a differently colored pixel pattern,(iii) coating said color processed print material at its silver halide emulsion layer assemblage side with a hydrophobic water-impermeable organic resin layer(iv) curing said organic resin layer by heating said layer at temperatures between 100.degree. C. and 250.degree. C.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: July 8, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Luc Vanmaele, Jean-Pierre Tahon, Raymond Roosen
  • Patent number: 5614356
    Abstract: A method for forming a color image comprises the step of developing an image-wise exposed silver halide color photographic photosensitive material at the presence of the following color developing agent or its analogue. According to this method, the rapid process can be attained, causing only a slight deterioration of the developer with time and capable of sufficiently exhibiting high yellow and cyan densities to achieve an excellent color balance.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: March 25, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazumi Nii, Kiyoshi Morimoto
  • Patent number: 5604082
    Abstract: A method has been disclosed of processing an exposed silver halide photographic material comprising at least one coated hydrophilic silver halide emulsion layer comprising tabular grains rich in chloride, bounded by [100] or [111] major faces, characterized by the steps of developing, followed by fixing, rinsing and drying the said material, wherein developing proceeds in a developer, comprising hydroquinone in an amount from 0 to 30 g per liter, an auxiliary developer, as silver halide complexing agents alkali metal sulphite salts in an amount from 1 to 50 g per liter, at least 1 g of a compound corresponding to the formula (I), a precursor thereof, a derivative thereof and/or a metal salt thereof ##STR1## wherein the substituents are defined in the main embodiment of the specification.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: February 18, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Freddy Henderickx, Hieronymus Andriessen, Ann Verbeeck
  • Patent number: 5593817
    Abstract: A photographic developing solution and a method of developing silver halide materials in the said developing solution is disclosed, the said developing solution comprising hydroquinone in an amount from 0 to 30 g per litre, an auxiliary developer, and silver halide complexing agents in an amount from 0 to 50 g per litre, characterized in that said developer further comprisesin amounts from 0.1 to 5 g per litre a compound corresponding to the formula (I), accompanied by charge compensating anions,Z'N.sup.+ --R--N.sup.+ Z" (I)wherein at least divalent group R contains at least one oxyethylene group and wherein Z' and Z", being the same or different, are composed of enough atoms to form a heterocyclic aromatic 5- or 6-ring;andat least 1 g of a compound corresponding to the formula (II), a precursor thereof, a derivative thereof and/or a metal salt thereof ##STR1## wherein each of A, B and D independently represents an oxygen atom or NR.sup.1 ;X represents an oxygen atom, a sulphur atom, NR.sup.2 ; CR.sup.3 R.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: January 14, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Freddy Henderickx, Ann Verbeeck, Pascal Meeus, Hieronymus Andriessen
  • Patent number: 5556736
    Abstract: A method for processing an exposed silver halide color photographic photosensitive material is disclosed, which comprises the step of developing the exposed material with a color developer in a color development tank of an automatic developing apparatus, the developer in the developer tank being replenished with replenishing water and a solid color developing composition comprising a p-phenylenediamine color developing agent having a water-solubilizing group, wherein the replenishing amount of the water is 30 to 75 ml per m.sup.2 of the material processed and the replenishing amount of the color developing agent is 0.024 to 0.066 mol per liter of the replenishing amount of the water.
    Type: Grant
    Filed: October 19, 1994
    Date of Patent: September 17, 1996
    Assignee: Konica Corporation
    Inventors: Tsuyoshi Haraguchi, Ichiro Tsuchiya
  • Patent number: 5508155
    Abstract: Substituted hydroxylamine antioxidants can be prepared by reacting hydroxylamine or a mono-substituted hydroxylamine with an epoxide. The antioxidant reaction product is not removed from the reaction mixture, but is used without separation after combination with a color developer to provide a photographic color developer composition. The antioxidants are highly water soluble and thus exhibit no objectionable odor.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: April 16, 1996
    Assignee: Eastman Kodak Company
    Inventors: Carl A. Marrese, Paul A. Zielinski
  • Patent number: 5492796
    Abstract: A silver halide color photographic material having on a support at least one light-sensitive silver halide emulsion layer, wherein the color photogrphic material contains a nondiffusing coupler represented by formula (I):Cp--(LINK).sub.n --N(R.sub.1)--Ar(OR.sub.2)--X (I)wherein Cp represents a coupler residue (residual group) which can undergo coupling reaction with the oxidation product of a color developing agent to release --(LINK).sub.n --N(R.sub.1)--Ar(OR.sub.2)--X; LINK represents a group which can release --N(R.sub.1)--Ar(OR.sub.2)--X after cleavage of bond to Cp; n represents 0 or an integar of 1 or 2, Ar represents an arylene group; X represents an amino group, an alkoxy group or a hydroxyl group; R.sub.1 represents a hydrogen atom or a substituent; and R.sub.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: February 20, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masashi Ogiyama, Seiji Ichijima
  • Patent number: 5478704
    Abstract: i) A method of forming color images improved in color reproducibility and sharpness, which comprises providing a silver halide color photographic material which has on a support at least one emulsion layer unit constituted of at least two silver halide emulsion layers having the same color sensitivity and different photographic speeds, and which contains at least one DIR compound represented by the following general formula (II) in at least one layer selected from said emulsion layer unit and other constituent layers; exposing said color photographic material, and processing said color photographic material with a color developer containing at least one compound represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an alkyl group or a hydroxyalkyl group containing; R.sub.2 represents an alkylene group containing, or a straight-chain or branched hydroxyalkyiene group containing 3 to 6 carbon atoms; R.sub.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: December 26, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Taniguchi, Nobutaka Ohki, Mitsuru Yamamoto, Akimitsu Haijima
  • Patent number: 5460919
    Abstract: A process of forming a super high-contrast negative image is disclosed, which comprises the steps of imagewise exposing a negative-working silver halide photographic material comprising a support having thereon one or more hydrophilic colloidal layers, at least one of the one or more hydrophilic colloidal layers being a negative-working silver halide emulsion layer, and then developing the photographic material with a developer containing an aminophenol derivative developing agent and a reductone compound in the existence of an organic compound having a negative reduction potential. A negative-working silver halide photographic material and a photographic developer being used for the image-forming process are also disclosed.
    Type: Grant
    Filed: July 22, 1994
    Date of Patent: October 24, 1995
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu, Jun Takeuchi, Kiyoshi Suematsu
  • Patent number: 5459014
    Abstract: A method for forming a color photographic image is disclosed. The method comprises steps ofimagewise exposing a silver halide color photographic light-sensitive material comprising a support, and a silver halide emulsion layer and a non-light-sensitive layer each provided on the support,developing the light-sensitive material with a color developer, andbleach-fixing the developed light-sensitive material with a bleach-fixing solution,wherein the silver halide emulsion layer or the non-light-sensitive layer contains a compound represented by the following Formula 1 and the color developer contains a chloride in an amount of not less than 6.times.10.sup.-2 moles per liter; ##STR1## wherein R.sub.1 is a tertiary alkyl group; R.sub.2 is a primary or a secondary alkyl group; R.sub.3, R.sub.4 and R.sub.5 are each an alkyl group, an alkoxycarbonyl group, a phenoxycarbonyl group, an alkoxy group, a phenoxy group or a phenylthio group, the groups represented by R.sub.1, R.sub.3, R.sub.4 or R.sub.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: October 17, 1995
    Assignee: Konica Corporation
    Inventors: Toyoki Nishijima, Motoi Nishimura
  • Patent number: 5427897
    Abstract: A method for processing an imagewise exposed silver halide color photographic material comprising a support having thereon at least a silver halide emulsion layer containing a cyan dye-forming coupler, a silver halide emulsion layer containing a magenta dye-forming coupler, and a silver halide emulsion layer containing a yellow dye-forming coupler: wherein the silver halide color photographic material contains at least one cyan dye-forming coupler represented by the following general formula (I) or (II) in the silver halide emulsion layer containing the cyan dye-forming coupler: and wherein the processing comprises color developing the imagewise exposed silver halide color photographic material with a color developer containing a p-phenylenediamine derivative represented by the following general formula (III): ##STR1## wherein the substituents are defined herein the specification.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: June 27, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Nakamura, Masato Taniguchi
  • Patent number: 5419997
    Abstract: A method for processing a silver halide photographic material is disclosed and the photographic material has a support thereon, comprising at least one silver halide emulsion layer and containing a hydrazine compound represented by following formula (I) in the above emulsion layer or the other hydrophilic colloid layers, which comprises processing the silver halide photographic material after exposure in a developing solution containing:(1) 0.2 to 0.75 mole/liter of a dihydroxybenzene developing agent,(2) 0.001 to 0.06 mole/liter of a 1-phenyl-3-pyrazolidone or p-aminophenol auxiliary developing agent,(3) 0.3 to 1.2 mole/liter of a free sulfite ion, and(4) a compound represented by following formula (II), and having a concentration ratio of a compound represented by formula (II) to a dihydroxy developing agent of 0.03 to 0.12 and pH of 9.0 to 11.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: May 30, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mitsunori Hirano
  • Patent number: 5380625
    Abstract: A method for processing a silver halide color photographic material, which comprises processing an image-wise exposed silver halide color photographic material comprising at least one silver halide emulsion layer and containing an N,N-substituted malondiamide type coupler with a color developer containing an aromatic primary amine color developing agent represented by the following general formula (D) or (E): ##STR1## In a preferred embodiment, the photographic light-sensitive material contains a cyan coupler represented by the following general formula (C): ##STR2##
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: January 10, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Masato Taniguchi, Naoki Saito
  • Patent number: 5372911
    Abstract: A process of forming a super high-contrast negative image is disclosed, which comprises the steps of imagewise exposing a negative-working silver halide photographic material comprising a support having thereon one or more hydrophilic colloidal layers, at least one of the one or more hydrophilic colloidal layers being a negative-working silver halide emulsion layer, and then developing the photographic material with a developer containing an aminophenol derivative developing agent and a reductone compound in the existence of an organic compound having a negative reduction potential. A negative-working silver halide photographic material and a photographic developer being used for the image-forming process are also disclosed.
    Type: Grant
    Filed: June 11, 1992
    Date of Patent: December 13, 1994
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Naoki Obi, Yasuhiko Kojima, Yasuo Shigemitsu, Jun Takeuchi, Kiyoshi Suematsu
  • Patent number: 5346809
    Abstract: A method of photographic color image formation is disclosed. The method gives a color photographic image having high preservability under a condition with a lowered replenishing amount of developer. The method comprises the following steps;(1) imagewise exposing to light a silver halide color photographic light-sensitive material which comprises a support having thereon a silver halide emulsion layer,(2) developing the exposed light-sensitive material with a color developer,(3) bleach-fixing the developed light-sensitive material with a bleach-fixer, and(4) washing the bleach-fixed light-sensitive material, In the above method, the silver halide emulsion layer contains a specified yellow coupler having a molecular weight of not more than 800 and a specified antifungal agent. The developing step is carried out for a time not more than 25 seconds and developer is replenished with a developer replenisher in a ratio of from 20 ml to 150 ml per square meter of light-sensitive material developed the developer.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: September 13, 1994
    Assignee: Konica Corporation
    Inventors: Shun Takada, Satoshi Masumi
  • Patent number: 5328812
    Abstract: A dye image-forming method comprising color developing an image wise exposed silver halide color photographic material comprising a support having thereon a layer containing an acylacetamide yellow coupler having an acyl group represented by a following formula (YI) ##STR1## wherein R.sub.1 represents a monovalent group; Q represents a group of atoms necessary to form 3- or 5-membered hydrocarbon ring or a 3- to 5-membered heterocylcic ring; provided that R.sub.1 is not a hydrogen atom and is not combined with Q to form a ring; with a developing solution containing at least one aromatic primary amine color developing agent represented by formula (D) or (E): ##STR2## wherein R.sub.4 represents a linear or branched alkyl group having 1 to 6 carbon atoms or a linear or branched hydroxyalkyl group having 3 to 6 carbon atoms; R.sub.5 represents a linear or branched alkylene group having 3 to 6 carbon atoms or a linear or branched hydroxyalkylene group having 3 to 6 carbon atoms; R.sub.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: July 12, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akimitsu Haijima, Masato Taniguchi
  • Patent number: 5324624
    Abstract: An imagewise exposed photographic silver halide color material is treated in a first processing bath containing a developer solution comprising a color developing agent. After treatment in the first bath, the photographic material is treated in a second processing bath containing a developer/amplifier solution comprising an amplifying oxidant and the color developing agent, wherein developer solution is carried over with the photographic material from the first bath to the second bath. The second bath is replenished with developer/amplifier replenisher solution. The first bath is replenished with developer replenisher solution in sufficient volume to cause overflow of the developer solution from the first bath, which overflow is conveyed from the first bath to the second bath. The concentration of the color developing agent in the developer/amplifier solution of the second bath is maintained at 0.1 to 20 g/l.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: June 28, 1994
    Assignee: Eastman Kodak Company
    Inventor: Peter J. Twist
  • Patent number: 5310634
    Abstract: A p-phenylenediamine series color developing agent or a precursor thereof having a substituent A at the ortho-position; Substituent A: ##STR1## wherein R.sup.1 represents a hydrogen atom or an alkyl group and X represents --O--R.sup.7 or ##STR2## wherein R.sup.7 represents an alkyl group, an aryl group, or a heterocyclic ring and R.sup.8 and and R.sup.9, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group, or a heterocyclic ring, R.sup.8 and R.sup.9 may combine with each other to form a heterocyclic ring, and a process for forming an image which comprises imagewise exposing a silver halide color photographic material and thereafter color developing the color photographic material in the presence of a p-phenylenediamine series color developing agent or a precursor thereof having the aforesaid substituent A.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Mikoshiba, Mitsugu Tanaka, Kei Sakanoue
  • Patent number: 5278034
    Abstract: A process for forming a color image comprises the step of developing an image-wise exposed silver halide color photographic material with a color developing composition containing an N-(4-aminophenyl)pyrrolidine derivative such as ##STR1## which produces an excellent hue in a rapid process.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: January 11, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobutaka Ohki, Koichi Nakamura, Masato Taniguchi
  • Patent number: 5264331
    Abstract: There are provided p-phenylenediamine color developing agent such as ##STR1## which makes it possible to form a yellow dye having a color image fastness to light while its ordinary photographic properties such as the developing activity and hue are kept. A processing liquid composition for a silver halide color photosensitive material comprises the p-phenylenediamine color developing agent and a pH buffering agent, and has a pH of 9 to 12. A process for forming a color image of claim comprises color-developing an image-wise exposed silver halide color photographic material with the processing liquid composition at a temperature of 30.degree. to 45.degree. C. for 20 seconds to 4 minutes.
    Type: Grant
    Filed: June 11, 1991
    Date of Patent: November 23, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Taniguchi, Nobutaka Ohki, Koichi Nakamura
  • Patent number: 5236803
    Abstract: A color light-sensitive material comprising a support having thereon at least one light-sensitive layer containing light-sensitive silver halide, and further comprising in the at least one light-sensitive layer or any other layer, independently, a binder, a reducible dye-providing compound, and a reducing agent represented by formula (I): ##STR1## wherein X represents --CO-- or --SO.sub.2 --; R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group, an aryl group or a heterocyclic group, any of which groups may be substituted; R.sup.3 represents a hydrogen atom, a halogen atom, an aryl group, an acylamino group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an acyl group, a sulfonyl group, a carbamoyl group or a sulfamoyl group, any of which groups may be substituted; R.sup.2 and R.sup.3 may be combined together to form a carbocyclic ring or a heterocyclic ring; and the reducing agent may be in the form of a dimer or a trimer through R.sup.1 or R.sup.
    Type: Grant
    Filed: July 27, 1992
    Date of Patent: August 17, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Michio Ono, Takeshi Nakamine, Hiroyuki Hirai
  • Patent number: 5206123
    Abstract: A method for high contrast development of an image-wise exposed photographic element comprising a support and at least one silver halide emulsion layer, which method comprises contacting said exposed element in the presence of a hydrazine compound with an aqueous alkaline developing solution which has a pH between 10 and 13 and contains a dihydroxybenzene developing agent a 3-pyrazolidinone or an aminophenol developing agent sulphite ions and a contrast promoting amount of an amino compound characterized in that said developing solution further contains an aprotic solvent corresponding to general formula (I) or (II) : ##STR1## wherein R.sub.1 represents alkyl, substituted alkyl, alkylamino or substituted alkylamino, andR.sub.2 and R.sub.3 each independently represent alkyl substituted alkyl orwherein R.sub.1 together with R.sub.2 represent the necessary atoms to form together with the carbon and the nitrogen atom respectively to which they are attached, a heterocyclic ring, and R.sub.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: April 27, 1993
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Richard A. Ooms, Piet Kok
  • Patent number: 5202229
    Abstract: A method for forming a color photographic image is disclosed. The method comprises steps ofimage wise exposing to light a silver halide color photographic light-sensitive material which has a silver halide emulsion layer containing silver halide grains having a silver chloride content of not less than 50 mol %, and the amount of silver coated on said light-sensitive material is not less than 2 g/m.sup.2 in total, anddeveloping said exposed light-sensitive materiaI with a color developer containing a color developing agent represented by the following Formula I; ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently a methyl group, an ethyl group, a propyl group, a hydroxyethyl group, sulfon-alkyl group or a .beta.-methanesulfonamidoethyl group, provided that at least one of groups represented by R.sub.1, R.sub.2 and R.sub.3 is a .beta.-methanesulfonamidoethyl group; X is surfuric acid, hydrochloric acid, p-toluene-sulfonic acid or phosphoric acid.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: April 13, 1993
    Assignee: Konica Corporation
    Inventors: Satoru Kuse, Hiroaki Kobayashi